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By H. K. Work

THE instrument for the rapid determination of carbon in steel, described in this paper, was developed originally to facilitate the opera-tion of the pilot-sized open-hearth furnace in the Jones & Laughlin Research and Development Laboratory. In this small furnace, with its shallow bath, the drop in carbon is accelerated, and a rapid, reliable test for carbon content is indispensable. This problem becomes rather acute when it is desired to finish heats at a carbon content higher than can be estimated with any degree of accuracy by the fracture test. Several independent methods for determining carbon were investigated, therefore, and it was found that a relatively simple magnetic device could be made to give reproducible results. A laboratory instrument was designed and set up for the use of the furnace operators. It was tested exhaustively in the laboratory and was used with considerable success for following the carbon content in the furnace bath. As soon as suffi-cient data had been compiled to indicate that the instrument might have a wider application, a more rugged model was constructed and placed in the mill to be tested on commercial heats. Finally, about a year ago, instruments were furnished to the plant open-hearth shops, and these have been in use since that time. As a matter of convenience, the instrument has been named the "Carbanalyzer," and will be referred to by this designation in the following pages. ?

Jan 1, 1939

By Richard L. Ash, Thomas E. Pearse

Most theories of blasting phenomena are based on the condition that explosive charges have a spherical shape. If a cylindrical charge is considered, the explosive is usually assumed to have an infinite velocity of detonation. Another limitation is also often imposed whereby only one free face is considered to exist. Unfortunately, these conditions all serve to limit the number of variables involved and tend to over-simplify analyses. The result is that explanations for actual effects from blasts are seldom realistic. In addition, no solution has yet been found to explain the actions of certain blasting agents that appear to stress materials in a different manner than do many of the high explosives. In order to determine causes for some of the unexplained phenomena, investigations were conducted by the writers on both actual field blasts and theoretical problems. Although many solutions have been proposed to explain the rock breakage processes, none relate the effects of hole depth, explosive and rock energy- propagation velocities with charge placement geometry. Evidence indicates there is a definite interdependence of those factors and that they are of vital importance in proper drill-pattern design. For simplicity most of the discussion in this paper applies to vertical blast-holes drilled in uniform massive rock for open pit blasting, although the basic principles presented apply to all forms of blasting with certain basic modifications being necessary for specific field conditions.

Jan 9, 1962

By W. A. Clark

THE production of sand in an oil well increases operating costs because of abnormal wear in subsurface equipment, the necessity for frequent cleanouts, and the need for a means of disposing of the sand. Moreover, removal of sand from the zone can bring about the creation of cavities from which bodies of formation, sand or shale, may slough into the hole, endangering the shutoff, impeding production or collapsing the liner. The procedure known as gravel packing is attracting attention as a means of controlling these factors and contributing to the productive life of a well. That gravel packing is now substantially beyond the preliminary stage on the Pacific Coast is reflected in the 191,000 bbl, of oil produced monthly by the 66 gravel-packed wells in 11 different producing sectors. REASONS FOR GRAVEL-PACKING Gravel packing, if properly carried out, can be expected to provide the following benefits: 1. Prevent the movement of sand and thus eliminate sand production and sand fills, and prevent the formation of cavities. 2. Provide a practical, relatively inexpensive, large-diameter hole, which will provide well-known theoretical advantages. 3. Support the walls of the hole by completely filling the space between the liner and the formation, regardless of its irregularities, and afford a support for liners. 4. Provide for more efficient pumping operations in wells by: (a) possibly utilizing the gravel as a gas trap in pumping gaseous fluids, (b). allowing deep submergence of the pump into the oil zone.

