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By R. L. Pascual, W. J. Whiten

"The froth flotation process is not well understood. Both flotation models, and the parameters used to describe the stream flows are not well defined. They in fact vary considerably in different applications. This creates difficulties is designing a simulation program suitable for use by plant personnel, consultants, and researchers. In addition to simulation, an effective simulation program can be expected to provide a range of other services.This paper shows how a process circuit simulator can be designed with sufficient flexibility to satisfy these needs, and discusses some of the additional services."

Jan 1, 2003

By Howard S. Avery

The wear resistance of an alloy in heavy mill liner sections may be quite different from that of the same alloy in small balls and other light sections. This fact was established by means of a well standardized laboratory test that was validated for ball mill service. The salient properties of mill liner alloys, including austenitic manganese steels, medium alloy hardenable steels, and abrasion resistance cast irons are described, critically compared, and quantitatively ranked in terms of mill liner service. Where they are tough enough the high-chromium and other martensitic cast irons (e.g. Ni-Hard) promise maximum economy, but their section sensitivity is a limitation. To overcome this an extensive research program studied over a hundred experimental alloys, ranking them for heavy section abrasion resistance by means of the laboratory test. Computer analysis of the results provided a parabolic formula in terms of composition, the apexes of the parabolas providing optimum wear resistance. From the extensive family of parabolas one apex was selected for intensive study in experimental liners, pilot plant production, development of quality controls, and finally full scale production. This is a 19% chromium iron critically alloyed with nickel and molybdenum and hardened by heat treatment. It has excellent resistance to various types of abrasion, but its chief advantage is in heavy mill liner sections, where it has about 25% better abrasion resistance than the best of the quality controlled chilled Ni-Hards. It is also tougher. After production problems were solved, a number of ball and rod mill tests were arranged on a guaranteed performance basis. Two of these, representing about 138,000 pounds of mill liner castings, have recently confirmed in service the superiority that was predicted by the laboratory tests.

Jan 1, 1969

By Dr. Anurag Agrawal, Fathur Rozaq, Nella Lubis, Relinda Sanistya, Herry Saputra, Rudolf Sitorus

In mining operations, basic drone applications such as pre- and post-blast photo comparisons, blast video recordings, and sample-based fragmentation analysis are often used to assess blast performance. However, these methods lack the depth needed for comprehensive evaluations, leading to suboptimal results. This study explores the innovative integration of drone mapping technology with artificial intelligence (AI) at the Martabe Gold Mine in North Sumatra Province, Indonesia, to address these limitations. High-resolution drones and ground control points (GCPs) are utilized to create detailed orthomosaic maps, and advanced AI algorithms are applied to enhance the accuracy of blast performance insights. Field experiments reveal substantial improvements in comprehensive blast performance evaluations through this integrated approach. Enhancements include improved pre- and post-blast evaluations, AI collar detection, fragmentation size measurements, heave muckpile profiles, cast material measurements, floor prediction models, and muck pile topography volume, which is vital for ore tonnage predictions. Notably, this method achieves an average volume accuracy of 1% compared to light detection and ranging (LiDAR) technology. While LiDAR is known for its precision, the drone-based method offers a highly accurate, cost-effective, and user-friendly alternative suitable for mining applications. Despite LiDAR's superior precision, our approach provides a practical solution due to its accessibility and ease of implementation. In conclusion, the integration of advanced drone mapping and AI technologies has the potential to revolutionize blasting operations. By addressing the limitations of previous methods, this approach meets the evolving needs of the mining industry and sets new standards for accuracy and effectiveness in blast performance assessment. The combination of high-spectral drone images and AI-based software analysis demonstrated nearly 99% accuracy in ore tonnage prediction models compared to LiDAR, showcasing its promising capabilities.

Jan 21, 2025

By John D. Hanifin, C. Kevin Moon, Eric C. Wang

Value Engineering on Connecticut DOT’s Walk Bridge selected the trenchless option for utility relocation to address the channel crossing’s environmental concerns. The design and construction considerations of the twin micro-tunnel drives and associated shafts are presented. Key challenges included vertical alignment selection to achieve minimum one-tunnel diameter stable cover within thin glacial till underlying extremely soft clay, limited choice of pipe and joint materials meeting stringent non-metallic conduit requirements, thermal grout backfill application, and the close proximity of temporary trestle piles. Mitigation measures were developed for potential point loading pipe damage from remnant boulder fragments in the annular space.

