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By Isabel F. Barton, MarkD. Barton, Christian A. Rathkopf

Molybdenite is the world’s principal source of rhenium (Re), a critical element in multiple high-tech applications. However, the Re contents in molybdenite vary by orders of magnitude on scales ranging from single grains to whole deposits. In order to better understand the systematics of this variation and what geochemical factors control molybdenite Re concentration, and hence overall Re resources, we examine global patterns in molybdenite Re contents through a compilation of > 3000 measurements of Re in molybdenite from > 700 mainly ore-bearing moderate- to high-temperature hydrothermal systems of different types. Our results are similar to but expand on those of earlier studies. Rhenium concentration in molybdenite has a lognormal distribution and varies systematically with type of geologic system, intrusive lithology, and Mo grade. The lowest-Re molybdenite occurs in greisens (geometric mean 1 ppm ± a multiplicative standard deviation of 9), quartz vein-hosted W-Sn deposits (2 ± 5 ppm), unmineralized granites and granodiorites (12 ± 8 ppm), intrusion-related deposits (24 ± 8 ppm), and porphyry W-Sn deposits (16 ± 11 ppm). Rhenium is most enriched in molybdenites from volcanic sublimates (23,800 ± 5 ppm), with skarn Fe and Au (560 ± 5 ppm and 540 ± 3 ppm respectively) and porphyry Cu and Cu-Au deposits next (470 ± 4 and 430 ± 7 ppm respectively). Among porphyries, skarns, and quartz vein-hosted deposits, Re is most highly concentrated in molybdenites from Cu and Au systems and its concentration decreases systematically through Cu-Mo, Mo, Sn, and W deposits. In nearly all cases, molybdenites from systems associated with intermediate igneous rocks contain more Re than molybdenites from systems of the same type with more felsic rock associations. The disparity between Re contents of molybdenite in felsic and intermediate systems is largest for porphyries, quartz vein-hosted, and skarn deposits and is near zero for subeconomic or barren granite and granodiorite Mo systems; felsic intrusion-related deposits have slightly higher molybdenite Re than their equivalents associated with intermediate intrusions. In most systems, molybdenite Re content does not correlate with metal grade, but may have an inverse correlation with Au grade in intrusion-related deposits (based on a small number of data points) and does exhibit a strong inverse correlation with deposit Mo grade. Dilution of Re through larger amounts (higher deposit grades) of molybdenite explains about 40% of this correlation, but the relative enrichment of Re in molybdenite from low-Mo deposits must also reflect some selective enrichment of Re/Mo in porphyry Cu systems compared to porphyry Mo systems. We found no evidence for secular increase or other systematic temporal variation in molybdenite Re content. The data regarding the use of molybdenite Re content as a proxy for mantle influence are ambiguous. Nearly all observed empirical correlations can be traced back to differences in redox state and sulfide concentration, the two geochemical factors identified here and by previous experimental work as the controlling influences on Re mobility under hydrothermal conditions. Hydrothermal systems with reducing conditions (W- and Sn-rich) tend to have low molybdenite Re even though compiled whole-rock data indicate that their source rocks have as much or more Re as those of more oxidized systems (e.g., Cu-rich). Vapor-phase exsolution, crustal assimilation, and mixing with external fluids may all enrich molybdenite Re concentrations in individual deposits and deposit types, but their extent and importance in overall hydrothermal concentration of Re is uncertain. Thus, it appears that the available molybdenite Re resource in an ore deposit largely depends on how the deposit’s redox and sulfidation conditions have varied over time and space during the timespan of hydrothermal activity. Oxidized, high-sulfide conditions tend to concentrate Re in molybdenite, whereas reducing conditions tend to leave Re dispersed at low concentrations in the bulk rock.

