Search Documents

By Ernt. W. D.

A membrane based mixed extractant process was developed for selective removal of copper from waste acidic cupric chloride etchant solutions found in printed wire board manufacturing. The process uses a mixture of Adogen 381 (tri-isooctylamine), MOC®-45 (ketoxime) and MOC® 55TD (aldoxime) in a kerosene diluent. The mixed extractants recover the copper from a hydrochloric acid medium and transfers it to a sulfuric acid medium. The process also utilizes unique wetted membranes to separate the aqueous and organic phases. The driving force for these membranes is not pressure but the difference in surface tension between the two phases. By using these membranes, complete phase separation results. There is no physical entrainment contamination as found in conventional systems. The only cross contamination is the solubility concentration of one phase in the other. This however is less than 10 mg/l.

Jan 1, 1998

By Kenneth L. Driggs

The Environmental Protection Agency's Clean Air Act? of 1970 provided the driving force for the current Magma Smelter configuration. The historical and technical perspectives of those process developments are reviewed?. Innovations in procedures and equipment have allowed compliance with the requirements of the regulating authorities?. The wet scrubbing of converter gasses and the monitoring of converter operations by a controlling foreman are two of the major contributors? to these successes. The Clean Air Act Amendments of 1990 have posed many new concerns? for all U.S. industry, including the few (seven) primary copper smelters remaining. Future concerns include tightening the sulfur dioxide ambient ?Standard from the current three-hour averaging period to one hour.

Jan 1, 1992

By M. P. Neira

In-situ leaching of copper from chalcocite relies on ferric iron concentration in the lixiviant being reduced to ferrous. To re-establish the ferric concentration in solution, ferrous must be re-oxidized. This reaction is slow under normal chemical conditions but it is catalyzed by Thiobacillus ferrooxidans bacteria. BHP Copper's Miami In-situ unit developed a bio-reactor as a method of oxidizing ferrous to ferric. The effects on oxidation of temperature, CO2? oxygen, and air injection flowrate were defined. This paper summarizes the results of ferrous bio-oxidation using plastic column packing and oxide ores as bio-reactors and the leaching results of the bio-reacted lixiviant on chalcocite ores.

Jan 1, 1997

By C. V. Jude

This U. S. Bureau of Mines (USBM) report presents results of stress analyses and field observations to investigate the effects of elevated trench drifts on the structural stability of rock mass zones surrounding a production draw drift in a mine utilizing a mechanized load-haul-dump (LHD) trench undercut panel caving system. A two-dimensional boundary-element mine stress model was developed to predict the locations and extent of damaged rock mass zones surrounding draw drifts where adjacent, parallel trench drifts are either elevated or not elevated above the LHD production draw drift level. A Mohr-Coulomb shear-failure criterion was obtained directly from in situ borehole shear test data. Hock-Brown shear-failure parameter values were computed from borehole-shear and triaxial test data. A procedure is described to estimate these parameters when a rock mass rating (RMR) value and triaxial data on intact samples exist, and no borehole shear test data exist Results indicate that trench drifts, elevated to the level equal to the height of the LHD production draw drift, would not minimize material damage nor significantly enhance the stability of rib and crown pillar zones surrounding production draw drifts in the mechanized LHD trench undercut caving panel investigated at this mine.

Jan 1, 2010

By D. E. Shanks

The Bureau of Mines surveyed a variety of inorganic ion-exchange materials to determine their suitability for removing valuable accessory elements and troublesome contaminants from metallurgical process and waste streams. Most of the materials, which included molecular sieves, heteropolyacid salts, and hydrous metal oxides, did not give adequate separations, did not have the necessary stability in strong acids or bases, or were not in a physical form suitable for ion-exchange use. Many of the suitable inorganic materials, especially the hydrous oxides, were capable of cation exchange with high capacity only in basic conditions, which caused hydrolysis of most of the cations tested. Multivalent anions, such as arsenate and phosphate, were easily removed from acidic solutions by hydrous oxides. Hydrous zirconia was the best material for this purpose. Multivalent anions were not easily des orbed because of compound formation; therefore, conventional ion-exchange techniques could not be employed. As an alternative approach, hydrous ferric hydroxide was used as a filter material to remove arsenate and phosphate from acid solutions. One gram of arsenic was removed from solution for each 20 g of ferric hydroxide. Ferric hydroxide is preferable to hydrous zirconia for use as a filter material because of low cost.

