Search Documents

By G. J. Kipouros, W. Judge

"The prevalent metal extraction processes for most reactive metals are fused salt electrolysis and metallothermic reduction. The feed material for both of these processes is the anhydrous chloride of the metal under consideration. Dehydration of the feed material is then a critical step in the production of most reactive metals and requires rigorous thermodynamic analysis. Thermodynamic data for most of the reactive metal chloride hydrates have not been measured. Improper dehydration of the metal chloride may lead to a prohibitive amount of hydroxychloride, oxychloride, and oxide. To prevent hydrolysis a certain pressure of hydrogen chloride is required. An estimation and prediction model is presented for the vapour pressures of reactive metal chloride hydrates in an attempt to deduce the conditions necessary for dehydration to proceed without hydrolysis. Thermodynamic data including heat capacities, standard entropies, and standard enthalpies are estimated/predicted for all conceivable intermediate hydrate compounds. Estimations are based on published data as well as trends proven in similar systems. The thermodynamic estimations and predictions are presented for the magnesium, neodymium, praseodymium, and dysprosium chloride hydrates. INTRODUCTIONThe high reactivity of metals such as the alkalis, alkaline earths, and lanthanides prevents their reduction by traditional pyro- or hydrometallurgy. In their elemental form, these metals are raw materials in the manufacture of intermediate products such as alloys and electronic components. Currently the only two viable metal production methods are fused salt electrolysis and metallothermic reduction. Various feed materials have been proposed for these processes. Using the chloride of the metal as a feed material offers advantages in separation and purity of the final product, as well as lower energy input. Chlorides, however, are hygroscopic and must be dehydrated before use. Improper dehydration will lead to a prohibitive amount of oxychloride which will lower efficiencies and contaminate the final product.Optimum conditions for proper dehydration of MgCl2•6H2O to produce pure MgCl2 without hydrolysis have been calculated from existent thermodynamic data and have been reported previously (Kipouros, 1987; 2001). Calculations were also performed for the case of production of pure anhydrous NdCl3 from NdCl3•6H2O (Roy, 1997)] and the mechanism of dehydration was elucidated. Some thermodynamic studies on the dehydration of chlorides of the rare earths have also been conducted (Sundstrom, 1997; Hong, 1997; Aschcroft, 1968; Haeseler, 1965; Ukraintseya, 1989)."

Jan 1, 2012

By BUREAU OF MINES

The approval of the U. S. Bureau of Mines when granted to a manufacturer for a gas mask is a certification that the particular device has been submitted to the Bureau of Mines for inspection and test and has been found to meet that bureau's published minimum requirements for safety , durability , and satisfactory performance . Any de- Gas masks are approved by the Bureau of Mines only as a complete unit or assembly of parts , as canister , facepiece and harness . This is in order that responsibility for rigid adherence to the bureau's requirements may be definitely located and not divided . vice marketed under this approval must be a unit composed of parts identical in detail of design , assembly , workmanship , and quality , and produced under the same control and inspection as the original device to which approval has been granted . The particular parts which comprise the approved assembly are designated in a letter to the manufacturer at the time the approval is granted . In recent years they are also specified in the approval plate authorized for use in connection with the sale of the device . Each part permitted in the assembly is legibly marked by name or number for the guidance of users of masks in ordering and identifying approved parts when making repairs , and thereby maintaining their equipment as an approved device . In view of the foregoing , any change in the design of parts or deviation from the permitted assembly of parts would violate the conditions under which approval was granted and the device would not be considered as meeting the approval requirements of the Bureau of Mines . The U. S. Bureau of Mines has been frequently requested to interpret the approval status of a gas mask assembled from parts which have separately met its requirements as components of two or more approved devices but which in the form of a complete unit has not been submitted for tests or been granted approval . Responsibility for the elements and for their proper assembly is in such case divided . Such assembled units have no status as permissible equipment under the Bureau of Mines system of schedules . The reasons underlying this policy are that the approval is granted only to some one who assumes responsibility for the whole and that the details of assembly and coordination of parts are considered to be important to the satisfactory performance and safety of the device .

