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By NARAYAN K. BHAGAT, ARVIND K. MISHRA, C. Sawmliana, Rakesh Kumar Singh, Panchanan Hembram

Mining operations in close proximity to dwellings and sensitive structures present challenges in terms of mitigating the undesirable effects of blasting while maintaining productivity and ensuring the safety of surrounding communities. This paper explores the application of advanced blasting techniques, including the use of electronic detonators and the splitting of total explosive charges, to address these challenges. A series of experimental blasts were conducted, comparing blasts conducted with and without splitting of holes, to assess the impact on ground vibrations. The results demonstrated significant reductions in vibration magnitudes when implementing controlled blasting practices with splitting techniques. The findings highlight the importance of total explosive charge in determining ground vibration magnitudes within the danger zone of mine workings. The use of electronic detonators provided precise control over blast sequencing, contributing to safer and more efficient mining practices. These advanced blasting methods offer a practical and innovative solution for conducting safe mining operations near dwellings and sensitive structures, ensuring compliance with safety regulations while sustaining productivity.

Jan 23, 2024

By Ed D. Thimons, Douglas E. Pollock, Andrew B. Cecala, Gregory J. Chekan, Jay F. Colinet, John A. Organiscak

Researchers at the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) work to reduce respirable dust exposures in mining operations. One focus of this research is silica dust control for surface and underground operations in the metal/nonmetal mining industry. PRL researchers analyze dust sampling results from the Mine Safety and Health Administration (MSHA) to identify high-risk occupations to guide research efforts. Research is then conducted in an effort to improve existing technologies and/or develop new controls for reducing worker exposure to airborne silica dust. During the last few years, PRL researchers have conducted research related to the following goals: improving protection provided by enclosed cabs on mobile surface mining equipment, reducing dust generation from surface drills, reducing dust levels in iron ore operations, and developing a new method to clean dust from workers’ soiled clothes. A description of each of these controls and subsequent dust reductions quantified through site surveys will be provided.

By William L. Crentz

Late in the nineteenth century en active coal-mining industry was begun in the Lower Freeport bed near Reynoldsville, Pa., where the bed thickened to more than 10 feet in places . The coal was readily accepted as an excellent steam fuel. Much of the thick coal his been depleted, but there are many areas where the deposit averages about 14 feet in thickness. As the more desirable mining sites were worked out in the Lower Freeport bed, other beds were exposed from which will come the county's major cowl production in future. The Lower Freeport bed is still the most important bed in Jefferson County from a production standpoint. The Lower Kittanning bed is second. Sporadic mining is being done in the Upper Freeport, Upper Kittanning, Middle Kittanning, Clarion, and Brookville beds. Strip mining has permitted recovery of much coal that could not be mined profitably by conventional underground methods.

Jan 1, 1953

By Kessi E. Zicko, Eric A. Hackenberg, Paul J. Lewis

"Following snow melt and spring rains in 2011, a landslide measuring approximately 600 feet long and 300 feet in slope length occurred within the southbound roadway embankment of a heavily travelled 2-lane divided highway in North Central Pennsylvania. Driven steel piles were designed to stabilize the embankment slope. Factors affecting the selected stabilization technique included an adjacent reservoir, wetlands, the length and depth of the failure plane, extent of glacial lake deposits, excess pore pressures in the foundation soils, and an area of archaeological interest. Field reconnaissance and subsurface explorations including borings, instrumentation, geophysics, and laboratory testing indicated that glacial lake deposits were present in the toe region of the embankment. Instrumentation proved key in measuring excess pore pressures and in locating the failure plane, and geophysics was utilized to estimate the extent of the soft glacial lake deposits and to estimate pile lengths. The existing condition of the embankment was modeled in computer slope stability analyses, which were also used to help assign soil parameters. Significant costs were associated with constructing a berm due to the impacts on adjacent site features. Therefore, multiple rows of driven steel H-piles were designed for installation along the toe of the embankment. The design lateral load in the piles was based on slope stability analyses, and the pile size and number of piles were based on lateral pile computations with modified p-y curves to account for installing piles in an active landslide. The relationship between the factors of safety from slope stability and the LRFD pile design was significant in determining pile loads for lateral analyses.INTRODUCTIONA landslide developed along the lower portion of the southbound embankment of State Route 15 in Tioga County, Pennsylvania. The road passes through a steep valley and is located along the southern extent of the Tioga Reservoir. Although no damage to S.R. 15 was attributed to this landslide, the close proximity of the slide to the road posed a concern for the long-term stability of this section of roadway.This paper presents a summary of the site history; the subsurface conditions based on borings, instrumentation, a geophysical survey, and laboratory testing; slope stability analyses including alternatives assessment; and the pile design.SITE HISTORYS.R. 15 was originally located in the valley along the Tioga River and traversed through the towns of Tioga and Mansfield. Although the reason is unknown, it is interesting to note that Old S.R. 15 curved away from the river in the area of the landslide. In the mid 1970’s, S.R. 15 was relocated to the eastern hillside prior to construction of the Tioga-Hammond Reservoir by the U.S. Army Corps of Engineers. The relocated highway was constructed in stages. Two lanes of relocated S.R. 15 were initially constructed to carry one lane of northbound and one lane of southbound traffic. At this same time, the majority of the fill was placed for two future lanes immediately to the west, which would eventually allow for two lanes in each direction. The two eastern lanes would then carry northbound traffic after completion of the two southbound lanes to the west."

