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By S. Monette, D. B. Dreisinger, D. Vleeschhouwer, G. B. Harris, G. A. Kordosky

A new process for the recovery of pure (>99.95%) palladium and platinum is described. The process, which has been tested at the pilot scale, comprises (i) the simultaneous solvent extraction of palladium and platinum by a new Schering Berlin reagent, TN 1911, (ii) washing of the loaded extractant to remove co- extracted impurities, and (iii) differential stripping of first platinum at pH 3, and secondly palladium with strong hydrochloric acid, and (iv) precipitation of palladium and platinum salts, followed by reduction to metal. The process is, unusually, a non-ammonia one requiring only small amounts of ammonia at the end where final purification may be necessary for particularly complex feed solutions.

Jan 1, 1993

Provide a rapid, reliable means of warning underground miners of a fire or other emergency. Approach An ultalow-frequency electromagnetic signaling system was designed, breadboarded, and tested at various under around mines. How It Works Current fire warning systems for underground mines, such as stench, audible alarms, and messengers, arc slow, unreliable, and seldom achieve total mine coverage. An ultralow-frequency electromagnetic fire warning alarm system with true through-the-earth signaling capabilities was developed to solve these problems. The system was originally designed for high-back room-and-pillar mines where stench systems are unusable due to the low velocity of mine air flow. However, the system has an application to all underground mines.

Jan 1, 1988

By Laura Kelsey

Contaminant Robust In Situ Water Extractor CRIWE Nafion-based water clean-up Extract purified water from natural extraterrestrial sources In situ water processing for downstream electrolysis Chemically resistant to process contaminants such as acid

May 1, 2013

By T. Ikeda, M. Maeda, K. Mita

Galvanized steel sheet is the major product for the automobile industry. Therefore, automotive recycling results in zinc-containing scrap that should be remelted in EAFs. Naturally, the EAF dust is a very important source of zinc for zinc recycling processes. The thermodynamic properties of the Fe-Zn intermetallic compounds formed on the surface of galvanized steel sheet should be clarified to make clear the evaporation mechanism of zinc; however, there are few reports on these compounds because of difficulties in their synthesis. There are various intermetallic compounds in the Fe-Zn system. We synthesized them at about 673K. A specimen was examined chemically and X-ray diffraction was applied to ensure the formation of intermetallic compounds. Material containing two phases was placed in a Knudsen type effusion cell and the mass spectrum studied to evaluate the vapor pressure of zinc. The thermodynamic property of intermetallics was then evaluated through measured intensity.

Jan 1, 2000

By Qiang Guo, Zongliang Zuo, Mengqi Wei, Qingbo Yu, Qin Qin

Activated carbons, derived from waste ion-exchange resin by CO2 physical activation, were applied to separate CO2 from flue gas against global warming. The BET specific surface areas of activated carbons at different activation temperatures and times were investigated. The CO2 adsorption capacity was tested under non-isothermal and isothermal conditions. The experimental results show that when keeping the activation temperature constant, the specific surface area increases firstly and then decreases with increasing activation time. For the given activation time, the specific surface area rises firstly and then declines with increasing activation temperature. The adsorption capacity decreases with increasing temperature. The maximum adsorption capacity is 51.46 mg/g under the condition of 298 K and pure CO2. Fractional order kinetic model is the best one to describe the kinetics of CO2 adsorption. The activated carbons show the potential to be an effective adsorbent for the removal of CO2 from flue gas.

Mar 1, 2018

Pilot-Plant Testing of Ammoniacal-Cyanidation for Gold Recovery from Copper Gold-Bearing Ore The results of pilot-plant tested ammoniacal-cyanidation of gold recovery from copper gold-bearing ore are presented in this paper. This ore is from a deposit of Russian Federation with gold and copper grade 9.5 g/t and 0.4 per cent, respectively. Copper is largely present as malachite and azurite. The presence of chalcopyrite and bornite is also observed. In order to recover gold, gravity is recommended. Two options of ammoniacal-cyanidation using leaching of gravity tails, CIP and filtration, were tested. It was found that ammoniacal-cyanidation using filtration of leaching tailings and recycled solutions is the most optimal option. The proposed flow sheet provides for 89.7 per cent gold recovery from gravity tailings at the consumption of NaCN 0.9 kg/t and (NH4)2CO3 7.5 - 9 kg/t. Compared to conventional cyanidation, this technology decreases the consumption of sodium cyanide from 4 up to 0.9 kg/t at the same gold recovery. It can be recommended for the treatment of copper gold-bearing ores with the similar composition.

