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Callide Coalfields produces a sub-bituminous, very subhydrous, low rank, steaming coal with good combustion properties, primarily for domestic power generation. Geological input into planning of coal extraction requires expedient production of detailed structural, lithological, analytical, geophysical and geotechnical data. The CSIRO-developed SIROLOG borehole logging software and hardware system allows for detailed spectrometric analysis of coal/interburden. The gamma-gamma and neutron-gamma SIROLOG techniques both provide improved prediction of ash content over other borehole techniques. The neutron-gamma technique also predicts density and some important ash constituents (especially iron, alumina and silica). The software/hardware configuration allows for quick, easy interpretation of coal seam depth and lithology, parting thickness and ash/ash constituent contents immediately after a borehole has been logged. Within certain mine areas in the Callide Basin, the iron content of mined coal is widely variable in both vertical and lateral extent within and between seams. This variability creates problems in predicting the slagging behaviour of æas-receivedÆ coal during combustion, especially where the iron content of the ash exceeds 19 per cent. Using the SIROLOG tool in co-operation with traditional borehole sample laboratory analysis results, patterns in this variability can be determined and related to geological properties and process of formation of the coal seams. Subsequently, areas of high iron can be predicted in advance of mining. Since 1992, on-going collection and interpretation of SIROLOG downhole geophysical log data has significantly contributed to a number of research projects related to gaining a preliminary understanding of the iron distribution and formation during the Coal MeasuresÆ deposition. Because the probe was able to record variations in coal mineral matter content, it was found to complement more conventional techniques such as reflected light petrography, X-Ray Diffraction and SEM techniques that examine the mineralogy of iron species. Additionally, software has been developed to allow integration of SIROLOG data into existing geology databases, enhancing coal quality modelling and daily prediction of parameters such as raw ash, silica and iron contents that are indicators of ash fusion propensity. The correlation of SIROLOG-derived iron geophysical traces between drillholes and other sample points highlighted lithological and structural controls in the iron distribution in the sequence previously not detected. This work has allowed the development of a methodology for predicting iron in advance of mining and reconciling as-sold coal quality to that predicted. Predictions are currently being assessed at the coal face as mining progresses through high-iron zones.

Jan 1, 2000

By Bernard L. Merlo

INTRODUCTION Modern mine management is constantly striving to develop improved mining methods which will not only increase productivity, but will also provide a safer work environment and make the most efficient use of our natural resources. Progress can be seen in this area by tracing mining methods through history. Work that was originally done with hand tools progressed with the age of mechanization to conventional mining, matured to continuous and longwall mining, and the advent of short¬wall mining, a combination of continuous and longwall, has recently been seen. This new method of shortwall mining provides a promising method for safe and ex¬pedient coal extraction. This study focuses upon the planning, design de¬velopment, and operation of the first producing short¬wall unit in the US which was operated in the Pittsburgh coal seam in northern West Virginia. MINE DESCRIPTION The mine is located in northern West Virginia at Grant Town in the heart of the high volatile Pittsburgh coal seam. Originally opened in 1901, the mine has be¬come one of the largest in the US, encompassing an area of approximately 103.6 sq km (40 sq miles). The seam being mined was the high volatile Pittsburgh seam which ranged in thickness from 1.8 to 2.96 m (6 to 91/2 ft). Three types of mining methods were employed: con¬tinuous mining, longwalling, and shortwalling, with each type accounting for 50%, 30%, and 20% of total pro¬duction, respectively. A total of 630 contract and super¬visory personnel were employed to produce the mine's designed annual tonnage of 1.8 Mt (2 million st). There were ten producing sections, eight continuous miners, one longwall, and one shortwall, operating a total of 22 unit shifts per day. Eight shafts, varying in depth from 80.2 to 194.2 m (263 to 637 ft) provided entrance to the Pittsburgh coal seam. These shafts were used for ventilation, portaling, coal hoisting, supply, and emergency escape hoisting. Ventilation was achieved by means of three exhaust fans which provided 707.9 m3/s (1.5 million cfm) of air to the mine and removed approximately 141 584 m3 (5 mil¬lion cu ft) of methane per 24 hr period. The room-and-pillar method was used for secondary recovery with designed barrier blocks between panels of 61 m (200 ft) in width. A double row of blocks was left around each gob area to provide efficient bleeder action

