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By A. H. Burns

"Regenerative and recuperative burner systems require advanced combustion techniques to minimize NOx emissions. Various methods of pollutant minimization and furnace design considerations are described. Cited examples are a large high temperature furnace and a small Zinc vaporizing furnace. The concept of total carbon footprint is introduced. The application of Biomass combustion as an effective method of cost and green-house gas (GHG) reduction is discussed. Practical considerations of scale, location and process limitations are discussed. Two examples of biomass fired equipment are cited. Ideal sites have large biomass resources available locally. Processed biomass fuels will be an important substitute for fossil fuel. INTRODUCTIONIn 1992, I presented a paper entitled Combustion Strategies In The Modern Industrial Environment (1992). At that time an abundant supply of cheap fossil fuel made many of the measures I talked about difficult to justify for anything but new equipment.Since 1992 we, as a society, have demonstrated an ability to accelerate the pace of industrial and societal change. The term industrial revolution applied to this age of incessant change is completely meaningless, implying a discrete moment in historical time. What our society has built is a system capable of unfettered, continuous and accelerating technological change. With this change comes an increasing demand for energy and materials.This year is the anniversary of the Titanic disaster, a moment in time when technological certainty met the caprice of nature and gave us a brutal reminder of what can happen to us if we underestimate that power (Mowbray, 1912). In the intervening interval we have regained the technological arrogance that was lost in 1912 bringing us back to the problems of climate change and the need for sustainable industrial activities.We use advanced mathematics to describe many complex systems, sometimes with disastrous results. For example there has been a recent attempt to model the global economy as a completely deterministic system. This premise is flawed at its foundation as human nature and emotion are indeterminate constants in the equations, yielding probabilistic solutions at best. As engineers we are all familiar with stiff problems. The solution to such a problem is meaningless and we have all had the misfortune to live through and rue the effects of that miscalculation over the last few years."

Jan 1, 2012

By M. Downing

This paper gives a brief overview of impacts of coal blending on coal-fired power plants performance and discuses the preliminary results of an on-going study aimed at evaluating the effect of coal properties on the effectiveness, compatibility and thermal reactivity of coal blends. Plant survey studies reported no significant impacts on an existing plant designed for a high rank coal when switched to a blend of low-and high-rank coal. However, slight modification of some aspects (handling, fuel storage/stockpile, transportation, preparation, and general housekeeping) of plant design and operation may be necessary. The preliminary results of an on-going study at the Mineral Industry Research Laboratory shows that more compatible and better blends could be made from coals where ranks are closer than from those where ranks are far apart.

Jan 1, 1997

By T. A. George, David J. Sellmyer

"The concept of achieving a useful high-energy-product magnet through appropriate nanostructuring of known hard and soft phases has been tantalizing researchers since the idea was first proposed. The fabrication of exchange-coupled nanocomposite magnets faces several challenges including aligning the easy anisotropy axes of the hard-phase grains. Here we investigate experimentally two-phase nanostructures of hard Lio-ordered FePt and soft iron-rich/cc Fe(Pt). The Fe-Pt thin films were produced by epitaxial cosputtering onto MgO (001) single-crystal substrates which lead to strong (001) texturing. The measured hysteresis loops indicate nearly ideal exchange coupling. Excellent magnetic properties are obtained, with largest values of coercivity (51 kOe), saturation magnetization (1287 emu/ cm3, J, = 16.2 kG), and nominal maximum energy product (58 MGOe).1. IntroductionA key figure of merit for permanent magnets is the maximum energy product (BH)rrw.x. The achievable maximum energy product is determined by a magnet's saturation magnetization M, and its magnetic anisotropy. For example, it is well known that (BH)rrw.x :S 4n2M,2• In the past, record energy products have been the result of discovering new compounds with high values of magnetization and anisotropy. However, finding new compounds with better magnetic properties than the current record-holding magnet Nd2Fe14B has proven to be difficult. A different approach is to exploit the exchange coupling mechanism between known hard and soft magnetic phases to enhance the maximum energy product [1-5]. In such a composite system, high coercivity is achieved due to the anisotropy of the hard phase as well as a nanostructure which prohibits large-scale domain wall reversal mechanisms. Magnetization is enhanced by the soft phase and loop squareness results from texturing of the hard phase easy-axis as well as complete exchange coupling between the coexisting hard and soft grains."