Sep 1, 1932

By W. W. Adams

The extent to which coal mines have installed various types of haulage systems and mining machines is a subject about which there is little definite information available in convenient form for the country as a whole . A few State mine inspectors include in their annual reports such information for their respective States , but uniform data for the United States have not until recently been compiled . Several years ago the Bureau of Mines compiled from one of the standard mining directories * a statement showing the kinds of machines and haulage used in coal mines . The first statement was prepared from the 1918 edition of the directory in which detailed descriptions of coal mines were given . The information presumably related to the calendar year 1917. Similar statements have been compiled from the directories for 1919 , 1920 , and 1922 , the statement for 1921 having been omitted because the directory for that year did not become available . The latest statement is given below and is based upon the directory for 1922. It relates to conditions prevailing in 1921 , and covers a total of 7,088 coal mines . Of these , 5,064 mines . or more than 71 per cent , were using animal haulage . As compared with the total number of all classes of mines , those in the animal - haul age group constituted 71.4 per cent , the percentage having remained practically stationary during the past four years , although the actual number of mines in the group has increased . Rope haulage was reported by 1,066 mines , or 15 per cent of the total , representing a larger number of mines than in 1918 , but a decrease of 2 in the percentage for the group as compared with all classes of mines . Electric haulage was reported by 3,274 mines (46.2 per cent ) , and the number of motors in use was 11,265 . The percentage of mines in this class has not changed materially, but the actual number of mines has shown a gain of about 900 during the past four years . Compressed-air locomotives have not increased either in actual or relative number , the percentage for the past year being but 1.2 . The number of mines using storage- battery locomotives has increased from 3.6 per cent of the total shown four years ago , to 9.8 per cent for last year, the latest figures showing 693 mines with 1,428

May 1, 1922

By R. S. Shoemaker, R. M. Darrah

Expanded markets for copper in the past few years and a consequent search for new ore bodies have revitalized the widely known but seldom applied method of producing copper called heap leaching. Heap leaching is defined here as the process applied to oxide ores which have been mined solely for the purpose of leaching. In this case, all costs of mining the ore become a part (and a substantial one, as will be shown) of the cost of the copper produced, whereas in dump leaching the mining cost has already been accounted for as a stripping cost for the sulfide ore. Of course, with newly opened ore bodies, stripping costs may be divided through accounting procedures, between the copper produced by the mill and that obtained by leaching, but in general this type of operation must be economic on the basis of the sulfide ore alone. Heap Leaching Requires Low Capitalization Heap leaching, as a beneficiation method, is unique in that it is the only process used for the recovery of a metal in which the time involved from mining the ore to metal production is measured in months instead of hours or at the most, days. Then too, after the ore body has been depleted and mining has ceased, metal production will continue for some substantial period of time. Heap leaching is also unique because unlike any other method of beneficiation, metal recovery cannot be accurately forecast ahead of time and recovery will never approach that of a conventionally milled sulfide ore or even that of a vat leached oxide ore. Counter-balancing this drawback, however, is the relatively low capital expenditure necessary to put a heap leaching operation into production and the consequence that smaller ore bodies which would not support the higher capital cost involved in a vat leaching plant can be made into producers. Stated more simply, in heap leaching the operator accepts low recovery in exchange for low capital costs and low break even point. Whether the operator chooses vat leaching with its higher recovery and higher capital costs, is a mater of economics which depends in part on the nature of the ore to decide. For instance, an ore that will vat leach in 7 to 10 days using 7 pounds of sulfuric acid per pound of copper produced might use double or triple that amount of acid during the months that are required for heap leaching.

Jan 12, 1968

By Magdelinka Padenkova-Yaneva, Emilia Christova Kostakeva

"Environmental protection is becoming over the years an increasingly significant problem of mankind. Up to the last decade the only way to make the domestic waste harmless in Bulgaria was deposition on uncontrolled landfills without undertaking actions for protection of the soils. This also caused pollution to spread into the surface and underground waters and that is why actions are now undertaken for remediation of contaminated soils. This is achieved by developing projects for the closing down of polluted sites. In the present paper some projects for closing down of polluted areas are discussed. The actual conditions are examined and project decisions for preventing the surface waters from penetrating into the waste are presented. In this way the pollution of the soil is stopped and the soils are gradually remediate.IntroductionSoil is the topmost layer of the earth crust. It consists of mineral particles, organic substances, water, air and living organisms and is an extremely complex and changing living environment. Soil is a non-renewable natural resource which is of considerable importance in a number of crucial processes (production of foods, storing, filtrating and turnover of many substances, including water, carbon and nitrogen). It also serves as a basis for human activities, shaping the landscape, ground on which cultural heritage is built, and source of raw materials. These functions of soil must be protected both because of their social and economic significance and from the point of view of environmental protection.The processes of erosion, loss of organic substances, compaction, salination and contamination contribute to the degrading of soils accompanied by a negative impact on human health, natural ecosystems and changes in climate, as well as on the economy. All these make it necessary to protect soils from contamination. Over the last years intensive work started in Bulgaria for the construction of controlled sanitary landfills for rendering municipal solid waste harmless. Pursuant to Bulgarian legislation, in these controlled sanitary landfills measures are undertaken for protecting the soils from contamination through appropriate project decisions – the filtration of the products from the biological decomposition of waste into the adjacent sites (soils) and, therefore, the contamination of the surface and underground waters is prevented. At the same time the purity of air is maintained, human health is protected and conditions are created for including the controlled sanitary landfills into the surrounding landscape."

