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By Aldo L. Furno

Sufficient quantities of combustible vapors are released by some sulfurs to produce flammable atmospheres under prolonged storage. Hydrogen sulfide and carbon disulfide appear to be the principal flammable constituents in the vapor space above molten sulfur. If sufficient carbon disulfide is present, ignition of the vapor-air mixtures can occur spontaneously on contact with the heated surfaces found within storage tanks.

Jan 1, 1963

By John S. Pack

The application of square shaft helical piers in expansive soils is a standard of practice in many areas of the United States. Over 20 years of performance monitoring show exceptional performance and economy will result if proper design procedures, specification requirements and installation procedures are followed. This is true for new foundations and the repair of existing foundations, including lightly loaded wood-frame structures on expansive soils. Proper design includes: 1) site geotechnical characterization, 2) pier layout such that each pier is loaded to its maximum design capacity, 3) maximize spans between piers, 4) minimize the number of piers, 5) isolate the structure from the expansive soil with an appropriate void zone below all grade beams, slabs or other components that would otherwise be in soil contact and 6) utilize only single helix piers. Proper specification employs a performance specification that specifies: 1) the design load on each pier with a suitable safety factor, 2) the minimum installation torque, typically 4,000 ft-lbs (5.4 kN-m), or refusal, 3) a minimum pier shaft steel Fy = 70 to 90 ksi (483 to 621 Mpa) and pier helix steel Fy = 80 ksi (552 Mpa), 4) 1.5 to 1.75 inch (38.1 to 44.5 mm) square shafts, 5) smooth shaft surface, 6) the ICC Evaluation Report (ER) number of the manufacturer and 7) the manufacturer ISO 9001 certification for material quality control. Proper installation requires: 1) equipment with sufficient axial compression force (crowd) on the pier shaft so the helix engages the soil and advances to the specified minimum installation torque or refusal, 2) additional specialized techniques for expansive soils and 3) qualified specialty helical pier installation contractors experienced in expansive soils who submit and utilize pier configurations, techniques and equipment that will most effectively and economically meet the specified performance.

Jan 1, 2007

By George T. Faust

The petrographic microscope plays an important role in the mineral dressing of nonmetallic materials. Petrographers and mineral technologists have evinced an interest in the technique developed, specifically, for mineral-dressing problems. The following dissertation makes the informa¬tion more generally available. ACKNOWLEDGMENTS The authors are indebted to O. C. Ralston, chief engineer, Nonmetals Division, and to Will H. Coghill, supervising engineer of the Southern Experiment Station for a critical reading of the manuscript. They are also indebted to their colleagues for technical information obtained in the course of cooperative work, in particular to J. B. Clemmer for the use of the data on fluorite.

Jan 1, 1940

By Clair Murdock, David Heath

The 1,280 MW Sir Adam Beck II Hydroelectric Project was constructed in the1950s, at Niagara Falls, Ontario, Canada. The twin intake tunnels total over 17 kilometers in length and pass deep below the City of Niagara Falls. The tunnels were excavated using drill and blast methods, with a top heading and bench approach. The shot rock was loaded with electric shovels and transported to the five shafts with off-highway trucks. The tunnel muck was hoisted to the surface by skip and transported by truck to disposal areas. The volume of underground excavation for the 15.55 meter diameter tunnels and the shafts exceeds 3,500,000 cubic meters, then and now the largest underground civil works excavation by drill and blast in the Western Hemisphere. The lining required over 900,000 cubic meters of concrete. All of this work was completed in three years, remarkable progress, considering the technology of the day, comparing very well with the rapid excavation and tunneling methods of the twenty-first century. Big, fast, and deadly—at least 20 lives were lost in construction accidents.