Jan 1, 2012

By D. Wolfe, R. Cleminson

"The Aurora North mine has been operating for more than ten years, and is the source of over half of Syncrude’s bitumen production. The slurry systems at Aurora experience high rates of wear, and mission lengths on current slurry pumps are nominally 1500-2000 hours. Recent work has enabled a better understanding of the significant adverse effect of large particle impingement damage to impeller vane leading edges - which is the known life determining issue for Aurora hydrotransport pumps. A new pump design has been developed with a larger diameter impeller and increased vane lengths, and is expected to triple Aurora’s mission length for hydrotransport pumps.INTRODUCTIONSlurry Pumps are Critical Equipment at SyncrudeSlurry pumps are a critical component in Syncrude’s operations. In a typical Aurora application, each pump stage helps move over 8000 dry tonnes per hour of oil sand, plus an equal volume of process water that has been added to create the slurry. The average impeller life in oil sand hydrotransport service at Aurora has been nominally 1500-2000 hours, or 12-16 million tonnes of oil sand pumped. Generally, the slurry pump application at Aurora has proven very difficult to improve due to the unique combination of high sand abrasivity, 125 mm (5”) large particle top size (lumps), and high flow rate relative to basic pump size; a factor that results in higher than optimal impeller vane speeds for the service conditions.PROJECT BASISSlurry Pumps are the Reliability Bottleneck at AuroraSlurry pumps are currently the shortest-lived components that determine the overall system run length at Aurora, in Hydrotransport, Extraction and Tailings. Vibrating screens and piping had been previous bottlenecks, but their reliability has been improved through upgrades in equipment design and wear materials. Both vibrating screens and piping can now achieve 4000 hour mission lengths."

Jan 1, 2013

By Diana Diaz, Rakshith Shetty, Vitaly Proschenko, Mike Mooney

Cohesive clay soil poses a significant risk to earth pressure balance tunnel boring machines (EPBM) due to unstable face pressure, clogging potential, high cutterhead torque, poor muck flow, low advance rate, etc. This paper details the performance measures desired when EPBM tunneling in clay soil, and the scientifically-supported conditioning methods to transform in-situ clay to a muck with such characteristics, giving particular attention to ground conditions. The paper then examines TBM data from multiple clay soil projects in the context of these performance measures to demonstrate the influence of cohesive soil conditioning on EPBM performance.

Jun 13, 2023

By J. P. Harrison, G. F. Gambino

"This paper examines unpredictability in the parameters governing hydraulic fracturing (HF) as used in stress amelioration for underground excavations, with the aim of showing how this unpredictability may affect design decisions. Using uncertainty models that are appropriate to particular levels of information and degrees of uncertainty, this paper demonstrates how these can aid in decision-making related to feasibility assessments of HF arrays for stress amelioration.Cave mining operations produce large underground voids and high stress concentrations around critical mine locations. These stress concentrations increase the potential for rock burst events. Although de-stress blasting has a long history for redistributing high stress concentrations, to improve safety and reliability HF is now being trialled as an alternative.Unfortunately the HF process is extremely uncertain, and so predicting fracture propagation geometry is difficult. Although the major parameters governing HF propagation have been previously identified, no indication has been given regarding the contribution that uncertainty in these makes to unpredictability in the overall HF system. Using simplified models of HF and referencing a recently proposed characterization of unpredictability, we relate unpredictability in the various governing parameters to the effect it has on strain energy density (SED) in the surrounding rock. Within these models we analyse SED as well as the stress intensity factor (KIc) when investigating the effect of parameter uncertainty and its influence on various crack propagation criteria (Sih & Macdonald, 1974). These models are applicable to unpredictability associated with the development of new fractures; the case of pre-existing fractures is the subject of on-going work.The paper will assess in greater detail the various governing parameters, and investigate the appropriate use of other uncertainty models. As a result, we will show how assessment of uncertainty in HF parameters can be used to both guide feasibility studies and determine the optimal allocation of resources to improve the final design."

