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By Oliver C. Ralston

[This paper is an expmded revision of a report entitled "Froth Flota- tion and Agglomerate Tabling of Honmetdlic Idinerds, " published in Trans- actions of the Canadian Ir-stitute of Iriining and !,letdlurgy (vol. 40, November 1937, pp- 6? 1-726) and al'enared a year pr~viousl:~. Revisions en'oodied herein brinc the &ta I:T to Jn?uac"g 1, 193;. References have also been added to make the earlier paper more complete for the period it covered. This paper is an expmded revision of a report entitled "Froth Flota- tion and Agglomerate Tabling of Honmetdlic Idinerds, " published in Trans- actions of the Canadian Ir-stitute of Iriining and !,letdlurgy (vol. 40, November 1937, pp- 6? 1-726) and al'enared a year pr~viousl:~. Revisions en'oodied herein brinc the &ta I:T to Jn?uac"g 1, 193;. References have also been added to make the earlier paper more complete for the period it covered.]

Jan 1, 1938

By Michael J. Atwood

Many buildings in Boston are founded on untreated wood piles, which can deteriorate and lose their structural capacity if groundwater levels are lowered below the tops of the piles, exposing the wood to air in the unsaturated soils that surround the piles. The problem of wood pile deterioration due to lowered groundwater levels in Boston first became evident in 1929 following discovery of rotten piles beneath walls of the Boston Public Library building. Repairs to reconstruct the library building?s wood pile foundations were made in 1930 using pit underpinning methods. Today, more than 80 years later, the subsurface conditions beneath several of Boston?s historic neighborhood areas continue to be plagued with low groundwater levels - regrettably resulting in ongoing deterioration to the wood piles that support some of Boston?s oldest and most beautiful buildings. Pit underpinning is still recognized as the preferred approach to repair wood piles and restore uniform foundation support beneath the impacted buildings. This paper provides a brief historical review of the land filling in Boston through the early 1900s that led to the use of wood piles as building foundations. Also discussed is the impact that groundwater level can have on the long term performance of wood pile foundations and the pit underpinning procedures used to reconstruct decayed wood pile foundations in 1930 beneath the Boston Public Library, and today beneath some of Boston?s oldest buildings. Also included are discussions on engineering controls and permitting requirements that help ensure safety and protection to the workers and buildings during underpinning, and some procedures being used to supplement and improve the loading capacity of the reconstructed foundations and facilitate construction of new useable below-grade space.

Jan 1, 2011

By Lincoln A. Stewart

"INTRODUCTION The First Supplemental National Defense Appropriation Act, approved August, 25,, 1941, authorized the Bureau of Mines to investigate sources of raw, material for western production and appropriated funds for that purpose. Numerous iron deposits and prospects in the Western States were investigated. Among those selected for more detailed investigation were tile Apache and Chodiski deposits in Arizona.The United States Geological Survey had examined these deposits in 1929 3/ and estimated that ""the quantity of minable ore reasonably to be expected in this locality will reach 10,000,000 long tons, but it will require prospecting by core drill to demonstrate this quantity with certainty"". C. H. Johnson, a mining engineer of the Bureau of Mines, made a preliminary examination in October 1941 and proposed exploration of the Apache deposit Canyon Creek.A trench sampling project was set up, and work at the Apache deposit commenced in November 1941. Mapping, trenching, and sampling of outcrops was completed in March 1942. Trenches were laid out at approximately 200-foot intervals for about 9,200 feet along the iron outcrop east of Canyon Creek, and channel samples were taken across the iron formation. The outcrop also was explored by trenching and sampling along a 1,900-foot outcrop on the west side of Canyon Creek.The first diamond-drilling campaign at Apache was initiated in May 1942 and continued to January 1943, when work was suspended owing to depletion of funds. Six holes spaced at approximately 500-foot intervals and, 500 feet back from the outcrop on the east side of Canyon Creek were drilled through the iron formation during this period.While this drilling was in progress, the Chediski deposit was mapped, trenched, and sampled. The trenches were spaced at intervals of approximately 800 feet along 10,000 feet of the iron-ore outcrop."

