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By T B. T Nguyen, L Matthews, D O’Dea, T Honeyands, T Harvey

Productivity and fuel consumption of the blast furnace is driven by the quality of the iron ore sinter, which in turn is related to the sinter mineralogy. The sintering conditions including temperature and gas composition have a significant influence on the formation of melt and finally the mineralogy of the sinter. In this work, analogue sinter tablets were produced from iron ore fines in a laboratory furnace with tightly controlled temperature profile and oxygen partial pressure in the gas. The mineralogy of the sinters was analysed using reflected light microscopy. The results showed that increasing thermal enclosed area (area enclosed by heating and cooling curve above a reference temperature) reduces primary hematite and platy silico-ferrite of calcium and aluminium (SFCA) contents. This is attributed to increasing melt formation, leading to greater assimilation of the iron ore particles. Lower magnetite was found for tablets with greater median pore size, which is thought to be due to greater oxidation of magnetite to hematite during cooling in air. It was also found that higher alumina content was found to result in more SFCA formation under the same heating/cooling conditions, whereas tablets with higher goethite had higher assimilation and produced more secondary hematite on cooling. Finally, it is necessary to relate the enclosed area to the temperature at which the melt formation becomes significant which strongly depends on chemical composition of the ore studied.

Nov 8, 2021

By Xuemei Zheng, Aiyuan Ma, Chao Liu, Guojiang Li, Chenyu Sun, Jinhui Peng, Libo Zhang, Yongguang Luo

In this paper, the removal of fluorides and chlorides from blast furnace dusts by water vapor enhanced microwave roasting was investigated, combined with the advantages of microwave selective heating and based on a thermodynamic analysis of zinc and lead halides. According to proposed reactions in the process, detailed experiments were systematically conducted to study the effect of roasting temperature, holding time, air flow, water vapor flow rates, and stirring speed on the efficiency of the removal of F and Cl. The results show that 97.26% of F and 64.23% of Cl could be separated when the condition of the roasting temperature of 650°C, stirring speed of 80 rpm, holding time at 60 min, air flow of 350 L/h and water vapor flow rate of 8 mL/min was optimized.

Jan 1, 2016

By S. Niyomwas, T. Chanadee

The influence of flux CaO2–Al ratio on the Self propagating high temperature synthesis (SHS)-casting reaction products in WO3–Si–Al system has been investigated in this study. Incorporation of CaO2–Al amounting to 1–5 wt% of total charge has been found to be adequate to form WSi2 intermetallic with a maximum hard-W5Si3 secondary phase. The micro-hardness of tungsten silicides intermetallic product increased significantly with CaO2–Al ratio. The as-SHS-casting products were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM) with energy dispersive x-ray (EDX) technique.

Mar 1, 2017

By T. Wang

A new kind of mixed chelate collector was prepared in order to separate gangue (mainly quartz) and iron minerals efficiently during room temperature. The collector was was composed of two chelate collectors DES and DA. Floatation tests were carried out under 28?C with mixed magnetic concentrates of Donganshan sintering plant, and optimal test conditions were obtained, in which a direct floatation was undertaken and then a close circuit reverse floatation tests ( one roughing, one cleaning, and two scavenging), and a result of Fe grade of siderite concentrate 36.49%, Fe recovery of siderite concentrate 10.65%, Fe grade of final concentrate 66.27%, Fe recovery of final concentrate 78.25%, and Fe grade of tailing 16.22% was gained. Fourier Transform Infrared (FTIR) Spectra and Zeta potential of siderite and quartz adsorbed the DES and DA collectors before and after were measured in order to analyze the reaction between the collector and minerals. Furthermore, Molecule electronegativity of DES and DA was calculated by Electronegativity Proportionality Principle (EPP). Results showed that DES molecules have five active adsorbing sites and their molecule electronegativity was stronger while DA molecules have three active adsorbing sites, which all make the mixed collector has efficiently collecting performance. Zeta potential results of Quartz and siderite showed that at pH 11.5 both kinds of particles charged negative and at this pH value the mixed collector were mainly anionic collectors which indicate that electrostatic adsorption does not exist at this situation. FTIR results showed that characteristic peaks of the mixed collector changed before and after adsorption with the minerals, which means that there exists chemical adsorption or hydrogen bonding.