Jan 1, 2007

By S. Swanepoel, A. V. Cherkaev, Q. G. Reynolds, M. Erwee

Ferrochrome (FeCr) is a vital ingredient in stainless steel production and is commonly produced by smelting chromite ores in submerged arc furnaces. Silicon (Si) is a componrnt of the FeCr alloy from the smelting process. Being both a contaminant and an indicator of the state of the process, its content needs to be kept within a narrow range. The complex chemistry of the smelting process and interactions between various factors make Si prediction by fundamental models infeasible. A data-driven approach offers an alternative by formulating the model based on historical data. This paper presents a systematic development of a data-driven model for predicting Si content. The model includes dimensionality reduction, regularized linear regression, and a boosting method to reduce the variability of the linear model residuals. It shows a good performance on testing data (R2 = 0.63). The most significant predictors, as determined by linear model analysis and permutation testing, are previous Si content, carbon and titanium in the alloy, calcium oxide in the slag, resistance between electrodes, and electrode slips. Further analysis using thermodynamic data and models, links these predictors to electrode control and slag chemistry. This analysis lays the foundation for implementing Si content control on a ferrochrome smelter.

Mar 14, 2024

By J. Zachwieja

As part of a general review on study of surfactant blinding agents to improve gold recovery during cyanide leaching of carbonaceous gold ores, processes of CIL and RIL leaching using surfactants were investigated. When refractory ores were treated by surfactants, CIL and RIL leaching processes yielded significant improvement on gold recovery. This paper will discuss and compare the laboratory results from two different leaching processes on preg-robbing ores, as well as, illustrate the difference of potential fouling of the blinding agents on activated carbon and resins.

Jan 1, 2015

By Richard L. Ash

Usually stresses generated by explosive charges during blasting are considered to propagate through materials in a spherical manner. Although conical stress-waves had been suggested by a few investigators they have never been clearly defined or critically observed. An experimental technique using models and lengths of Mild Detonating Fuse was developed to produce conical stress-waves and study their effects. Several materials with different properties were tested to compare the influence of those properties on wave shape and crater formation. The investigations showed that whenever column charges were end-initiated, conical stress-forms were produced if the explosive's velocity exceeded the energy propagation velocity of the surrounding material. The stress-cone angle significantly affected fragment size and shape as well as the geometry of craters produced.

Jan 1, 1967

By R. S. Dean

In addition to the normal work and that pertaining to strategic minerals, the Metallurgical Division has been made responsible for carrying on major investigations in the development of processes' for the treatment of low-grade domestic manganese ores that heretofore have failed to yield products suitable for the preparation of ferromanganese, an alloy essential to every ton of steel produced. These investigations are particularly important at this time because of their part in tucking this country self-sufficient with regard to manganese when the stock-piled ore becomes e exhausted and as foreign shipments of ferro-grade ore are cut off. The results indicate that there is a good probability of accomplishing this objective, while at the same time conservation may be promoted through the use of normally useless material from the large, low-grade ore deposits.

Jan 1, 1941

By Osama Safaqah

The new Cooper River Bridge will replace two existing bridges along U.S. Highway 17. The cable-stayed bridge will be one of the largest in the U.S and will connect the City of Charleston and the town of Mount Pleasant, South Carolina. The 1,546-foot long main span over Cooper River is supported by two diamond-shaped towers and will allow for 1000-foot wide navigation channel. The Charleston high-level approach is approximately 4351-foot long and will provide 250-foot wide navigation channel over Town Creek, while the Mount Pleasant high-level approach is 2090-foot long. Due to the high seismicity in the region, potential vessel impact, and hurricanes, large lateral loads are expected. Among various types of foundations, 10-foot diameter drilled shafts were selected for their high capacity against lateral loading. The shafts are founded on a stiff to very stiff lightly cemented calcareous sandy clay or sandy silt layer, called Cooper Marl, which underlies coastal sediments of interbedded clays and sands. The main towers will be supported on a group of 11 shafts and protected from ship collision by a rock island. The High Level Approach piers will be supported on a pair of 2 shafts. The shaft tip elevation is up to 230 feet below water line. An elaborate geotechnical investigation has been conducted on the site including a load test program on full-scale shafts under axial and lateral loads. The results of the tests were used to calibrate the lateral and axial soil resistance. The objective of this paper is to present the different aspects of the bridge foundation design.

