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By H. R. Page, A. E. Jr Lee

From the inception of zinc retorting on a commercial scale in the United States in 1890,' the retort employed has undergone wide variations in its composition and manufacture, facilitating in part equally remarkable improvements in furnace capacities. The early day hand made clay retort was charged with carbonates or silicates or with coarse dead roasted concentrates mixed with a large proportion of charge fuel resulting in a relatively low zinc burden and fired 24 hr in direct coal fired furnaces. Its modern counterpart is fabricated in hydraulic presses from clay mixtures containing sizeable amounts of either silicon carbide or silica flour, charged with sintered flotation concentrates to more than three times the early day zinc burden and fired 24 to 48 hr in gas fired furnaces. This paper does not attempt to describe in detail the early day clay retort practice as it is well outlined in treatises by Ingalls,2 Lodin,3 Liehig,4 Hofman5 and others. A brief review of clay retort practice is presented together with a description of the major developments since 1912. Clay Retorts The Belgian type retort, both in the circular and elliptical forms, has been used almost exclusively. Typical dimensions of press made clay retorts around 1910 are shown in Table 1. Variations in these dimensions were used at different plants according to local conditions to a maximum inside diameter of 9 in. and inside length of 54 in. However, the effective heat penetration in a 24 hr firing cycle and the tendency of the retort to bend limited the retort size. Use of the elliptical vessel was an attempt to present a stronger cross-section resisting the tendency to bend and to increase the burden without increasing the depth of heat penetration. One exception to the 48-54 in. length was the 60 in. retort used as early as 1905 at Palmerton by means of supporting the last 12 in. at the butt end with a specially designed furnace back-wall. This backwall construction with the 60 in. retort had been developed and used at Bethlehem by G. G. Con-vers and A. B. DeSaulles. An attempt was made at Blende, Colo. to use even larger retorts of the Rhenish type based on European practice and requiring much higher furnace temperatures. Satisfactory plastic clays capable of withstanding these temperatures were not available, and the plant never operated successfully. PREPARATION OF BATCH Composition of the clay retort by weight was 40 to 50 pct raw clay and the balance "grog." Generally speaking the mix consisted of 7 parts plastic clay to 9 parts grog by volume. Principal source of the clay used was the Cheltenham vein—sometimes referred to as "St. Louis city clay." A typical analysis was A12O3-31.0 pct, SiO2-50.0 pct, Fe2O3-2.5 pct, MgO-0.3 pct, CaO-1.5 pct and loss on ignition 14.0 pct. At the smelter the clay was weathered whenever possible and then crushed to 0.08 in. or finer. Grog consisted of calcined adobies, cleaned retort scrap and cleaned refuse fire brick such as old furnace brick, blast furnace linings, and others. Saggers from ceramic plants and calcined flint clay were later used. The grog materials were ground to 0.12 m. or finer. Occasionally coke dust up to 10 pct of the mix was substituted for a part of the grog following European practice.² Particle size of the grog has a major influence on the retort properties—the larger the grain, the better can the retort withstand thermal shocks, resist bending at furnace temperatures and resist corrosion from slag; the smaller the grain, the lower the loss of zinc vapor through the retort walls. Grog forms the skeleton of the retort, and the clay shrinks around its grains to act as a binder. In the drying process, the grog has a stabilizing effect on the drying rate, decreasing shrinkage and giving up previously absorbed water to the surrounding clay to minimize the danger of cracking or checking.² Grog and clay were mixed through a horizontal pug mill with 10 to 20 pct water added, depending on whether the retort was to be formed by hand or mechanically, more water being required for the hand process. The batch or "mud" extruded from the pug mill was cut in convenient lengths for handling, stacked in piles or in special rooms, covered with wet burlap and allowed to "rot" or age from 1 to 8 weeks to increase plasticity. HAND MOLDING If the retort was to be molded by hand, the mud was repugged after the rotting period and given to the molders. Their molds consisted of 3 sheet iron or wood cylinders, each one third the retort length and defining the outer shape of the retort. Beginning with the bottom section, mud was placed in the form and tamped with a rammer

