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By Antonio Kodsy, Lutful Khan

A research was carried out to test the possibility of reducing the pullout resistance of metal sheet piles driven in clay soils using Electrokinetic (EK) conditioning. The hypothesis was applying an electric gradient for a certain period of time should reduce the adhesion between the clay soil and the sheet piles. Tests were conducted on bench scale thin stainless-steel metal plates embedded in pure kaolinite clay, and mixtures of kaolinite clay and sand. The pullout resistances were determined after 20, 40, and 60 minutes residence times of steel plates in the soils before and after EK conditioning under an electric gradient of 1500 V/m. In kaolinite clay, the pullout resistance showed linear reduction with the duration of EK conditioning and about 60 % reduction in pullout resistance was observed after 60 minutes EK conditioning. For the kaolinite-sand mixtures, the pullout resistances were reduced by about 70% and 80% for 20% and 30% sand contents respectively after 20 minutes EK conditioning and showed no significant improvement with the increase in conditioning duration. It was concluded that the proposed electrokinetic conditioning process could potentially reduce the pullout resistance of metal plates embedded in clay and clayey soils. SHEET PILE WALLS Sheet pile walls are typically used at waterfronts as retaining structures or during the construction phase to shore the soil and avoid collapse of the excavations. When used as permanent structures, sheet pile walls are not removed after the completion of the project. However, as temporary support, they are extracted after the completion of the project and reused. In pure clay soils the extraction processes often becomes a challenge requiring very large pullout forces which could damage the sheet piles. There is a research need for developing an efficient method of sheet pile extraction from clay soils addressing the issue of pullout force reduction. However, very few researches have been conducted regarding the extraction techniques of sheet piles and their economic effect on the cost of a project. In this study a novel method for reducing the pullout resistance of sheet piles in clayey soils using electrokinetic conditioning was explored. The hypothesis of this research is that the electrokinetic process in soil/water system, specifically electrophoresis and electroosmosis, could be used to loosen the sheet pile walls embedded in cohesive soil and hence reduce the required force of extraction. The aim of this study was to test this hypothesis through laboratory tests carried out on steel plates embedded in cohesive soil samples. The pullout forces of the steel plates before and after varied duration of electrokinetic (EK) conditioning were evaluated and compared. The process was also investigated for clay-sand mixtures.

Jan 1, 2019

By Christian Leble, Dr. -Ing. Jakob Vogelsang, Dr. -Ing. Oksana Solt, Dipl. -Ing. Joachim Meier, Dr. -Ing. Wolfgang Orth

In the course of closing the gap between the Brandenburg Gate and Alexanderplatz, the Museum Island station was built by Implenia Construction GmbH. The tunneling for the platform hall took place on a length of about 106 m (347 ft) under the protection of a major ground freezing measure and crossed the Spree canal as well as the listed castle bridge. The approximately 20,000 m³ (4.54 E+06 US gal dry) frozen mass lay mainly in the Berlin sands. In order to ensure safe tunnelling and to protect the adjacent buildings, the planners had defined requirements for the mean freezing temperature and thickness of the frozen mass. For a reliable conclusion on the dimensions of the frozen mass, we used innovative temperature sensors as well as the new, web-based 3D measurement visualization and the associated site-specific evaluation software. The largely automated evaluation enabled a quick and reproducible determination of the temperature distribution in the frozen soil and its thickness in the relevant cross-sectional areas. The measurements were validated by thermal calculations using the Finite-Element-Method. Thus, an objective and clear assessment basis was available to ensure rapid coordination between stakeholders. The evaluations provide new insights into the temperature influences from tunneling, the application of shotcrete and the concreting of the inner shell. The newly implemented active thawing system is also an interesting innovation.

May 1, 2022

By Elders. Wilfred A.