Jan 1, 2005

By R. G. Rosehart, S. Y. Lee

"The current investigation concerns the removal of arsenic from waste waters using ion-exchange resin and activated carbon as sorption media. Use of certain weak and strong base anion exchange resins permits the removal of arsenic. Arsenic may be loaded on the weak base resin in the pH range of 2 to 3 and on the strong base resin above pH 5. The elution of arsenic is successfully achieved using 0.5 M NaCl or a mixture of NaCl and NaOH. The activated carbon investigated was less effective on loading arsenic, but the arsenic loaded was easily eluted by simple pH adjustments."

Jan 1, 1972

By Wei-Tong Du, Yu Wang, Gang Wen

Carbon dioxide (CO2), a major component of the greenhouse gases, could be comprehensive utilized as a valuable resource to oxidize vanadium during the converter vanadium extraction process. The thermodynamic software, FactSage, was utilized to study the oxidation ability and theoretical cooling ability of using weak oxidant CO2 as coolant in vanadium-containing hot metal. Besides, experimental research on vanadium extraction in CO2 and O2 mixed blowing extracting process had been undertaken. The results indicated that the elements C, Si, V, Mn etc. could be oxidized by weak oxidant CO2, and the content of V2O3 in slag was approached to pure O2 blowing. Furthermore, CO2 had a remarkable cooling ability and the molten bath temperature kept on decreasing as CO2 blowing rate increases. This research has proved that CO2 and O2 mixed blowing in vanadium extraction process are effective.

Jan 1, 2015

By M. M. Monte

A method for removing metallic mercury from contaminated tailing, using the flotation process, is described. In order to define some relevant parameters for the mercury flotation system, microflotation and electrophoretic mobility tests were carried out on (pure) metallic mercury in the presence of several surfactants. Based on the results obtained from fundamental studies a series of bench scale flotation experiments with mercury containing tailings from two wetland sites in Brasil were done. The results of microflotation tests with mercury showed that by using cetyl trimethyl ammonium bromide, an increase in mercury flotability is observed in the acid pH range, whereas in the presence of potassium oleate the highest mercury flotability was found in the alkaline pH region. The mercury flotability using potassium amyl xanthate was improved by the addition at sodium dithionate as an activator. The bench scale flotation tests with contaminated tailings from Poconé (brazilian wetland site) showed a recovery of 70% when sodium dithionate was used as activator and potassium amyl xanthate as collector. The resulting coefficient of separation is around 60%. However, the results of the flotation experiments with fine fractions from amalgamation tailings from Peixoto de Azevedo (brazilian wetland site) showed a low mercury recovery (32%).The results from this work suggest that since in the Poconé site tailings, the metallic mercury is not completely associated to the finer particles, the flotation process to recover the metallic mercury seems very promisor.

Jan 1, 1996

By J Evans-Wheeler

"The mandate of the 2005 VALMIN Code to provide ‘(all) reliable, thorough, understandable material information required by investors and their advisers when making investment decisions’ requires that due diligence for tenure be full and thorough. Yet a published due diligence would often appear to be simply a list of tenures allegedly held without any commitment as to the standing of the tenure as safe and secure or otherwise.The value of due diligence for tenure, as mandated in the 2012 JORC Code and the 2005 VALMIN Code, must focus on compliance rather than simply on ‘vital statistics’. Enforcement in every jurisdiction in Australia focuses on penalties (some more harsh than others) for non-compliance, which, in turn and most importantly, reflects directly on security of tenure. Some 22 Acts (on average) impinge on security of tenure and fundamentally underpin the security of any mineral asset.This paper will outline regulatory processes to demonstrate how tenure compliance is achieved and argue that the rigorous application of good practices in tenure evaluation will lead to more of this information being made available on a regular basis.The paper will then focus on further practical examples of tenure compliance failures, the application of these to the requirements of the JORC and VALMIN Codes and due diligence that failed to fulfil the mandate. Examples will be given that alerted other professionals using the JORC Code to complex geological and mining situations of which they were unaware in their valuations.Finally, the author will make a personal plea for tenure to be considered at the commencement of any reporting process.CITATION:Evans-Wheeler, J, 2016. The VALMIN code and tenure compliance – not just a list, in Proceedings Project Evaluation 2016, pp 112–121 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 8, 2016

