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By G. Thodos, E. M. Phillips

A reduced density correlation for the gaseous and liquid regions of ethane has been developed from all the experimental PVT data available in the literature for this substance. Saturated vapor and liquid densities reported for methane, propane and n-butane were utilized to establish the rectilinear-diameter line for ethane. This line was then used with the saturated-vapor data for ethane to produce the saturated envelope for this substance. Most of the saturated liquid data reported for ethane were found to be inconsistent with the saturated-liquid curve resulting from this study. The correlation covers the regions 0.65 < TR <6.0 and 0 < PR < 15. For regions for which no experimental data have been reported, the isobars of the correlation were extended by the use of the theorem of corresponding states. This correlation is presented both on rectilinear and log-log coordinates. INTRODUCTION At the present time, there is considerable interest in the exact PVT behavior of pure hydrocarbons. Matschke and Thodos12 recently have developed a comprehensive compilation of experimental vapor and liquid density data for methane. Similar studies have been conducted for other pure substances.4, 7 In the present study the density data available in the literature for gaseous and liquid ethane have been critically reviewed and utilized to develop a reduced density correlation for this substance. SATURATED LIQUID AND VAPOR DENSITIES The rectilinear-diameter rule proposed by Cailletet and Mathias5 states that the sum of the saturated liquid and vapor densities of a pure substance is a linear function of temperature which passes through the critical point. This law, although empirical, has been well established by continued verification since its conception in 1886. This rule has been applied to the saturated density data of methane,6 propane 17 and n-butane8 to produce the straight lines presented in Fig. 1 which pass through the critical point TR = 1.00, Pr = 2.00. The rectilinear-diameter relationship for ethane was established from the lines for the other substances in Fig. 1 by plotting the quantity p~, + PR against zc for different reduced temperatures. A critical analysis of the saturated vapor and liquid densities reported for ethane by Kuenen,10 Maass and McIntosh,11 and Sage, Webster and Lacey18 revealed that the values of PR1 + pr resulting from these studies were inconsistent with the rectilinear-diameter line obtained from the reliable density data of the other substances, as shown in Fig. 1. In the analysis of these data, reduced quantities were calculated using the critical con-

By Sanna Mustonen, Seppo Mellanen, Mellanen, Pekka Kantia

In Finland Posiva Oy (Company) is responsible for implementing the final disposal programme for spent nuclear fuel of its owners. Company is preparing for the geological disposal in Olkiluoto crystalline bedrock. Excavation will be executed using drill and blast method. Method unavoidably causes variable excavation damaged zone (EDZ) on tunnel surfaces. The EDZ constitutes a risk for long term safety and therefore good control methodology of the blasting technique is required. The thicker the EDZ, the greater is the likelihood for detrimental transport pathways for ground water to transport radio nuclides, should those be present.

Jan 1, 2016

By Mike Ghassemi

It is clear that precise overground and under-ground mapping is an important factor for all designers. Due to rapid changes in underground construction, tunnel designers are increasingly in need of updating project information. This article explains the latest techniques for detecting under-ground utilities as well as underground mapping. Global Positioning System (GPS) is a very ac-curate and popular navigation and mapping system that has been used extensively above ground, but is not used for underground mapping as signals are not strong enough to pass through ground or water. Most underground techniques were developed for military applications during the first and second world wars. Later, the techniques became public. For example, ground penetrating radar was developed for the military in 1970 to be used for locating tunnels under the demilitarized zone between North and South Korea. Later, the same technique was used for detecting unexploded ordinance such as plastic land mines.

Jan 1, 2011

Biologically-mediated phenomena are involved in many of the natural processes by which mineral deposits are formed and ore bodies transformed and degraded. They may facilitate the environmentally-damaging effects of mining and mineral-processing operat- ions. Under contrived and controlled conditions, however, these phenomena can form the basis for economically- attractive processes for the recovery of metals from low-grade deposits by dump, heap or in situ leaching. They have application also in processes for the regeneration of leaching reagents and some potential for&apos;-the recovery of metals from dilute solution. The micro- organisms concerned are potential sources for the production of novel flotation and solvent-extraction reag- ents. Perhaps the greatest opportunity for biotechnological processes in min- ing and metallurgy lies in the possib- ility of the evolving of novel proced- ures for the substantially complete recovery of metals from process tail- ings by the unlocking of recalcitrant and complex mineral assemblages, and for the beneficiation of some mineral materi,hls.