Jan 1, 2008

By S. J. Leach

The possible solution of some of the problems raised in H. L. Hartman's article "Determining Ventilation Requirements for Continuous Miners," which appeared in the March 1962 issue of MINING ENGINEERING, is offered by recent investigative work done at the Safety in Mines Research Establishment, Ministry of Power, Sheffield, England. Highlights of this research are outlined here. Accumulations and layers of methane form in a mine roadway because it is difficult to mix methane with air beneath it by turbulent diffusion. Such mixing involves work contrary to buoyancy forces. In specifying requirements for good ventilation it is not, therefore, sufficient to state that the airflow must be turbulent in the absence of methane. Fundamental work at SMRE on the behavior of methane roof layers has led to the formulation of rules for controlling methane roof layers which specify the ventilation velocity needed to ensure adequate mixing in terms of the rate of flow of methane into the layer (V = cu ft per min) and the airway width (D = ft). A "layering number" for methane and air has been defined by [U37/V/D] where U is the mean ventilation velocity in ft/min in the upper half of the airway. In a horizontal airway there is no mixing by turbulent diffusion for values of the layering number less than about 2, resulting in extensive roof layers. But with a layering number of 5, the layer is "brought under control"-i.e., a further increase in the layering number will shorten the length of the layer only slightly, and a small decrease in the layering number will cause only a small increase in the length of the layer. In a sloping roadway with uphill ventilation, higher values of the layering number are needed to achieve this "controlled" condition; the values range from about 5 at small slopes to about 8 at a slope of 1: 10. In downhill ventilation it is possible for layers to "back" against the ventilation, i.e., to flow uphill. The critical condition for preventing backing can also be expressed in terms of the layering number. Backing will be prevented if layering numbers are about 3 for small slopes and about 4.5 for large slopes; these values for downhill ventilation also give good control of the layer.

Jan 10, 1962

He was born at Montreal, Canada, in 1875. His earliest education was received in Montreal hut was continued from 1885 to 1892 at schools and academies in Brooklyn, Whitestone, and Flushing, L. I. For his technical education he returned to McGill University, where he graduated in 1897. His first professional occupation was as transitman enga.ged in the running of township lines in the Rainy River District of Ontario. In 1899, he was made assistant chemist at the Cuggenheim smelter at Aguascalientes, Mexico. From 1900 to 1903, he was chief chemist for La Compañia Minera de Peñoles, at Mapimi, Durango. We have no information as to his pursuits during the next eight years, but from 1911 until 1914, when he became a member of the Institute, he was chief engineer for the Bankhead mines in Alberta, Canada. Lieutenant-Colonel Alfred Winter Evans Lieutenant-Colonel Evans, who was in command of the Third Battalion of the New Zealand Rifle Brigade, and had been cited in Distinguished Service Orders and received the Distinguished Conduct Medal, was killed in action on Oct. 12, 1917. Alfred Winter Evans was born in Natal, South Africa, in 1881, and received his preliminary education in the Durban High School. For the next five years he attended St. George's School at Harpenden Heights, England, until 1898. Returning to South Africa, he worked . for three months of 1898 as underground sampler for the Crown Deep Gold Mining Co., at Johannesburg, and for six months of the following year he was shift-boss for the Crown Deep, Ltd. At the outbreak of the Boer War he took an active part and was engaged on military service from 1899 to 1902. At the close of the mar, he came to New York and attended the Columbia School of Mines, where he graduated with the degree of E. M. in 1906. A part of that year he spent as assayer to a mining company at Poland, Arizona. In 1907, he returned to South Africa and engaged as underground contractor in charge of mining and development at a number of the South African mines, notably the French-Rand, the ViIIage Main Reef, the City Deep, and others. In 1908, he acted as shift-boss for the Fer-rerra Gold Mining Co. at Johannesburg. In 1909, he was appointed acting general manager for the Consolidated Goldfields of New Zealand,

Jan 1, 1920

By A. Andreas

New Mexico retained its position in 1938 as the sixth largest oil-producing state, with a total production of 35,510,176 bbl. This was 2,875,598 bbl. less than the 1937 production of 38,485,774 bbl., or a decrease of 0.077 per cent, which was caused by the lack of pipe-line facilities and storage at the pipe-line terminals. The production for Lea County (excluding Maljamar) was 32,926,788 bbl.; for Eddy County (including Maljamar) was 2,225,411 bbl.; and for northwestern New Mexico (San Juan and McKinley Counties), 357,977 bbl. The average daily nonmarginal well allowable for Lea County on Jan. 1, 1938, was 65 bbl. At the close of the year it was 49 bbl. The average daily pipe-line runs for domestic consumption were less than the state allowables recommended by the United States Bureau of Mines. There was a demand for Artesia crude for foreign export, which if included in the daily production for New Mexico would be slightly in excess of the daily production recommended for New Mexico by the Bureau of Mines. The daily average production for the year was 97,329 barrels. There were 622 completions in the state, of which 520 were oil wells; 16 hydrocarbon gas wells; 5 carbon dioxide gas wells, and 81 dry holes. Of the dry holes 38 were in or near-by proven fields and the remainder, 43, were wildcats. Five new fields were discovered in New Mexico during 1938, three in Lea County and two in Eddy County. Southeastern New Mexico Lea County.—The Monumcnt field was the largest producing field in Lea County, with 9,440,334 bbl., and was closely followed by the Eunice field with 8,872,335 bbl. The Hobbs field was third with 5,010,414 bbl. The greatest activity in Lea County was in the Vacuum pool, with 129 completions, of which 126 were oil wells and three were dry holes. The Texas Company completed its Corbin NO. 1 in the KW 1/4 SW1/4 sec. 10, T. 18 S., R. 33 E. in August. This well was drilled to a depth of 5118 ft. in a white sand, encountering salt water. It was plugged back to 4315 ft, and pumped 43 bbl. of 36" gravity oil in 12 hr. It was approximately 6 miles southwest of the closest production in the Vacuum

