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By John Shirokoff, Ladan Khaksar

"Cyclic polarization technique and also potentiodynamic measurements were applied to study corrosion behavior of 13% chromium steels in chloride containing environment. Potentiodynamic measurements were performed at 25 and 75 °C with 0, 10 and 20 g/l NaCl in 0.01 M hydrochloric acid solution. At the same time, the significant pitting parameters such as corrosion potential (Ecorr), pitting potential (Epit), protection potential (Epro) and passive current (Ipass) of cyclic polarization curves with various NaCl concentration were analyzed and compared to describe the corrosion behavior of 13% chromium stainless steel. Surface measurement techniques such as SEM and EDS were used for morphology and analysis of corrosion products. The results showed that both temperature and Cl- concentration had significant effects on corrosion behavior of 13% chromium stainless steel in acidic solution.INTRODUCTION Of all the corrosion resistant alloys (CRA) used in oil and gas developments, martensitic stainless steels (MSS) are some of the most common ones these days. These steels not only have the advantages of normal steels: high strength, cost-effective, easy to manufacture, available in a wide variety of product forms, but they also have good CO2 corrosion resistance at higher temperatures as a result of their 11% minimum chromium content. One of the most common types of MSS used in the oil and gas industry is 13% chromium steel. NACE and API standards both reference several different varieties of 13% chromium steels for use in oil and gas projects(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013). All types of 13% chromium steels have about 12 to 14% chromium and other minor alloying additions, and can be placed into two general groups: conventional and modified. Conventional 13% Cr steels (13Cr) are those most common in oil and gas, some of which are CA6NM (UNS J91150), AISI 410(UNS S41000), and AISI 420 (UNS S42000). These alloys have excellent corrosion resistance when compared to carbon steels up to about 300°F (150°C) and are used for a variety of wellhead, tubular, and downhole components however they have very limited resistance to cracking in H2S (Vallourec Group, 2015). Modified 13% Cr (M13Cr) steels came from the need for increased corrosion resistance at higher temperatures, increased H2S cracking resistance, and increased yield strength above 85 ksi (586 Mpa) primarily for tubular goods and other downhole equipment. These features were developed by taking a conventional 13Cr steel and adding nickel (Ni), molybdenum (Mo), copper (Cu), and other alloying elements. M13Cr provides better corrosion resistance than 13Cr up to about 350°F (177°C), yield strengths up to 110 ksi (758 Mpa), and also improved H2S cracking resistance(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013)."

Jan 1, 2017

The tangible effects of leakage are presented graphically, and a technique for quantifying the leakage characteristics of a ventilation column using the æSolveÆ capabilities of a common spreadsheet is demonstrated. A case study of a working decline in Western Australia is used to demonstrate the potential for more realistic design of development ventilating systems, and for more cost effective management of the condition of the duct.

Jan 1, 2002

By F Diaz, G Hovestadt, B Friedrich, D Latacz, M Sommerfeld

The metallurgical sector significantly contributes to the global carbon footprint and encounters the challenge of developing more sustainable production methods. This study introduces novel approaches aimed at reducing CO2 emissions within the industrial sector, some of which have been developed up to the demonstration scale. In two case studies, urban waste from the agricultural sector (corn, olives, coconut etc) and waste electrical or electronic equipment (WEEE) recycling residues (shredder light fractions (SLF)) were subjected to thermal treatment. The resulting materials were then used as substitutes for conventional fossil-based reducing agents in both the copper and ferroalloy industries. Furthermore, hydrogen was employed at different scales to assess its efficacy as a reducing agent for recovering metal oxides from fayalitic copper slags. Our findings reveal promising prospects and defined specific challenges for the integration of these alternative reducing agents in the industry. The synergistic use of pyrolysed SLF, bio-coke, and hydrogen presents a viable pathway to significantly diminish CO2 emissions while simultaneously improving the sustainability of the metallurgical sector.