Jan 1, 1950

By Yujing Jiang, Xuezhen Wu, Bo Li, Tomomi Iura, Gang Wang

"Yielding bolt has been widely used for rock reinforcement in mining and civil engineering in high stress conditions. However, the interaction mechanism of yielding bolt and matrix mass is still not clear at present, and no analytical model is available to predict its reinforcement effect quantitatively. In this paper, the mainstream yielding rock bolts were reviewed firstly. After that, a coupling model is proposed to account for the interaction between yielding bolt and matrix mass. Based on the plane strain axial symmetry assumption and the incremental theory of plasticity, equilibrium equations and compatibility equations of matrix mass, and also the response of yielding rock bolt are deduced theoretically. The proposed method was programmed in Visual Basic development environment, and a semi-analytical solution for the coupling model is achieved. The reinforcement mechanism of yielding bolt in conventional tunnelling is clearly demonstrated through an illustrative case study. The reinforcement effect of yielding bolt is estimated quantitatively, and the distribution of axial force along the bolt is presented. In addition, the validity of proposed method is verified by numerical simulations. INTRODUCTIONHigh stress in surrounding rock mass can cause serious stability problems such as massive squeezing in soft rock and rock burst in hard rock. It is observed that many conventional rock bolts failed when experiencing large displacement, which implies that they are too stiff to sustain large deformation and dynamic conditions (Stillborg, 1994; Hoek et al., 1995). Yielding bolt, which can also be called energy-absorbing bolt, has been widely used for rock reinforcement in mining and civil engineering for these conditions (Neugebauer, E., 2008). This paper focuses on the static reinforcement effects of the yielding bolts with analytical method and numerical simulations."

Jan 1, 2015

By R deMoraes, A Bobet

The last decade has seen a resurgence of interest in lunar exploration and the emergence of countries like China and India as space fairing nations. In 2004, the US announced a new Vision for Space Exploration, whose objectives focused on human missions to the Moon and then Mars. The near future is likely to see the emergence of a worldwide drive to revisit the Moon as the first step in investigating the Solar System. To date, the Apollo missions provide our only experience of human operations on the Moon or anywhere else beyond Low Earth Orbit. Much was learned from these missions. However, their short duration means that many of the environmental effects that will be important for longer-duration missions could not be quantified. In addition, long-duration missions and infrastructure on the Moon require new technologies and capabilities, which must operate successfully and reliably in this lunar environment. Developing these technologies poses significant challenges for the exploration program. The paper discusses the risks associated with the construction of lunar surface and underground structures and the challenges to adopting the standards and rock mass classification systems developed on Earth and their applicability to the Moon. Moreover, an exchange of views to explore near-surface geologic and geotechnical profiles of the Moon is emphasized and implications of the lack of knowledge on rock mass characterisation of the Moonrock mass, the lack of theoretical/empirical experience on the use of rock mass systems outside Earth, and uncertainties.

Nov 29, 2022

In many base metal sulphide concentrators reagents such as collector and cyanide are often added to the grinding mill as well as to the flotation circuit. Whilst good reasons can be cited for splitting the reagent addition in this way, the benefits of such are rarely quantified and the complex reagent-mineral-media interactions occurring during milling are often poorly understood in terms of pulp chemistry. A new laboratory batch grinding mill designed by Magotteaux allows the user to measure, monitor, and control the pulp chemical conditions during grinding when testing different ores and media. Some of these parameters include pulp pH, pulp Eh, temperature, gaseous atmosphere, and dissolved oxygen concentration. In a recent development, the mill has been coupled with a simple on-line reagent monitoring system, designed by CSIRO, which allows the levels of species such as xanthate and cyanide in the grinding pulp to also be measured continuously during milling using a robust UV detection system. In this way the uptake of collector during grinding and the rate and ex-tent of cyanide interaction with the minerals and media can be determined as a function of grinding time. A series of grinding tests using an Australian nickel sulphide ore was conducted with the coupled system in which the cyanide dose, xanthate dose, and media type were systematically varied. The xanthate and cyanide levels were monitored as a function of grinding time and the data collected are discussed in terms of the pulp chemistry of the system and implications for plant reagent dosing strategies.

