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By W. C. Smith, P. J. Hickey

After a short historical background of the process evolution, this article descvibes present-day plant facilities and operating techniques utilized for high-purity bismuth production. The plant is one of the world's largest, with an annual output of some one million pounds of refined bismutlz. PREVIOUS papers1 written by staff members of Cerro de Pasco Corp. have referred briefly to the production of refined bismuth. Since the Corporation is one of the world's foremost producers of high-purity bismuth, a detailed description of the process for extracting the metal may be of general interest. Following a short historical background of the development of the actual process, this presentation will trace the progress of bismuth from its entry into the primary smelting circuits to its concentration in electrolytic lead cell slimes. Our facilities for the treatment of anode muds will be described and the extractive methods given in some detail, with particular emphasis on the techniques which result in the production of refined metal. HISTORICAL BACKGROUND Shortly after Cerro de Pasco began smelting operations at Oroya, Peru in 1922, it became apparent that the dust carried by copper converter gas contained appreciable amounts of bismuth. Although dust collection efficiency was poor prior to building of the 550-ft stack and installation of the central cottrells in 1938, a large stock of dust was accumulated during the intervening years, having the following approximate composition: Oz. per ton Ag - 11.0 Pct Sn — 0.5 Pct Pb - 49.0 Pct Zn - 6.5 Pct Bi - 2.0 Pct Insol. - 1.5 Pct Cu - 0.7 Pct Fe - 2.3 Pct Sb - 3.0 Pct S - 10.0 Pct As - 7.5 In the mid-1920's, experimental crucible melts of this dust with carbon indicated that most of the bismuth and silver, and some of the lead, could be reduced to a fairly clean bullion. Other products were a small amount of leady copper matte and a slag high in zinc, arsenic, antimony, and lead; this slag contained some tin but only small quantities of silver, bismuth, and copper. After the laboratory results had been confirmed by operation of a small reverberatory, a dust reduction furnace was constructed. The ±10 pct Bi-Pb bullion produced from this operation was stocked until 1930, when an Oroya-designed converter type furnace3 was installed for the elimination of arsenic, antimony, and some lead from the bullion. This process concentrated the bismuth from 10 to about 60 pct. By means of the bismuth process developed4 by W. C. Smith at East Chicago (1909-1914) and the discovery of a method5 for separation of lead from bismuth with chlorine gas in 1929, it became possible to begin production of refined bismuth. Unfortunately, bismuth deleaded with chlorine always contained residual chlorides, and the removal of the chlorides by caustic soda left a lead content of 0.02 to 0.04 pct. This final problem was solved6 by substitution of air-blowing for the caustic treatment, which effectively removed all excess chlorine and gave bismuth which was practically lead-free. In 1934, a pilot electrolytic lead refinery began operations at Oroya. Lead smelting was resumed in 1935 and two years later a 100-ton-per-day lead refinery was put into service. In conjunction with the latter, the present-day Anode Residue Plant was constructed. Until 1940, the plant treated both lead anode slimes and dust reduction bullion. The dust reduction furnace was shut down in that year, and all cottrell dusts (with the exception of the product from the arsenic cottrell) were mixed with pyrite and treated in a Wedge roaster to eliminate all possible arsenic. Calcine from this operation joined the sinter plant feed; hence the bismuth from the copper and lead circuits was collected in the lead bullion and subsequently in lead anode slimes from the electrolytic lead refinery. The latter source has been the only bismuth-bearing material of any consequence entering the Anode Residue Plant from late 1940 to the present. A copper refinery began operating in 1948, and the cell mud from this plant is mixed with lead slimes and processed through the same circuit, though only a small quantity of bismuth is present in electrolytic copper cell residues. BISMUTH INTAKE Present-day routes which are followed by the new bismuth feed from its entry into the primary smelting circuits to its arrival at the Anode Residue Plant are traced schematically in Fig. 1. As illus-