Jan 1, 1939

By Daniel Levacher

Pile load tests in site require extensive means of action and time. To get outstanding tests, the environmental test conditions must be perfectly known and acceptable. They concern the support installation, the loading, the access and instrumentation site conditions and the economical aspects. In particular cases as offshore areas, the load tests are not feasible. Moreover the variability of soil characteristics limits the interpretation results at the considered tested site. The use of centrifuge modellling offers an other way to study the loaded pile behaviours. Centrifuge tests lead to parametric approaches which constitute for geotechnical engineers an important data base tor recommendations and design codes. To accurately simulate pile behaviours by checking similitude laws linked to the studied problems, the installation of model-piles must be also representative of the in-situ piles. Driven piles account for a large part of the piles installed through the world, mainly for offshore or harbour constructions. So, to explore driven pile problems by centrifuge tests, miniature pile driving hammers must be developed and tested under macro-gravities. The paper describes two types of these ones in details. They are commonly used at the centrifuge centre of the Laboratoire Central des Ponts et Chaussées - (LCPC) - [Réf. 1] for different deep foundations researches. Performances and limitations are given for both miniature pile drivers and some results from their use are presented to illustrate the suitability of these apparatus.

Jan 1, 1996

By T. R. Cass, M. R. Achter

A technique for measuring the creep and rupture strength of nickel specimens bonded by sintered oxide layers has been developed for the investigation of the role of grain-boundary oxide in the oxidation strengthening of nickel during creep at 817 °C. Prom the inverse dependence of the rate of bonding on the thickness of the starting oxide, it is suggested that the rate of diffusion of Ni++ through NiO is the controlling process at the start of sintering. Cornparisons of the creep and rupture strength and of the microstructure of sintered couples with conventionul creep specimens suggest rupture in nickel is prevented by load-bearikzg, ikltergranular layers of oxide. A number of recent investigations have shown that at high temperature and low stress the creep-rupture strength of nickel and nickel-base alloys may be much greater in air than in an inert gas or vacuum.'-7 For example, at 817°C and 2500 psi, nickep failed in vacuum in 48 hr but not in air after 4000 hr, and a Ni-Cr-A1 alloy5 at 1038°C and 3000 psi failed in vacuum in 4 hr but not in air after 731 hr. Fig. 1 is a typical creep curve in air for materials experiencing this pronounced environmental strengthening. A common feature of these curves is the entry into a third stage of accelerating creep, concurrent with the for-

Jan 1, 1962

By Hawes GW

Until 1980 copper, lead and zinc sulphide slurries have been success- fully dewatered for rail and sea transport for many years at the Rose- bery site of North Broken Hill Holdings Ltd. utilizing conventional vacuum disc filtration systems. An upgrading and mill expansion program completed in 1981, which also permitted the introduction of ore streams changes, had resulted in difficulties dewatering copper and lead sulphide slurries to comply with transportable moisture limits. Following an extensive investigation which included both laboratory and pilot plant testing a program was commenced to replace the 2 vacuum disc filtration systems with 2 pressure filtration systems for use on copper and lead slurry dewatering and also to retain other existing vacuum disc filters as standby. An analysis of mill operations performance resulted in slurry storage tanks with a capacity equivalent to 20 hours of normal production being incorporated into the project. The pressure filters are mounted above the concentrate stock- piles. A sealed sloping floor incorporating launders is used to prevent any accidental contamination of the concentrate from pipe leakages, spillage, or from water hoses used for clean up purposes around the area. The project was completed in 1985 and operating performance has been better than that predicted from testwork. Equipment availability at 95076 together with the slurry storage capacity provided results in minimal requirement for the standby vacuum filtration system. Some typical operating results are given.

Jan 1, 1988

By G. F. Friel, G. S. Morrow, J. C. Edwards

An experimental program in the U.S. Bureau of Mines' Safety Research Coal Mine evaluated the effects of dead end crosscuts on the transport time of CO along a mine entry. The presence of carbon monoxide is a characteristic of a fire in its incipient stage, and is significant in the determination of a fire location in a mine from the analysis of arrival times of pre-set concentrations at CO monitors. In this investigation two entries, with a total of ten crosscuts, connected by a room were instrumented with CO sensors as part of a real-time monitoring and data acquisition system. Controlled release of 1% CO was monitored as the contaminant traveled the entries for several different configurations of CO sensors and exhaust fan settings. In addition to the normal longitudinal dispersion of CO due to turbulent mixing at the front of the CO wave, the induced rotation of air established within a crosscut by the entry flow diluted the CO concentration through entrainment. It was determined experimentally for the entry and crosscut configuration considered that the transport time for a specified CO concentration was 27% greater than the predicted time based upon entry volume only, but 13% less than the predicted time based upon entry and total crosscut volume. The proper interpretation of the measured transport time of a specified contaminant concentration between sensors is important for mine safety in the isolation of a fire and plans for miner evacuation.