Dec 1, 2022

By Brian Lewis, Reinhold Daykin Schnell

Blasting specifications and guidelines are very important aspects of detailed project specifications covering any scope of work (SOW) that involves explosives and blasting procedures. A lot of larger construction or tunneling projects require some degree of project specifications for the entire scope of work on such project, including blasting specifications. It is important that all blasting specifications effectively and accurately address all explosives and blasting concerns associated with the SOW for such project. This includes safety and security, required personnel and their associated responsibilities, procedures and applications involving explosives, blast design and planning, blast monitoring and reporting, quality assurance and quality control, and local, state, and federal regulations and limitations. With the of wide range of information required in blasting and overall project specifications along with the risks associated with work involving explosives, it is also important to ensure qualified personnel are involved in interpreting or compiling and approving any blasting specifications and guidelines. The purpose of the following paper is to explore and present the basic information, as summarized above, that should be included and considered in the creation of detailed blasting specifications and guidelines. Detailed information is presented in specific relation to a potential bid package that would be compiled for a construction or tunneling project requiring protective or high-profile blasting.

Feb 6, 2023

By J. C. Gathje

The Robinson copper ores were mined for many years from pits containing varying ore grades, sulfide and oxide ore types, and differing mineralogy. The ores also contain gold and molybdenum values, and their recoveries are an integral part of the flowsheet development. Metallurgical responses were characterized using a standard flotation procedure. Further studies investigated primary and regrind particle sizes, reagents, and other variables. The metallurgical testing was supported by mineralogical studies. Results demonstrated a high degree of metallurgical success for flotation. Final copper concentrates ranged in grade from approximately 28 to 30% copper and copper recoveries were 89 to 95% based on laboratory and pilot plant data.

Jan 1, 1992

By M. Moinpour, E. Liao, C. Y. Aw, D. J. Brown, P. W. Cheung

"Currently, silicon-based insulated-gate field-effect devices are being widely developed as the basic structural elements in a new generation of chemical microsensors. In this paper, we discuss some of the process considerations related to the fabrication of the Chemically Sensitive Field-Effect Transistor (CHEMFET). This ion-sensitive CHEMFET (or ISFET as it is often called) can be used for pH measurements (i.e., as a pH sensor) when the gate insulator of the electrolyte/insulator interface is made of Si3N4 obtained by the LPCVD method. Effects of processing parameters such as the Si3N4 deposition rate, gas composition, total flow rate, annealing treatment, etc. on Si/Si02, Si/Si3N4 and Si/Si02/Si3N4 structures are discussed in relation to the CHEMFET fabrication. Their effects on the electrical characteristics and chemical response of the sensor are also examined. Capacitance-Voltage (C-V) measurements and ESCA analysis have been used to interpret the results. The Si3N4/Si02 double dialectric layer provides improved ion blocking for the gate insulator in electrolyte solutions with enhanced pH sensitivity over time. The stability and performance of the fabricated CHEMFET sensors were tested by measuring the pH sensitivity in various storage conditions. The SEM analysis was used to evaluate the hydration effect at the ISFET's gate insulator with respect to different storage conditions.IntroductionThere has been a continuous interest in the development and fabrication of various chemical microsensors for chemical and biomedical applications over the last fifteen years. The application of semiconductor (particularly silicon) technology to the area of sensor fabrication has led to an emergence of a new generation of miniaturized, microelectronic, solid-state chemical sensors. There are numerous clinical situations where continuous monitoring of body electrolytes concentrations such as Na+, K+, Ca+2 , etc. and blood gases (pH, Po2 , and PC02) would be essential for the effective diagnosis and management of patients under critical conditions. Solid- state microsensors can be used for direct and continuous in vivo measurement of the above parameters in most instances."