Jan 1, 1982

By Fred N. Kissell

INTRODUCTION During the last few years, several new ventilation developments have attracted the interest of mining engi¬neers. Some of these developments are applicable pri¬marily to hard-rock mining, while others are more applicable to coal mining. STOPPINGS Parachute Stopping The parachute stopping is a new type of quick-erect stopping that is intended for temporary use in hard-rock mines (Kissell, Thimons, and Vinson, 1975). As shown in Fig. 1, the stopping is shaped very much like an ordinary parachute, with a canopy of impermeable fabric that is sewn to regularly spaced straps running to a common point. To erect the stopping, the straps are attached to a fixed anchor point such as a roof bolt, and the edge of the canopy is lifted into the moving air¬stream. The airstream pops the parachute canopy into place, and the differential air pressure across the stop¬ping holds it in place, forcing the fabric against the walls, roof, and floor of the mine opening. The principal advantage of the parachute stopping is that it requires only a few minutes to install, making it a great time-saver for emergency use or for day-to¬day changes in ventilation during the production cycle. However, the parachute stopping does require some minimum air velocity to lift it and some minimum differential pressure to hold it in place. For a fabric weighing 0.27 kg/ m2 (8.0 oz per sq yd), the minimum air velocity is about 0.5 m/s (100 fpm), and the mini¬mum differential pressure is about 0.05 kPa [0.2 in. water gage (WG) ]. There is always some air leakage around the stop¬ping, mainly depending upon the extent to which pipes or other obstructions encumber the airway and prevent good sealing. Leakage of a few cubic meters per second (a few thousand cubic feet per minute) can be expected, unless foam is used to improve the seal at the edges of the canopy. Quick-Fix Blowout Stopping The quick-fix blowout stopping is a variation of the parachute stopping (Thimons and Kissell, 1976), and it is used in the proximity of blasting operations. This type of stopping is designed to be blown out easily by the blast forces, and it may be reinstalled quickly and easily. The long high-strength straps of the parachute stopping are replaced by groups of short straps that tear easily. These straps are attached at six equally spaced locations around the perimeter of the canopy. To erect the stopping, one strap of each of the six groups is fastened to the mine wall, roof, and floor by using spads, by setting pins with a powder-actuated gun, or by tying the straps to some firm anchor point. Once the straps have been attached, the differential air pressure across the stopping, which must be at least 0.025 kPa (0.1 in. WG), forces the stopping perimeter against the mine walls, thus creating the air seal. It is the self-sealing feature of this stopping that makes it a significant time-saver. Only a few attachment points are needed; in many cases, four attachment points are sufficient, since the stopping naturally tends to form a seal with the airway surfaces. When nearby produc¬tion blasting exerts excessive forces on the stopping, one or more of the straps tears away from its attachment point, protecting the stronger canopy from damage. Damage-Resistant Brattice The damage-resistant brattice is a stopping that is designed for use in mines such as salt and limestone mines where the differential pressures are low and the roof is relatively flat. As shown in Fig. 2, the damage-resistant brattice consists of a series of brattice panels that are hung vertically and joined by Velcro® connections. When the brattice is subjected to strong blast forces, the Velcro® connection peels apart and allows the panels to open without incurring damage. The Velcro® connections can be resealed by hand within a matter of minutes. Such damage-resistant brattices have withstood the blast effects of 318 kg (700 lb) of ammonium nitrate-fuel oil (ANFO) explosive detonated as close as 91 m (300 ft) from the brattice. Ordinary brattice cloth is used for the panels, with a 51-mm (2-in.) wide strip of Velcro® hooks sewn along one edge of the length, and a 51-mm (2-in.) wide strip of Velcro® pile sewn along the other edge. Both the hooks and the pile are sewn onto the same side of the brattice cloth. The resulting Velcro® seal formed be¬tween adjacent panels is perpendicular to the brattice itself, and the leading edge of the seal can be directed either toward or away from the blast forces; the brattice works equally well in either case. To hang the brattice, panels of brattice cloth about 0.9 m (3 ft) longer than the height of the airway are cut from a 1.8-m (6-ft) wide roll. The additional 0.9 m (3 ft) of brattice cloth allows 0.3 m (1 ft) for attachment to the roof by means of a board, with 0.6 m (2 ft) for forming a good air seal at the floor. Each brattice panel is wrapped once or twice around a 51 X 102 mm (2 X 4 in.) or 25 X 76 mm (1 X 3 in.) mounting board that is 254 to 305 mm (10 to 12 in.) shorter than the width of the panel. For convenience in

Jan 1, 1982

By Phil Patton, Bill M. Stewart, Curtis Clark

Handling materials in underground mines continues to be a major safety problem. To help reduce materials-handling injuries, the National Institute for Occupational Safety and Health (NIOSH) at the Spokane Research Laboratory is developing, modifying, and testing equipment to replace the necessity of doing lifting tasks manually. To reduce single-event lift injuries, equipment having mechanical automatic weight sensing and balancing control was investigated. The Coleman manipulator was selected for testing. Modifications to the Coleman manipulator to make it more suitable for underground mine use included mobilization, self-containment, all-purpose gripper attachment, and support jacks. To reduce or eliminate the need to clean off manually the materials that commonly plug grizzly openings (timbers, wire mesh, roof bolts, and other debris), a track-guided pincher arm device was developed. The TGPA attaches to an impact hammer head, and the pincher arms are controlled by the operator of the hammer. Oversized rock can be broken with the pincher arms in the up position; the arms can then be lowered to grab and remove debris. Sweeping action to remove cohesive fines bridging grizzly openings is also greatly improved. This device is especially useful in recessed grizzlies. An industrial gun was tested to evaluate its effectiveness in breaking oversized rock. Boulders up to 76 cm in diameter were successfully broken to minus-33 cm. Although methods to control fly rock need to be developed, an industrial gun may be a safe and inexpensive alternative to breaking oversized rock in certain underground mining situations.