Jan 1, 2014

By Bertrand L. Johnson

Pure talc is a hydrous magnesium silicate (Mg3Si4010(OH)2). Pyrophyllite, although it resemble: talc in certain physical properties and uses, is a hydrous aluminum silicate (Al2Si4010(OH)2) - like kaolin, except that kaolin has a somewhat different composition (Al2Si205(OH)4) and structure. Soapstone can be considered essentially an impure talc grid when pulverized is used for many of the same purposes as talc. Massive, compact varieties of talc often are called steatite. PROPERTIES Talc and pyrophyllite are characterizes; by their softness (hardness on Mohs' scale, 1) their greasy feel, pearly luster, white color, and perfect basal cleavage. They have similar crystal structures, and this similarity explains the close resemblance of the two minerals in physical acid chemical properties. Talc is a good electrical insulator, resists the action of most acids and alkalies, and has an exceptional heat-retaining capacity. Its specific gravity is about 2.7.

Jan 1, 1939

By R Justa Cámara, L M. Pinillos Lorenzana

Barcelona Metro Line 9 (Line 9) is an essential infrastructure, improving the transversal transport in Barcelona by connecting the greater part of the currently existing radial lines. The purpose of Line 9 is to create a peripheral line surrounding the city of 1.6 million people (metropolitan area exceeds five million), and includes 52 stations, of which a total of 32 are deep shafts and 19 transfer stations in a densely populated area with several geographical constraints.The tunnel has an inner diameter of 10.90 m, bored with an earth pressure balance (EPB) tunnel boring machine (TBM) in soil sections with precast concrete lining type universal ring and segments 40 cm thick.A single tunnel solution was adopted, driven by functionality and costs savings. The internal tunnel section is divided into two levels to allow for one way rail transit including the platforms in each station on each level in order to optimise the space created by the TBM excavation and comply with the operational needs. The division in two areas of the tunnel was carried out through the construction of a horizontal slab resting on the tunnel segments with a constant thickness of 40 cm at the central part of the slab and supporting side walls.CITATION:Justa Cámara, R and Pinillos Lorenzana, L M, 2014. Two transit levels in one tunnel tube – an innovation in Barcelona Metro Line 9, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 387–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By Haibin Wang, Kaile Tang, Chenn Q. Zhou, Guangwu Tang, Zhixiang Cui, Ping Zhou, Armin K. Silaen, Hongjie Yan, Zhi Wang

Bath smelting technology, such as the submerged lance smelting furnace, is used in the modern copper making industry. The first submerged lance smelting furnace developed by Dongying Fangyuan Nonferrous Metals Co., Ltd has shown potential for high productivity and energy savings. In this study, computational fluid dynamics (CFD) was applied to investigate the current design of the furnace. A three-dimensional multiphase CFD model was developed to study the interaction between injected gas and the liquid bath. The multiphase Eulerian model was used for simulating gas/liquid two-phase flow. The flow pattern in the submerged lance smelting furnace indicated rapid flow development and strong turbulent interactions between the gas and liquid phases. The model was validated based on a water model experiment of the mixing process. Mixing times from the simulation results show good agreement with experimental data. Additionally, based on this model, the gas residence time and liquid copper matte splashing phenomena under varying gas flow rates were investigated.

