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By G. M. Savov

Copper recovery via Solvent Extraction (SX) process is a well-known technique, which is practiced commercially for approximately 40 years. The main advantages of the SX process are: an absence of using high temperatures (not more than 50oC), complete recycling of barren solutions, very high selectivity at removal and purification of metals, metal conversion to a form, suitable for easy subsequent recovery. Despite the wide acceptance of Solvent Extraction, it does have some shortcomings, namely SX employs large quantities of volatile organic substances. This leads to huge plant ?footprint? of SX circuits. The SX is very sensitive to low temperatures and quantity of total suspended solids in feed solutions and this causes bad phase disengagement times and therefore poor process performance. And most important ? low grade solutions (with copper concentrations below 1 gram per litre) are very unattractive for treatment via Solvent Extraction process, because capital costs for SX plants are not a direct function of copper tenor in the feed. The combined process with Ion Exchange (IX) and Solvent Extraction ? further called IX/SX by IONTECH Engineering was developed. This combination eliminates SX negative characteristics shown above. The key findings of the IX/SX process are; (1) recovery of copper from pregnant leach solutions with metal concentrations, varying on a broad range; (2) can be operate effectively with very low-graded copper pregnant leach solutions; (3) the construction of large ponds for pre-filtration of the pregnant leach solutions is not necessary; (4) working with turbid solutions and solutions containing large quantities of suspended solids; (5) winter operation without troubles; (6) strongly reduces organic losses; (7) technological approach lead to plant sizes reducing. This paper reviews the main stages of the combined IX/SX process, the applications for metal recovery and introduces projects where the process is applied. Key findings of the process are also presented. A comprehensive technical comparison between processes has been carried out. This paper also evaluates the advantages of using combined IX/SX technology as a purification and separation step in copper production process, with the aim of further increasing the overall copper recovery and to ensure that a suitable copper concentration in the advanced electrolyte is achieved. The implementation of a Ion Exchange (IX) process in the classic Solvent Extraction-Electrowinning process(SX/EW) is found to be beneficial for processing of pregnant leach solutions both from spent and new copper heaps and dumps, acid mine drainage and other industrial streams without any preconditioning as well as in terms of achieving improved recoveries and copper cathode quality.

Sep 1, 2012

By Olexandr Gydin

The evolution of grain and dislocation structures during cold deformation of the new steel LH800 of Salzgitter AG is investigated in the frame of this work. The main feature of this material is its ability to air-harden by carbon content of about 0.1%. The initial ferrite structure of the metal provides high plasticity at cold deformation and subsequent heat treatment increases tensile strength approximately two times. Described are results of in-situ tensile tests in the SEM. SEM and TEM analysis of grain and dislocation structures evolution in samples, which have been uniaxially deformed to certain strains, are carried out. After statistical evaluation of results the grain elongation against strain is determined. A microstructure of a deep drawn cup is analyzed by means of SEM. A quantitative evaluation of grain elongation on the different cup zones and comparison of these data with prediction results based on tensile tests are carried out.

Jan 1, 2009

By J. Drzymala

Ores and raw materials are subjected to mineral processing operations to increase the content of their useful components. Upgrading of these materials can proceed with different selectivity and therefore, there is a need to know and monitor the separation results of the process. The separation results can be evaluated using tables and graphs called upgrading curves. The course of lines in the upgrading curves is usually complex and depends on the graph type and process parameters. The Halbich grade vs. recovery plot is frequently used because is practical and it indicates several characteristic features of separation results. Separations by means of flotation of several different shale, dolomite and sandstone copper ores were performed along with determination of their mineral composition, copper content, liberation degree, and the maximum theoretical copper content in the first concentrate. These data, plotted as the Halbich upgrading curves, allowed to find other characteristic points such as practical maximum copper content in the first concentrate, maximum curvature coexisting with the liberation degree, maximum recovery of ore valuable components, and the slope the recovery-grade line at high recoveries as a measure of liberation. Correlations between theoretical and practical maximum copper contents in the first concentrate as well liberation degree and maximum curvature were also presented. They show that the ore type significantly influences the shape of the Halbich curve and its characteristic points.