The use of belt air in underground coal mines has been a continuous discussion since it was first introduced in the Federal Coal Mine Health and Safety Act (Coal Act) of 1969. Although the Coal Act prohibits the use of belt air to ventilate active workings, there were two exceptions prior to the 2004 Final Rule. There have been several major studies/rule-proposals by MSHA since 1985 and the most recent of which is the Technical Study Panel (TSP) established by the Mine Improvement and New Emergency Response (MINER) Act of 2006 to study the use of belt air and related issues. This paper reviews the history of belt air use, its associated controver-sies, and more specifically, the 20 recommendations unanimously approved by the TSP.

Jan 1, 2009

By Timothy Batchler, Khaled Mohamed

Standing supports have been used in coal mines for decades to enhance roof support capability. Sometimes standing supports are used as a tool to resist the lateral movement of spalled ribs. Researchers from the National Institute for Occupational Safety and Health (NIOSH) are conducting a testing program for different types of standing supports (steel and timber) to investigate the effect of lateral loading on their vertical loading capacities and the factors affecting their lateral loading capacities. In this paper, the mine roof simulator (MRS), at the NIOSH Pittsburgh research facility, was used to determine the response of steel props to vertical and horizontal loadings. Finite element models (FEMs) were developed and verified using the tested steel props. To justify the testing program for testing standing supports with end-conditions of rock-like materials, the verified prop models were used to study the effect of a wide range of roof and floor materials (gray shale, shale, and claystone) on the critical buckling loads of the steel props. Also, several lateral loading scenarios were evaluated in which the steel props were laterally loaded at different heights. The critical buckling load for steel props setting up against a claystone roof and floor was found to be one-half of that shown by the MRS test where roof and floor platens are made of steel. Minimum prop performance was observed when the lateral load was applied at the mid-height of the steel prop, especially at small lateral displacement (less than 2 in).

Sep 10, 2022

By O. Porterfield, M. O’Kane, M. Endersby

BHP Iron Ore initiated research programs in January 1995 to develop long-term plans for decommissioning waste rock material at its Mt. Whaleback operation. More than 2 Gt (2.2 billion st) of waste rock were deposited during the past 30 years. Ultimately, a total of 4 Gt (4.4 billion st) will be deposited in waste rock dumps constructed near the open pit. The Mt. Whaleback operation is located in a semiarid climate adjacent to Newman, Western Australia. The primary research program includes the development of technology for the long-term performance of the waste rock dumps with respect to vegetation, slope stability, surface runoff, erosion and water infiltration. This paper focuses on the design and implementation of a cover system to prevent water infiltration to the underlying waste rock. Data obtained from a laboratory program and from soil-atmosphere modeling was used to design horizontal field test plots. The construction of the horizontal surface field test plots is discussed together with the field instruments installed to monitor performance. The cover system is designed to maximize infiltration during wet periods for subsequent evapotranspiration while minimizing surface runoff. The result is a near-zero net infiltration to the underlying waste material. An important feature of the design is the use of run-of-mine waste material as the cover material. Monitoring is in progress and will continue for at least two annual wet/dry cycles. The optimum cover system should minimize the net infiltration of water to the underlying waste rock while maintaining physical and ecological integrity for long-term performance.

Jan 1, 2000

By G. Akdogan, T. P. Kekana, Q. G. Reynolds

The DC arc plasma gasifier concept is currently under development at Mintek for testing the feasibility of producing syngas from waste coal fines and dry steam. The technology is intended for the valorisation of low-grade discard coals into market-quality syngas, which may then be used for largescale electrical power generation to address current grid supply challenges in South Africa. Other potential applications include feedstock for petro-chemical plants, fuel for transportation vehicles, domestic and industrial heating, and others. The proposed concept of a DC arc plasma gasifier was developed based on a plasma torch, metallurgical-based and entrained flow coal gasifiers. The principles of design and operation of the proposed gasifier are based on the concept of the Westinghouse Plasma Corporation (WPC) gasifier where the torches are substituted by graphite electrodes from which electric arc plasmas are generated. The DC section of the gasifier will be designed considering Mintek’s experience in the sealing of the furnace as carried out in the Mintek Thermal Magnesium Process. As part of the building blocks of a full conceptual design, the feasibility of the DC arc plasma gasifier was investigated through testing and modelling of its critical elements as proof of concept. The main activities of this work included pilot scale evaluation of the arc behaviour in the presence of dry steam, modelling of the temperature distribution within the reactor and explosibility studies on three different coal dust samples. Keywords: DC arc plasma gasifier, explosibility index, lower explosion limit, minimum ignition energy

Jan 1, 2020

By Anthony Konya, Calvin J. Konya

The publication, RI8507, from the U.S. Bureau of Mines established an envelope equation that related scaled-distance to peak particle velocity in an attempt to predict ground vibration in the design phase of a blast. This has been further modified by Oriard, Dupont, Konya & Konya, and others to develop more refined prediction models for specific situations to obtain better predictions. While these equations can be an ideal starting point for a greenfield blasting project or a project with no given information, these equations can have errors.

