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By Roy McKinstry, Mark Rantapaa, Thomas Bolles

"More efficient drilling and blasting techniques have shown measurable improvements in throughput at the Barrick Goldstrike wet grinding mill.A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the Open Pit and Process areas participated closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of improving throughput in future years, despite the projected harder ores. Plant studies were conducted to determine if adjustments to drilling and blasting could positively influence throughput. At the Goldstrike mill the greatest opportunity from the D2M initiative is realized on the hardest ore. Grinding throughput for softer ore, <15 kWh/st, can meet or exceed the downstream pressure oxidation requirements. Grinding throughput for harder ore, >15 kWh/st, is limited by the SAG milling capacity. Better fragmentation in the D2M ore, as demonstrated by image analysis, increased throughput 5% to 10% (25 to 50 stph) compared to the standard mining methods.Better fragmentation and a subsequent increase in mill throughput were achieved through the use of:1) Electronic caps for more precision and flexibility, as well as for allowing extremely fast shots.2) Explosives with a higher velocity of detonation (VOD), to provide for improved shock energy.3) Improved distribution of the explosives by decreasing pattern spacing.INTRODUCTIONThe Barrick Goldstrike Open-Pit group, along with the Process division, began experimenting with novel blasting technology and techniques to improve mill throughput in the spring of 2001. A series of tests were developed to determine if fragmentation and ultimately mill throughput could be influenced by optimizing the drilling and blasting program in known"

Jan 1, 2004

By Gisele R. Passalacqua, Taylor Malangone, Subhash Mahali

New York City is a busy metropolis with 8 million people. New York has the largest public transportation system with 6 million riders a day throughout the subway system. Keeping this infrastructure in service is vital to the overall economy of the region. Hurricane Sandy proved to have a devastating impact on infrastructure in Metropolitan New York. New York City Transit is on the forefront to provide resiliency and maintain its facilities with the use of flood protection systems. This paper presents flood protection structures utilized at Hammels Wye substation site in Far Rockaway, Queens, New York. The site is in close proximity and surrounded by water. The subsurface conditions consist of loose silts overlain by medium dense glacial sand. The high groundwater level combined with limited access to the site presented challenges. A flood protection system consisting of flood walls was recommended for this site. In certain areas the flood walls consisted of retaining walls supported on micropiles. For other areas, the flood walls consisted of steel sheet piles with jet grout columns to reduce seepage below the walls. The effect of driving sheet piles with vibratory hammers on nearby existing structures is always a concern. Recently, hydraulic hammers with variable moment/frequency are being considered as a mean to reduce vibration effects during driving. In this project, an instrumentation testing program was performed to measure peak particle velocity during sheet pile driving utilizing the variable moment vibratory hammer. Plots of peak particle velocity versus frequency were generated. This paper will present the design aspects of the flood walls and construction challenges during installation. This will prove beneficial to engineers in both design and construction fields.

Sep 8, 2021

By I Clark, S C. Dominy

Bulk sampling programs are typically applied in coarse gold mineralised systems to verify resource/reserve grades. In recent years, there have been controversies surrounding some results of underground bulk sampling exercises compared to the predictions using diamond drill data. Just how realistic is it to predict 100 t lots from drilling that was designed to model blocks of several thousand tonnes? This study looks at the variation of relatively small units within larger planned mining units and compares some of the geostatistical techniques which purport to provide tools for such studies. Relative difficulty of application, computer timings and summaries of results will be used to illustrate the likely variation in bulk sampling units as opposed to mining units and large-scale planning units. A case study based on publicly available data from a gold project in North America is presented. A simplistic and unconditional geostatistical simulation model demonstrated that up to 50 per cent of a relatively high-grade mining block could show as uneconomic low-grade subblocks. A subsequent study will consider a similar demonstration using uniform conditioning. Erroneous impressions of early sampling results can lead to unsupported prejudgements of the final results. Bulk sampling programs require detailed planning based on ore characteristics, where protocols must fit the mineralisation type. Any program requires definition of aims and data quality objectives across grade, geological, geotechnical and geometallurgical parameters.CITATION:Clark, I and Dominy, S C, 2017. Underground bulk sampling, uniform conditioning and conditional simulation – unrealistic expectations?, in Proceedings Eighth World Conference on Sampling and Blending , pp 3–20 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By Nan H. Lee, Christopher J. Hunter, Stephen H. Chung

Several factors affect the productivity of mining operations. The geological structure of a mineral deposit and the fragment size of blasted material are considered to be most influential. It is well known that productivity varies with mucking cycles and that this is related to the explosive energy produced by a blast.

