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By Nikhil Dhawan, Ashwini Kumar, Yogendra Pratap, Himanshu Tanvar

India does not possess any soluble potash reserves and depends completely on imports. In this study, an attempt has been made to recover potash (K) values from the mica sample employing thermal and mechanical routes followed by leaching. Direct leaching of mica in different lixiviants is found to be ineffective with very low K-dissolution (1–5%). Heat treatment with different fluxes, such as NaCl, NaOH, and CaCl2, is carried out and almost 85% K-values are recovered. Mechanical activation of mica and with different calcium additives is carried out to recover potash values. K is recovered in leach solution in the form of soluble salts, such as K2CO3, K2SO4, and KOH, and leach residue consists mainly of calcium-alumino-silicates. Using mechanical activation with flux, it is possible to recover >95% K-values from mica sample. Mechanical activation with calcium-based flux is found sustainable in the recovery of K-values from mica.

By Ashish Kumar Vishwakarma, Vivek Kumar Himanshu, Kaushik Dey

The accurate prediction of blast-induced ground vibration due to underground ring blasting is a prominent need for ensuring the safety of structures. Different site-specific empirical equations are available for the prediction of ground vibration. These empirical equations are best suited when the monitoring and blasting locations are present in the same medium. The change in the medium alters the behavior of wave propagation. Hence, existing empirical equations have limitations in peak particle velocity (PPV) prediction when the blasting location is an underground hard rock mine and the monitoring location is ground surface. This is because the underground metal mine comprises different levels having void in the form of excavated stope or paste-filled stope. It is very difficult to predict the magnitude of PPV on the surface in such instances. Therefore, this study has been carried out to predict the PPV at surface due to underground blasting. In this paper, PPV data was recorded at surface for 207-ring blasts. Furthermore, the PPV has also been measured at different underground locations for 47-ring blasts. Different empirical equations along with k-nearest neighbor (KNN) and random forest (RF) model of machine learning technique were developed for the prediction of PPV. Most of the empirical models have higher accuracy in the prediction of PPV at an underground location. This shows that scaled distance-based empirical predictors are best suited when the monitoring and blasting media are the same. However, the empirical models do not predict PPV accurately when the monitoring location is ground surface and the blast is conducted underground. The machine learning models are better suited for PPV prediction in such cases. Based on the analysis performed for the case study site, RF model predicts PPV at surface with the highest accuracy. The coefficient of determination and root mean square error for RF model used for predicting PPV at ground surface are 0.94 and 0.438 mm/s respectively. The RF-based model is also the best suited among all the models for predicting PPV at underground locations as well.

Apr 20, 2024

By Martin H. Stanczyk

The Bureau of Mines studied continuous closed-circuit attrition grinding of a coarse commercial filler-grade kaolin to produce paper-coating-grade clay having a particle size analysis of at least 70 percent minus 2-micron equivalent spherical diameter (esd). The coarse clay, containing about 12 percent minus 2-micron-esd material, was ground in a Bureau-developed 10-inch-diameter attrition grinder in closed circuit with a 5-foot-diameter bowl classifier. In the best test, a finished product containing 82.7 percent minus 2-micron-esd material was obtained when grinding 20 pounds of raw clay per hour at percent solids with a 100-percent circulating load. Energy consumption was about 341 kilowatt-hours per ton of clay feed, or 487 kilowatt-hours per ton of minus 2-micron-esd material produced. Closed-circuit grinding gave some-what greater particle size reduction and lower energy consumption than either batch or continuous open-circuit grinding.