Jan 1, 1983

By M. R. Geer

This report presents the results of washability examinations of seven coals from the principal coal-producing fields of Montana. A complete performance test of the Baum-type jig operated at one of the mines is included, as are the results of cleaning tests made on two of the coals in a dense-medium pilot plant. The coals examined from the Red Lodge, Bull Mountain, and Forsyth fields are comparatively easy to clean. Ash contents of 5 to 10 percent can be obtained at yields of washed coal ranging from 90 to 95 percent. The coal from the Great Falls field, however, could not be cleaned readily to less than 14 percent ash, and the rejection of impurity would amount to over 25 percent. The two coals treated in the dense-medium pilot plant were characterized by sharp separation of impurity, high recovery efficiency, and satisfactory reduction in ash content.

Jan 1, 1955

By M Singh, R C. Steinhaus, J J. Rust

Metallurgical process control systems in mineral plants often employ state-of-the-art monitoring analysers in an attempt to optimise plant operations and enhance mineral recoveries. These systems are unfortunately invariably fed by simplistic ‘sampling’ designs consisting of various in-stream methods or pressurised probes. These are unfortunate compromises and provide a false picture of what a mineral flotation or other process can achieve. The situation is further aggravated by some manufacturers using misleading marketing to suggest discrete cross-stream methods for metallurgical accounting and unreliable continuous in-stream off-takes for control sampling and that they are of synonymous integrity.Reliable, absolute or representative samples are often absent in many modern day concentrator plants, due to compromises around sample taking, particularly in terms of delineation and extraction errors and thus leading to sample bias. For more reliable information from online analysers we need a continuous, but much more reliable sample taken, than is current practice.Online analysers require a fully proportional and continuous supply of sample for effective process control, otherwise maximised or benchmark recoveries will be nothing but a pipe dream. Large discrete cross-stream samples from mechanically less reliable equipment cannot be used as feed to online analysers, as it will negatively impact real-time feedback and efficient process control.It is possible to build correct sampling systems that could do both process controls online and metallurgical accounting at the same time. Multotec Process Equipment (Pty) Limited, in close association with experienced sampling consultant Francis Pitard, have jointly patented a concept to achieve this and which is embodied in the design of the unique Rotating Cone® Sampler (International Patent Application No. PCT/IB2016/057464). This versatile unit for dry and wet applications has high division ratios via two-step sampling and division.A prototype was built and tested to validate the design and levels of precision achievable when employing the unit to split dry mineral fines or even certain foodstuffs.CITATION:Steinhaus, R C, Rust, J J and Singh, M, 2017. Does process control sampling always have to be a compromise?, in Proceedings Eighth World Conference on Sampling and Blending , pp 197–202 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By Tamas Kekesi

Anion exchange in HCl media is considered an efficient alternative to the combination of the conventional purification methods. Anion-exchange distribution functions have been determined for cobalt and the main impurity elements by the technique of batch equilibration. Results were confirmed by spectrophotometric investigations and elution tests. Based on the new and the available distribution functions, combined with the assessment of thermodynamic stability, a procedure of anion exchange separation has been devised to eliminate virtually all the impurities from the cobalt-chloride solution. Separation of copper has been enhanced by the introduction of a preliminary step under reduced conditions. The rest of the impurities are eliminated in a second anion-exchange step applying rinsing and elution stages under oxidized conditions. The optimum parameters of the procedure have been determined according to performance characteristics (purification ratios, yields and volume efficiencies) derived from the analysis of elution curves obtained with laboratory scale ion-exchange columns. Special computer programs have been developed to facilitate thermodynamic simulation, analytical correction and data processing.

