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By Melânea Almeida Ramalho Medeiros

A liga de níquel 718 encontra aplicações variadas nas indústrias aeronáutica, aeroespacial, óleo e gás e nuclear em função da excelente combinação entre resistência e ductilidade. As diferentes formas de processamento utilizadas para sua elaboração tendem a unir processos de deformação com temperatura, a fim de melhorar as propriedades mecânicas do material. Sendo assim, o presente trabalho tem como objetivo a caracterização e investigação do efeito de rotas de processamento termomecânicos distintas, avaliando a repercussão na fração de contornos especiais, dos carbetos (Nb,Ti)C e nas propriedades mecânicas do material endurecido por precipitação.

Aug 17, 2017

By M. G. Schulz

Mining of molybdenum at Questa, New Mexico has been accomplished by block cave methods since August, 1983. As caving progresses, a periodic geologic evaluation is made of the rock-types present in finger raises on the Grizzly Level of the mine. The production maturity of the cave can be monitored by relating this data to geologic cross-sections through the ore body. The draw point mapping program is a simple and effective tool that is used in making draw control decisions at Questa.

Jan 1, 1985

By Breno Totti Maia

A aciaria 1 da Usiminas Ipatinga é composta por 03 convertedores BOF e uso de ventaneiras para promover a melhor mistura do banho. No intuito de garantir e melhorar a estabilidade operacional da etapa sopro na produção, foi iniciado uma séria de desenvolvimentos na lança de oxigênio através da aplicação da tecnologia Slagless® com objetivos de melhorar a formação de escória, evitar cascão de lança, evitar cascão no sistema OG (recuperação de gases) e aumentar a disponibilidade de lanças através do aumento de sua vida. Os resultados apresentados são extremamente favoráveis, pois após a implementação da tecnologia, todos os objetivos foram atingidos associado com uma vida extremamente elevada do bico de lança, agora chamado cartucho, garantindo estabilidade e conforto operacional para a equipe da aciaria 1 da Usiminas Ipatinga.

Aug 15, 2017

By W. J. Birch, R. Farnfield

Nuisance caused by perceived high vibration levels as a result of blasting on quarries and opencast coal mine is now the number one environmental concern of residents living adjacent to such operations. The intrinsic nature of blast vibration monitoring and prediction is that it is impossible to accurately forecast the vibration levels that will be experienced by a given blast at a given location. Thus it is that a statistical approach to the problem is the only viable option. Unfortunately, persuading local residents living adjacent to a project that requires blasting that this is the best way of safe guarding both their homes and their quality of life is not an easy task. Thus routine monitoring involving both operators and regulators play a key role in building trust. However, public confidence is often shaken when regulators and operators use two different blast monitoring instruments side by side to record a blast at a local resident’s house and arrive at different results. To make certain that this does not happen in future, what is needed is a protocol that ensures that any two different blasting seismographs give the same peak particle velocity values at the same observation point. To do this all the equipment manufacturers, regulators and relevant professional explosive engineering bodies need to be involved.

Jan 1, 2014

By Roy Woodall

Successful mineral exploration is the lifeblood of the mining industry. Contrary to what the environmental lobby would have the world believe, the industry is replacing the metals it is extracting. The reserve base has not changed significantly in 20 years (Fig. 1.) Mineral exploration is a research activity. First there is the idea, the vision or the intuitive thought. The experiments follow. These involve repeated phases of data gathering, data interpretation and concept testing through drilling. For many companies, exploration is the main investment in scientific research. Each mineral exploration experiment may involve years of costly work. Despite the improving tools of science and technology, the investment remains high-risk. Only the promise of high rewards, or desire to survive as a mining company, will stimulate the necessary commitment and level of investment. Confidence that an economic return can be achieved, confidence in the science and technology being applied and confidence in the people involved are the foundations upon which successful mineral exploration is built (Woodall, 1984). The challenges facing the explorationist in the 1990s fall into two categories: - the challenge to make the activity economic; and - the challenge to make the activity socially and, therefore, politically acceptable.