Jan 1, 2018

By R. J. Seibel

A statistical comparison of the dust exposures of coal miners with identical occupations in Pittsburgh, Pocahontas, Freeport, and Kittanning seams was conducted. Results indicated that, in some cases, identical occupations have different dust exposures in different seams. For example, the continuous miner operator in the Pittsburgh and Pocahontas seams is exposed to more dust than the same man in the Kittanning seam, but the Kittanning seam has more dust along the haulage roads than the other seams. Also, average dust exposures for similar occupations in continuous and conventional mining operations are similar.

Jan 1, 1974

By S Lockie, G Ivanova, J Rolfe

One of the consequences of mining expansion in the Bowen Basin region of Central Queensland in Australia has been a substantial increase in demand for housing, with subsequent impacts on housing and rental markets. Those pressures are reduced to some extent by a proportion of the workforce choosing to live in other centres and commuting to workplace for block periods. The main factors influencing location choice are: housing availability and affordability, basic urban services and lifestyle of the town and the town physical attractiveness such as coastal town. Low costs housing provided by the mining company acts as an attracting factor for some miners to live in the mining town. Recommendations for three short-term and two long-term strategic policy guidelines to address housing situation and location issues are provided.

Jan 1, 2009

By Noel N. Moebs

Five LANDSAT lineaments in the coal mining region of southwestern Pennsylvania were investigated by the Bureau of Mines to determine their geologic character, relation to subsurface conditions, and the means of discriminating one from another. The investigation included earth resistivity and very low frequency (VLF) electromagnetic traverses, soil moisture sampling, and a correlation with coal mine roof conditions. The lineaments could not be detected by the methods used, suggesting that they might be a surface phenomenon unrelated to subsurface geologic structures or roof stability in coal mine workings beneath.

Jan 1, 1987

By M. Cowling, S. Kumarl, A. W. Piper, R. A. Forsdick, C. Bailei, M. Patell

"The lead-refining process takes place in hemispherical vessels called kettles. In these kettles, lead-bullion is mixed at a certain temperature to remove impurities from the melt. This paper presents steps in a novel method for calculating vortex shape and flow field in the refining kettle using Computational Fluid Dynamics (CFD). First of all a two-dimensional axisymmetric model is used to calculate the vortex shape at the liquid-air interface. Here action of impellers and baffles are accounted for by adding source and sink terms to the appropriate momentum equations. The model includes Yolume of Fluid (YOF) method to predict the shape of interface deformation, i.e. vortex. This strategy reduces the computationally intensive three-dimensional transient simulations to a more efficient two-dimensional model. The calculated vortex shape is then used to regenerate a full three-dimensional grid. This grid is used to carry out steady-state simulation using the standard multiple-reference-frame method of impeller-fluid-baffle interaction within the commercial code Fluent. Simulation results for both stages of the development are compared with experimental data.IntroductionOne of the most important steps in Lead Refining process is impeller stirred mixing of Lead Bullion in hemispherical vessels. During this process, the melt is treated with one or more reagents in order to remove impurity elements such as copper, antimony, silver and bismuth. These impurities react selectively with the reagents and float to the melt surface in the form of a powdery layer, which is then skimmed for further processing. Figure-! shows (a) the lead refining kettle and (b) the schematic representation of involved flow pattern. Stirring of the lead bath using specific impeller designs, which creates a central vortex, provides a mechanism for draw-down and dispersion of the buoyant reactants. Clearly, effective control of the impeller generated vortex and flow pattern is crucial to achieving efficient operating conditions."

Jan 1, 2001

By Max Gwynn, Tony Suckling

"The new Wembley Stadium is the most spectacular soccer stadium in the world, built to the highest specifications, using the latest technology and offering visitors an unrivalled match-day experience. Wembley Stadium is the home of English soccer, dating back to 1918 when the British Government began planning a British Empire Exhibition with a stadium as its centrepiece. The Empire Stadium, as it was originally known, was completed in 1924 in just 300 days and cost £750,000 ($1.4m). It was finally closed in 2000.The new Wembley Stadium, which opened in 2006, features fully covered seats for 90,000 fans and a striking arch that sits above the northern half of the stadium. With a span of 315 m (1040 ft), the 133-m (440-ft) tall arch is the longest single-span roof structure in the world. It supports the entire weight of the northern roof and 60% of the weight of the southern retractable roof. This means there is no need for columns within the stadium and ensures unobstructed views.Multiplex Constructions (UK) Ltd. employed Stent Foundations Limited to construct the £10m ($19m) foundations package for the new stadium. The scope of works for the foundation package included the design and construction of all foundations, including all main works piling, temporary works piles for the arch and roof, and tower crane piles. The scope also included trial piling and pile testing, setting out and removal of spoil.Piles were constructed by using bored cast-in-place techniques with both hydraulic and traditional crane-mounted rigs. Stent also installed sheet-piled walls at three locations to the site’s northern boundary. In addition to the main contract works, Stent constructed a £2m ($3.8m) contiguous bored-pile retaining wall within the demolition and earthworks package (Figure 1). This work was carried out as a subcontractor to Griffith McGee."