Jan 1, 2015

By Aly M. Mohammad

Croton Point Avenue Bridge carries Croton Avenue over Metro-North main tracks at Harmon Rail Yard in Westchester County, New York. The new bridge is 1100 foot long and 36 foot wide nine span structure with three spans continuous units. The spans are steel multi-stringers, composite with concrete deck. The piers are solid wall piers and the foundations are spread footings. During the design of the bridge foundations it was determined that the relatively loose to medium dense sand layer is susceptible to liquefaction under a design earthquake with a seismic coefficient of 0.15g. Several foundation options were considered for the new bridge including both shallow and deep foundations. It was determined that the most cost effective alternative is to use spread footing foundations supported on densified soils. Vibratory probes were utilized to densify the loose to medium dense sand layer and reduce the risk of liquefaction. Densification test sections were performed to determine the optimum spacing for the vibro probes. The test sections included performing piezocone tests before and after the densification to compare the increase in relative density of the sand. In addition, ground surface settlement due to the vibro probes was measured and correlated to the increase of soil relative density. The paper will present the results of the ground improvement method utilized and correlate the spacing of the vibro probes and the increase in relative density and the results of the piezocone tests performed before and after the densification. It was found that the vibro probes are not as effective as thought at shallow depth below the ground surface. It is believed that the results and finding presented in this paper will benefit both the design and construction industries by providing a relatively cost effective means to improve the soils

Jan 1, 2007

By S Barrow, D Kent

Controlling the access of equipment, and people, has become more critical over the last few years for improving productivity and to meet safety responsibilities imposed by legislated obligations to have safety management systems. Hence Mine Site Technologies (MST) has spent the last three years completing the development of the tagging system to meet the mining industryÆs requirements, particularly streamlining access control. The basic tagging system tracks active Tags carried by personnel, or attached to vehicles and equipment, within underground zones. These Tags are detected (read) by Beacons placed strategically throughout the mine. As a Tag, or Tags, go past a Beacon they are read and the information transmitted back to the main database PC. This allows the current whereabouts of personnel and equipment to be known, as well as the history of their movements. The objectives of implementing the TRACKER Tagging System at Oaky No 1 Coal Mine were to: maintain a count of personnel inbye a particular point, and can alarm when a pre-set number is reached (eg the limit imposed by availability of SCSRÆs, etc); maintain a count of vehicles (and vehicle type) inbye a point, and can alarm if when a pre-set number is reached (eg when rated diesel units exceeds the limit for the ventilation present in that zone); manage the vehicle fleet, by keeping track of various vehicles underground better control and dispatch management of the equipment is achieved; keep track of equipment, knowing the location of equipment (such as forks, baskets, pumps, fans, etc) where last used or stored will minimise the risk of losing gear and assist in keeping inventory to a minimum; and locate personnel in emergency situations, by placing read Beacons throughout the mine the location of all personnel can be known in real time so that in the event of an emergency, their withdrawal can be monitored.

Jan 1, 2005

By M. M. Oosterveld

"In South West Africa diamonds are mined from ancient beach deposits by the Consolidated Diamond Mines of South West Africa, Limited.To improve the control of mining production, a computer is used for the calculation of statistically more accurate and homogeneous ore blocks. Geological and sampling information has been digitized and stored on magnetic files.The figures derived for each block entail the calculation of the diamond size frequency distribution, the diamond density distribution and the ore reserve by using the density distribution.The diamond size frequency distribution is used for estimating the revenue in an ore block.A description is given of how a linear programming system can be used for production planning."