Jun 19, 2024

By P. Rusin

Toxic substances in On solutions can retard biological leaching of copper sulfide dump ores. On solutions were analyzed for metals, organics, and chloride, and showed inhibitory concentrations of aluminum, manganese, and chloride. Inhibition of bacterial activity by the solid fraction of On solution, with and without the organic constituents, was evaluated. Toxicity to bacterial species was evaluated by monitoring bacterial numbers, pH, Eh, and rates of iron oxidation. The On solution solids were toxic at 50 -60% of their field concentration. Most of the toxicity of the On solution was due to the organic fraction. Different SX reagents show varying degrees of inhibition of T. ferrooxidans. Bacterial inhibitory effects of carriers and lixiviants used in the SX plant should be determined so that entrained SX reagents do not retard biological dump leach systems. The reagents used should be the most cost effective and the least toxic.

Jan 1, 1994

By H. R. Shell, John L. Miller, M. V. Denny

In the mica research program conducted by the Bureau of Mines at Norris , Tenn . , many micas other than silicon fluorphlogopite have been synthesized . It has been well established since the initiation of the program that synthetic micas are important materials useful for their superior or unique properties as well as substitutes for natural micas . The possibility of controlling the physical properties of synthetic mica by isomorphic substitution of other ions in the fluorphlogopite lattice further emphasizes the importance of these materials . Accurate measurement and reporting of their properties constitute an essential part of the research program . The study of germanium fluorphlogopite is in keeping with the requirements of a comprehensive study on isomorphic substitution , specifically to identify precisely the material -- chemically , structurally , and optically . The X- ray measurements , including indexed powder and single crystal data , with a description of the methods used to obtain these data , are provided . 5 Earlier work on germanium mica by R. A. Hatch et al . (5) gave an estimate of the cell parameters from X - ray powder data , but no attempt was made to index the diffraction pattern or to determine the space group symmetry . Later work by E. A. Schatz and J. C. Withers (9) listed X- ray and optical measurements , but no attempt was made to index the mica or determine its symmetry . Roth (7) found that germanium dioxide having the a - quartz structure , when heated with equimolar percentages of MgO , CaO , Sr0 , or Ba0 at 1,235 ° C , formed ABO3 -type compounds , e.g. MgGe03 isostructural with enstatite (MgSiO3 ) . Geo₂ also has a rutile - type polymorph with Ge ++ ions in octahedral coordination . Germanium was substituted for silicon in the serpentine structure by Roy and Roy (8 ) using hydrothermal techniques . These authors wrote as follows : "The substitution of Ge + for Si + yielded a magnesia - germania serpentine , formed easily in euhedral hexagonal plates which in some instances were visible in the light microscope . Electron micrographs and the sharp X - ray diffraction patterns confirm a plate - like rather than tubular habit . " It has been shown in this investigation that substitution of germanium for silicon in the mica structure is readily accomplished without radically changing the characteristics of the mica . Substitutions in the mica structure take place in three locations : Tetrahedral , octahedral , and interlayer positions . The tetrahedral positions are normally occupied by Sit or by a combination of Sit with Al +3 the most common combination being 2A1 +3 and 6Si +4 · , The octahedral position , which has six - fold coordination in phlogopite , contains a larger cation such as magnesium . In muscovite it contains only 2A1 ions ; therefore , this mica is considered a dioctahedral mica , whereas phlogopite is considered trioctahedral . +3 The interlayer position has twelve - fold coordination with six oxygen ions from each of two adjacent tetrahedral silica layers . This is the cleavage plane of the mica and commonly contains the largest cation in the mica structure (e.g. potassium) .

Jan 1, 1964

By H. Mischo, R. Ellmies

Uranium has been mined in Namibia since the 1970s. The worldwide increasing need for energy in the early 2000s has led to the development and opening of a second uranium mine in 2007 and has triggered an increased interest in uranium exploration, often referred to as “the Namibian Uranium Rush.” In all, four mining licenses have been granted by the Namibian Government, which currently has two mines in operation, a third undertaking trial mining and the fourth in project finance negotiations. In addition, highly intensive prospecting activities at additional deposits are at an advanced stage. The finalization of the strategic environmental impact assessment (SEA) on uranium mining in 2010, the first of its kind and scale in the world, has enabled the Namibian government to assess this uranium rush and its tremendous legal, socioeconomic and environmental impacts and to prepare for the different future scenarios conceivable when this article was written in 2011, including both a skyrocketing and a complete breakdown of demand scenario. The Fukushima disaster and plans of the Namibian government to significantly increase royalties and company taxes in 2011 have threatened the market situation, forcing investors to reevaluate Namibian uranium mining projects. However, with the tax and royalty increase initiative since withdrawn, most projects are back on track at this point in time.