"Large scale open pit mining and quarrying operations dictate safe and reliable pit wall stability. The current approach of employing the particle velocity-scaled charge distance approach to estimate and minimize damage to residential structures is considered inadequate to protect rock slopes. This study utilizes close-in blasting vibration data as input to an advanced 2D numerical code to study its applicability to serve as a predictive tool in terms of blast-induced rock slope failure. Two tri-axial accelerometer stations, consisting of high-frequency and high-amplitude (20 kHz, 100g) sensors, located within ~100m of the blast, but at two different bench levels, were used to monitor a production blasting in a quarry. The production blast consisted of double-decked explosive loads in 155 mm (6 in) diameter holes, with an inter-deck delay of 42 ms, and each deck consisting of 130 kg (285 lb) of emulsionexplosive. The blasting vibration data obtained at the two bench levels were critically analyzed, and thevibration results served as input to the numerical model consisting of a single rock block with a 45 degree persistent joint plane but with specified strength properties, significantly different from that of the intact rock. The model was able to characterise progressive accumulation of damage in the form of micro-cracks along the joint surface as a function of the vibration load from successive explosive decks. The results showed that such a numerical model can serve as a very good diagnostic and predictive tool, when backed up by careful vibration monitoring and further supported by detailed slope monitoring."

Jan 1, 2017

By B Mohanty, A Siamaki, K Esmaeili

Large scale open pit mining and quarrying operations dictate safe and reliable pit wall stability. The current approach of employing the particle velocity-scaled charge distance approach to estimate and minimize damage to residential structures is considered inadequate to protect rock slopes. This study utilizes close-in blasting vibration data as input to an advanced 2D numerical code to study its applicability to serve as a predictive tool in terms of blast-induced rock slope failure. Two tri-axial accelerometer stations, consisting of high-frequency and high-amplitude (20 kHz, 100g) sensors, located within ~100m of the blast, but at two different bench levels, were used to monitor production blasts in a limestone quarry. The production blast consisted of double-decked explosive loads in 125 mm (5 in) diameter holes, with an inter-deck delay of 42 ms, and each deck consisting of 130 kg (285 lb) of emulsion explosive. The blasting vibration data obtained at the two bench levels were critically analyzed, and the vibration results served as input to the numerical model consisting of a single rock block with a 45 degree persistent joint plane but with specified strength properties, significantly different from that of the intact rock. The model was able to characterise progressive accumulation of damage in the form of microcracks along the joint surface as a function of the relatively low vibration load from successive explosive decks. The results showed that such a numerical model can serve as a very good diagnostic and predictive tool, when backed up by careful vibration monitoring and further supported by detailed slope monitoring.

Jan 1, 2017

The reactivity of clay minerals and variety of these reactions are greater than any other known colloidal material. While it is acknowledged that clay minerals can cause problems in mineral flotation, the literature contains conflicting evidence, particularly with respect to the effect of clays on froth stability. It is well known that achieving and maintaining optimum froth stability is an influential factor in determining froth flotation performance. However, the presence of clay minerals in the ore is a major challenge to obtaining a stable froth. In fact, clay minerals could reduce froth flotation performance by both decreasing and increasing froth stability. The mechanism by which clay minerals affect froth stability is not fully understood and needs to be investigated further. In order to improve flotation performance, reliable knowledge of the effect of clay minerals on froth stability is essential which is discussed in this paper. Keywords: froth flotation, froth stability, clay, clay minerals

Sep 1, 2012

By Y. M. Fu

In order to evaluate the flotation process, the process flow sheet was investigated. The process mineralogy of main products was studied. Through chemical mineralogical and screening analysis as well as surveying using a microscope and scanning electro-microscope, the oxidation degree and mineral composition of main-products the liberation of main minerals, the occurrence of elements such as Pb, Zn were revealed. It is pointed that to determine the flotation process, the type of prod-ucts optimum grind of original ore and middling was provided on the basis of liberation of main minerals is reliable. As correct finer ground original ore, first high-grade lead-concentrates and zinc-concentrates fast was floated from a great part of free of the galena and sphalerite of liberated. Then for finely re-ground middling of locked mineral grains of difficult liberation, mixing lead-zinc-concentrates second was floated. The four products was best in contact with characteristic of ore of Fan Kou. Therefore be obtained certain to successful economic effect.