Jan 1, 1993

By F. O. Willhofft

The symposium on mine safety held in connection with the annual meeting of the Institute three years ago, it. was pointed out that "at present no convenient, reliable, accurate means for determining the gas content of mine air is available, for use by the ordinary mine man." In a letter addressed to Coal Age and published on Feb. 25, 1925, Thomas T. Read, then Director of the Safety Service of the Bureau of Mines, stated: "It is to be hoped that sometime in the near future some-one will invent a reliable methane indicator that is con-venient to, use and will permit the keeping of all flames of every character out of bituminous mines, through doing away with the safety lamp." The Martienssen methane detector, which has re-cently received the official approval of the Bureau of Mines, is intended to. meet the demand for such an in-strument as expressed at that meeting and on many other occasions. The characteristics which qualify it for the task are the following: (1) simplicity; (2) small bulk and light weight; (3) ruggedness; (4) accuracy sufficient for the requirements; (5) safety; and (6) dependability. The principle on which the working of the instrument is based may best be explained by giving a brief out-line of the various stages of development through which the inventor, Professor Martienssen of the University of Kiel, Germany, advanced to the final solution of the problem which he had undertaken to solve.

Jan 2, 1928

This paper comprises a discussion of standards for comparing conditions in mines, of methods for measuring the flow of air, of a comparison of fan performances, and the application of these matters to mines in Western Australia.UNDERGROUND CONDITIONSIn approaching the question of mine ventilation one naturally searches for some standard by which to measure the conditions in a mine.There are several clauses in the Mines Regulation Act defining the conditions which are permitted. The quantity of CO2 is limited to 0·25 by volume, but the estimation of CO2 involves a chemical determination and is not suited for general use in a mine.The maximum temperature is fixed at 87 0 F. (dry bulb), and at 80° (wet bulb). The reading of temperature is easily done in the working places, and this is a very valuable and practical test of the conditions in a mine.The wet bulb temperature is probably the most important factor in determining working conditions. It is obvious that human life cannot be sustained for any appreciable period if the wet bulb temperature is above blood heat (about 97°F.). In places where the wet bulb temperature is 90°F. there is danger of heat stroke.In places where the air in a mine is still, the wet bulb temperature rises to a value close to the rock temperature.Adequate ventilation cools the workings by transference of heat from the rock to the air stream, and the temperature...

Jan 1, 1939

By Eric L. Christiansen

A dynamic simulation model for the iron blast furnace has been developed which predicts flow rates, compositions, and temperatures of the top gas, slag, and hot metal exit streams as a function of time from specification of the time-dependent tuyere inputs and raw material charges. As a matter of convenience, a previously developed steady- state model is employed to fix furnace-dependent parameters. It also provides initial conditions for the internal states of the furnace for subsequent dynamic solution of the simultaneous differential equations which describe the local rates of chemical reaction, heat transfer, and mass transfer in the stack, bosh, combustion zone, and hearth of the furnace. The dynamic model was tested by a demonstration of its ability to relax to steady-state representations of the time-averaged data from two separate industrial blast furnaces and of its ability to follow eight days of time-dependent operating data for one of them. Simulated responses to step changes in tuyere input and burden variables have been shown to be of the correct magnitude and duration. Although complex functions of many variables, a proper description of these responses is needed for the development of optimization and control strategies . The model correctly predicts the non-minimum-phase type dynamic response observed in real furnaces in which the output variables proceed through local minima or maxima, often including inverse responses (i.e., opposite signs from their final steady-state values ) .