Jan 1, 1939

By O. D. Sherby, J. E. Dorn, C. D. Wiseman

MCLEAN' has shown that the total strain obtained during creep of aluminum polycrystals arises exclusively from the mechanisms of 1) microscopically observable slip, 2) subgrain tilting, and 3) grain boundary shearing. Extensive analyses, however, suggest that the high temperature creep of metal polycrystals is controlled by a single thermal activation process."" These somewhat contradictory observations might be reconciled if it could be shown that the activation energies are identical for each of the mechanisms isolated by McLean. Such identity of the activation energies, of course, would demand that the same unit process controls the functioning of each individual mechanism. Under these conditions the activation energies for creep of single metal crystals and polycrystalline aggregates and for grain boundary shearing should be identical. This paper is primarily concerned with the possible identity between the activation energies for high temperature creep of single crystal and polycrystalline metals. In addition, comparisons will also be made between the activation energies for creep of single crystals and polycrystals with previously reported activation energies for grain boundary shearing.0"8 Materials and Techniques The same high purity aluminum, lead, and tin were used in the creep tests for single crystals and polycrystalline aggregates. Single crystals of aluminum and tin were prepared by the strain-anneal technique, whereas lead single crystals were prepared by growth from the melt. The tensile creep stress was maintained constant by Chalmers-Andrade parabolic-type lever arms. Strains were measured to &0.0002 in. per in. with rack and pinion type extensometers, and temperatures were maintained to within & 0.2"C of the reported values by mercury-thermoregulated resistance-heated silicone oil baths. The previously reported unambiguous technique for determination of the activation energy for creep was employed throughout this investigation.' ." It involves periodic abrupt small changes in temperature during the course of creep, accomplished by rapidly replacing one creep bath at temperature TI by a second bath at T,. The abrupt change in creep rate from i, to & attending the abrupt change in temperature is due exclusively to the change in temperature, since both the stress and the substructure are identical the instant before and the instant after a change of temperature. Therefore, all other factors being identical where AH is the activation energy for creep and R is the gas constant. Results Typical examples of the creep rate vs creep strain data during temperature cycled creep tests of single

Jan 1, 1958

By Charles Legrand

(San Francisco Meeting, September, 1915) THE problem of mine pumping is so much affected by local conditions, and those conditions are so liable to changes during the life of a mine, that the best system to use is difficult to determine. The experience of the;, writer has been that, in general, for copper mines, electric pumping is most satisfactory unless the quantity of water to be pumped is great or. the mine does not use electric power for any other purpose. As a rule, however, figuring on the cost of necessary power plant, the total cost of: installation is greater with electric pumps than steam- pumps. As the water is liable to be gritty, outside-packed plunger pumps are to be recommended, and if the water is not acid, or only slightly so, chilled cast-iron plungers pay for their extra cost very quickly in diminished cost of packing. With chilled plungers it is possible to use metallic, packing instead of soft packing, if the water, is not too gritty nor the lift too high. In vertical pumps this packing is satisfactory for lifts up to 400 ft., in the experience of the writer; and may be found satisfactory for higher lifts. For water slightly acid, cement-lined pump bodies have given good satisfaction. For acid. water, both plungers and pump bodies should be made of acid-resisting bronze. For high lifts, especially with gritty water, a satisfactory pump valve is difficult to find. To reduce the unbalanced pressure on the valve at time of opening it is advisable to have narrow seats; this, however, brings high pressure on the seats when the valve is closed. On large valves for lifts of 600 to 1,000 ft. we have used leather, hard rubber, vulcanized fiber, and soft brass; for clear water the latter has given best satisfaction. The difficulties due to grit make it advisable to have large sumps where water can settle, and if possible, to have two of them so that they can be cleaned alternately. At the mines of the Old. Dominion Copper Mining ,& Smelting Co.; Globe, it was found that a small air. ejector discharging into a mine car is a very convenient way to clean mud and sand from a sump. .