Jan 1, 2014

By Ibezim J. Anazia

Electrothermal production of elemental phosphorous (P4) generates substantial amounts of highly toxic phossy water and sludges. Because of their high phosphorous content and lack of reliable processing technology, large tonnages of these hazardous wastes have accumulated from current and past operations. To date, the sludges are stored in ponds or above ground in special containment vessels at various locations around the country. Two samples of electric furnace phosphorous sludge obtained from the Tennessee Valley Authority (TVA) in Muscle Shoals, Alabama and FMC Corporation in Pocatello, Idaho were investigated using physical separation techniques to recover the elemental phosphorous in the sludge and to render the residual material non-hazardous. The techniques tested include sizing, froth flotation and dispersed air oxidation. Flotation and sizing produced concentrates containing 69 -90% P4 with a recovery in the range of 60 -87%. Dispersed air oxidation of the fines and tailing products was effective in removal of an additional 10 -15% of the P4 in the sludge.

Jan 1, 1991

By K. C. Liddell

"Cu/Ni multilayers exhibiting giant magnetoresistance were deposited from a single electrolyte under stepped potentiostatic control. To enable transport measurements to be made without remounting the multilayer film, we developed a novel method that involved plating on a thin metallic basal layer atop a rigid non-conducting Si substrate. Rotating ring-disk electrode techniques were used to monitor the composition and thickness of individual plated layers. Transmission electron microscopy confirmed that the interfaces between adjacent layers were sharp and that the structure of the layers was uniform throughout the film. Atomic force microscopy images indicated that the film's surface was smooth and free of defects.ELECTRODEPOSITION OF THIN MULTILAYER MAGNETIC MATERIALSI. IntroductionElectrodeposition of compositionally modulated films will in all likelihood continue to be used to produce the read heads for stored magnetic data. However, the next generation of head materials will require both improved sensitivity and reduced film thickness. Certain multi layers consisting of thin alternating ferromagnetic and nonmagnetic layers exhibit giant magneto resistance and consequently are promising candidates for read head applications. We have successfully made multilayer films with giant magnetoresistance that have total thicknesses as low as 25 nm, approximately 120 times thinner than the thinnest similar films reported in the literature. This paper describes early results from our work on electrodeposition and characterization of Cu/Ni multilayers, a model system with enhanced magnetic and mechanical properties, including the GMR effect. The structure and composition of the multilayers were determined using TEM, AFM, and electrochemical methods, and their magnetoresistance was measured by the standard four-probe technique. A novel method developed in this work enabled the transport properties of the ultrathin films to be measured reliably without the need to dissolve the cathode or handle the films. To provide a context for these results, short accounts of other work on giant magnetoresistance and multilayer electrodeposition are also included."

Jan 1, 1997

By D Mather, H R. Asche

"In the civil tunnelling field, the use of tunnel boring machines (TBM) has now overtaken the use of conventional excavation methods (drill and blast / roadheader). This is due to a number of reasons, including the increasing availability and reliability of TBMs, the ability to deal with a wider range of face conditions, and the reduced excavation cost that TBMs can bring.Mining companies have spearheaded the advances in shaft boring by mechanised means, both in blind and raise boring. However, mining companies have been slower to adopt mechanised tunnelling.When contrasted with a conventional mining contract, there are good reasons why TBMs in mining applications are relatively rare. A conventional decline contract may have very little geotechnical information. The decline alignment can be subject to change as the tunnelling progresses. The infrastructure requirements are less for a conventional decline, and the sunk cost prior to excavation commencing is lower. Contract documents can be very simple.The history of TBM use in mining is reviewed and lessons are described. From the case histories and lessons learnt, the paper identifies ways that mining companies can maximise the potential benefit of TBM technology.We believe that despite the additional requirements for TBM declines, the cost and time advantage to mining companies is very attractive. The challenge is to recognise and to meet the requirements for success in a TBM drive to achieve the advantages of: faster advance rates reduced rock damage/overbreak reduced support requirements uniform muck characteristics greater personnel safety.From the case histories and lessons learnt, the paper identifies ways that mining companies can maximise the potential benefit of TBM technology.CITATION:Asche, H R and Mather, D, 2014. Use of ?tunnel boring machines in the mine environment, in Proceedings 15th Australasian Tunnelling Conference 2014, pp 655–662 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 17, 2014

