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By Aline Lima da Silva

The reduction in SOFC operating temperature due to recent development in materials and fabrication techniques enables the use of ferritic stainless steels as interconnects for SOFCs. Ferritic stainless steels offer many advantages over traditional ceramic interconnects, such as higher thermal and electronic conductivity, as well as relative ease of fabrication. However, the formation of chromium oxide on ferritic stainless steel results in an increase in ohmic resistance and can lead to the loss of cathode catalytic activity (due to Cr volatilization, with cathode poisoning). The oxide growth depends on several factors, such as steel composition, temperature, oxygen partial pressure. In this way, knowing the phase stability, the oxidation behavior of the material and the oxidation kinetics is of great interest. In this context, a thermodynamic study of the oxidation of ferritic stainless steel 430 under oxidizing atmosphere (cathode), at the temperature of 750ºC, is carried out. As one can see, the thermodynamic system can be very complex, involving several phases (chromium oxide, (Fe,Cr,Mn)3O4 Spinel, iron-chromium oxides, etc.). The effect of oxygen partial pressure and alloying elements on phase distribution is evaluated. Thermodynamic modeling is compared with experimental results from literature.

Aug 8, 2018

By C. B. Manula

This report is volume 4 of at. eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment: The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation,' and ventilation. This volume of the final report describes the Roof Support subsystem of the Master Design Simulator. This model is based on popular roof support practices for different geological environments with related restrictions imposed by the Coal Mine Health and Safety Act of 1969. From geological sections, the model determines the anchor horizon for roof bolts and the density of roof support necessary. The roof support subsystem is tied to both the geology and reserves subsystem and the production subsystem of the Master Design Simulator, but can also operate as a free standing model. Several case studies are presented showing the application of the model. A detailed user's manual, including a program listing, is presented in the appendices.

Jan 1, 1974

By J. H. Adkins

The goal of this program was to produce a set of baseline health and safety training materials that could be used by the metal/nonmetal mining industry to reduce injuries and to comply with federal training requirements. The materials developed are arranged in a two level outline format. The first level provides the title, course goals, background and topical outline while the second level provides a detailed outline of the course content. Visuals, designed to portray miners in a positive, attractive fashion, were done in simple line drawing so they would reproduce for handouts without loss of quality. Each of the required units in the Baseline Guides have one or more self-checks. These are designed to be suggestive of evaluation techniques the users can develop for themselves. An instructors guide and a mining terms glossary are included. In a second phase the program developed performance based training guides for Annual Retraining and Experienced New Hires in the Underground Salt Industry.

Jan 1, 1983

By Robert C. Speck

The U.S. coal industry has long utilized the pillar-extraction mining technique as a method for maximizing coal recovery. Like longwall mining, it causes large-scale movements that progressively propagate from mine-level to the ground surface and may affect the groundwater regime, surface drainage and surface structures. The U.S. Department of Energy, in an effort to foster in- creased use of total extraction mining techniques, has recognized the need for a better understanding of these movements that will lead to a greater compatibility between coal mining and present and future land use. As part of that goal, GAI Consultants, Inc. is currently in- stalling instrumentation to monitor the ground movements associated with pillar extraction mining at Kitt Energy Corporation's No. 1 mine in northern West Virginia.

Jan 1, 1982

The decrepitation technique is a rapid means of measuring abundances, temperatures and to some extent the fluid compositions, of fluid inclusions in transparent and opaque minerals. The method has been used to investigate the hydrothermal fluid systems associated with gold mineralisation in the Tennant Creek, Pine Creek and Halls Creek Goldfields. At the Enterprise Mine, Pine Creek, several different stages of quartz veining are distinguished and within these, gradational changes in fluid temperatures and compositions help to define the centre and nature of the thermal system responsible for the mineralisation. In the surrounding Pine Creek region and at Tennant Creek and Halls Creek, the results were applied on a regional scale to characterize outcrops and aid in the discrimination between potentially mineral- ized and barren outcrops. The decrepitation method involves the heating of a small (lgm) sample of crushed and sized grains up to as high as 800 degrees celsius. During the heating the fluid inclu- sions within the grains develop sufficient internal pressure to physically burst, the temperature of such bursting being dependent on the type of fluid and the prevailing tem- perature at the time the inclusion was originally trapped. The resulting tabulation of the number of inclusion bursts per 10 degree temperature interval is plotted as a histogram of decrepitations versus tempera- ture and called a decrepigram. The decrepi- grams frequently show several distinct peaks at different temperatures which are caused by different populations of inclusions in the sample. The areas of the peaks indicate the abundances of inclusions in each population while the shape and mean temperature of the peak provides a guide to the type of fluids involved. Of particular importance in this study is the presence of decrepitation peaks at fairly low temperatures (around 2000 C. These are characteristic of C02 rich fluids which build up internal pressure very quickly when heated. The Enterprise Gold Mine at Pine Creek comprises a number of overlapping quartz vein systems hosted by Burrell Creek Formation sediments. The geology of this mine has been described at this conference by Dann and Delaney, who have defined several distinct stages of quartz veining based on structural, mineralogical and physical features of the veins. For this decrepitation study, 19 quartz samples from the mine and environs, including some from each stage of veining were collected. These results suggest that there are 4 major vein types, within 3 of which additional small variations can be discerned which are due to gradational changes in the temperatures and fluid compositions in the mine area.

