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By W. R. Donaghue, R. L. Robinson, C. Scott

Whilst spontaneous combustion has never been considered a major problem in south Durham, certain collieries in the area have a history of heatings and precautions are essential. Three collieries are affected - Shotton, Vane Tempest and Seaham - and in the case of the last two, there are huge areas of high quality coal to work under conditions where spontaneous combustion is a real hazard. The seam being extracted has an immediate roof in goaf left by the incomplete extraction of a contiguous seam worked before the turn of the century. The presence of residual coal stocks and old roadways and cavities adds to the difficulty of preventing unwanted air movement. The main preventive measures adopted are the construction of airtight gateside packs and the use of sprayed surface coatings in the gate. Sampling systems and sampling points are described and, in particular the field of continuous monitoring from the surface is examined. The resulting possibility of a quantitative as well as qualitative assessment of the preventative measures required is discussed.

May 23, 1905

By W. R. Crane

Recent papers on support of roof and top rock in mines representing present practice in so far as it hits been described by engineers in all of the principal mining countries, cover a relatively aide range of topics. The papers abstracted herein include such subjects as the testing of materials of support, failure and movement of rock above workings, effect of excessive pressures on rock masses, axed the application in mines of timber, metal, concrete, packing, and filling support. It is not within the scope of this paper to present a logical and orderly discussion of the elements of support and their application to conditions influenced by the material worked or the method of mining. Only the essential facts of a paper appear in the abstracts, the idea being to give a fairly clear picture of the behavior of various types of support under brows conditions and to put into concise form important information concerning present practice, modifications of practice, and the trend toward new practice. With such valuable facts from others experience made readily available, it Is hoped that the engineer with particular and often trying problems may obtain suggestions that will be immediately helpful.

Jan 1, 1932

By Benjamin C. Pollard

The location and production potential of a large block of strippable reserves in North Dakota were determined by using published data as a base and adding new drill hole data or other data contributed by companies that presently own or lease coal lands. Only beds exceeding 5 feet in thickness, under less than 120 feet of overburden, and in large blocks of 5 million tons or more were included in the estimates. All such reserves are in the Fort Union Formation of western North Dakota and are lignite in rank. Sixteen large blocks of reserves evaluated in this study are estimated to contain a total of 4.1 billion tons of strippable lignite.

Jan 1, 1972

"Bay d'Espoir is in the approximate center of the south coast of Newfoundland. The geology of the area can most conveniently be considered in terms of three units: (1) an Ordovician or older polydeformed terrain termed the Little Passage Gneisses; (2) a Lower-Middle Ordovician volcano-sedimentary sequence assigned to the Baie d'Espoir Group; and (3) granitoid intrusive rocks of mid-Paleozoic age. Mineralizing events accompanied the formation of the latter two units.The Baie d'Espoir Group comprises a dominantly sedimentary sequence of pre-Middle Ordovician shelf and distal turbidite sediments deposited on the eastern margin of Iapetus. A significant volcanic component is, however, present in the Isle Galet Formation, consisting of up to 30% felsic volcanic rocks interbedded with sedimentary and epiclastic rocks. The Isle Galet Formation hosts several disseminated to thinly bedded Pb-Zn-Ag occurrences associated with altered felsic tuff and graphitic shale. They occasionally grade laterally into pyrite iron formation and appear to have been deposited in a very distal volcanic environment. The Isle Galet Formation is a time equivalent of the mineralized pre-Caradocian island-arc sequences of central Newfoundland, but differs from them both in style of volcanism and in the nature of the associated mineral deposits. It is, however, comparable in many respects to mineralized volcanic sequences in the La Poile Bay area of southwestern Newfoundland.Mineralization associated with granitoid rocks in Bay d'Espoir is best developed around the southeast margin of the North Bay Granite, where two-mica leucogranite forms a marginal phase. Numerous minor base metal showings occupy quartz, quartz-carbonate and barite veins in the adjacent sedimentary rocks. Collectively, the showings exhibit a well-developed, zonal pattern around the granite margin; molybdenite (±py, cpy) predominates near the contact, giving way outward to galena (±sph, py, asp, cpy) and eventually to stibnite (±asp, py) at the periphery. Mineralization associated with granites in similar settings elsewhere in southern Newfoundland includes tungsten in the Grey River and Granite Lake areas and molybdenite in the Rencontre Lake area."