Jan 1, 2015

By Theodore H. Eyde

The porphyry copper province of the southwestern United States and northern Mexico, is the largest copper producing region in the world. Most of the deposits occur in Arizona which now produces over 54% of the newly mined copper in the United" States. As the many recent discoveries are brought into production, Arizona's share of the nation's copper production will increase. The term "porphyry copper" as used in this paper includes all deposits of generally low grade disseminated copper mineralization amenable to bulk mining techniques. Therefore, copper deposits such as Pima-Mission, Twin Buttes, and Vekol where the copper mineralization occurs principally in the intruded rocks will be considered as "porphyry copper" deposits. Most of the deposits have been discovered since World War II, consequently, the southwest, and particularly southern Arizona is perhaps the most intensively explored area for copper deposits on earth. Most of the major natural resource companies in the United States and Canada maintain exploration offices in southern Arizona. To illustrate the success of exploration efforts, the location of porphyry copper deposits either known or producing prior to World War II are shown on figure 1 and the deposits discovered since World War II which are either in production or in the exploration and development stage are shown on figure 2.

Jan 1, 1973

By Deepesh Yadav, B. S. Choudhary

Underwater drilling and blasting is conducted for deepening of sea channels for port berths, lake or reservoirs for water supply etc. so that rock dredging becomes easier. During this process there are several associated unwanted effects having potential to cause damage to surrounding structures and the environment, flora and fauna. Though all these ill effects can’t be completely eliminated but adopting controlled blasting techniques can minimize these to tolerable levels. It is recognized that ground vibrations resulting from rock blasting below water near dam may endanger the safety of earthen dams. Therefore, controlled blasting technique was used to ensure the safety of dam and its efficacy was established by monitoring of blast vibrations. The usage of small quantity of explosives confined in blast holes, non-electrical delay detonators and initiating each hole with a separate delay helped to minimize the ground vibration effects on surrounding structures.

Jan 1, 2018

By James P. Kimball

Jan 1, 1881

Mining has long been an important activity for the people of Australia . The Aboriginals used rocks and minerals in their culture many thousand years before European settlement. It was not until 1840 that silver-lead ore was discovered in the Mount Lofty Ranges , and developed as Australia's first metalliferous mine. The mining industry contributes significantly to all aspects of the Australian economy, generating substantial employment opportunities, investment and income, export earnings and royalties for Governments. While the mining industry in South Australia is small by comparison with Western Australia, Queensland and New South Wales, it is nevertheless a very important industry in the State.   With the discovery of the world's third largest Cu-Au-U-Ag resource at Olympic Dam in 1975, the State saw a period of intense exploration activity through the early to mid-1980s. However, failure to locate additional world class deposits saw a dramatic reduction in exploration activity during the late 1980s. A perceived lack of prospectivity was compounded by the recognition that exploration for such deposits was neither easy nor inexpensive in South Australia because more than 80% of the State is masked by surficial sand and silt.