By M Jacobs

This abstract discusses a heap leach copper mine that was failing to perform and as a result was not meeting targeted production. The mine had numerous technical challenges including: high water inflows, low levels of geotechnical monitoring, performance issues with mining, resource model and grade control reconciliation issues, and unexplained low levels of performance from the heap leaching operations. A team from various organisations with specialist skill sets including: a forensic accountant, the owner’s representative and a mining engineer, was arranged to visit the site. The task was to investigate the situation and determine what could be done to turn the performance of the mine around. After an initial assessment in late 2018, efforts were directed to better understanding the operations and improving the performance of the site through preventative management. A key part included the creation of production forecasts that could be achieved that would help restore confidence in the operations. Uncertainty in the mine achieving production forecasts and the performance of the heap leaching operations were contributing to the decline of the operations. Investigations uncovered the fact that while the resource model could reliably predict total copper, a lack of sequential leach data meant the accurate prediction of soluble and insoluble copper species, both important for heap leaching, was difficult to do with any degree of certainty. The crushing and mining contractors also appeared to have suffered somewhat from a lack of management by the owner’s team and performance had affected the production of copper. Collaboration and management were used by the team to understand and stabilise the operations. Ongoing collaborative efforts by the management team, site personnel and contractors resulted in a positive outcome for the owners and their mine – and could at yours.

Jun 22, 2022

By C. H. Schack

Although viscosity is known to be important in processing and handling finely ground urea, its effect has never been fully quantified. This report describes the methods used and the results obtained in the initial phases of a broad investigation of the influence of viscosity of water suspensions of minerals in flotation, thickening, filtering, and other mineral-dressing unit operations. Several types of vis-cosimeters were tested before reliable and reproducible results could be obtained on mineral suspensions. After the viscosimeter used in the research was calibrated and standardized, tests were made on six pure minerals to study the relationship of pulp density, particle size, crystallinity, and cleavage on viscosity. An orifice-type viscosimeter equipped with a mechanical stirrer gave as good results as other types and was more flexible, faster, and simpler to operate. The orifice-type viscosimeter, when calibrated and standardized with glycerin and water mixtures, proved satisfactory over a wide range of viscosities. The accuracy and reproducibility were reasonably constant between 1 centipoise and 200 centipoises, the anticipated range in common mineral-dressing unit operations.

Jan 1, 1957

By Q Qu

Reliable prediction of longwall gas emission sources and rate plays a critical role in mine ventilation and methane drainage capacity planning. Over the years, Australian longwall mines have been using the historic Winter method and the Flugge method in modelling specific gas emissions (SGE). The predicted results often experience high discrepancies from the operational reality. To improve gas emission prediction, post-mining gas contents were measured in several mines in Qld and NSW by safely drilling core holes into the longwall goaf. The results revealed many new insights into gas emission characteristics from different coal seams and the drawbacks of the European methods in their use in high-production gassy Australian longwall mines. Based on measurement data, a new, time-dependent gas emission prediction model has been developed. Considering several factors such as caving, desorption and production rate, the new model can predict more accurate and meaningful gas emissions to meet today’s needs in mine gas emission management. A case study is provided to demonstrate the application of the new SGE model.

Oct 12, 2022

By Pigdon SP, Anderson RM

The production of stabilised backfill at mine sites commonly uses Portland cement as the binder. Calcined gypsum has cementing properties and is cheaper to produce than cement. This paper discusses the strength of fills stabilised with calcined gypsum. Laboratory tests were carried out on specimens prepared from tailings obtained from four different sites to allow for the wide variety of tailings found in practice. The results show that the gypsum-based fills can achieve a strength of I MPa using around two and a half to four times the corresponding amount of cement.