Jan 1, 2003

By W Roy

When it comes to plan implementation and securing success in organisations in the 21st century, if there was such a thing as the secret to success it would be effective communication. Commoditisation brings financial, operational and cultural advantages to organisations that use effective communication. Effective communication tools turn æpeople problemsÆ into system control solutions, removing personality clashes that hide procedural malfunctions. By introducing communications frameworks available in the market place today, and case studies of their use, this paper provides insights into the successes available to organisations courageous enough to redefine their communications for the 21st century.

Jan 1, 2006

By R. B. Crookston

Oil shales differ from coals in that they contain less carbonaceous material, convertible to volatile hydrocarbons, and more inorganic rock. In all pre-commercial oil shale development, involving extensive full scale mining operations, there have been no explosions. However, large scale mine tests with oil shale dusts by the Bureau of fines showed that propagating explosions could be induced under certain circumstances. Laboratory tests were conducted on a broad spectrum of oil shale dusts to define chemical properties and to seek correlations with subsequently determined fire and explosivity properties. These latter properties, indicative of safety hazards, increased as the Fischer assay oil yield of the dusts increased and as particle size decreased. Laboratory data were used to relate fire and explosivity properties of oil shales to those of coals and other carbonaceous materials and to assist in the identification and evaluation of potential hazardous situations which may be encountered in oil shale mining and processing.

Jan 1, 1978

By Braden Lusk

The problem of predicting damage in densely developed areas due to incidental or malicious explosions is one of considerable importance to local, state, and federal governmental bodies. The difficulty of making such a prediction is confounded by the urban canyon phenomenon as the shock wave intensifies or rarefies depending upon the particular arrangement of buildings. The specific method detailed herein used a Computational Fluid Dynamics solver, ANSYS AUTODYN, to operate on Geographic Information Systems data, ArcGIS, which captured the geospatial relationship between the various buildings in downtown Oklahoma City, prior to the Murrah Building bombing. The model of Oklahoma City was first developed using the building footprints and elevations provided by the ArcGIS database. Due to the sheer size of the problem, the model was then subdivided into annular zones of increasing distance from the center of the blast. Each subsection was then solved using an Euler model in a cascading fashion with the output of the preceding model forming the input of the present model. To further reduce computational time, the size of the Euler nodes was increased at each stage as the section area increased. Due to the loss of precision in capturing peak pressure values when using larger size nodes, it was necessary to perform a transformation on the results using one dimensional wedge calculations with higher precision. The Murrah Building bombing event was an excellent case study due to its available ArcGIS data and the level of documentation of damage to surrounding structures due to the blast. The results from the staged CFD calculation were then used to develop a damage potential contour map. The documented incidents of damage in the area surrounding the Murrah building were then compared to the model generated damage potential contour map. Copyright ©

Jan 1, 2010

By B. J. Scheiner

The Federal Bureau of Mines has successfully demonstrated an electrooxidation-solvent extraction-carbon adsorption process for recovering molybdenum and rhenium from offgrade concentrates. The flow sequence consists of dissolution of metal values by electrooxidation, liquid-solid separation by thickening, acidification and chlorate ion removal by sulfur dioxide treatment, solvent extraction to concentrate the molybdenum and rhenium, separation of molybdenum and rhenium by carbon adsorption, and metal recovery by crystallization. Molybdenum and rhenium were recovered as ammonium paramolybdate and ammonium perrhenate. Electrolysis of brine-concentrate pulps to generate a hypochlorite oxidizing agent in situ resulted in the dissolution of 98.9 and 99.1 pct of the molybdenum and rhenium, respectively, at an energy consumption of 13.7 kwhr/lb of molybdenum extracted.

Jan 1, 1976

By Marcel F. DeGuire

Pilot plant operations are described for the treatment of manganiferous zinc concentrates from the Gamsberg ore deposit in South Africa via conventional electrolytic zinc processing. Two methods were employed for the control of excess manganese ions in the pilot plant electrolyte involving (1) chemical oxidation and (2) anodic oxidation. The chemical oxidation method for manganese control was very successful. It also was found that the addition of manganese dioxide ore was not required for oxidation of ferrous iron during the neutral leach or jarosite precipitation steps. A new method (JAR process) for iron removal also was tested in the pilot plant.