Petrological and geochemical methods, the utility of which has long been established in the mining industry, are proving useful and cost-effective in elucidating the thermal evolution of active geothermal fields. In return, they yield insights into sulfide-silicate equilibria, mass and energy transfer in convecting hydrothermal systems, and the genesis of hydrothermal ore bodies. Within the Plio-Pleistocene sediments of the delta of the Colorado River, in the Salton Trough, several active geothermal systems are known. Temperatures vary from 100-365°C, at less than 2 km depth, and salinities vary from 3,000 to 280,000 ppm, total dissolved solids. The hydrothermal alteration causes marked induration of the sediments, producing greenschist facies metamorphic minerals, including hydrothermal ore minerals. Subsurface authigenic minerals show strong correlation with increasing temperature. A typical sequence in sandstones is (below 150°=C) montmoril-lonite-kaolinite, (above 180°C) chlorite + illite, (above 225°C) calc-alumino-silicates, (above 325°C) biotite. There is a transition from porosity-dominated\to fracture-dominated permeability in the hottest and deepest geothermal reservoirs. This regular series of minerals provides a practical tool during exploration drilling. From drill cuttings, we can make predictions on reservoir temperatures, useful in making decisions on well completion. Other types of geothermometry we have employed include light stable isotopes, fluid inclusions and vitrinite reflectance measurements. A combination of these techniques not only improves our temperature predictions, but together with fission tack annealing studies, permits us to model the dynamics of temperature change and fluid flow in these geothermal reservoirs.

Jan 1, 1981

By Potts J. D.

Installation of a horizontal air-blocking shelf around the inside perimeter of the surface mining drill deck shroud is proposed to improve dust capture. Without the use of this shelf, a strong Coand? effect airflow pattern results in dust leakage to the environment, especially at the shroud-to-ground interface. Bailing air exits the drill hole and travels along the drill steel to the underside of the table, where it fans out across the bottom of the drill table and continues down the sides of the shroud. This dust-laden bailing air then strikes the ground and fans out under gaps between the shroud and the ground. The proposed shelf prevents dust-laden air from striking the ground by redirecting it toward the center of the enclosure, where it can be captured. Laboratory tests demonstrated that the shelf reduced dust levels outside of the shroud by 81% under operating conditions consisting of a 1.9:1 collector-to-bailing-airflow ratio and a 51-mm (2-in.) gap between the shroud and ground. The shelf was 152-mm (6-in.) wide and was located at a height equal to 2/3 the distance measured from the bottom of the shroud to the bottom of the drill table. The air-blocking shelf was also capable of overcoming the adverse impact of vertical leakage along the shroud seams as long as this leakage was confined to an area below the horizontal plane defined by the shelf location.

Jan 1, 2008

The development of the potential supply analytic system has advanced to the point that quantitative estimates of economically recoverable resources can be made as the final step of the traditional regional mineral resource assessment process. In 1983, the BOM and the ADGGS jointly developed a methodology to quantitatively assess the potential for undiscovered yet economically recoverable minerals within a designated geographic area. This methodology was first applied in the assessment of the undiscovered mineral potential of the Kantishna Hills, Alaska (White et al., 1987). At that time the assessment procedure combined a series of technical judgements regarding the major geologic, engineering and economic factors that influenced the occurrence and exploitation of mineral resources in the Kantishna Hills area. Since then the methodology has been further developed and enhanced, particularly with respect to the engineering and economic analysis components. The resulting Potential Supply Analysis System (PSAS) was recently used to evaluate the economic potential of selected types of undiscovered precious-metal deposits in the Tonopah quadrangle of Nevada (Gunther, et al., 1988) and, with some enhancements, has been used to estimate the' economic value of the undiscovered mineral potential of the WMNRA/SNCA study area. The PSAS has been designed to address five basic questions about the mineral potential of an area: 1) What alternative states of geologic nature are possible in the area of interest (e.g. How many and what types of undiscovered deposits could be present and what might be their grade, tonnage and depth attributes?) ?;

Jan 1, 2011

By Steve T. Laflin

Since the beginning of the nuclear era, there has never been a commercial solution for the large quantities of depleted uranium hexafluoride generated from uranium enrichment. In the United States alone, there is already in excess of 1.6 billion pounds of DUF6 currently stored. INIS is constructing a commercial uranium processing and fluorine extraction facility. The INIS facility will convert depleted uranium hexafluoride and use it as feed material for the patented Fluorine Extraction Process to produce high purity fluoride gases and anhydrous hydrofluoric acid. The project will provide an environmentally friendly and commercially viable solution for DUF6 tails management.