Jan 1, 1984

By P. Mousset-Jones, G. Danko

Rock thermophysical properties, i.e. heat conductivity and thermal diffusivity, were obtained for reference values at the Waldo Test Mine for mine fire simulation purposes. An in situ measurement method was chosen since it could include the effect of rock fractures. The REKA method (Rapid Evaluation of k and alpha) was used because it can measure conductivity (k) and diffusivity (alpha) simultaneously within an eight-hour measurement period. A total of six measurements were taken in three different holes, and at two different depths from the collar of the hole. Each measurement provided an averaged conductivity and diffusivity for a volume of rock of approximately one cubic meter. The boreholes were driven into the upper and lower limestone, two at right angles to and one parallel to, the stratification of the rock. Significant representative conductivity and diffusivity values were obtained for the whole mine by averaging the six measurement results. The thermal properties for the band of shale in between the two limestones were not measured in situ, but only in the laboratory. Problems were encountered in the evaluation because of unexpected heat conduction on one side of the symmetrically built probe. A modification was made to the previously developed evaluation method together with further testing and correction, before the final results were obtained. As expected, the in situ and lab- oratory measured values of k and alpha compared favorably, since the in situ rock was dry and relatively unstressed.

Jan 1, 1989

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By Walter W. Lilly, Issa S. Oweis

Application of rock engineering in geotechnial consulting practice considered herein is in areas of: (a) bedrock verification for foundation support, (b) bearing capacity and settlements, and (c) excavations. A routine geotechnical investigation usually provides data on depth to rock, rock classification, and rock quality. In cases of rock outcrop, such outcrops are mapped for geologic structures and rock mass description. In addition, the regional geology and the general aspects of the groundwater regime are usually known from either published literature or previous experience. The predominant technique for ground and site investigation are usually drilling and geologic reconnaissance. Other techniques involving seismic and geophysical soundings, borehole camera, and oriented cores are used by by no means routine. Performing laboratory strength and compressibility tests is often made to be considered as routine. The use of the point load test is gaining increasing use in the United States and would, perhaps, become a routine field or laboratory test due to its simplicity and, more importantly, its relatively low cost. The purpose of this paper is to describe cases where mostly routine investigation and testing were used to arrive at engineering decisions. Bearing Capacity and Settlements The allowable bearing values for foundation support on rock is usually dictated by local building codes which presumably should reflect local experience. The interpretation of the code, however, can present a problem, especially if the interpretation is made by a designer under the delusion of knowledge in rock engineering. For

Jan 1, 1982

By Frederick Prime

IN this second supplementary list no titles to which an * is. Pre-fixed have been seen by the compiler; and he will be most thankful to have, any omissions or inaccuracies in the list sent to him to be published as a third supplement in the next volume of- the Trans-actions. The author is indebted to Prof. J. J. Stevenson, of New York, Prof. P. R. Uhler and John W. M. Lee, Esq., of Baltimore, and Lloyd P. Smith, Esq., of Philadelphia, for valuable assistance. OFFICE, ALLENTOWN IRON COMPANY, 230 SOUTH THIRD STREET, PHILADELPHIA, September 5th, 1881. ALABAMA. Geological Survey of Alabama. Report of Progress for 1879 and 1880, by Eugene A. Smith, State Geologist. Montgomery, 1881. 8vo., 158 pp., and 2 maps. CALIFORNIA. Omit Report of Hon. T. Butler King, in Supplement 1. For Trash's Geology and Industrial Resources, etc., in Supplement I., read Tyson's, etc: Fremont's Memoir on Upper California, is also published as XXXth Congress, 1st Session. Senate Mis. Doe., No 148, and has a map. For Randall's Report in Supplement I, read Report of the Special Committee in favor of a Geological Survey, submitted by Mr. Randall, April 24th, 1851. a.d., 1851. 8vo., 1.9 pp. XXXIst Congress, 1st Session, Sea. Ex. Doc., No. 47, Part 2 [Part 1 is Tyson's Report.] Report of the Secretary of War in further compliance with the Resolution of the Senate, calling for Copies of