Jan 1, 2014

By Masahiro Hirasawa

"As a fundamental study on pyrometallurgical process that involves recycling steel-making dusts, of which major components are oxides of Zn and Fe, and waste polyvinyl chloride simultaneously ·at. a temperature below 1273 K, the reactions between the mixture of ZnO + Fe20 3 and PVC or the compound ZnFez04 and PVC are investigated in a series of thermogravimetric and small scale reactor experiments under inert atmosphere at below 1273 K. The reaction mechanisms are discussed· on the .basis of the thermogravimetric data. From the results of reactor experiments, it is shown that the chlorination of Zn in the oxides by Cl in PVC, the vaporization of ZnC12, the reduction of iron oxide to metal Fe by C and H in PVC, and, thereby, the separation of Zn and Fe in the oxides take place simultaneously at the temperature ~= 1200 K.IntroductionSteelmaking dusts are metallurgical wastes consisting mainly of oxides of Zn and Fe with smaller amounts of other heavy metal elements, such as Pb. In the recent investigation, [1] the present authors have investigated the fundamental aspects of a potential pyrometallurgical process· of recycling steel-making dust with polyvinyl chloride (PVC) at temperature T < 1273 K under Ar atmosphere. The performance of a similar process, in which HCl in the combustion gas of PVC is used to chlorinate Zn in the EAF dust under oxidizing atmosphere, has been investigated by Tailoka and Fray [2] with fundamental experiments. Figure 1 shows an example of the potential ·diagram of Zrt-Cl-0 and Fe-Cl-0 systems. In the figure, we can find two regions where ZnCl2(g) can be separated from Fe containing compounds. One is ZnCiz-Fe20 3 coexistence region at higher oxygen and chlorine potentials and the other is ZnCl2-Fe coexistence region at lower oxygen and chlorine potentials. The process adopted by Fray and coworkers is aimed mainly at the performance of Zn/Fe separation in the higher oxygen potential region. In the present study, the lower oxygen potential region is focused on."

Jan 1, 2000

By Susumu Okabe

Top blow injection has been applied to continuous copper smelting and converting by Mitsubishi Materials Corporation since 1974. In this process, injected feeds are captured by and dispersed in the molten bath immediately and effectively, and the reaction is enhanced by the agitation of the bath. The continuous motion of the molten bath, however, may cause severe damage of furnace lining materials, if the injection is not controlled and the furnace is not designed properly. In order to suppress refractory wear, especially at the bath line, surface wave of the molten bath should be moderated. A cold model study was carried out with water bath in a cylindrical vessel and the physical model was derived which correlates the oscillation of gas jet impingement on the bath surface and the surface wave. It was found that a half of the proper frequency of the gas jet impingement coincides the proper frequency of the surface wave.

Jan 1, 1998

By Sami Kara, Marsel Nabium

This paper provides an overview of the solution applied in underground Silver mine in Russia. The paper reviews the dilution problem throughout the entire mining process, and provides a rational approach to underground mine Blast design in order to minimize dilution

Feb 1, 2020

In Mr. Weed&apos;s interesting paper, frequent reference is made to the Cananea copper-deposits, which are said to have been so vigorously exploited that they produced 14,000,000 Ib. of copper in 1901. The ore-bodies which yielded this large quantity of metal are described as a product of contact-metamorphism, and in Mr. Weed&apos;s genetic classification of such deposits, they receive a place under the sub-heading, "Deposits impregnating and replacing beds of contact-zone."* They are considered by Mr. Weed to represent a special type under this head, and are further classified as: " l. Chalcopyrite deposits: (a) Pyrrhotite ores; (6) Magnetite ores, Cananea type." In condensing much information into a comparatively small space, the presentation of a subject may be so abbreviated as to detract from its clearness. The situation at La Cananea, considering its importance from an economic as well as scientific standpoint, may he worthy of more detailed description. As Mr. Weed rightly remarks, " structural differences are so important, and have SO marked a bearing, not alone on the theory of their genesis, hut also on the working of the deposits and a determination of their value as mines, that they merit a full discussion."† It is my present purpose: (1) to show that it is doubtful whether the copper of La Cananea is mined, except to a limited

