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By Z. Zak Fang, P. Fan, S. Middlemas

"Titanium dioxide (T1O2) has been widely used as pigment in paints, paper and cosmetic products, as well as high-tech applications such as PV Cells, semiconductors, biomedical devices and air purification. T1O2 pigment is primarily produced by the high temperature chloride process, resulting in considerable CO2 emissions. A novel hydrometallurgical process for making T1O2 pigment without direct CO2 emission is investigated. The new method promises to eliminate direct CO2 emissions, consume significantly less energy, and produce minimal environmental waste. The novel process involves molten salt roasting of titania slag, with subsequent washing, leaching, solution purification, hydrolysis, calcination and post-treatment stages, resulting in high-purity anatase or rutile pigments while realizing significantly reduced environmental impacts. Pigment whiteness is critically sensitive to trace amounts of discoloring impurities such as iron and chromium. Several methods for reducing the levels of these impurities are investigated. Energy consumption and emission models are also developed.IntroductionTitanium dioxide (T1O2) is one of the most commonly used minerals in the chemical manufacturing industry. It has been commercially processed since the early 1900's, and has a wide variety of applications. Pigment is used in paints [1], plastics and paper [2], sunscreen [3], cosmetics and even as a food additive [4]. T1O2 has also been used in photovoltaic cells [5], biomedical devices [6], and in air purification [7]. T1O2 pigment has a refractive index of 2.7, which imparts a high level of opacity (and hence whiteness) to whatever material it is added [8]."

Jan 1, 2012

By W. L. Grose, J. E. Nealy

A device developed by the U.S. Bureau of Mines for the detection and quenching of coal mine explosions suffers from the inability to discriminate between the light emitted from hydrocarbon combustion and that emitted by electrical sparks and miner's cap lamps1. Since the quenchant device is activated by an internal explosive charge, the possibility of serious injury to nearby personnel demands a detector which can reject false signals. Described herein is a detector which can provide a rapid response signal upon the emission of radiation from hydrocarbon combustion and concurrently reject spurious signals from such sources as sparks and cap lamps. It was suggested that a detector might be developed to operate on the principle of monitoring the radiation intensity emitted from two separate spectral regions and ratioing the intensities2. A series of experiments was conducted for combustion of methane-air mixtures which demonstrate the ability of such a detector to discriminate between combustion and spurious signals. Experimental Apparatus A cylindrical (3.8 in. diam by 12 in.) stainless-steel shock tube test section was used as a combustion chamber. The test section was equipped with quartz windows (2 in. diam) on either side, a piezoelectric pressure transducer, and two steel electrodes. A 10-kv capacitor discharged across the electrodes provided a submicrosecond duration spark to ignite the gas mixture within. The desired partial pressures of methane and air were obtained by using a Wallace and Tiernan 0-800 mm Hg pressure gauge with which pressures could be determined to an accuracy of % mm Hg. All tests were conducted with a total pressure of 1 atm in the chamber. To

Jan 1, 1972

By Gavin Lind

The Minerals Council of Australia (MCA), through its Minerals Tertiary Education Council (MTEC), builds capacity in higher education in the core disciplines of mining engineering, metallurgy and minerals geoscience. Over the past fourteen years, this all-of-industry approach in securing the long-term supply of these critical skills (which remain a chronic skills shortage for the Australian minerals industry) through nationally collaborative programs across sixteen Australian universities delivers spectacular and sustainable results for the industry. These unique, world-first programs are built on a healthy platform of dedicated industry funding and in-kind support and forms part of the MCA’s broader uninterrupted, sustainable education and training pathway to increase workforce participation, workforce diversity and workforce skills, regardless of the business cycle in the industry. This paper will highlight the origins, iterations and current successful programs of MTEC, including its future vision, and presents a mechanism for industry and academia to collaborate to address future professional skills needs in the minerals industry globally.

