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By B. P. von der Heyden, P. Neethling, M. Tadieb, L. Babedi

The effects of trace element substitutions in sphalerite mineral structure on optimised floatation response have, as yet, not been fully constrained or fully understood. To further this important field of study, this contribution focusses specifically on mineral and surface chemistry, and electro-chemistry of Cd- and Co- substituted synthetic sphalerites using Raman spectroscopy and Zeta potential experimentation. Raman spectroscopy illustrates that the presence of these impurities results in the introduction of a new mode, the relative intensity of which can be correlated (Cd r2=0.95 and Co r2= 0.99) to the dopant concentration. Comparison to X-ray Diffraction results measuring the unit cell parameter further shows that this relative intensity (Cd r2=0.81 and Co r2= 0.99) may provide insights into the degree of lattice strain within the mineral structure. The zeta potential distribution of an un-activated Cd-sphalerite show no detrimental effect as function of Cd content. Although the iso-electric point shifted from 2.45 at 1 wt.% Cd to 2.69 at 3.68 wt.% Cd, the zeta potential remained negative at alkaline media. Conversely, cobalt at low concentration of 0.36 wt.% had a detrimental effect on the surface charge, resulting to a close to neutral zeta potential at different pH. The adsorption of Cu ions on the surface of Co-bearing sphalerite conditioned in an alkaline media slightly increases the zeta potential of Co-sphalerite. While the Cd-bearing sphalerite decrease in negative zeta potential at >1 wt.% Cd indicating a complete exchange between Cu and Zn. The results presented herein illustrate that, based on the chemical nature of the substituting metal; sphalerite will exhibit multiple response to flotation reagents. Maximum recovery of zinc can thus only be achieved through multidisciplinary study and fundamental understanding of the effects of cation substitution on mineral structure and surface chemistry, the latter necessarily affecting the floatation response.

Jan 1, 2018

By W. W. Adams, T. D. Lawrence

"Despite the manpower shortage and other difficulties of operation in war time, the National Safety Competition of 1943 for the promotion of safety in the mineral industries of the United States was notable for having a larger enrollment of mines and quarries than in any other year except 1941 and 1942 since the yearly safety contests were inaugurated in 1925. The competition was also notable for having a larger number of man-hours represented by the competing companies than in any previous contest except that of 1942. The ratio of accidents and days of disability resulting from accidents to the number of man-hours of work performed was more favorable than in 1942; the accident-frequency rate was lower and therefore better than in 13 of the 19 years during which the annual safety competitions have been conducted, and the accident-severity rate was better than in 16 of the 19 years.The National Safety Competition is a yearly safety contest conducted by the Bureau of Mines, United States Department of the Interior. Companies that win first place in their respective group in the contest are awarded a bronze trophy, ""The Sentinels of Safety,"" which is provided by THE EXPLOSIVES ENGINEER magazine. Competing companies are segregated into six groups: Underground bituminous-coal mines, underground anthracite mines (in Pennsylvania), underground metal mines, underground nonmetallic-mineral mines, open-cut mines (without regard to kind of mineral produced), and open quarries (without regard to kind of stone produced). The bronze trophies are retained by the six winning companies for 1 year and are then transferred to the winners of the succeeding year's contest. On the pedestal of each trophy is engraved the names of the winners of the trophy. With the award of the trophies for 1943, therefore, the pedestal of each trophy bears the names of 19 winners."

Aug 1, 1944

By A. D. Pittuck

Refractory minerals .containing uranium and columbium have been successfully treated at Queen's University, Kingston, to produce high-grade concentrates. Recoveries of over 90 per cent of the uranium and columbium have been obtained when treating concentrates containing euxenite, fergusonite, betafite, and pyrochlore. The processes ?consisted -of leaching the columbium with hydrofluoric acid, and the uranium with nitric acid, sulphuric acid, or sodium carbonate solutions. The leach liquors were extracted with organic solvents from which the values were stripped and precipitated, producing final products assaying 45 to 55 per cent Ob2O5 and 60 to 70 per cent U3Os.