Jan 1, 1978

By B. K. Gorain

"The Air-Metabisulfite (AMBS) process has been developed to treat complex copper, molybdenum and precious metals (gold, silver) bearing ores using brackish and sea water. This process was able to produce significantly better copper concentrate grades and higher recovery than possible using conventional lime and/or cyanide based processes for certain complex ores with high sulphide gangue minerals. The AMBS technology in now used commercially following a rigorous evaluation process emanating from laboratory curiosity to plant applications. In addition, many projects have embraced this technology at a feasibility level involving various complex ore bodies.This paper presents a summary of the findings from testing the AMBS technology on various ores types. Experiences gained from this successful development from bench to piloting and then to plant applications are also presented in this paper.INTRODUCTIONProcessing of sulphide copper, molybdenum and precious metal ores typically involves flotation of copper bearing minerals while depressing non-sulphide and other non-copper sulphide minerals such as pyrite, pyrrhotite and sometimes arsenopyrite. Though in many precious metal ores, the values are in these sulphide minerals as well. The conventional method employed in the industry to produce a saleable copper concentrate requires depression of these non-copper sulphide minerals using an alkaline pH above 9.5, though 10.5 to 11.5 is more common. Alkalinity is controlled by the addition of a pH modifier. Lime is normally employed as a pH modifier due to its relatively low cost; however, the costs associated with adding lime can be significant and the effectiveness of lime as a depressant could be drastically reduced when the process water supplied to the flotation circuit contains high level of dissolved salts. In some cases, a small amount of cyanide is used along with lime to depress non-copper sulphide minerals especially when its proportion to copper sulphide minerals in the ore is higher than three."

Jan 1, 2016

By Mäkinen, Eero

OUTOKUMPU, a large copper mine in eastern Finland, has the distinction of being one of the few important mines in the world discovered by a geologist the late Otto Triistedt, of the Geological Sur- vey of Finland, having found the out- clop in 1910 by tracing glacial ore boulders, some of which had been carried as far as fifty kilometres. As the mine had no connection with either railways or waterways and the possibilities of transport were poor, the owners first tried the Hybinette hydrometallurgical process to extract the copper. The raw ore was finely crushed, treated by a sulphatizing roast. and then leached. The resulting solution was electrolyzed, using lead anodes. This experimental plant, having a capacity of 10,000 tons (all Ions are metric tons in this paper) of raw ore and producing 300 to LEO0 tons of electrolytic copper annually, was built in 1913 and run until dis-

Jan 1, 1938

By Roberto L. Romero

The dressing of Bolivian tin ores has been done up to the present by classical. gravity methods, taking advantage of the high specific gravity of cassiterite compared with that of the accompanying gangue. For this purpose, jigs and shaking tables are used in the treatment of the various size fractions in which the ore is classified. Bolivian ores are mainly of the vein type and, to obtain a reasonable separation, crushing and several stages of grinding are necessary during the process to substantially liberate the cassiterite from the gangue. Gravity processes for cassiterite are effective for sizes down to 200 mesh. Below this size the efficiency of the gravity methods falls off very rapidly with increasing fineness of the mineral grains. The conventional treatment for this material is desliming followed by tabling on shaking tables various other types of machines have been designed for the gravity treatment of these fine particles but they have had limited success. Bolivian ores contain an appreciable amount of minus 200 mesh material constituted by "primary fines" caning from the mine itself, and "secondary fines" originated during the crushing and grinding necessary for liberation of the difficulty in the treatment of these fine particles is one of the causes why the recovery of tin in concentrates is only of around 50% in the mines owned by Corporacidn Minera de Bolivia, the State owned enterprise. The average figure for other Bolivian mines is