Jan 1, 1992

By F. R. Archibald, C. F. Jackson

THE prospect of winning aluminum from clay was recorded almost a century ago at a time when the metal was no more than a curiosity.? As the industry developed, and it has probably developed faster than that of any other metal, the expanding need for raw materials was adequately met by the ample supplies of bauxite ore. As with the other metals older in industry, however, lower grade ores have gradually entered the raw-material field through improvements in ore dressing, insufficienoy of high-grade ore supplies, favorable geographic location, or national necessity for domestic supply. So with aluminum, or alumina, which has been established as the requisite intermediate, the time may have come when a satisfactory process, with favorable location and suitable raw materials, can hold a sound place both in metallurgy and economics. It is the purpose of this paper to describe the Ancor process and its proposed application in treatment of clay in a plant now under construction at Harleyville, South Carolina, by the Defense Plant Corporation. DEVELOPMENT OF THE ANCOR PROCESS The Ancor process has developed through successive stages of laboratory investigation, pilot-plant demonstration using nepheline syenite and pilot-plant demonstration using kaolin-type day from South Carolina, and is now in preparation for unit trial on an operating plant basis using the latter material. The laboratory studies were carried out over a number of years in the laboratory of the American Nepheline Corporation in Rochester, N. Y., and for the same company in the ore-dressing laboratory of Beattie Gold Mines, Que. Ltd. at Duparquet, Quebec. Both companies are associated with Ventures Ltd., Toronto, and its associated American companies. The work was originally undertaken with a view to recovery of alumina and alkalies from nepheline syenite as an adjunct to the American Nepheline Company's established business in the glass and ceramic trades, but as a process developed the possibility of application to clay and other aluminous raw materials become apparent and the laboratory studies were broadened to include these as well. Under the more pressing impetus of wartime needs and possibilities, pilot-plant operations were undertaken at the Canadian Bureau of Mines Ore Dressing Laboratories in Ottawa, and for purposes of demonstration under joint sponsorship of the Canadian Bureau of Mines, The American Nepheline Corporation, and The Aluminum Company of Canada Ltd.

Jan 1, 1944

By J. Brent Hiskey

At present, approximately 80 % of the worlds mine production of copper is achieved by smelting and electrorefining. The principle aim of copper electrorefining is to satisfy the large demand for extremely pure copper. It is remarkable that high quality copper cathodes with the required purity (99.99+% Cu, ASTM B115-10) and structural characteristics (i.e. deposit density and morphological texture) are produced from impure copper anodes dissolved in electrolytes containing a variety of impurities. This is accomplished with the proper control of operating parameters such as: current density; temperature; copper and sulfuric acid concentration; agitation; substrate preparation; and the application of electrolyte additives. The basic elements of the electrolysis of copper have not changed significantly over the past 150 years since the early developments of James Elkington. Importantly, our fundamental understanding of the underlying electrochemistry has advanced considerably. This is especially true regarding our knowledge of the mechanistic role of additives during the electrocrystallization of copper. This is a very complex subject and modern electrochemical techniques and the development of surface characterization and imaging instruments has helped immensely in our ultimate understanding of how additives control the deposit structure and morphology. The purpose of this paper is to review the historical development and application of electrolyte additives in copper electrorefining and to examine our current knowledge regarding their use. INTRODUCTION The first transatlantic telegraph cable was completed in August 1858. Regrettably, this cable failed shortly after the initial connections. After several more failed attempts, improvements in materials and copper quality resulted in successful communication between Europe and America on July 28, 1866. In many ways this hallmark event demonstrated the need for high purity copper. The first copper refinery in the world was commissioned in May 1869 in Pembrey, South Wales by partners Josiah Mason and James Balleney Elkington. (Historical Note). The 1865 and 1868 British patents issued to James Balleney Elkington were the foundation for the first commercial production of high purity electrolytic copper (Elkington, 1865, 1869, 1870). This important achievement was made possible primarily by the invention of the dynamo which was based on the fundamental operating principles advanced by Michael Faraday. A symbiotic relationship between copper refining and the dynamo was henceforth established. The dynamo provided electric current for electrolytic refining of copper and the electrorefining tankhouse provided pure copper which was required for the generation and transmission of electricity.