Jan 1, 2014

By J. Sattarvand, P. C. Augustine

Despite significant safety improvements, the mining industry remains one of the most hazardous occupations globally and the evacuation of Miners, when an uncontrollable incident occurs in the mine, is the best bet to saving lives. However, Human factors/behaviors during an emergency are likely to influence the evacuation performance. Other industries have made a significant effort to determine these human factors that can impede evacuation performance, however, the current state-of-the-art in mine evacuation or self-rescue is that the evacuation route is predetermined, and a static sign is used to direct miners to the predetermined safe location. This method is limited in representing actual conditions that arise in a real emergency, neglecting the different behaviors displayed by humans. As optimization of the evacuation of a mine plays a fundamental role in emergencies and modeling evacuation behavior and movement of miners is a complex task, this research utilized Agent-Based simulations to simulate the evacuation behavior and performance. It was observed that people with the smart evacuation device made fewer mistakes and arrived at the safe place in less time compared to those have no access to the device. The Mathematical model used in optimizing the shortest path to a safe place is also explained in this paper.

Jun 25, 2023

By Clifford H. Summers

This report describes an experimental program which we conducted on behalf of the U. S. Bureau of Mines, to select from currently available materials two novel systems of construction for air-restraining bulkheads to be used in control of radon-polluted air in underground uranium mines. The program included both laboratory and field tests, the latter conducted in a portion of an operating mine owned and operated by Union Carbide Corporation at LaSal, Utah. The test site was a worked-out, double entry stope having a Volume of about 2000 cubic meters, and was located immediately adjacent to an exhaust airway. The bulkheads were constructed of 15 cm x 1.5 cm timber uprights, 5 cm x 15 cm horizontal members supporting a close-fitted 13 mm plywood curtain-wall., which was covered with a low-permeability membrane to seal in the radon-polluted air. The two membrane materials selected for testing were chosen from a list of twenty-two potentially acceptable candidates using criteria such as strength, flammability, ease of application, adhesion, radon permeability, and elasticity. Thirteen of the candidates were tested in our laboratories for adhesion to plywood and to both wet and dry concrete (simulating wet and dry mine rock surfaces), and for their general physical properties, including radon permeability. The final selections made by the Technical Project Officer, and based on our recommendation, were a pre-formed ethylene propylene diene monomeric rubber (EPDM) membrane 1.12 mm thick, normally used as a roof sealant in industrial construction, and available from Carlisle Tire and Rubber Co., Division of Carlisle Corp., Carlisle, PA, and Aquafas 48-00, a water-based mastic used in a wide variety of commercial applications and available from H. B. Fuller Co., Foster Products Division, Spring House, PA. The EPDM membrane was applied as a single sheet, laminated (dry) between two layers of plywood, and the Aquafas was applied both by troweling and spraying onto a plywood surface. In the field test, radon concentrations were continuously measured before, after, and in the trapped air behind each bulkhead. Temperature, pressure, and velocity of the air in the adjacent airway were also measured and recorded continuously. Radon fluxes at the rock/air interface and through the bulkheads themselves were measured manually on a frequent basis. All continuously acquired raw data were recorded automatically on two USBM Data Aquisition Systems (DAS), and the raw data were converted into engineering units and recorded on magnetic disks by a specially programmed microcomputer that was interfaced with the DAS's. Relatively clean (i.e. low radon concentration) air was pumped into a point near the face of one test bulkhead from a location 170 meters away through vent bag. Several air curtains and two air-restraining bulkheads were erected in passageways adjacent to the test area in an effort to control both velocity and radon concentration of the air flowing past the bulkhead faces. An average concentration of approximately 500 pCi/liter at a flow of 550 m3/minute was attained as the background concentration against which leakage through the bulkheads was measured. The entire field test period extended from October, 1981 to March, 1982, a total of six months, and was subdivided into seven successive time periods: 1) site preparation 2) background measurements prior to bulkhead construction 3) passive restraint, with bulkheads in place and totally sealed 4) open bleeder period of natural convection ventilation in and out of the bulkheaded area through a 10 cm (diameter) opening, with connecting tubing; leading into an Exhaust airway 5) open bleeder period, having forced exhaust through a 1.0 cm opening using a servo-controlled fan 6) charcoal trapping period, using the servo-controlled fan to exhaust air through the charcoal traps, to test the effectiveness of such traps in removal of radon from the exhausted air 7) site decommissioning Each of the two systems tested, one incorporating the pro-formed EPDM-rubber membrane and the other utilizing Aquafas 48-00, was assessed for effectiveness in controlling radon-polluted air by observing the change in the radon concentration in the ventilation air flowing continuously over the surface of each bulkhead. The sensitivity of the observed measurements was limited by the volume flow-rate of the ventilation air and the radon concentration in that air. The data would indicate that the observed increments in radon concentration in the ventilation air moving across bulkheads B-l and B-2 were essentially zero within the limits of sensitivity of the measurements. Data from radon flux measurement taken both on the sealed ribs adjacent to the bulkheads and on the bulkheads themselves did not differ significantly from blank data.