Jan 9, 1915

By D. Mizer, J. B. Clark

In a recent investigation of the entire magnesium-yttrium phase diagram, Gibson and Carlsonl report the maximum solid solubility of yttrium in magnesium as 8.0 wt pct Y at 1050°F (565°C). However, independent studies of the precipitation in magnesium-yttrium alloys, 2 conducted prior to the publication of the above phase diagram, indicated a greater solid solubility of yttrium in magnesium. Accordingly, the magnesium-rich region of the diagram was re-investigated to determine more accurately the liqui-dus, solidus, and solvus of the magnesium solid solution in this system. Metallography and thermal analysis were chosen as the best corroboratory methods for accurately determining this region of the diagram. A magnesium-yttrium master alloy was prepared from yttrium of 99.9 pct purity and singly sublimed magnesium of 99.9 pct purity. Subsequently, the twelve magnesium-yttrium alloys shown in Fig. 1 were prepared using standard alloying procedures for magnesium. Metallographic samples of the alloys were heat treated under an SO, atmosphere in an electric furnace capable of control within ±3oF of the desired temperature. Alloy samples for the metallographic determination of the solvus, and for the precipitation studies were solution treated at 1000° F for 16 hr. Subsequent aging times for the solvus determination varied from a minimum of 6 hr for the higher temperatures up to 816 hr for lower temperatures. Periods of 30 min at temperature were used to generate liquation for the metallographic placement of the solidus and eutectic horizontal. The liquidus and the eutectic horizontal were determined by thermal analysis. Simple time-temper- ature heating and cooling curves were obtained from 10-g alloy samples heated and cooled in a well-insulated electric furnace. An Iron-Constantan thermocouple was placed in direct contact with the sample. The thermocouple did not contaminate the alloy sample since metallographic examination showed that the alloy melt did not wet or attack the thermocouple. The heating and cooling rates were approximately 5 to 8OF per min. The standard metallographic procedures for magnesium were used in polishing and etching the magnesium-yttrium alloys studied. Glycol etchant* was etchant was used to reveal precipitate in the solvus determination. The redetermined magnesium-rich region of the magnesium-yttrium diagram is shown in Fig. 1. The

Jan 1, 1962

By A. Andreas

New Mexico retained its position in 1938 as the sixth largest oil-producing state, with a total production of 35,510,176 bbl. This was 2,875,598 bbl. less than the 1937 production of 38,485,774 bbl., or a decrease of 0.077 per cent, which was caused by the lack of pipe-line facilities and storage at the pipe-line terminals. The production for Lea County (excluding Maljamar) was 32,926,788 bbl.; for Eddy County (including Maljamar) was 2,225,411 bbl.; and for northwestern New Mexico (San Juan and McKinley Counties), 357,977 bbl. The average daily nonmarginal well allowable for Lea County on Jan. 1, 1938, was 65 bbl. At the close of the year it was 49 bbl. The average daily pipe-line runs for domestic consumption were less than the state allowables recommended by the United States Bureau of Mines. There was a demand for Artesia crude for foreign export, which if included in the daily production for New Mexico would be slightly in excess of the daily production recommended for New Mexico by the Bureau of Mines. The daily average production for the year was 97,329 barrels. There were 622 completions in the state, of which 520 were oil wells; 16 hydrocarbon gas wells; 5 carbon dioxide gas wells, and 81 dry holes. Of the dry holes 38 were in or near-by proven fields and the remainder, 43, were wildcats. Five new fields were discovered in New Mexico during 1938, three in Lea County and two in Eddy County. Southeastern New Mexico Lea County.—The Monumcnt field was the largest producing field in Lea County, with 9,440,334 bbl., and was closely followed by the Eunice field with 8,872,335 bbl. The Hobbs field was third with 5,010,414 bbl. The greatest activity in Lea County was in the Vacuum pool, with 129 completions, of which 126 were oil wells and three were dry holes. The Texas Company completed its Corbin NO. 1 in the KW 1/4 SW1/4 sec. 10, T. 18 S., R. 33 E. in August. This well was drilled to a depth of 5118 ft. in a white sand, encountering salt water. It was plugged back to 4315 ft, and pumped 43 bbl. of 36" gravity oil in 12 hr. It was approximately 6 miles southwest of the closest production in the Vacuum