Jan 1, 1982

By D. P. Power

The development of an accounting code for the metallurgical industry has been debated for many years. Following the series of tumultuous economic events in the nineties and earlier this century that have affected business, there was much need for legislation to be passed to minimize potential risk. One of the consequences to affect the mining industry was the enhancement of existing geological codes for reporting. In parallel the sponsors of AMIRA have taken the brave step to develop a generic code for metal accounting that embraces the full gamut of industry. In this paper the code will be reviewed in the context of metallurgical accounting as it applies to coal preparation. This paper provides the background for this development and an insight into the mechanism for the debate for the generation of this code. The key elements of the code as it applies to the coal industry are explained but most importantly the key opportunities are highlighted.

Jan 1, 2010

By G. Noce

The ever more present necessity for greater precision in foundation structures on vertical piles subject to horizontal forces applied to the heads, in the light of of the latest knowledge about the elastic-plastic behaviour of the soil has led to the use of numerical calculation for the formulation of a general resolution method for the problem. The calculation method that will be set out, applicable to piles with inertia moments variable discreetly along their axes is especially useful when studying steel structures for medium and large tonnage vessels for which the metal piles are often constructed for the assembly of section of equal external diameter but different thickness and therefore different inertia moments. Two examples are given of constructions whose foundations have been projected with these calculation tools, one in the railway sector (foundation pile for the river Nera viaduct - Italy) important for the limitation of horizontal relative deck displacement, the other maritime (Dolphins of the petroleum pier of the port of Bandar Abbas - Iran).

Jan 1, 1989

By Halvor Dalaker, Pål Tetlie

The decomposition of methane has been studied experimentally in contact with various oxides at elevated temperatures. For each oxide, the temperature at which the cracking starts has been determined. No correlation was found to exist between the temperature for the onset of cracking for a given oxide and the affinity for carbon of the oxide's metallic component. In terms of potential for using methane as a reducing agent, calculations are presented that indicate that the suitability of an oxide for such reduction depends on the desired methane+oxide reaction being more energetically favourable than the methane+methane=ethylene/acetylene reactions.

Jan 1, 2014

By Ken Schei, Martin Reed, Samuel Bowser, John Wright

From October 18 through October 21, 2001, United States Antarctic Program blasters opened ten access holes for research divers in 11-ft. thick sea ice at Explorers Cove, McMurdo Sound, Antarctica. During this project, a blasting seismograph with a hydrophone accessory was used to monitor the underwater shock waves associated with the blasting technique. Shock wave values averaged 42.3 psi for initial (cratering) shots and 5.9 for subsequent clearing shots, indicating that the ice absorbs most of the shock wave. The results also provide data for refining safety protocols for divers and for the protection of marine biota.

Jan 1, 2003

By F. Milton Lewis, Roshan B. Bhappu

The methods for preparing operating cost estimates for a proposed mining venture are outlined. The procedures for estimating the direct and indirect operating cost for proposed mining and ore processing facilities are reviewed. Profits from the by-products are credits to the total operating cost, direct plus indirect, and are subtracted to obtain the total net operating cost. The non-operating costs which are a part of the total expenses are defined but are not considered in this manuscript. A method for developing the operating cost for a typical copper concentrator in the southwest is described in detail.

Jan 1, 1978

By Raimo Vuolio

"Over the past 30 years, the Nordic countries have developed similar practices for estimating damage caused by rock blasting vibrations. However, over the last few years the risk of damage has sometimes been estimated by using international values, which have created unnecessary costs, since they are too conservative. This paper gives a proposal for Finnish blast vibration standards and a calculation model for the extent of the zones for building inspection, risk analysis, and vibration measurements. The international conclusion is that particle velocity is the best descriptor for limiting damage potential for structures. Over 900 000 vibration data recordings from 52971 blasts were collected for this paper during 1970-1989. They show that the most practical description is the vertical component of the peak particle velocity. As rock is a nonhomogeneous medium, it is hard to predict the need and scope of risk analyses, building inspection, and vibration measurements. As a large number of blasts were monitored for the recording of the peak particle velocity in several locations in Finland, and the data combined, it is possible to establish safe scaled distances for the calculation of the need and scope of risk analyses, building inspections, and vibration measurements."

Jan 1, 1991

By Stephen W. Kline

Rock suitable for crushed-stone aggregate is almost entirely restricted to the Highlands region of Arkansas, mostly from Paleozoic sedimentary units, but also from a few Cretaceous igneous plutons. Reserves in the state are sufficient for local needs, and Arkansas is geographically well situated for export markets to the south, where resources for crushed-stone aggregate are lacking. A study of 423 quarries, test pits, and exploration sites in Arkansas has been completed to evaluate the relative quality of bedrock units for producing crushed aggregate. Of these, 274 sites have records of engineering tests for stone evaluation done by the U.S. Army Corps of Engineers and/or the Arkansas State Highway and Transportation Department (AHTD). Of the 1,775 sample records from these sites, the most commonly reported parameters are the LA abrasion test and the Na-sulfate soundness test. Many records also have absorption and specific-gravity data, and, for some, petrographic information helps identify the potential for alkali-silica reactivity in portland-cement concrete. By determining the bedrock sources of the tested samples, comparison is made between the various geologic mapping units as to their relative quality for crushed stone.