Jan 1, 2019

By Leslie G. McMillion

A field project to develop and demonstrate a method for alleviating problems of highly mineralized ground water where they occur as isolated zones or pockets in fresh-water aquifers is being conducted in the Ogallala aquifer of eastern New Mexico by the Robert S. Kerr Water Research Center. Removal of contaminated water is by a large-capacity well and the pumped poor-quality water is used locally for secondary recovery of oil. Benefits of the operation are threefold in that the aquifer is being reclaimed for future fresh-water production, contaminated water is being used beneficially, and fresh water which otherwise would have been used for waterflooding is available for other purposes. Ground-water quality in the site has improved markedly after two years of operation. Use of water in the arid and semiarid Southwest has grown so rapidly that demands in many localities far exceed available supplies. In the High Plains region of New Mexico, Oklahoma, and Texas, the only large sources of water are underground reservoirs, being depleted at an alarming rate. In some parts of this region, the aquifers contain pockets of highly mineralized waters; and the mineralized waters in some of them have started spreading in response to the drawdown effects of pumping wells. The aquifers of this region are primarily composed of sand and gravel beds; any cleanup by natural processes will require many tens or even hundreds of years. Most of these pockets of highly mineralized water were caused by oil-field brines seeping downward from earthen disposal pits. Thousands of these pits were in use in the region until only a few years ago when they were prohibited by the oil regulatory agencies of the respective states. The resulting areas of poor quality water are serious enough to warrant much corrective attention. Correction will involve one or more of three approaches: 1) Restrict the pumping of fresh water in the zones where the drawdown of the pumping well will significantly influence the movement of the contaminant. 2) Remove the highly mineralized water entirely from the affected area. 3) Develop and pump the poor-quality water in such a manner that its movement is held in check, even though only a part of the contaminant is actually removed. The principal hurdle to overcome in applying methods 2 or 3 is financing of the operations, since there are very

Jan 1, 1972

MAY began with a general strike of the bituminous and anthracite coal miners in the United States in progress, while in Great Britain about three quarters of a million workers became idle by a lockout, caused by a dispute respecting the question of the rights of management in their shops. The employers opened their shops on May 3 to men wishing to resume work, but few availed themselves of the opportunity. Up to this time the statistics had been showing a little increase in the rate of employment in Great Britain and business conditions were considered to be improving. From Russia came reports that the results of the famine had not been so bad as had been prophesied, which is not to say that they were not grievous. In prognostications such things are habitually overesti-mated. Seeding for the new crop has now begun in Russia, with hopes for better results than last year. However, the general economic situation in Russia steadily becomes worse. We had advices during May to the effect that the Soviet Government had decided to abolish the gold ruble even as a theoretical calculating unit and substitute a "goods index." This idea would be somewhat on the lines of Professor Fisher for stablizing the dollar, and there may be a chance to see how it will work in practice. There was a contradictory report from Russia, however, that it had been decided to revert to the gold basis. This is the more plausible report, for if there be anything to be deduced from economic theory and history the present paper rubles will completely collapse and return to gold basis will ensue simply because the people will refuse to sell their goods on anything else. The civil war in China came to a head during the first week in May when General Wu-Pei-fu crushed the forces of General Chang Tso-lin around Pekin. The victor declared his intention to be to reunite the North and the South and in course of time to arrange for a constitutional convention. We probably do not under-stand the conditions in China, but recent events do not appear to have solved the grave difficulties there, though they may be a step toward it. However, the immediate outlook does not appear good, General Chang having retired to the north and declared the secession of Manchuria and Mongolia.