Aug 1, 2010

By Lon Santis, Bill Evans, John Tatom

Debris data from the Department of Defense Explosives Safety Board’s Project ESKIMORE full-scale explosives event test program are compared to quantity-distance (Q/D) standards and quantitative risk analysis (QRA) methods. The ESKIMORE test program involved quantities of explosives ranging from 1,000 to 60,000 pounds detonated in typically sized structures made of metal and concrete. Debris from these events was extensively surveyed and catalogued. The debris patterns from these events show varying degrees of directionality normal to the walls of the structures. These density patterns are overlaid an existing explosives storage site that is comparable to the test conditions. Analysis of the debris patterns in relation to Q/D standards shows that exposures located beyond the Q/D arc but along the normal to walls of potential explosion sites (PES) may have much higher debris density than exposures at the same distance on the corners of the same PES. Analysis of the debris patterns shows that predicted patterns using the QRA tool IMESAFR v2.0 closely match actual patterns. Additionally, IMESAFR based QRA methods are able to quantify the different risk levels of being exposed along the wall’s normal as compared to being exposed on the structure’s corner. Methods and decision making criteria to mitigate risk based on the directionality of PES debris are presented. Copyright ©

Jan 1, 2015

By Stephen C. Tadolini, Thomas M. Barczak

Western mines have had limited choices for standing support. Wood cribs were often too soft and unstable. The introduction of the Can support in the early 1990’s provided a very effective alternative and remains the dominant form of tailgate support. Water-filled prestressing cells are now used to cap the Can and preload it to provide an active roof load. The Cluster Prop, consisting of three timber wedge props bundled together, provides more capacity than an equivalent sized Can support and improves transport efficiency. However, the Cluster Prop is less stable and does not maintain a consistent load throughout its loading profile. Pumpable roof supports are another alternative support, but they have not been proven in high deformation environments. Alternative supports are also being used in longwall recovery operations. These include the Rocprop and Omni Prop, which are extendable support systems. They also provide active roof loading which can be beneficial in these applications. Specialty supports, such as the Sand Prop and Spider Prop, have also been introduced into western longwall operations. This paper compares the performance characteristics of these various support systems.

By S. Frimpong, E. Gbadam, W. Nyaaba, G. Somua-Gyimah

Recent studies towards dragline excavation efficiency have focused on incrementally achieving automation of the entire excavation cycle. Initial efforts resulted in the development of an automated dragline swing system, which optimizes the swing phase time. However, the system still requires human operation for collision avoidance. For full dragline autonomy, a machine vision system is needed for collision prevention and big rock handling during the ‘swinging’ and ‘digging’ phases of the excavation operation. Previous attempts in this area focused on collision avoidance vision models which estimated the location of the bucket in space in real-time. However, these previous models use image segmentation methods that are neither scalable nor multi-purpose. In this study, a scalable and multi-purpose vision model has been developed for draglines using Convolutional Neural Networks. This vision system averages 82.6% classification accuracy and 91% detection in collision avoidance. It also achieves an 87.32% detection rate in bucket pose estimation tasks. In addition, it averages 80.9% precision and 91.3% recall performance across terrain recognition and oversized rock detection tasks. With minimal modification, the proposed vision system can be adjusted for other automated excavators. Keywords: Surface mining, dragline bucket, deep learning, machine learning, oversized rock, convolutional neural network, machine vision, object detection, earthmoving equipment. INTRODUCTION Complete excavator automation is widely regarded as the next phase in efforts toward improving earthmoving efficiency. Earthmoving often involves complex, forceful interactions between an excavator and the ground. The nature of these interactions depends largely on the type, properties and physical characteristics of the earth material. This process is further complicated by the random occurrence of tree roots, boulders and other such obstructions. Therefore, the ability of a controller to detect changes in the operating conditions, adjust the digging strategy and respond in real-time is of utmost importance. Early studies into autonomous excavation identified some key performance criteria which included the following [1]: • The autonomous excavator must be able to work in any type of earth material. • Its excavation accuracy must be within 50mm. • It should be able to handle different surface and underground obstacles autonomously. • It should be able to operate at the speed of the average operator in any condition. • Its operation should be capable of safe integration with other site systems.