Jan 1, 2014

By Henry M. Howe

THIS paper gives the composition of the iron and slag at different stages in the "air-furnace" process of preparing "hard metal," or white cast-iron, for conversion into malleable cast-iron by annealing. The details of the process are given in an appendix. One of us had been trying for years to work some chemist of some of our malleable-iron works up to a degree of enthusiasm which would lead him to make such au investigation. It would have had the advantage of the greater familiarity with the conditions which one habitually on the spot must have. Failing in this, he made use of an opportunity which presented itself of taking samples here represented, with such fairness as the conditions permitted, holding firmly that a rough approximation to the truth is better than the complete lack of data, or that a bird in the hand is worth two in the bush. We hope that this attempt may stimulate others effectively to duplicate this work, and thus correct or confirm it. Our results are shown in Table I. and graphically in Figs. 1 and 2. Discussion.-At the time when the first two samples were taken, the metal and slag were still too sluggish to permit fair sampling, and not until sample 6 were the conditions really favorable, because at the time of the fourth sample the metal was not fully melted, and even at the time of sample 5 it was still sluggish. Indeed, the slag was probably very heterogeneous throughout, because it took up silica and alumina rapidly from the bottom, and because it was so siliceous as to be sluggish at this relatively low temperature. This hetero-geneousness is exaggerated in the two samples of slag 8, apparently by the great viscosity due to its extraordinary acidity. Note that the manganous oxide of one sample is about two and

Mar 1, 1909

By D. C. Panigrahi

The paper presents the development of a thermodynamic based network analysis model. It uses transient heat flow algorithm for computing the heat flow from strata and predicts the environmental condition in different branches of the network. Along with the environmental condition, the mass flow distribution in network is computed by using nodal pressure method based on linear theory approach. The algorithm has been coded using object oriented programming approach and it has been validated in actual field condition. The correlation is satisfactory.

Jan 1, 1997

By Eduard Hamm

The main reasons for the development of higher heat levels in German coal mines are the increasing depth of working with the con- sequent higher rock temperatures, increased use of electrical equipment, and increasing coal output due to concentration and mechanisation of workings. In place of the normal decentralised underground cooling plants, schemes and pilot plants have been developed to produce the required cooling capacities in central air cooling units, which then supply the cold air to the underground working points where needed.

Jan 1, 1980

By D. Blackwell, W. R. Reed, G. Ross, S. Peters, M. Shahan

Dust collectors for roof bolting machines generally use a dry box to collect the roof bolting material. Recently, an underground mining operation converted a dry box dust collector to a wet box dust collector with a unique exception from MSHA for testing purposes. Water is routed to the roof bolter from the main water line of the continuous miner. The wet box utilizes a water spray to wet the incoming material. Testing was conducted comparing the two different collector types. Respirable dust concentrations surrounding the roof bolter with the different collection boxes were similar. The main difference in respirable dust concentrations occurred when cleaning the dust boxes. The average respirable dust concentration during cleaning of the wet box was 0.475 mg/m3, and during the cleaning of the dry box the average respirable dust concentration was 1.188 mg/m3. The silica content of the roof material was high, ranging from 28.9% to 52.7% during this study. The results from this study indicate that using the wet box as a collector reduced exposure to respirable dust up to 60%when cleaning the collector boxes. INTRODUCTION Currently, the dry vacuum dust collection system is the standard dust collector on roof bolters in underground coal mining. It has been proven to be an effective dust control to prevent roof bolter operators’ overexposure to coal mine respirable silica dust during roof bolting operations [Potts eta l, 2011 and Colinet, 2013]. The dry collection system works as follows: drill cuttings are vacuumed into the precleaner. The precleaner dumps oversized material onto the mine floor while undersized material enters the dust box via vacuum airflow produced by a blower. The cuttings entering the dust box are either deposited on the floor of the dust box or into a dust collector bag. The vacuum airflow leaves the dust box through a final filter which removes any small particles from the airflow. Figure 1 shows the internal view of two dry collection system boxes; one that does not use the dust collector bags and another that uses the dust collector bags. Dust collectors that use dust collector bags to contain material inside the dust collector box have been shown to provide better protection to roof bolter operators than dust collectors that do not use the bags [Listak and Beck 2008]. The dry collectors are very efficient at reducing respirable coal mine dust exposure from roof bolting activities. Recently, Blue Mountain Energy’s Deserado underground coal mining operation, outside Rangely, CO, made a modification to the dry collector system to convert it to a wet collector system with a unique exception from the Mine Safety and Health Administration (MSHA) for testing purposes. The wet collector system still uses a vacuum system to pull material from the vertical roof bolt hole, but incorporates a water spray nozzle located inside the dust box to wet the incoming material. The flow through the nozzle ranges from 1.9–7.6 lpm (0.5–2.0 gpm) at 0.69 MPa (100 psi). The conversion to the wet collector system removes the precleaner and the cyclones inside the dust box. The wet material (sludge) then empties through a specialized valve in the bottom of the box. The final filter is still used to prevent respirable dust from leaving the dust box through the exhaust. During operation, the wet collector dust box is opened and hosed clean after roof bolting every place. After every two entries the final filter is changed out. Figure 2 shows the inside of the wet collector box.