Jan 6, 1922

By Louis V. Bender, R. E. H. Pomeroy, David H. Browne

E. P. Mathewson, Anaconda, Mont.—After hearing about the success of D. H. Browne with his furnaces, we in Anaconda decided we might venture into the field of pulverized coal for reverberatory smelting. We sent a delegation of investigators to see Mr. Browne and his work, and they returned, filled with enthusiasm, and said they would recommend it strongly.. We thereupon asked for an appropriation, and after some delay obtained the same and fitted up one furnace to use pulverized coal. We copied Mr. Browne's practice and his selection of machinery for drying and pulverizing coal; and we also copied the burner he used, which was a standard article on the market. We got an expert coal-dust machinery man to design our plant, and were very glad we did so as we avoided some of the unpleasantness that had been experienced at other plants through fires and minor explosions. I want to say, before describing our apparatus a little in detail, that we were quite familiar with the work of Mr. SÖrensen, the pioneer in the use of pulverized coal for copper smelting. Our attention had been called to it by Mr. Klepetko early in the game. And afterward we were familiar with the work done at Cananea by Mr. Shelby. We sent an expert to investigate the question 10 years ago. He examined the work of Mr. SÖrensen; and then went to the cement men and examined their work, and reported at great length that coal dust was the ideal fuel for them, as they took the ash from the coal and sold it as cement. He reported that coal-dust firing could not be made economical in reverberatory copper smelting, and his reasons were that a blanket of nonconducting material would cover the charge in a short time and insufficient heat would reach the charge proper, and we would have floaters over all our furnaces. The flues would be stopped by the dust that did not settle on the charge. We accepted that until our Irish friend got busy and showed us how to do it. Then we built a furnace which we thought was a slight improvement over Mr. Browne's. We put railroad tracks over our furnaces to draw the charge to the furnace. We had

Jan 1, 1915

By T. O. Anderson, E. J. Stahl

Tests to increase knowledge concerning the process of hydraulic fracturing have been performed on three wells in the Allegheny field in western New York. The fracture orientation and its physical appearance at the well-bore was determined by impression packers run at appropriate times throughout the program. Fract~tre azi171uth and its dimensions thus determined were compared to the rock properties and treatment conditions. Logs to provide data concerning rock properties and to improve identification of vertical fractures were run before each step of the fracture treatment. Pressure osc~illu~iot~s were studied after each phase of tile treatments surface pressures during treatment. These measurements show that subsurface pressures exhibit many of the same characteristics as surface pressures during treatment of a well; however, transient pressures are dampened and deelayed in time at the bottom of the well when COmpared with surface pressures. Data obtained from this study provides a means to help locale and determine orientation of vertical fractures made in the open wellbore. Although these rests were performed in only one area, much of the information gained may be applied to fracturing programs in orher areas. INTRODUCTION In this study, various tests were made to provide data to better understand formation fracturing in situ. The reservoir studied is the Richburg oil sand which is a part of a series of predominantly grey sandstones and shales with occasional brown sandstone layers, known as the Caneadea unit of the Canadaway group of Upper Devonian age. Average physical characteristics of 12 cored wells in this area are 13-ft thick gross sand formation, 12-ft thick net sand. 1.7 md permeability, 11 percent porosity, 44 percent oil saturation (before secondary recovery) and 16 percent water saturation (before secondary recovery). This particular area of the Allegheny oil field was originally drilled prior to 1890. The first waterflood secondary recovery attempt was made in 1929. The present sustained waterflood development began in 1951 and is being carried out on a 4.5 to 5-acre spacing. Objectives of these tests were to (I) study fracture azimuth and dimension in relation to rock properties and treating conditions, (2) improve fracture identification techniques, (3) compare surface and subsurface pressure during all phases of treatment and (4) compare the periods of the fluid column oscillations occurring after each phase of treatment. Although the areas of investigation listed appear divergent in purpose, the program was designed primarily to increase knowledge of down-hole conditions leading to rock failure and extension of the fracture thus created. TEST PROCEDURES Wells upon which tests were conducted are designated as Wells 1 through 3. Well 2 was located 440 ft north of Well 1, and Well 3 was located approximately 880 ft west of Well 1. Wells 1 and 2 were completed with cable tools, while the producing interval of Well 3 was rotary cored using fresh water as the drilling fluid to obtain oriented cores. Tests were divided into separate phases on each well as the fracturing program progressed and consisted of measurements performed prior to treatment, during and after the formation breakdown operation. during fracture treatment and after treatment. To verify location and azimuth of the fracture created, and to obtain an impression of wellbore irregularities, a packer was used (Fig. 1). This packer was lowered on tubing into the wellbore opposite the interval under study and inflated in stages to allow the impression material to conform to the wall of the wellbore. A magnetic compass was attached to the tool for orientation reference. Impressions made prior to treatment showed no existing fractures in the wells under study. Impressions made after both formation breakdown and treatment pro-