Jan 1, 1991

By E. D. Gradner

During 1924 a number of lives were lost and other men incapacitated by the toxic effects of gases produced in blasting in massive sulphides. In one mine, three men working in a raise were caught by gases from blasting a drift round in massive sulphide on the level. The round in the drift was shot ahead of time and it was necessary for the three men to travel through the gases to the intake air course. Two of the men lost their lives, and the third was injured, apparently for life. Other men at this same mine have been caught in the gases at blasting time and seriously injured. At a second mine, the gases from blasting in sulphides appear to be very dangerous, and it was necessary to send a number of men who were caught in such gases to the hospital. One man who was seriously gassed has not recovered in over a year is time. Another man similarly gassed soon died of influenza.

Jan 1, 1926

By P Rowe

New Zealand Steel&apos;s Taharoa titano-magnetite mine, south of Auckland, set two national load records when it transported around 2000 t of mining equipment three kilometres overland on time, under budget and without safety incident. It was the first time in New Zealand that four platform trailers were assembled end-to-end to transport a load. It was also the first time that a single load of 1000 t was transported on platform trailers. The need for the relocation of all equipment was realized five years ago. It took two years of planning and specialist advice to relocate the mine&apos;s 250 t dredge, 500 t surge bin, 1000 t concentrator plant and ancillary equipment from the Southern Mining Region across a specially designed haul road to the Central Mining Region. The project was carried out during a six-week shutdown in early 2001. Two dry docks were constructed, one at each end of the relocation route. The equipment was floated into a dismantling pond that was interconnected with the dry dock in the Southern Region. Through pumping, the water levels were controlled to allow transfer of the separated units from the dismantling pond into the dry dock. Once drained, sets of self-elevating platform trailers were used to transport the main units, one at a time, between the dry docks. Five prime movers were used to pull the loads. At the receiving end, the units were off-loaded in a dry dock interlinked with ,the first mining pond. The equipment was relocated because the reserves in the Southern Mining Region were mined out. A natural watercourse û the Wainui Stream û defines the northern boundary of the Southern Region and the objective became to relocate the mining plant to the other side of the stream and re-establish in the Central Region. The project team selected the trailers as the most effective means of transporting the equipment, particularly given the non-invasive means of crossing the Wainui Stream. Negotiations with prime contractor Tranzcarr Heavy Haulage Ltd commenced in mid-2000. The remainder of 2000 was spent in developing concepts with the contractor, detailed designing, preparing the dry docks, haul road and initial mine plan for the Central Region. These activities occurred with no conflict to the normal site production.

Jan 1, 2001

By C. Zener, H. Nielsen, D. Van Winkle

THE internal friction of metals has been studied frequently at elevated temperatures.1-4 In most cases it rises rapidly with increasing temperature. The notable exceptions are ferromagnetic materials, and lead.2 This paper describes an investigation of the general features of the high-temperature internal friction of 70-30 alpha brass. EXPERIMENTAL METHOD The internal friction of a metal is a measure of the rate at which it dissipates energy of vibration. The measure adopted here, I/Q, is (I/2p) times the specific damping capacity, a measure commonly used by engineers. In the measurements of this investigation, the stress level was kept so low that the observations were independent of the stress. The general method of making such measurements, and of observing the temperature of the specimen during a measurement, has been described elsewhere.5,6 The driver and detector coils were wound with wire insulated with glass thread, in order to withstand the high temperatures used. In previous work electrical eddy currents in the specimen served as the coupling between the mechanical vibration of the specimen and the electrical circuits of the driver and detector. The high values of the internal friction in the present investigation rendered this coupling insufficient. In order to increase this coupling, pole pieces cut from ordinary telephone diaphragms were attached to the specimen. A mixture of French chalk and water glass proved a satisfactory cement. All measurements were made at the fundamental frequency for transverse vibration, which lay between 600 and 900 cycles per second. SPECIMENS The measurements described herein were made upon a single cylindrical rod of brass, kindly furnished by Dr. Cyril Stanley Smith, of the American Brass Co. This rod was the specimen E of the set of alphabrass rods described in an earlier paper.6 Successively larger grain sizes were obtained by annealing at successively higher temperatures. A slice was cut off one end after each set of measurements. Grain counts were made on each slice by W. E. Lindlief, of the American Brass Co. Nine fields were viewed on each piece, located as shown in Fig. I. Results are given in Table I. The grain size is defined in the usual way; namely, Grain size = I/n ½ where n is the mean number of grains per square millimeter. EXPERIMENTAL RESULTS This paper is concerned exclusively with the part of the internal friction that becomes dominant at high temperatures. It is thus desirable to separate this part of the internal friction from the part that is