Jan 1, 1982

By A. C. Ter-Oganesyants, N. N. Anisimova, G. P. Kotukhova, G. N. Dylko

The process utilized at Norilsk Nickel Polar Circle Division for treating slimes from the electrorefining of copper and nickel was developed in the late nineteen fifties and has survived without any fundamental changes. This technology is a combination of pyro and hydrometallurgical operations to produce PGM concentrates that are sent away for refining. The characteristic feature of the current technology is multiple-stage, extended cycle treatment with significant incomplete production, low labour and automation efficiency and poor hygiene and sanitary conditions. To eliminate all negative aspects mentioned above, specialists of Norilsk Nickel Polar Circle Division have developed a new hydrometallurgical process for treating electrolytic slimes. The main steps of the flow sheet developed are autoclave leaching of the slimes and electrochemical opening-up of a cake from autoclave leaching. The implementation of the new process will allow Norilsk Nickel Polar Circle Division to shorten the process cycle 4-5-fold thus reducing the volume of incomplete production, considerably increase labour efficiency, simultaneously improving working conditions, upgrade the final concentrate, reducing costs and increasing PGM recovery during refining and, ensure higher security of precious metals by employing automated processes and vacuum sealed units.

Jan 1, 2004

By Wei Bin, Liu Zhe, Liping Xiao, Jichi Bai

The Acid Mine Drainage has characteristics of low pH, high concentrations of heavy metal ions, such as Fe2+, Mn2+, Cu2+ and Zn2+. In this paper, the composite particles that consisted of bentonite and steel slags were used to dispose the Acid Mine Drainage. Bentonite is the mineral materials and can adsorb heavy metal ions excellently. The steel slags are alkaline and industrial solid waste for the treatment of the Acid Mine Drainage. The main influencing factors, such as adsorbent dosages, shaking rates, concentrations of heavy metal ions, temperatures, adsorption time and pH value were studied by the static experiment. Increasing the adsorbent dosages and the concentrations of the heavy metal ions, speeding up the shaking rates, raising the temperatures, extending the adsorption time and improving pH would improve the removal efficiencies of heavy metal ions. Through considering the removal efficiencies and the treatment costs, the optimum reaction conditions for the four kinds of heavy metal ions were obtained. The adsorbent dosage 21 mg/L, the rotational speed 120 r / min, the temperature 25?, adsorption time 100 min and the initial wastewater pH 7. The four kinds of heavy metal ions existed independently in the simulated mine wastewater. The highest initial concentrations of Fe2+, Mn2+, Cu2+ and Zn2+ were 150 mg/L, 100 mg/L, 170 mg/L and 140 mg/L respectively. The removal rates were 93.42%, 92.64%, 93.86% and 95.17% respectively. The determination of the particles’ SEM-EDS Microscopic characterization showed the composite particles could play a part in neutralizing, absorbing and the chemical precipitation. The acidity decreased notably and the heavy metal ions of Fe2+, Mn2+, Cu2+ and Zn2+were adsorbed and precipitated effectively. The research results can extend the practical engineering application of the composite particles.