Jan 1, 2012

By Tanya J. Gallegos, Mojisola A. KunleDare, James V. Jones III, Charlotte E. Riggs

The United States Geological Survey (USGS) provides scientific information for the Department of Interior and the nation, consistent with its original mission expressed in the Organic Act of 1879 (43 U.S.C. 31): “the classification of the public lands and examination of the geological structure, mineral resources, and products within and outside the national domain.” Legislation such as the Energy Act of 2020 and the 2022 Infrastructure Investment and Jobs Act (43 USC 31l) and recent executive actions (Executive Orders 14154 , 14153, 14241 Secretary’s Orders 3417, 3418, 3422, 3436) underscore the importance of mineral resources and focus USGS activities on mapping and assessing mineral resources, with a particular focus on those presently identified as critical, both in ground and above ground in mine wastes. This article reviews selected activities and accomplishments by the USGS Mineral Resources Program related to critical minerals in 2025. Highlights include a new List of Critical Minerals, a first-ever national mine waste inventory, international minerals partnerships, mineral resource assessment advancements, and national data collection activities and outcomes of the Earth Mapping Resources Initiative (Earth MRI). The selected contributions are not comprehensive but are intended to demonstrate USGS leadership in critical mineral mapping and assessment, the importance of domestic and global partnerships, and the breadth of research activities that are responsive to national needs and priorities.

May 1, 2026

By J. McCreedy

"The addition of Portland cement to hydraulic sand fill has resulted in the production of stable and self-supporting cemented sand fill. The use of cemented fill in the mines of The International Nickel Company has resulted in substantial economies in timber requirements, de-creased dilution of ore and greater flexibility in mining methods.Coupled with special mining techniques, it has permit-ted mining by both cut-and-fill and shrinkage stoping methods to much greater depths than heretofore. The use of cemented sand fill has permitted revisions to undercut-and-fill mining which have significantly improved the efficiency of this method.Automated mixing systems have been developed for preparing cemented sand fill in surface sand plants on a continuous throughput basis. Control of cement-sand mixtures is obtained by the use of a mass flow measuring system and weighing cement feeders."

Jan 1, 1966

By Yongbin Yang, Meixia Cai, Yufeng Guo, Guanzhou Qiu, Tao Jiang, Jianjun Fan

"A series of sintering and metallurgical experiments were carried out to optimize the blast furnace burden structure in this study. The results indicated that the sinter disintegrated seriously with basicity around 1.4, and after this “turning point”, the sintering properties were improved gradually with the increase of basicity of sinter. Based on the results, an idea was put forward which focused on producing two different kinds of sinter with different basicity. Different with the original burden structure of 85% sinter with basicity 1.4-1.5 + 15% pellets, an alternative new BF burden structure was proposed by the following structure?44% sinter with basicity 1.05 + 44% sinter with basicity 1.87 + 12% pellets. This new alternative BF burden structure has been adopted by some steel plants.IntroductionIn recent years, conventional blast furnace (BF) process was put into operation to produce hot metal in “A” steel plant. “A” steel plant owns two sets of sinter strands at present. Because the sinter production capacity exceeds the actual requirements of BF, a burden structure with 85-90% self-made sinter + 10-15% purchased pellets is adopted to take advantage of the low–cost sinter. But the serious problems encountered with the BF operators are that the sinter disintegrated easily during transportation and storage process. Therefore, the rate of return fines is very high after sinter being screened."