Mar 1, 2017

By M. S. Seehra, V. S. Babu

"INTRODUCTION The accurate determination of the free silica index in coal mine dusts is an important requirement because severe health hazards are believed to be associated with the inhalation of respirable-sized silica particles.1-6 Free silica refers to the three polymorphs of silica (Si02)viz., quartz, cristobalite, and tridymite-although quartz is usually the dominant form in most mine dusts.6 The free silica index is the concentration in micrograms of free silica in air per m3 of air sampled corrected to standard conditions of 25°C and 760 mm/Hg, the present MSHA (Mine Safety and Health Administration) limit on time-averaged basis being 100 µ.g/m 3 for coal mines. A recent review7 has concluded that quartz, cristobalite, and tridymite particles impart nearly equal long-term hemolytic damage when compared on a per unit surface area basis.At present, two experimental methods-viz., transmission infrared spectroscopy (TIRS) and x-ray diffraction (XRD)-are commonly used for the determination of silica concentrations in mine dusts. In TIRS, which has been adopted by MSHA and is commonly called the P7 method, the silica absorption band near 800 cm - 1 is used for quantification. However the mineral kaolinite, which is commonly present in mine dusts, also has absorption band, albeit weaker, at 800 cm- 1• To correct for this interference, one uses the stronger 915-cm -1 band of kaolinite to determine the concentration of kaolinite, and the kaolinite contribution to the absorbance at 800 cm-1 is then determined from a calibration curve, leading to the determination of silica by subtraction. In the XRD technique, usually an internal standard such as CaF 2 is used to determine the concentration of silica from line intensity measurements. XRD has the added advantage that concentrations of quartz, cristobalite, and tridymite can be determined.8•9 In an exhaustive study on the precision of the techniques ofTIRS and XRD for monitoring worker exposure,9 the conclusion has been reached that both methods measure silica within 253 of the ""true"" value 953 of the time in a single laboratory."

Nov 1, 1995

By O. A. Olaseinde

The 2101 lean duplex stainless steel has wide potential application in storage, heat exchangers, and in the oil and gas industries. This work investigates the electrochemical behaviour of 2101 duplex stainless steel with an addition of 0.15 wt% ruthenium, using potentiodynamic techniques in 1M H2SO4 at 25º, 40º, 60º, and 80ºC. The microstructures of samples were characterized using optical metallography and scanning electron microscopy. The results showed that the ruthenium addition moved the corrosion potential of alloy 2101 to a more positive potential. All samples containing ruthenium displayed longer passive regions at 25°C and 80°C compared to those without ruthenium. Alloys without ruthenium had higher critical current density (icrit) values when compared to the alloys with ruthenium. Ruthenium additions decreased the passive current densities and inhibited anodic dissolution. At room temperature the corrosion rate of alloys with ruthenium was lower than these without ruthenium.

Jan 1, 2012

Rotary kiln incinerators are widely used in the incineration of various types of hazardous wastes. However, the complex transport processes within the incinerator are not well understood. Due to large variations in waste types and difficulties in feed characterization, the incineration process meets great challenges in a smooth operation, and expects uncertainties in the process chemistry and emission control. In order to get better understanding of the incineration process, process simulation was made on the kiln behavior by using Computational Fluid-dynamics (CFD) to characterize gas flow, temperature distribution and waste combustion in the incinerator. Temperature measurement was conducted in an operating incinerator to validate the CFD model. This paper addresses the environmental issues related to the hazardous incineration process, and reports the recent simulation results on gas flow and mixing, combustion heat transfer, and potentials to reduce emissions.

