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By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

Ground-water and tailings pond monitoring in the Upper Santa Cruz Basin Mines Task Force's Special Studies Area has been performed to determine the nature and extent of aquifer contamination from copper tailings pond's recharge in the basin. A monitoring program for each of three mining areas (Mines A, B, and D) was developed. Analysis of data shows that recharge from Mine A's ponds has caused increased hardness, sulfate and total dissolved solids in local ground water. However, pumpage in the area has controlled most of the water's movement. Pond recharge from Mine B has led to similar conditions, and the degraded water is moving towards a local public-supply well. Pumpage from Mine D's interceptor wells is controlling some, but not all, of the movement of recharge seepage from Mine D's ponds. Recommendations include the need for enhanced monitoring programs at each current mine site, development of a monitoring program for Mine C's area, development of water budgets for all mines, investigation of tailings pond compaction and sliming, establishment of mine closure plans for containment of recharged pond water, and the need for additional interceptor wells in several locations.

Jan 1, 1983

By V. I. Lakshmanan

Recycling helps to save energy and is good for the environment. It is also important for preserving the limited natural resources. In addition, recycling creates economic benefits and frees up space at the landfill sites. Process Research Ortech Inc. (PRO) has conducted extensive testwork in the area of waste processing and recycling. A process was developed for the recovery of Zinc from galvanized steel by alkaline leaching followed by solvent extraction and electrowinning. Extensive testwork has been conducted at PRO to obtain a useful by-product from rice husk. Rice husk was combusted in a gas/solid reactor to obtain an environmentally acceptable amorphous silica ash suitable for use in high strength concrete. In another development, vanadium was recovered from fly ash by separating carbon first, followed by alkaline pressure leaching, solvent extraction and precipitation. PRO has also developed an environment friendly process for treatment of industrial wastewater for its reuse to obtain zero or minimal effluent discharge. In this paper, four case studies related to recycling of zinc scrap, controlled combustion of rice husk, processing of fly ash, and reuse of waste water will be discussed.

Jan 1, 2011

By Marco Antonio Meggiolaro

Notches are preferential sites for fatigue and for environmentally assisted cracking (EAC) initiation. Semi-empirical notch sensitivity factors have been used for a long time to quantify notch effects on fatigue design. Recently, this concept has been mechanically modeled using techniques which properly consider the notch tip stress gradient influence on the fatigue behavior of mechanically short cracks. This model properly calculates such values from the basic fatigue resistances of the material, its fatigue limit and crack growth threshold, considering the characteristics of the notch geometry and of the loading, without the need for any adjustable parameter. Such criteria to estimate notch sensitivity and tolerable short cracks on fatigue have been extended to EAC conditions and verified by proper tests. In its simplest version, the criterion for the maximum tolerable stress under EAC conditions uses the resistances to crack initiation and to large crack propagation and the characteristic short crack size under EAC, considering the crack size and stress intensity factor. Moreover, the tolerance to short cracks under fatigue and under EAC conditions can be unified in an extended Kitagawa-Takahashi diagram, a new and potentially very useful tool for material selection tasks.

Aug 8, 2018

By Murad Y. Abu-Farsakh, Md Habibur Rahman

The properties of all natural soil deposits are highly variable, and they are rarely homogeneous. Cone penetration tests (CPT) were used to assess the site variability, which was then incorporated into the Load and Resistance Factor Design (LRFD) of pile foundations. Data from six project sites with multiple CPT tests conducted at various locations were collected for this research. The semi-variogram was used to assess the spatial variability of CPT data (corrected tip resistance, qt) for each location. For each location, the coefficient of variation due to spatial variability (COVR,spatial) was calculated. From COVR,spatial and COVR,method, the total coefficient of variation (COVR,total) for each site was calculated, which was then used to calibrate the resistance factors (ϕspatial, ϕtotal) for use in LRFD pile foundation design. The findings of this study demonstrated the importance of using site variability in LRFD pile design. For sites with lower site variability than the design method (i.e., COVR, spatial < COVR, method), the value of the COVR, total will be decreased, and hence the resistance factors (ϕspatial or ϕtotal) will be increased (credit), and vice versa.

Sep 8, 2021

By A Huebner, A Noack

Companies all over the world are very sensitive concerning their IT and network security. In most network connected technical installations and machines however, network security is not taken into account to a significant extent: insecure protocols are run, unencrypted information is exchanged freely and even broadcasted wirelessly and networked machines are accessible via insecure file transfer protocol (FTP).What happens in case of malfunctions of such technical installations? Who is responsible? Who can be held liable in case of accidents? The first computer worm for automation systems (æSTUXNETÆ) (Symantec, 2010) was discovered during 2010.The paper is intended to create sensitivity among decision makers for potential security and resulting safety leaks and points out the current status quo in technical network security. It outlines best practices for secure networking and procedures for remote access and remote software updates on stationary equipment and mobile mining machinery. It describes how to ensure authentic and genuine configurations and software targets and how to ensure secure communication for autonomous and remote controlled equipment. For such equipment in particular, the following statement should apply: æThere is no safety without network securityÆ.