Jan 1, 1958

By Zhi-biao Yin

Copper smelter flue dusts often cannot be directly recycled to the smelting process and accumulate as hazardous wastes requiring environmentally acceptable disposal. Because of the limited amount of flue dust, a separate copper extraction process must be simple and require-a small plant investment. A flue dust process has been developed, consisting of the following steps: (1) roasting a pelletized mixture of hydrated lime and flue dust to fix arsenic and sulfur as insoluble calcium salts, (2) heap leaching the roasted pellets with a buffered ammonia/ammonium salt solution to extract copper as an ammine complex in a lined cell that is the final repository of the leached pellets, and (3) boiling ammonia from the lixiviant to precipitate copper. Condensed ammonia and the filtered solution are returned to leaching. Heap leaching in the final repository cell lowers the capital investment significantly compared with competing extraction processes. Chemistry with respect to arsenic, sulfur and copper is discussed.

Jan 1, 1992

By Vernon C. Davis

"SUMMARY AND CONCLUSIONSIn initial attempts to mine taconite by conventional open-pit methods, the material tended to break into tabular blocks that were too large to be handled by conventional shovel dippers and were unsatisfactory in an ordinary crusher feed. A great amount of secondary blasting was necessary, which added considerably to the cost of mining.The Bureau of Mines and others are engaged in studies designed to contribute to the solution of taconite-mining problems. These studies concern problems related to drilling techniques and patterns, types and methods of use of explosives, and other factors relative to effecting maximum fragmentation at minimum cost.This report is concerned with study of the application of shaped charges in drill holes, the effectiveness of shaped charges as compared to capped charges in secondary blasting, and the merits of different drilling patterns and methods of detonation of conventional-explosive charges.Fragmentation of taconite at or near the surface is controlled or strongly influenced by joint and bedding planes. Since all tests in this study were made in a jointed and bedded area, a definite conclusion as to the relative effect of a shaped charge in a drill hole, as compared to a conventional charge at greater depths and tighter ground, is precluded. However, application of shaped charges in primary blasting of taconite appears to be of no advantage.In secondary blasting of taconite, conventional, capped charges produced better breakage than shaped charges of the designs tested.Based on the results of conventional blasting practice in horizontal-, inclined-, and vertical-hole tests, no better fragmentation is obtained from blasting either horizontal or inclined holes, compared to vertical holes.Holes drilled in staggered parallel rows that intersect both series of joint planes at the greatest possible angle, give maximum breakage compared to rows parallel to one of the series of joint planes.Methods of detonation made little difference in breakage; but the millidelay caps produced the best conditions for moving the broken rocks."

Jun 1, 1953

By Erika Moonin, Jim Nickerson, Claudio Cimiotti, Roberto Bono

"In response to the severe drought on the Colorado River basin and in order to preserve existing water capacity to the Las Vegas Valley, the Southern Nevada Water Authority contracted a new deep-water intake (Intake No. 3) located in Lake Mead. The current project (Contract No. 070F-01-C1) includes 5 km (3 miles) of tunnel with very difficult geological conditions and a 200- m (650-ft) deep shaft and marine works. This paper will present the current status of the design-build contract being constructed by Vegas Tunnel Constructors and the challenges and problems faced and the innovative solutions developed to handle the difficult conditions encountered during tunneling with up to 15 bars of pressure.ProjectbackgroundThe Las Vegas Valley receives the majority of its water from Lake Mead, which is located approximately 30 km (20 miles) east of the Las Vegas, NV metropolitan area. Due to the severe drought that has hit the southwest region of the United States, the water level in Lake Mead has receded from its high water level of 372 m (1,221 ft) above mean sea level (amsl) to a low of 330 m (1,076 ft) amsl in June 2015. Should the lake level continue to fall, at elevation 320 m (1,050 ft) amsl, the current water intakes will not be able to draw enough water to meet the needs of the local area. The risk of losing water capacity has prompted the construction of a new deeper intake. Not only is the new Intake No. 3 situated at a lower elevation in the lake at 262 m (860 ft) amsl, the new Intake No. 3 is also located to draw better quality (Fig. 1).Project challengesThe project has had several difficult challenges to overcome:• The work consisted of a 1.2 kt (1,300 st) structure constructed on a barge and lowered 100 m (330 ft) into Lake Mead anchored with 9,200 m3 (12,200 cu yd) of tremie concrete.• The drill-and-blast starter tunnel was impacted by three inflow events, resulting in a one-year project delay.• One of the main challenges was selecting the tunnel boring machine (TBM) and excavating the tunnel with expected hydraulic head pressure of as much as 17 bar (16 bar was the highest pressure recorded during the drive), crossing faulted areas, low rock cover and the risk of tunnel instability due to direct connection with the lake.• Extensive pre-excavation grouting with a constant head pressure ranging from 12 bar to 15 bar.• Structural repair of the cutterhead in difficult hydrogeological conditions [water inflow of approx. 800 m3/hr (4,000 gpm)].• Complete repair of the cascade sealing system for the main bearing and two replacements of the pinion bearings.• The TBM approach to the intake structure."