Jul 1, 1947

By P. C. -H. Rhee, H. -G. Lee, J. -H. Choi, D. S. Kim, S. -B. Lee

In order to predict the composition of inclusions and to ascertain a method to prevent inclusions from forming in liquid Fe-16 mass Cr alloy, a thermodynamic database was developed through a quantitative determination of thermodynamic relationships of Cr-Al-Si-Mn systems in the liquid Fe alloys. Applications of the databases to the prediction of Mn/Si complex deoxidation with Alin Fe-16 mass Cr alloy were demonstrated in succession. The electromagnetic levitation technique using a cold crucible was employed to separate inclusions from liquid metallic alloys completely and to prevent any contamination from surroundings. Various interaction parameters in the liquid Fe-16 mass per cent Cr alloy system were determined; these are: [eAl(Fe)Cr= 0.19/T, rAl(Fe)O,Cr= -0.01, rAl(Fe)O,Cr= -0.00013, eS1Cr(Fe)= -0.38/T,rSi(Fe)O,Cr= 0.007, rO(Fe)Si,Cr= 0.0044, rA1(Fe)Si,Cr= -0.0075, rSi(Fe)A1,Cr= -0.0078, rSi(Fe)Mn,Cr= 0.005, and rMn(Fe)Si,Cr=0.01.] An improved database, utilizing interaction parameters for molten metal determined in this study, and the Fact Sage slag database of the MnO-SiO2-Al2O3-CrOx-MgO system were used for thermodynamic calculations. These were carried out under various thermodynamic conditions, and results were compared with experimental data of Si/Al, Mn/Si, and Mn/Si/Al deoxidation equilibria. With the abovementioned results, together with experimentally obtained data, thermodynamic conditions were determined, in particular Mn and Si contents, under which liquid inclusions form in liquid Fe-16 mass per cent Cr alloy. The critical Al content in liquid Fe-16 per cent Cr alloy, above which solid inclusion of corundum phase ((Al,Cr)2O3) formed, was as low as 10 ppm. This indicates that extreme care must be taken in controlling the Al content in the metal to avoid formation of solid corundum phase ((Al,Cr)2O3) inclusion. The compositional change prediction of inclusions, which originate from slag entrapment and by Ca addition, was demonstrated by use of the alloy database optimized through this study, and the Fact Sage oxide database. For Si-deoxidized Fe-16 per cent Cr alloy, high Si and low basicity of slag are effective to obtain liquid inclusions. For Al-deoxidized Fe-16 per cent Cr alloy, it is important to keep the Si content lower than 0.1 per cent and it is required to add Ca. Keywords: inclusion, thermodynamic simulation, deoxidation, Fe-16 per cent Cr alloy,stainless steel, interaction parameter, cold crucible

Jan 1, 2004

By W. Zhang

"Western China has many shallow coal seams. Mining of these shallow seams contributes to environmental deterioration in part due to disruption of groundwater sources. The lowering of the phreatic surface is attributed to the instability of the impermeable rock groups as a result of mining leading to an increase in permeability and drop in phreatic surface. Underground mining with partial backfilling is one of the fundamental methods of controlling the lowering of the water table in sensitive cases. At present, although significant research has been done in shallow seam mining, there has been no research on the laws governing the movement of impermeable rock groups in partial backfill mining using backfill materials of lower strength. this research, conducted in the Yu Shen-fu region of Western China, developed similar material of sand-based paste filling materials, tested the mechanical parameters of similar material of sand-based paste filling materials, researched on long wall partial backfill mining through similar simulation experiments, obtained the development of “upward fractures” and “downward fracture” under different gap-filling widths and body-filling widths and the movement law of impermeable rock groups under different gap-filling widths and body-filling widths. INTRODUCTION Jurassic coalfield is in the North of Shaanxi province in China, located in border areas of the Maowusu Desert and the Loess Plateau, water resources of Jurassic coalfield in the North of Shaanxi province is meager, ecological environment is fragile (Wang, 2010). With the large-scale development of the mining area, permeable fracture zone will directly affect and spread to the aquifer, causing direct damage to water sources, and lead to the dried up of reservoir, river, wellspring which is recharged by the aquifer(Qian, 2003). There are many researches on aquiclude or impermeable rock groups of shallow coal seam in china, but researches are mainly based on the key strata theory characterized by hard rock as skeleton, without considering the flexibility of impermeable rock groups which is important to reduce the cost of control (Huang, 2010). There are some researches on the stability of impermeable rock groups, but the researches are mainly on permeable fracture zone, which is also called the ""upward crack"" (Wang, 2010), ignoring the influence of the ""downward crack"" on the edge of subsidence basin of impermeable rock groups (Huang, 2010). Previous researches showed that pillar-and-room mining can control the rock crack and surface subsidence (Qiu, 2013), but with the loss of coal resources, and existing disaster a threat of a large scale roof falling. Partial backfill mining mainly by eolian sand bring hope to water-preserved-mining (Fan, 2000), successful practice of paste material backfill mining under buildings and water(Song, 2010)showed its feasibility. Through useing the filling materials with low strength, flexibility and small ratio of height to width, eliminated the threat of a large scale of roof falling, the quantity of partial backfill materials relative to full backfilling are little, the price of sand paste backfilling material is low(Huang, 2011), through designing rational parameters of partial backfill mining, we can achieve the purpose of protecting the phreatic. In this paper, based on the similar simulation experiments, researched on development of the ""upward crack"" , ""downward crack"" and subsidence of impermeable rock groups, researching results can provides the rational parameters to partial backfill mining, and can reduce the cost of filling mining."