Jan 1, 2012

By Megan Badonie, Devlon Shaver, Evan J. Owen, Virginia T. McLemore, Jakob Newcomer

Critical minerals are becoming more important in our technological society because they are used in many of our electronic devices, batteries, and magnets. In New Mexico, low to moderate concentrations of critical minerals are found in Late Cretaceous coal and related strata in the San Juan and Raton Basins. These rocks are being characterized as part of the DOE’s CORE-CM (Carbon Ore, REE, and Critical Minerals) program. The New Mexico coal, humate, and clinker deposits are relatively low in REE (<325 ppm TREE), Li (<90 ppm), V (<168 ppm), Co (<51 ppm), Ni (<108 ppm), Zr (<557 ppm), and many other critical minerals compared to normal economic deposits. Some of these rocks are enriched in Al2O3 (<40%) and Sr (<3740 ppm), both critical minerals. Common minerals hosting the critical minerals in these rocks include clay minerals, zircon, and rutile/anatase. As the demand for some of these elements increases because of increased need and short supplies, the dollar value per ton of ore rises, enhancing deposit economics. Ultimately, economic potential will most likely depend upon production of more than one commodity, maybe even from coal, humate, and clinker deposits.

Feb 1, 2024

By Charles E. Locke

IN gathering material for this review the aid of the individual members of the Milling Committee was invoked and the assistance received is hereby most grate- fully acknowledged. The replies were much alike; almost everyone stated that in 1932 his operations had been cur- tailed or stopped entirely, that the only activity and progress were in milling gold ores, and that the Hadsel mill&apos; looked like a coming machine in the crushing and grinding field. However, further inquiry and search have shown that the year was not quite so barren of developments as the foregoing statement would indicate.

Jan 1, 1933

By X. Wang, Y. Luo

The propensity of coal spontaneous combustion can be evaluated using various laboratory testing methods, such as R70 adiabatic tests, thermal gravimetric analyzer (TGA) tests and critical self-heating temperature (CSHT) methods. Each of the methods has its unique characteristics and index for classifying the propensity of self-ignition of coals. Accountable relationships among the propensity indices of different methods should be established. Using the newly established R70 and TGA testing setups in our ventilation laboratory, samples from U.S. coal mines have been collected and tested. The TGA is a relatively new quantitative method. A test can be conducted in a relatively short time, within about one and a half hours, compared to the adiabatic tests. The temperature and weight of the sample can be measured with high precision and then used to determine the activation energy of the coal, which is a good indicator of the potential for self-heating. Under a specific experimental design, the TGA technique could perform the proximate analysis for determining coal quality parameters (e.g., moisture, volatile matter, fixed carbon and ash content). These parameters can be used in an empirical equation for assessing the potential for coal self-ignition. The trend of activation energies determined using TGA techniques is reasonably consistent with the trend of activation energies determined using adiabatic tests. As a case study, a comparative analysis of these two methods for determining activation energy was made on coal samples collected from Indiana. The kinetics of the spontaneous combustion mechanism has been explained. If the functional groups of a coal such as hydroxyl (-OH), carboxyl (-COOH), methyl (-CH3), etc., activate more easily with a small amount of activation energy at a relatively low temperature, the coal will have a higher potential for self-heating. With the kinetic and coal quality parameters determined by the TGA setup, it has been found that the coal with a low potential for self-ignition has low self-heating rate, a high activation energy and a high minimum self-heating temperature.

Jan 1, 2012

By Qingchun Yu, Bin Yang, Yong Deng, Heng Xiong, Fei Wang, Minxiu Chen

"Metal aluminum produced by non-electrolysis process received much attention due to its lower energy consumption. In this paper, carbothermic reduction and carbothermic-chlorination of alumina in normal pressure and vacuum were studied. The products were examined by means of XRD, EDS and SEM. During the carbothermic reduction process using carbon reductant in normal pressure, no metal aluminum was found. However, when coal was used as reductant, a mixture containing metallic aluminum, A14C3, and silicon was obtained, but metallic aluminum couldn't be separated from the mixture. During the carbothermic-chlorination process in vacuum, Al404C and Al4C3 were produced by the reaction between alumina and carbon, and Al Ch gas reacted with Al404C and Al4C3 to produce Al Cl gas. Metallic aluminum was produced due to the disproportionation of A!Cl gas and condensed on the collecting plate. Meanwhile, the initial temperature of carbothermic reduction of alumina reduced in vacuum compared with that in normal pressure.IntroductionIndustrial production of primary aluminum is carried out in alumina cell by the so-called Hall- Heroult process, necessitating the use of very high currents of low voltage. The alumina from which metallic aluminum is gained must be chemically pure, otherwise impure metal results. The main drawbacks of the electrolytic production are its very high energy consumption, the release ofperfluorocarbons, and the high specific C02 emissions [1]. During the past years, there were a lot of attempts to produce metallic aluminum by carbothermic reduction of A1203 [2, 3]. Cox [4] determined the vapor pressure over the A1203-C system and performed X-ray diffraction analysis of condensed products. It was demonstrated that an increase in the carbon content in the system leaded to the sequence of transitions: A1203~Al404C~A1zoc~A14C3 ~AI [5]. In any carbothermic reduction process for aluminum, extremely high temperatures (2000 °C ) were required [6]. In spite of considerable effort, the carbothermic reduction of alumina to aluminum remains a formidable technical challenge, due to the high temperatures required, and to the formation of aluminum carbide and oxycarbide byproducts [7]."