Jan 1, 1942

By Yasunori Kosaka, Junya Tokita, Aramaki Shosaku, Inoue Junji

Light ANFO that satisfies blasters and customers who want to reduce the amount of explosive consumption without changing blasting effects and designs and passes Cap sensitivity test regulated by law. The reduced loading density of light ANFO reduces the amount of explosive consumption. The loading density of conventional ANFO is 0.X-0.9g/ml, while the loading density of light ANFO is 0.7-OXgiml. The detonation velocity of light ANFO is maintained not to reduce blasting effects. Detonation velocity of conventional and light ANFO using steel tube of inside diameter 36 mm are 3200 - 37OOms. detonation velocities are the same though the loading density of light ANFO is reduced by O.lg/ml. This suggests that the reactivity of light ANFO improves.

Jan 1, 2002

By D. M. Holloway

As a part of the 1-15 Reconstruction Project, static and dynamic (high-strain) testing methods formed the basis to estimate long-term axial capacities, and to assess the magnitudes of bearing capacity gains (setup) from the end of installation to the time of static/dynamic tests weeks later. This paper summarizes the results of nine full scale pile load tests to failure in compression, and how the designers used these data to finalize pile selection and penetration criteria bridge-by-bridge in the final design stages. Soil conditions along the project alignment ranged from deep, lightly over-consolidated Lake Bonneville clays interbedded with granular strata of varying consistency, to sites dominated by dense alluvial deposits of cohesionless soils well above the water table. The test sites were selected to bracket the conditions that are expected. Twelve-, 16-, and 24-inch-OD pipe piles are to be used to support the new bridges. The team plans to impact-drive all piles closed-end to final penetrations. The test piles varied from 35-ft-long pipes driven to refusal in the shallow dense sands at some sites, to 115-ft-long pipes stopping at 3 blows per foot in predominantly cohesive deposits. The capacities gained with time proved to be reasonably predictable, and significant setup was noted both in the cohesive and cohesionless strata. The test program objectives included providing the means to estimate long-term capacities from short-term (24- to 48-hour) restrikes following installation of foundation piles during production driving operations.