By G. Winkel

Safety conditions in industry have greatly improved over time. However, around the world, in Canada, and in each province or territory, people are still the victims of serious industrial accidents. The increasing safety of people at work then continues to be an imperative in industry today.<p> So how do we achieve a workplace where no one gets hurt? Well, in simple terms, folks need to be protected from unplanned exposures to equipment or energy sources that can do harm. If you think about it, all of our efforts in loss management and safety should then be directed toward avoiding these uncontrolled events. And it works! Our safety performance over the years has enjoyed tremendous improvement due to this support for loss management and safety. We now explore best practices toward achieving that next step in safety improvement.<p> As shown following, a large combination of loss management activities act together to support safety performance. Many of these activities are interrelated and some people have described them as the ?inputs? into an approach or program for achieving safety. Using this description, it follows that the ?outputs? of the program are some of the advertised measures of safety we see around us today, such as injury frequency rates. <p> It is asserted that a leadership focus to regularly measure safety and loss management activites (so-called ?inputs?), as a basis for taking supportive actions to ensure their effectiveness, is the basis for safety results (so-called ?outputs?) that consistently achieve high standards of excellence.<p> The concept of managing input activities, as enabled by effective measurements, can significantly act to transform our focus and priorities in the workplace. Supporting input activities like strategies, plans, or procedures with our best efforts will get us to our intended goals. Tracking outputs alone will not.<p> Safety and production have traditionally been cast as competing objectives. When both objectives are mutually supported and considered, however, people will invent ways of doing work that support both safety and production, and any other business parameter. When done right, innovation through meaningful involvement of affected people in the workplace will support safety excellence in a manner that in turn improves business efficiency overall.<p> For a workplace to be safe, it then requires everyone?s help and participation to make it happen, a collaborative effort by management, leaders, and frontline folks with the power and responsibility to take appropriate action at every level in the organization. In this way, everyone becomes a leader in safety.<p> The achievement of commitment to loss management input activities by folks in the workplace is the basis for attaining safety excellence. A workplace founded on commitment supports a safety culture with a vision for safe work performance at outstanding or world-class levels of achievement.<p> One may ask if injury incidents will be eliminated with this commitment and focus on workplace safety? Well, despite our best efforts in this area, there is never a guarantee that things can?t go wrong. We are simply not perfect. There remains in our workplace complexities and unanticipated risks that can have disastrous consequences if not managed at every moment. And when it goes wrong, we need to know we?ve truly tried our best, and now we have more to learn so we can get even better. <p> That?s the challenge represented by the safety imperative, a challenge to take safety performance that next step, a fulfillment of our commitment to the moral obligation we have to each other?s safety. It?s an effort that will continually raise the bar of world-class safety performance achievement for future generations. It?s a legacy we can be proud to be part of.