Jan 1, 1995

By J Joy, A Bye, G V. Kizil

This paper demonstrates an application of a recently developed Risk-Cost-Benefit (RCB) Framework to environmental risk management in the mining industry. The environmental application of the RCB Framework as part of an ACARP project (Kizil, Bye and Joy, 2012) involved a thorough selection process with site visits and in-depth discussions with the case study siteÆs environmental management team. Under their guidance, the highest risk of environmental impact at the case study site was identified as æroad subsidenceÆ at the time when the project work was undertaken. This paper presents the unique application of the RCB Framework to examine the risk of mining-induced subsidence and its impact on one of AustraliaÆs busiest highways, with a traffic volume of 38 000 vehicles per day (NSW RTA AADT, 2008). The RCB Framework was employed to assess the optimum group of controls for road subsidence risk management to ensure highway availability while mining occurs. Whilst this paper focuses on road subsidence, the methodology employed can be directly applied to other environmental concerns including preparation for mine closure, rehabilitation planning and waste management. The RCB Framework incorporates mathematical modules which were developed to enable complex yet tightly integrated RCB calculations. The process integrates the risk-control effectiveness assessment to determine that the selected safety initiative is financially beneficial to the mine site and company. This concept has been applied to a number of high-risk mining areas targeting safety, productivity and environmental issues. This paper introduces the five-staged RCB Framework, incorporating the RCB tools RCBGEN (Risk-Cost-Benefit Generator) and RCEMETHOD (Risk-Control-Effectiveness Method), and demonstrates its practical application to the risk management of a road subsidence case study. The case study looks at potential pavement damages, in particular, the occurrence of pavement stepping on the surface of the highway as a result of vertical subsidence. This type of road damage was previously experienced at another major inter-city route while underground mining occurred in the region where the case study site is located. The RCB Framework has been successfully applied to the analysis of the road subsidence case study and determined the risk reduction and financial benefits of implementing a range of risk-controls. User-friendly RCB Charts to provide an aid for decision-making were produced. The value of using the RCB charts to achieve balance between risk, cost and productivity in the decision-making process for risk management has been explained. The case study determined that pavement slots and fibre-optic cable monitoring were relatively low-cost and effective controls applied in the mining industry for the first time at a global level.This paper supports the industryÆs ongoing efforts to manage risk to ALARP (as low as reasonably practicable) and achieve æzero harmÆ by providing a new Framework to more effectively establish the adequacy of controls.CITATION:Kizil, G V, Bye, A and Joy, J, 2012. Application of risk-cost-benefit analysis to highway subsidence due to mining, in Proceedings Life-of-Mine 2012 , pp 197-206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By W. L. Falconer

"IntroductionThe very recent emphasis on the importance of the northern portions of the Alberta basin as a prospective oil province has led the oil companies northward into new and undeveloped territory. Northern Alberta is a land of continuous forest, covering a plains-type topography. The plains are only occasionally broken by sharp, broad river valleys. Tributary streams head up quickly and very soon lose themselves in large undrained areas. It is these pseudo-swamps that cause most of the troubles and headaches of the oil explorer.The rivers have served as the main transportation arteries since people first ventured into this area. The bush is being pushed back, but the advance is slow and there is very little more than trappers' trails beyond a few miles from the Northern Alberta Railway lines and the recently built Grimshaw or McKenzie Highway. Indeed, bush and muskeg flank many miles of the railways and roads within as close a distance as fifty miles of Edmonton. Northern Alberta is pioneer country in the truest sense of the word, and our greatest problems derive from this fact. In all pioneer areas, the first requirement is the development of access roads, and before active oil exploraton can get down to the job at hand these roads and trails must be an accomplished fact. There are two factors in Northern Alberta which offer discouragement to the oil explorer: the first and greatest stumbling block is presented by the numerous muskegs, large and small; the second is the fact that road building uses up so much of reservation time. Of course, the second is aggravated by, and a direct result of, the first. So we come back to the main problem facing the development of the north - the muskegs."

Jan 1, 1950

By G. S. Hume

FOR MANY YEARS Canada lived in the hope of attaining a substantial production of petroleum and natural gas that, to geologists familiar with the sedimentary basins of this country, seemed an entirely reasonable expectation. There have been surges of exploration activity stimulated by oil and gas discoveries and development such as occurred in Turner Valley. However, it was not until the Leduc field in Alberta was found in 1947, and the significance of that discovery was realized, that the search became really intensive and continuons. Expansion now has become a matter-of-fact attitude based on results which would have been considered impossible of achievement a few years ago.

Jan 1, 1957

By Asa Weber

With continuing pressure from stockholders not only to maintain but to increase mineral revenues, producers have increased plant capacity. Depressed mineral prices have accentuated the trend toward higher production rates to maintain consistent cash flow, and these same trends have promoted the development of large-scale processing equipment. In addition to the need to handle increased throughput, larger flotation equipment can result in decreased capital-equipment and operating costs. The development of larger column and conventional flotation equipment relies, in part, on suitable scale-up procedures. To properly scale-up large flotation cells and columns, certain constraints and design parameters must be taken into consideration, including velocities in the vessel, residence time, solids suspension, and lip loading. This paper will review the design constraints and scale-up criteria for WEMCO® flotation cells. Scale-up criteria are augmented with computational-fluid- dynamics analyses and high-speed imaging techniques, as well as multiple regresesion analysis of in-plant operational data.