Sep 13, 2010

Records over the past ten years indicate that there is potential for serious multiple accidents due to engulfing associated with rockpasses. Significant attention is not usually given to the design of rockpasses, with the implication that mistakes leading to poor performance of the passes are often repeated. This paper outlines general guidelines for the design, support, operation and rehabilitation of rockpasses based on information obtained from the limited amount of literature on the subject.

Jan 1, 2005

By Robert P. Kennedy, Andrew H. Merritt, Edward J. Cording, Thomas R. Kipp

INTRODUCTION Measurement of certain data associated with nuclear testing necessitates the reception of waves at the instrument location which are unaffected by reflection off internal structures or tunnel surfaces. Therefore, in order to provide necessary facilities for the fielding of experiments in support of the underground nuclear testing program, the Defense Nuclear Agency (DNA) commissioned a cost and feasibility evaluation pertaining to the design and construction of large underground cavities in Rainier Mesa. The effort included research into past experience pertaining to the excavation and support of large underground caverns, assessment of the geological conditions which exist in Rainier Mesa, preliminary design of the chambers and their rock support systems based upon the geological setting, development of mining plans for the excavation of the caverns, and estimation of the cost and manpower schedule to complete construction. This paper summarizes the results of the feasibility evaluation. The investigation was limited to modified hemispherical configurations ranging in size from 24.4 to 91.4 m (80 to 300 ft) in diameter. Two cavity support systems were considered. The first employs internally installed rockbolts as the means of primary rock support while the second involves the use of annular tendon galleries located above the chambers from which primary support members are introduced prior to general excavation. The internal support configuration was considered for cavities with spans of 24.4, 36.6, 48.8, and 54.9 m (80, 120, 160, and 180 ft) while the external support configuration was considered for cavities with spans of 54.9, 73.2, and 91.4 m (180, 240 and 300 ft).

Jan 1, 1979

By T. Reed Woodbridge

The object of this paper is to bring to notice a method in use at the Cedar Point laboratory of Witherbees, Sherman & Co., for determining the phosphorus in the ore mined at Mineville, N. Y. This ore is magnetite, with a gangue containing crystals of apatite. In 1886, Mr. H. F. Dawes, then head chemist at the works, suggested that as all the phosphorus seemed to be in the apatite, it could be obtained in solution by dilute nitric acid. After some experimenting the following method was adopted, and has proved invaluable for rapidity and ease; half a dozen determinations requiring very little more time or trouble than one. From + to 10 grammes of ore are weighed into a 150 c.c. beaker; 50 C.C. hot water and 10 c.c. strong nitric acid are added; the beaker is covered and the contents are boiled for 1/2 hour (10 minutes sometimes proves sufficient; but 4 hour is safer). The bumping which ensues if more than & gramme is used need cause no trouble. The hot solution is filtered into a 250 C.C. beaker. The filtration and washing (with hot water) proceed rapidly, as the magnetite itself is but slightly acted upon. After the addition of 15 C.C. ammonia and 15 c.c. nitric acid, the solution is cooled to 45' C., and from 15 to 40 C.C. of molybdic acid solution is added and stirred vigorously. In 5 minutes the precipitate will be down, and the determination can be finished by any good method. At Cedar Point the method more commonly used is weighing as yellow salt. Good washed filter-paper is used, No. 0 Swedish being preferred; and dozen 3 1/2-inch filters are numbered and dried and weighed at 110°C. These are always kept in stock. The yellow salt is filtered on one of these, washed with dilute nitric acid (2 per cent. by volume); dried for 1 hour at 110' C., and then weighed, 1.63 per cent. of weight being calculated as phosphorus. The filters vary in the two weighings from

Jan 1, 1889

By Timothy P. Smirnoff

Sustaining the region?s mobility needs, achieving projected economic growth, and maintain Midtown Manhattan as a center of regional, national and global importance has led to continued investment in commuter rail and transit infrastructure in New York City and resulted in design and construction of large underground caverns. The current plans for stations in Manhattan include New York Penn Station Expansion (NYPSE) caverns for Trans Hudson Express (THE) Tunnel Project for New Jersey Transit (NJ Transit) and the Port Authority of New York and New Jersey (PANYNJ), Metropolitan Transportation Authority Capital Construction Long Island Railroad (MTACC/LIRR) twin caverns for East Side Access (ESA) Project, and station caverns of the No. 7 Line Subway Extension Project and Second Avenue Subway Project for Metropolitan Transportation Authority Capital Construction/New York City Transit (MTACC/NYCT). This paper provides a general overview of these large caverns now in design or construction in Manhattan, the area?s geologic setting, the geotechnical factors considered and approaches commonly applied for cavern design.