Jan 1, 2019

Avoca Resources LimitedÆs Higginsville Gold Project has a resource base of over 1 300 000 oz of gold. The Trident underground mine, which forms the basis of the project development, has a resource base of 927 000 oz of gold. Avoca is building the Higginsville Gold Project based on a minimum ten year vision, producing over 150 000 oz per annum. The project development has taken less than three years from the Trident discovery hole in October 2004 to the first ore production in June 2007. This paper discusses the background work associated with the development of the Trident underground mine in a difficult period for new project development in Western Australia. The resources boom, led by the iron ore industry in the Western Australian Pilbara region, is creating cost pressures and, combined with a lack of people and equipment, is placing cost and timing stress on a small developing project. Avoca Resources has developed a project execution management strategy aimed at mitigating cost blow outs and schedule delays.

Jan 1, 2008

Compressive crushing is applied in crushing plants used in mineral, mining, and aggregate in-dustry for fragmentation of rock materials. From a global perspective, the total volume of crushed rock is massive and corresponds to several billion tons. All societies have to fulfil a daily need of rock material products and its derivatives such as metals and minerals. The business for metals and minerals is global while the aggregates production is mainly a local industry. This paper presents a broader overview of optimisation with respect to product yield, use of natural resources and energy consumption. High level plant optimisation of compressive crushing plants is covered as well as real-time optimisation and optimisation of single production units. Each of three optimisation areas are presented and a discussion around how these three areas will be able to communicate with each other is given. Several models, e.g. process performance behav-iour with respect to wear, as well as fitness functions can be common for all three areas. Well-defined and representative fitness functions are of the utmost importance in order to assure that the optimisation results reflect the production targets. It is concluded that great benefits can be achieved by linking together different areas of optimisa-tion. The future for compressing crushing lies, without a doubt, in tailored processes both with re-spect to machines optimised for each customer, plant parameters and operation routines as well as an on-line adjustment, which takes into account current information and control possibilities.

Jan 1, 2014

By M. Morales, J. Yianatos

"In this work, an alternative approach to evaluate the flotation performance along a flotation rougher row is presented. The collection zone as well as the froth zone performances were separately evaluated. For this purpose, sampling for metallurgical balances along with sampling of top-of-froth (TOF) grades in each cell of a flotation row were employed. The modelling of the rougher circuit consisted of using TOF grades for evaluating the collection zone recovery, because they are a good representation of the bubble loading, which identifies the true flotation process, as shown in previous studies for shallow froths. In addition, the feed characterization, size-by-liberation, allowed the identification of the mineral distribution and its evolution along the circuit. The latter result was obtained by fitting the recovery profiles as well as the TOF grades down the flotation bank. The flotation rates and the maximum recoveries in terms of size-by-liberation (size classes: -45 µm, +45-150 µm, +150 µm, and liberation classes: -20%, +20%-80%, +80%) were then estimated. The results were in good agreement with those reported in literature by other authors and showed the new approach allows flotation kinetics to be characterized in industrial circuits.INTRODUCTIONMineral recovery in industrial flotation circuits is a function of the mineral characteristics, such as particle size distribution and liberation (Trahar, 1981, Jameson, 2012), and operating conditions such as air flowrate, pulp flowrate, solids percent and reagent conditioning (Jameson 1977; Klimpel, 1980; Mehrotra and Kapur, 1974). The cell type and size (self-aerated or forced air) and the circuit arrangement (single cells or banks of cells in series) are also relevant factors. Sampling of circuits (e.g. rougher, cleaner or scavenger) are commonly carried out using standard automatic samplers for metallurgical balance assessment. However, the flotation plants are generally not provided with proper accesses for local streams, which hinders the recovery estimations and the flotation rate characterization."