Jan 1, 2008

By C. F. Feng, L. Froyen

"In-situ processes have emerged as new and promising techniques for metal matrix composite fabrication. They offer significant technical and economic advantages over conventional processing. One of the in-situ processing routes that have been used is reactive free sintering of a mixture of powder reactants. However, materials synthesised via this route are always porous because of density differences between reactants and products. An example are the porous Al/(TiB2+Ah03) MMCs obtained by heating powder mixtures of Al+ Ti02+B with Ti02 and B in stoichiometric ratios for forming TiB2• In this study, porous Al/(TiB2+Ah03) composites were further processed by hot-pressing at temperatures above 600°C. This processing cycle was designed so that the composites could be densified. Furthermore, the reaction kinetics of the in-situ processing are studied by means of DSC analysis measured at different heating rates. The activation energies of the three intermediate steps that are involved in the reactive processing for preparing AV(TiB2+Alz03) MMCs are determined to be 923 kJ/mole, 241 kJ/mole and 235 kJ/mole respectively.XRD proved that the hot-pressed products consist of Al, TiB2 and Al203- Properties of the products are assessed by microstructural characterisation (LOM, SEM and EDS), microhardness, Young's modulus and bending tests. The results show that good microstructures, elastic properties and strengths, as well as acceptable ductilities were achieved. For the composition 79.74wt% Al-15.95wt% Ti0z-4.31wt% B, after the reactive free-sintering and hot-pressing cycles, Young's modulus is 105 GPa, bending strength is 509 MPa and maximum strain is 5.0%; for composition 88.73wt% Al-8.87wt% Ti0z-2.40wt% B, they are 89 GPa, 311 MPa and 8.2% respectively. It can be seen that the properties of products can be tailored by adjusting the relative amounts of reactants in green samples. Furthermore, for comparison reasons, Al and a binary system Al-Ti02 were identically processed as the ternary systems. Their microstructures and properties were studied."

Jan 1, 1998

By R. H. Frazier, J. M. Hodge, F. W. Boulger

This paper reports the results of studies of the impact properties of quenched and tempered alloy-steel plates as a function of sulfur content. It was found that the impact energy levels decreased continuously as the sulfur content increased and that there was a straight-line relationship between impact energy and sulfur content when plotted on logarithmic coordinates. Cross rolling raised the level of these Lines for transverse tests and lowered the level for logitudinal tests proportionately to the amount of cross rolling. ALTHOUGH it has been generally recognized that, for applications in which notch toughness is critical, the sulfur content of the steels used should be held to a low value, quantitative information on the effect of sulfur on notch toughness has not been available. For such applications, it is a common practice to specify minimum impact values, and in order that these may be met consistently it is important that the steel producer know quantitatively the effect of sulfur on notch toughness so that realistic sulfur content limits can be applied to the steels they produce. In many instances, particularly in flat-rolled products, impact properties are specified in the direction transverse to the principal rolling direction, so that the factors affecting the anisotropy or directionality of impact properties are also of concern to the steel producer. For some applications, furthermore, it is a common practice to increase the sulfur content of steels in order to improve their machinability, and, in such instances, the effect of this practice on notch toughness may often be of concern. This paper reports on an investigation, carried out at Battelle Memorial Institute, designed to furnish this quantitative information on the effect of sulfur on notch toughness and also to furnish further information on the factors affecting the anisotropy of impact properties in wrought heat-treated alloy steels. MATERIALS AND EXPERIMENTAL PROCEDURE The experimental steels were of intended base analysis: 0.30 pct C, 0.80 pct Mn, 0.25 pct Si, 2.5 pct Ni, 0.80 pct Cr, and 0.45 pct Mo. Steels were made with sulfur contents varying from 0.005 to 0.179 pct. The steels were prepared from 600-lb induction-furnace melts. Steels containing 0.020 pct or more sulfur (at meltdown) were melted from a charge of ingot iron (except for one heat): lower-sulfur steels were made from electrolytic iron. The charge consisted of ingot or electrolytic iron, ferrosilicon to give 0.10 pct Si, and ferromanganese to give 0.05 pct Mn. At meltdown, electrolytic nickel, ferromolybdenum, iron phosphide, and pyrite were added followed in sequence by ferrochromium, sili-comanganese, ferrosilicon, and ferromanganese. The slag was then removed and graphite added to give the desired carbon content. Bath temperature was adjusted to 2850°F and, when no other additions were to follow, 2 lb per ton of aluminum was added, immediately before tapping. Compositions of the experimental steels appear in Table I. Analyses are from single determinations, except sulfur which was analyzed in duplicate. A test sample (3 in. in diam by 6 in. long) and a 575-1b ingot were poured from each heat. The test sample was poured in a sand mold; the cooling rates of the test sample and the large ingot were approximately the same. Chemical analysis chips and metal lographic specimens were taken from the test samples. The ingot was 8 in. sq at the base and 9 in. sq at the top. A 5 X 5 X 6-in. sand mold hot top was completely filled in teeming the ingot. After solidification, the mold was stripped from the ingot which cooled to room temperature. Ingots were reheated to 2250"F and rolled to 1.9-in. slabs on a commercial mill. The slabs were box-cooled to room temperature. Sections of the 1.9-in. slabs were heated to 2250°F and rolled on a Battelle laboratory mill according to one of three schedules: 1) rolled straightaway to 0.5-in. plate; 2) rolled straightaway to 1.3-in. thickness, then cross rolled to 0.5-in. plate (29 pct cross rolling); or 3) cross rolled from 1.9-in. to 0.5-in.-thick plate (46 pct cross rolling). The 0.5-in.-straight- or cross-rolled plates were normalized at 1700°F for 1 hr and then water quenched from 1600°F. Plates were then tempered 2 hr at 1240°, 1170°, 1080°, or 860°F to obtain Rockwell C hardness of 25, 30, 35, and 40, respectively. Tempering was followed by quenching to room temperature to avoid temper embrittlement. Slack-quenched plates were isothermally transformed for 26 min at 800°F, quenched, and tempered 2 hr at 1170°F. Pearlitic microstructures were obtained by holding 168 hr at 1200° F, followed by quenching. Charpy V-notch specimens were taken both transverse and longitudinal to the main rolling direction, notched perpendicular to the plate surface, and tested. Slabs and plates which were to be homogenized