Jan 1, 2013

By Gustav Wafe

"INTRODUCTION The discovery in 1901 of ""gusher"" oil production at Spindletop, Tex., Tex., a salt-dome structure, led to exploratory drilling on other known domes and known domes and in areas contiguous to salt domes in the Gulf Coast region of Texas and Louisiana. Early drilling on the flanks of the domal structures disclosed incompetent 3/ shales, which flowed into the hole when attempts were made to drill through them. Often these shales seized the drill pipes and presented with equipment then in use, an insuperable barrier to deeper drilling. The obstructing incompetent shales came to be called ""heaving"" shales by drillers who attempted to drill through them. Formations of this type have hampered the penetration of the drill bit in many area in the Gulf Coast region to such an extent that the drilling of wells through heaving shale has become a major problem."

Mar 1, 1942

By R. G. Warncke, D. Harrington

"INTRODUCTION The use of black blasting powder as an explosive in coal mines has long been recognized as hazardous and has been responsible for many of the worst disasters in American coal mines. One of the most pressing of the numerous problems confronting the Bureau of Mines, upon its creation in 1910 was to determine methods that would lessen the hazards created by the use of explosives in coal mines. The Bureau continued the study begun by the Technologic Branch of the Geological Survey as to the nature of explosives and made numerous tests to determine types of explosives suitable for blasting in coal mines. The Bureau has tested and approved hundreds of types of explosives and has disseminated information on methods and conditions for use underground to make them permissible as to safety. The Bureau of Mines has encouraged the use of permissible explosives for coal-mine blasting, and its experts both in the laboratory and in the field believe that the use of black blasting powder in any form (granular or pellet) is hazardous in any underground coal mine. Despite the information published at various times and innumerous ways and the general knowledge of the hazards that the use of black blasting powder in any form creates in the blasting of coal, the coal mines in the United States, during 1947 used approximately 34 million pounds of black blasting powder (granular or pellet), or approximately 11.8 percent of the total quantity of explosives used by the coal-mining industry.Many coal mines of the United States, for various and sundry reasons, probably will continue the use of black blasting powder, and this circular has been written for the benefit of such users, not that any suggested method or methods will make the use of this explosive safe, but it has been found that methods and conditions of use of black blasting powder can be improved so as to lessen, though not eliminate, the hazards created by its use."

Mar 1, 1949

By J. O. Lewis

In its efforts to reduce waste, and increase efficiencyin oil production, the Bureau of Mines is investigating methods of increasing the recovery from the underground sources of supply, which are the foundation of the petroleum industry and the many allied industries wholly or partly dependent on it. In the face of a demand that is increasing faster than the production and that, in the consensus of opinions of well-informed authorities, is soon likely to outstrip the productive capacity, it is well to consider whether it is not possible to extract more oil from the known sources of supply. It is universally acknowledged that by the usual production methods much oil is left underground, the general opinion being that at least 50 per cent of the oil in a field remains unrecovered when the field is abandoned as exhausted. From the writer's own investigations he believes the average recovery is even less, and if any considerable portion of this oil being left underground could he made available it would have a tremendously favorable influence on the petroleum industry and all the industries dependent on it. In this publication are considered the principles involved in increasing recovery and methods of extracting more oil from the oilbearing formations than by the usual ways of producing. These methods are: The use of gas or vacuum pumps, forcing compressed air or gas through the oil-bearing formations, displacing the oil by water, and better utilization of the natural pressures in the oilhearing formations. Especial attention is being given to a processcommonly known as the Smith-Dunn-for forcing compressed air through oil-bearing formations because it is believed to hold most promise for the future.