Jan 1, 1965

By Wilson Blake

The occurrence of rock bursts in some deep mines throughout the world constitutes a severe operational hazard. In addition to endangering the safety of the miners, the rock-burst problem is a major factor in mining economically in deep mines because of the loss of production and expense owing to cleanup and repairs following a burst. Developing means of controlling or eliminating rock bursts has been the subject of intensive research for over 50 years. While much has been learned about the effects of rock bursts, little is known about their basic causes; hence, control measures have been at best only partially effective--attested to by the number and severity of bursts that continue to occur throughout the world each year. In the Coeur d'Alene mining district of north Idaho, the rock-burst problem continues as the silver and lead veins persist at depth. These veins are presently being mined at greater than 7,000 feet below the surface and will be mined to some 10,000 feet in the future. The majority of rock bursts in this district occur in pillars. While pillar bursting has been essentially eliminated in some deep-mining districts by longwall techniques, modification or application of this technique to the thin, irregular, and near vertically dipping veins of the Coeur d'Alene district has not been found to be practical. The creation of pillars is a consequence of the horizontal cut and fill mining method used. Figure 1 shows a vertical longitudinal projection of the silver vein at the Galena mine, illustrating the mining method. Stoping progresses between raises and is carried upward between levels. A horizontal pillar is created as a stope approaches a mined-out level. Recent broad-band micro seismic monitoring of rock-burst-prone stopes by the Bureau of Mines has shown that potential burst zones could be delineated weeks in advance of a burst and that a definite sequence of events took place prior to the occurrence of a pillar burst (1). Hence, time was available for control measures to be effected when a stope pillar reached a critical burst geometry.

Jan 1, 1971

This paper reports on the behavior of mercury and its compounds during the thiosulfate leaching and recovery of gold. Thiosulfate solutions are shown to dissolve Hg0 and Hg2Cl2 to a similar extent as cyanide, but the leaching of HgS is significantly slower in thiosulfate solutions compared to cyanide. Hence, the use of thiosulfate may be an option for treating ores containing high levels of cinnabar, especially since the legislation concerning the discharge or sale of mercury is becoming more restrictive. The deportment of mercury during gold thiosulfate loading and recovery using a strongly basic anion-exchange resin was also studied. Although the mercury thiosulfate complex loads on the resin, the adsorption is weaker than for gold, with an equilibrium constant between gold and mercury of 51. Resin loaded with gold, mercury and copper was pre-eluted with thiosulfate (to remove copper) and eluted with a chloride and sulfite eluant. The majority of the mercury is eluted by the eluant and, hence, its deportment closely follows gold and the eluate would need to be treated to remove either mercury dur-ing or prior to gold electrowinning.

Jan 1, 2010

By R. M. Powers

The Florida Institute of Phosphate Research (FIPR) has funded a four-year research project to develop a computer model 'which will predict the hydrologic impacts of phosphate mining on surface and groundwater systems. The core of the model is an analytical geographic information system (SPANS) which integrates EPA's Hydrology Simulation Program Fortran (HSPF) surface water model with the McDonald-Harbaugh groundwater model (MODFLOW). The hydrologic model conducts both event and continuous annual Simulations driven by variable precipitation and temperature data. The model is currently being calibrated and will be ready for distribution to the user community in mid-1991.

Jan 1, 1990

By Yi Luo, Jian Yang, Hua Jiang

Surface subsidence events induced by underground longwall coal mining operations can cause various disturbances to surface structures ranging from integrity and stability to functionality problems. Highway bridges, as a kind of special road construction that can only tolerate smaller movements and deformations than road pavements, are particularly susceptible to severe influence caused by subsidence-induced ground movements and deformations. However, based on accurate subsidence prediction and correct influence assessments, efficient and effective mitigation and remediation measures can be designed and implemented to ensure the continuous service of bridges, safety of the travelers and smooth mining operations. In this paper, based on the predicted final and dynamic surface movements and deformations, the techniques to assess subsidence influence on the integrity, stability and functionality of bridge structures (e.g., decks, beams, abutments, etc.) are presented. A number of mitigation measures to protect the bridge structures are recommended along with an actual application case.