Sep 1, 2012

By Q Liu

Open stoping is one of the widely adopted methods in underground bulk mining. In this method, fanned or parallel holes are often drilled from a top sill down to a sublevel in the ore zone and blasted ring by ring into a stope for excavation. A mass stope blast may involve blasting rock from multi-level drift rounds and displacing the muck to specific locations in order to allow safe and easy access for ore removal. This paper presents a strategic mass stope blast that took place at a large lead and zinc underground mine in eastern Canada. The blast consisted of more than 800 holes drilled in six blocks from three different sublevels. The challenge lay in the control of ground vibration and muck movement using precise timing to complete the blasting within 6.5 seconds. During this time span, sufficient voids were created in each level to allow the muck to move from the upper to the lower levels in sequential order across the six mining blocks without bridging. This paper describes stope blast simulations using a discrete element computer code for modeling blast-induced rock displacement as well as the application of electronic detonators. These detonators provided the means to accomplish the desired firing sequence including a drop raise blast at the start of the mass blast. The modelling concept is also described in the paper.

Jan 1, 2005

By Hervé Thomasson

Siemens VAI has made an important Research & Development effort since 10 years on laser welder field. The last step of this program was in 2010, the evolution of its laser welder range by implementing the solid state technology with laser cutting and welding. Since this step, 8 welders were produced by Siemens VAI. Now after more than 1 year of industrial feedback, the results are showing a high level of performances on very demanding processing lines for a large range of products from Silicon steel to High Strength Steel with DP and TRIP grades. This laser welder concept using laser cutting and welding through solid state laser source is also proposed by Siemens VAI for pickling lines and tandem mills with significant advantages compared to standard solution.

Jul 30, 2018

By Nabil F. Ismael

Load tests were carried out to examine the ultimate bearing capacity of short, large diameter bored piles in connection with the construction of a multistory building on the Arabian Gulf in Kuwait. Testing included 0.45 m, 1.0 m, and 1.2 m piles installed through loose sand into a bearing stratum consisting of very dense cemented sands. All tests were carried out to failure. The base resistance and shaft friction were calculated using the Meyerhof method for a layered soil profile. The method employs the standard penetration test N-values. The results indicate that the piles are end bearing piles with a great portion of the pile capacity due to base resistance. The mobilized skin friction is small. The calculated pile capacities were very close to the measured values with the maximum difference not exceeding 10%.

By S Azam

Coal is a vital energy source and source of carbon for metallurgical applications, contributing significantly to the world economy. Coal mining and processing involve multiple processes that generate Respirable Coal Mine Dust (RCMD), one of the primary sources of health hazards for coal workers. Since 2000, the rate of Coal Workers’ Pneumoconiosis (CWP) has continually increased in the U.S, with severity of the cases also worsening. Increasing evidence shows that exposure to RCMD in coal workers is a high-risk factor for lung cancer, which causes more deaths than the following three major cancers combined in the US Recent observations show an increased incidenceof CWP or other lung diseases, particularly among young miners in the Appalachian basin. The CWP prevalence in Appalachia is four times higher than the national average. Although various regulations are in place, the resurgence of such disease among coalminers demands additional efforts to better understand all the possible facets of coal dust toxicity, taking insights from current interdisciplinaryresearch efforts. One such important field is the interaction of coal dust with moisture in underground mines. Although moisture is prevalent and dynamic in an underground mining environment, it has never been evaluated for its impact on modifying the toxicity of coal dust and transport or flow behaviour. However, research conducted in atmospheric sciences in the past decade makes it clear that moisture in the atmosphere can significantly alter the behaviour of mineral dust. This paper is a part of research aimed at understanding how moisture interacts and alters the characteristics of coal dust. Such insight is crucial in understanding the potential toxicity of coal dust and developing mitigation technologies.