Jan 1, 1984

By George M. Bouton, Lawrence Ferguson

The experiments described in this publication were inspired by the Bell System's large interest in lead-alloy sheathed cables and by the wide range of fatigue and corroding conditions to which they are sometimes subjected in service. The first experiments consisted of operating specimens of lead + I per cent antimony telephone cable sheath alloy in a fatigue test while they were immersed in water taken from a manhole. Because of many published reports concerning corrosion-fatigue phenomena of various metals and alloys, a reduction in fatigue life was expected(1)2 Instead, however, the fatigue test ran on for many times the normal number of cycles an4 was finally stopped without failure. Because of this, the experiments were broadened to include the effect of many media on the fatigue properties of four lead alloys over a wide range of testing speeds and strains. One material, a viscous tacky polymerized isobutylene3 used in

Jan 1, 1945

By R. V. Ramani

This report is volume 3 of an eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment. The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation,' and ventilation. This volume of the final report describes the Methane Generator subsystem of the Master Design Simulator. This subsystem is used to determine methane emission rates into the mine environment. These flow rates are then used by the simulator in planning primary and secondary ventilation systems, planning a methane drainage system, and analyzing complex ventilation networks. Both steady state and unsteady state gas flows are included, and have been modeled as second order nonlinear partial differential equations. Finite difference equations are used to obtain numerical solutions to the models using a central differencing scheme. An application of the model is presented. The appendices include derivation of the gas flow equations used in the model as well as a users manual for the computer program.

Jan 1, 1974

By Adrian C. Deneys, David G. C. Robertson

"Fluid flow phenomena on the surface of a molten slag have been documented using video photography in a laboratory scale D.C. arc furnace. The flow on the surface of the slag appeared to be electromagnetically influenced. This was confirmed by varying the position of the anode, which changed the direction of flow on the surface of the slag. Temperature measurements in the bath also confirmed the change in the directional nature of the fluid flow induced by the arc.During some periods, solids were fed into the arc attachment zone (AAZ) down the center of the hollow graphite electrode. Significant movement of the arc around the basal annular surface of the hollow electrode takes place. The point of attachment of an arc on a hollow electrode was more variable than an arc attached to a solid graphite electrode. Video images showed that the solids were rapidly incorporated into the bulk of the slag. Temperature measurements confirmed the existence of a superheated slag layer at the slag-gas interface, which allowed the solids to be rapidly incorporated into the melt.This work has been conducted to study fluid flow, temperatures, and solid behavior during feeding, in the arc attachment zone of a D.C. arc furnace. The work also has relevance to optimizing furnace design for pyrometallurgical slag cleaning processes."

Jan 1, 1999

By V Sanmartfn, J Torracchi

The broad biodiversity of our country is manifested through several different biological forms. From the villages of Portovelo and San Gerardo in the southern part of Ecuador, some samples of water and rocks were taken in order to identify the native micro-organisms which take part in the natural processes of leaching of sulfurous minerals. The presence of Spp Thiobacillus ferrooxidans was determined together with a fungi sample which has not yet been characterised by the current workers. These have been isolated, grown, experimented and conserved in appropriate cryogenic environments. The present research intends to study the individual and group adaptation of the bacteria and the fungi upon suitable systems of agitation and ventilation, in combination with several different concentrations of refractory auriferous samples. These refractory samples were derived from old mine workings and the experiments were performed to test the effectiveness of the isolated species in bioleaching as pre-treatments upon the cyaniding processes. The capability of these bacteria to develop in environments with high concentrations of cyanide has also been studied, to investigate the possible use of bacteria in the biodegradation of cyanide. The presence of Thiobacillus ferrooxidans in acid conditions has already been tested in advance, however, the presence of fungi species in these conditions are studied to prove their efficiency as another alternative for the bioleaching of refractory auriferous minerals and Baptista, 1998).