Jan 1, 1999

By Charles B. Newmarch

Abstract In the course of coal studies undertaken by the B.C. Department of Mines in southeastern British Columbia, special attention was directed to problems of coal seam correlation. Methods that had been used successfully in other coalfields were found, in the Crowsnest area, to have a restricted use or furnished only additional evidence that might prove helpful when used in conjunction with other criteria. A correlation technique involving semi-quantitative spectrographic analyses of coal ashes was developed. Elements detected in the ash include Si, B, P, Fe, Mg, Mn, Pb, Ti, Cr, Ga, Ca, Al, Ge, Ba, Mo, V, Ag, ?y;b, Na, Zn, Zr, Ni, Sr, Cu, K. Of these, the elements found to be most useful in correlation were Na, Ba, Si, V, and Mg. The element Na was invariably detected in the ash from one of the seams but was not found in samples taken from any of the others. In all of the four seams sampled statistically, significant differences in the amount of certain trace elements were noted. When the values obtained for these trace elements were portrayed in the form of histograms, the resulting diagrams had a characteristic shape for each seam. The diagrams provided a basis for seam identification within the limited area (8,000 feet by 4,000 feet) that was investigated. Introduction During the field seasons of 1946, 1947, and 1948 the British Columbia Department of Mines undertook a geological investigation of the coal measures of southeastern B.C. As field work progressed in the Crowsnest area it was found that, within the Kootenay formation, which contains all the commercial seams of the region, the coal beds are the most persistent stratigraphic units. Because of relatively rapid changes in ?both the thickness of the seams and the interval between seams, difficulty has invariably been experienced in attempts at correlation. Even short-range correlati0ns by able geologists who have worked in the Crowsnest coal basin have been questioned by the operating companies. It was apparent, therefore, that a more dependable correlation technique was needed so that stratigraphic and structural studies could be of greatest value. This paper presents, firstly, a summary of the results obtained in attempted correlations using methods that have been found effective in other coalfields. Secondly, a method based on semi-quantitative spectrographic analysis of coal ash is described and the apparently promising results are discussed.

Jan 1, 1950

By Chee S. Theng

As the 2017 president of the Society for Mining, Metallurgy & Exploration Inc., I am pleased to present the 2017 issue of the Transactions of the Society for Mining, Metallurgy & Exploration Inc., Vol. 342. A significant portion of the contribution that we make as a professional society is the publication of professional and technical papers that accelerate the advancement of scientific knowledge and enable the transfer of technology. Communication within the mining community is the key to a successful society. This technology exchange continues a tradition that dates back to the 1871 meeting of 22 mining engineers in Wilkes-Barre, PA, that resulted in the founding of the American Institute of Mining, Metallurgical and Petroleum Engineers (AIME). Those individuals envisioned that these transaction volumes “would form a most valuable and greatly needed addition to our professional literature.” This volume fulfills that pledge. The 2017 Transactions contains some of the most interesting research and insights from the past year and features an international slate of authors spanning industry, academia and government. Papers include the latest findings from the U.S. National Institute for Occupational Safety and Health (NIOSH), a special review article on Heap Leach Modeling, and articles from two Special Issues on Rare Earths. The 2017 Transactions consists of a total of 54 technical papers, encompassing all 21 papers published in 2017 in the Technical Papers Section of Mining Engineering (Vol. 69) and all 24 papers published in 2017 in Minerals & Metallurgical Processing (Vol. 34). Additionally, this volume contains 9 papers that are being published for the first time in this issue. The papers presented in this volume were written by some of the most distinguished professionals in the industry worldwide. All of the technical papers were peer-reviewed. The process of review and publication requires much hard work by authors, reviewers and our Publications staff. As the 2017 president of SME and on behalf of all our members, I would like to extend our gratitude to all whose volunteer efforts contributed to the publication of this volume.