Jan 1, 1903

By Mingming Zhang, Marcelo W. Andrade

The evolution of microstructure and mineral phases in iron ore sinters have been investigated by scanning electron microscope and QEMSCAN (Quantitative Evaluation of Minerals by Scanning Electron Microscopy). It was found that MgO, basicity and Al2O3 content play an important role in the formation of mineral phases and microstructure in sinter. The low Al2O3 (<2.0 wt%), medium MgO (2.0–2.5 wt%) and high basicity (>3.0) sinter showed higher low temperature degradation index (LTD) due to the presence of silico ferrites of calcium and aluminium (SFCA), and magnetite phase, and lower pore phase as compared to low basicity iron ore sinter.

Mar 1, 2017

By C E. Woolley, A Hosseini, J Foster

Northern Star’s Thunderbox Open Pit C-Zone cutback was designed to maximise extraction in a short life excavation; In fresh rock on the western wall this included 20 m to 30 m bench heights with 6.5 m to 10 m berm widths and a 90° pre-split angle. Rock mass quality in this area is generally fair to good, however, there are sections where the dominant foliation runs parallel with the designed pit wall, and more closely spaced, altered, foliation is present: these areas are difficult to predict and prone to failure. Stringent controls and monitoring were required in order to safely access below these areas, in particular the use of slope stability monitoring radar, Trigger Action Response Plans (TARPs), re-entry procedures, visual inspections, drone inspections and day-to-day personnel awareness of the hazard. Robust and comprehensively planned remediation was also required after two significant slope failure events where long reach equipment and rope access techniques were utilised to remediate the areas in question safely, but also in a timely manner, such that expected production targets were impacted as little as reasonably practicable. This combination of rigorous risk management and well planned remediation resulted in a successful and complete extraction of the C-Zone cutback with no impact to operational safety.

Jun 22, 2022

By E. J. Owen, A. Appah, I. C. Sanchez, K. T. Stafford, N. Hurtig, R. Otoo, N. A. Iverson, S. A. Moses, V. T. McLemore

New Mexico lies at the eastern edge of one of the world’s great metal-bearing provinces hosting numerous Laramide and Paleogene mineral deposits. Southwestern New Mexico contains Laramide porphyry Cu (±Mo, Au) and Paleogene Mo-W deposits. Porphyry deposits are generally large, low-grade deposits containing Cu, Fe, Mo, Au sulfides (and other metal sulfides) associated with porphyritic intrusions and exhibit characteristic alteration styles. Porphyry deposits can also be spatially and temporally associated with skarn deposits and polymetallic veins. All of these deposits have the potential to host various critical minerals, including Cu, Zn, Bi, Co, Ni, rare earth elements (REE), Te, and W. Critical minerals may be found as substitutions within ore minerals or as separate mineral phases. These deposits are constrained using 40Ar/39Ar dating into three ore-producing magmatic pulses: 1) ~78–71 Ma Laramide pulse, 2) ~59–50 Ma, Laramide pulse, and 3) ~40–30 Ma Paleogene pulse. New and historic whole-rock geochemical data have highlighted areas with critical minerals potential that require further study.

Feb 1, 2025

By A. C. Munro

This paper, which describes the milling practice at the Britannia concentrator, Britannia Beach, B. C., is one of a series being prepared by the Bureau of Mines. The concentrator treats copper ore at the present rate of 6,000 to 7,000 tons of dry ore daily and produces copper concentrate and pyrite concentrate by selective flotation methods. The copper concentrate is smelted and the pyrite product is utilized for acid manufacture.