Jan 1, 1982

By Yeonuk Choi, Gus Van Weert

"In regular CIL circuits, activated carbon is used for two purposes: avoiding solid/liquid separation after cyanide leaching, and minimizing gold losses in the tails. The carbon distribution and gold profiles in the successive CIL stages are operating variables, not objectives. When the CIL feed contains a preg robbing constituent however, such as native carbon, there will be competition for gold cyanide and this conflicts with minimizing of losses of gold to CIL tails. This paper examines some of the limitations of activated carbon in CIL circuits handling preg robbing Carlin Trend ores.INTRODUCTION Carbon-In-Leach (CIL) has been a great success treating regular gold ores, but the technology is still challenged by preg robbing feedstocks. Little information is available in the gold milling literature on CIL gold extraction from “free” milling gold ores which are preg robbing, or on autoclave discharge (POX’ed) slurries of double refractory ores. Neither feedstock is readily available for experimentation. No literature reference could be found describing deliberate modifications to CIL operations or CIL circuits due to the presence of two types of carbon: “native” and activated. There is some literature on the gold cyanide adsorption activity of native carbons (Schmitz, Duyvesteyn, Johnson, Enloe & McMullen, 2001). Various tests have been devised to measure this activity, commensurate with CIP and CIL practices (Tretbar, Arehart & Graves). In this paper, the term “native” carbon indicates (severely) preg robbing carbonaceous materials found in gold ores. There is considerable literature on the gold cyanide adsorption activity of man-made “activated carbons”. Various tests have been devised to measure this activity, commensurate with CIP and CIL practices. These tests are comparative, i.e. results relate to a standard carbon and depend on the test methodology and carbon history. The test results are equilibrium oriented, hence of limited value to CIL circuit designers or plant operators handling preg robbing solids; in CIL circuits most carbons are not loaded to capacity. Information on gold cyanide adsorption and desorption kinetics might be more relevant and that is one subject explored in this paper."

Jan 1, 2012

By W. T. Robson

ONE of the problems encountered in any mine is the effect of increasing pressure manifested by increasing depth. Although the depth at which excessive pressure assumes serious proportion, and the manner in which it appears in underground workings, are influenced by a variety of factors, nevertheless the difficulty is present in all mines and its gravity increases with increasing depth. In the Kirkland Lake camp, as far back as seven years ago, mining had proceeded to depths sufficient to result in the formation of pressure great enough to cause violent disruption of masses of rock. It is proposed in this paper to deal with the effect of pressure caused by mining as observed at Lake Shore Mines, and to describe some of the methods which have been adopted to counteract it. There are many contributing factors in a study of the problem, and results vary widely in individual mines and in different localities. One feature common to all, however, is that there is ground subsidence, evidenced either by a gradual settling accompanied by crushing and shearing of the ore and wall-rocks, or the disruption of the ground surrounding the periphery of an excavation may take place suddenly, attended by more or less violent shattering of the rocks. Such violent failure of a mass of rock has been designated by the term rock-burst. The history of rock-bursts extends over a great number of years. They have occurred in some form or other in practically ali places where mining operations, at all but very shallow depths, have been carried out. Since the theoretical aspects of the subject have been dealt 'with at great length by capable and experienced writers (1), the present paper will give only a brief résumé of the theories propounded by those engaged in deep mining operations in various parts of the world.