Jan 1, 1881

By C. T. Yavuz

Higher environmental standards have made the removal of arsenic from water an important problem for environmental engineering. Iron oxide is a particularly interesting sorbent to consider for this application. Its magnetic properties allow relatively routine dispersal and recovery of the adsorbent into and from groundwater or industrial processing facilities; in addition, iron oxide has strong and specific interactions with both As(III) and As(V). Finally, this material can be produced with nanoscale dimensions which enhance both its capacity and removal. The objective of this study was to evaluate the potential arsenic adsorption by nanoscale iron oxides, specifically magnetite (Fe3O4) nanoparticles. We focused on the effect of magnetite particle size on the adsorption and desorption behavior of As(III) and As(V). The results show that the nanoparticle size has a dramatic effect on the adsorption and desorption of arsenic. As particle size is decreased from 300 nm to 12 nm the adsorption capacities for both As(III) and As(V) increase nearly 1000 times. Interestingly, this increase is more than expected from simple considerations of surface area and suggest that nanoscale iron oxide materials sorb arsenic through different means than bulk systems. The desorption process however, exhibits some hysteresis with the effect becoming more pronounced with small nanoparticles. This hysteresis most likely results from a higher arsenic affinity for magnetite nanoparticles. This work suggests that magnetite nanocrystals and magnetic separations offer a promising method for arsenic removal.

Jan 1, 2006

By C. Twigge-Molecey

All projects that are implemented, have been given corporate go-ahead on the basis of a set of clearly defined targets. These are typically a production goal at a capital cost, operating cost and production schedule, that will yield an acceptable return on investment by the companies internal criteria. The challenge for the implementation team is two-fold, firstly to properly define the project criteria prior to board approval and secondly to deliver an operating facility that meets these objectives, in particular the ROI. The paper addresses the issues a project team and the company management must address for a successful project. Key questions that will be explored are: ? What is the status of key technologies? Are they well proven in commercial practice, completely novel or in between? ? Is the project schedule driven by market constraints or cash flow constraints? ? Are the risks of fast tracking worth the potential rewards? ? For a retrofit project, are all the technical and production interfaces and issues known at the time of approval to proceed? ? How much should be invested in technological development and engineering and at which phase? ? For an owner-operator, how much responsibility is it wise or appropriate to push down to vendors? The answers to these questions for a specific project will define how you go about a project, the resources required, the contracting strategies, the phasing and the appropriate level of investment in the definition and procurement phases, prior to starting major capital commitments and construction.

Jan 1, 1999

By Stephen P. Harrison

The ventilation of coal mines has long been a major challenge for the mining industry. Prior to the 1969 Health and Safety Act, mine ventilation planning was almost entirely handled by individuals in mine operations and engineering who had extensive practical experience. Their background and expertise was sufficient to deal with existing ventilation problems and planning. A recent decline in the number of qualified individuals combined with more stringent state and federal regulations have necessitated a thorough engineering oriented approach to ventilation in mine planning design. To plan for an existing mine, a thorough ventilation survey must be conducted to determine the capabilities of the existing ventilation network. A ventilation survey also provides considerable useful data for long range planning. Essential information such as friction factors, entry resistance, and potential ventilation problem areas is gained from the survey data. With this information a comprehensive computer analysis can be conducted to evaluate alternative mine plans. This evaluation of mine plans is essential to minimize the number of shafts required while still maintaining the quality of mine ventilation. Using an existing mine as an example, this paper outlines a detailed procedure for organizing, con-ducting, and evaluating a ventilation survey. In addition, specific ventilation problem areas are isolated and alternative methods for their solution are considered. Furthermore, a long range mine plan is evaluated and the most feasible variation of the plan is selected.