Sep 26, 2011

The primary (sulphide) resources at Aphrodite are refractory in nature, requiring an oxidation process stage to be introduced to facilitate extraction of the gold. The company is investigating the use of pressure oxidation (POX) as the oxidation method for processing of high grade gold bearing concentrate it plans to produce at Aphrodite. POX has been used extensively around the world for the past 30 years and continues to be the favoured option for a number of refractory gold plants currently in the design and construction stages. Initial pressure oxidisation testing investigated the effect of temperature, pressure and grind size on a bulk flotation concentrate prepared from Alpha lode material. The concentrate averaged 47.3 g/t gold and was prepared from a composite of core samples averaging 1.49 g/t gold. Sub-samples of the concentrate were subjected to POX for 1 hour resulting in rapid oxidation during this very short period. Testing undertaken showed that there was a significant increase in sulphide oxidisation at higher temperature (220°C) and pressure (2,500 k/Pa) for the two grind sizes (75 and 20 microns) evaluated. The proposed flowsheet, OPEX and CAPEX are critical aspects for project development.

Jan 1, 2014

By R. Pandey, G. Elie, E. Sarver

Respirable crystalline silica (RCS) is generally considered the most hazardous constituent of coal mine dust, and a new federal rule is expected to further limit exposures in U.S. mines. For regulatory purposes, RCS is monitored by collecting filter samples, which are analyzed for quartz (the predominant form of RCS in coal mines). The analysis is done using Fourier transform infrared spectroscopy (FTIR) in a centralized laboratory. To enable more timely results, National Institute for Occupational Safety and Health (NIOSH) mining researchers developed a directon- filter (DOF) FTIR analysis method and free FAST software that can be used in the field. For samples collected under specific conditions, FAST processes the FTIR spectral data to determine quartz mass. While the DOF FTIR method is not approved for regulatory RCS monitoring, it could be useful for engineering purposes, such as to evaluate mining parameters or new dust controls. This field study demonstrates how the method, including FAST, can be applied using low-cost, widely available sampling components. It further demonstrates how quartz percentage can be estimated in the field, by pairing a continuous personal dust monitor with a filter sampler.

Jun 1, 2025

By M-E Boucher

While the haematite concentrates produced in Eastern Canada and the magnetite concentrates that Australia will soon be producing are different feed materials, the pellets they produce have similar physical and metallurgical properties. This paper will examine the similarities and differences in the evolution of pellet microstructure for pellets produced from magnetite and haematite. The molten slag phase generated at high temperatures has a lower melting point when in contact with magnetite compared with haematite due to the higher divalent iron content. The presence of some slag is beneficial for bonding but too much can inhibit oxidation of magnetite, although slag generation at lower temperatures reduces energy usage. In pellets produced from haematite, magnetite is generated artificially from the combustion of the carbon particles added to the pellet feed as a source of energy. Maintaining the optimum production level and mineralogy of such æsecondaryÆ magnetite, allowing for its subsequent reoxidation, is important for the quality of haematite pellets. In both magnetite and haematite pellets, balancing the slag formation and oxidation (re-oxidation for haematite pellets) of the magnetite (secondary magnetite for haematite pellets) is necessary.

Jan 1, 2007

By AIME AIME

As already announced in the January Bulletin, this publication will be issued during the coming year monthly instead of bi-monthly as heretofore. Among other reasons for this change, it is desired to effect thereby the earlier transmission to members of important papers, lists of candidates for membership, and other items of timely information. Spokane Meeting and Excursions. Further details of the&apos; 97th meeting of the Institute have been sent to members in the Circular of May 8, 1909. For, convenience of the members a summary of the additional in¬formation is here presented. A special train of Pullman cars will leave Chicago about September 15. This train will be side-tracked at all places visited, and the sleepers will be available for lodging and the dining-car for meals during the entire trip, except during the Yellowstone Park tour. The general. cost of the trip per member will be $300, which includes transportation, berth, and meals for the entire trip from Chicago back to Chicago, almost 6,000 miles, and the tour through Yellowstone Park, occupying in all about 30 days. Special accommodations on the train will be furnished at the following, rates

May 1, 1909

In order to realise seafloor massive sulfide (SMS) mining, the environmental baseline survey around targeted SMS mining areas and the creation of an environmental assessment technique suitable for quantifying the impacts of ocean floor mining are necessary. The targeted areas generally host large chemosynthetic communities in association with active hydrothermal venting. The ecosystem structure around the chemosynthetic communities has not been clarified yet in macro-scale or quantitatively. The systematic approach and plan for the baseline survey and the environmental assessmentÆs basic studies are introduced. An&nbsp;EXTENDED ABSTRACT&nbsp;is available for download. A full-length paper was not&nbsp;prepared for this presentation.