Jan 1, 1971

By T D. Jolly, L A. Balzan, A R. Harris, Z Bauk

"The availability of real-time data in any process control system is critical for effective management of that system. At MMG LXML Sepon Copper Operation in Lao PDR, controlling the copper grade of the feed to the leaching circuit is paramount for maximising both productivity and copper recovery. Since 2008, real-time analysis data has been available to the process engineers from the Geoscan on-belt analyser installed on the Copper Mill feed conveyor, and highly accurate results on copper grade have allowed the process engineers to strictly control blending to overcome the variability in plant feed grade. The availability of real-time analysis data is crucial, as effective sampling of this stream is both difficult and error-prone, being only a snapshot in time of highly variable ore stockpiles, as well as having significant laboratory turnaround delays. Periodic sampling is used to verify the Geoscan data as accurate. Since its installation, the copper result has been the most critical output of the Geoscan. In recent times, the process engineers have sought to utilise other results from the Geoscan to further improve and control the process. One measurement of particular interest involves the real-time measurement of calcium and magnesium as a gauge of ore feed gangue acid consumption. To satisfy this end, accurate measurement of calcium and magnesium is becoming increasingly more important and has been the subject of ongoing collaboration between Sepon and Scantech, the manufacturer of the Geoscan. This paper discusses this work, describing the calibration process and results obtained, while also providing a basis for Geoscan use in operations to enable enhanced process control for all potential Geoscan users.Citation:Balzan, L A, Jolly, T D, Harris, A R and Bauk, Z, 2016. Greater Use of Geoscan On-belt Analysis for Process Control at Sepon Copper Operation, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 231–238 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By Larry M. Southwick

Considerable process and equipment development and analysis were conducted during design of Freeport Sulfur's laterite nickel facilities in the late 1950's. These covered ore concentration at Moa Bay, Cuba, and concentrate refining at Port Nickel, Louisiana. Both facilities utilized acid pressure leaching and product refining steps that were similar to those later used elsewhere in the laterite processing industry. Unfortunately, developments in Cuba removed the Moa Bay facilities from Freeport control. This deprived the project of a start-up that would have allowed thorough resolution of difficulties and a quicker attainment of production capacity. This meant lost opportunity to positively prove and complete the technology when optimum resources and staff were available. This paper reviews the original rationale of how design was developed via laboratory, bench scale and pilot studies by Freeport Sulfur. Some later operating problems will also be discussed. This case is unusual, but the lessons learned may be instructive in the application of difficult and complicated technologies, as well as the need to understand and retain access to the original development and design activities Keywords: Moa Bay, Freeport Sulfur, Port Nickel, acid pressure leaching, pilot plant, pachuca, Chemical Construction, pressure letdown, cobalt, titanium

Jan 1, 2004

By K. W. Grubaugh

The recently enacted federal surface mine law (P.L. 95-87) will increase further the complexity of securing a reclamation permit. This law intensifies the need to present the required reclamation plan in a thorough and comprehensive manner. One plan format, that used in construction performance contracts, offers promise of filling this need. Reasons for using the format of expressed, bilateral, negotiated contracts common to the contruction industry, and the salient aspects of an application which uses this format are reviewed. Advantages of this procedure are seen to be improved mine planning, awareness of the total design job, potential for improved speed of permit acceptance and improved cost control.

Jan 1, 1978

By Rodrigo Carvalho, Marcelo Tavares

"The accurate prediction of the outcomes in SAG grinding has been a great challenge to researchers and process operators. The use of Discrete Element Methods for modelling charge motion in tumbling mills allowed extraction of not only visual data, such as the position of the charge, but also the energy transfer in terms of the energy dissipated in the collisions. One of the advantages of DEM technique is its scalability to different mill sizes and some operational conditions such as speed and mill filling. Recently the Authors proposed the coupling between DEM outputs and modified Population Balance Models that with proper dedicated ore characterization tests allows the prediction of the outcomes of an energy transfer example. This modelling framework is called the Multi-scale Mechanistic Modelling. This paper shows the application of the Multi-scale Mechanistic Model to a set of pilot plant tests ran at different operational conditions. The prediction of the grinding outcomes and even the stabilization of the charge was achieved by the use of the Multi-scale Mechanistic Modelling framework. This approach has a great potential to become a powerful tool to design and optimize AG and SAG mills."

Jan 1, 2014