By S. Kashani-Nejad

The formation of oxides during the dehydration of MgC12,6H20, Bischofite, was studied by heating the bischofite over a range of time and temperatures in ambient atmosphere. Using a methanol-leaching technique developed by authors, the oxides that formed were isolated, identified and assayed. Three distinct regions of oxide stability were identified. The oxide produced at dehydration temperatures less than 300 °C was Mg2(OH)3C1,2H2O; at 300 °C, mixtures of MgOHC1 and Mg2(OH)3C1.2H2O were formed and at 400 °C, MgOHC1 was the only oxide produced. The presence of MgO observed in the products of the dehydration of bischofite at temperatures above 400 °C was due to the thermal decomposition of the MgOHC1 that was formed while the sample was heating to over 400 °C.

Jan 1, 2006

By Dingwu Feng, Jannie S. J. van Devente

"The effect of ultrasonication on reactions at solid/liquid interfaces was investigated in two slurry systems, i.e. gold cyanidation and geopolymerisation. The kinetics of gold extraction were significantly enhanced and the cyanide consumption was reduced in the cyanidation of a pyrite concentrate using ultrasonication, probably due to the prevention of leaching passivation, the improvement of the dissolution of the gold host sulphides and the oxidation of soluble sulphides to sulphate. The effectiveness for ultrasonication was improved with the injection of oxygen and the addition of dithiophosphate through enhancing the formation of the oxidation radicals and selectively inducing cavitation bubbles directly at the sulphide interfaces. Ultrasonically enhanced cyanidation could render currently uneconomic deposits viable for extraction by improved cavitation efficiency with the aid of surfactants.Ultrasonication increased the compressive strength of the formed geopolymers through accelerating the dissolution of the Al-Si materials, strengthening the bonds at the solid particle/gel phase interfaces, enhancing the polycondensation process and improving the formation of semi-crystalline to crystalline phases. The use of power ultrasound will yield high-performance geopolymer materials."

Jan 1, 2003

By Y. C. Guan

In an attempt to replace the traditional cyanide process of extracting gold, a new technology using ammoniacal solutions has been developed. In this study, the electrochemical behavior of gold in ammoniacal solutions at temperatures above 100°C has been investigated. An electrochemical cell in an autoclave has been introduced to carry out this study. The system consists of a gold working electrode, a platinum counter electrode, and an external saturated calomel electrode (SCE) which is connected to the autoclave system through a Birch wood plug. Techniques used in this study included potentiodynamic polarization, galvanostatic polarization, cyclic voltammetry, and Tafel polarization. The electrochemical reaction mechanisms governing the dissolution process are presented.

Jan 1, 1996

By A. Saigal

A finite element analysis based investigation using DEFORM software was undertaken to model the extrusion of 15% alumina and 15% silicon carbide reinforced aluminum metal matrix composites. The study dealt with predicting the extrusion load as a function of ram displacement and initial billet temperature. The finite element simulation was also used to determine the maximum extrusion load, temperature distribution, maximum temperature, strain rate, velocity and stress distributions in the billet during the hot extrusion process. The constitutive equation used was of the type: Z = E exp(Q RT) = A{sinh(ao-)}" where Z is the Zener-Hollman parameter (temperature compensated strain rate), s is the strain rate, Q is the activation energy, R is the gas constant, T is the absolute temperature, a is the flow stress and A, a and n are constants. Based on the work of Davies et al and McQueen and Konopleva, the values of Q (KJ/mol), a (MPa-1), n and A for aluminum 6061 composites reinforced with 15% alumina and 15% silicon carbide used are 181, 0.024, 4.15 and 1.33x10'2 and 233, 0.052, 2.60 and 1.26xl0'4, respectively. Even though the individual parameters are quite different, it was found that the predicted maximum extrusion load, temperature distribution, maximum temperature, strain rate, velocity and stress distributions are quite similar and differ by no more than 1-2 percent between the two composites indicating that the deformation behavior is primarily controlled by the matrix material and is not a function of the type of reinforcing ceramic particulates.