By T. Peter Philip, Erich U. Petersen, William J. Tafuri, Donald M. Hausen, Douglas N. Halbe

Scarcely a month goes by that I or someone else at Newmont Mining or Newmont Gold isn't asked to give a talk on the topic I was asked to discuss today. Investors, financial analysts, geologists, metallurgists, even our government--everybody wants to know what the future holds for gold mining. Well, you're not going to get exactly what you asked for. Today, I'm prepared to focus primarily not on what the future will bring to us, but rather on what the future will demand from us. More than that, I cannot undertake because it isn't within my scope to predict how wise and resourceful everyone in our industry will be in the future. What our future will hold, as I see it, will depend on our--and our colleagues'-- responses to these very real demands. Three critical issues stand out in my mind as to what the future will demand of us in the gold mining industry. And these demands will be for: 1. The very greatest of technical expertise and innovation. 2. The highest order of environmental sensitivity and timely accommodation. 3. Planning, planning and more planning. All of these flow inexorably today from the traditional objective of any mining company--or any company in any business, and that is, to make money. Nothing as I see it, should be undertaken by a geologist, metallurgist or even an environmental department, unless the exercises will enhance profits; and nothing may be ignored which can have consequent damage to the bottom line. Thus, the three issues I've listed for you subordinate themselves to the objective of making money, although at least in the environmental area, it might seem to some that we can only incur additional costs without even a dollar-for-dollar return. I hope to disabuse you today of any such out-of-date notion. Let's tackle the first issue-- Technical Expertise and Innovation. Newmont Gold Company this year is celebrating its 25th anniversary of successful and profitable operations on the Carlin Trend. Carlin in 1961, which is when exploration began on the "Trend" by Newmont, actually may share a lot of similarities with Carlin today. They didn't then know where the gold was and, if they found it, they had one hell of a challenge mining and processing ore at a profit because gold was selling at only $35 an ounce. Today, we know where the current reserves are. But we don't know where our future reserves lie. Furthermore, we don't know exactly how we're going to mine them, and, as everyone here knows too well, we don't know what the optimum metallurgical treatment is, even if we can find and mine them. And all that despite the abundant level of modern experience and skills within the current generation of mining companies, and the fact that, even taking inflation into account, gold sells at a higher price today than in 1965 when Carlin began operations. But, of course, I'm telling you what you already know.

Jan 1, 1990

The development of research activities at Risdon and the implementing of a policy of instrumentation in plant processes have, in recent years, entailed a considerable increase in research staff and created an urgent need for more space and modern laboratory facilities. The existing laboratories have been in use for 25 years and are now inadequate. New buildings have been authorized.The new buildings will comprise, firstly, a laboratory building of three floors giving a totai .floor space of approximately 11,000 sq.ft., and a pilot plant building as an annexe to the laboratory building, of approximately 4,900 sq.ft. The laboratory building will accommodate from 20 to 22 research workers, and additional plant operatives will be used for the control of processes in the pilot plant building. The new buildings are designed to provide facilities for three principal functions; the investigation and improvementof existing processes, the development of new processes up to the pilot plant stage, and the control and maintenance of instruments.LOCALITY AND ORIENTATION OF BUILDINGSThe site of the buildings is elevated ground on the eastern side of the main plant, near the main entrance and general office building. There will be no obstruction to sunshine at any time of the day, and the laboratory building will command views of wide radius from wooded hills across the River Derwentto the open sea on the south-eastern quarter.The buildings are located to provide space for future extensions. The main laboratory building faces approx...

Jan 1, 1949

By Thomas Domanski

Any type of deep excavation whether for Bored Piling, Diaphragm Walls or Contiguous Bored Piling Walls depends on forming a stable borehole with a defined cross-section to receive safely the permanent materials. In modern construction the excavation depth can reach well the range of 100 m and above. The diameters of the Piles reach often sizes of 2.5 m and bigger. Top casings in Bored Piles (Diaphragm Wall none) are rather short and stability below the casing, need to be secured by stabilization slurry. The boreholes need to be formed through a variety of different materials and stand open for an extended period. Without a safe stable borehole, it is impossible to produce quality products and work cost-efficient. The understanding and proper usage of a suitable slurry is a key element essential for the delivery of Foundation Elements with high quality and within a reasonable budget. The setting of mechanical and rheological parameters in specifications is necessary and helpful, but probably insufficient to embrace and control such a key element in the practical implementation of foundation construction. The proper selection, design, implementation and supervision of slurries on site requires both from Contractors and Engineers to understand how different slurries do function. Only with this knowledge the right decisions in slurry operations can be made. This talk is directed to give some help to both, Contractor’s and Engineer’s, in understanding how different type of slurries do work. (Which ones should be preferred in what kind of soils.) The better knowledge will help the Contractor to control cost and enhance production. The Engineer will be able to assist in arriving at the appropriate technical choices and include in the specifications.