Jan 1, 1940

By Alain Simard, Sylvain Lacroix, Louis-Martin Dubé, Pierre Pilote

"The Harricana-Turgeon belt (HTB) is a poorly known volcano sedimentary belt in the NW part of the Abitibi Sub-province; it includes the Matagami, Joutel, Brouillan and Casa-Berardi mining districts. The HTB is dominated by volcanic rocks, which covers 65% of its surface area, followed by sedimentary (18%) and plutonic (17%) rocks. It is also transected by numerous deformation zones located either at the contacts of volcano-sedimentary units and granitoid bodies or cross-cutting them. A preliminary geological synthesis shows that mineral deposits are associated with certain regional geologic elements.The volcano-sedimentary units are grouped here into twelve band-shaped lithotectonic domains, most of which extend for more than 150 km E-Win the HTB. Each domain is defined by lithologies and facies associations, and gradiometric and electromagnetic signatures.Eight domains are composed of basaltic or basaltic to komatiitic associations, interlayered with thin pelagic sediments, representing sub-marine lava plains. Two domains are composed of basaltic to rhyolitic associations that are interpreted as volcanic arcs formed by one or several central volcanic complexes.The sedimentary rocks are grouped into two lithotectonic domains. Each is composed of rhythmic sequences of turbiditic sandstone- siltstone-shale, Algoma-type banded iron formations and conglomerates bearing plutonic and volcanic pebbles. These three facies come partly from mass flow at the bottom of a slope in a moderately deep marine environment. In each domain, a conglomerate sandstone- siltstone sequence, containing poly genetic pebbles of local provenance, is similar to Timiskaming-type alluvial deposits.The nineteen granitoids, found within the HTB and at its border, belong to numerous petrographic suites, and have been grouped into four structural families: pre-tectonic, pre- to early-tectonic, syn- to late-tectonic, and late- to post- tectonic. The pre- to early-tectonic plutons are presumed to be sub-volcanic and are generaly associated with the volcanism of central complexes.The HTB mineral resources consist essentially of polymetallic (Cu-Zn-Ag-Au) and gold (Au-Ag) deposits. The polymetallic deposits are located exclusively in the two lithotectonic domains composed of basaltic to rhyolitic associations (Matagami-Brouillan and Joutel Raymond). All gold deposits are associated with deformation zones superimposed on lithotectonic domain contacts and highlighted by graphitic units. Most of the deposits are hosted in the Casa-Berardi and Douay deformationzones, located at the contact of the Cartwright basaltic to komatiitic domain and the Taibi sedimentary domain"

Jan 1, 1990

A single aggregate mix design was developed based on a slag/Portland binder blend and crusher sand. The primary design criterion, after performance, was the fluidity of the shotcrete and concrete product to ensure compatibility with existing manufacturing and shotcrete equipment as well as the pipeline transport system Cullinan Diamond Mine was investigating. Initial work had determined an optimum slag/Portland to aggregate ratio while retaining a water to slag/Portland binder ratio of approximately 0.4 to maintain the flowability of the product. A super-plasticizer was used to further increase the flowability of the product as opposed to increasing the water content. Finally a polypropylene reinforcement fibre was included in the wet shotcrete product to improve the energy absorption characteristics of the shotcrete. Previous work on the strength development of the slag/Portland based shotcretes and concretes suggests that strength class based on the EN 206 specification is C40/50 while the toughness classification based on the EFNARC plate test is c, or greater than 1000 joules1. Typically, Cullinan Diamond Mine wanted a shotcrete with a uniaxial compressive cube strength of 45 MPa and an energy absorption, based on the EFNARC plate test, in excess of 700 joules. This is an EN 206 strength class of C36/45 requiring a uniaxial compressive core strength of 30.5 MPa and a toughness classification of b1. In addition to the shotcrete development, Cullinan Diamond Mine required concrete products with a compressive strength range of between 25 and 60 Mpa for differing construction operations underground to be manufactured from the same mix design and raw materials as for the shotcrete. Finally, Cullinan Diamond Mine carries out extensive dry shotcrete operations and an investigation into the possibility of using the single aggregate mix design for dry shotcreting was also entered into. This paper presents data that indicates that, under the terms of reference, a wet and dry shotcrete and concrete product appears to be possible from a single aggregate less than 6.7 mm in size, and that a slag/Portland binder is suitable for use as the hydraulic binder in all the products, and that the necessary performance parameters of strength and energy absorption can be achieved.