Jan 1, 2019

By J. J. Drost

The feasibility of basic oxygen furnace (BOF) offgas heat recuperation by preheating scrap was investigated on a pilot plant scale by the Bureau of Mines. In this study, offgases generated during the oxygen blowing of a molten pig iron and scrap charge were passed through a static bed of shredded auto scrap. Scrap quantities varying from 100 to 180 pounds and representing from 22 to 40 percent of the 450-pound BOF metallic charge were preheated in this manner. Average scrap bed temperatures of 1,650° F for 100 pounds of scrap and 1,150° F for 180 pounds of scrap have been achieved during the blows. As compared to cold scrap used in the normal BOF practice, it was found that by preheating scrap, usage could be increased by 43 percent. The thermal energy recovered by this preheating method can account for up to 44 percent of the energy necessary to melt the scrap.

Jan 1, 1974

By C. Sarkar

Increased competition in today’s global economy has put mineral industry under excessive pressure to effectively manage production assets to generate business wealth. Capital intensive industry (CII) organizations are seeking ways to manage skill resources, internal processes, and organizational networks with a view to reduce the cost of ownership of assets and increase efficiency of operations and service. The emerging concept of Enterprise Asset Management(EAM) is a collection of business processes that allow CII with right focus on return on investment on assets, to make right decisions on planning, acquisition, maintenance, operation, rehabilitation, and disposal of assets. Information technology (IT) can drive significant returns if the infrastructure covers seamlessly all business processes and all systems, like geographic information system, maintenance management, investment management, laboratory information management, and supervisory control and data acquisition system. The simple approach to IT in the past with disconnected silos of technology, information, and business processes cannot deliver the expected benefits under the modern business environment. Identification of business and application component is a prerequisite for the development of an asset management system that links effectively disciplined processes having characteristics of agility, speed, and integration. This paper discusses various issues and outlines the steps for developing an asset management roadmap in an organizsation. It also presents major business and application components of the system. Keywords: Enterprise asset management, Business architecture, Business component, Application component, Asset ownership, Asset operations, Information technology, Capital Intensive industry

Jan 1, 2003

By James R. Myers

A source of clean gas containing sulfur dioxide and sufficient oxygen for convers.ion to sulfur trioxide ?is essential to the production of sulfuric acid. S02 containing gases obtained from roasting sulfide ores are heavily contaminated with inorganic dust and volatile impurities. If not removed, these contaminants will reduce product acid quality, foul the catalyst beds and mist eliminators, and accelerate equipment corrosion. This paper reviews conventional gas cleaning systems for metallurgical acid plants, followed by a discussion of modern systems utilizing DynaWave Scrubber technology. This technology is based on a unique approach to? gas scrubbing that can concurrently accomplish several gas cleaning/processing tasks scrubbing liquid is injected into the gas stream to create. a "Froth Zone". This is a region of extreme turbulence, with a very high rate of liquid .surface renewal. It efficiently removes both particulate matter and gas contaminants, and is also a cost effective quenching device for gases as hot as 1250º C. Smelter

Jan 1, 1992

By James R. Myers

A source of clean gas containing sulfur dioxide and sufficient oxygen for conversion to sulfur trioxide is essential to the production of sulfuric acid. SO2 containing gases obtained from roasting sulfide ores are heavily contaminated with inorganic dust and volatile impurities. If not removed, these contaminants will reduce product acid quality, foul the catalyst beds and mist eliminators, and accelerate equipment corrosion. This paper reviews conventional gas cleaning systems for metallurgical acid plants, followed by a discussion of modern systems utilizing DynaWave Scrubber technology. This technology is based on a unique approach togas scrubbing that can concurrently accomplish several gas cleaning/processing tasks. Scrubbing liquid is injected into the gas stream to create a "Froth Zone". This is a region of extreme turbulence, with a very high rate of liquid surface renewal. It efficiently removes both particulate matter and gas contaminants, and is also a cost effective quenching device for gases as hot as 1250 o C.