Jan 1, 2015

By A. U. Miller

"Ventilation is one of the meet important factors in mining, although until recent years less thought has probably been given to effective ventilation than to any other one phase of mining. In the past, very little, if any, attention was given air courses until they became so constricted by falls that the volume of air was greatly reduced; and, in addition, the stoppings and doors were so poorly constructed that only a very small percentage of air reached the face workings.As a matter of fact, mines have been visited where the volume of air being circulated in certain sections was much larger than in others, and where the management was striving to increase the flow of air in those sections with the least air current, believing the ventilation to be deficient. After sampling and analyzing the return air from the various sections in such mines it has been found that the quality of the air in certain places with the largest flow was more impure than in some of those with the least flow.In past years, practically all mine fans were operated by steam-driven engines supplied with steam from the mire boiler plant. No check was made on the steam consumption or the power cost of operating the fan, therefore the management had very little if any definite information as to cost of ventilating the mine.With the increased use of electrically-driven equipment in mines electricity is being used more and more to drive mine ventilating fans, and since in many instances the current is purchased from central power plants operators have come to realize that in many cases the cost of operating the fans is very high. Some engineers estimate that it ranges from 20 to 50 per cent of the total power cost of the mine. This information, together with the fact that mines are now being developed on a larger scale, requiring larger quantities of air for the men to dilute the gases liberated, has caused the large progressive companies to make, a more comprehensive study of mine ventilation, resulting in a decided improvement in the quality and quantity of air at the face workings, as well as reducing materially the ventilating costs."

Oct 1, 1930

By Arnaud Faucher, Claude Bazin, Marilène Renaud, Mohamed Mai Manga

"Grinding circuits are operated in the presence of disturbances due to ore changes and equipment malfunctions. One of the challenges faced by the operators is the detection of a disturbance, the identification of its origin and of the action needed to minimize its impact on the process. Hydrocyclones overloading, worn or partly plugged apexes of the units of a nest, surging and internal liner detachment may cause a loss of classification capacity and quality. Recovery losses in downstream leaching or flotation circuits justify the effort in developing techniques for the detection of hydrocyclone malfunction. Two approaches for the detection of hydrocyclone fault are presented in this paper. The first proposed method uses the conventional sensors available in a grinding circuit allowing real time detection of hydrocyclone abnormal operation. The second technique is based on the use of vibration sensors installed on the hydrocyclone of a nest. This last technique enables the classification of the hydrocyclone malfunction as surging, overloading and plugged apex. The two techniques can be combined to increase the robustness of the problem detection.INTRODUCTIONHydrocyclones are used for many purposes ranging from water separation, fines removal and obviously for the preparation of the feed for subsequent concentration circuits in a mineral processing plant. The strategic role of the hydrocyclones for the preparation of the feed to the concentration circuit is often underestimated because of their simplicity of operation and robustness (Napier-Munn et al., 1996; McIvor, 1988). It remains that despite their simplicity, hydrocyclones have been studied extensively from 1970 to 1990 with the objective of developing mathematical models of their operation to be incorporated into grinding circuit simulators (Napier-Munn et al., 1996; Lynch, 1977; Flintoff et al., 1987). Such a development effort is already an acknowledgement of the importance of these units in a mineral processing plant. Several authors (Del Villar et al., 1996; Plitt and Kawatra, 1979; Casali et al., 1998) proposed soft sensors to estimate the classification efficiency of hydrocyclones using sensor measurements. However, few of the proposed sensors are used in the industry. More recently several papers were published to discuss the application of 3-D modelling of the hydrocyclones (Narasimha et al., 2005; Cullivan et al., 2004) and sensors (Bond et al., 1999; Neesse et al., 2003; Hou et al., 1998; Olson and Waterman, 2004; Williams et al., 1995; Willams et al., 1997) to help in the detection of hydrocyclone malfunction."