Jan 1, 1932

By Rogerio C. Guimarães, Antonio E. C. Peres

The production of phosphate concentrates (phosphate rock) from slimes represents a challenge to the phosphate industry worldwide. In Brazil, this challenge is particularly relevant due to the consistently low P2O5 grades and the igneous origin. The Brazilian phosphate deposits are made up mainly of apatite from alkaline chimneys, representing 80% of the Brazilian reserves; phosphorite deposits contribute 18% and the other sources (guano, phosphorous bauxite, and apatite from veins) reach 2%. The Brazilian industry beneficiates phosphate ores that are mineralogically more complex than those treated elsewhere. The low apatite grade, inherent to the igneous Brazilian ores, added to the mineralogical complexity due to the weathering of the rocks, has represented a permanent challenge to the Brazilian process engineers. The total measured, indicated and inferred reserves reach 3.2 million tonnes of ore with average grade 11% P2O5. The development of local technology for phosphate beneficiation started in the 1960’s. The first industrial experiences of producing phosphate rock from slimes (-44µm or -325#) fraction started at Arafertil, currently Bunge Fertilizantes SA, in Araxá, in the 1980’s. This production corresponds, nowadays, to 35% of the total production of concentrates in the company (830,000t/year) in a circuit consisting of desliming in 40mm microcyclones and concentration in flotation columns, corn starch and fatty acids being utilised as reagents. The performance of slimes flotation and the process control, at Bunge´s concentrator, were improved after the introduction of column flotation technology, in the first half of the nineties. The column flotation technology for slimes recovery was expanded to other Brazilian concentrators still in the nineties: Ultrafértil (Catalão – GO), Bunge (Cajati – SP), Fosfértil (Tapira – MG) and Copebrás (Catalão – GO). At present the Brazilian production of phosphate rock is approximately 4.5Mt/year, with a strong trend for a market increase. Genuinely Brazilian technology is utilised for the processing of slimes, the concentrates representing 11 to 13% of the overall production. The production of apatite concentrates from slimes was relevant to increase phosphate recovery and reduce costs, contributing to the growth of the fertilisers industry.

Jan 1, 2003

By F. Karakas

Organo-bentonite production enjoys important applications including solvent based paints and, more importantly, the production of polymer/bentonite nanocomposites. Quarternary ammonium salts in this regard are still considered as the most versatile reagents in the process of hydrophobization. In this study, a purified form of Resadiye region bentonites, which is one of the most significant sodium bentonite deposits in the world, was used. The raw Na-Bentonite was typically characterized by chemical analysis, XRD and DTA analysis and more importantly for its cation exchange capacity (CEC). Other technological properties such as swelling index, pH, apparent viscosity, water absorption, oil absorption were also conducted on the raw bentonite. The mineralogical analysis of the raw bentonite reveals that it contains about 80 % montmorillonite together with other associated gangue minerals including feldspar, quartz, calcite, dolomite, coloured impurities and other clay minerals. The raw bentonite was subjected to two stage processing involving a series of hydrocylones. Different apex and vortex diameters and different pressures were employed in order to produce a bentonite concentrate with 95 meq/100g CEC from a CEC of 71 meq/100 g. This high quality concentrate was used in the production of organo-bentontonite. The modification was performed with two different quaternary amines, i.e. Trimethyl Phenyl Ammonium Chloride (TPAC) and Hexadecyl Trimethyl Ammonium Bromide (HDTMA-Br). In the modification procedure, three parameters, i.e., adsorption density, zeta potential, swelling index and apparent viscosity were studied simultaneous-ly from the same suspension to identify both the mechanism of the process and also the degree of hydrophobicity. Adsorption measurements were made as a function of conditioning period, pH, and reagent concentration. Simultaneous examination of the adsorption density, zeta potential and apparent viscosity enabled us to pinpoint the optimum region of hydrophobicity which was subsequently tested by settling and critical coagulation concentration in both water as polar and toluene as nonpolar solvents. The results are analyzed in the light of experimental data.