Jan 1, 2017

By Louis H. Berkelhamer

"INTRODUCTION The method of differential thermal analysis suggested by Le Chatelier (1)1 in 1887 has recently emerged as an outstanding means of studying the constitution of various substances, particularly clays, soils, and miscellaneous hydrous materials (2). The literature ably discusses the applications and results obtained but has paid too little attention to specific details of construction of the apparatus. Knowledge of the apparatus is of importance to the experienced research man as is extremely useful to the novice v ho ventures into this field of analysis. Further, it is generally acknowledged that the variations in design and conditions of operation are one of the essential causes for differences in characteristic temperatures as reported by various investigators. A step forward in the elimination of such differences is the publication of the details of construction and operation of a simple and inexpensive apparatus that has proved useful at the southern Experiment station of the Bureau of Mines, where it was used in cooperation with the University of Alabama, Tuscaloosa, Ala."

Jul 1, 1944

By D. R. Tweeton

The U.S. Bureau of Mines has developed tomographic computer programs for geophysical applications and is distributing them as part of a Bureau plan to facilitate the transfer of technology to potential users. These programs were developed for predicting and monitoring the flow pattern of leach solution during in situ mining. The Bureau has also applied them to assessing high-wall blast damage and examining the integrity of mine-related geological structures. This report describes the curved ray program BOMCMTR (Bureau of Mines curved ray tomographic reconstruction), tells how to run it, and gives examples with synthetic and field data. BOMCRATR provides optional mathematical constraints to counteract the nonuniqueness of tomographic reconstructions with crosshole data. These constraints include limiting the maximum and minimum velocities, fixing the velocity at any point to any value, and establishing layers in which velocity does not vary with horizontal position. The user can test for nonuniqueness by varying the initial velocity pattern, The program can perform either curved or straight ray analysis. Ray paths are calculated analytically in triangular pixels, which is faster than incremental numerical approximations,

Jan 1, 2010

By C. B. Daellenbach

A prototype particulate size analyzer system was developed that would rapidly determine size distributions of homogeneous and two-mineral materials in the 74-micrometer (200-mesh) to 7-micrometer size range. The system sizes particles in a series of hydrocyclone elutriation steps and senses the weight of the five sized fractions by nuclear attenuation techniques. Size distribution of materials was determined from experimentally developed mathematical relationships that existed between particulate weight and the measured transmittance of gamma rays from an Americium-241 source. In the developmental phases, size distributions of three minerals (quartz, magnetite, and hematite) and a laboratory prepared two-mineral mixture of quartz and magnetite were accurately determined by the prototype system. In later stages of the investigation, semiconcentrates, an intermediate magnetic product from a taconite plant, were evaluated. Using 25-gram feed samples of this industrial material, the analyzer system was found to predict weight percentages for individual size fractions with an accuracy of ±0.85 percent or better at a 95-percent confidence level.

Jan 1, 1974

By R O’Sullivan, D Taylor, J G. McLellan, B Miller

The Mount Isa copper deposit is located adjacent to the city of Mount Isa, Queensland, and lies within a series of Palaeoproterozoic to Mesoproterozoic Superbasins. The deposit is hosted almost entirely within the Urquhart Shale (US), a unit of the Mount Isa Group sediments and part of the Isa Superbasin. The copper mineralisation is separated into two distinct orebodies: the X41 mine (1100 and 1900 orebodies) and the Enterprise mine (3000 and 3500 orebodies). The orebodies are situated in the hanging wall of the major controlling structures, the Paroo Fault, which has juxtaposed older basement Eastern Creek Volcanics against the younger Mount Isa Group sediments cf 1655 ± 4 Ma. Conjecture remains over the exact timing of this thrust event. However, it is clear that inflections on the Paroo Fault have a close association with the orebodies and are an important structural feature in the mineralisation of the Mount Isa copper deposit.The life-of-mine is reducing steadily and new geomechanical modelling techniques were employed to target structurally controlled mineralised zones in three dimensions. Following a structural review of the mine using underground mapping, structural data and core shed observations, a conceptual 3D mine model was constructed utilising existing data modelled in MineSight®. This conceptual model included all the main lithological units and structures. The conceptual model aimed to test the effects of deformation on the main lithological and structural components of the system and attempted to highlight areas of anomalous stress and strain that may indicate a higher likelihood of fluid focusing and mineralisation potential. This project was focused on testing the latter stages of a D3 event (NE–SW compression) and D4 event (SE–NW compression), which are considered to be responsible for the current location of the mineralisation.The fully coupled 3D finite element analysis models resulted in highlighting anomalous patterns of stress and strain and subsequent fluid flow as a result of the two deformation events. The NE–SW D3 simulation provided the best correlation with the known distribution of mineralisation. This event also indicated several areas on the Paroo Fault and within the US that have potential to host further areas of mineralisation. The SE–NW D4 simulation provided less of a correlation with known mineralised zones. However, this event may have been responsible for post mineralisation re-mobilisation of copper on a relatively small scale. Areas of maximum shear strain, shear stress, volumetric strain and fluid flow correlated well with areas of minimum principal stress and provided the best overall match with known mineralised zones. Furthermore, several additional highlighted areas provide a high potential for further discovery of copper mineralisation. Recent exploration drilling north of the Enterprise mine 3000 orebody, utilising geomechanical modelling as part of the targeting criteria, intersected copper mineralisation, providing further validation of the modelling results.CITATION:McLellan, J G, O’Sullivan, R, Miller, B and Taylor, D, 2014. Geomechanical modelling of the Mount Isa copper deposit – predicting mineralisation, in Proceedings Ninth International Mining Geology Conference 2014 , pp 197–206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By Zhigao Xu, Ming Wu, Jun Qu, Rong Zhang, Wenrui Nie, Ruan Chi, Zhenyue Zhang, Zhengyan He