Jan 1, 2015

By Je M. Oh

The Bureau of Mines is conducting research to determine the high temperature oxidation resistance of substitute stainless steels (SS) containing two less strategic elements, Al and Si, instead of Cr. Chromium is considered to be a critical and strategic metal. Although the Cr content was reduced to 8 wt pct, the alloys showed better oxidation resistance than did 304 SS containing 18 wt pct Cr. Specifically, the alloys that contained Fe-8Cr-16Ni with combinations of Al and Si showed excellent oxidation resistance even at temperatures up to 1,000° C. In this study, the effects of the alloying elements on oxidation kinetics and morphology of oxides were investigated using a Cahn Rg electrobalance, scanning electron microscopy, an energy-dispersive X-ray analyzer, X-ray diffraction, and an electron microprobe. Aluminum and silicon additions in combinatin were more effective in providing oxidation resistance than either element was alone.

Jan 1, 1986

By Russell L. Wood

The title of this session seems to have been picked especially for this paper. It is 1984, it is the morning after, and there is one monumental hangover among many if not most of the oil companies that have invested in mining in the past decade or so. How an oil company looks at mining depends on what time period you are talking about. A few years back around the time of investment this is what they were probably looking at: 1. A balance sheet of their own that was beginning to go wild, with many of their commodity prices having already seen increases of two, three, or four fold, and with no end in sight. 2. A need to invest their earnings someplace fast before the stockholders or the government got too interested. And that someplace should be in an industry where their own management skills could be applied. (Only a true cynic would suggest that this is a form of job security) 3. In mining there was an industry amazingly similiar to their own, one working with non-renewable natural resources, dealing with the same types of government agencies, and having the same type of critics and pressures from the general population. 4. An industry that was somewhat backward as compared with their own, and one where a generous ration of the capital and management skills so handsomely bestowed upon the oil industry could be used to great advantage.

Jan 1, 1984

By M. E. Tyrrell

Despits its high melting point (2,135° C.), resistance to attack by molten metals, and its hardness (8), spinel (MgO?Al203) synthesized by the fusion of alumina (Al 2 0.) and magnesia (MgO) is not used on a large scale as a commercial furnace lining, mainly because of the prohibitive cost. This investigation by the Federal Bureau of Mines was prompted by the possibility of producing synthetic spinel from inexpensive raw materials by methods outlined in U.S. Patent 2,029,773, "Process for Obtaining Products Containing Spinets," dated February 4, 1936. In this patent Ture B. Haglund described a process for recovering crystalline spinels from melts in the system Mg0?Al203-2CaO-SiO2, a system well suited to the use of starting materials such as dolomite CaMg(C03)2, olivine [2(Mg?Fe)0.Si02], and bauxite (Al203?2H20) which are abundant in the southeastern United States. Compositions, ranging from a low content in the eutectic mixture of 35 percent spinal and 65 percent dicalcium silicate (2 CaO?SiO2) to a high of 75 percent spinel and 25 percent dicalcium silicate, were fused in electric furnaces of the arc-resistance and internal-resistance types. So long as members of the system were in proper chemical balance, "dusting" slags could be produced over the entire range of spinel concentration.