Jan 1, 1939

By Robert E. Green, Edmund G. Henneke

The velocities of the three possible modes of elastic wave propagation have been calculated for single-crystal copper at 1-deg intervals throughout the standard stereographic triangle. The results are presented as isospeed contours. The deviations between the direction of maximum energy flux and specimen axes are presented as arrows drawn on stereographic projections. The orientation factors associated with dislocation motion on the primary slip system only and also on all twelve slip systems have been calculated for all three elastic waves. The orientation factors associated with a longitudinal standing wave resonant specimen have also been calculated. The results of these calculatians are compared with earlier calculations on aluminum crystals and the relevance of these results to ultrasonic attenuation measurements is discussed. GREEN and inton' have recently outlined a procedure for determining the orientation factors for dislocation damping in single crystals. The stress field associated with a given mode of elastic wave propagation is resolved on the slip systems in which it is assumed the dislocations are vibrating due to this stress field. Since, at room temperature, slip has been observed on a limited number of systems in fcc and hcp metal crystals, it is assumed that these systems are the appropriate ones to use for the resolving process. This procedure has been applied to aluminum crystals by Hinton and hreen' and to zinc crystals by Henneke and Green.3 In the present paper the modes of elastic wave propagation have been calculated for copper crystals possessing orientations at 1-deg intervals throughout the standard stereographic triangle. The deviation of the energy flux vectors from the specimen axis have been calculated for each mode. The stress field associated with each mode has been resolved on the (111)(110) slip systems in order to determine the orientation factors for dislocation damping. MODES OF ELASTIC WAVE PROPAGATION For any direction in a linear homogeneous aniso-tropic material three elastic modes can be propagated. In general, each of these modes has both longitudinal and transverse particle displacements associated with it and thus are not "pure" modes. However, there is always one component which is greatest in either a longitudinal or transverse direction and hence the mode may be referred to as quasi-longitudinal or quasi-transverse, accordingly. For certain axes of high symmetry pure modes may be propagated. The phenomenon of refraction of the energy flux vector is also exhibited by elastic wave propagation in ani-

Jan 1, 1969

By A. Karim, T. G. Langdon, C. Y. Cheng, J. E. Dorn

The effect of changes in temperature and stress on the creep behavior of Fe-4 pct Si was investigated over the temperature range from 650° to 1175K Over the temperature range of 799° to 110l°K, the shear strain rate, ?', obeys the relationship: where K is a constant, 7 the applied shear stress, G the shear modulus, g the free activation energy for diflusion, R the gas constant, and T the absolute temperature. The results strongly suggest that the creep in this alloy is controlled by a dislocation climb mechanism. In a recent investigation, Ishida, Cheng, and Dorn1 observed that the apparent activation energy for creep of a! Fe from 480" to 775°K corresponded to that for self-diffusion. Over the magnetic transformation range (775" to 1045"K), the apparent activation energy for creep increased steeply with increasing temperature in agreement with the known decrease in the free activation energy for self-diffusion. Passing through the Curie temperature, the apparent activation energy decreased abruptly following which it then increased mildly as the temperature further increased. Inasmuch as the apparent activation energy for creep of a! Fe below the Curie transformation range of temperatures appeared to decrease with increasing values of the stress, the data were analyzed in terms of a model based on the nonconservative motion of jogged screw dislocations. But since the observed creep rate was much higher than that which could be accounted for on the basis of usual models, the authors found it necessary to assume that pipe diffusion became significant over the lower temperature range. Furthermore, the abnormally high activation energy for creep above the Curie temperature was attributed to grain boundary migration which became prevalent in this temperature range. It was thought that a number of the interesting issues that arose in the creep of a Fe might be resolved by investigating the creep of Fe-4 pct Si alloy: This alloy has about the same Curie range and therefore should give creep results that closely parallel those for a Fe and in this way provide comparable data for analysis of creep mechanisms. Furthermore, it can be annealed at higher temperatures which could provide some stabilization against grain boundary migration. In addition, it might serve to illustrate the possible effects of short-range ordering on creep.

Jan 1, 1969

By J. R. Cahoon, W. V. Youdelis

In a previous communication by one of us,1 a theory of inverse segregation was presented by which the maximum segregation and segregation distribution throughout a unidirectionally solidified, binary-alloy ingot could be calculated. The theory, which is based on the mechanism of volume contraction and interdendritic flow, quantitatively accounts for the observed maximum segregation in the A1 (rich)-CU' and Al-Zn2 alloy systems, and for the segregation distribution along the ingot lengths for the A1-Cu system.''4 One of the drawbacks to a more extensive use of the segregation equations is their complexity, particularly for the calculation of the segregation distribution throughout the length of the ingot, involving long tedious numerical calculations to obtain the segregation. Computer pro- grams, written in Fortran II for use on an IBM 1620 computer, have been developed by the authors (and are available from them), providing quick and accurate methods for the determination of the theoretical maximum segregation in any binary-alloy system, and also for the segregation distribution in any unidirectionally solidified binary-alloy ingot. The segregation distribution is controlled by the lengths of the various solidification zones'74 which are in turn controlled by the cooling rate, and are determined from temperature-distribution curves obtained during solidification. The theoretical segregation distributions shown in Fig. 1 illustrate the effect of the zone lengths on the distribution Curve 1, indicative of a slowly cooled ingot, represents an ingot having long solidification zones, while Curve 2, indicative of a rapidly cooled ingot, represents an ingot having relatively short zones. Although these distributions are calculated for an A1-10 pct Cu ingot, the shape of the distribution would be similar for any binary-alloy ingot. These curves show clearly why early workers obtained results which indicated that the maximum (chill-face) segregation approached zero at very fast cooling rates.3 Actually, the maximum segregation is independent of cooling rate,' but even at short distances from the chill face the amount of segregation drops considerably, particularly in a rapidly cooled ingot, making it very difficult to establish the amount of segregation occurring at the chill-face. The authors would like to thank Dr. J. A. Goldak for his assistance in the preparation of the programs. The financial assistance of the Steel Co. of Canada and of the National Research Council of Canada in the form of Scholarships to one of us (J. R. Cahoon) is gratefully acknowledged.