Sep 1, 2004

By A. F. Usov

"The use of the Electric Pulse Discharge method of materials destruction (EP) for disintegration of materials in an industrial-waste processing are examined. The principles and Experience of the development device of EP-disintegration have been described, the technological efficiency of disintegration of industrial minerals estimated.IntroductionThe Russian scientists have proposed and comprehensively studied the electric pulse (EP) technique which is applied in ores and materials disintegration [1, 2 ]. The different aspects of the problem have been presented by the authors in papers at many international congresses [3-6]. Recently the technique is intensively developed in many countries, and various disintegration installations are exhibited.Crashing and disintegration of ores by EP-method is characterized by high selectiveness of destruction. It provides better disclosure of mineral grains and prevent it from destruction. EPmethod reduces slurry formation. All this provides better mineral extraction at ore beneficiation and improves concentrate quality. It also prevents the product from polluting with equipment metal, inwall and grinding equipment material. The possibility to change the character of dynamic loading allows controlling grain-size composition and getting small-size product in contrast to mechanical method of crashing.The product of EP-crashing is characterized by less toughness and greater specific surface area of grains since the new surface is formed at splitting and chinks extension. The product is of high sorption and reactivity in chemical changes. Open grains of mineral spots correspond to their natural condition and it is of great importance for studying mineral.The principles of the development deviceLong-term studies of the technique carried out by research institutes such as Research Institute of High Voltages (Tomsk), Kola Science Centre of RAS (Apatity), Institute ""Mekhanobr"" (S.Pertersburg), made it possible to substantiate principles of the disintegration installations design, make exploratory stands and technological installations to carry out pilot tests and operations under production conditions. The construction design of disintegrating installations depends on many technological and physical factors. Of all the technological factors, the most significant one is to preserve the liberated product because it is the peculiarity of the EPdisintegration to have high selectivity of disintegration. The preservation of the mono-mineral product liberated from the rock mass means that this product is not overgrinding, which causes the loss of the product with slime in processing, and that the initial natural form of the mineral inclusion is also preserved because it is the size and the integrity of crystals that determines its cost value (precious minerals). On the one hand, it is provided by a stage disintegration technique, with the product classified after each stage, and, on the other hand, by selection of specific conditions of electric breakdown, which ensure high performance of electric breakdown and effective disintegration of material fragments, with the useful mineral inclusions preserved intact, with its size considerably exceeding the discharge gap. These conditions are provided by the appropriate geometry of electrodes, the discharge gap and the screen size due to the material’s nature and grain size."

Jan 1, 2008

By Frands Jensen, Erik Eriksson

"Haldor Topsoe’s Wet gas Sulfuric Acid (WSA) technology has been proven in a number of industries converting sulfurous gasses to concentrated sulfuric acid. In the metallurgical sector plants have been delivered handling SO2 gasses from copper, zinc, molybdenum, and lead ore. WSA has high energy efficiency and allows autothermal operation from feed gas strengths as low as 3.0% (volume). Recent variants of the WSA process have been developed that allow very high SO2 conversion efficiencies of over 99.9%. This paper describes the technology, its advantages and industrial achievements.The WSA technology is well suited for production of concentrated sulfuric acid of commercial quality from the sulfur dioxide (SO2) gas that inevitably emerges from the metallurgical processes. Some of the features that make the WSA technology attractive for this application are:- High SO2 conversion rates (up to 99.99%)- High energy efficiency leading to a low autothermal point (~ 3% SO2)- No need for gas cooling and drying to produce concentrated sulfuric acid- No production of waste- Very low cooling water consumptionThis paper describes the WSA process principles and highlights features that make this process attractive for handling SO2 gases."

Jan 1, 2014

By C. J. Chindgren

Upgrading of commercial red cake and recovery of vanadium oxide from uranium-vanadium mill solutions were investigated by the Bureau of Mines. Alternative procedures potentially useful for manufacture of high-quality vanadium oxide at the mill site were explored and developed. The simplest and best procedure for converting commercial red cake containing about 10 percent combined sodium and potassium oxides (Na20) (K20) into a 98- to 99-percent vanadium pentoxide (V205 product appeared to be a metathesis in an ammoniacal solution of ammonium sulfate. Molybdenum, as well as the alkali metal oxides, was removed from the red cake by this procedure at a modest expenditure of labor and reagents. When preparing vanadium oxide of higher grade, it was necessary to dissolve the red cake and reprecipitate the vanadium as ammonium metavanadate. Calcination at 450° C, decomposed the metavanadate and yielded oxide of about 99.5 percent V205. By recyrstallizing the metavanadate before decomposition, an oxide product approaching 99.9-percent purity was obtained.

Jan 1, 1962

By Ernest R. Lilley

THOSE acquainted with the fundamental differences between the, educational .systems of Great Britain and. the United States would hardly expect .the training of men for the petroleum industry to proceed along the same lines- in the two countries. The youth entering an English university is, except in the case of-the student from some of the British colonies or from foreign countries, almost invariably a product of the English "public school." This is in no sense comparable .with the American public school. It is a private institution, frequently of considerable age and heavily endowed. In many aspects it seems to be comparable with the American preparatory school. Yet to some extent its activities remind one of the first years of the undergraduate: course in the American college. Certainly it takes to-itself many of the social, functions of the American college.