Jan 1, 2014

In-pit crushing and conveying (IPCC) is being increasingly considered as an alternative to traditional truck-shovel mining methods. The move towards IPCC is driven by a number of factors including the potential to reduce greenhouse gas emissions, the availability of skilled labour and the need to increase extraction rates to levels that present significant challenges to traditional methods.When considering the relative performance of IPCC and truck-shovel methods, the outcome can be inadvertently impacted by either the use of different simulation approaches, or techniques that do not adequately model the processes in sufficient detail.A simulation approach is proposed that models both IPCC and truck-shovel using the same software platform and is capable of functioning at a wide range of resolutions from life-of-mine scale through to second-by-second asset tracking level. The simulation framework also holds models of processing equipment and hence the mining simulations can be extended to gauge the impact on downstream plant.The approach, known as mine-process operational simulation (MPOS), can be tailored to the level of information available and hence the type of study required, ie order of magnitude, prefeasibility, feasibility, or detailed design.Using information from block models and a range of detailed equipment and process models, MPOS can span major system discontinuities, typified by the mine-plant interface, to allow the estimation of final mine and plant product specifications.

Dec 6, 2010

By Richard L. Rains

In 1992, the Bureau of Mines evaluated mineral resources of the 34,043-hectare Caribou City and 41,943-hectare Stump Creek study areas in southeastern Idaho. No resources were delineated. The areas had been proposed for wilderness. Rocks underlying the study area are part of the Idaho-Wyoming Thrust Belt. At Caribou Mountain they have been intruded by diorite-monzodiorite. Where the intrusive rocks contact calcareous members of the thrust belt, skarn bodies have formed that host metal deposits. Gold, both placer and lode, occurs in the Caribou City area, and salt occurs in the Stump Creek area. Production records show 73.5 kg (2,363 ounces) of placer gold were produced; however, field studies indicate more than 2,000 kg (67,000 ounces) probably were recovered. Minor amounts of lode gold, silver, and copper were recovered from the hard rock mines. Production of salt from the Stump Creek study area in the 1860&apos;s was used by emigrants on the Oregon trail and also shipped to various mining districts for use in silver recovery. Oil and gas were drilled for, but all holes are plugged and abandoned. There are no current leases. Examined workings consisted of 25 adits, 3 shafts, 50 prospect pits, and extensive placer workings all in the northern tip of the Caribou City area, Current BLM records show 168 placer and 146 lode claims; 14 claims are patented.

Jan 1, 1993

By A. J. Thompson

The Metropolitan Transportation Authority (MTA) East Side Access project (ESA) will, when it is complete, provide a new link to the east side of Manhattan from Long Island, NY that, linked with the Second Ave. Subway currently under construction, will assist in relieving overcrowding at Penn Station as well as the Lexington Ave. subway. ESA will bring Long Island Railroad (LIRR) directly from Long Island into a new station located 37 m (120 ft) beneath the existing Grand Central Terminal (GCT) located in the heart of Manhattan. It will connect the LIRR?s mainline tracks in Queens, via the existing 63rd Street Tunnel under the East River, to a new terminal constructed within, and beneath, the historic Grand Central Terminal.

Jan 1, 2012

By Martim Hideki Nakayama Kurauchi

One of the main issues regarding the use of charcoal in metallurgical processes is its mechanical strength, which is much lower than coke. There is no defined standard to determine charcoal compression strength, and the methods described in the literature consist in using a prepared specimen and applying compressing load in the same direction of the charcoal fibres. As charcoal is highly anisotropic, it is proposed a procedure that does not use a specimen and with load applied on a specific direction. Instead, it intends to simulate industrial conditions by randomly dumping charcoal inside a tube, without preferential directional arrangement. This is an attempt to determine charcoal mechanical strength and predict the behaviour of bulk charcoal under a static load, as in a blast furnace. Experiments with controlled loads have been carried out on randomly distributed bulk charcoal with controlled initial size and their effect on the size distribution has been analysed. After compression, charcoal is screened and each size is weighed, determining the particle size distribution of the experiment. This method can therefore be used to evaluate charcoal mechanical strength.