Jan 1, 1962

By W. E. Wallace, C. A. Hill, M. J. Keane

"Diesel exhaust particulate material from exhaust pipe scrapings of two trucks, diluted automobile diesel exhaust particulate material collected on filters, and two oil shale ores were prepared for the Ames mutagenrcity assay by dichloromethane OOP ex¬traction, by dispersion into 0.85% saline, or by dispersion into dipalmitoyl lecithin (DPL) emulsion in saline. Salmonella typhimunum TA98 was used to detect frameshift mutagens in the samples. Samples of diesel soot gave positive mutagenic responses with both DCM extraction and DPL dispersion, with the DPL dispersion giving higher results in some cases. The results suggest that possible mutagens associated with inhaled particles may be dispersed or solubilized into the phospholipid component of pulmonary surfactant and become active in such a phase.INTRODUCTIONThe Ames Salmonella/microsome assay (Ames et al., 1975) has been shown to be a useful test for detecting genotoxic properties of various agents. Hundreds of specific chemicals have been screened (McCann et al., 1975), and the test has been applied for many types of environmental samples. Airborne mutagenic agents, for example, have been found in urban air (Chrisp and Fisher, 1980; Hughes et al., 1980; Ro· senkranz et al., 1978), in diesel engine exhausts (Huisingh et al., 1978), and in the by-products of coal combustion processes (Chrisp et al., 1978).Samples of airborne particles are typically collected on membrane filters, and undergo a rigorous extraction procedure with organic solvents and/or ultrasonic agitation (Clark and Hobbs, 1980). Often extracts are transferred to another solvent that is compatible with the assay system. These extraction procedures, while efficient from an analytical perspective, are not physiologically plausible. The questions that present themselves are whether a demonstrated mutagen can be taken up in vivo and whether the process is quantitatively or qualitatively different from the above laboratory procedure (Wallace et al., 1984).When a particle of respirable size is inhaled to the alveolar region of the lung, its first physiological contact is with pulmonary surfactant that lines the inner surfaces of the alveoli. This surfactant is an aqueous fluid containing proteins, phospholipids, and other components (R. J. King, 1982). The principal phospholipid constituent is L·alpha-phosphatidylcholine, beta,gamma-dipalmitoyl, or dipalmitoyl lecithin (OPL) (l. C. King et al., 1981)."

Jan 1, 1989

By Chikabumi Yamauchi, Mitsuru Tanahashi, Toshiharu Fujisawa

"Thermodynamic properties of impurities in molten silicon are of prime importance in developing economical production methods of solar grade silicon. In the present research work, thermodynamic properties of boron, the most difficult element to remove from molten silicon, were measured by chemical equilibration techniques at 1723 and 1773 K. Activity coefficients and self-interaction parameters of boron in molten silicon were determined by equilibrating the melt with solid BN under controlled nitrogen partial pressures. Interaction parameters between boron and nitrogen in molten silicon were also determined by equilibrating the molten Si-B alloys with solid Si3N4• Based on the data obtained, the stability diagram of the Si-B-N system was established.IntroductionPhotovoltaic power generation using a silicon solar cell is expected to be the most promising energy source, because it is inexhaustible, cleaner and more safety than conventional energy sources, such as thermal or atomic power generation. At present, expensive off-grade silicon for semiconductor (SEG-Si) is used for a solar cell production. However, if a large-scale photovoltaic energy conversion using silicon solar cell comes into wide use in the near future, silicon will be sure to be in short supply for the cell. Therefore, a development of a new large scale process for solar grade silicon (SOG-Si) production is definitely necessary, which can remove contained impurities from silicon.Among the impurities contained in silicon, boron is one of the most difficult ones to remove by a zone melting or an unidirectional solidification, because its segregation coefficient in silicon is close to unity (0.8). In addition, boron behaves as a p-type silicon semiconductor dopant and, therefore, its content in SOG-Si must be severely controlled. Although some attempts to remove boron by various metallurgical methods have been carried out [I -4], quantitative analysis has not been made due to lack in the information on the thermodynamic properties of boron in molten silicon. From this view point, the activity of boron in molten silicon was determined in the present study by chemical equilibration techniques at 1723 and 1773 K."

Jan 1, 1998

By Hui Wang

With the great increasing use of nickel metal hydride batteries recently, the waste of this kind batteries have been paid for close consideration. For the main reason that the waste of the batteries contained precious metals and lanthanide which cost great lose. This paper introduces the pyrometallurgical process of recovering nickel and cobalt from the waste of the nickel metal hydride batteries. Particularly, the waste for the process was from factory during the producing program. The use of designed solvent to divide nickel and cobalt in melted state from the waste is described. Also, the result of the nickel and cobalt and melted gangue that mainly consist of lanthanide oxide are included in details. The aim of the paper is to find out a simple and feasible way to reuse waste from nickel metal hydride batteries.