Jan 1, 1998

By J. Xie

In underground coal mining, the potential for an outburst of coal and gas is considered to be one of the major hazards. As such, considerable emphasis is given to understanding and preventing such events. A number of indices are used in the prediction of the outburst in a coal mine. The main indices include initial gas desorption rate, gas pressure, gas content, coal strength, gas flowrate from a borehole drilled in a coal seam, and combinations of the above. Some of these indices are considered to be inadequate, inappropriate or impractical for some coal seam conditions, such as those with soft and friable coal. The Huainan Mining Group (Huainan) in China and the Commonwealth Scientific and Industrial Research Organisation (CSIRO) in Australia have been jointly developing gas content based technologies to predict the risk of the outbursts. One of the major progressive achievements is a new method for determination of outburst gas content threshold values. The method utilizes empirical analyses, numerical modeling, and seam-specific knowledge . This paper describes the method and its application for the #11 Seam at Guqiao mine, Huainan.

Aug 1, 2013

By G Anders

Underground tests of slusher cables at first might seem to be quite simple and inexpensive. They do, however, take a long time and give results that may be ambiguous and unreliable. Also, because underground test conditions are not exactly duplicable, tests carried out at different times or in different mines could not be compared. An attempt was made to develop a laboratory test method that would provide for all factors affecting slusher cable performance underground in such a way as to make it possible to achieve comparable results from different series of tests by exactly duplicating test conditions. Such a method should also make it possible to vary individual factors systematically in order to give a proper assessment of the effect of changing conditions on cable performance. A set of tests, comparing the same two types of cable both underground and in the laboratory, is described. AN assignment at the Algom Nordic mine called for the comparison of two types of %-in. slusher

Jan 1, 1964

By Kilian Neubert, Hermann Wotruba, Henning Knapp

Sensor-based sorting has been integrated into more and more applications in mineral processing over the past decades. Various sensor types, such as line scan cameras, near infrared sensors and X-ray transmission sensors, allow the separation of a vast variety of raw materials. Sensor-based sorting has several economic benefits which can make the difference between an uneconomic operation and a profitable mine. Sensor-based sorters can be applied to fulfill various sorting tasks, such as waste rejection, product quality improvement and ore type diversion, and have a significant impact on the layout of the processing plant. Therefore, it is important to include sensor-based sorting into the planning of a processing plant at an early stage. To evaluate the applicability of sensor-based sorting for any specific ore type, it is currently necessary to provide several hundred kilograms of material for subsequent bulk tests. In exploration, ore samples are usually rare and only available in form of drill cores. The acquisition of drill cores is time-consuming and expensive especially for deposits in great depth. Hence, it is unfavorable to spoil valuable drill cores for bulk tests. This paper describes a methodology to evaluate the applicability of sensor-based sorting based on drill core analysis. That methodology offers the possibility to calculate the achievable performances of different sensor types for various grain sizes without comminution of drill cores. The general methodology is shown on basis of an exemplary test work on drill cores from a currently conducted exploration.

Jan 1, 2014

By D. H. Flather, J. W. Hendry, K. Drover

Black Hawk Mining Inc. has completed a comprehensive program on the prediction and management of acid rock drainage (ARD) at their Keystone Gold Mine (Keystone) near Lynn Lake, Manitoba. The program, initiated in 1994, followed a phased approach utilizing initial acid-base accounting (ABA) results and subsequent laboratory kinetic testwork to define site-specific sulphide oxidation and neutralization consumption rates in waste rock. Net acid generating waste rock at Keystone was defined through the kinetic testwork as waste rock yielding a net potential ratio (NPR) of less than two. A preliminary waste rock management program based on blending of potentially acid generating and acid neutralizing waste rock was advanced. Subsequent refinement of the management program followed the analysis of over 1580 ABA samples collected from individual blast holes during the initial bench development phase of the Keystone pit. Uncertainties in actually achieving adequate blending within the dumps at a mining- scale resulted in the development of a revised waste rock management program based on segregation. Recognizing that any successful management plan requires that the ARD characteristics of the waste rock be identified prior to in-pit blasting, the extensive ABA database was utilized to develop a rapid characterization scheme. By implementing a characterization scheme based on total sulphur concentrations and fizz rating, waste rock could be quickly segregated without delaying the natural flow of ore from the pit. Interestingly, it also became apparent that gold values were strongly correlated with total sulphur, such that traditional fire assays were supplanted with a simple and more cost-effective total sulphur determination. The program highlights the importance and benefits of collecting and exploiting data beyond that necessary to acquire appropriate development permits.