Jan 1, 2002

By N Steenkamp, L Furstenberg, W Cele, M Richter

Managing productivity and improving efficiency for a healthy return on capital employed have become key mining industry strategies under prevailing tough global market conditions. However, achieving this in a multisystem environment such as a mining operation can be daunting. The field of discrete event simulation offers some relief, giving engineering teams insight into multivariable systems and stochastic processes. It allows for integrated system thinking and domain expertise to be woven into project thinking fibre. Directed system optimisation and therefore improved efficiency becomes possible. Furthermore, capital discipline accrues from optimal upgrade investments. This paper illustrates the practical application of this approach by reviewing a typical case study for a direct shipping iron ore operation. Dynamic simulation was used to establish maximum processing plant capacity under varying material characteristics and identify capital-efficient upgrades for increasing production.The study started with descriptive statistical analysis of existing data. Discrete equipment and system capacities were defined, followed by static plant mass balance calculations to establish bottlenecks and overall static capacity. Equipment ‘uptime’ and ‘downtime’ analyses established system and overall plant availability and utilisation. From this information, a dynamic simulation model could then be developed and initially calibrated against actual plant performance to verify its robustness. Once confirmed to accurately represent existing plant dynamics, system capacity response to variable changes could be tested to ultimately determine maximum plant capacity. Additionally, plant optimisation was incorporated to arrive at optimal upgrade points. Maximum capacity and necessary upgrades were established as a function primarily of feed size distribution. Additionally, the interfacing effects of rehandling feed material to the final product grade and potentially to life-of-mine were established as important outcomes. The results of the study illustrate the value of using dynamic simulation models to realistically and cost-effectively increase throughput.CITATION:Cele, W, Furstenberg, L, Richter, M and Steenkamp, N, 2015. Capacity evaluation of iron ore processing facilities utilising dynamic simulations, in Proceedings Iron Ore 2015, pp 597–604 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Axel Preusse

Due to a political decision, German hard coal mining will come to an end in the year 2018. By then, there will have been more than 150 years of industrial grade mining activities. Located in the western part of Germany is one of the most densely populated areas of Europe. Multiple coal seams have embossed the earth?s surface up to 20 meters (21.87 yards), as mining has subsided. The aftercare of hard coal mining will consist of three tasks: groundwater management, polder management, and groundwater treatment. The Ewigkeitslasten (cost in perpetuity) at the current groundwater level has been determined in the past. The actual cash value is calculated to be about 12.4 billion euros (approximately 16.5 billion dollars). The cost of groundwater management is directly related to the groundwater level. Rising groundwater levels will reduce the cost of pumping water. Known effects of rising groundwater are uplift of the surface, emission of methane gas at the surface, higher risk of cave-ins, and contamination of drinking water horizons. Each of those processes produces cost in order to prevent negative consequences (e.g., uncontrolled methane emissions) or to handle reparations (e.g., damages caused by surface uplifts). In the long run, it is the goal to minimize the Ewigkeitslast. As a first step, all cost-generating processes are specified, and a cost type based characterization is performed. The objective of this case study is to identify key parameters to determine the quality of a cost-generating process (proportional cost, fixed amount cost). Afterwards, it is intended to specify the quantitative impacts of each parameter and to set up an optimization model to minimize the overall cost. The quantitatively specified parameters will form the base out of which the optimization model is created.

Jan 1, 2013

By Soobhankar Pati

Solid oxide membrane (SOM) technology has been successfully employed for the production of high energy metals such magnesium, titanium and tantalum by directly reducing their oxides. This paper reports on the recent investigation done for calcium production by SOM process from calcium oxide, dissolved in fluoride and chloride based fluxes. This process employs an inert oxygen-ion-conducting stabilized zirconia membrane to separate the inert cathode in the flux from the anode. When the applied electrical potential between the electrodes exceeds the dissociation potential of calcium oxide, oxygen ions are driven out of the melt and through the zirconia membrane to the anode where they are oxidized. Reduced calcium metal deposits or evolves at the cathode depending on the operating temperature. The SOM cell has been electrochemically characterized, and key concepts related to CaO dissociation, leakage current, solubility of Ca in the flux, and hygroscopic nature of the flux relevant to the SOM process are explained.

Jan 1, 2008

By Michel G. Drouet

Dross, a major by-product of all processes involving molten aluminum, forms at the surface of the molten metal as the latter reacts with the furnace atmosphere. It generally represents 1 to 5 wt% of the melt, depending on the process, and contains on average about 50% free aluminum dispersed in an oxide layer. Since aluminum production is highly energy-intensive, dross recycling is very attractive from both the energy and the economic standpoints. The conventional recycling process using salt rotary furnaces is thermally inefficient and environmentally non-acceptable because of the production of salt slags. Hydro-Quebec has developed and patented a new salt-free technology using a rotary furnace heated by an electric arc between two graphite electrodes, called DROSCAR®. A 600-kW pilot plant in operation at LTEE is in use to demonstrate the process. This process provides aluminum recovery rates over 90%, using a highly energy efficient, environmentally sound production method. In 1994, 400 tonnes of aluminum dross were treated in this facility and several tests on various types of dross have also been conducted in early 1995. A report on the results will be presented.