Oct 12, 2022

By N. A. Gokcen, S. Fujishiro

The dissociation pressure of Cr3C2 has been measured in the range of 1908" to 2237°K by means of graphite Knudsen effusion cells. It has been found that Cr3C2 vaporizes according to the following reaction: 1/3 Cr3C2 (s or 1) = 2/3 C (graph.) + Cr (g). The equilibrizcm pressure, P, of Cr (g) is found to be log Ps=- - (21,194/T) + 6.525 over solid Cr3C2 and estimated as log P, = - (19,535/T) + 5.76 over liquid Cr3C2. CARBIDES of chromium are of great importance in alloy steels and cemented carbides. The published data on their therm odynamic properties at high temperatures, however, are meager. The heat capacity and change in entropy of Cr3C2 were determined calorimetrically by Kelley and Moore1 in the range of approximately 50" to 300°K, and by Oriani and Murphy2 from 297" to 1188°K. The standard entropy of Cr3C2at 298.15°K, obtained by Kelley.7 was later confirmed by DeSorbo.4 Equilibrium in the reaction was investigated by Boericke.5 A recent tabular summary

Jan 1, 1962

By F. H. Nehl

The U.S. Bureau of Mines investigated the selective electrowinning of Ag and Au from cyanide solutions contaminated with Cu with the goal of decreasing the amount of Cu codeposited. Decreasing Cu codeposited will reduce refinery costs. Direct current was applied to the cell in pulsed and square wave voltages at 0.070 A?h per 150 mL of solution. Times tested for each cycle ranged from 1 to 10,000 ms. Graphite, lead, and stainless steel were evaluated as electrode materials. Square wave electrowinning at 70° C gave the best separation of Ag and Au from Cu. Applying 2.5 V during the duty cycle, 0.0 V the rest of the period, a duty cycle of 10 to 30 pct, and a period of 100 to 1,000 ms gave the following results: Ag concentrations decreased from 34 to 0.1µg/mL, Au concentrations decreased from 54 to 0.2 µg/mL, and Cu concentrations remained almost constant at 560 µg/mL.

Jan 1, 2010

By Ralph H. Whaite

The Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region is described. A catalog of the maps that have been microfilmed in the Eastern Middle anthracite field--the first area to be covered in the program--is presented. Additional catalogs will be published as significant mining areas are completed.

Jan 1, 1965

By Ralph H. Whaite

The Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region is described. A catalog of the maps that have been microfilmed in the Eastern Middle anthracite field--the first area to be covered in the program--is presented. Additional catalogs will be published as significant mining areas are completed.

Jan 1, 1965

By R. Pot

"IntroductionTHE PURPOSE of this paper is to discuss briefly the main logging and testing devices presently at our disposal, to point out some of their limitations, and to suggest possible improvements of the techniques.Some of the more important devices .are those that are used in:(1) Coring(2) Formation testing(3) Electric well logging(4) Radioactive well logging(5) Measuring of bottom hole pressures(6) Sampling of reservoir fluidsThe first four of these procedures are concerned with the well while it is in the process of drilling. The last two are carried out as soon as possible after a well has been brought into production and .at intervals during its life. My remarks will be concerned mostly with certain aspects of formation testing. The reservoir engineer is dependent on the information derived from these operations in order to obtain a clear picture of the conditions in a reservoir and to enable him to assess and forecast its future behaviour.Since any calculation is no better than the data on which it is based, not enough emphasis can be placed on the necessity for the testing and logging equipment to be of the highest quality and for the analysis of the results obtained to be thorough."