Jan 1, 1964

By C. F. Willis

Many of the failures in vocational education are due to the fact that the educational methods were not designed to the capabilities, habits, and environments of those to be trained; rather they were based on the policy that education is education and lessons are lessons, whether for youngsters of fifteen or for men of forty. Vocational education among miners involves, first, a study of the men themselves, their habits, and the use of their leisure time; second, a study of the differences between the methods of teaching required for men and for children. Certain fundamental requirements of training methods for miners are reasonably universal and may be applied with success to any ordinary mining community. The rate of labor turnover is another consideration; it would be useless to design a four-year course for men who remain in one place only a few months. Length of Course The first consideration should be the length of the course. Few mining communities have a sufficiently stable population to make it possible successfully to carry on a course for over a year. While some men might complete a four-year course, the number is comparatively small compared with the number to whom a shorter course would be of service, and it is better to raise the standards of education even a little for a large number than to raise them to a high level for a few. It is perfectly possible to attain both objectives by arranging the courses in small units; all the units, when grouped together, should comprise a fairly complete course, yet any one unit should be complete in itself and of benefit to the workman. It should not take many of these units to make a miner or a timberman out of a mucker; but to do this the course should be short, because muckers seldom stay in one place long. By grouping a number of these units together it Would be possible for a miner to become a shift boss or a shift boss a foreman, and so on. As far as possible the units of the course should not be dependent on those preceding or following. The workman understands the completed job but he is not accustomed to carrying on several jobs at the same time and

Jan 1, 1920

By Louis A. Carapella, William E. Shaw

MAGNESIUM and its alloys have long been characterized as possessing limited capacity for mechanical forming at atmospheric temperatures prior to rupturing despite their outstanding performances in this respect at elevated temperatures. Responsible for this behavior are the fundamental facts that these hexagonal-type metals have comparatively few slip elements at low temperatures for any extensive deformation and that, at high temperatures, additional slip elements become operative, thus enhancing greater plasticity under strain. The transitional point has been set at 225°C by Schmid1 for single crystals, and at 250°°C by Morell and Hanawalt2 for extruded magnesium metal. In a recent X-ray investigation on polycrystalline magnesium-alloy sheets, Barrett and Haller3 have revealed that, below the transitional temperature, the initial plastic deformation proceeds mostly by a twinning action; that, above such a temperature, the action is mostly by slip. The deep-drawing performance of the magnesium + 1.5 pct alloy sheett over a wide range of temperatures has been investigated by Weber and Vanden Berg,' and their results are presented in Fig r. It should be noted from this work that a maximum drawability of about 25 pct at room temperature has been obtained on this alloy under the conventional deep-drawing operations. For the same alloy, it is now possible to augment the cold drawability to about 40 pct by a process to be disclosed. Hitherto, this value has been obtained only by deep-drawing the alloy at around 230°C. That greater plastic flow is attainable at atmospheric temperatures on magnesium under certain deformational techniques was discovered by the authors6 in their analyses of plastic-deformational behaviors of pure magnesium. This fact is best illustrated in Fig 2 from the Hargreaves analysis6 performed by the authors under two different modes of loading. For direct test, a separate unstrained specimen was used for each load duration, whereas for the integrated test the same specimen was employed for all the five intermittent loadings so that the load duration was made additive throughout the investigation. The higher plastic flow-rate at room temperature, as designated by the Hargreaves constant S, was obtained by the integrated or intermittent loading procedure. The authors5 in further tests showed that, under such a procedure greater plastic flow was also realized with a progressive increase in deformational loads. These findings have been applied