Jan 1, 2006

"Mineral separation by exploiting the differences in mineral or metal specific gravities (sg) has been used since antiquity. In the modern era, this is most commonly seen in the recovery of gold by the use of centrifugal concentrators and the separation of coal (low sg) from waste rock (high sg) using heavy media cyclones and jigs. Other metals, notably oxides of tin and tungsten, are successfully recovered using some combination of jigs, spirals and shaking tables. However, many conventional gravity separation systems are limited to fairly coarse (>1 mm) to medium (>100 micron) particle separations due to the limitations of the gravitational separation forces in conventional equipment.Many of the high specific gravity minerals of interest are friable (e.g. cassiterite, wolframite, etc.) and excessive fines are generated in the grinding/comminution circuits which cannot be recovered with conventional equipment and may be lost directly to the tailings stream. Recent developments in centrifugal gravity separation equipment specifically designed for fine or ultra-fine particle separation and recovery have resulted in heavy mineral particle recoveries as fine as 10-20 microns. Ongoing research work has also identified the benefit of closed-circuit, multi-stage gravity recovery circuits using some combination of centrifugal concentrators and conventional equipment (tables, spirals, flotation, etc.) which can substantially increase overall plant recovery and final concentrate grade.This paper will provide details of the evolution of non-fluidized bed gravity concentrators for high sg mineral recoveries, correlate laboratory scale development work with plant results to confirm scale-up, and show how recent flowsheet developments have contributed to significantly improved plant performance.IntroductionGravity concentration is one of the oldest and most cost effective metal and/or mineral recovery systems, ranging from the classic hand panning of alluvial gold, through to the large scale production of a wide range of metals and minerals, including gold, silver, PGMs, black sands, coal and iron oxides. Conventional gravity recovery systems, comprised of some combination of sluices, spirals, jigs and shaking tables have limited application in fine particle (i.e. <100 microns) recovery, or where there are limited differences in particle specific gravities (sg), e.g. the separation of high sg, high value metal oxides (e.g. those of tin, tantalum or tungsten), from medium sg, lower value metal sulfides such as pyrite and pyrrhotite. These unit operations tend to have limited capacity, and while double and triple turn spirals and multi-deck tables have been developed, extensive floor space is often required in order to process the tonnages incorporated in the modern mineral processing plant."

Jan 1, 2017

By Michael S. Contratto, Dave Marshall, Tom Brodersen

The European Union (EU) completed a new directive 2002/44/EC1 called the Physical Agents Directive (PAD) that establishes action and limit values for hand-arm and whole body vibrations. The directive specifies that: “…workers shall not be exposed above the exposure ‘limit value’.” 1 and “…once the exposure action values … are exceeded, the employer shall establish and implement a programme of technical and/or organisational measures intended to reduce to a minimum exposure to mechanical vibration and the attendant risks…” 1 The PAD limit value is effective for new machines starting July 6, 2007 and for used machines by at least July 6, 2010. These requirements apply to the users of machines, but machine manufacturers will be challenged to provide machines and information to help the users comply with the directive. Caterpillar manufactures machines with the goal of enabling our customers to comply with all regulations dealing with health and safety. Caterpillar designs all of our machines to provide a safe, comfortable and productive work environment. This study was to determine if seat suspensions could provide a reduction in the vibration environment experienced by operators of Caterpillar mid sized (<50,000KG) Track Type Tractors Methods Seat manufacturers were asked to provide seat suspensions that provide improved isolation over and above current seat suspension. Each supplier was provided with ride profiles and was asked to demonstrate the vibration reduction on a shaker table. Two suppliers provided suspensions that were compared with the current seat suspension in a field study. Three full factorial experiments were conducted. The first experiment was to evaluate overall suspension performance for four operations. The second experiment was to determine the benefit of the adjustable vertical damper at three different levels and the third experiment was to determine the effect of the fore/aft and side/side isolators. Six operators were used for the study. Acceleration was measured at the seat base and at the operator seat pad. Both the transfer function and the ISO 2631 RMS ride values were used to determine the seat suspension’s effectiveness of isolating the operator from vibration. A structured questionnaire was used to determine the operators’ subjective assessment of the seat suspensions. Results There was significant operator-to-operator variability in the vertical direction (>35%), however there was little variability in the fore/aft and side/side direction based on seat base