Jan 1, 1952

By M. C. Smith, W. V. Green, D. M. Olsen

The creep-rupture behavior of commercial powder-metallurgy molybdenum rod is reported in the temperature range 1600" to 250O°C, at stresses up to 9000 psi and times up to 1 month. The effects of temperature, stress, and grain growth are discussed. Rupture time is fitted to the Larson-Miller parameter and compared to lower-temperature and higher-stress results reported by pugh.1 BECAUSE of its high melting point, molybdenum should retain useful strength to relatively high temperatures. Combined with its ready availability in the United States, this makes it attractive for many applications in missiles, rockets, and so forth—wherever its susceptibility to oxidation can be tolerated or overcome. The mechanical properties of molybdenum rod in the temperature range —200" to 1540°C have been reported by pugh,' Bechtold,' Parke,3 and Carriker and Guard.4 Madden and chen5 have measured the tensile properties of molybdenum single crystals in vacuum up to about 2500°C. As one further step in evaluating its mechanical usefulness, the constant-load creep-rupture properties of commercial powder-metallurgy molybdenum rod have been investigated in the range 1600" to 2500°C. MATERIAL TESTED Creep specimens were machined from 1/2-in. round commercial molybdenum rod, manufactured from powder by pressing, sintering, and swaging. Spectrochemical analysis of the rod showed "traces" (less than 0.01 pct) of silicon, aluminum, chromium, iron, and zirconium, and "faint traces" (less than 0.001 pct) of manganese, magnesium, cobalt, and nickel. Carbon content was 130 to 200 ppm, nitrogen was 110 to 180 ppm, and oxygen 30 to 35 ppm. A typical microstructure of the as-received rod is shown in Fig. 1. Room temperature tensile properties for five specimens strained at about 0.015 in. per in. per min are shown in Table I. CREEP SPECIMENS USED The specimens used for creep-rupture testing are illustrated in Fig. 2. The 1/4-in.-diam gage section was 3/4 in. long, and terminated at shoulders 5 mils high. These shoulders served as fiducial marks for optical strain measurements. Surface finish on the gage section was 16pin. r.m.s. One specimen, for a "long-time" test described below, was modified by dividing the 3/4-in. gage length into three 1/4-in. long sections with individual diameters of 0.250, 0.230, and 0.210 in., each terminating in a pair of fiducial shoulders. TESTING PROCEDURE The constant-load creep-testing machine used has been described by Smith, Olson, and Brown.6 In it the specimen is held vertically on the axis of a cylindrical tantalum or tungsten heater tube by threaded molybdenum or tungsten grips. Both specimen and grips are heated by radiation from the heater-tube, which is heated by its own electrical resistance. The bottom specimen grip is held at its lower end by a clevis pin. The testing load is applied to the specimen through the upper grip by means of hanging weights, a constant force-multiplication lever system, and a pull rod sealed to the chamber lid by a bellows. The incandescent specimen is viewed by an external optical system through slots in the heater-tube and radiation shielding, and an enlarged image of it is projected on a ground-glass screen. Gage-length measurements are made on this image with a pair of cathetometers. Thorium oxide coatings were applied to the threaded ends of most specimens, to prevent diffusion-welding of specimens to grips during testing. Without such a coating welding usually occurred, and grips were often broken by subsequent efforts to remove the tested specimens.

Jan 1, 1960

By Zhihe Dou

SHS reaction system has advantages of heat flux density, energy concentration and reaction speed, with sufficient conditions in thermodynamic and kinetic reaction. This paper invented a new technology of SHS metallurgy of preparing melting point alloys and refractory compounds using its own chemical energy. SHS-leaching process for preparing nano boron powder or ultrafine boride powder and SHS-casting process for preparing titanium-based alloy and immiscible alloy were studied. The results indicate that highly active boron powder of greater than purity of 93%, particle size less than 100nm and purity greater than 98.5%, particle size less than 400nm REB6 can be prepared. With SHS-Casting process, the oxygen content of less than 0.59% ferrotitanium, oxygen content of less than 0.5% titanium alloy and ?40-80*100mm large size of CuCr, Cu-Fe alloy ingots were prepared. This technology has greatly enhanced the thermal reduction method added values of preparing metallurgical products and its competitiveness.