Jan 1, 1947

By G. D. Arsdale

This paper describes a series of experiments leading to the development. of a method for leaching the mixed ores of the Inspiration Consolidated Copper Co., containing chalcocite and silicates of copper, by the use of solutions acidified with sulfuric acid and carrying ferric sulfate. Iron is added to the solutions and ferric iron is regenerated electrolytically to a percentage high enough to act as an efficient solvent. The decreased yield is partly compensated for by a higher current density. AN IMPORTANT problem in modern copper metallurgy, particularly in the Southwest, has been to obtain good recoveries from what are commonly known as mixed ores; that is ores in which the copper occurs partly as oxide and partly as sulfide compounds. The dividing line between mixed ores and ores commonly accepted as concentrating is not definite. In other words, much ore now being concentrated carries considerable copper in non-sulfide form, on which recoveries are hot so good as on ores carrying less of these constituents. While treatment by concentration may be commercially profitable, on ores carrying oxide copper within certain limits, there are large deposits for which the application of con-centration could not be considered, and yet which have not been considered amenable to leaching because they carried too much sulfide. The Inspiration Consolidated Copper Co. has large amounts of such mixed ores, and this paper is an account of the experimental work by which a method was developed for their treatment, and for which a large plant is now being erected by the Inspiration Co. It is not claimed that the method is a general solution of the problem of mixed-ore treatment but it is apparently well adapted for leaching the ores of the Inspiration Co., for which it was designed. The work done has covered preliminary laboratory and test-plant investigation, and .a pilot-plant run, extending from March to the middle of December, 1923. Thoroughly consistent and satisfactory results, were obtained continuously for more, than six months in the pilot plant; and it is believed that the results; and probable costs that can be had on a large scale have been definitely, proved. The method, however, was designed for local conditions; and while the basic principles are general, there are ores on which it will not work and other ores for which considerable modification may be required.

Jan 10, 1925

By G. D. Van Arsdale

This paper describes a series of experiments leading to the development of a method for leaching the mixed ores of the Inspiration Consolidated Copper Co., containing chalcocite and silicates of copper, by the use of solutions acidified with sulfuric acid and carrying ferric sulfate. Iron is added to the solutions and ferric iron is regenerated electrolytically to a percentage high enough to act as an effcient solvent. The decreased yield is partly compensated for by a higher current density. An important problem in modern copper metallurgy, particularly in the Southwest, has been to obtain good recoveries from what are commonly known as mixed ores; that is ores in which the copper occurs partly as oxide and partly as sulfide compounds. The dividing line between mixed ores and ores commonly accepted as concentrating is not definite. In other words, much ore now being concentrated carries considerable copper in non-sulfide form, on which recoveries are not so good as on ores carrying less of these constituents. While treatment by concentration may be commercially profitable on ores carrying oxide copper within certain limits, there are large deposits for which the application of concentration could not be considered, and yet which have not been considered amenable to leaching because they carried too much sulfide. The Inspiration Consolidated Copper Co. has large amounts of such mixed ores, and this paper is an account of the experimental work by which a method was developed for their treatment, and for which a large plant is now being erected by the Inspiration Co. It is not claimed that the method is a general solution of the problem of mixed-ore treatment but it is apparently well adapted for leaching the ores of the Inspiration Co., for which it was designed. The work done has covered preliminary laboratory and test-plant investigation, and a pilot-plant run, extending from March to the middle of December, 1923. Thoroughly consistent and satisfactory results were obtained continuously for more than six months in the pilot plant; and it is believed that the results and probable costs that can be had on a large scale have been definitely proved. The method, however, was designed for local conditions; and while the basic principles are general, there are ores on which it will not work and other ores for which considerable modification may be required.

Jan 1, 1926

By N. A. Gjostein

The self-diffusion coefficient D, for a surface near the (100) plane in copper was determined by means of the Mullins theory of thermal grooving, and was found to obey the Arrhenius relationship, and Do = 6.5 x 10' sq cm per sec. Suppression of surface diffusion by chemisorbed impurities encounters difliculties as a satisfactory explanation for the large Q, and Do. Instead, a model is presented which indicates that Q,, as determined by a mass-transport technique, may involve both the energy needed to form an adsorbed atom from a ledge in the surface as well as that for the movement of the adsorbed atom.; LITERATURE reviews1-3 indicate that the mechanism of self-diffusion on metal surfaces is not clearly understood. The lack of experimental data on the temperature variation of the surface self-diffusion coefficient DJ has contributed greatly to this situation. Radioactive tracer techniques4-rn have been used to measure Ds, but for many years only Nicker-son and Parker8 had determined (for polycrystalline silver) an activation energy B, and a frequency factor Do for the surface self-diffusion process. Even in this case, a mechanism could not be clearly inferred because it was suspeted7 that a contribution from volume diffusion was not taken into account by the investigators. Some later work by Li and parkere on polycrystalline gold, in which they obtained essentially the same results as for silver and in which volume diffusion could be accounted for, seems to invalidate this criticism. In 1957, Mullins10'11 developed the theory for the thermal grooving process. This advance has opened a new and promising technique for measuring the surface self-diffusion coefficient Ds. Recognizing that a thermal groove may form by several different mass transport processes, Mullins first consideredlo the cases where a) the groove forms by evaporation and condensation or b) by diffusion along the groove surface, in either case, in a system where a metal surface is in contact with only its dilute vapor phase. In a later paper," he extended the treatment to cases where the groove forms by volume diffusion into c) the solid phase or d) by mass transport through a passive gaseous phase at 1 atm pressure. The time dependence of the groove dimensions and the shape of the groove profiles predicted by Mullins' treat-

Jan 1, 1962