Jan 1, 2017

By E. M. Cox, A. S. Skapski, N. H. Nachtrieb, M. C. Bachelder

D. T. ROGERS*—The conclusions drawn in this paper have important practical significance to the steelmaker and the metallurgist if, in practice, it is demonstrated that metallic copper in the charge will pick up sulphur from the furnace atmosphere and thus increase the sulphur content of the bath. The problem of residual copper arising out of increasing copper in the scrap available to the industry is, in itself, a matter of concern to the steel maker. If, in addition to the often detrimental effects of high residual copper upon the physical properties of some important steel grades, there is to be a complication of the sulphur problem, then we have a set of conditions that bodes no good for the open hearth melter and the open hearth metallurgist. M. B. BEVER*— Investigations of gas-metal equilibria continue to be of interest, especially as new possibilities for improving experimental techniques emerge. Higher purity of reacting substances, better refractories, improved methods of temperature control and an increased awareness of the pitfalls of high-temperature equilibrium work are

Jan 1, 1950

By John J. Schanz

The ideal entering freshman for the College of Mineral Industries possesses the necessary aptitude to complete successfully a difficult technical curriculum, has a highly developed intellectual curiosity and adequate preparation in basic mathematics, sciences, and English, is enthusiastic about pursuing a career in the mineral industries, and puts forth a good academic effort while attending Penn State. The present programs of the University?s Division of Counseling and the College of Mineral Industries are directed toward providing the College with students who will meet these requirements. At present, freshmen are admitted to the Pennsylvania State University without entrance examination if they are in the upper two-fifths of their high school classes. All Pennsylvania students in the lower three-fifths are required to take the University Aptitude Test and all out-of-state students the College Entrance Board Examinations. Such students are admitted only if they score sufficiently high on either test to indicate the ability to do satisfactorily the work of University students. Only to this extent, are native intelligence and areas of greatest aptitude known for the Freshman prior to admission, and they are, therefore, largely beyond the control of either the Division of Counseling or the College of Mineral Industries. Because all freshmen, with exceptions that are numerically minor, are required to select a curriculum before admission to Penn State, each student who presents himself for required counseling during the summer, prior to his first semester, has already made a choice of his course of study. In many instances, such choices have been made without a rational and serious consideration of the student?s abilities and interests. Through tests given between the date of admission and the date of the counselling interview, it is possible to measure these characteristics and for the Division of Counselling to advise the student of his chances of success in his chosen curriculum. If he is qualified for the curriculum he has selected, Counselling Service goes on to direct the student?s attention to those other curriculums which are in the same general area as the one he has chosen and which will also challenge his abilities and correspond to his interests, Through this counselling, the curriculums of the College of Mineral Industries, which are often less well known to high school students than others for which they are no more qualified by ability or interest, are brought to the attention of the incoming freshman.

Jan 1, 1959

By B. Voyzelle

The deterioration of highway and bridge infrastructure has received considerable attention in recent years because of the billions of dollars needed for repair and rehabilitation. A major factor contributing to this problem is the corrosion of steel reinforcement. Reinforcing steels with good corrosion resistance and relatively low price are therefore essential for maintenance, cost reduction and service-life extension of the steel-reinforced structures. This article describes the development of low-alloying steels that offers good corrosion resistance with reasonably low cost. Topics include steel microstructures, mechanical properties, corrosion performance, industrial applications and economic aspects.