The leaching processes and mechanisms of weathered crust elution-deposited rare earth (RE) ores with ammonium sulfate were investigated for their high efficiency and low consumption exploitation. The leaching process is a typical reversible heterogeneous ion exchange reaction in liquid–solid systems. The raw ore and leached tailings were analyzed by SEM and FTIR. Results indicated that no dissolution or structural changes of the ores occurred during the leaching process. The migrations of RE3+, Al3+, and NHþ 4 in the leaching process were studied under various liquid–solid ratios. With increasing liquid–solid ratio, the content of NHþ 4 adsorbed on clay mineral by physical effect decreased, NHþ 4 adsorbed by ion-exchange increased, and the content of exchanged RE and Al increased until reaching equilibrium. The adsorption capacity of the RE ores for NHþ 4 remained about 0.61–0.63 mg/g. It was difficult to desorb NHþ 4 from RE ores with washing water alone. The leaching mechanism of Al was the same as RE, but the leaching of Al slightly lagged behind RE. At the optimal liquid–solid ratio of 0.4:1, the leaching efficiencies of RE and Al were 95.51% and 90.99%, respectively, and 56.65% of NHþ 4 remained in the leachate. After impurity removal and RE precipitation, the leachate can be reused by replenishing fresh leaching agent. The aim of this study is to enhance the leaching process of RE, restrain the leaching of impurities, and decrease the consumption of leaching agents.

By Z. Jin, D. DePaoli, P. Zhang

"Phosphogypsum is a byproduct created during the production of industrial wet-process phosphoric acid. This study focused on recovering rare earth elements (REEs) from a Florida phosphogypsum sample and investigated the effects of removing detrimental impurities such as phosphorus pentoxide (P2O5 ), uranium (U) and fluorine (F) during the leaching process. Experimental results indicated that REE leaching efficiency increased rapidly, reached a maximum and then began to decrease with sulfuric acid concentrations ranging from 0 to 10 percent and temperatures ranging from 20 to 70 °C. At a sulfuric acid concentration of 5 percent and leaching temperature of 50 °C, REE leaching efficiency obtained a maximum value of approximately 43 percent. Increasing the leaching time or liquid/solid ratio increased the leaching efficiency. The leaching efficiencies of P2O5, U and F consistently increased with sulfuric acid concentration, temperature, leaching time and liquid/solid ratio within the testing ranges. A fine-grain gypsum concentrate, sized smaller than 40 µm, was separated from leached phosphogypsum through elutriation, in which the P2O5, U and F content levels were reduced by 99, 70 and 83 percent, respectively, from their content levels in fresh phosphogypsum. IntroductionPhosphogypsum is a byproduct generated during the industrial wet process of phosphoric acid production, in which sulfuric acid is used to digest phosphate rock. Gypsum (CaSO4·2H2O), the main component of phosphogypsum, usually accounts for 65 to 95 percent of phosphogypsum by weight.There are small quantities of impurities in phosphogypsum, such as phosphates (H3PO4, Ca(H2PO4)2·H2O, CaHPO4·2H2O and Ca3(PO4)2), fluorides (NaF, Na2SiF6, Na3AlF6, Na3FeF6 and CaF), sulfates, trace metals and radioactive elements (Rutherford, Dudas and Arocena, 1996). Global phosphogypsum generation is estimated at 200 Mt/a (Parreira, Kobayashi and Silvestre, 2003; Yang et al., 2009), but only about 15 percent is recycled as building materials, agricultural fertilizers or soil stabilization amendments (Tayibi Choura and Lopez, 2009)."

Jan 1, 2017