Jan 1, 2004

By Alan K. Burton

Along with tires and transmission systems, engines have been a limiting factor in the growth of large off- highway trucks. The problem, primarily, has been the development of reliable, high-performance engines that are not prohibitively heavy or expensive. For many years, horsepower to overall truck weight ratios have been in the vicinity of 300 lb per hp for rear dump units up to 50 tons capacity. This ratio is obviously very poor when compared to the much lighter and smaller highway trucks, which frequently have a performance ratio of 100 lb per hp. Unfortunately, the larger mining trucks have not been able to match even the 50-ton trucks, and in some cases, ratios have dropped as low as 450 lb per hp. This results in a performance of only 67% of that achieved by the older smaller trucks. Thus, the message is clear: what is needed is more horsepower and less weight.

Jan 10, 1975

By P. G. Guest

Many of the gases and vapors used in anesthesia form explosive mixtures with oxygen or air. Sources of ignition for these mixtures always have existed, in operating and anesthetizing areas. When ether was first introduced, candles and gas-lights and coal stoves caused fires and mild explosions of the vapor-air mixtures. Today the chief causes of ignition are electrical. Fires and explosions are still much too frequent; and, because many of the mixtures are rich in oxygen, the explosions sometimes are very violent. Obvious sources of ignition, such as electric-power sparks and arcs in open motors, switches, and receptacles, as well as exposed incandescent wires and hot plates, usually are recognized by hospital personnel and corrected. A source of ignition that is not so obvious to many is static electricity. Until quite recently the presence of this hazard in a large majority of anesthetizing areas was not even suspected. However, numerous explosions -many of them fatal to patients -have been attributed, with good reason, to sparks from static electricity. In this paper the authors present facts to show the prevalence of static electricity in the average hospital anesthetizing area, and the degree to which this easily developed electrical form of energy constitutes an explosion hazard. An effort is made throughout to explain how static electricity behaves, why it is a hazard, and why certain safety measures are needed and recommended. Following the introduction and a short general discussion of static electricity, which incorporates a glossary of pertinent electrical terms, an account is given of inspections and tests made in a number of hospitals. This account includes many suggestions that should be useful to any person who plans to make similar inspections and tests. However, a comparison of materials and equipment used with those described in the report will reveal, in many cases, the potential dangers and obviate the necessity for tests. The hospital work was supplemented by considerable laboratory research designed to determine the spark energies required to ignite anesthetic-gas mixtures and the exact amount of time involved in developing the usual static charges. The results of this research are reported and the implications examined. The paper concludes with a general discussion of static and related hazards in anesthetizing areas and of the most urgent preventative measures.

Jan 1, 1952

By Madan M. Singh

Increasingly, geotechnical data are being collected for various types of coal development projects. In many cases, a specific design concern is addressed. However, many data collection programs are not intended to immediately support mine design activities or to resolve a specific concern. The following discussion describes some current geotechnical approaches in mine planning, development of reserves, and peripheral activities. Types of Data Collection Programs Geotechnical data collection is increasingly becoming a part of standard coal exploration programs, performed along with stratigraphic evaluations and coal quality tests. The aims of such programs vary. The purpose of the exploration may be to fill out the portfolio on a block of reserves that is to be sold, leased, or held for potential future development. In such a case, a generic suite of geotechnical data are collected. The resulting engineering reports may touch on the more well known mining problems of the area, but detail may be lacking. The geotechnical data are mostly intended to enhance the saleability of the package. Mine design alternatives are generally not addressed.