Jan 1, 1917

Successful evaluation and exploitation of resources and reserves relies on the collection of high quality sample data. The quality of the sample data must be maintained through the application of a robust quality assurance and quality control (QAQC) program, including documentation of sampling procedures, training of sampling personnel and the regular monitoring of control samples. However, the application of QAQC programs in the minerals industry is often poor and the purpose misunderstood. It is all too common to have good quality control data collected, but no analysis work carried out until after drilling is completed. In a lengthy drill program, this can lead to problems not being discovered and corrected as they happen. Moreover, rectifying problems afterwards will be costly in terms of time and money, if not impossible. The consequences of poor quality sample data are many and include such effects as over- or underestimation of block grades, misclassification of ore and waste, and lower confidence in the resource/reserve models. The purpose of this paper is to highlight, using case studies, the importance of good QAQC practices to monitor the quality of sampling and laboratory sample preparation and analysis.

Mar 1, 2010

By G. Kleyn

"Sub-standard practices and their adverse impact on safety performance remain a challenge in the South African gold mining industry. The purpose of this study was to investigate the root causes of sub-standard practices and the effect on safety performance in South African gold mines. The focus of the study was on the underground production operations at a gold mine in the Free State. The study consisted of three parts: a personal investigation into the causes of sub-standard practices at the mine, a comparison with the results of a cultural study performed at the West Wits mines, and a behavioural survey.The studies described in this article yielded similar results in terms of the key drivers behind sub-standard practices. It was found that substandard practices had a number of causes, and the origin lies within the habits, attitude, and behaviour of employees. Current methods of addressing sub-standard practices and improving safety performance were found to discourage employees from performing work safely and according to procedure. It was concluded that the lack of critical behavioural habits for the given work environment and job title could possibly be the primary reason for the occurrence of sub-standard practices. IntroductionSince the implementation of the Mine Health and Safety Act, 1996 (Act 29 of 1996) and the Mine Health and Safety Regulations, the South African mining industry has been striving to improve health and safety performance and has placed great emphasis on adherence to mine standards.The Act requires employers in the mining industry to report accidents, incidents, and dangerous situations to the Regional Principal Inspector of Mines in their area. The data provided by employers is captured and analysed by the South African Mines Reportable Accident Statistical System (SAMRASS) and made available for public viewing (Department of Mineral Resources, 2011).A review of the national mine-related accident statistics shows clearly that the South African gold mining industry has improved its safety performance markedly over the past decade, but is still facing major challenges (Figure 1). These include meeting the Mine Health and Safety Milestones (Department of Mineral Resources, 2011)."

Jan 1, 2016

The Operation of the LAROX PF-50 Pressure Filter at &apos;Ellatzite-Med&apos; Flotation Plant, Bulgaria The implementation of Larox pressure belt filter, type Larox PF-50 provided within 6˜8% moisture content of the produced copper concentrate, which allowed good market realisation. The start-up of the pressure filter in 2009 reduced the electricity costs several times and had a positive impact on the technological regime of flotation. This article reveals the investigation results from the operation of the pressure filter according to different situations (density of the pulp, time for filtration, pressure of the material, pressure of the drying air, time for drying with air and other factors). The investment made in the pressure filter application is a guarantee for the successful operation of &apos;Ellatzite&apos; flotation plant, Bulgaria in the coming years.

Sep 13, 2010

By Charles Will Wright

The purpose of this paper is to present briefly certain preliminary results of the study of mining methods by the United States Bureau of Mines; to show the relative importance of each method in terms of tonnages mined and man-hours consumed; to give to the mining engineers and particularly to the young student of mining a better understanding of the principal mining methods; and to indicate changes now in progress and to present suggestions for improvements in the art of mining. Questions of mine development and details of underground practice such as drilling and blasting, loading, hauling, hoisting, ventilating, pay systems and mine management are omitted, as these have been or will be discussed in other bureau publications.

Jan 1, 1931