Jan 1, 2014

By W. J. Crawford, P. M. Gruzensky

"Several experiments have been carried out in efforts to evaluate qualitatively a variety of electrolytes for refining bismuth. Most extensive work was done with the basic tartrate, hydrochloric acid, and hydrofluosilicic acid electrolytes. Deposits that are smooth and adherent can be obtained from these three electrolytes if low cathode current densities are employed. All three electrolytes were effective in purifying crude bismuth considerably, with additional purification indicated in each instance by a reelectrolysis step.With the basic tartrate electrolyte best results were obtained when the electrolyte was at 40° C. and contained at least 100 grams of bismuth per liter. An apparent disadvantage was depletion of bismuth from this electrolyte, causing the deposits to become spongy and nonadherent.The hydrochloric acid electrolyte had the greatest tendency to yield rough, dendritic deposits. Best deposits were obtained at cathode-current densities below 2 amperes per square decimeter. A small amount of glycerin helped to produce a smoother deposit, and adding sulfuric acid or methyl sulfuric acid retarded the deposition of impurities. Very good results were obtained in electrowinning bismuth from a bismuth trichloride-hydrochloric acid electrolyte.Smooth and adherent deposits were obtained from a hydrofluosilicic acid electrolyte, with very good refining as regards lead and silver impurities; however, higher reagent costs and slow decomposition of the electrolyte have discouraged its use.INTRODUCTIONMethods of recovering bismuth from ores and byproducts were underdeveloped for many years because of the limited uses for bismuth, the pharmaceutical industry being the chief consumer. In the past decade or so additional uses for bismuth, particularly in the metallurgical field, have brought about increased demand for the metal with the result that bismuth is being recovered from byproducts that were once discarded. In addition to such uses as low-melting alloys, solders, bearings, die setting, etc., some interest has been indicated in bismuth as a possible coolant for nuclear reactors. The advent of ductile bismuth and bismuth-alloy thermocouple wire has contributed greatly to temperature measurement, particularly in the below-zero range."

Jan 1, 1956

By W. A. Wall, R. L. Kidd

IN present-day flotation practice, grinding of the flotation feed is carried to extremely fine sizes, 70 to 80 per cent minus 200 mesh being customary. The greatest flotation losses occur in the coarsest and finest sizes, but the losses in the very fine sizes are, of course, much the more important because of the large proportion of fines in the feed. These losses are particularly high in zinc ores so a study of the effect of size on the flotation of sphalerite has been made. The mineral used in these experi¬ments was a pure sphalerite, especially free from copper, from the Joplin district in Missouri. The sizes coarser than 200 mesh were separated by screening, the sized mineral then being deslimed on a Wilfley table. The sizes finer than 200 mesh were obtained by water elutriation as described by H. R. Bradford (M. S. Thesis, University of Utah, 1932) ; particles finer than 6.5 microns could not be obtained with the apparatus used.