Jan 1, 1985

By W. W. Yankie, A. T. Chatas

This paper is written as a discussion of the paper, "Buckling of Tubing in Pumping Wells, Its Effects and Means for Controlling It" by Arthur Lubinski and K. A. Blenkarn, which war published in the March, 1957, issue of Journal oP Petroleum Technology. An analogy is drawn between the buckling of tubing in pumping wells and a fiube, fitted with frictionless pistom, linked by an inelastic rod, and which is subject to an internal pressure. A simple derivation shows that the critical internal pressure exerts a hydrostatic force on the pisfon which is close to the Euler load for compression buckling of the same tube. While the results agree with those of Ref. I, the basis of calculations has been changed and clarified. The presence of internal upsets at the pistons is discussed. INTRODUCTION In the Appendix, Lubinski and Blenkarn state that a tube with ends closed by frietionless pistons connected by an inelastic rod (Fig. 1) will behave as a column loaded with a force equal to the tension force in the rod. They note that, while the fluid may not resist a shear force, the moment in every cross section is piston force multiplied by the elastic line deflection (c.f., the loaded column). Since the equations of the elastic lines are similar in the two cases, the solution is carried over from the loaded column. On the contrary it is suggested that while the method of solution remains unchanged from the column case, the actual stress distribution is different, a fact which is taken into account in this note. A simple method of approximating the buckling pressure is given, and their reasoning in our mathematical language is continued. GENERAL EQUATIONS The equation of an elastic line, initially straight in the x direction (Fig. 2), is given by In the case of a loaded column, this may be written: For the pressurized tube it was shown, by analogy with the loaded column, that tion has a solution that, for P, = EI/P, any deflection is stable (a criterion for buckling). An attempt will be made to describe more precisely, the forces acting on the tube, and to analyze the buckling condi,tions. DISCUSSION If the tube assumed a deflected position, the volume between the pistons would increase so that in deflecting, the energy of the fluid would decrease. When the increase in elastic energy of the tube (due to bending) is equal to the decrease of fluid pressure energy, buckling conditions exist. Analyzing the forces on the tube (Fig. 3), two transverse forces, T,, T,, exerted by the pistons, are balanced by a resultant of the pressure elements which are linearly dependent on the local curvature of the elastic line (Fig. 4). Unlike most buckling cases, the forces depend on the shape of the elastic line, a condition that makes a rigorous mathematical treatment difficult. Several approximations may be used to clarify the problem.

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

Abbey, Robert Graham, District Mgr., The W. W. Sly Mfg. Co., 50 Church St., New York, N. Y. '21 Abbott, A. N Ave. Morelos 84, Cuernavaca, Morelos, Mexico '23 Abbott, Argyle Campbell, Geol 42 Everett St., Arlington, Mass. '29 Abbott, Clarence E., V.P., Charge of Raw Materials, Tenn. Coal, Iron & R. R. Co., 1242 Brown-Marx Bldg., Birmingham, Ala. '04 Abbott, Louis Benjamin, Chief Engr., Consolidation Coal Co., Watson Bldg., Fairmont, W. Va. '15 Abeel, George H., Jr., Cons. Min. Engr 1281/2 S. Canon Dr., Beverly Hills, Cal. '18 Abel, Raymond L., Asst. Prof., Dept. of Pet. Refin., Univ. of Pittsburgh. .Pittsburgh, Pa. '28 Abel, Walter D., Cons. Engr 650 S. Grand Ave., Los Angeles, Cal. '82 Abele, Louis T., Min. & Met. Engr., Supt., Texas Hill Mine Coulterville, Cal. '31 Abell, Leo M. Millicent, S. Australia '31 Abernathy, George Elmer, Prof. of Geol. & Min., Kansas State Teachers College, Pittsburg, Kan. '20 Aborn, Robert H., Research Lab., U. S. Steel Corp. Lincoln Highway, Kearny, N. J. '19 Abozeid, Mahmood, Dept. of Mines & Quarries Cairo, Egypt '26

Jan 1, 1932

By B. E. Davis

A fundamental study of the mechanisms involved in the conditioning of coarse Florida phosphate has led to some interesting discoveries. Studies by the Bureau of Mines have shown that conditioning time and mixing intensity greatly affect the grades and recoveries of the phosphate minerals and quartz in the rougher concentrate. In particular, as the conditioning time or mixing intensity increased, the phosphate recovery remained constant while the amount of quartz floated decreased. This phenomenon is contrary to conventional wisdom and could lead to a more efficient coarse flotation circuit.