Jan 1, 2009

By Steven D. Knudsen, Dale S. Preece

Computer modeling of the blasting process can aid in gaining an understanding of the physics controlling the process. The sequence of events in a blast occur so rapidly and in such a violent environment that measurements are still difficult to obtain. Computer modeling using a program such as DMC [Taylor and Preece, 1989a, 1989b] can provide insights into the physics of the rapid and violent events associated with a blast. DMC has been used to simulate crater blasting @‘teece, 199Oc] and the blasting of Oil Shale for modified in-situ retorting [Freece, 1990a, 1990b]. This paper will address the influence that damping has on the velocity distribution in the rock mass during the rock motion phase of a blast. Since velocity distribution is a controlling factor of muck pile shape, damping also conbibutes to muck pile shape.

Jan 1, 1992

By J. A. Finch, A. M. Elmahdy

Blending frothers is becoming common in flotation practice apparently enhancing performance. However, there have been no studies to understand the blend mechanism. In this paper, the effect of two frother blends ofF150 (polyglycol) with MIBC or pentanol (both alcohols) on bubble size, gas holdup and froth height is reported. The blends focused on a small addition of the polyglycol to the alcohols as base frother. The tests showed that the bubble size at blend concentration below the critical coalescence concentration (CCC) of the base frother was decreased but was significantly larger above the base CCC. Froth build-up showed a strong synergistic effect.

Jan 1, 2009

By Ramachandra Rao

THE occurrence of copper ores at Garimenapenta, 14 59 min 30 sec N Lat., 79 33 min 10 sec E Long., in Nellore district, Madras State, India, has been examined and investigated on numerous occasions during the past two centuries.' No tangible orebody was ever located as a result of all the ex- tensive trenching and shafting done in the area by various agencies. However, during 1933 Messrs. Piepmeyer & Co., a German firm engaged by one of the leaseholders of the area, carried out an electrical survey using inductive methods.' On the basis of certain strong indications found in their survey, they recommended that the prospect be proved by drilling or shafting. But for want of financial backing no further work was carried out. When the Madras government more recently proposed investigation, Dr. Krishnan, then Supt. Geologist of the Madras Circle, urged that before further costly ventures were carried out a test geo-

Jan 1, 1954

By A. A. Smith, J. S. Smart

THE controlled amounts of phosphorus, arsenic, sulphur or selenium found in commercial coppers perform a variety of highly useful functions. Indeed, a large segment of modem copper technology is essentially dependent upon the presence of one or more of these elements. Consequently, the literature contains many references to their effects but the scope is broad and has been only partly covered. New data are presented herewith directed toward a better understanding of the basic behavior of these elements in copper, with particular emphasis on the composition range 0 to 0.05 per cent. These data are a part of a general program of research on the effects of impurities on the properties of oxygen-bearing and oxygen-free copper, other portions of which have been reported previously.1-2-3 Schematically, the behavior of individual elements is determined from measurements of conductivity and softening temperature,1, 2 and the binary alloys employed are synthesized from high-purity copper in order to eliminate interference from the effects of extraneous impurities. Alloys of selected composition were first prepared in the oxygen-free form by continuously casting the melts in the form of 3/8-in. diameter rod. Oxygen was added subsequently to portions of the alloys, either by remelting or by diffusion at 850°C. from a surface scale. Test wires were drawn one B. and S. number per pass, using four 30-min. 600°C. anneals at o.3125, 0.257, o.204 and o.162 in., and a final cold reduction of 95 per cent t0 0.081 in. Oxygen-bearing slugs made by remelting were hot-rolled to 5/16 in., drawn to 0.162 in., annealed for 30 min. at 600°C. and cold-drawn 95 per cent to 0.081inch. The alloys containing phosphorus, having been compounded very early in the program, were prepared in the form of 5/16-in. rod, and processed to wire with only the last three intermediate anneals listed above, all of these having been conducted in commercial nitrogen. In addition, the conductivity anneals on these alloys were also performed in the same atmosphere, and the small amount of oxygen present as an impurity in the gas resulted in some loss of accuracy at temperatures of 700° to 800°C., as will be shown later. Subsequently, the anneals for all oxygen-free alloys were conducted in hydrogen to prevent oxidation, and purified nitrogen was employed only for oxygen-bearing samples. All conductivity anneals were of one hour duration followed by a rapid quench in 10 per cent H2SO4. EFFECT OF PHOSPHORUS The widespread use of phosphorus as a deoxidant has resulted in universal appreci-