Jan 1, 2010

By Licheng Zhou

The use of aquatic plants for the removal of heavy metals from wastewater has gained high interest. In this study, batch experiments were conducted to evaluate the adsorption of copper ions in aqueous solution by P. pectinatus L. under various conditions of contact time, initial pH of the solution, metal concentration and adsorbent dosage. The results showed that the maximum adsorption amount of copper ions by P. pectinatus L. was 22.60 mg/g when the initial copper ions concentration was 98.41 mg/L at pH 4.5. The Langmuir and Freundlich models were used to describe the adsorption equilibrium of copper ions on P. pectinatus L. and the adsorption followed the Langmuir isotherm. The adsorption kinetic was well-fitted with pseudo-second-order sorption equations.

Jan 1, 2009

By Walter S. Bergholz, Michael L. Schreder

"Since Escondida began operations in fiscal 1991, a series of aggressive expansion projects have enabled market share to be increased and ever larger profits to be realized. This was possible due to the very large size of the ore body and its high grade - averaging 2.7% copper from startup through fiscal 1997. The situation has now changed: ore grade is falling rapidly and is projected to be only 1.55% by 2003. Since revenue is directly proportional to ore grade, while costs are proportional to quantity of ore processed, profits will begin to fall dramatically. The Phase IV Expansion Project is intended to forestall this drop in profits by increasing ore processing capacity by over 85%.The Phase IV concentrator is designed for a nominal capacity of 110,000 MTPD and the key to achieving this value is through the proper design of the grinding circuit. This paper presents the general design criteria for the grinding circuit, as well as a description of the facility.INTRODUCTIONThe Phase IV Expansion Project consists of a new copper concentrator located 8.5 km south of the existing operations, a new tailings disposal and water reclaim system, a new concentrate slurry pipeline to the coast, and added concentrate handling capacity at the port of Coloso. The new concentrator has a nominal capacity of 110,000 tonnes per day (MTPD), compared to the existing concentrator’s capacity of 127,500 MTPD. The Laguna Seca concentrator is based on using the largest and most efficient ore grinding mills now available.The concentrator has been designed for a 110,000 MTPD nominal capacity. The process design criteria for the Phase IV project were established from in-house operating information and from test work. Unlike a green field project, Escondida already had an operating plant and it processes ore from the same pit that feeds the Phase IV plant. It is expected that the current mineralization will be similar for the first 6 years of operation of the new project. Therefore, some of the current plant operating conditions were incorporated directly into the design criteria."

Jan 1, 2004

By Albert H. Fay

Through the hearty cooperation of the State coal-mine inspectors, the bureau is able to present in this paper a a complete statement of the coal-mine fatalities occurring throughout the United States during the calendar year 1919. The reports received from the inspectors for the year just closed show a reduction of 10.58 per cent in coal-mine fatalities as compared. with 1918, while in 1918 the reduction was 4.3 per cent from 1917 figures. The total number killed was 2,307 in 1919 and 2,580 in 1918, a reduction of 273. There was a decrease of 128, or 25 per cent, in fa tali ties resulting from mine cars and locomotives, and a decrease of 198, or 15 per cent, in the fa tali ties due to fall of coal or rock. Surface accidents show a decline of about 25 per cent as compared with the previous year. There were, however, increases in accidents due to gas and dust explosions and also explosives. There occurred during the year nine disasters in which five or more men were killed, representing a total of 201 fatalities. The worst disaster of the year was the one occurring at the Baltimore Tunnel No. 2, Wilkes-Barre, Pa., resulting from the explosion or burning of a number of kegs of powder, by which 92 lives were lost. This disaster emphasizes the need for stricter regulations relating to hauling men and explosives into the mine at the same time. The question of whether electricity was responsible or not does not affect the consideration of the various dangers which arise in underground transportation and handling of explosiveB. At best the handling and hauling of explo.sives is hazardous and such being the case, no one, other than the necessary attendants, should be permitted to ride in cars or cages transporting explosives. As a result of this disaster, the report b of the coroner's jury to the governor of Pennsylvania brings out some important dangers to be avoided in the use and transportation of explosives.