Jan 1, 2005

By J Fewings, T McCredden, S Seet, C Fitzmaurice

"Flotation of nickel sulfide ores are generally constrained by nickel grade and impurity concentrations (notably magnesium and arsenic) in the product delivered to smelters. Being a physical separation process, flotation recoveries and grades are limited by the grade recovery curve of a particular operation, where increasing product grades are invariably associated with lower recoveries. Impurities put further pressure on this relationship, as removal of impurities from the final concentrate is almost always associated with nickel losses.Western Areas Ltd are developing a proposed expansion to its Cosmic Boy concentrator to treat an impurity stream, that is high in nickel and would otherwise report to tails. Through the use of BioHeap® technology Western Areas aims to recover the nickel and discard the arsenic to tailings. This expansion will consist of a biohydrometallurgical plant that leaches the nickel arsenic minerals, removing the arsenic as a stable iron/arsenic hydroxide, while recovering the nickel as a high-grade nickel sulfide product (at approximately 50 per cent nickel). This can then be blended with final concentrate to improve nickel grades and recoveries, while simultaneously reducing impurity levels or used to produce high value products like nickel sulfate.The introduction of a small microbial leach plant may be beneficial to base metal concentrators constrained by impurities or grade.Citation:Fewings, J, Seet, S, McCredden, T and Fitzmaurice, C, 2016. BioHeap® - Breaking the Grade/Recovery Curve for Nickel Concentrators, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 361–368 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By J. S. Hegwer, P. M. Dunlap

An improved acid for the treatrrzent of sulfate-con-raining limestones and dolomites is described. The acid is designed to reduce he reprecipitation of dissolved calcium sulfate and the possibility of plugging permeable flow channels. In addition, this improved acid has a much lower reaction rate than that of regular acid; the advantages of a "retarded" acid are obtainable. Field testing of the acid has shown it suitable for use in sulfate-containing formations. Substantial improvements in productivity generally resulted. INTRODUCTION Acid treatments of limestones, dolomites and other formations bearing carbonate deposits are frequently unsuccessful when the calcareous formation contains sulfate, either as anhydrite (CaSO,) or gypsum (CaSO4. 2H2O). Preliminary dissolution in acid followed by redeposition of calcium sulfate appears to be a major factor contributing to poor well performance after acidizing. The precipitate is usually the gypsum form of calcium sulfate, but in higher temperature formations it may be anhydrite. The freshly precipitated crystals are nearly always very small and needle-like. They may occupy a gross volume many times that of the original anhydrite crystals and will obviously constitute an impediment to flow through newly enlarged flow channels. It is believed that the redeposition problem is most severe when anhydrite lines the fracture systems and large pores which supply the effective permeability of a formation. Microscopic inclusions of calcium sulfate also present large sulfate surface areas for dissolution in acid. In either case, great amounts of calcium sulfate may dissolve before the acid can be spent on formation carbonates. For regular spent acid (originally 15 per cent hydrochloric acid) the precipitate could be as much as 270 Ib gypsum/1000 gal acid. Two techniques have been applied by the industry for reducing sulfate plugging during acidizing. The method'.' commonly employed in the field is the attempted removal of a quantity of regular treating acid before it has reacted completely with the formation. This is practiced because the solubility of calcium sulfate is greater in a solution that is still acidic than in one which has been largely spent on the formation rock. The chance of precipitative plugging is therefore reduced if the withdrawal is successful. However, it is often impossible to get the acid out of the formation before precipitation occurs. A second possible method, which at first glance appears practical, involves addition to the acid of sequestering agents which form strong soluble complexes with calcium ions. These chemicals do increase the "solubility" of calcium sulfate in fresh acid, but to a lesser extent in spent acid. The sequestering agents have, therefore, proved unsatisfactory because the amount of sulfate eventually deposited from the spent acid may be greater than that from regular acid. Another logical approach to the problem of calcium sulfate reprecipitation is the prevention of the initial dissolution of calcium sulfate by the common ion effect. This may be accomplished by adding a soluble calcium salt to the fresh acid. The use of calcium salts in treating acids is not entirely new. An earlier suggested use of a soluble calcium salt in hydrochloric acid apparently failed to recognize the full extent to which the solubility of calcium sulfate could be suppressed. The present study extends this earlier work and adds certain improvements toward the development of a practical anti-anhydrite acid. LABORATORY DEVELOPMENT Calcium Sulfate Solubility Table 1 shows the results of a laboratory study performed to establish the effect of calcium chloride concentration on gypsum solubility. Because of the strong tendency of calcium sulfate to form supersaturated solutions, accurate solubilities are difficult to determine. These solubility data probably are reliable to within ± 15 per cent. The solubility of calcium sulfate in 15 weight per cent hydrochloric acid increases with increasing temperature. This trend is also followed in hydrochloric acid which cantains calcium chloride. This is contrary to the solubility behavior of calcium sulfate in water, wherein the solubility decreases with increasing temperature.