Jan 1, 1998

By W. O. Philbrook, H. W. Hosking, N. B. Melcher

A simple and inexpensive mercury-tracer method has been develohed to study rates and Patterns of gas flow in blast furnaces. A Pulse of mercury is injected into the hot blast, and its arrival at the sampling Point is recorded by an electronic circuit that measures resonant absorbtion of ultraviolet light by mercury vapor in the gas aspirated .through the detecting. cell. A rapidly developing interest in blast-furnace technology in recent years has created a strong demand for precise knowledge of the rates and patterns of gas movement through the stock column. Classical fluid-flow theory cannot supply the desired information because the complexity of the blast-furnace situation precludes the accurate determination of many of the parameters required for solution of the equations. In fact some of the terms employed in fluid-flow treatments become almost meaningless under blast-furnace conditions. The void fraction of the stock column, for example, varies widely from place to place and is affected by the segregation of charge materials, attrition of lumps during descent, and channeling. Gas density varies with changes in local pressure, temperature, and composition, while viscosity varies with temperature and composition. Even if mean values for these functions were acceptable, they would be either impossible or extremely difficult to determine with a high degree of accuracy since the value of the mean for all gas properties would depend upon the flow distribution itself. Attempts to study gas movement by the pitot-tube determination of kinetic pressures have met with little acceptance. Reproducibility of results is extremely difficult to achieve in a situation where alignment of the tube orifice with respect to the flow direction in tortuous channels cannot be guaranteed. Because of these difficulties it would appear that progress can be achieved only with a direct method of measuring gas velocities and determining the shape of flow paths through the stock. The establishment of such a method is described in this paper. SELECTION OF METHOD Direct measurement suggests the use of a tracer by means of which the progress of a "parcel" of gas can be followed through the furnace. Several requirements must be met before any selected material can be considered a suitable tracer. First of all, it must be a substance not normally present in blastfurnace gas or dust; otherwise its presence in a gas sample will have little significance. It should be volatile at temperatures normally existing within the furnace, to ensure that it will travel with the gas, as a gas. It should possess special properties enabling its presence in the gas to be detected readily, and it should not undergo exchange reactions with any material normally present within the furnace, including refractories and coke as well as all components of the metal and slag. Radioactive materials naturally are considered because their radioactivity renders them susceptible to detection. However, of the many radioactive materials available, almost all are eliminated from final consideration by their unsuitability in terms of other properties. Radioactive silicon, carbon, calcium, phosphorus, and many others have been considered and discarded, either because they are not volatile over the whole range of significant temperatures, or because they could be expected to undergo exchange reactions with burden or refractory materials. Others which might be suitable in terms of these properties are eliminated because of a low activity, short half life, or the necessity for fragile counting apparatus. Of the many elements available in radioactive form, perhaps radon is the only one suitable for blast-furnace gas-flow studies. This has been used in several investigations1-4 with considerable success. The use of radiotracers has certain inherent disadvantages. One is the cost. An appreciable sum must be allowed for materials each time a test is made. Also, special methods of handling must be employed, and very often the progress of an investigation must be governed by the availability of isotopes and the delivery arrangements that can be made for them. An advantage is immediately gained if the tracer material can be a substance which can

Jan 1, 1960

By Jorge Armstrong, Sean Warren, JOSEF BOURGEOIS

The paper investigates the influence of slope height, slope angle, slope material, and rock size on rockfall runout distance in openpit mines. Using statistical analysis and simulation, the study aims to improve rockfall hazard assessment and catch bench design by identifying key variables affecting rockfall behavior.

Oct 1, 2023

By Gene Long

10.4-1. Load Design and Construction. Surface mine haulage roads are used for transporting raw products to the mine site, preparation plant, or loading facilities, and to provide personnel and equipment an access to the pits and mine area. All of the aspects of highway engineering, including minimum slope inclines, properly banked curves, and adequate drainage, must be followed to facilitate construction of safe and efficient haulage roads for fast and economical transportation of the mined product to its destination. By maintaining good haulage roads, both truck and equipment maintenance will be kept to a minimum, resulting in reduced mining costs and subsequently higher profits. [ ] There are several basic considerations in haulage road planning. Most important, one must follow all safety procedures in both design and construction of the roadway. A maximum effort should be made to follow current mining plans when laying out and planning haulage roads (aerial photographs can be extremely useful in planning and routing of roadways). Grades, road widths, and curves must be maintained within limits of present and/or planned haulage equipment specifications, since all these factors can limit speed, and hence production (Table 10.4-1). Grades in most mining operations are adverse (against the loaded haul), which increases haul cost per mile. Operators must balance these increased

Jan 1, 1968

By W. C. Meyer

A physical model of flotation, derived from viewing froth as a kinetic species since it constitutes the carrier of ore particles, not only agrees with and is simulated by engineering math models, but is statistically verified by actual laboratory flotation data. The model couples the mechanical removal of froth using paddles with the more rapid chemical interactions taking place in the bath. It clearly shows that the kinetics of mass removal is dictated by flotation cell dimensions, paddle speed, and, more importantly, froth characteristics. Some conclusions and predictions of the model are presented.