Jan 6, 2006

By J. J. Pavlica

Grinding in steel mills adversely affects the flotation removal of pyrrhotite from magnetite ores. To elucidate the effect of grinding media on the floatability of pyrrhotite, rest potential and short-circuit current measurements were made on electrode combinations of pyrrhotite-mild steel and pyrrhotite-stainless steel. Galvanic contact of pyrrhotite with mild steel increased the rate of surface reactions on pyrrhotite in air-exposed and oxygenated solutions. It was postulated that the formation of &apos; an iron hydroxide coating on the pyrrhotite adversely affected its floatability. Its formation was minimal when pyrrhotite was contacted with stainless steel. Fine magnetite particles caused slime coating on pyrrhotite surfaces by magnetic interaction and impaired the flotation of pyrrhotite.

Jan 1, 1982

By M. J. Gavin

Within the past three years numerous inquiries for information on oil shale have been received by the Bureau of Manes. These inquiries have been increasing to such an extent that it has seemed advisable to issue a short paper prior to the publication of a bulletin on the subject, giving a, general discussion of the subject and a comprehensive list of references, so that those interested in the details of obtaining oil from shale can find additional information without much difficulty. Some of those who desire information are interested only in a general discussion of the subject, or are not in a position to refer to books and&apos; articles describing the industry. The material for this paper is largely derived from published information on oil shale. Much of the information is obtained-from the books and articles mentioned in the list of references, and has been compiled with the intent of furnishing information to those not interested in all the details.

Jan 1, 1921

By C Maloloy-on, S Morgan, M Deiparine, H Mackie

There is a strong focus in the mining industry to limit its impact on water quality and usage. This is even more evident in developing countries, where mining companies operate within local communities and have to be diligent not to affect them negatively. In mineral processing operations, the vast majority of water reclamation occurs at the tailings thickener area and tailings storage dam. It is often more effective to maximise water recovery at the tailings thickener before material transport to the tailings dam. Tailing dams are relatively inefficient, and experience a high degree of water loss due to evaporation, seepage and water retention. In addition, tailings dams present the biggest environmental liability for mineral resource projects, so it is beneficial to limit their size and loading.In the past, it was common for tailings thickener areas to have a significant footprint with several large diameter conventional thickeners, producing underflows of between 45-55% solids (w/w). At times, these multiple thickeners were difficult to operate, leading to inefficiencies in water recovery and quality. The development of High-Rate Thickeners (HRT) has resulted in improved settling properties and HRTs usually operate at significantly higher solids loadings (= 1.2 t/m2.h) when compared to conventional thickeners (= 0.1 t/m2.h). Subsequently, thickener diameters have reduced in size and HRT technology has become the preferred option for thickener circuit design in both new and existing operations. HRTs also produce higher water recoveries with increased underflow densities = 55% solids (w/w).The Carmen Copper Corporation (“Carmen Copper”) circuit upgrade is a recent example of these HRT benefits, where one, 39 m diameter, Outotec HRT treats the solids flow rate of five 76 m diameter conventional thickeners. This has allowed operations to increase dry plant tonnage by 50%, maintain key performance targets and provide a framework for further plant expansion. This paper details the sustainable approach to the Carmen Copper tailings thickener upgrade, where metallurgical performance, cost-effectiveness and environmental impact were key considerations.CITATION:Morgan, S, Mackie, H, Maloloy-on, C and Deiparine, M, 2015. Carmen Copper – a sustainable approach to tailings thickener upgrades, in Proceedings MetPlant 2015, pp 416–430 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