By Italo Onederra, Gary Cavanough, Ewan Sellers

Reactivity of ammonium nitrate based explosives is associated with the presence of iron sulfides in the ground reacting with explosive products and in some instances causing spontaneous reactions which can lead to detonation. The stability of explosive products can also be linked to in-hole density, which influences detonation efficiency, breakage performance and the potential generation of Nitrogen Oxide (NOx) fumes. Reactive ground testing involves detecting a temperature rise of a mixture of a bulk explosive product sample, a ground rock sample and some specific chemical agents. This paper describes improvements in reactive ground testing involving the use of time lapse video analysis and detection of NOX gas emissions from the sample. Reactivity is stored and linked to a using cloud based software to map of the mine showing the exact location of the sample. The location marker can be selected to allow quick access to the sample test results and video. In addition to reactivity, the stability and detonation performance of bulk product can also be influenced by depth. In this paper, a system that simulates product at depth and measures density changes and monitors the structure of bulk samples is described. Results from an explosive product are analyzed and detonation performance is assessed by the measurement of velocity of detonation and detonation pressure.

Jan 1, 2018

By S. K. Kawatra, J. A. Halt

"INTRODUCTION Iron ore beneficiation needs advances in areas such as process control, automation, burner and furnace designs, silica-free binders, and even alternative iron making routes. While some – like new binders – are only step-changes, all are tools that can help make the ironmaking industry more sustainable. This paper focuses on binders. Binders are added to iron ore fines before they are agglomerated. Binders are used to control the balling process and increase the mechanical quality (e.g. strength) of green-balls and pellets. Agglomeration usually follows thickening and filtration. Good-grade ores, which don't require upgrading, are wet ground to decrease particle size and increase specific surface area. Low-grade ores are often extensively upgraded through wet operations (flotation, dispersion and selective flocculation, magnetic separation, etc.). For both types of ores, thickening and filtration conclude the circuits so that moisture contents are lowered and the ores can be agglomerated. It's been known for a long time that thickening and filtration behaviors are influenced by zeta potential (Sandvik, 1979). Highly-negative zeta potential is good for dispersion while low zeta potential is good for filtration. So, the zeta potentials of iron ore particles are lowered with additions of acid or carbon dioxide, for example, to increase filtration rates and throughputs (Eisele et al., 2005). What happens to particles as their zeta potentials are lowered? Particles aggregate together, effectively forming larger particles. How stable then, are those aggregates during mixing and balling? Are they easily broken up during mixing (if mixers are even used)? Are they broken up during balling? Or, do the aggregates resist breakage so that the availability of ultra-fines, which are so beneficial for agglomeration (Stone, 1968), is decreased? For plants where high doses of bentonite are used as binder, the above questions may be of no concern. The bentonite adds the necessary amount of fines; however, even at those plants, the calcium and magnesium contents in the water affect bentonite's effectiveness (more magnesium and calcium means less effective bentonite). (Engesser, 2003) For plants where new silica-free organic binders are being developed and used, the above questions may need to be considered. The binder is only amongst the iron ore particles for a short period of time – until it burns away or thermally decomposes in the induration furnace – so the liberation, availability and distribution of fine particulates is very critical for the quality of balls and pellets. It was hypothesized that high zeta potential conditions would lead to good pellets, while low zeta potential conditions would lead to relatively bad pellets."

Jan 1, 2018