Jan 1, 2004

By R. S. James, D. C. Peck, P. T. Chubb

"The East Bull Lake gabbro-anorthosite intrusion is one of several Early Proterozoic layered mafic intrusions occurring along the Southern Province - Superior Province boundary in the Elliot Lake - Sudbury region, Ontario. The base of the East Bull Lake intrusion comprises abundant plagioclase cumulates (Leucogabbronorite Zone) hosting two distinct styles of sulfide mineralization: (1) disseminated magmatic sulfides, and (2) disseminated to massive, structurally controlled sulfides. Both types of mineralization are enriched in Pd, Pt, Au, Cu and Ni. The host rocks to the sulfide mineralization display a range of interesting features including nodular textures, dendriticpegmatitic mafic pods, inclusion-rich zones (pyroxenite, anorthosite and granitic inclusions) and magmatic breccias. Disseminated chalcopyrite, pyrrhotite and pentlandite occur in concentrations of up to 100/0 within erratically distributed gossan pods near the base of the intrusion. The sulfides were originally precipitated from intercumulus liquids, but were subsequently recrystallized and locally remobilized along fractures during the major period of metamorphism and deformation that affected the East Bull Lake intrusion. The base- and precious-metal tenor of the structurally controlled sulfides can be explained by extensive remobilization and reconcentration of the pre-existing magmatic sulfides in the vicinity of a major shear zone. Both styles of sulfide mineralization locally contain ppm abundances of POE + Au and are generally Pd- and Cu-rich, although both display large variations in Pd:Pt and Cu:Ni ratios. The magmatic sulfides are more strongly enriched in POE and contain up to 1470 ppm Pd in 100% sulfide. Several factors, including source characteristics, magmatic processes (crustal assimilation, fractional crystallization) and post-magmatic interaction with hydrous fluid, have influenced the present distribution of POE, Cu and Ni in the East Bull Lake intrusion.The magmatic sulfide occurrences from the East Bull Lake intrusion compare favorably with marginal-type deposits from rift-related intrusions (Noril'sk-Talnakh region, Siberia; Duluth Complex, U.S.A.) in terms of their distribution, but are most similar to reef-type POE deposits with respect to their base- and precious-metal geochemistry. The combination of high POE tenors and large tonnages that is observed for the POE-Cu-Ni mineralization from the East Bull Lake intrusion suggests that a good potential exists for the presence of economic concentrations of Pd, Pt, Au, Cu and Ni in the intrusion. On a global scale, the East Bull Lake intrusion is part of a suite of Early Proterozoic plutons, many of which contain significant volumes of stratiform and/or marginaltype POE-Cu-Ni mineralization. The East Bull Lake intrusion is also one of the oldest mineralized intrusions derived from a sub-Superior Province mantle source region that has given rise to several significant magmatic POE-Cu-Ni deposits during the period 2.5 Ga to 1.1 Ga."

Jan 1, 1993

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar

An electrochemical technique based on the solid oxide galvanic cel Mo / Mo + MoO2/ ZrO2-MgO / Fe + (FexO)slag + Ag / Fe was used in a determination of FexO activities in liquid slag systems. The emf measurements, scanning electron microscopy, and microprobe analysis of the cross-sections of the electrolyte tubes used in direct contact with the slag melts indicated that slag attack did not affect the open-circuit emf values during normal cell operation, The reliability of the cell was confirmed by the good agreement between the standard free energy of formation of liquid Fep obtained in the present study and those reported in the literature, The FexO activities were determined in FexO -CaO and FexO-SiO2 slags at 1673 K, and are in good agreement with those measured by the conventional gas-equilibrium technique. The experimental technique was successfully extended to the measurement of Fe2O activities in the complex slags that are used for the external desilliconization of the hot metal product of the blast furnace.