Jan 1, 1945

By J. G. Groppo

A beneficiation process has been developed to provide selective separation of unburned carbon from high loss-of-ignition (LOI)fly ash. Using froth flotation to achieve selective separations requires long residence times and high reagent costs. A proprietary reagent system has been developed to address these limitations. Based on the results obtained from laboratory and pilot-scale investigations, a flowsheet design has been developed to produce two distinct usable products from class F fly ash — low LOI ash and a high-carbon product suit-able for reburning or further upgrading.

Jan 1, 1996

By Evans RH, Todd G

Statistical thinking and statistical process ppq;ro4 are essential adjuncts of total quality management aqd too continuous improvement of operating efficiency arid, p*Nc; a4 W,

Jan 1, 1991

By PROCEEDINGS OF MEETINGS

THE opening session of the Institute was held at Hazle Hall, Tuesday evening, October 27th, with a large attendance of members. President Raymond called the Institute to order, and after a few introductory remarks, introduced Mr. I. Lowthian Bell, President of the Iron and Steel Institute of Great Britain, and Honorary Member of the American Institute of Mining Engineers. Mr. Bell was received with great applause, and made his acknowledgments in a brief speech, of which the following is the substance: He desired to thank the Institute personally for the honor conferred upon him in his election to membership, and also for the invitation extended last year to the body of which he was President. The difficulty felt by many members of the Iron and Steel Institute, of leaving for a long journey the works of which they had charge, aggravated by special industrial troubles at the time of the invitation, had obliged them to conclude that it could not then be accepted in a fitting manner. The iron manufacture of this country is a subject of great interest to Englishmen, who look with pride upon the achievements on this side the water of the descendants of a common ancestry. His own reception in this country had far surpassed in cordiality even the well-grounded anticipations he had formed from the assurances of the President and other friends. Notwithstanding the flattering manner in which his friend, in introducing him to the Institute, had spoken of his contributions to the science of iron metallurgy, he could not take to himself alone the significance of this welcome. He knew it was a recognition of the services rendered by the body which he had the honor to represent; and he was glad to see present a member of that body, Mr. Thomas Whitwell, who had fortunately been able to make the journey at this time, and whom he had had the pleasure of meeting on the shores of Lake Champlain. He had been requested to say something of his impressions of the American iron industry. It was not easy to digest so soon the vast

Jan 1, 1875

By C. L. Lin

A PC image-based, on-line instrument for the measurement of coarse particle size on a conveyor belt is under development. Both the hardware and software required to implement such a system are discussed, including the interface for the special image acquisition hardware. The system concept is given with examples to illustrate the step-by-step procedure for the implementation of image-processing algorithms.

Jan 1, 1992

At depths greater than several kilometres in the crust, elevated temperature, confining pressure, and the presence of reactive pore fluids typically drives rapid destruction of permeability in fractured and porous rock. Ongoing deformation is required to regenerate permeability and facilitate the high fluid flux necessary to produce hydrothermal ore systems. A dominant influence on the evolution of fluid pathways in hydrothermal systems is provided by stress states, fluid pressures and reactions that drive permeability enhancement and compete with permeability destruction processes (Cox, Braun and Knackstedt, 2001). An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Ben C. Gerwick

Large diameter steel tubular piles installed vertically or on a slight rake, offer many advantages as the foundations of major overwater bridge in regions of high seismicity. By proper selection of diameter and wall thickness, an optimum balance between stiffness and strength can be achieved. Under strong seismic motion, the piles will deflect and bend so as to reduce the acceleration forces transmitted to the superstructure, while still limiting drift. A major advantage of this concept is that the mass of the footing block is significantly reduced from that of the conventional pier. The design of the footing block requires great care in order to transfer the high shears and moments. Where the soils consist of significant depths of sediments, the kinematic interaction of soils, piles and structures must be considered. Moments will be a maximum just under the footing block. Filling the top portion of the pile with concrete will prevent local buckling and assure ductile behavior even under overload. Typically the piles will be long, with most or all of their support furnished by friction and will require the use of very large pile hammers to achieve the required capacities. Where the piles are founded on rock or in hardpan, sockets will be drilled and filled with reinforced concrete. For these piles, high moments can occur both at the head and just below the rock surface, so the concrete infill should extend the full length. This paper describes the use of tubular piles driven through the deep silty sands of the Jamuna River, Bangladesh, and also where socketed into the near-surface rock for the mail pylon pier of the new San Francisco-Oakland East Bay Bridge in California.