Jan 1, 1992

By J. H. McKibbon

THE metallurgical industry has purchased more than sixty per cent of the industrial gas cleaning equipment installed in Canada. This includes cyclonic collectors, scrubbers, cloth filters and Cottrell Precipitators. These are the principal types of equipment which are used commercially for the cleaning of gases which result from the processing of iron, nickel, copper, lead, zinc, gold, gypsum and aluminum ores. The recovered dust, which usually contains metal values, is returned to the process. The cost of the equipment is thus economically justified. This is in contrast to other industries, such as those involving steam power generation, asbestos, cement and lime production, where, though dust collection equipment is extensively used, it is installed primarily for nuisance abatement. Communities are becoming more and more conscious of air pollution, new and more stringent legislation is being enacted, and, for other than economic reasons the smelting industry will eventually be required to install more efficient gas cleaning equipment. This paper

Jan 1, 1962

By A. A. El-Midany

Traditionally, the choice amongst different upgrading techniques or in finding the optimum operating conditions for a given upgrading technology depends on whether one is looking at the grade or the recovery of the valuable mineral in the concentrate. In fact, the conclusions are not usually the same. This is because the best technique or optimum operating conditions for the highest grade are not the same as the conditions to achieve the maxi-mum recovery. Therefore, a unique measure that takes into consideration both grade and recovery is urgently needed. Finding such a measure is the objective of this paper. A proposed measure provides a selectivity index in the range of 0 to 1, where 0 is no selectivity and 1 is ideal selectivity. The index can be obtained by plotting the so-called Fuerstenau upgrading curve, which relates the recoveries of the components in products of separation and a running regression applying a one-parameter equation. The measure was applied to assess the selectivity of selective flocculation under different operating conditions when used as a sensitive upgrading technique for ultrafine ground ores. After applying the proposed selectivity measure in the case of the selective flocculation of ultrafine Egyptian iron ore without the addition of cations, it was found that the optimum conditions are pH 11, 1 kg/t sodium silicate and 0.4 kg/t potato starch with a selectivity index of 0.55. With the addition of cations, the optimum conditions were found to be pH 11, 1 kg/t sodium silicate and 2 kg/t potato starch with a selectivity index of 0.65. It should be noted that determining these optimum conditions using the traditional grade or recovery measures was highly ambiguous.

Jan 1, 2008

By John M. Gomes

Two molten salt systems were evaluated as electrolytes for the repetitive recovery of tungsten from tungsten oxide (W03) made by calcining commercial-grade ammonium paratungstate. Using a sodium chloride-sodium fluoride-potassium aluminum tetrafluoride electrolyte at 800° C, 1 pound of 99.8 percent tungsten was recovered for each 2.7 kilowatt-hours of energy consumed. The metal contained 1,100 ppm carbon, was in dendritic masses of spherical grains, and had an apparent bulk density of 5.41 g/cm3. T ngsten of 99.9 percent purity was won from a sodium pyrophosphate-sodium tetraborate-sodium chloride electrolyte at 1,000° C; 6.0 kilowatt-hours of energy was consumed for each pound of metal recovered. The metal contained 120 ppm carbon, was in dendritic masses of hexagonal acicular crystals, and had an apparent bulk density of 7.25 g/cm . Each metallic impurity--aluminum, calcium, copper, iron, nickel, and silicon--in the two tungsten products was 16 ppm or less.

Jan 1, 1966

By M. K. Mohanty

One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m2, an enhanced gravity separator having a bowl diameter of 250 mm and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The ?linear screen + enhanced gravity separator + screen-bowl circuit? provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61%, respectively.

Jan 1, 2008

By R. W. Fedors, S. T. Green, F. T. Dodge, D. B. Walter

Spatial and temporal temperature variations in a high-level radioactive waste repository drift can give rise to moisture transport within the drift. Knowledge of this moisture transport may be important to assessing the potential for corrosion of all metallic components in the drift. The model presented here shows one approach to simulating evaporation, transport, and condensation of water in large underground openings using a framework based on computational fluid dynamics. Simulation results that explicitly model water and latent heat transport are presented.