Jan 1, 1986

By M Fylak, R Wenda

Advanced preparation techniques open new ways for SEM and X-ray diffraction (XRD) investigations on hydrating cementitious systems. In this paper the early time hydration of Portland cement is studied with advanced cryo scanning electron microscopy techniques in combination with in situ X-ray diffraction and heat-flow calorimetry. The application of preparation techniques and analytical methods to Portland cement hydration are presented and discussed. Some aspects of hydration reactions are focused. The reaction products of the first minutes, changes in ettringite morphology, AFm formation during the deceleration period and the visualisation of C-S-H microstructures were special points of interest. X-ray diffraction analyses and Cryo-SEM images gave essential information about phase development, reaction kinetics, microstructure and morphology of hydration products. Portlandite, AFt and AFm phases were detected by in situ XRD. Cryo-SEM analyses enabled high resolution imaging and EDX-analyses of cement particles and reaction products. The results of the different analytical methods were compared to obtain detailed information about crystallisation processes and microstructural development during the first three days of Portland cement hydration.

Jan 1, 2008

The National Institute for Occupational Safety and Health conducted laboratory and field tests to evaluate the effectiveness of dust collector bags for reducing dust liberation and operator exposure from a roof bolter?s dust collection system. The laboratory tests evaluated the bag?s effectiveness to contain dust and the effect on canister filter loading in both a bag and bagless condition. The dust emissions from the collector?s exhaust were also measured in each condition during laboratory testing. Laboratory results show that nearly 100 percent of the test dust fed into the collector was captured by the dust bags. Loading and pressure drop on the dust collector?s canister filter is greatly decreased when using the bags, enabling longer periods of drilling without filter removal/cleaning. The field results showed that, even though dust standards were met, respirable dust in exhausted emissions was reduced around the bolter. Laboratory and field results show that benefits from use of the bags are realized in all areas of operator exposure.

Jan 1, 2008

Conditional simulation can be used to determine the probabilities of block iron-grades being above selected cut-offs. However, there are much faster alternatives that can produce acceptable results. In this paper blasthole data from a selected area of Joffre Member hosted ore of the Brockman Iron Formation at the Mt Whaleback orebody is used as the basis of a case study to assess alternatives to simulation. Iron grade, in per cent, is interpolated from a blasthole dataset into a block model using ordinary kriging. Samples are then removed from this blasthole dataset to produce data subsets. A complete distribution of iron grades for points or blocks is obtained utilising the data subsets and the following techniques: conditional simulation, median indicator kriging, the probability from conditional expectation and confidence intervals attached to the estimation of blocks in the framework of the discrete Gaussian model. The complete blasthole dataset is considered to represent the true iron grades at sample point support while the ordinary kriging estimate derived from these samples is considered to represent the true block grades. The distributions obtained from point estimates, block estimates and simulations are compared to each other and to the true estimates of iron grades using graphs and statistics. The conditional expectation technique reproduced the results obtained from conditional simulation extremely well and it is a viable alternative to simulation at point support. At block support the confidence intervals technique reproduced the results of the conditional simulation more closely than the median indicator kriging and in the data subsets tested the confidence intervals technique actually reproduced the true grade distribution more closely than the conditional simulation.

Jan 1, 2005

By J. B. Gwiazda

S.S. Peng The highlights of this paper are : • The shield supports with lemniscate links will exert a tangential force on the roof strata, causing unnecessary and harmful roof movements, thus damaging the roof structure. The principal source of the tangential force is the horizontal movement of the point O, the pivotal joint between the canopy and the caving shield. When the support height is changed during setting, the point O will move along a curve upward and rearward toward the gob. As a result, it produces a vertical movement, causing the roof to move up a distance of ?d, and a horizontal movement toward the gob, creating vertical fractures in the roof. • The major purpose for employing the lemniscate-link system is to protect the hydraulic legs against the action of the bending moments induced by the tangential force that causes deformation or destruction of the legs. • Based on these two points, the author suggested that, in order to eliminate the harmful effects of the lemniscate-link system and strengthen its advantageous features, a shield support with a new design of that mechanism has been developed. With the new design, the conventional rigid lemniscate links are replaced by hydraulic rams. When the pressure inside the rams reaches a certain level, the ram will yield.

Jan 12, 1986

By Jamie Archibald

The Department of Mining Engineering at Queen?s University conducted a study of backfill practices in underground mines across Canada to assess the current state of backfill usage and to overview potential hazards associated with backfill practice, from preparation to transportation to placement. The primary aim of this study was to cover each component of a typical mine backfill system, and to identify potential incidents leading to the disruption of backfilling operations and any associated corrective actions. This paper, Part II of the study, deals with underground operations consisting of backfill transportation and backfill placement. Part I of the study, which deals with surface operations consisting of backfill material supply and backfill plant preparation, is also presented in these proceedings. A review of safety measures associated with current backfill operations and recommendations for procedures of best practice that should be implemented to reduce fill-related hazards in all mine backfill workplace environments are presented. In general it has been found that system failures normally lead only to minor losses to the operations.