Jan 1, 1961

By Millard M. Gilkey

This Bureau of Mines report presents results of a detailed study of water usage in the Wyoming mineral industry along with projections for the future In 1964, the mineral industries of Wyoming used 20 billion gallons of new water, nearly all self-supplied, and reused 72 billion gallons, a total usage of 92 billion gallons. Consumption amounted to 2.8 billion gallons. About one-half of the 20 billion gallons of new water was obtained from [srface] sources and the rest from ground water. Reported costs, covering power and maintenance, for the self-supplied new water at mineral industry operations ranged from less than 1 cent to 20 cents per thousand gallons and aver-aged 8 cents. At one mineral-related operation, water was hauled by truck to supplement a well supply. The cost was $2.00 per thousand gallons delivered. However, the supplemental requirement was only 10 gpm. Cost figures for the recirculation of water, covering power and maintenance, averaged 2 cents. In terms of water usage, the value of product for the entire industry was $25 per thousand gallons of new water intake and about $180 per thousand gallons consumed. The study revealed that Wyoming has a water deficiency but that the shortage is less severe than in the arid Southwest. Projection of the water needs of the Wyoming mineral industries indicates that the demand for new water will increase from the 20 billion gallons used in 1964 to 25 billion gallons in 1980, a 25-percent increase. The projected new-water requirement for the year 2000 is 40 billion gallons, a 100-percent increase compared with the 1964 figure.

Jan 1, 1967

By Harry K. James

Experimental studies of the physical and explosion characteristics of pure hydrazine nitrate and multicomponent systems containing hydrazine nitrate, supplemented with an extensive Literature survey, are presented. Such proper- ties as melting point, heat of fusion, density, viscosity, surface tension, thermal stability, decomposition process, detonation velocity, impact sensitivity, and TNT equivalence are included.

Jan 1, 1970

By Reginals W. Burroughs

Diatomaceous or infusorial earth, also called diatomite; fossil meal, or kieselguhr, is derived from the lowest form of vegetable life, the unicellular alga:. It consists of the siliceous remains of extremely minute aquatic plants, which exist in both salt and fresh water. Light i~ a prerequisite to their development. These very small particles secrete silica in much the same way that molluscs secrete lime to form their shells. The diatoms at death sink to the bottom of the body of water in which they lived, and the organic matter gradually decays and is washed away, leaving the skeletons. Thousands of years are required by this means to develop bed5 of sufficient thickness to be of commercial value. The siliceous remains vary in size according to the species, but all are very minute and, as a general rule, they can be identified only under a high-power microscope. Over one thousand types have been distinguished and named. They are all composed of a hydrous or opalescent form of silica, with silica content ranging from seventy to ninety-five per cent. Magnified, they present an attractive sight, a very fragile structure with many interstitial openings known as cells. Many of them consist of two parts, defined as valves, held together by means of a girdle. Certain species, belonging to the Pinnularia family appear as a long comb, in half longitudinal section. The spaces between the teeth are the cells. This particular genus is very common in Nova Scotian deposits.

Jan 1, 1928

By C. Riveros, H. Henein

Bulk Metallic Glasses have a high potential as advanced engineering materials due to their various properties including strength and corrosion resistance, to name a few. This paper investigates amorphous phase formation and rapid solidification characteristics of impulse atomized Co-based alloys in order to understand and control the application properties of the final products. Amorphous fraction and kinetic crystallization properties of the atomized Co-based alloy powders were quantified by means of Differential Scanning Calorimetry. In addition, different but complementary characterization tools were used to analyze microstructures of the powders. These include optical microscopy, X-ray diffraction and micro-hardness tests. While the amorphous fraction within the powders is promoted by high cooling rate and smaller powder size as expected, hardness is found to decrease with the fraction of amorphous phase.