Jan 1, 1920

By Fanke Meng

Electrolyzing oxides of titanium, aluminum and niobium could prepare high-Nb bearing TiAl alloy (Ti-45Al-9Nb) at 1500°C. The chosen electrolysis voltage is 3.5V, which is lower than reducing voltage (~4.7V) of electrolyte CaF2, but higher than that of titanium, aluminum and niobium oxides. The investigation shows that compared with traditional methods, this method for preparing high-Nb bearing TiAl alloy is of many advantages such as few steps, friendly environment, low energy consumption, low cost and high current efficiency.

Jan 1, 2009

By G. Warren

"In the past, smelting and refining of the precious metals recovered from ore has been generally looked upon as a small and relatively minor component of the business of gold mining. This is not surprising when one considers that the manpower, space and capital components of a gold refinery at an operating mine can be several orders of magnitude smaller than other unit operations at the same location. This philosophy is changing however, as economic and environmental pressure are forcing a re-evaluation of all aspects of gold mining and milling.This paper describes and evaluates three furnace technologies available and used by precious metal operators. The operation of arc, induction, and reverberatory furnaces are discussed and their strengths and weaknesses with respect to capital cost, impurity removal, slag quality, and environmental concerns highlighted.INTRODUCTIONIn the past, smelting and refining of precious metals recovered from ore has been generally looked upon as a small and relatively minor component of the business of gold mining. This is not surprising when one considers that the manpower, space, and capital components of a gold refinery at an operating mine can be several orders of magnitude smaller than other unit operations at the same location. Generally, gold producers will spend a great deal of effort to squeeze the last drop of efficiency out of a leach or grinding circuit via simulation or testwork but will design and build the refinery based upon past practices or industry standards. That past practices or industry standards will provide a functional refinery is undisputed; that this philosophy achieves the efficiencies that are possible or demanded in other plant operations is debatable.Environmental and worker hygiene requirements are considerations as well. Pollution control equipment can become a substantial contributor to both the capital and operating costs of a refinery and furnace selection has a marked influence upon the type and cost of this equipment. Slag characteristics and subsequent processing options available also play a role in furnace selection as precious metal slag losses and the recovery effort can greatly influence the cost / benefit analysis of a particular technology."

Jan 1, 2001

By Alan Rojas

La simulación estocástica de variables categóricas (facies) es un campo donde se busca integrar conceptos geológicos tales como posiciones relativas, orientaciones diferenciadas de facies, tipos de contactos y proporciones de las diferentes facies geológicas con el fin de presentar patrones de atributos geológicos con comportamiento más realísticos. Sin embargo, faltan más indicios de dicho estudio y algunos de los métodos de simulación geoestadística estándares existentes, fallan en proporcionar muchas de las relaciones espaciales geológicas. En este sentido, el presente texto señala la eficacia del método plurigaussiana, el cual proporciona una forma sensata de representar toda la información para inferir las distribuciones de las facies, así como la capacidad de reproducir imágenes respetando la información experimental y la proporción de las facies incluso si estas tienen un comportamiento no estacionario en un depósito de Nickel Laterítico localizado en Nueva Caledonia.

Oct 21, 2015

By Alexandre Bellegard Farina

O sistema MgO-NiO é um dos importantes sistemas para o entendimento das reações metal-escória na elaboração das ligas de à base níquel. As ligas à base de níquel usualmente apresentam adições de magnésio com o intuito de melhoria da plasticidade destas o que permite o seu processamento através de processos de conformação mecânica. Neste trabalho foi realizada a modelagem termodinâmica deste sistema utilizando o modelo de células de Kapoor-Frohberg-Gaye e o módulo PARROT® do pacote Thermo-Calc® com objetivo de complementar o banco de dados SLAG®. Como resultado foi obtido um conjunto de parâmetros termodinâmicos que descrevem as fases deste sistema.