Jan 1, 2018

Mineral processing plant operators are faced with the necessity to choose between many different possibilities for plant improvement. Only a few such possibilities, however, can be tested on the industrial site. Steady-state simulators make it possible to assess the effects of several different flowsheet modifications in a few days, thus helping the process engineer to make his choice implement the solution that seems the most appropriate and check it. The example described here is the crushing and grinding circuit of the Shila Gold Mine, jointly owned by CEDIMIN SA and BUENAVENTURA SA, in Peru. Several possible modifications for the purpose of increasing capacity have been simulated and the results assessed in terms of technical quality, investment costs and energy consumption. The best solution indicated by the USIM PAC simulator was implemented and gave a 20% increase in capacity with a pay-back time of two months.

Jan 1, 1993

By LEWIS F. THOMAS

MINING geologists and mining engineer, rarely give due thought to the geography of mining deposits. They realize, it is true that what may be ore in one place would be only worthless rock in another because f the in accessibility of a smelter r a market; and they may consider the lack of a supply of labor, or water, or power to carry on operations. But they do not think (of these things in terms of geography. Geography may be defined as the science of relationships between earth and man, so geographers are vitally interested in the how and why of mining as it is carried on at different place, having entirely different environment-. Such environments are geographic complexes or composites of natural and cultural elements, which are listed and briefly discussed in the following paragraphs.

Jan 1, 1941

By C. W. Burrows

The burden a man can endure depends on its magnitude and the number of times it is applied, as well as on many other factors. The resisting power of steel likewise is dependent on many factors. The maximum load it can support indefinitely is much less than its possible momentary burden. A light load straining the metal far within its elastic limit, if repeated indefinitely, ruptures the metal. The magnitude of the stresses that may be alternately applied and removed without rupturing the material depends on the number of repetitions of the cycle; the intervening periods of rest; the thermal, electric, and magnetic conditions, as well as the presence of secondary streessses. While we are unable to formulate the law between the magnitude of repeated stresses necessary to produce rupture and the length of time during which these alternating stresses may be applied before rupture, my experience is that the time increases as the magnitude of the force decreases, according to a law which! to a first approximation, is exponential. In other words, F = Ce-t where F= magnitude of alternating stresses; t= time for which stresses are continued; C = constant, which depends on the conditions under which the operations are carried out. It is quite probable that the same type of law holds for the magnitude of a continuous force and its duration. When a rod of steel is subjected to the blows of a drilling hammer several things happen. First, one end is struck by the hammer and the other end is driven into the rock, thus causing a bodily displacement of the entire material of the steel drill. The greatest stresses involved in this bodily displacement are located at the two ends of the steel and manifest themselves by the distortion of these parts. Second, after the blow has been delivered, the steel drill, due partly to its own resiliency and partly to the resiliency of the rock, experiences a vibratory motion as a whole, this motion is quite similar to the bouncing of a rubber ball thrown violently upon a smooth pavement. Third, the free vibration of the drill is determined only by its own natural period of vibration. This motion involves all the characteristics of any vibrating body emitting sound. Certain elements of the rod will experience alternations of condensation and rarefaction and, in these regions, the individual steel