May 1, 2009

By R. V. Ramani

This report is volume 10 of an eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment. The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation, and ventilation. This volume of the final report describes the Ventilation subsystem of the Master Design Simulator. The Ventilation subsystem has the capabilities to handle: (1) branches in parallel or series, (2) fans in parallel or series, (3) multiple fans, (4) methane, compressed air, or other injections into the system, (5) leakages and fixed quantities, and (6) calculations of absolute pressure at nodes. The program uses the Kirchoff's Junction and mesh laws, and the Hardy-Cross iterative technique to converge to the desired accuracy in solving fox the head quantity. A case study is included in the report illustrating the use of the model. The appendices of the report constitute a user's manual for the Ventilation subsystem, and include a program listing.

Jan 1, 1975

By K. G. Thorne, M. J. McLeod, D. Hoy

"Throughout the Paleozoic, a variety of gold depositional environments were created in the New Brunswick segment of the northern Appalachians because of the complexity of arc and continental plate collisions and subsequent erosion of the orogen. In southwestern New Brunswick, recent exploration and research has focused on deposits and occurrences that can be broadly classified as intrusion-related, generated by late- to post-orogenic felsic to intermediate plutonic rocks emplaced during the Early to Middle Devonian. This work has led to the establishment of models for gold mineralization and guidelines for exploration in this area, which might also be applicable elsewhere in the southern part of the province and, perhaps, throughout the northern Appalachians. The deposits in the vicinity of Clarence Stream in southwestern New Brunswick exemplify this deposit type, and highlight the emergence of a possible major gold district in the region. Durant le Paléozoïque, une grande variété d’environnements aurifères ont été créés dans le segment néo-brunswickois des Appalaches du nord en raison de la complexité des collisions entre arcs et plaques continentales ainsi que durant l’érosion subséquente de l’orogène. Dans le sud-ouest du Nouveau Brunswick, les travaux d’exploration et de recherche récents se sont tournés vers les gisements et les indices appartenant à la classe des gîtes associés aux intrusions, générés par des roches plutoniques felsiques à intermédiaires tardi- à post-orogéniques mises en place au Dévonien précoce à moyen. Ces travaux ont permis d’établir des modèles de mise en place pour la minéralisation aurifère ainsi que des guides d’exploration pour ce secteur, lesquels pourraient aussi être appliqués ailleurs dans le sud de la province et, possiblement, dans l’ensemble des Appalaches du nord. Les gîtes aux environs de Clarence Stream dans le sud-ouest du Nouveau Brunswick sont un exemple de ce type de gisement, mettant en valeur ce qui pourrait devenir un district aurifère majeur dans la région."

Jan 1, 2008

By Christopher J. Bambridge, Lee Seng Hoor

The Stormwater Management and Road Tunnel (SMART) Tunnel is a world first in the use of tunnel space transmitting both road and water through the same spatial envelope. The unique aspect of the SMART project is that the highway decks are used periodically for the conveyance of water. This aspect of the project has posed its own technical challenges that have been overcome in the design stage of the work allowing the project to be taken forward to construction with confidence in the systems to be Installed in the tunnel.

Jan 1, 2005

By Richard Short

Shallow rainfall-induced landslides in residual and colluvial hillslopes and steep embankments are a common occurrence in many settings [1, 2, 3]. While occasionally posing a threat to property and life-safety, they more often present an ongoing maintenance problem and can lead to the initiation of larger failures. Typically, these slides consist of 2 to 4-foot thick translational movements of silty and clayey soils down slope through the reduction of strength from increases in pore water pressures. Direct surficial infiltration and indirect groundwater seepage are the normative triggers for failure. In the residential community of Blackhawk, California, located east of the San Francisco Bay, these types of landslides are a common occurrence (Figure 1). However, shallow landslides have also been a repetitive and constant problem along many state highways where steep embankments have been constructed in close proximity to busy thoroughfares. Given the real threat to property values in residential and commercial settings and the constant maintenance problem posed to lifeline structures such as utilities, roadways, and pipelines, new methods to deal with these landslides are needed.

Jan 1, 2007