By Zay Jeffries

AN acute current shortage of copper, with the prospect that conditions may become worse, indicated by Office of Production Management information. Present estimates of copper requirement for defense indicate that nearly all the available metal will be required in the future for this purpose. Severe dislocations are, expected, but the objective is to distribute the copper available for civilian use in such a manner as to minimize these dislocations. The advisory committee on metals and minerals has been asked for a suggestions which may be helpful in meeting this situation.\

Jan 1, 1941

By Arthur West

IT is the purpose of this paper to describe briefly some recent large power stations for blast furnaces, where the blast is exclusively supplied by gas engines using furnace gas. The stations are given in the chronological order in which they were designed, in order to indicate the various improvements suggested by experience. Fig. 1 shows the blowing-engine station of the Bethlehem Steel Co. at Bethlehem. Although the picture shows only five blowing engines, the house now contains 11 engines. In the diagrammatic. plan the arrow shows the position and direction of camera. This station handles five modern blast furnaces of 450 to 500 tons capacity each. In this, as in all the other stations described in this paper, each furnace is blown by-two single tandem gas engines. Ten engines are thus required for five furnaces, leaving one single tandem spare engine. This spare capacity has been shown by several years' experience at Bethlehem to be adequate to insure continuous operation. The engines in the Bethlehem station are right hand and left hand, arranged in pairs. The outboard bearings of each pair are close together so that there is not room for passageway between them. On the right of the picture are shown the inclined drums communicating with the cold-blast lines outside of building, so that any engine may be operated on any furnace. The illustration shows four cold-blast gate valves with pipes passing through wall, but since the photograph was taken the drums have been extended to take care of a fifth valve for a fifth furnace. At the extreme back of the picture can be seen the tubs of three twin vertical-horizontal Southwark steam blowing engines, which, although of modern design and as good as new, are not operated because of the greatly reduced blowing cost shown by the gas blowing engines.

Jan 6, 1915

By G. Duncan

Distinct trends in grinding mill technology have emerged in recent years. In an effort to optimize overall mill performance for the needs of the End User, broad measures of logistical speed, process flexibility, operational risk, and overall costs now exert greater influence on the specification of grinding equipment. As a result, innovative alternatives to conventional grinding mill structures, supports, drives, feed, and discharge configurations are now being offered and selected with greater frequency. This paper investigates these trends in grinding mill technology, utilizing optimization and decision-theory techniques. In particular, the paper considers how specific advances in process design, product engineering, manufacturing techniques, and mining operations continue to relax technological constraints, enabling further mill innovation. In this context, a methodology is presented, illustrating how proper selection and specification of grinding mill components and configuration can target an optimization of the four End-User performance measures listed above..

Jan 1, 1999

By W. L. Staker

Alternatives were developed to the conventional ammoniacal carbonate leaching-steam stripping procedure for recovering copper as an oxide from contaminated scrap metal. By entraining air bubbles in the leach solution, the copper dissolution rate was increased to 1.5 g/in2 of copper surface per hour, compared to 0.5 g/in2/hr produced by conventional agitation in stirred tanks. Using entrained nitrogen gas bubbles for agitation in conjunction with powdered sulfur not only resulted in rapid dissolution but also simultaneous precipitation of the copper from solution as a high-grade cuprous sulfide.

Jan 1, 1971

By D. L. Paulson

Electric furnace smelting of blister copper directly from copper precipitates (cement copper) was investigated by the Federal Bureau of Mines. Copper concentrations in five different lots of cement copper in the investigation ranged from 62.5 to 82.5 wt-pct. Laboratory-scale smelting tests were made in a 50-kva electric-arc furnace to establish the reductant and flux requirements. Best recoveries were realized by adding 60 pct of the carbon required to combine with the contained oxygen in the cement copper. Operating parameters established during the laboratory-scale smelting tests were used successfully in smelting 20 tons of cement copper during 12 pilot-scale tests in an 800-kva electric-arc furnace. Over 98 pct of the contained copper was recovered as blister-grade metal. The projected energy consumption for a commercial-size furnace was 380 kwhr per ton of cold charge.