Jan 1, 1922

By AIME

TURMOIL has been rampant in the lead producing industry during 1946. The chronic labor shortage was aggravated by various work stoppages in mines, smelters, and refineries, while shortage of materials was widespread. Price uncertainties helped to confuse the situation in many countries and particularly in the United States until the removal of price control in the latter part of the year. At the end of the first year of peace, lead, which had been comparatively plentiful during the war years, was a scarce and high-priced metal throughout the world. It is the hope of the industry that the law of supply and demand, if allowed to operate without interference, will bring about a satisfactory balance between production and consumption. Under these circumstances it is not surprising that there have been few important developments in the metallurgy of lead, though a number of items of general interest to the industry have been reported. An ore body which may prove to be of considerable importance has been discovered at Mpanda, Tanganyika. The scarcity of lead ore is illustrated by the announced reopening of the La Manche lead mine in Newfoundland, idle for 56 years. A new lead producer came into production when Rhodesia Broken Hill started up its new smelter. Lead concentrate of 75 per cent grade is smelted in Scotch hearths and the lead is refined to market grade by the Harris process without desilverizing. Production is about 1000 tons per month. One Australian lead producer, Mount Isa, has returned to lead production after having operated its lead plant for the production of copper during the war. The East Chicago plant of the International Smelting and Refining Co. has been sold to the Eagle-Picher Co.

Jan 1, 1947

By James Westfield

A brief résumé follows of recent activities of the Division of Coal-Mine Inspection that have had a favorable effect on health, safety, and the reduction of injuries at coal mines: 1. The Federal Mine Safety Code for Bituminous Coal and Lignite Mines of the United States was issued originally by the Director of the Bureau of Mines on July 24, 1946, after consulting with management and labor representatives of the coal-mining industry. The code has been used by Federal coal-mine inspectors while inspecting bituminous-coal and lignite mines as a basis for determining the existence of unhealthful and unsafe conditions and practices in these mines. A revised code was issued by the Secretary of the Interior on October 8, 1953, after further consultations with representatives of management and mine workers and was incorporated by reference in the 1952 and subsequent bituminous-coal wage agreements. The agreement of May 29, 1946, between the Secretary of the Interior, acting as Coal Mines Administrator under authority of Executive Order 9728, and the United Mine Workers of America, covering bituminous-coal and lignite mines in Government possession, charged Federal coal-mine inspectors with the responsibility of making periodic investigations of the mines and reporting to the Coal Mines Administrator any violations of the Federal Mine Safety Code. Federal coal-mine inspectors also had temporary authority to close mines found to be imminently dangerous, but such authority (under Executive Order 9728) was removed on June 30, 1947, when Government control of the mines was terminated.

Jan 1, 1958

By S. Balideh

A good understanding of the behavior of rock helps us to make more informed decisions regarding geo-structures. Engineers need accurate equations to calculate the strength and deformation of rock before and after failure. Previous studies explain the failure of rock to ultimate strength, and laboratory tests adequately determine the ultimate strength and deformation modulus of rock. However, there are few comprehensive equations to determine the post-failure strength and deformation of rock. Previous work shows that the post-failure behavior of rock depends on the behavior of the broken rock particles after failure. The following question is then posed: How can the post-failure behavior of rock be determined by the behavior of broken rock particles? In order to answer the question, this study pursues three objectives: (i) to explain the behavior of broken rock at low confining pressure; (ii) to estimate the behavior of broken rock via the extrapolation of scaled laboratory testing; and to suggest a procedure (iii) to outline the post-failure behavior of a rock mass at low confining pressure commensurate with the behavior of broken rock in a rock mass.