Jan 1, 1960

By Mendeckl A. J

Anglo American Corporation has always viewed technological development as vital and as such has placed research and the implementation of new technological practices high on its priority list. Support is given to a number of research institutes but a significant degree of reliance is placed on in-house research carried out at individual companies and at the Group's main laboratory complexes. The Corporation's interests are diverse with advanced practices and innovative technology ranging from new battery technology with wide application to deep level shaft technology with very specific application. In this paper, we aim to concentrate on a particular system developed primarily for use in seismically active deep mines. The system has proved to have far wider application and has the potential to be further enhanced to meet the needs of users across a broad range within the industry and even beyond. As the nature of this conference is to inform delegates of advanced mining practices, we should simply mention that we could have talked on subjects relating to the advances made in deep level winding technology including winder drive and brake control to alleviate dynamic rope loads, shaft steel design for high pay load high speed winding and shaft safety systems such as slack rope devices and moving lip loading facilities to cater for rope stretch. Other areas of interest relating to refrigeration using ice technology or non-explosive rock cutting using diamond wire or saw technology could also have been of interest. As the South African gold mines become deeper and the problems associated with depth become more acute, answers had to be found and systems developed to cope with very high rock stress and the related seismicity. The fundamental understanding of the behaviour of the rock mass has always been important but became critical on our mines to ensure the safe extraction of the orebody. Basic research into and the application of physics, applied mathematics, seismology, rock mechanics, electronics and computer technology have helped us to develop the Integrated Seismic System - Integrated because of the system's abilty to monitor seismic and non-seismic sensors simultaneously and because it encompasses data acquisition, processing and interpretation into one system. The system which is in use at all our gold mines has found application not only in South Africa but also in such locations as Australia, Chile, Canada, Europe and Japan. A highly motivated team of scientists under the leadership of Aleksander Mendecki developed the majority of the hardware and software needed for the system. In essence, the system allows us real time monitoring of energy release and stress transfer data that with the aid of modern computers is turned into useful information. The information so obtained has allowed us to improve our mine and extraction designs to minimise the inherent hazards. The system has proved to be an extremely useful management tool as substantiated by the demand for the product. The paper is intended to convey to the reader the technical concepts and the presentation is intended to demonstrate the usefulness of the system.