Jan 1, 1982

Bureau of Medical Inspection, Broken Hill, New South Wales.INTRODUCTIONFor a considerable time it has be3n realised that the pathological changes produced in human lungs by the inhalation of free silica varied, not only according to the amount of silica inhaled, its particle size and the period during which it was inhaled, but also according to other mineral elements which might be admixed with the fine silica dust and inhaled along with it, or inhaled subsequently to the silica containing dust. It was observed that, in many instances, these admixed dusts tended to inhibit the action of the free silica in causing injury to the lungs, as well as the development of certain complications, whilst in other cases it was felt that certain substances could actually accelerate the tissue damage caused by the silica.A fresh impetus to the problem of the prevention of the development of silicosis was given when, in 1937 and 1939, Denny, Robson and Irwin published papers entitled &quot;The Prevention of Silicosis by Metallic Aluminum.&quot; Working at the same time at the Saranac La.boratory, and quite independently, and using a colloidal aluminum hydroxide, Gardner arrived at the same conclusions as Denny, Robson and Irwin, namely, that in experimental animals the development of silicotic changes could be prevented if eithertogether with the silica, or subsequent to its inhalation...

Jan 1, 1946

The 15m high Inco flash furnace uptake was designed as a reaction chamber with the objective of destroying the H2S contained in the furnace off-gas by combustion with oxygen at about 1300°C. Until recently, the oxygen required for this purpose was injected through afterburners located at the bottom of the uptake. An undesirable side effect of this practice was the formation of build up accretions on the inside walls of the uptake. This buildup had a negative impact on both the furnace on line time and the control of the flash smelting process. In late 200 I, the afterburners were relocated to the roof of the uptake. As a result, about 80% of the uptake accretion buildup disappeared with obvious beneficial effects for the operation of the furnace. This paper discusses key flash smelting aspects that affect the operation of the flash furnace uptake such as the dusting rate, the formation of H2S in the freeboard of the furnace, and the impact of using coke to supply some of the heat required by the process. The mechanism of buildup formation and its dependence &apos;on uptake afterburners location are also examined. Prof. Yazawa&apos;s sulfide smelting thermodynamic relationships proved instrumental in understanding the conditions that influence the formation and the elimination of H2S and uptake buildup.

Jan 1, 2003

By J. B. Gwiazda

Maintenance of a constant load setting throughout longwall support units and selection of the proper initial bearing capacity depending on the type of roof strata are the basic factors that ensure good performance of roof support in a longwall. These requirements can only be met by hydraulic support. The greatest advantage of hydraulic support is achieved when uniform pressure is imposed on the roof throughout the length of the longwall. Such support, however, is provided only if each of the support units acts with the same force against the roof, i.e., has the same setting load. In such cases, the roof behaves like a uniform plate without bending and shearing stresses, thereby ensuring an undisturbed structure. Without a positive set value system, achieving an equal setting load for all units of the longwall support is impossible. Due to alterations of the feed line pressure of support units as well as some reasons related to man&apos;s psychology, operators extend the height at different setting loads. This produces nonuniform roof stress, and disturbs the structure. Consequently, the roof usually cracks. The author has developed a positive set value system, which is described in this Technical Note. Selection of the setting load Two pressure values in the feed lines are usually applied in longwall hydraulic systems. Lightweight support is fed by 25 MPa (250 bar) liquid, while heavy duty units receive a nominal pressure of 31.5 MPa (315 bar). Such pressure is required not only for the props but also to power the adjust¬ment jacks and the advancing ram. If the feed pressure is too low, there will be difficulty in shifting the unit despite the inversion system of the advancing rams. On the other hand, for many roof types, the feed pressure often appears to be too high when applied as the setting load pressure. An excessive setting load acts too strongly against the roof, crushing weak strata close to the roof. The author has recognized a case where an excessive setting load destroyed not only the nearby roof strata but also the strata above a 2-m (6.6-ft) sandstone layer. In addition, an excessive setting load relieves the side¬walls, increasing the resistance when using cutting machines. As a result, the yield of coarse coal is diminished, and increased fines dominate in the final product, lowering its economic value. As indicated, selection of the proper setting load, depend¬ing on the mining and geological conditions of the extracted seam, is extremely important. In some mines, measures applied to prevent disturbances include reduction of the feed line pressure by adjusting the feed pump valve. The disadvantage accompanying reduced feed line pressure is more difficult operation in advancing the ram. Due to the reduced feed line pressure, the force of the advancing ram is much lower than the designed value. Other designs suggest using a third feed line. However, installation of supplementary valves on the support units is required, a time-consuming and expensive procedure. The disadvantages of the powered supports are eliminated by a system designed by the author. So far, such a method of setting load control has not been used in any type of support. Setting load control unit The designed positive valve set for prop loading and the setting load control correspond to existing control systems for hydraulic powered support. The layout of the unit connected to the hydraulic prop control is presented in Fig. 1. The unit is marked LIDS. It incorporates three valves that may operate separately or connected. Valve A automatically opens and closes with liquid flow in the prop feed circuit. The valve is opened when the canopy touches the roof and closed when the support unit is withdrawn. Valve B serves as the setting load control. Valve C automatically opens and closes the flow in the line connecting the under-piston space of E to the prop F with the separator G. The valve block of each support prop is marked BZ. The UDS unit is connected by the hydraulic lines to the F prop control circuit. A valve is connected by H to pressure line J and by K to the G separator. In the UDS-3 version, line L is connected to M, linking the over-piston space of F prop with the G separator. Valve B is linked with valve A by a connector; it is also connected to the under-piston space E of prop F by line P. Valve C is fixed between lines K and P, connecting space E of prop F with the separator G. When setting the support, the liquid flows from line J through separator G, the BZ valve, and valve C to the space E of prop F. When reaching the roof with the canopy, valve A is opened and C closes. In this way it is impossible for the operator to cause the liquid pressure in space E of prop F to reach the level of line J. The prop pressure is set by valve B of the UDS unit. When withdrawing the support, valve C is automatically opened and A closed. Three UDS units have been fabricated and are designated