Jan 1, 1931

By D. W. Butner

This report is concerned with the conditions affecting the methods and costs of mining phosphate rock in that part of the western phosphate field that is in Bear Lake and Caribou Counties in southeastern Idaho ( see fig . 1) . The area was selected because it contains most of the known phosphate reserve and because its geology has been studied more extensively than that of other sections . Deposits of phosphate rock on public land may be leased from the Government under the terms of the Mineral Leasing Act of 1920 , subject to the regulations of the Bureau of Land Management . Public interest in phosphate production is growing , as shown by an increasing number of applications for leases . Two mines are being operated steadily for the production of phosphate rock by companies that have also the necessary processing plants for the manufacture of fertilizer . Total western phosphate - rock production in 1947 is reported by the Economics Statistics and Division of the Federal Bureau of Mines to have been 1,193,000 long tons , mined in Idaho , Montana , and Wyoming . The average grade was 30.7 percent of contained phosphorus pentoxide (P205 ) ; the average value at the mines was $5.67 per long ton . Idaho contributed 905,000 tons , or somewhat more than 75 percent of western production . Western fertilizer plants took 23 percent of total production; 76 percent was exported . Strip mining accounted for 75 percent of the Idaho tonnage; the remainder was stoped from underground workings . Rock must contain a minimum of 30 percent P205 to be commercially useful for the production of superphosphate fertilizer by current acid treatment methods . Research by corporations and Government agencies has been directed toward the use of lower - grade ore . So far , only by smelting can rock containing as little as 25 percent P205 be used economically . Any development of processing or use pattern that would render the mining of , say , 20 percent rock profitable would have important effects in reducing the unit cost of mining . In the search for metallurgical improvements , consideration should be given to the saving of valuable components of the rock, such as vanadium and fluorine , both of which are present in the beds .

Oct 1, 1949

By Stephen Buttling, Zhong Rui

"A single unit gas fired power station was being built on the edge of the Gulf of Thailand in 2001. The soil conditions consisted of very soft to soft Holocene Marine Clay, and the site was part of a coast line which had been subsiding below high water mark for some time. In order to provide access around the power station a road system in a figure-of-eight formation was required, and this also needed to be above the design flood level, allowing for future settlement. A ground improvement scheme was proposed and constructed, which consisted of two spacings of prefabricated vertical drains (PVD) over two depth ranges, vacuum consolidation and pre-loading, and rigid inclusions.During the construction phase, the vacuum consolidation was applied for 202 to 221 days in different zones, and monitoring allowed a prediction that the future settlement, including secondary consolidation over a period of 25 years, would be within the range of 175 to 355 mm, which met the contract requirement of less than 400 mm.The power plant was completed and became operational in 2003. Monitoring of the road levels continued, as did the settlement, and in early 2010 the total settlement since the end of vacuum consolidation had reached about 800 mm. The monitoring data both during the ground treatment and for the following 7 years is presented and analysed. This is supported by numerical analysis using 3D finite element methods which shows good agreement with the measured data, and allows a preliminary explanation as to why the predictions were so far out.BACKGROUNDAfter a period of bidding and negotiation, the Eastern Power and Electric Co Ltd (EPEC), an Independent Power Producer, entered into an agreement with the Electricity Generating Authority of Thailand (EGAT) in November 1997 to sell them power. In 1999 an Engineering, Procurement and Construction (EPC) contract and an Operation and Maintenance contract were signed with a supplier to provide a gas-fired (with oil as a back-up fuel) 350 MW combined cycle power plant in Bang Bo, Samut Prakarn Province, east of Bangkok. The site of the plant at Bang Bo is located immediately to the east of the Samut Prakarn Wastewater Treatment Plant, adjacent to the Gulf of Thailand (see Figure 1) in an area of very soft to soft marine clay (Bangkok clay) having low shear strength and potential for excessive settlement. The site layout comprises the main Power Plant components of generating block, cooling towers, fuel unloading area and storage tanks, switchyard and administration block, separated by access roads."

Jan 1, 1900