Jan 1, 1993

By Wing G. Agnew, Paul L. Russell

"INTRODUCTION During the past few years, the development of millisecond-delay electric blasting caps has made possible a more flexible control over timing the firing of individual charges in blasting, The use of these caps has proved especially productive in quarry blasting and in numerous construction operations, but their use in underground mining is developing more slowly, although in some cases, as the solution to a difficult breaking problem, they have been well-received. When used in metal-mine drifts, the general objection is that the broken rock is thrown too far. In nearly all cases, however, use of millisecond-delay caps results in better fragmentation of the rock and a lower powder consumption per ton of rock broken.Prom 1949 to 1952, several series of experiments were conducted at the Mount Weather, Va., Experimental mine in conjunction with driving a 6- by 10-toot ventilation raise. 3/4/ The raise-round experiments in this 238-foot shaft, using millisecond-delay electric blasting caps in various drill-round patterns, are the subject of this report.SUMMARY AND CONCLUSIONSAll rounds discussed in this report were drilled in the hard rock (epidosite and greenstone) of the ventilation raise at Mount Weather Experimental mine (figs. 1 and 2). The drill-round patterns varied from 28- to 32 holes and from a V-cut design to one having no cut boles at all. With the exception of the first two rounds, all blasting was done with millisecond-delay electric blasting caps. In all rounds 60-percent ammonia gelatin dynamite was used and holes were stemmed with two cartridges of sand stemming."

Apr 1, 1953

By Harold Vagtborg

Equilibrium vaporization ratios were obtained for light hydrocarbons, nitrogen, carbon dioxide, and hydrogen sulfide in a reservoir fluid containing 35 mole per cent hydrogen sulfide. The data cover the range from 700 to 2500 psia at 154°F. The results of this study are compared with results obtained by other investigators on systems containing less hydrogen sulfide. When large amounts of hydrogen sulfide are present, the equilibrium vaporization ratios for ethane and heavier hydrocarbons are greater than the ratios for systems containing little or no hydrogen sulfide. Large amounts of hydrogen sulfide have the reverse effect on the ratios for methane. Routine PVT studies were performed on the reservoir fluid including flash and differential liberations of the dissolved gas. The pressure-volume relationships of the saturated fluid were also determined. It is shown that the use of published correlations on physical properties of reservoir .fluids can lead to gross errors when applied to systems containing large amounts of hydrogen sulfide. INTRODUCTION Equilibrium vaporization ratios for various components in naturally occurring crude oil and condensate systems have been reported in the literature.1,2,3,4 Recently, several papers have been published with emphasis on non-hydrocarbon components such as nitro- gen, carbon dioxide and hydrogen sulfide.5,6,7,8,9 The increased discovery of reservoir fluids having high concentrations of these non-hydrocarbon components, particularly hydrogen sulfide, has created a need for a further study of their phase behavior. Equilibrium vaporization ratios are known to vary with pressure, temperature, and overall composition of the system.'" It was anticipated that ratios for systems containing large amounts of hydrogen sulfide would differ from the ratios for systems containing small amounts of hydrogen sulfide. Therefore, the present work was undertaken in order to obtain reliable equilibrium vaporization ratios for the reservoir-fluid in question. PROCEDURE The procedure followed was evolved after considerable experimentation on methods of handling the very sour crude. It was found that drying agents (e.g. CaCl2 and CaSO4) absorbed an appreciable amount of hydrogen sulfide from the gas used to prepare the recombined samples. The concentration of hydrogen sulfide dropped as much as 10 mole per cent in a single pass through a 3-ft drying tube. It was also found that when undried gas was agitated with mercury in the PVT cell, a black scum, believed to be mercuric sulfide, was formed and the hydrogen sulfide content of the gas dropped several mole per cent. Because composition changes during a run could not be tolerated, separation of the mercury and sour fluid was necessary. In order to effect this separation, a stainless steel piston, equipped with Teflon O-rings, was placed in the PVT cell between the mercury and the sour fluid. This piston had to be constructed in three parts because

Jan 1, 1955