Jan 1, 1995

By W. H. Ode

Because trade increased among various nations after World War II, the Coal Committee of the Economic Commission for Europe established a Classification Working Party in 1949 to develop an International system for classifying coal. Although national classification systems existed, they had been developed in accordance with characteristics of domestic coals without reference to coals of other countries. Terms for describing similar or identical coals differed in each nation. This caused confusion in evaluating coals shipped in international trade and also hampered exchange of technical information on problems of coal utilization. Experts4/ participating in the classification project early in their work agreed that two systems should be formulated, one for the higher rank coals or so-called "hard" coals in European terminology and the other one for the lower rank coals, the latter designated mainly as brown coals and lignites in the various countries. Rank refers to the degree of metamorphism (progressive alteration) in the natural coalification series from lignite and brown coal to anthracite. The system for classification of hard coals was published late in 1956 as a document of the United Nations.5/ Results of a study for applying this system to American coals were published in 1958.6/

Jan 1, 1960

Teleoperation is one method by which an operator can remotely control and monitor a vehicle. The operator monitors the status and progress of the remote vehicle by watching the video transmitted from one or more cameras which are mounted on the vehicle. In the case of an LHD, it will be fitted with three cameras. For a twin-boom Jumbo, four cameras are mounted on the drill, three of which will have remote pan, tilt, 15x zoom, focus and lens cleaning controls. The advantage of teleoperation is that an operator can stand in the drive and send the remote vehicle around a corner, completely out of sight and still clearly see what is happening. This means that an LHD returns with a full bucket and a Jumbo can be operated from a safe distance. Standing in the drive teleoperating vehicles, exposes the operator to passing traffic including the remote vehicle. There are two solutions to this problem. One is to equip the operator with a Nautilus æBuddyÆ jacket which will help to protect them from all vehicles. The other is to move the operator into a safe room or area, away from the fumes, the noise and the traffic. In this comfortable, less stressful environment, the operator will be more productive and less likely to accidentally damage the vehicle. The operatorÆs æsafeÆ room does not have to be a formal control room, it can be any area which has AC or DC power available and is large enough to contain a chair and a 1.5 m x 0.75 m table. The æsafeÆ room can be on the surface or underground, it does not matter to the operation of the Nautilus Equipment. If the LHDÆs, trucks, locomotives, etc are automatically guided from origin to destination, the operator is free to operate several vehicles at a time, performing only those tasks which are too difficult for a computer to do by itself.

Jan 1, 1998

By H. M. Giegerich

"INTRODUCTIONThe Red Dog Project in Alaska is being developed by Cominco Alaska, a subsidiary of Corninco Ltd. of Canada, and the Nana Regional Corporation, one of the 12 native corporations created by the Alaska Native Claims Settlement Act of1971.The State of Alaska is also a very key part of the project through its financing of the transportation system for Red Dog. Red Dog will be the third, and largest, of Cominco's Arctic mining developments in the past thirteen years, after the Black Angel Mine in Greenland, which started up in 1973, and the Polaris Mine in the Canadian Arctic, which began production six years ago in 1982.Red Dog is one of the world's great mineral deposits, with a unique combination of large size, high-grade, and a waste-to- ore ratio less than I: I, which will make it the world's largest, and one of the lowest cost zinc producers, when at full production. The present mineral reserve is estimated to be 85 million tons , at a grade of 17.1010 zinc, 5% lead, and 2.4 ounces per ton of silver. Based on the current production forecast, this will give a mine life of almost 50 years, and the deposit is still open in two directions, although the structure is becoming thinner at depth. As well, there is a satellite zone about one mile south of the main deposit which could contain up to another 8 million tons of mineral at Red Dog grades or better. This is not presently included in the reserve due to potential processing difficulties.In relation to other zinc deposits, Red Dog is the second largest ever discovered, smaller than the original Broken Hill deposit in Australia, but larger than Cominco's own Sullivan Mine in British Columbia, which is number three. It is quite possible that, when the area is adequately explored, Red Dog will be number one."