Jan 1, 1988

By Phil Rice, Mohammed Nasim, Richard Flanagan

"The Gateway Trans-Hudson Partnership (GTHP), a joint venture of WSP USA, Inc., AECOM USA, Inc, and STV Incorporated, is providing preliminary engineering services to Amtrak for the Hudson Tunnel project as well as supporting the NEPA process for getting the record of decision (ROD). This preliminary engineering design effort by GTHP includes geotechnical exploration and laboratory testing, design of structures, tunnel contract packaging and procurement planning.The Hudson Tunnel Project includes the construction of a new Hudson River Tunnel system and rehabilitation of the existing North River Tunnel. The new tunnel system will be constructed south of the existing North River Tunnel, from North Bergen under the Palisades to Hoboken in New Jersey, below the Hudson River, and connecting directly to Penn Station in New York (Fig. 1). The tunnel system is configured as two single-track tubes, intermediate ventilation shafts and cross passages in compliance with NFPA- 130 requirements. The adjacent surface alignment west of the Palisades will be constructed on viaducts, embankment and retained fills. The existing North River Tunnel (Fig. 2) consists of two single-track, electrified rail tunnels extending from tunnel portals in North Bergen, New Jersey to Penn Station in New York. Completed in 1910 by the Pennsylvania Railroad, the tunnel opened at the same time as Penn Station and the four, single-track, East River tunnels that connect Penn Station to Queens and onto Long Island and New England, respectively. Both tunnels in the existing North River Tunnel were inundated with brackish river water during Superstorm Sandy (Fig. 3), resulting in the cancellation of all Amtrak and NJ Transit service into New York City for five days. After the brackish water was removed from the tunnels, the residual chlorides and sulfates have had on-going detrimental impacts on the interior concrete and rail systems."

Sep 1, 2019

By N. A. Beier, N. Slingerland

"Oil sands tailings impoundments rank among the largest (spatially) in the world, covering a total of approximately 220 km2 of northern Alberta, Canada. A preliminary geomorphic design for an oil sands tailings storage facility (TSF) landform was completed with the goal of eventual closure and delicensing in mind. This paper outlines methods identified during the design process that streamline closure when implemented early in the mine planning and TSF design stages. With most oil sands TSFs currently in active operation (and some still in the planning stages), geotechnical engineers and mine planners have the opportunity to make operational and design decisions, such as those outlined herein, that are likely to improve the geotechnical and environmental performance of the landform post closure. ¦ KEYWORDS Alberta, Athabasca oil sands (AOS), Landform design, Reclamation, Sand dam, Tailings storage facility (TSF) RÉSUMÉ Les bassins d’accumulation des résidus issus des sables bitumineux font partie des plus grands (en termes d’espace) au monde, et couvrent au total environ 220 km2 dans le nord de l’Alberta, au Canada. Une conception géomorphologique préliminaire a été réalisée pour le modelé d’une installa¬tion de stockage des résidus (ISR) issus des sables bitumineux en gardant à l’esprit la fermeture et le retrait de permis à terme. Cet article présente les méthodes identifiées pendant le processus de conception qui simplifient la fermeture lorsqu’elles sont mises en oeuvre dès les premières étapes de planification de la mine et de conception de l’ISR. La plupart des ISR issus des sables bitumineux se trouvent dans des exploitations actives (dont certaines en sont encore aux étapes de planification), aussi les ingénieurs géo¬techniques et les planificateurs miniers ont la possibilité de prendre des décisions en termes d’exploita¬tion et de conception, telles que celles présentées ici, qui pourraient améliorer la performance géotechnique et environnementale de la phase suivant la fermeture du modelé. ¦ MOTS CLÉS Alberta, assainissement, barrage de sable, conception du modelé, installation de stockage des résidus (ISR), sables bitumineux de l’Athabasca (SBA)INTRODUCTION The Athabasca oil sands (AOS) underlie 140,200 km2 of land in northeastern Alberta, Canada. Oil sands located within 100 m of the original surface account for 4,800 km2 of the total area and are considered to be economically mineable (Figure 1; ERCB, 2009). Bitumen, the thick, tar-like substance contained in the AOS, is extracted through open-pit mining and in-situ methods. During mining, the overburden is first removed as waste and the sandy, bitumi¬nous ore (“oil sand”) is transported to processing facilities via conveyor belts and 400 t trucks. Warm and hot water, as well as process aides such as caustic soda, are mixed with the oil sand, creating a slurry from which bitumen is mobilized and extracted. The resulting slurry waste product is called “tailings” and contains mineral solids, process water, and small proportions of unrecovered bitumen (Masliyah, Zhou, Xu, Czarnecki, & Hamza, 2004; Sobkowicz & Morgenstern, 2009)."