Aug 1, 2013

By G. Danko, C. Lu

"High temperature and humidity at the working negatively affect safety and health in deep and hot underground mines. It is necessary to predict during design the dynamic changes in temperature with heat and moisture emitted into the mine ventilation-thermal-humidity (VTH) system from various sources such as auto-compression, wall of strata, mining equipment and workers. Currently available mine ventilation and climate models are either furnished with a simplified, step-change-type (SCT) model for thermal solver (such as in Climsim, VnetPC, Minevent, MFire, etc), or with more advanced models to account for the “thermal history effect” (also known as thermal flywheel effect), such as in Ventsim and MULTIFLUX. The goal is to quantify the modelling error caused by the lack of variable thermal history component in the SCT model. Two models are compared: one with and one without the thermal history component in long, single airway examples with long-term climate simulations for 20 years assuming an input air temperature with daily variation. The examples illustrate the magnitude and the time-lag phase of the variation of the modelling errors with space, time and model conditions. Large errors are shown in the order of +14°C and –7°C errors, persistent for long time periods, up to 20 days in one example.INTRODUCTIONIt is important to predict the heat and humidity distributions during the design of hot and humid underground mines for the safety and health of the workers. The feasibility of extracting a rich deposit in great depth may depend on the extent of ventilation and mine climatization for maintaining an acceptable working environment. The cost of ventilation and cooling may be substantial, up to 40–50% of the total energy cost of mining (Clausen, 2017). The accuracy of model solution is important in view of the low profit margin in mine feasibility for deep and hot mines. Safety and health of the miners, the primary concerns, are therefore inherently connected to finding ever better solutions in simulation methods and ventilation control techniques."

Jan 1, 2019

By F. E. Diebold

The methodology for describing the geochemistry of elements in a coal seam have been developed. This has been applied to the Rosebud Coal Seam, which is an economically important member of the subbituminous coals of the Fort Union Formation in Eastern Montana. The method development has involved a detailed study of two popular techniques for determining the metal geochemistry of coal, namely, whole coal analyses and coal physical fractionation. The mathematically contrived element associations (whole coal analyses technique) and the element concentration trends in the float and sink fractions (physical fractionation technique) are considered to lead to only qualitative conclusions concerning the chemical associations of the elements in coals. Additionally, the processes taking place with the coal during low temperature ashing in an oxygen plasma are experimentally investigated and shown to be of sufficeint extent that the use of such low temperature ash for deciphering element geochemistry is questionable. The method developed in this study is a chemical fractionation that involves the sequential leaching of coal with water, 0.5 N HC1, 3 N HC1, 2 N HNO3, and 48% HF. These leach solutions are shown to selectively dissolve the predominate inorganic phases, sulfates, Ca and Mg carbonates, Fe sulfides and K alumino-silicates and quartz, respectively. These phases were identified with the use of XRD, SEM, EM and leaches (water and 0.3 N HC1) of whole coal and low temperature ash. The incorporation of the anion-exchange step in the leaching scheme was investigated and was observed to warrant further study of such intensity to be, at the time, unuseable. The use of this sequential leaching technique on several coal samples from the same seam generates element concentration trends that can be quantitatively interpreted with respect to the chemical associations of the minor and trace metals in the coal seam. The properties of the various seams of economic importance in the Fort Union Formation in Eastern Montana are compiled and presented. The subsequent conclusion is that there is not a large variation in the properties of these coal seams and that the variations within the Rosebud are within one order of magnitude. The chemical fractionation technique, investigated in this study, was applied to composite tipple samples of the Rosebud seam. Each composite sample represented 76,800 tons of coal. A minimum of 32% of the Ca and Mg are present as separate water soluble sulfates. An excess of the sulfate ion in the water extracts shows the predominating influence of the ion exchange capacity of the organic compounds in the coal. Based upon the CO content of the coal and the HC1 leachate data, 25 to 30% of the alkaline earth elements exist as separate carbonates and the remainder are associated with the organic compounds. The small fraction of the illite that dissolves in the HC1 and HNO3 leachates accounts for the K and Al. Slight dissolution of the pyrite in the HCl solvent occurs, the small amounts of Li and As do not relate to any known phase and Mn is present as a separate carbonate phase. Fe and a significant amount of the As exist in the pyrite that is dissolved in the HNO. Se is equally partitioned between the pyrite and the organic compound~. Most of the trace elements are found in the HF solutions. Li, V, and Cr were interpreted to be associated with the clay minerals (kaolinite and illite). Ni and Pb appear to be present as separate phases and 50% of the Hg is HF soluble but is not chemically related to any known inorganic phase.

Jan 1, 1983