Jan 1, 1989

By W. W. Adams

Lower accident rates were the outstanding feature. of the second annual sand and gravel safety competition conducted in 1930 by the United States Bureau of Mines in cooperation with the National Sand and Gravel Association. Both the frequency and, severity rates for accidents were greatly reduced as compared with those shown by the first year's contest, that for 1929. Three times as many plants were enrolled, and the number of man-hours of work represented wad more than doubled. Seventy-six sand-and-gravel plants, situated in 20 States, participated in the competition, as compared with 26 plants, located in 13 States, in the year before. The number of man-hours of employment, which indicated the amount of exposure to occupational hazards, was 4,915,592 an increase of more than 100 per cent over, the previous year's total of 2.259,572 hours. The frequents of accidents declined from 74.4 per million hours for all plants enrolled in the first year's contest to 42.7 per million man-hours for all plants enrolled in 1930. The accident-severity rate was reduced from 9.7 days of disability per thousand man-hours of exposure in 1929 to 5.9 days of disability per thousand man-hours of exposure in 1930.

Jan 1, 1931

By S Speed, N Corlis, A Goldstone, G N. Browne, M Fitzpatrick

In 2005, Solid Energy New Zealand Limited obtained non-notified consent for the disposal of 1Mt of coal ash at the Rotowaro minesite, forming part of a coal supply agreement with the Huntly Power Station. A non-notified resource consent was sought which necessitated that environmental effects be shown to be æless than minorÆ, and resulted from robust science and a pragmatic approach to design. As part of the assessment of environmental effects, there was a need to understand the effects of boron concentrations on aquatic organisms (ie algae, plankton, plants and invertebrates) in the receiving environment. Boron is a naturally occurring element that is found in the form of borates in the oceans, sedimentary rocks, coal, shale, and in some soils but Waikato coals and ashes have particularly high boron content. Boron is an essential micronutrient for higher plants with interspecies differences in the levels required for optimum growth. As aspects of the ANZECC (2000) derived boron limits are based on toxicity of aquatic algae and plants to boron it was important to assess these components in the environment. The effects on the receiving environment of the Awaroa Stream were assessed using predicted water chemistry and comparing actual boron concentrations in a comprehensive and multifaceted reference-condition approach of catchment ecological indicators. In addition a toxicological-based assessment of boron and a re-calculation of the ANZECC trigger levels were undertaken and applied to the ecological indicators. The reference-condition approach revealed that habitat and overall water quality attributes at and between sites was more influential in determining the aquatic biotic communities than boron concentrations alone. There was no evidence of any gradient of changes in ecological indicators with changing boron concentrations, nor evidence of any residual effect of high historic boron concentrations on the aquatic biota.

Jan 1, 2006

By H. S. Caldwell

The objective of this investigation by the Bureau of Mines was to develop and test for laboratory use a retort embodying many features required for practical commercial-scale applications of vacuum distillation of metals. A gas-fired vacuum retort was developed comprising a hollow, cylindrical graphite liner encased in a thin shell of stainless steel. The liner prevents the shell from collapsing under vacuum and protects it from corrosion by metal vapors and the molten metal charge. The vacuum-tight shell protects the liner from oxidation and flame erosion. The retort was used to distill zinc from dross and die-casting scrap. More than 99 percent of the zinc was recovered as a condensate containing 99.8 to 99.9 percent zinc. (Atmospheric distillation recovers 95 to 98 percent at a purity of 99.5 percent zinc.) Distillation rates of 50 pounds of zinc per hour were attained at a temperature of 65° C. with pressures ranging between 50 and 100 microns. Distillation at this low temperature is not practicable at atmospheric pressure. Also, the retort is suitable for distilling other volatile metals such as cadmium and magnesium.

Jan 1, 1961