Jan 1, 1990

By R. Hogg, S. Chander

"The distribution of the wettability of coals of different rank was determined by measurements of contact angles for individual particles. The contact angle was estimated from the equilibrium partitioning of a particle at the water/air interface. Using this technique contact angles were determined for a larger number of particles from a given sample and a frequency distribution of contact angle was obtained. The contact angle distribution was broad for all the coals tested with included an anthracite, a hvA bituminous and a sub-bituminous coal. In comparison, spherical particles of polymethylmethacrylaie gave a much narrower distribution. The distribution for irregular polyethylene particles was somewhat broader than that for the polymethylmethacrylate spheres but broader than that for the polymethylmethacrylate spheres but considerably narrower than that for coal. The broader wetting distribution for coal was attributed to differences in surface chemical properties.INTRODUCTIONA knowledge of the wetting properties of coals is very useful in coal cleaning by flotation and other processes in which separations are based on differential surface properties. The various methods available for measuring wetting characteristics include: contact angle, 1-2 time, time, 3-5 bubble attachment, 6 film flotation,7 displacement pressure, 8-9 penetration rate, 10-11 bubble pick-up, 12 induction time, 13 imbibition time, 14 and calorimetry. 15-16 Of all these methods, however, the measure¬ment of contact angle by the sessile drop and captive bubble techniques have been most widely used. Brady and Gauger"" demonstrated through the use of the contact angle method that the natural hydrophobicity of coal varied greatly from sample to sample. Subsequent experiments showed that this difference correlated well with rank, the larger contact angles generally being associated with the higher rank coals. 18-19 More recent studies by Aplan and co-workers' show that the wettability of various ranks of coals as determined by sessile drop and captive bubble methods is a more complex function of rank. The hydrophobicity of coal usually increases with rank up to about 80% fixed carbon (dmmf) and then decreases."

Mar 1, 1992

By Reynold Q. Shotts

Underground mines, penetrating well below the water table, quickly fill with water when abandoned. Ordinarily, these natural cisterns are not thought of as sources of industrial water. Under special circumstance, if chemically treatable, they might become valuable industrial water reservoirs. An example of a group of about 20 mines in a geological and structural setting insuring water entrapment, rapid recharge and a possible minimum of contamination, are the small, compact Belle Ellen and Piper basins in Alabama&apos;s small but second most productive coalfield, the Cahaba. The mines have been abandoned from more than 50 to less than three years. The county now produces about a million tons of coal annually, all from strip mining. Figure 1 shows an idealized cross section of the strata in the Belle Ellen syncline near West Blocton, Bibb County, Alabama. Figure 2, 3 and 4 are maps showing the location of the syncline, other structural features, the outcrop lines of the three principal coalbeds underlying the basin, and the mined-out areas on the three beds (1).