Jan 1, 1980

By Tetsuo Yamazaki

The Kuroko-type seafloor massive sulfides (SMS) in the western Pacific have received much attention as sources for economic recovery of gold (Au), silver (Ag), copper (Cu), zinc (Zn), and lead (Pb). Since the end of the 1980s, the Kuroko-type SMS have been found in the back-arc basins and on oceanic island-arc areas. In Okinawa Trough (Halbach et al., 1989) and on the Izu-Ogasawara Arc (Iizasa et al., 1999) are the typical representatives in the Japan’s EEZ. They yield a higher concentration in Au and Ag than the SMS found in ocean ridge areas (Rona, 1985). Similar formation processes with the Kuroko ore deposits on-land in Japan have been expected and outlined by many researchers (Sillitoe, 1982; Scott, 1985). The higher Au and Ag contents have increased the chances for profitable mining operation, which is under consideration by a private company (Malnic, 2001). Information about the resource potential of the targeted Kuroko-type SMS deposit, such as the amount of SMS ore body, the inside structure, the mean metal yields, and the geographical details are necessary for a technical and economic validation analysis for the development. The Sunrise Deposit of Myojin Knoll on Izu-Ogasawara Arc in the Japan’s EEZ is selected as a target for the technical and economic validation analysis. The relatively higher amount of information on its resource potential is the reason why the deposit is selected.

Sep 24, 2006

By Frederick Prime

In this second supplementary list no titles to which an * is pre fixed hare been seen by tlie compiler; and he will be most thankful to have any omiesisne or inaccuracies in the list sent to hiin to be ptiblisi~cd as a third supplement in the next volume of the actiotra. The author is indebted to Prof. J. J. Stevenson, of New Tork, Prof. P. R. Uhlcr and John 'CV. M. Lee, Esq., of Balti more, and Lloyd P. Smith, Esq., of Philadelphia, for valuable assistance. office, allkntorn iron compaxy, 30 South Third Street, Philadelphia, September 5th, 1881. Alabama. Geologiml Survcy of Alabama. report of Progress for 1879 and 1880, by Eugene A. Smith, State Geologist. Montgomery, 1881. 8vo., 158 pp., and 2 maps. California. Omit Report of Hon. T. Butler Ring, iu sopplemeut I. For Trask's Geology and Illdustrial honrecp, etc., in Supplenlvut I., read Tyson's, etc. Fremont's Menloir on Upper Califijrnia, is also published as XXXth Congress, lat Session. Senate Ms. Doc., No 148, and has a map. For Randall's Report in Supplement I, rend Report of the Special Committee in favor of a Geological Snrvey, subrn-itted by Mr. Randall, April 24th, 1861. n.d., 1851. 8cWo., 19 yp. XXXIst Congress, 1st Session, Sen. Ex. Doc., No. 47, Part 2 [Part 1 is Tyson's Report.) RejW of the Secretary of War in further compliance with the Resolution of the Senate?, calling for Colbies of

Jan 1, 1881

A novel process is being developed for metal recovery from waste electrical and electronic equipment involving a leach reactor coupled to an electrochemical reactor. Metals such as Ag, Au, Cu, Pb, Pd, Sn etc. are dissolved from shredded electronic scrap in an acidic aqueous chloride electrolyte by oxidising them with aqueous dissolved chlorine species. In the electrochemical reactor: (i) chlorine is generated at the anode for use as the oxidant in the leach reactor, and, simultaneously, (ii) at the cathode, the dissolved metals are electrodeposited from the leach solution. The extended Butler-Volmer equation was used to provide predictions of the electrode potential dependences of partial current densities and, hence, total current densities, current efficiencies and alloy compositions for acidic aqueous chloride electrolytes containing Ag(I), Au(III), Cu(II), Pb(II), Pd(IV) and Sn(IV) species, together with dissolved chlorine. With judicious choice of kinetic parameters, the predicted total current density ? electrode potential behaviour of such solutions was in good agreement with experimental data for a rotating Pt disc electrode. Reduction of dissolved chlorine at a Pt rotating disc electrode exhibited mass transport controlled behaviour, in agreement with Levich?s equation over the potential range 0.3-0.9 V (SHE). This could form the basis of a linear sensor, possibly using a microelectrode for measurement and control of the dissolved chlorine concentration in the efflux of leach reactors and inlet to electrowinning reactors in the envisaged process.

Jan 1, 2003