Jan 1, 2008

By H. Skretting, J. Gundeesen

The paper compares operational parameters for the electric reduction smelting of pig iron and ferroalloys in pilot and industrial furnaces. Data from two pilot furnaces of approximately 200 and 500 kW operating-load capacity, as well as from several production furnaces, are included. Examples are given for the smelting of pig iron, ferronickel, ferromanganese, ferrochromium, and ferrosilicon. In most instances, the results from the pilot furnaces, such as the values for consumption and product analyses, corresponded fairly well with comparable data from the industrial furnaces. For ferrosilicon, the power consumption in the pilot furnace was higher than that in the industrial furnace.

Jan 1, 1979

By L. Woollacott, R. P. King

Although several models for the carbon-in-pulp (CIP) or carbon-in-leach (CIL) processes have been published, most of these models do not consider in detail the way in which the carbon phase flows on large-scale plants. This paper illustrates the importance of these details if the CIP or CIL process is to be modeled correctly. An appropriate model, based on population-balance techniques, is then derived. Suitable mathematical techniques for the solution of the model equations are also described. Finally, a method for estimating the model parameters for a full-scale plant is described.

Jan 1, 1990

* A loan, perhaps as great as $100 million, from American insurance companies is about negotiated for development of Labrador iron ore properties. The program will call for a total expenditure of up to $200 million, including, as well as all mine development work, the power facilities, housing for mining personnel, and auxiliary equipment. * Mobile air compressors and a water tank, mounted on a 30-ton rubber-tired trailer and towed right up to the drilling crews, eliminates the need for expensive underground water and air pipe lines in the experimental oil shale mine operated by the Bureau of Mines near Rifle, Colo.

Jan 11, 1950

By W. H. Craig

Techniques have been developed for installing model piles into beds of soil under high sustained acceleration levels aboard a centrifuge. These piles have been subjected to static and/or cyclic lateral loading in order to assess their performance and provide a data base for assessment of various design techniques for laterally-loaded single piles. From measured bending moment profiles the so-called &apos;p-y&apos; curves have been deduced using fifth order splines for curve fitting, followed by subsequent differentiation and integration. The results show some divergence from the predictions of the semi-empirical designs, but these latter are generally found to be acceptable.

Jan 1, 2010

By Stuart A. Bengson

It is extremely difficult to revegetate disturbed sites and mineral wastes in an arid environment because of sporadic and undependable rainfall. Thus, irrigation is often a must for starting seed germination and vegetation. Quite aside from the harsh climate, mining disturbances by themselves cause various adverse conditions for a revegetation program. The problems of revegetating a harsh soil, for instance, are often compounded by the steep slopes of mine wastes. Since these steep slopes intensify the droughty conditions by rapidly draining away soil moisture and accelerating runoff, supplemental irrigation may be the only solution for establishing vegetative cover on the slope.

Jan 8, 1976

TENDENCIES toward nationalization grew noticeably stronger in some areas. Late last fall Bolivia took over the tin mines of four foreign operators and handed them a bill for a fabulous amount claimed for damages. In the same breath, the price Bolivia offered to pay for the mines appeared to many to be slightly ridiculous. Many engineers felt that the country would not be able to run the mines successfully. Even if they could, some thought that the Bolivian Government would gut the orebodies in an attempt to get at rich deposits for high profits, leaving the lean ores in unmineable condition.

Jan 2, 1953

By E. Northcott, F. N. Oberg

High-grade concentrates from Florida pebble phosphate deposits have long been recovered by wet methods. When work was begun in the field, only the coarse pebble (generally +1 mm) was recovered. In the 1920&apos;s a froth flotation process was developed to separate quartz from the finer phosphate fractions, but this method proved unsatisfactory for treating the intermediate fraction (-1 mm +35 mesh). Consequently various other processes were adapted, including agglomerate tabling and spiral separation of reagentized feed. Today the three processes are used-washing and screening for coarse pebble, tabling or spiraling for intermediate sizes, and flotation for -35 mesh material.

Jan 10, 1958

By E. G. King

Low-temperature heat capacity determinations of the minerals goethite and pyrophyllite were made in the temperature range from 510 to 298° K. The entropies at 298.15° K were evaluated as 14.43 ±0.15 cal/deg mole for goethite and 56.6 ±0.5 cal/deg mole for pyrophyllite. The entropies of formation from the constituent oxides are -4.4 ±0.2 cal/deg mole for goethite and -12.3 ±0.6 cal/deg mole for pyrophyllite. The standard free energy of formation of goethite from its oxides is ?G°298.15 = 0.16 ±0.20 kcal/mole.

Jan 1, 1970

By D. Duffey, P. F. Wiggins, F. E. Senftle

An examination of the neutron capture gamma ray method using a 252CF neutron source indicates that this technique may be feasible for process stream analysis of ores. Simulated laboratory experiments were made on iron in taconite and magnetite, and copper and nickel in their respective ores. Satisfactory analyses were obtained for 500-1000-g samples in a combined irradiation and counting time of 100 min. For large industrial size samples this time could be shortened. Based on these experiments, a set of guidelines are given for the use of the neutron capture gamma method in an industrial mill.

Jan 1, 1974