Jan 1, 2019

By H. J. Glass

Collection, preparation, and analysis of blasthole chippings is expensive. Frequently, interpolation of grades at unsampled locations is considered using techniques like kriging. A pre-requisite for kriging is that an experimental variogram is established. In order to assess the quality of the experimental variogram, a measure is developed in this paper. The measure is derived from analysis of the time-honoured expression relating the variance, semivariance, and covariance. It reflects the weighted average deviation of the summed semivariance and covariance from the biased variance. The proposed measure allows assessment of the influence of key variables on the quality of the variogram. Using simulated data, it follows that the quality improves with an increasing number of samples, increasing density of the sampled locations, increasing regularity of the sampling pattern, and increasing uniformity of grades in the absence of correlation. Application to real data shows that the minimum number of samples could coincide with a marked decrease in the value of the measure. Establishing a threshold value is subject to further research. Keywords: variogram, variance, covariance, semivariance, minimization, sampling.

Jan 1, 2003

By C. Dai, S Raathiv

The Waikato Expressway is one of the New Zealand Transport Agency’s (NZTA) seven roads of National Significance. Coffey is part of the City Edge Alliance engaged by NZTA for the Hamilton Section of the project. The 22km Hamilton Section is the largest and most geotechnically complex section of the Expressway. The Mangaonua gully in Sector 6 is the most challenging geotechnical area of the project for piling works. Together Coffey and Brian Perry Civil have carried out the temporary and permanent design and construction of embankments, piling works, retaining walls and soil improvement works for the bridge construction. The design and construction works were governed by weak alluvial layers and artesian pressure layers several meters beneath the ground level. This paper presents the action taken to improve the foundation of temporary platform, control the artesian pressure, prevent bentonite leakages into the highly permeable alluvial layer and challenges in the base grouting process. This paper summarises the key components in the construction and supervision of bored piling works and outlines innovative solutions for challenges which we faced during the construction.

Nov 1, 2022

By Yoginder P. Chugh

This paper discusses design of sprays systems for dust control around a continuous miner (CM) in about 4.2 m (14 ft.) high mining areas with about 1.0 m to 2.0 m (3-6 ft.) of out-of-seam dilution mining. The challenges included low air volumes and velocity at the end of the line curtain, dust produced from out-of-seam dilution rock being very fine with 50% of the particles less than 10 micron, poor capture of aerosol through scrubber suction inlets, dust escaping through the sides of the loading pan in mining high areas, overloading of dust-laden air in the wet-scrubber, and dust rollback toward workers. The challenges were resolved through CFD modeling of airflows; improved line curtain installation, redesign and varying the spatial locations of spray systems as compared to low mining height areas. Water sprays on CM is the primary engineering control for dust control in coal mining. In 2010, the authors developed several spray system concepts for dust control (Chugh, Patwardhan, Gurley, & Hirschi (2009), Chugh & Gurley (2009), Chugh 2012). These included increased contact time between dust particles and water droplets, improved potential for the dust aerosol to be sucked in through suction inlets, and reduced dust-roll back to the operators and workers. CFD modeling was used to understand airflow patterns around mining areas and to identify spatial locations for sprays to minimize dust exposure of CM operator (CMO), haulage unit operator (HUO), and workers downwind of the operating CM in the last open crosscut (LOXC). Face area ventilation plays a key role in dilution and removal of dust generated by mining operations. High mining heights and large pillar sizes associated with longwall mining reduce the air volume reaching the face area to achieve good dust dilution.

Aug 1, 2013

By John J. Sammarco

The U.S. Bureau of Mines is conducting research into computer-assisted mining, which requires investigation of new techniques for development and application of computer-based technologies. Today's technology can require significant effort in software development, as has become evident in the early stages of this Bureau research. Technologies for software automation, such as computer-aided software engineering (CASE), are available. This report explores CASE, its general features, and its importance in software development. Information is presented to assist in selection and application of the variety of CASE tools and methods for automating various stages of software development. When evaluating CASE for use, it is important to examine tools that support an organization's existing methods of software development. Support for existing hardware platforms must also be examined. Merely selecting a "good" CASE tool does not insure success. Thorough evaluation of implementing CASE is also critical. Subjects to evaluate for CASE implementation include organization culture, support from management and end users, training resources, and pilot projects. Organizations that benefit the most from CASE evaluate CASE features with respect to their needs and they properly implement CASE.