Aug 17, 2017

By Larissa Rodrigues de Carvalho Rocha, Mauro Vivaldino Fernandes, Maurício Covcevich Bagatini, Beatriz Fausta Gandra, Adriano Cesar Carvalhido

O combustível com menor granulometria, denominado small, pode ser carregado juntamente com a carga metálica, em substituição ao coque, no intuito de melhorar as condições de permeabilidade do gás e a redutibilidade da carga no alto-forno. Na Usiminas, o equilíbrio na geração e no consumo desse material limita o seu uso em taxas abaixo da média nacional. Nesse sentido, foi avaliado o efeito do coque verde de petróleo (CVP) em substituição ao small coque no consumo de combustível e na estabilidade operacional do alto-forno. Os resultados do teste industrial indicaram a possibilidade de substituição até 45 kg/t gusa, com manutenção do fuel rate, da permeabilidade e da produtividade do alto-forno.

Oct 1, 2019

By Michael J. Beus, Stephen Iverson

BACKGROUND A mine shaft is the lifeline to underground mines. Mine operators depend on safe, uninterrupted, and efficient movement of workers and materials. The shaft and hoisting system provides access to the network of openings used to recover the underground resource, provides vertical transport of miners and materials, and serves as an escapeway in case of an emergency. Accidents involving hoisting can be catastrophic. Such was the case in 1973 at the Markham Colliery in Derbyshire, UK when the conveyance overwound and fell to the shaft bottom, resulting in 17 deaths. Hoist and elevator machinery must meet the requirements specified in the Code of Federal Regulations (CFR), Parts 57 and 75. According to the Mine Safety and Health Administration (MSHA) data, many shaft-related accidents in the United States are associated with the hoisting cycle. MSHA statistics show that there were about 1500 shaft- related accidents in the 5-year period between 1992-1996. Most of these accidents resulted from the action, motion, or failure of the hoisting equipment or mechanism and involved movement of the conveyance which includes cages, skips, ore buckets, and elevators. A hoisting hazard may be characterized as an "unsafe hoist operating condition caused by insufficient or inaccurate information available to the hoist operator" (authors' quote). Earlier investigators have defined safety features and operating and maintenance standards for hoists, and reported on monitoring and control systems and sensors for hoists and conveyances [Farley, 1983; Ward, 19931. However, despite the considerable technological progress and hoisting control improvements in recent years, safety- related issues that require further investigation still remain. The hoist operator must constantly be aware of two important hoist-operating conditions: the position of the conveyance and the tension in the hoist rope. If this information is not available or is inaccurate, the hoist becomes unsafe. Current technology provides this information indirectly from sensors and indicators in the hoist room. However, unlike a building elevator hoistway, mine shaft hoistway problems often include: 1. poor ground conditions and excessive shaft wall and guide displacement; 2. rock bursts in deep mines (resulting in large rock movements and fragments blocking the hoist way); 3. water, ice, and salt buildup (impeding the smooth flow of the conveyance); 4. severe vibration from hoisting (resulting in loose guide support brackets, broken welds, or other alignment and conveyance mechanism malfunctions). The second issue relates to dynamic rope loads applied during normal winding, particularly during loading, acceleration, and stopping. Safety factors on wire rope are based on static load. They are artificially high to account for all cases of dynamic loads, even though the total load history on the rope (static and dynamic) during service is unknown. Therefore the tension, and thus the compliance with wire rope load safety factors, is unknown to the hoistman.