Jan 1, 2004

Studies of human relations are being made by a team of psychologists within management and in the community of Kambalda as a whole. Some of the first results are discussed with reference to extensions required in management when it also has to run a mining town. Implications are noted for town planning policies of the attitudes and preferences of the population with regard to housing and to other major planning areas. Some of the theoretical and practical difficulties of 'planning the human ecology' are outlined.

Jan 1, 1973

By L. Max Scott

[INTRODUCTION] The significance of gamma exposure to uranium miners has been recognized only in the last few years. Most ore deposits which have been underground mined, were 1% or less U308. Full-time mining of this grade ore can result in exposure exceeding 1 Rem per year. Several companies in Saskatchewan are planning to mine recently discovered ore bodies which contain ore pods in excess of 10% U308. The purpose of this paper is to present dose data which can be used to estimate gamma exposure from high-grade ore deposits, and to present mining techniques which will minimize miner exposure. [Dose Estimates] When one has a point source of radiation, the conventional laws of isotropic emission and the fall of dose with square of the distance, make dose calculations relatively easy. However, if one has an area source of infinite thickness, the assumption must be made that a uniform gamma flux is being emitted from all faces of the source (Figure 1). Dose from gamma emission would fall off only due to air attenuation up to such a distance at which the source can be considered to be a point source (usually 10 times the largest dimension of the source). For short distances, such as to the cab of ore-moving equipment, the dose reduction would be negligible. Assumptions: 1) Radium and gamma-emitting daughters are in secular equilibrium with uranium. 2) All gamma radiation is emitted from radium and its daughters. 3) Average gamma energy of 0.8 MeV. 4) Uranium ore has a linear attenuation coefficient of 0.212 cm-1, similar to that of Si02(sand). 5) Uranium ore density of 3.0 gm/cm3. 6) One curie of radium emits 6.84 x 1010 photon/sec(l). 7) One percent uranium ore contains 1 x 10-8 Ci/cm3 of radium. 8) Each MeV of 0.8 MeV photon results in a dose of 2.10[ ]10-3 mRem/hr. per MeV/cm2 -sec. 1) 9) Minimum ore depth 100 cm. 10) Linear attenuation coefficient instant for radium gamma of 0.374 cm -1 [ ] The photon flux from a radioactive slab is computed as follows: [Flux = photon/cm3 3(1) 2u S] [where, us is the linear absorption coefficient of s the source (uranium ore).] Thus, 1% uranium ore, in the form of an infinite slab, emits 1613 photon/cm2-sec, which results in a dose rate of 2.71 mRem/hr. Since the dose from an infinite slab is the same as a dose from an infinite radius right circular cylinder, the only correction needed from the above dose rate is for finite radius and point of dose above the end of the cylinder (Figure 2) [Dose = mRem/hr. {E2(bl) - E2(b3) - [(E2(b1sec[E] -E2(b3sec[E]]cos[O](1)]

Jan 1, 1981

The application of reinforcement techniques to enhance the stability of underground coal mine roadways subject to high stresses is discussed. Research conducted in the Illawarra Coal Measures has been aimed to delineate the factors which influence the behaviour of rock above roadways and the performance of the reinforcement placed. Design considerations for the reinforcement of mine roadways in the Bulli coal are based on a quantification of the rock response together with a reinforcement strategy to enhance the structural integrity of the roof strata.

Jan 1, 1986

By D. Whittles, S. Kingman, S. Bradshaw, N. Miles

The influence of microwave energy at high electric field strength on ore strength has been investigated. Two ores of varying mineralogy were treated in both multimode and single mode microwave cavities. After treatment, any change in strength relative to untreated ore was established. It was shown that in the multimode cavity reduction in strength was related to the applied power level. Results of tests carried out in the single mode cavities showed that, for both ores, reductions in ore strength > 50% could be achieved in very short periods (<1 second). Thermal stress analysis showed that the mechanism of microwave induced failure was the development of tangential stresses at the grain boundaries. It was concluded that operation at 915 MHz with high power and short residence times gives feasible scale-up possibilities.

Jan 1, 2003