Jan 1, 1990

By ByongPil Lee, Changkyu Lee, Jin Gyun Park, Hyung Sub Eom, Sung-Koo Jo, Jae-Young Lee, Gilsoo Han

"A new hydrometallurgical process for nickel extraction from a low grade laterite ore such as limonite has been developed by RIST and POSCO. This POSCO Nickel Extraction Process (PosNEP) consists of five main processes: ore reduction using hydrogen as a reductant; acid leaching at atmospheric pressure and temperature; cementation by the use of reduced-ore seed; production of the main product such as ferronickel or a high purity nickel compound; and production of by-products such as cobalt and iron in the forms of cobalt sulfate and iron oxide. In addition, hydrogen produced in acid leaching and hydrochloric acid regenerated in pyrohydrolysis for iron oxide production can be reused in the process, which makes PosNEP more cost-effective. The performance of PosNEP has been proven through pilot tests, showing that this process is economically and technically viable. In this paper, basic concepts and detailed test results of PosNEP are shown.INTRODUCTIONNickel has been extracted from two types of ore, sulfide and oxide ore. Nickel and cobalt usually occur together in the ores. The principal ore mineral of the sulfide is pentlandite, (Ni,Fe)9S8, which is easily beneficiated to produce sulfide concentrates(Moats & Davenport, 2014). These concentrates are usually treated by smelting and converting to make a matte. The produced matte is then purified through either hydrometallurgical or pyrometallurgical processes to produce high-purity nickel. In general, this process for sulfide ore has been known as a more cost-effective process than that for oxide ore.The oxide ore is laterite comprised of two different ore types, saprolite and limonite. The main nickel-bearing mineral of saprolite is nickeliferrous garnierite,(Mg,Ni)6Si4O10(OH)8, and that of limonite is nickeliferrous goethite (Fe,Ni)O·OH ore (Moats & Davenport, 2014). Since the saprolite has high contents of nickel and slag formers (MgO and SiO2) and a low content of iron, it tends to be treated by a pyrometallurgical smelting process such as calcination and electric furnace techniques to produce ferronickel for use in stainless steel. In this process, the cobalt in the ferronickel does not have any economic value."

Jan 1, 2017

By Jim Sarvinis, Mark Berkley, David Clarry, Jason Berzansky

"Technologies developed to sequester CO2 or use CO2 for enhanced fossil fuel recovery are currently being utilized across the globe. Taxation regimes and CO2 credit trading are becoming drivers for a number of projects. Some mining companies have also identified ancillary opportunity to sequester CO2 in their by-products; recent work in the alumina industry is a prime example. In addition to process plant emissions, mining companies are becoming increasingly aware of their overall carbon footprint, including CO2 generated during the production of utility power. New power plant designs, in various stages of development, include CO2 separation and sequestration techniques. This paper summarizes the state-of-the-art for these technologies; including integrated gasification combined cycle (IGCC) power plants. A concept to use the gasification products as reductant in metallurgical processes is also described. The relevance of technology from power plant designs with post-combustion capture to the processing of off-gas generated in metallurgical facilities is also reviewed.IntroductionGlobalization and international economic growth have led to an increase in energy demand worldwide, and a corresponding increase in greenhouse gas (GHG) emissions. In 2005, 81% of global energy supply came from fossil fuels [1]; and while alternative energy technologies are emerging, it will require many decades to curb society’s fossil fuel dependence. Given the global concern of climate change and its scientific relationship with anthropogenic carbon dioxide (CO2), there is at present great interest in the development of techniques to reduce emissions of CO2. While most of these efforts are related to power generation and energy efficiency, the development of technologies for CO2 capture may offer opportunities in reducing emissions from industrial processes."

Jan 1, 2008

By Nathaniel Schaefer, Christopher Newman, Zach Agioutantis

"As mining reserves continue to be developed in deeper and more complex geological and geometric conditions, there has been an increased demand for underground mine designs to better reflect site-specific conditions, measurements, and observations with respect to ground control safety and stability. Current ground control design software are limited to a given device and data files generated can only contain a single design. However, with the growth of cloud computing and increases in internet access, even underground where permissible, web-based software applications allow for in-the-field calculations, as well as collaborations, from multiple users. webGroundControl (webGC) utilizes a multiple-tier architecture, building upon existing NIOSH ground control design software, more specifically ARBS, ALPS, and ARMPS. By providing operators the ability to access ground control design programs from any device, given an internet connection, webGC allows for on demand calculations to ensure underground pillar and roof stabilities with respect to current site-specific parameters, geometries, and geology. Through the development of new features, which aid in design analyses, as well as project collaborations, webGC provides the modern engineer with a more versatile ground control design tool for the improvement of underground health and safety. With the completion of the ARBS, ALPS, and ARMPS modules, this paper introduces potential users within the mining industry to the navigation and operation of the webGC application, as well as its ability to facilitate collaborations between operational personnel and planning engineers. The purpose of this paper is to raise interest in the web-based application before its official launch in Summer 2018."