By H. Ipek

Industrial grinding machines used in the mineral processing industries are mostly of the tumbling mill type. These mills exist in various types: ball, rod, pebble, autogenous, and semi-autogenous. Balls and rods are traditionally media shapes used in the tumbling mills. In resent years, as an alternative to balls, grinding charges with various shapes are being used. Cylpebs are slightly tapered cylindrical grinding charges with length equaling diameter, and all the edges being radiused. Cylpebs of equal diameter and length have 50% greater surface area and 45% greater weight than balls of the same material. In addition, they have 9% higher bulk density than steel balls, or 12% higher bulk density than cast balls. An important advantage of cylpebs over balls is that cylpebs produce narrower granulometric distribution due to their shapes. However, some discrepancies were found in the literature regarding the milling performance of cylpebs in comparison with balls (Chi, 2004). In recent studies, Chi (2004) has provided detailed information on cylpebs and has compared these to balls in relation to media mass, size distribution, surface area, and input specific energy. Ipek (2006) has investigated the effects of cylpebs and balls with equal mass and surface area on the breakage rate of quartz, using cylpebs and balls separately. Similarly, Lameck and Moys (2006) have investigated the effects of balls and worn balls on breakage rate of material using worn balls as grinding environment. However, no study has attempted to investigate the effects of grinding environment other than balls on the brekage distribution. As indicated by Prasher (1987), the breakage distribution function is independent of the following variables in ball mills: hold-up (Mika et al., 1967; Kelsall et al. 1969), mill speed and ball load (Herbst and Fuerstenau, 1972), media load and ball density (Kelsall et al., 1973), mill diameter (Malghan and Fuerstenau, 1976), and powder charge (Shoji et al. 1980). The aim of the present paper is to compare the effects of cylpebs and balls on the breakage distribution function of quartz with respect to same mass and same surface area. BACKGROUND Comminution as a rate process is called kinetic approach. Studies on the kinetic approach are reviewed by Oner (2001). Oner states that grinding kinetics are based on studies by Kolmogorov in 1941 and that Robert (1950) is the first to suggest this approach. Later, Melzak, Loeveday, and Reid have improved the grinding kinetics equation; and, Austin and Lynch have conducted two basic studies on the analytical solutions of these equations. Considering the results of studies comparing the size reduction mechanisms, it has been accepted that breakage constitutes of two operations. These two basic operations, first defined by Epstein (1948), are those of selection of material for breakage and the distribution of breakage material to particle sizes smaller than the initial size (Lynch, 1977). Epstein defined the two operations as: ? Pn(y), the probability of breakage of a particle size in the nth step of the breakage process. ? F(x,y), the cumulative distributions by weight of particles of size x<y arising from the breakage of a unit mass of a size y. Probability of breakage is called a selection or a breakage-rate function (Si). Characteristics size distribution after breakage is called a breakage distribution or appearance function (Bi,j). Due to the difficulties in representing particle size distributions mathematically and constantly, the batch equation based on particle size fraction is suggested. Thus, as is the case in breakage distribution and specific rate of breakage, the breakage parameters were defined by batch grinding experiments conducted in laboratories (Oner, 2001). When effective breakage occurs in the mill, the breakage of material with single feed size fraction usually fits first order grinding kinetics and the specific rate of breakage values can be calculated through the slope of semi-log plot. The values of the breakage distributions are deduced from the size distributions at short grinding times where there is mainly size 1 material breaking and only small amount of smaller sizes to rebreak (Austin et. al., 1984). B values can be calculated by using BII. [ ] where j is the top size of the charge, Pi(t) is the cumulative percent undersize of i th size interval at the short grinding time which gives no more than about 30% broken out of the top size interval. Cumulative primary breakage distribution, Bi,j, is also defined in an empirical form by [ ] where xi is the top size and Bi,j is the weight fraction of primary breakage products. The parameters F, ? and ß define the size distribution of the material being ground. On plotting size versus Bi,j on log scale, the slope of the lower portion of the curve gives the value of ?, the slope of the upper portion of the curve gives the value of ß, and F is the intercept as in Fig.1. [ ]

Jan 1, 2009

By S. A. Falconer

The benefication of non-sulfide or non-metallic minerals by froth flotation has been practiced commercially for at least 30 years. In the pioneer stages of development of this flotation art, most of the promoters investigated were fatty acids or soaps that had been found to float sulfide minerals. When commercial application of froth flotation started to assume importance in the late 1920&apos; s and 1930&apos;s, a great deal of fundamental research work was done in the laboratory (11-14, 19, 22, 23, 26, 29, 32). Among other subjects, this work included studies of the relative effectiveness of the different fatty acids and their salts on the flotability of various non-sulfide and non-metallic minerals. The successful present-day use of fatty acid and petroleum sulfonate type promoters results from better understanding of the principles of non-sulfide flotation plus the developnent of effective selectivity modifying agents. Many investigators have contributed to a greater appreciation of the numerous interrelated factors involved in fatty acid and soap flotation of non-sulfide minerals. Of these, mention should be made of recent fundamental studies by Tagart and Arbiter (31); Wolstenholme and Schulman (35); Schulman and Smith (28); Wark and his co-workers(3,4) Du FIietz(l5); and J. Leja(24). According to J. Rogers, K. L. Sutherland and E. E. and I. W. Wark(27), "the basic requirements for a &apos;collector&apos; in flotation are that it shall form a film over the surface of the mineral to be floated and that this film should be oriented so that hydrocarbon (non-polar) groups form the effective surface." When modified in that way, the mineral surface possesses some degree of air avidity. All investigators would agree with Taggart, Taylor and Ince (33)that such a film can be produced only if the collector compound contains an active (polar) group to be attracted to the mineral surface, as well as the non-polar group. The commonly used anionic-type promoters for non-sulfide, non-metallic and metallic oxide ores include: 1. Fatty acids, and their soaps and emulsions. 2. Fatty acids residues — "pitches" and "foots." 3. Sulfonated and sulfated fatty acids and so-called "petroleum sulfonates." 4. Paraffin chain salts — sulfonated and sulfated higher alcohols. 5. Cyclic organic acids or salts, such as naph-thenic acid and naphthenates. Certain fatty acids are more effective than others as promoters for particular minerals under certain specified conditions. Some of the more costly fatty acids or collectors of the paraffin chain salt type may give improved selectivity in some instances and are being used commercially in a limited number of operations. Local availability may dictate the choice of the fatty acid used — for example, the use of palmoil fatty acid for flotation of copper carbonate ores in the Belgian Congo. Coconut oil fatty acids have also found limited use.