Jan 1, 1999

By John M. Karpinski, David S. Cahn

A new device based on a constant rate of loading has been developed for the compression testing of green and dry pellets. This device has a lower test variation for green pellets than the existing constant deformation rate tester. While the test variations for dry pellets are similar for both types of machine, the new tester is sensitive enough to measure dry pellet deformations of 15 µ in. for cyclic loading studies. In the study discussed here, the compressive load at which a pellet breaks proved to be a normally distributed random variable, and the load-deformation relationship was found to be linear for dry pellets but not for green pellets. The paper emphasizes the need for a standardized test procedure throughout the industry. For many years the green and dry compressive strengths of pellets have been considered as possible criteria of pellet performance during induration. Little attention, however, has been given to standardizing the unfired pellet compressive strength test or to determining the characteristics of this test. The purpose of this study was to compare the constant deformation rate test with constant loading rate

Jan 1, 1969

Papers presented at a U.S. Bureau of Mines (USBM) technology transfer seminar describe the causes of violent material failure in U.S. mines, measurement techniques for monitoring events that result in violent failure, and mitigation techniques for controlling failure. Specific factors contributing to violent failure are identified on the basis of geotechnical monitoring in 16 U.S. hard-rock and coal mines and on statistical analyses of 172 coal bump events. New monitoring and analysis techniques developed as tools for assessing violent failure; geotomographic methods that provide new capabilities for the study of material failure and stress changes over large areas; and seismic methods for determining source locations, calculating energy release, and determining source mechanisms are described. Fair correlations have been established among seismic parameters, elastic stresses, face support load, and violent events. USBM studies have identified the advantages using both yielding and stable pillars for coal bump control. A computer program has been developed as an aid for selecting room-and-pillar layouts. The practical aspects of implementing a destressing program is outlined for coal mines, while the importance of mine orientation and timely support installation in controlling buckling-type failure is identified for hard-rock mines.

Jan 1, 1995

By B. J. Barfield

Standard erosion plots (4.6 m by 22.1 m on 9 percent slope) were constructed on the Alston Surface Mine of Peabody Coal Company in Western Kentucky to evaluate the effects of placement technique and density on the erodibility and eroded size distribution from mine spoil and reconstructed topsoil. PLots were constructed with a dozer and scraper pan from shale spoil material, topsoil (A horizon) and subsoil (B and C horizon mixture) using soils stockpiled at the Alston Surface Mine. Plots were evaluated under fallow conditions with a tilled plot surface and two compacted conditions. One compacted condition was generated by tracking the surface with a dozer and rolling with a loaded scraper pan. The second was generated by rolling the surface with a solid wheel compactor. Rainfall was supplied with the Kentucky Rainfall Simulator at a rate of 63.5 mm h-l with the plots in three different soil moisture conditions; dry, field capacity, and very wet. Runoff was evaluated for flow rates, sediment concentrations, and aggregate and primary particle size distributions. Sediment yields and the Universal Soil Loss Equation E130 indexes were calculated from the data for each plot. The erodibility was calculated from the tilled plot data using a weighted soil loss and E130 value from the dry, field capacity and wet runs, and a cover management factor calculated for every other condition. For the topsoil and subsoil plots, sediment yield was greatest for the dozer scraper pan plots and lowest for the tilled plots. For the shale plots, erosion rates from the wheeled compacter plots were the highest and tilled plots the lowest. Average erodibilities were 0.14, 0.38, and 0.41 tons ac h ft-1 tonf-1 in-1 hundred ac-1 for the shale, subsoil, and top-soil plots. Cover management factors for each plot were 1.29, 1.42, and 1.17 for shale, topsoil and subsoil plots compacted with the solid wheeled compacter and 1.29, 3.79, and 2.51 for shale, subsoil, and topsoil plots compacted with the dozer scraper pan conbination. The accuracy of the Wischmeier erodibility nomograph was evaluated on the data collected. Erodibilities were accurately predicted for the topsoil plot and poorly predicted for the sub-soil plot. The accuracy of the CREAMS procedures for predicting the composition (size distribution) of eroded particles was also evaluated. The composition was well predicted for the topsoil plots, moderately well predicted for the shale plots and poorly predicted for the subsoil plots.