Jan 1, 2013

By Jack Zhang, Chuck Edwards

"The versatility and specificity of rare earth elements (REEs) have led to their use in an ever increasing variety of applications in new technologies. Consequently, demand for REEs has increased significantly. However, to separate REEs safely and effectively is a complex and expensive process. While China has consistently invested in R&D of REE processing technologies, there have been only sporadic activities in REE mineral processing in North America in the past 20 years. This paper presents a review of REE mineral processing technology, providing an update on current capabilities in REE mineral processing. This paper reviews REE extraction from the major commercially valuable REE-bearing minerals such as bastnaesite, monazite, and xenotime, and also from the ion-absorption type of REE deposits. Currently, there are four major REE mining areas in China, one in the United Sates, and one in Australia. A review of the REE extraction processes in these major REE mining areas closes out the paper.INTRODUCTION The rare earth elements (REEs) include the 15 lanthanide elements, plus yttrium and scandium. The lanthanide elements are normally categorized in two groups: the light rare earth elements (LREEs), i.e. lanthanum through europium (atomic number (Z) = 57 through 63); and the heavy rare earth elements (HREEs), i.e. gadolinium through lutetium (Z = 64 through 71). Yttrium is usually grouped with the HREEs due to similarity in physical and chemical properties. Table 1 lists the REEs, atomic numbers, and abundances in earth’s crust (Taylor and McCleannan, 1985). Promethium is the rarest due to lack of stable isotopes. REEs with low atomic numbers are more abundant than those with high atomic numbers. More interesting is that the REEs with even atomic numbers are much more abundant than adjacent lanthanide elements with odd atomic numbers as shown in Table 1."

Jan 1, 2012

By Pierre Sauvé, Guy Perrault, Armand Savoie, Pierre Trudel

"La Mine Doyon est une entreprise détenue à parts égales par Cambior Inc. et par Minerais Lac Ltée qui en est l'opérateur. Les statistiques de production au 1"" janvier 1990 indiquent que, depuis le début de son exploitation (1980), 10.3 Mt de minerai d'une teneur moyenne de 5,9 g Au/t ont été usinées. Les réserves sont estimées a 10,4 Mt à une teneur moyenne de 6,6 g Au/t jusqu' à une profondeur de-450m.Trois zones minéralisées sont présentement en exploitation. Ces zones sont caractérisées par la présence de veines de quartz-pyrite accompagnées localement de chalcopyrite. Les roches encaissantes sont les schistes a séricite (zone# 1), les roches volcaniclastiques de composition felsique (zone #2) et intermédiaire (zone #2, zone ouest) ainsi que les roches intrusives appartenant au pluton de Mooshla (zone ouest). Toutes ces roches ont subi un métamorphisme régional dont l'intensité correspond à la limite supérieure du facies schiste vert ( -425°C}.Les zones minéralisées sont situées à I' intérieur des zones de déformation et d'altération les plus intenses. L'étude des structures mineures nous indique que la région a subi plusieurs épisodes de déformation ductile a fragile qui sont antérieurs, contemporains et postérieurs al a minéralisation. L'analyse structurale indique également que la déformation majeure est associée à une importante phase de compression orientée N-S a NNE-SSW.L’ensemble des observations suggère que la minéralisation et I' altération associée sont de type épigénétique. La mise en place du minerai se serait effectuée à la fin de l'épisode principal de métamorphisme et de la déformation."