Jan 1, 2015

By Zetti Gavelan, Eric Ruiz, Emilio Delgado, Ely Loayza, Jesús Cruces

Debido a la variabilidad de la competitividad del yacimiento que está formado por skarn y pórfidos, para mejorar el concepto de conminución en Las Bambas el proceso de reducción de tamaño se inició en el manejo de los factores de carga, diseño de mallas de perforación y diseño de voladura del macizo rocoso. La maximización del sistema de molienda SAG se consiguió de manera sostenible con la integración del equipo de voladura en las optimizaciones realizadas en la planta. De este modo, se logró incrementar el procesamiento a 150 Kton/día.

Mar 30, 2020

By Charles R. Graig

El Laboratorio de Espectrografía del Departamento de Investigaciones de la Cerro de Pasco Corporation, elaboró un método de control de los circuitos de flotación por espectrografía de rayos - X. El método se basa en el uso de técnicas especiales de preparación de la muestra, los productos del circuito de flotación, y la fusión con pirosulfato de potasio. En este sentido, el objeto del texto radica en describir el procedimiento de la determinación cuantitativa por espectrografía de rayos-X, de las concentraciones de plomo, zinc, cobre y fierro en las cabezas, los concentrados y las colas de los circuitos de flotación. Es importante considerar el diseño del laboratorio de rayos X para la elaboración de los resultados de planta dentro del tiempo especificado. Así, el control de los procesos de flotación permite la rápida obtención de resultados exactos, lo cual hará posible una mejor regulación de los reactivos de flotación añadidos a los circuitos, mejorando el proceso.

Nov 20, 1967

By Thiago Félix dos Santos

A maioria dos materiais poliméricos sintéticos apresentam superfícies quimicamente inertes, isentas de porosidade e baixa energia de superfície. Este trabalho tem como objetivo realizar a modificação superficial do substrato têxtil de forma a aumentar a sua molhabilidade. Os tecidos de poliéster são hidrofóbicos e, por isso são desconfortáveis aos usuários, pois a fibra não absorve o suor do corpo, outro fator que é prejudicado pela hidrofobicidade da fibra de poliéster é o tingimento das mesmas. Portanto, tratamentos superficiais vêm sendo utilizados para minimizar esse problema e o plasma é uma técnica que se mostra bastante eficaz. O plasma ao interagir com a superfície do substrato provoca alterações químicas e físicas melhorando suas propriedades. Portanto, através do plasma é possível alterar as propriedades físico-químicas das superfícies de tecidos de poliéster, tendo como resultado o aumento da hidrofilidade dos mesmos com o incremento de grupos funcionais polares e o aumento da rugosidade em sua superfície. As amostras foram tratadas em um reator de plasma de barreira dielétrica a pressão atmosférica, em diferentes tempos de tratamento e voltagem. Após as funcionalizações as amostras foram submetidas ao teste de capilaridade, a fim de observar a melhora na hidrofilidade. Todas as amostras tratadas tiveram aumento na molhabilidade, com exceção, as amostras tratadas com 10 kV, onde não houve alteração.

Aug 7, 2018

By José Raphael Olegário França

Separação eletrostática é o termo usado para todas as tecnologias de processamento que utilizam forças elétricas que atuam sobre partículas carregadas ou polarizadas sob um campo elétrico estático. O comportamento das partículas depende das suas propriedades elétricas, geométricos e tamanho das partículas. Portanto, a separação de espécies é possível se os parâmetros do campo elétrico e as propriedades elétricas diferentes das partículas são apropriados para o processo. No separador eletrostático de rotor as forças elétricas, combinadas com as forças gravitacionais e centrífugas agem sobre as partículas e são responsáveis pela separação mineral. No presente trabalho as forças eletrostáticas que agem no processo serão substituídas por um modelo de contato de coesão Hertz-Mindlin com JKR. O resultado apresentado, embora com limitações, conseguiu-se fazer uma boa estimativa do processo e alguns dos parâmetros do separador. Com a presente simulação é possível descrever o processo de separação além de permitir a redução de despesas de testes práticos, melhorar a compreensão das relações fundamentais, simular as influências dos diferentes parâmetros e por fim, estimar eventuais aumento de desempenho.