By R. B. Taylor

The Esmeralda mine is located about three miles west of the town of Parral, in the State of Chihuahua, Northern Mexico, and about 400 miles south of El Paso, Texas. The area is serviced by the Interamerican Highway and a branch line of the National Railways of Mexico. The Parral district is quite typical of the semidesert of Northern Mexico, lying near the western margin of the Chihuahua basin and range province known in Mexico as the ?Mesa Central? In the immediate mine area, low rounded hills and rolling plans slope toward the Parral River. Surface elevation at the mine is 5,800 feet. The Esmeralda vein outcrops strongly, but was too low grade to be of interest to the Spaniards, The first claims were staked in 1897 and limited exploration work to a depth of 550 feet was carried out prior to 1912, at which time work was suspended. The Eagle-Picher Company acquired the property in 1944 and by surface diamond drilling outlined an orebody to a depth of 800 feet, Minas de Iguala, S. A, de C.V., one of Eagle-Picher?s totally owned subsidiary companies in Mexico, then unwatered the old workings, developed the mine, installed a modern differential flotation plant and started production lage in 1948. To the present, more than two and ahalf million tons of ore have been mined and milled producing lead and zinc concentrates.

Jan 1, 1958

By Leland E. Paulson

The Grand Forks Energy Research Center and Commonwealth Edison of Chicago jointly conducted tests in which 400 tons each of subbituminous coal and lignite were dried in a commercial scale dryer, oil sprayed and cooled, then shipped in open-top rail cars from Pekin, IL to Grand Forks, ND and stockpiled. Cars containing raw coal and dried coal that had not been oil sprayed were also transported for comparative purposes. The tests were conducted in August and November of 1974. The subbituminous coal was dried from 26 to 16 pct moisture and the heating value was upgraded from 8,420 to 9,650 Btu/lb. The lignite was dried from 39 to 22 pct moisture and its heating value was increased from 6,420 to 8,300 Btu/lb. Before loading subbituminous coal was cooled to 115° F and sprayed with oil at a rate of from 2 to 6 gal/ton. Similarly, lignite was cooled to 85° F and oil sprayed at rates of from 1 to 2 gal/ton. Both shipments arrived in Grand Forks with a minimum of difficulty. The subbituminous coal was subjected to 2 inches of rain during transit with no change in average moisture content. The cars containing dried and oil treated coal had less material lost to wind than either cars containing raw or untreated dried coal. With both dried lignite and subbitnminous shipments, a moderate increase in temperature was measured during transit. With the subbituminous shipments, ignition occurred near poorly fitted bottom dump doors, but was limited to a very small area. The dried lignite was shipped when ambient temperatures were below freezing, and frozen coal was noted around the edge of the car. At Grand Forks, the coal was stockpiled using proven techniques and has remained stable to this date.

Jan 1, 1975

By Nadia C. Miller

In situ metals research to characterize the hydrology of a fractured crystalline rock mass in under-ground mine stopes is discussed. The objective of this study was to find the potential direction, velocity, and concentrations of a lixiviant plume, should leaching solvents (lixiviants) escape from a test stope. The study was conducted by the U.S. Bureau of Mines at the Colorado School of Mines Experimental Mine in Idaho Springs, CO. Since this was a method evaluation site, the lixiviant was simulated using water and acceptable tracers. The site is located in moderately fractured Precambrian migmatite-biotite gneisses of the Idaho Springs Formation. The data required for the characterization were obtained from geologic maps and reports, core logs, and air and water permeability tests. The acquired data were analyzed and applied to a computer model that calculated&apos; the characteristics of a lixiviant plume originating at the stope. A sensitivity analysis showed that dispersivity, ground water velocity, fracture porosity, and fracture spacing had notable effects on the concentration of the plume. Assuming a saturated rock mass, the lixiviant plume would disperse to undetectable levels in a very short time because of a high fracture density at the mine site.

Jan 1, 2010

By Iwasaki I.