Jan 1, 1990

By WALTER B. JONES

PIG iron was first produced in Alabama in 1818 from limonite or brown ore and since then much of this ore has come from the so-called mineral district of northern Alabama, especially along the Cretaceous-Paleozoic contact. For many years the Russellville district in Franklin County, where the first blast furnace was erected, produced more than 100,000 tons of brown ore annually. Limonite has been reported at many places in the Coastal Plain region, where the formations are of Mesozoic and Cenozoic age, but these scattered deposits were never considered to be of much commercial importance. However, in the last three years a considerable quantity of this ore has been scraped up and shipped, particularly from the city of Greenville in Butler County.

Jan 1, 1938

By W. G. Messner

Pipelines for transporting crude oil and refined products in the United States totaled 189,982 miles on January 1, 1959. This mileage was less than a 1-percent increase from the 1956 total of 188,540 miles. During the three-year period (January 1956 - January 199), 14,886 miles of new pipe and 10,649 miles of secondhand pipe was laid. Pipe taken up in the same period was 24,093 miles. The facts regarding pipeline mileage were obtained by the Bureau of Mines from pipeline companies and information provided by the Interstate Commerce Commission. Crude-oil gathering lines, as of January 1959, were 40 percent of the United States pipeline mileage and totaled 75,182 miles, an increase of 1,656 miles during the three-year period. Crude-oil trunklines totaled 70,317 miles or 37 percent of the United States pipeline mileage, a decline of 8,277 miles from the 1956 total. Some of this loss is attributed to the converting of crude lines to refined products. Refined product lines in January 1959, totaled 44,483 or 23 percent of the United States mileage, an increase of 8,063 miles during the three-year period.

Jan 1, 1959

By D. W. R. George, J. L. Stewart

Developments in the last decade, which have contributed to increased productivity and decreased coke rates in the iron blast furnace, are reviewed. Future progress in blast-furnace practice is also considered.

Jan 1, 1966

By Bryon Cerklefskie, Michael Schulte

"This case study explores the usage of polymer ducting as a replacement to curtains and FRP for face ventilation in two coal mines. There are two mines looked at, one is the highest elevation underground coal mine in North America, the other is the gassiest mine in North America. The paper details the trials of both mines switching from FRP and curtain respectively to polymer ducting. The results discuss the ability for the mines to not only achieve consistent airflows and keep them in compliance but the unexpected positives. Mine A was allowed to do longer cross cuts due to increased air volume at the face. This drastically cut their costs of mining down due solely to modification of the ventilation cycle. Mine B saw economic benefits due to longer cuts between place changes. Both mines have documented lower dust, methane, noise, and improved wear and tear on their equipment as a result.INTRODUCTIONThe emergence of longwall mining in underground coal operations has resulted in new ventilation challenges. Numerous production crews strive to complete their development sections with enough time to adequately prepare for the upcoming longwall panel. Continuous miners will cut out two or three entry development sections per their ventilation plan, that is approved and controlled by MSHA (Mine Safety and Health Administration), which will drive amount of footage that can be mined at a time prior to installing roof support. At this moment the continuous miner, hereafter referred to as the CM, will back out of the entry and moves to the second entry to complete a similar cut. Typically, a roof bolter crew will pull in to the finished cut section and install ground support. This is called a place change style of production coal mining. There is an alternate method that includes a miner/bolter combination as well but that was not featured at either test site in this case study. Ventilation has to be provided to sweep the working face of each entry to control dust and gasses. Each task will have an MSHA prescribed ventilation requirement dependent on the dust levels and methane emissions of the rock for that particular mine. The CM, roof bolting and unused headings will each require constant ventilation but at different volumes. Since each working face is changing throughout the mining cycle the ventilation requirement in a working heading is never static and is changing with the working task.Traditional Ventilation ControlsTraditionally face ventilation for coal mining operations has been completed thru the usage of a curtain system and\or using auxiliary fans and ventilation tubing. Room and pillar mining systems typically utilize curtain systems, which use curtain walls that are installed by the miners by erecting wood framing and covering it with brattice curtain. This splits the drift width to allow fresh air to sweep the face and take the contaminated air and dust behind the curtain to the ventilation exhaust\return area of the mine. This method is difficult to adjust the airflow from entry to entry during changing cycles and requires that a wider drift is mined out in order to have enough room for the brattice wall. In operations that require roof bolting, this method limits the length of the cuts from the CM prior to advancing and can lead to not providing enough ventilation to keep dust and methane levels below compliance requirements."

Jan 1, 2019