Aug 17, 2017

By Élida Gonçalves das Neves

Nos últimos anos as siderúrgicas têm investido na melhoria de seus processos e produtos buscando à produção de clean steels, onde menor nível inclusionário é almejado. Neste contexto foi objetivado neste trabalho, em um primeiro momento, realizar uma revisão bibliográfica afim de buscar um modelo que pudesse relacionar a composição química da escória com a capacidade da escória de remover de forma eficiente as inclusões, garantindo assim a limpidez de aços. A partir destes dados, buscou-se, como segundo objetivo, avaliar alguns resultados de escórias industriais e compará-los com o proposto pelo modelo. A viscosidade e molhabilidade foram os parâmetros de maior impacto neste estudo, sendo a viscosidade obtida através da termodinâmica computacional com o FactSage e a molhabilidade estimada a partir do modelo de Nakajima.

Jul 30, 2018

By Anderson Alves Cunha

Diante do cenário macroeconômico internacional, o setor mineral busca soluções inovadoras e sustentáveis para seus processos produtivos. Uma dessas soluções é, sem dúvida, aumentar a recuperação do mineral de interesse presente no rejeito proveniente de operações de beneficiamento de baixa recuperação metalúrgica. A substituição de matérias primas naturais por resíduos abre uma gama de oportunidades para melhorar a gestão de recursos não renováveis, contribuindo significativamente para o desenvolvimento sustentável e competitividade do negócio. O presente trabalho tem o objetivo de definir qual a faixa granulométrica, existente na lama, é mais adequada para concentrar e produzir pelotas, considerando a composição química, perda por calcinação, mineralogia e quantidade de elementos deletérios. Para isso, foram utilizadas técnicas de caracterização tecnológica, como: classificação granulométrica (peneiramento a úmido e cyclosizer), fluorescência de raios X, difração de raios X e microscopia óptica. Os resultados do trabalho permitiram identificar uma faixa granulométrica com alto teor de ferro e alto grau de liberação dos minerais de ferro, porém com teores de quartzo acima que um pellet feed comercial. Sendo assim, um determinado tratamento de concentração ou um blend será necessário para adequar quimicamente o material, para posterior obtenção de pelotas com baixo custo.

Aug 17, 2017

By Antônio Donizetti Giuliano, Fernando Codelo Nascimento, Viviane Tavares de Moraes, Cilene Cláudia Diógenes, Erivan Cardoso Rocha

Nos lagos ornamentais geralmente tem-se a dificuldade em controlar o crescimento de algas, pois existe a incidência de luz e a disponibilidade de nutrientes provenientes da ração fornecida aos peixes, os quais propiciam o crescimento e o desenvolvimento das algas. Uma alternativa de tratamento é o processo oxidativo avançado (POA) existente, a ozonização, com o objetivo de propor um processo de tratamento de água para controlar a proliferação de algas em um lago ornamental sem prejuízos à comunidade aquática, vivente no lago. A metodologia utilizada foi o estudo de caso do lago que envolveu as seguintes etapas: construção do lago ornamental; definição do sistema de tratamento; monitoramento de parâmetros como: a demanda bioquímica de oxigênio (DBO), a cor, o pH, a temperatura, a amônia (NH3) e o oxigênio dissolvido (OD) do lago durante três meses; aplicação do ozônio para controlar a proliferação de algas e monitoramento dos mesmos parâmetros durante o processo de ozonização. Dentre os principais resultados encontrados citam-se: a redução de 170 unidades de Cobalto platina (PCU) da cor esverdeada da água do lago; descimento de 60% da DBO; aumento de 16% da concentração de OD e a redução de 80 a 100% da concentração de NH3, eliminando assim odores desagradáveis e melhorando a qualidade da água. Por meio dos resultados obtidos conclui-se a aplicação de ozônio em lagos ornamentais é uma alternativa para a manutenção aquática e melhoria da qualidade da água..

Oct 2, 2019