This article discusses the effect of physical and chemical modifications of starches on the anionic and cationic flotation of silica from oxidized iron ores and magnetite-taconite concentrates, and the results of the interaction of starch, pH, and calcium ions on the flocculation, clarification, and filtration of iron ore slimes and magnetite-taconite tailings. Starches, particularly when anionically modified, were found to be effective depressants in anionic silica flotation. British gums and dextrins were beneficial for oxidized iron ores, but none of the starches or starch derivatives appeared to have any effect on magnetite-taconite concentrates. The flocculation and filtration of iron ore slimes were most strongly affected by the level of starch, to a lesser degree by the pH, and were virtually independent of the level of calcium chloride. The clarification of iron ore slimes was complexly dependent on these three factors. The flocculation of magnetite-taconite tailings depended mainly on the level of starch, whereas their clarification depended on the level of lime. As previously reported in the literature, selective flocculation and partial upgrading of a semi-taconite could be readily attained with starch and calcium chloride.

Jan 1, 1968

By H. D. Hess, C. P. Mabie

This report describes in detail the results of petrographic research conducted on 21 phosphate ores representing important deposits in southwestern Montana , southeastern Idaho , and northeastern Utah . The ores are described and categorized by mineralogical and chemical composition , thermal behavior of organic carbon , and textural constitution . Descriptive and genetic classification schemes applicable to western phosphate ores are discussed ; results from related studies made of the collophane mineralogy are also presented . The latter studies were centered on determining unit - cell dimensions and CO₂ , P2O5 , and fluorine content of collophane concentrates of 11 high - grade phosphate- rock hand specimens selected solely for this purpose . On the basis of this investigation , operational methods have been developed for quantitatively describing textural and compositional features that are likely to be significant in determining the response of phosphate ores to conventional beneficiation treatments ; systems for classifying the ores in relation to these features have been proposed . Studies to date point out distinct textural and compositional variations in the western phosphates and illustrate their importance in determining optimum beneficiation procedure .

Jan 1, 1964

By D. J. MacDonald

Wettability measurements and laboratory waterflood tests were compared under a wide variety of conditions. Experiments were conducted with synthetic and natural crude oils, treated and untreated outcrop and oilfield sandstone cores, and synthetic brines with and without caustic, detergent, or phosphate additives. Measurements were made on equilibrated and unequilibrated systems at 77° and 150° F. Wettability was evaluated by the Bureau of Mines method from capillary pressure curves determined with a centrifuge. The waterflood data were fitted by empirical curves; the parameters of the curves characterize primary and subordinate production and also give the ultimate oil recovery. Results showed that wettability measurements at 77° F were useful predictors of recovery efficiency in waterflood tests run at both temperatures. Oil recovery in the early stages of waterflooding increased with increasing water wettability; however, the ultimate recovery was highest at a slightly oil-wet condition. The oil displaced at highest speed in the centrifuge was correlated with ultimate recovery in waterflood tests. Chemical additives to the brine sometimes lowered wettability and also sometimes improved waterflood recovery, but wettability and recovery were not correlated with additives present. The effect of additives on recovery in waterflooding was best seen in water-oil ratio curves.

Jan 1, 1974

Gas-liquid contacting in the packed bed is a common operation in metallurgical reactors. Research has shown that, unlike wetting flow, non-wetting liquid flows in the form of discrete droplets or rivulets. Thus, modeling of the liquid phase as a continuum is in contradiction to the observations. Also, for the non-wetting case, continuum models have failed to describe liquid flow path when the liquid source is a point source. The aim of the current work is to put forward a combined Lagrangian-Eulerian approach to model the liquid and gas flow in the packed bed. Liquid is assumed discrete and modeled using a force balance approach. Gas is assumed to be interpenetrating continua and modeled using k-emodel for turbulent flow. Structured packing is assumed and x- ray imaging technique is used to visualize liquid flow lines in the bed. Simulation results for liquid flow path compared with the experiments.

Jan 1, 2006