Sep 1, 2022

By S. A. L. Read

"The intact rock constant, mi, is one of the three basic input parameters required for the widelyused Hoek-Brown failure criterion. Values for the constant should ideally be determined by statistical analysis of laboratory test data. In this paper the influence of the inclusion or exclusion of tensile test data on derived values is discussed. We firstly investigate the relationship between direct tensile strength (DTS) test values and Brazilian tensile strength (BTS) test values based on a literature search, finding that the correlation between the two test types is DTS = 0.9*BTS, independent of the lithology being tested. Secondly, using the shear strength database of Douglas (2002), we examine the influence of confining pressure range and the inclusion or exclusion of DTS and BTS test values on calculated values of mi.Chief amongst the influences was the exclusion of tensile data in the calculation procedure, particularly when the Hoek triaxial confining stress range requirement (?3?max = 0.5?c) was not satisfied. Based on a reasonable 1:1 relationship between R (the ratio of unconfined compressive to tensile strength), use of actual tensile data in the calculations for the Hoek brown failure criterion is considered to be a simpler and more robust approach to the use of a tensile cutoff based on empirical criteria such as that of Fairhurst (1964). We advocate the fitting a failure curve using compressive and tensile test data as the most reliable means of calculating mi, while at the same time satisfying requirements as originally advocated by Hoek relating to the appropriate triaxial confining stress range (?3?max = 0.5?c) and sufficient (>5) evenlyspread data points. In the absence of triaxial data the use of R provides a practical means of obtaining estimates of mi that are more robust than guideline values."

Jan 1, 2015

By Douglas Bartley, Brian Wingfield, Robert McClure

Recent studies and limited tests indicate favorable results utilizing high accuracy electronic detonator technology over conventional non-electric pyrotechnic systems. This study discusses the application of this technology using the Daveytronic programmable system in an on-going production basis. The study quantifies the performance as it relates to fragmentation, excavation, vibration and productivity in an eastern U.S. aggregate mining operation. In order to insure accurate data, tight field controls were adhered to during the drilling and blasting process as they related to blast design, bench preparation, pattern layout, drilling and blasthole loading. Following the blast the excavation and crushing procedures were studied to quantify any down stream advantages due to improvements in fragmentation. This study will help provide the industry with information as to the advantages of high accuracy electronic blasting systems over conventional pyrotechnic systems and show the results of an operation utilizing electronic detonator technology through their production season.

Jan 1, 2000

By D. J. Archambeault, A. Saigal

Substantial cost savings have been demonstrated by material design changes after initial product development. As more information about a product's operating environment becomes available to a designer, it is possible to consider a more costeffective material that still meets or exceeds the design intent, such as minimum low cycle fatigue life. This is especially true in the aircraft engine industry, where precise operating cycle data is not available until after the first engine is built and tested. A methodology for predicting estimated low cycle fatigue life has been developed to investigate potential material change candidates for an aft cooling plate. A twodimensional macromechanical finite element model (FEM) has been developed using ANSYS and used to determine the effects of varying material properties. It is shown that slight changes in density, coefficient of thermal expansion and modulus of elasticity have profound effects on component and effective stresses, and therefore, estimated low cycle fatigue (ELCF) life. Aerospace

Jan 1, 2006

By L. J. West, R. M. Perrry

This chapter describes the rock mechanics studies performed for a high cut at a nuclear power station in Pennsylvania. Two units presently are being constructed on the Susquehanna River. When these units are completed, they will generate approximately 2100 MW of electricity. It was necessary to excavate about 1 million cu yd of rock to prepare the site. This excavation resulted in a high cut on the west and north sides of the station area with a maximum height of about 200 ft. The location of the high cut with respect to the plant facilities is shown on Fig. 1. The recommended slope angles ranged from 1 ½ (horizontal) to 1 (vertical) for the upper residual soil to ½ to 1 for the deeper competent rock. Because of the significant height of this cut and the fact that the slope is immediately adjacent to the proposed nuclear facilities, extensive stability analyses were performed prior to, during, and after excavation to evaluate the steepest angle at which the slopes could be safely cut. The studies consisted of evaluating both qualitatively and quantitatively all apparent factors which could affect the stability of the slopes. These factors include the strength of the material, the zones of weak material which are present along the planes of schistosity, the prominent joint systems, the ground water, and postulated seismic effects. FIELD AND LABORATORY STUDIES A comprehensive program of field explorations was performed to evaluate the geologic characteristics of this site. This program consisted