Aug 1, 2018

By Hylton McWhinney, Doanh Tran, Jewel Andrew Gomes, George Irwin, Sameer Pallavkar, Md Islam, David Cocke, Mohammad Rafiqul Islam

"High-performance nickel-based nanocrystalline zinc oxide adsorbents have been prepared adjusting Ni/Zn mol ratio of 1 :5 by thermal decomposition, coprecipitation and sol-gel method for selective adsorption of thiophene in liquid hydrocarbon fuels at ambient temperature and pressure. To understand the nature of reactive adsorption of thiophene (C4H4S) on Ni/ZnO, the effect of preparation techniques, morphological and textural structure on the desulfurization activity was investigated. A model fuel (20 mL) consisting of pentane (C5H12) and thiophene was prepared and adsorption experiments were performed by a batch method under ambient conditions. The physicochemical behaviors of the fresh adsorbents were obtained using X-ray diffraction (XRD) with EDAX, scanning electron microscopy (SEM). The sulfur concentration in the mixture was monitored by UV-vis spectrophotometry. The adsorption reaction confirmed that ZnO played a crucial role in taking up S element to convert it into ZnS. The deposition of nickel on ZnO is an innovative approach which takes advantage of the selectivity of Ni towards S-species and the high adsorptive capacity of ZnO support.IntroductionLow temperature deep desulfurization of fuels via selective adsorption of sulfur compounds keeping coexisting aromatic hydrocarbons and olefins intact is receiving increasing attention in the research community worldwide in order to satisfy the upcoming environmental regulations and fuel specifications. The sulfur compounds in the transportation fuels is a matter of concern when global crude oil slate is becoming heavier and sourer and environmental restrictions on both the refining process and the refined products are becoming more stringent. According to the current refinery technologies, the sulfur content in refinery fuel is typically around 300-500 ppm by weight (ppmw) [1-3]. Starting in 2006, sulfur limits in highway diesel and gasoline were set to 15 ppm and 30 ppm, respectively. During combustion sulfur in the fuel are converted to toxic sulfur oxide (SOx) and contributes to air pollution and acid rains [ 4]."

Jan 1, 2011

By R Schiller, E Chait

"Quebrada Blanca is a porphyry copper deposit located in the Eocene-Oligocene belt of Chilean Andes. Operation started in 1994 and original reserves for supergene mineralisation gave a life-of-mine (LOM) of 20 years; however, further exploration extended the LOM until 2020.In order to optimise the remaining five years of supergene resource, geometallurgical variables were added to the geological model including copper recovery and acid consumption. LOM plan encompasses finishing the phase number eight and the future development of phases 11 and 13.LOM lithologies include diorites, quartz monzonites, porphyries, igneous and tourmaline breccias. Main alterations are: potassic, phyllic and argillic. Litho-alterations or geometallurgical units were formed by combining five types of rocks with three types of alteration. According to statistical information, the deposit can be represented with 12 litho-alteration units, which cover 98 per cent of the LOM volume.For copper recovery information, there were 40 mini-columns tests made in order to obtain kinetics curves and copper recovery values after comparing the difference between head and tails grades. Acid consumption was obtained using an automatic neutraliser device-based test.Historical data said that copper recovery in pads after 450 days of irrigation is around 75 per cent of recoverable copper while acid consumption is around 5.5 kg/t.According to this study, lower recoveries are related with potassic-altered diorites and argillic-altered quartz monzonites with values around 60 per cent. On the other hand, best recoveries could be found in potassic-altered quartz monzonites and argillic-altered diorites with values closer to 80 per cent.It was also revealed that the most reactive rock is the potassic-altered diorite with 12 kg/t of acid consumption. This rock covers approximately 40 per cent from phases 11 and 13.The final geomet model was calculated using a program that relates each geometallurgical unit with a specific copper recovery and acid consumption value. Results found after comparing model-obtained information with historical leached pads data were used to validate the model.CITATION:Chait, E and Schiller, R, 2016. Adding Copper Recovery and Acid Consumption Variables to the Geological Model of Quebrada Blanca, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 257–266 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016