Jan 1, 2017

By S. Abu-Samra

By virtue of its complex nature, the construction industry comprises a wide spectrum of interrelated variables and factors. This multifaceted character of the construction industry puts the use of engineering modeling tools and techniques on top of project management necessities. This research introduces a macro-level earthmoving management system using Genetic Algorithms (GAs) to reach the optimum allocation of earthmoving equipment. The Earthmoving Equipment Management System (EEMS) functions through four integrated modules: (1) A Central Database containing information about projects and available equipment; (2) An Equipment per Segment Selection module that calculates the cut and fill quantities, plots the Mass Haul Diagrams, and selects the equipment types to be used for each segment; (3) An Equipment Pool module which determines the production and cost for each available equipment, based upon the project site conditions; and (4) An Optimization Engine equipped with a GA optimization solver. This engine formulates the optimum earthmoving cost for all projects, by changing the number of allocated equipment. The Optimization Engine takes into account the number of available equipment and calculates the weekly equipment allocation. The EEMS model was implemented on an earthmoving company conducting five different projects on hand. The model proved to be an effective tool in providing decision makers with optimum equipment utilization on a multi-project scale to minimize the earthmoving cost. The results were then compared with the company?s existing micro-level management system, demonstrating better performance on the level of savings, amounting to 13% of total earthmoving cost.

Aug 1, 2013

By William H. Pomroy

Spontaneous combustion fires involving high-sulfide-content ores are a relatively infrequent yet serious safety hazard in mining. They are also the cause of lengthy mine shutdowns because they typically occur in areas of a mine where abundant fuel material is present but which are inaccessible for fire fighting. This Bureau of Mines report describes research to design, fabricate, and test in the laboratory and field a system that warns of spontaneous combustion fires in metal mines. Overall performance of the detection system was found to be satisfactory, in that the system was capable of reliably detecting low levels of combustion products believed to indicate the preflaming stage of spontaneous combustion in metal mines. Installation of similar systems in mines with a high risk of spontaneous combustion is recommended. Principal operating problems and recommended corrective actions are also discussed.

Jan 1, 1987

By Wei Victor Liu, Na Zhang, Chengkai Fan, Bei Jiang

This study used artificial neural networks (ANNs) coupled with Gaussian mixture modeling (GMM) to analyze truck haulage data from openpit mines. The proposed weighted ensemble models performed better than benchmark models in predicting truck productivity, providing a new means of solving complex data and improving mine planning and decision-making.

Jun 1, 2023

By H. E. Wilde

"Zinc has been used for many years as a galvanic coating for the protection of steel. Electrochemical measurements show that zinc actually overprotects steel. The corrosion rate of DQSK (drawing quality semi-killed) steel in air saturated salt water was determined as a Junction of applied cathodic potential. The resulting data indicate that at a critical cathodic over potential of - O. 725 Vsce an acceptably low corrosion rate of less than 1 mpy occurs. Using the developed criterion, alloys of Zn/X and AL/X were produced and evaluated in galvanic contact with steel in a standard laboratory test. The results indicate that Zn /Mn, Zn /Co, AI/Mg/Si and AI/Mg/Ge alloys offer excellent galvanic protection along with (a) no hydrogen evolution, and (b) improved dissolution life over Zn coatings.IntroductionZinc coated (galvanized) steel has been successfully used in applications where bare (or painted non-galvanized) steel would suffer corrosive attack. In general, galvanic coupling to zinc, as either an anode or a coating, is an effective means for combatting steel corrosion. Because of this, the use of galvanized steel has increased markedly, stimulated primarily by automobile manufacurers seeking to extend the corrosion warranties on automobiles(1).Although effective, zinc coatings are not without a number of drawbacks which warrant efforts to improve them. For example, because of the widely differing electrode potentials between zinc and steel ( - 1.05 Vsce and - 0.60 Vscc, respectively, in air saturated NaCl solutions), the zinc corrodes at a rapid rate to protect the steel. This is reflected in the limited lifetimes of galvanized unpainted siding. The basic electrochemistry controlling the situation is shown in Figure 1, for a system controlled by oxygen reduction. The zinc corrodes sacrificially to protect the steel, while cathodically polarizing the steel to a potential near that of zinc's open circuit anode potential."

Jan 1, 1990