Jan 1, 1970

By Chris A. Fleming

"Interest in the recovery of cyanide from gold and silver plant tailings has heightened in recent years. This interest has been spurred by several factors:Increasingly stringent regulations throughout the gold producing world, governing discharge limits for free and total cyanide to tailings ponds and the environment.The increasing cost of active chemical treatment versus passive (natural degradation) treatment of tailing, to bring them in line with environmental regulations.The worldwide trend to processing of more complex gold ore bodies, which is usually accompanied by higher levels of cyanide consumptions and greater concentrations of cyanide (particularly the copper cyanide complex) in tailings.The growing negative perception of the general public for the gold mining industry, due to several highly publicized cyanide spills in recent years (breaches of tailings dams, accidents involving trucks carrying cyanide to gold plants, etc.).The ability to recover cyanide from gold plant tailings has been known almost as long as the cyanidation process has been practiced, but there has been little incentive to process tailings in this way in the past. With the development of technologies that make it possible to recover and recycle free or complexed cyanide directly from gold plant slurry tailings, which indicates, on paper at least, the potential for significant cost savings compared to cyanide destruction, coupled with the introduction of legislation to seriously limit the discharge of cyanide to the environment in most gold-producing regions of the world, many companies are evaluating the cyanide-recovery alternative."

Jan 1, 2003

By Sumit Kumar Biswas, Moyukh De, Sibapriya Mukherjee

"The piles often are also subjected to lateral (horizontal) forces and moments. In fact, there are some structures where the primary function of piles is to transfer lateral loads to the ground. Proper analysis of laterally loaded piles is very important to the geotechnical and civil engineering profession.In the present investigation an experimental study has been carried out with free head short model cast iron hollow piles of outer diameter of 24 mm and L/d ratios of 8, 10, and 15. The experimental results have been supplemented by numerical techniques using PLAXIS-3D Foundation version 2.1 software. The results have been found to agree reasonably well with the experimental results. Further finite difference approach has been adoptedto reduce the computational time and to calculate the coefficient of modulus of subgrade reaction (?h) from the load- deflection data obtained from PLAXIS output at different pile depths. The parametric study has been extended for the non-dimensional form defined as flexibility ratio (F.R.),where ?h, L, Ep and Ip are the coefficient of modulus of sub-grade reaction, the embeddedlength of model pile, elastic modulus of pile material and the moment of inertia of model pile about the central axis respectively).The variation of coefficient of horizontal modulus of sub-grade reaction (?h) has been studied with respect to the following parameters for homogeneous soil system: relative density andL/d ratio. It has been found that the logarithm of flexibility ratio increases with increase inrelative density and increase inL/d Ratio. The values of ?h obtained by the proposed method have been, found to be close to the numerical results.As output of this research, graphs have been generated in respect of different parametric variations to gain an insight into behavior of piles under lateral load for short piles."

Jan 1, 2015

By D. J. Wynnemer, G. W. Preckshot

Precise electromotive force measurements have been made on the zinc-cadmium system over the temperature range 700° to 900°C. Activity coefficients, partial free energies, enthalpies, and entropies have been determined .for the entire composition range. The integral heat of mixing is positive and compares favorably with calorimetrically determined values. Vapor-liquid equilibrium compositions were determined .for a total pressure of 1 atm and these agree well with previous values determined in other ways. The use of electromotive force measurements to obtain thermodynamic data for liquid metal systems is a simple and well-known method. Several reviews of the various experimental methods and results have been published.2,3,11 However, most of the past work using this technique was carried out at temperatures slightly above the melting point of the alloy system where alloy composition changes due to vapor transport and increased metal solubility in the electrolyte are not important factors. One advantage of extending the electromotive force measurements up to and including the normal boiling point of the alloy is that it is then possible to evaluate the vapor-liquid equilibrium of the alloy at various pressure levels up to 1 atm. A detailed discussion of the thermodynamics of reversible electromotive force cells can be found in most advanced physical chemistry or chemical thermodynamic textbooks. The expression stating the inter-relation of the electromotive force and the thermodynamic functions is the Gibbs-Helmholtz equation.

Jan 1, 1962