Jan 1, 1961

By Robert Harris, Peter Pheeney

"The Murray Brook gold mine operated from September 1989 to March 1991. Approximately 1.2 million tonnes of gossan were mined from an open pit and treated at a rate of 900 tonnes per day. The facility applied an agglomeration vat-leaching cyanidation plant for gold and silver recovery. The leached ore or tailings were rinsed of residual gold and cyanide and placed on an adjacent clay lined pad for storage and containment. A 50,000 tonne heap-leach demonstration project was constructed at Murray Brook in 1992 to recover copper and zinc from ore located in a sulfide-rich zone occurring beneath the gossan. The operation proved unsuccessful because of poor recoveries and low metal prices. The project terminated in the same year.A corporate decision was made in September 1999 to undertake complete and final reclamation of the Murray Brook site. Jacques Whitford and Associates Limited were contracted to develop the final reclamation plan and to assist the company in presenting the plan to the New Brunswick government for approval. The government approved the plan in January 2000. Two important reclamation issues were the mobility of mercury from the gossan tailings and the potential of acid mine drainage from exposed sulfides. The mine site is situated upstream of a productive river system, and the issue or impact of chemistry changes to the environment over the long term became an overriding factor in the development of the reclamation plan.A resource assessment of the gossan tailings in 1999 indicated an average concentration of mercury of 40 ppm. The mercury occurred naturally as the mineral cinnabar, but the exposure to residual cyanide (less than 10 ppm) over several years in the pile has likely caused much of the cinnabar to decompose into more soluble mercury forms. The reclamation plan specified the replacement of all sulfides to the pit followed by approximately 600,000 tonnes of gossan. To ensure “fixing” of the mercury, the gossan was replaced in compacted lifts and both the remaining pile and that replaced to the pit covered with available till and compacted. The reclamation work was successfully completed in September 2000 and the chemistry of the receiving environment will be monitored over a three-year period, after which the company expects to achieve walk away conditions."

Jan 1, 2001

By Louis E. Dalverny

U.S. Bureau of Mines research to develop diagnostic methods to locate and evaluate fires in abandoned mines and waste banks and techniques to extinguish such fires was applied to an abandoned 60-acre underground bituminous coal mine (Renton, Allegheny County, PA) to locate and extinguish three separated fire zones. Mine fire diagnostics interpret changes from baseline values in subsurface pressures, temperatures, and mine gas composition under imposed pressure gradients induced by a borehole exhaust fan. The effective gas sampling area surrounding each borehole is greatly enlarged. Sampling iterations, using a "communicating" boreholes set, provide "fire signature" information for locating both heated and cold areas. Time-dependent monitoring differentiates heating and cooling periods resulting from combustion front movement and/or fire extinguishment activities. A water injection with fume exhaustion extinguishment effort involved injecting water through boreholes to quench the heated zones while exhaust fans actively removed heated gases from the mine. The technique was ineffective as implemented, primarily because of inadequate spreading of water from the injection points. The Bureau&apos;s diagnostic method determined the fire locations and the effectiveness of the water injection with fume exhaustion extinguishment technique.

Jan 1, 2010