Jan 1, 1983

By Charles D. Sutton

Safety is an important part of the everyday activity for the explosives industry. The overall accident experience has not been adverse, however, many insurance companies have eliminated coverage for explosive related activities. The Nobel Insurance Group has responded to this insurance problem for our explosives customers. It is vital that safety efforts continue for all aspects of the business. The continuation of insurance policies for explosives, clearly depends on safety.

Jan 1, 1987

By Bruce Haldeman

Timber has been used as pile support for structures for 6,000 years. Some means of preservation of wood go back almost that far. Timber piles support all types of structures ? some are buried below the water table; others raise a home for protection from animals or a chief&apos;s home for prestige. Millions of wood piles have been driven for bridge support. Earlier piles were driven by hand then by ingeniously raised weights. Charring, animal fats and oils have been used for preservation. Coal tar creosote and other preservative methods started only in the early 1800&apos;s and give effective protection.

Jan 1, 1984

By Raja V. Ramani, Wilson Miola

The potential health effects of quartz-bearing airborne dust in mine and mill atmospheres point to the need for the quantification of quartz content in the source material for determining the source-sink relationships and for choosing applicable control measures. While a standard method exists from a regulatory point of view for the sampling of coal mine atmospheres for determining (i) respirable dust concentrations and (i) the amount of quartz in thesamples, there is no generally accepted standard method for quartz analysis in bulk samples of coal and host rocks. Generally, the bulk sample is reduced to a powder for producing quartz analysis samples. Extensive controls are necessary to ensure representativeness of the analysis samples when these are very minute fractions of the bulk samples. Since the amount of analysis sample is not limited, alternative methods for quartz analysis may also be tried. It is, however, necessary to adopt a procedure which will satisfy several statistical requirements to guarantee representativeness of the quartz analysis samples. In this paper, the important factors in the preparation of quartz analysis samples from the host rocks and bulk samples are discussed. The method developed to prepare the analysis samples is outlined. The results of application of the procedures are presented. The procedure developed for quartz analysis sample preparation is based on sound statistical foundations. The procedure has been validated for reproducibility and homogeneity.

Jan 1, 1991

By V. Steinbach

Non-renewable mineral raw materials are grouped into three categories to investigate ways leading to sustainable use of natural resources: 1.) metallic resources, 2.) non-metallic resources with the exception of the fertilizer minerals, and 3) the fertilizer minerals for the nutrients nitrogen (N), potassium (K), and phosphorous (P). With the exception of minerals in Group 3 which are essential for plant growth, mankind does not need raw materials as such, only the intrinsic property of a material that fulfils a useful function. This is especially true for non-metallic materials. Metallic resources have the best chance to become renewable if one makes optimal use of the resources of the man-made technosphere. For the fertilizer elements K and N there does not exist a problem, because sea water or air respectively provide an inexhaustible source for them. This does not apply to P however. So P is serving as one of our apposite case studies for solving sustainability challenges. For all the challenges along the road from a non-sustainable to a sustainable resource economy technology can be envisioned to come to the rescue provided conditions that are considered to be essential for sustainable use for all natural resources-- affordable renewable energy and human ingenuity to find new solutions for functions, to optimize processes and to minimize losses-- are satisfied.

Jan 1, 2011

By L. B. Pankratz

The Bureau of Mines measured heat capacities of alpha and beta spodumene (LiAlSi2O5) and of beta eucryptite (LiAlSiO4) over the temperature range 51° to 298° K. The entropies at 298° K were found to be 30.9 ± 0.2 cal/deg mole for alpha spodumene, 36.9 ± 0.3 cal/deg mole for beta spodumene, and 24.8±0.2 cal/deg mole for beta eucryptite. High-temperature heat content measurements above 298° K were conducted for the same compounds. Measurements were made to 1,150° K for alpha spodumene, 1,600° K for beta spodumene, and 1,470° K for beta eucryptite. Tables of heats and free energies of formation are given from the elements and from the constituent oxides.

Jan 1, 1967

By Jeffrey W. Nelson

Predictions of creep closure for periods ranging up to more than 1,000 years are needed for designing a radioactive waste repository in a salt formation. Such long-term predictions must be based on the use of laboratory and field test results extrapolated by numerical modeling. Laboratory test results are presented which show highly variable creep behavior for salts from different sites as well as salts from the same site. Comparisons of measured creep closures against predicted closures are presented for two deep boreholes in Louisiana salt domes and for an exploratory shaft and drift in southeastern New Mexico bedded salt (WIPP). These data illustrate the significant uncertainties involved in long-term closure predictions and indicate the critical need for site-specific, in situ closure measurements over extended periods of time for repository design.

Jan 1, 1984