Jan 1, 1995

By Irving B. Cadoff, Alvin A. Machonis

The resistivity, Hall coefficient, Seebeck coefficient, and thermal conductivity were measured as a function of temperature for cation-rich alloy single crystals covering the composition range across the PbTe-SnTe system. Alloying of PbTe with up to 20 pct SnTe was found to have little effect on the energy gap. Above 20 pct SnTe the alloys were "p" type but below this range the sign could be varied by heat treatment. The lattice thermal resistivity of the compounds SnTe and PbTe is raised by alloying one with the other. Z values in the order the interesting values obtained. THE PbTe-SnTe system has several interesting features. For one, PbTe is a useful thermoelectric material and the possibility of improving its figure of merit by alloying with SnTe, an isomorphous compound, has been suggested since these pseudo-binary solid solutions generally have a more favorable ratio of electrical conductivity to thermal conductivity than either of the components.' Other interesting features relate to the conductivity mechanism, band structure, and stoichiometry of the compounds and their alloys. PbTe is a semiconductor with an energy gap of about 0.29 ev2 at room temperature whose conductivity sign and magnitude can be varied from "n" to "p" by controlling the proportion of lead and tellurium with respect to the stoichiometric ratio.3 Excess lead results in "n"-type conduction. SnTe is found to exist only as a "p"-type material of relatively high conductivity. This behavior is attributed to stoichiometric deviation by Brebrick4 but Sagar and Miller proposed that the behavior of SnTe must be due in part to the presence of an overlapped band. An investigation of alloys of this system, therefore, might give additional information which would permit one to evaluate which of the two proposals is the more appropriate one. Abrikosov et al.' studied the room-temperature electrical properties of these alloys and reported data for Seebeck coefficient and resistivity on poly-crystalline alloys. The present work is a more exhaustive survey of the PbTe-SnTe system. Re- sistivity, Hall coefficient, Seebeck coefficient, and thermal conductivity were measured over a wide temperature range for single crystals at 10-pct intervals of lead/tin ratio across the pseudobinary system. The relative concentration of tellurium was controlled so as to obtain metal-ion excesses in all cases. SAMPLE PREPARATION The crystals were prepared by melting elemental lead, tin, and tellurium in weighed proportions in evacuated Vycor capsules. The lead and tellurium were high-purity grades obtained from American Smelting & Refining Co. The tin was supplied by Comico. The proper calculated proportions of lead, tin, and tellurium were weighed and charged into prepared Vycor capsules prior to evacuation. The capsules were prepared from 15-mm Vycor tubing. A sharp point was worked on one end of the tube. A pyrolytic graphite coating was deposited on the Vycor walls by heating the tip to 800°C in an atmosphere of acetone-saturated argon. An additional coating of graphite was deposited on the pyrolytic coating from an Aquadag suspension. Above the coated tip the tube was reduced in diameter to form a constrictive neck. To avoid scratching the graphite coatings the charge was placed in the tube above the constriction. After a low-temperature bake, the evacuated capsule was sealed. On subsequent heating the charge melted down into the lower portion of the capsule. The crystals were grown by lowering the capsule through a Bridgman-Stockbarger furnace. The lowering rate was 1 in. per 8 hr. The upper portion of the furnace was set for 950°C and the lower portion for 800°C. In general the yield of single crystals was about 25 pct. The mixed compositions were, as expected, the most difficult to grow. The finished crystals were sectioned into 5/8-in. slices. The tip, end, and middle slices from each crystal were analyzed by X-ray fluorescence to determine the lead-to-tin ratio. The resulting values were used to plot a composition vs distance plot for each crystal. Slices were selected from each crystal, with the aid of the composition plots, to cover the complete range of compositions at 10-pct intervals. In general, the slices selected were taken from the seed end of the crystal where the longitudinal segregation (as determined from the X-ray fluorescence analysis) was a minimum. Laue single-crystal analysis and metallographic analysis was used to verify if a slice was single or polycrystal. Any grain boundaries were clearly visible in the as-cut and polished condition. In ad-

Jan 1, 1964

By A. McLean, D. W. Gomersall, R. G. Ward

An experimental study has been made of the solubility of nitrogen in liquid iron and liquid Fe-C alloys using levitation melting and a rapid quenching device. Iron alloy droplets were equilibrated with nitrogen gas at 1 atm pressure, quenched, and analyzed. Previous techniques for studying the Fe-C-N system have produced data which me in marked disagreement. This disagreement is due largely to errors caused by reaction between the molten alloy and the crucible material. With the levitation procedure, errors from this source have been eliminated and precise solubility data obtained for temperatures between 1450° and 1750°C. C-N interactions in molten iron have been expressed in terms of first- and second-order free energy, enthalpy, and entropy parameters. ALTHOUGH the solubility of nitrogen in iron base alloys is in general small, the effects of nitrogen on the properties of steel may be quite profound. For most purposes nitrogen in finished steels is undesirable, particularly in the low-carbon grades, since on cooling to room temperature the solubility limit of nitrogen in the steel may be exceeded and this can lead to embrittlement and loss of ductility on aging. On the other hand, nitrogen can improve the work-hardening properties and machinability of steels while in certain stainless grades nitrogen is important in order to stabilize the austenite phase. It is, therefore, desirable that one should be able to predict the solubility of nitrogen in liquid iron alloys. To do this, information is required concerning the interactions between nitrogen and the various alloying elements which may be present in liquid iron. There have been several investigations of these effects in recent years1"7 and the interactions between nitrogen and many elements dissolved in liquid iron are now known to a high degree of precision at steel-making temperatures. Unfortunately, a number of iron alloy systems which are of interest in steelmaking have been difficult to deal with by the experimental techniques generally used for this type of investigation. Among the most important of these are the Fe-C alloys. In the past, two methods have been widely used for determining nitrogen solubilities: the Sieverts' technique, in which the amount of nitrogen required to saturate a given mass of liquid metal at a particular temperature and pressure is measured volumetrically, and the sampled-bath technique in which liquid metal held in a crucible is equilibrated with a gas phase containing a known partial pressure of nitrogen, and samples drawn from the melt are quenched and analyzed. These two methods have been discussed in detail elsewhere.5,8 With the Sieverts' technique, errors may be introduced from the following sources: i) Gas adsorption on metal films which have condensed on the cooler parts of the reaction chamber. ii) Uncertainty in the determination of "hot volume" calibrations. iii) Crucible-melt interaction, particularly if a gaseous reaction product is formed or if the melt becomes contaminated with material from the crucible walls. The sampled-bath method may also suffer from errors due to reaction between the melt and the crucible material. In addition, there is the possibility that gas may be lost from the sample during solidification and cooling. In the present investigation, the solubility of nitrogen in liquid iron alloys has been studied by means of a new technique based on the use of levitation melting equipment and a rapid quenching device. In addition to the fact that problems of the type outlined above are avoided, this particular approach has the following advantages: i) The high-frequency current induces vigorous stirring within the levitated droplet so that gas-metal equilibration is rapidly attained. ii) The gas phase surrounding the melt can be changed very quickly and is easily controlled. For example, a droplet may be levitated in helium, deoxidized in hydrogen, equilibrated with nitrogen, and quenched, within a period of 15 min. ii) Melts can be readily under cooled or superheated, thus extending the effective temperature range of an investigation and allowing temperature-dependent data to be determined with a high degree of precision. Excellent reviews of levitation melting techniques and their application to physical-chemistry studies at high temperature have been published recently by Jenkins et al.,9 Peifer,10 and Rostron.11 In the present investigation a levitation melting technique has been used to obtain data for the solubility of nitrogen in pure liquid iron and liquid Fe-C alloys at temperatures between 1450° and 1750°C. The solution of nitrogen in liquid iron can be described by the reaction:

Jan 1, 1969

By T. H. Weldon, L. V. Whiton, R. R. McNaughton, J. H. Hargrave

Oxygen enriched air is being used quite extensively in the metallurgical plants of The Consolidated Mining and Smelting Co. of Canada, Limited, at Trail, B.C. The oxygen used for this purpose is a by-product from the Company's chemical plants located in the area. Most of the ore treated in the Trail metallurgical plants comes from Com-inco's Sullivan Mine at Kimberley, B.C. At Kimberley the ore is milled to produce lead and zinc concentrates which are shipped to Trail for further treatment to metal. One section of this paper deals with the use of oxygen enriched air in the suspension roasting of the zinc concentrates. In this process the concentrate is calcined for leaching preparatory to electrolytic recovery of the zinc. A second section of the paper describes the use of oxygen enriched air in operations at the lead smelter. There oxygen enriched air is used in the blast to the lead blast furnaces and in the slag fuming furnace which recovers the lead and zinc contained in lead blast furnace slag. The final section of the paper outlines the precautions necessary for the safe use of oxygen enriched air in any plant operation. The Use of Oxygen Enriched Air in the Suspension Zinc Roasters The suspension roasting of zinc concentrate developed at Trail, B.C., has been described in AIME Vol. 121, "The Electrolytic Zinc Plant of The Consolidated Mining and Smelting Company of Canada, Limited" by B. A. Stimmel, W. 11. Hannay and K. D. McBean. Since the publication of that paper, the use of oxygen enriched air in suspension roasting has been introduced as regular practice with marked advantage. The relative importance of a specific advantage may vary with changing conditions, but, in general, it may be stated that improved operation has been achieved at increased capacities. Suspension roasting is carried out at Trail in converted standard 25 ft diam Wedge roasters. The 2nd, 3rd, 4th and 5th roasting hearths have been removed and the drying hearth covered over. Drying of the concentrate is done on the drying hearth and the 1st roasting hearth. The dried concentrate, after any lump's have been broken up in a ball mill, is fed to a single burner located in the upper part of the combustion chamber. Oxygen is introduced at the burner fan along with the gases from drying, returned combustion gases from the waste heat boiler outlet and the required amount of new air. Up to 60 pct of the concentrate settles out on the 6th roasting hearth, the rest passilig out of the roaster. The product collected in the waste heat boiler is finished calcine, but the dust collected in the cyclones after the boilers is returned to the base of the combustion chamber where the sulphate is decomposed. Gases from the c'yclones go to a Cottrell precipitator. The discharges from the 7th roasting hearth and the waste heat boiler are combined with the Cottrell dust to give the finished calcine. Following small scale tests started in 1933, oxygen enriched air has been used continuously in the suspension roasting of zinc concentrate in Trail, beginning in 1937. A significant factor in promoting its use in this operation was the availability of by-product oxygen from the Company's near-by Chemical and Fertilizer Division. To-day it is standard practice at Trail to use oxygen enriched air for zinc concentrate roasting. The most important requirement in roasting a zinc concentrate for an electrolytic plant is that the zinc in the calcine should have maximum solubility. It is also desirable at Trail that the gas produced for the manufacture of suhhuric acid should have a ~naximum concentration of SO2 and that a substantial recovery of waste heat from the gas be achieved. High solubility of zinc requires that the sulphide sulphur and zinc ferrite in the calcine be kept low. These are both functions of temperature and time, with formation of zinc ferrite also dependent on contact between the iron and zinc particles. One of the inherent advantages of suspension roasting is that minimum time and contact are achieved. The limit on temperature is imposed by the fusion point of the concentrate and not by the need to control zinc ferrite formation. Operating temperatures are normally maintained within the limits of 1725" and 1850°F. A relatively low zinc sulphate in the calcine is required at Trail, and this results from discharging the calcine from the high sulphur dioxide atmosphere at a temperature above 1600°F.

Jan 1, 1950