Jan 1, 1978

By K. W. Fritzsche

The prosperity of any nation depends, to a large extent, on its natural resources such as oil, coal, 'metal, timber, waterpower, and fertile soil. Each one of these resources forms the basis of a huge industry. The mining and smelting industry ranks among the first since it paves the way for a number of other industries. The mines and smelters provide a market for electric power, coal, timber, and agricultural products: other industries in turn provide a market for metals and non-metals. The real pioneering, however, is done by the prospector who goes into the wilderness to search for the ores from which the metals are to be extracted for the use of men. Prospecting is an interesting and fascinating occupation. There are many difficulties and hardships in the way but the lure of gold and the vision of finding an outcrop that may develop into a large bank account, within a reasonably short time, will urge the prospector forward. Thus, on the outskirts of this northern hemisphere hundreds of prospectors are searching and toiling and of whom nothing is known or heard until they reach civilization and announce a new discovery. Then a mad rush takes place and everybody who can afford to go will take a gamblers chance and plant stakes in the neighbourhood of the new discovery, or wherever an outcrop of mineralized rock can be found, with the hope of winning a fortune.

Jan 1, 1925

By Robert C. Collins, Clifford L. Jewett

The development and production of artificially colored roofing granules have been key factors in the success of the asphalt roofing industry. They provide protection for the asphalt from solar radiation and satisfy the home-owner's desire for a wide range of attractive colors. As a result, the asphalt shingle has become the most commonly used roofing material today. In addition to providing a stimulus to the asphalt roofing industry, artificial methods of coloring granules completely changed the nature of granule production from one of quarrying, crushing, and screening to a complex technical operation. Today's roofing granules are the result of many years of research, and they are produced in modern plants to exact specifications. History Asphalt roofing materials available today are the product of a long evolution of technological development. Forerunners of the present bituminous products, appearing as early as 1780, were primitive constructions of burlap saturated with crude tar or pitch. An early improvement to this basic effort was the dusting of talc, mica, or other finely ground material on the coated surfaces to keep the roofing from sticking to itself in storage. At times some pigmentation was added with the dusting material for initial color, but this was far from satisfactory. In fact, this early product possessed none of the qualifications of a good roof surfacing material. It was not economical; it was difficult to handle and apply; it was not attractive; it provided no resistance to fire; and it would not withstand the elements as well as other products then in use. Methods and machines were soon devised to saturate endless webs of felt with asphalt from the fast-growing petroleum industry. Even though saturated felt became available, this product of rags and wood fiber had almost the same limitations as burlap and tar. Even with heavier coatings of asphalt applied to both sides of the sheet for rigidity and longer life, the product still lacked color and fire resistance. Further, it was found that constant exposure to the sun soon caused the asphalt to become brittle, and it eventually cracked and leaked. This led to the first important use for crushed mineral products on asphalt-coated shingles and provided the key to the subsequent growth of the asphalt roofing industry. When a layer of crushed mineral was embedded in the surface exposed to the weather, the asphalt coating was protected from ultraviolet light and retained its elasticity over a much longer period of time. In addition to this protection, the mineral surfacing provided some resistance to fire. Fire resistance in the past had been found only in the expensive slate or tile roofs and the unattractive and expensive metal roof coverings which were then available. The most common mineral granule applied to the early asphalt roofing products as they began to make their first significant advances after 1900 was screened waste from slate quarries. Slate granules being available in dull shades of red, green, black, purple and a few other miscellaneous colors did provide a degree of color. Since slate has a flat platelike cleavage, it provides a cheap protective cover for the asphalt-coated sheets. Records show that coarse slate screenings were used for asphalt roofing as early as 1906. As the asphalt roofing industry developed, many other natural colored rocks and minerals were used to coat the surfaces of the roofing. The list included silica