Jan 1, 1973

By Milton H. Fies

Although pig iron from iron ore and red cedar charcoal preceded the mining of coal by many years, for tradition says that Alabama iron was used to shoe the horses of Andrew Jackson&apos;s soldiers, coal was not produced until 1830. In that year, coal was mined in Tuscaloosa County, in the vicinity of what is now the University of Alabama, and shipped on flat boats (obviously during the wet season, for there were many shoals) down the Warrior River to Mobile. About that time, the first railroad, the Decatur & Tecumseh, was being constructed in northern Alabama to overcome the obstructions to freight traffic caused by the now well-known Muscle Shoals in the Tennessee River. This railroad was patterned after a railroad at Mauch Chunk, Pa., which was used for hauling anthracite from the Panther Creek valley. The Alabama railroad, which required about four years to complete, was 46 miles long and was used solely for the transportation of cotton. Although it was a failure, it demonstrated the practicability of the undertaking, and the succeeding railroads, which were begun in 1834, 1848, 1852, and 1853, added immeasurably to the development of the coal resources of the state. Between the years 1830 and 1860, practically all the coal mined in the state was dug from the outcrop near the river or from the river beds, and shipped by boat to Mobile. Transporting coal down the Warrior River was an undertaking of great risk, required much skill, and frequently had heavy losses. It is recorded that this coal was sold to the gas company in Mobile in 1844; it was most likely mined from the Black Creek Seam. In 1914, on the completion of Lock 17, the Warrior River became a navigable stream from 9 miles above Cordova, Ala., to Mobile and offers a great opportunity for the future development of the coal resources of the state. Coke for foundry use was first made in Alabama in 1855. It was 21 years later, however, in 1876, that pig iron was made from Alabama ore with Alabama coal.

Jan 1, 1925

By M. S. Seehra, R. S. Pandurangi

"A comparative study of the intensities of the IR modes in the pjlotoacoustic and. FrIR spectroscopy of amorphous and crystalline SiO2 particles is presented. It is observed that in photoacoustic spectroscopy of amorphous SiO2, IR modes of surface species are enhanced by over an order of magnitude compared to the bulk IR modes of SiO2. This effect, though not yet understood, may find applications in surface science.Since the publication of the Rosencwaig-Gersho theory of the photoacoustic effect in solids in 1976 [1], a great deal of attention has been paid to the development .of photoacoustic spectroscopy (PAS) into an analytical technique for condensed matter studies, especially when combined with the modern Fourier transform infrared (FTIR) spectrometer [2-8]. PAS has now been applied to a variety of experimental situations [2, 3] and it is particularly suitable for opaque powders and for cases where ~ample preparation (e.g. mixing with KBr as is usually done in FTIR spectroscopy) is not desirable. Another area of interest is the depth profiling feature of PAS, which is studied by varying the modulation frequency of the incident radiation [2-8]. The one-dimensional Rosencwaig-Gersho theory for non-porous samples has been extended to other cases [9-12]. Recently it has become known [11, 12] that for porous samples with porosity the IR modes are enhanced by a factor proportional toe. This enhancement is due to the pressure wave set up in the interstitial gas in the porous sample and this enhancement has been reported by a number of groups [12-14].In this Letter we report the observation of anomalously large enhancement of the PAS signal for certain surface IR modes on the surface of amorphous silica particles. This observation differs from the previous reports in that certain surface modes are enhanced by over an order of magnitude compared to the bulk IR modes. Although the reasons for this enhancement of the surface IR modes in PAS are not understood at present, this observation may open up new approaches to the study of surfaces. Results of these initial observations are given in this Letter. ·Experimental studies reported here were carried out on an FTIR spectrometer (Mattson Instruments, Model Cygnus 100) equipped with an MCT detector. The same instrument was used for PAS studies in conjunction with an MTEC (Model 100) PA cell. The sample cell and the spectrometer are continuously flushed with dry, CO2 free air obtained by the use of Balston Instruments Air Dryer Filter System (Model 75-60). Usually data were collected for 32 scans at 4 cm-I resolution, although both scan and resolution can be varied. For FTIR studies, samples were mixed with IR-grade KBr and pelletised. For PAS, no sample preparation is necessary and data are ratioed against dry carbon black [4, 5]."

Jan 1, 1989