Jan 1, 1933

By E. D. Gálvez, L. A. Cisternas, A. López-Valdivieso, F. Lucay

"The floatability of molybdenite fines in saline solutions was investigated through microflotation studies using a modified Hallimond tube. In addition, the effect of pH and gypsum precipitation from calcium ions (Ca2+) and sulfate ions (SO4 2-) ions in saline water on the recovery of the molybdenite was analyzed. It was found that the floatability of molybdenite fines significantly increased with the ionic strength of the saline solutions and is independent of pH above 0.5 mol/L ionic strength. The high floatability of molybdenite in saline solutions is explained as being due to the low electrostatic repulsion between bubbles and the edges of molybdenite particles, which is exceeded by interactions due to van der Waals and hydrophobic forces. The precipitation of Ca2+ and SO4 2- ions as gypsum had a detrimental effect on the natural floatability of molybdenite because of gypsum crystal attachment on the faces of the molybdenite particles. This precipitation phenomenon may be initiated in copper–molybdenite flotation circuits that use recycled saline water, like seawater containing Ca2+ and SO4 2- ions.IntroductionWater availability is a significant factor in mining projects. Water, particularly fresh water from rivers and underground water, is becoming a scarce resource for mining operations and new projects. Under these circumstances, the use of water with high concentration of salts in flotation plants is becoming increasingly important (Cisternas and Moreno, 2014). The use of seawater has been studied as a sustainable solution for many mining companies in dry areas located near the sea. Notably, using seawater in mining operations is how mining companies in Chile have coped with the problem of water resources (Cisternas and Gálvez, 2014). In 1930, small plants in Chile used seawater to float chalcopyrite from high-copper-grade ores. In 1975, the results of tests in pilot plants for the flotation of copper minerals with seawater were reported. It was found that froth formation in seawater at pH 9.5 was suitable to make the rougher circuit work properly, even without frothers. The Cenizas mining group successfully floated chalcocite, bornite and chalcopyrite in the Las Luces plant in Taltal in Chile using seawater (Moreno et al., 2011). Minera Centinela (Antofagasta Minerals S.A. Chile) is currently processing porphyry copper ores using a seawater mixture consisting of 20 percent fresh seawater and 80 percent recycled water. Lower consumption of flotation reagents was reported in both seawater and salt water. In addition, studies performed with synthetic seawater showed that certain frothers increase the froth volume, whereas others decrease it. Additionally, the froth produced with seawater carries a high amount of gangue, and low-quality concentrates are obtained, requiring more cleaning stages."

Jan 1, 2015

By I. Protkova

Versa Power Systems solid oxide fuel cell (SOFC) stacks operate at intermediate temperatures 700 ? 800 °C allowing the use of metallic interconnects. Thermal expansion good matching with other stack components and cost restriction led to selecting ferritic stainless steels as interconnect material. Analytical tools and techniques were developed to understand the ferritic stainless steel behavior at high temperature while exposed to dual environment. Analytical tools such as X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) have provided valuable information towards describing interconnect degradation in a variety of testing conditions. Several examples are presented to demonstrate interconnect oxidation and its relation with SOFC testing results.

Jan 1, 2005

By Raj K. Rajamani, Samira Rashidi

High pressure grinding rolls have been utilized in various operations during the past four decades, simply due to their inherent mode of breakage that offers metallurgical benefits with pronounced energy reduction. For every new application, wear and in particular roll surface wear protection has always been the focal point of HPGR trade-off studies. Wear remains an important issue throughout a mine’s life given inevitable variations in the ore deposits properties. Hence, the capability of continuous scanning of rolls provides ample information about any deviations in the design values as well as their effect on the wear pattern. In part I of this manuscript, we present the feasibility of in-line scanning of roll surface in a 200 × 100 mm lab-scale HPGR. First, the in-line scanning was developed in a mock-up roll and then the scanner was moved to the laboratory-scale HPGR. We present the choice of scanners and the methods adopted to achieve high-level accuracy of determining wear. Even though we planned for micron-level precision of scanning, the inherent variability in shaft rotation was higher than the variability in the roll diameter due to wear. The hundred-kilogram mass processed in the HPGR was not sufficient to create enough wear that is discernible to the in-line scanner. Yet, the method tested is a promising avenue for inline scanning of HPGR rolls.

By J. Lu, D. G. Ivey, H. Henein

Microalloyed steels are widely used in the oil and gas industry. They are a class of high strength, low carbon steels containing small additions of niobium (Nb), titanium (Ti), molybdenum (Mo) and/or vanadium (V). These steels have good strength, toughness and excellent weldability, which are attributed in part to the presence of nano-sized carbides, nitrides and carbonitrides. In the pursuit of developing higher strength microalloyed steels, it is of great interest to quantify the size, distribution, volume fraction and chemical speciation of these precipitates. However, characterization techniques suitable for quantifying fine precipitates are limited. Possible characterization techniques include SEM, TEM and matrix dissolution. A comparison is presented of the various techniques.

Jan 1, 2005