Jan 1, 1975

By L. A. Bromley, R. L. McKisson

A high temperature calorimeter designed for use up to 1500°K is described and the theory of its operation presented. This calorimeter was used to measure the heats of formation of Na-Sn alloys ranging in composition from tin to Na2Sn. The values tend to support those reported by Kubaschewski and Seith. ONE method of obtaining the heat of formation of an alloy is to measure the heat of mixing of the elements at high temperature. The principal advantage of this method is that the desired quantity is measured directly, while in conventional room temperature methods the differences of the heats of solution of the elements and the alloy in a suitable solvent are measured. A method of improving the accuracy of the high temperature measurements, when the precision of the measurement is lower than that of the heat capacity values for the elements, is to add one component at room temperature to the other at the high temperature, so that part of the heat of reaction is dissipated in heating the cold component to the high temperature. Thus, only a fraction of the heat of reaction is measured, and a result of higher precision is obtained. The limitations of the high temperature technique are that volatile systems cannot be studied, and that many alloys melt at temperatures higher than those at which the calorimetric apparatus operates readily. Nevertheless, a calorimeter operating at 1500°K would be useful in investigating many of the lower melting alloy systems and the low melting mixed oxide systems. A unit designed for these applications was built and is described here. The Na-Sn system was chosen for investigation because the temperature involved, 880°K, would adequately test the operation of the calorimeter. Further, the data reported in the literature for the various alloys of sodium and tin differ markedly, and it was hoped that this investigation would help to fix the values of the heats of formation in this system. Design of Apparatus A detailed discussion of the considerations involved in the calorimeter design is given by Mc-Kisson and Bromley,' and a brief summary follows. Fig. 1 shows a sectional view of the calorimeter. The inner graphite chamber is maintained at constant temperature by means of the circulating molten tin bath in which it is submerged. The tin is contained in a graphite vat. This unit comprises a thermostat whose heat capacity is about 7000 cal per "C. The main heating element consists of a machined graphite spiral with a room temperature resistance of about 1/2 ohm. These parts are separated from the powdered carbon external insulation by the cage, a cylindrical graphite chamber. The electrical insulators and separators, the auxiliary heater spool, and the loading tube liner are made of sintered alumina. The tin vat stirrers, the sample stir-rer, the melt thermocouple well, and the power leads are made of molybdenum. The auxiliary heater is wound with molybdenum wire and serves to compensate for the heat loss up the loading tube. All of the individual components in the high temperature region of the calorimeter will withstand at least 2000°K, and the various contacting materials should easily withstand 1500°K. The external container for the insulating carbon powder is a copper shell upon which copper tubes are soldered to serve as cooling coils.

Jan 1, 1953

By D. R. Hudson, M. J. Donaldson

"Study of gravity concentrates from the gold-recovery circuit of the Kambalda nickel mill has enabled an assessment to be made of the nature, relative abundance and compositional variability of platinum group element (PGE) minerals and other associated heavy minerals that are present in the Kambalda nickel deposits. The major platinum minerals are sperrylite, PtAs2, and nioncheite, (Pt. Pd, Ni)(Te, Bi)2, and the major palladium minerals are sudburvite, (Pd, Pt, Ni)(Sb, Te, Bi), stibiopalladinite, Pd6Sb2, and palladoarsenide, Pd2 (As, Sb), together with a palladium antimonide and a palladium arsenide that have not been fully characterized. Palladian melonites, which contain up to 10 wt% Pd, and palladian nickeline are also important PGE hosts. Sperrylite and sudburyite are by far the most abundant discrete minerals in the gravity concentrates.Gold occurs as argentian, cuprian and nickeloan—cuprian gold, and as the tellurides calaverite, petzite and auriferous hessite. Silver is present in petzite, hessite and volynskite. Other rare phases contained in the gravity concentrates include native bismuth, altaite, frohbergite, breithauptite, gersdorffite, parkerite, scheelite, tantalite, cassiterite, rutile, bunsenite, gahnite, barite and uvarovite.Descriptions of in-situ occurrences of PGE minerals at Kambalda are rare. Michenerite, PdBiTe, and testibiopalladite, PdSbTe, have been described from a telluride-rich quartz-carbonate vein that intersects massive sulphide ore in Lunnon Shoot. Moncheite has been observed in chalcopyrite-rich stringers, and sudburyite occurs as inclusions in nickeline in a quartz- carbonate veinlet. No discrete PGE minerals have been found within the massive and matrix ore zones in the Kambalda ore- shoots, and the geochemical distribution of PGE suggests that the formation of discrete PGE phases may be related to post- magmatic processes—in particular, metamorphic segregation of sulphides, and the interaction of the ore sulphides, containing PGE in solid solution, with younger hydrothermal fluids. This has led to local redistribution of the PGE, with concentration in footwall stringers and veins, and in reaction zones."

Jan 1, 1984