Jan 1, 2000

By Patrick Edward Connell

The next generation of the well-established 3-roll Reducing & Sizing Block (RSB), the RSB SCS® is the latest milestone in reducing and sizing technology for SBQ products. It offers enhanced bar quality, improved productivity, mill availability and economy as well as a simplified, safe and environmentally friendly operation. A newly developed modular drive concept of the RSB SCS® grants a smaller footprint in the layout, a reduced oil-lubrication volume and a simplified maintenance schedule. Intelligent engineering leads furthermore to reduced hydraulic functions of the RSB SCS®, which ensures a safe and environmentally friendly rolling. Another integral part of the RSB SCS® is an innovative stand changing concept, which allows automatic stand changing within three minutes. The new RSB SCS® also includes a Fast Remote Control (FRC) which enables the immediate adjustment of the roll gap against the rolling force (under load) within milliseconds. Size changes along the free-size range can also be made within the traditional billet gaps in less than five seconds. At the core of the future-oriented RSB SCS® is a real-time closed-loop control system called Size Control System (SCS®) acting with 3-roll stands adjustable under load (AUL) and / or the heavy duty stands. These features remarkably further improve the rolled tolerances and their reproducibility, and at the same time simplify the operation by means of an automated optimization of the process parameters for the rolled bars.

Aug 16, 2017

By M Khanal, J Qin, B Shen, Y Duan, X Luo

Gaining confidence in interpreting rock and strata properties of the coalmine roof is necessary for design, maintenance, modelling and optimisation of roadways supports. One of the key causes of roadway instabilities experienced in underground coalmines is an extreme variable nature (thickness, competence, discontinuities etc) of the coalmine roof. Normally, the thickness and strength of the roof are characterised with the geotechnical and geological data gathered from exploration boreholes, which are drilled often at considerable distances apart. This limited data cannot capture localised geological variations in the coalmine roof. With this background, this paper explores feasibility of using measurement while drilling concept to perform geotechnical characterisation of the coalmine roof. The parameters, for example, penetration rate, rotary speed, torque, sound, vibration, obtained during the drilling process can provide valuable insights into geotechnical properties. The paper describes the progress of the experimental work conducted at the laboratory on synthesized concrete samples representing various rock strata using a field-scale drilling machine. The samples with and without interfaces have been tested to replicate various underground roof strata. The signals returned from the drill machine, as the drill bit passes through the layers, have been analysed and interpreted to characterise whether the drill response data can differentiate various strengths associated with the rock layers. The initial laboratory results are promising as they show distinct responses of the various sample blocks in a controlled environment. The drilling data can differentiate the synthesized rock samples and detect ‘signatures’ of the roof strength variability and delineation of lithological interfaces (transitions). The weight and torque on the bit vary and show dependency on the strength of the blocks.

Nov 29, 2022

By Jean-François Stumper, Mario Moser, Mark Kruessmann, Volker Langer, Daniel Bastos Martins Cruz, Claude Meisch

The latest generation of probes and casthouse machines provide a wealth of data that has not been available a few years ago. The evaluation of this data gives direct feedback to improve the blast furnace efficiency, the equipment maintenance and design and it allows the early detection of critical or deviating process situations. A stable operation with lower operation and maintenance costs are the final customer benefits.

Oct 1, 2019

By J. J. Cilliers, I. K. Craig, J. D. le Roux, K. Hadler

An analysis of the state-observability characteristics of a dynamic tank-to-tank model of a flotation bank indicates that the concentrate-flow rate of each tank can be estimated from accurate measurements of the pulp height in each tank and the final tailings flow-rate exiting the final tank. Therefore, there is an opportunity to construct an observer (model-based soft-sensor) which can estimate the concentrate flow-rate of tanks in a flotation bank. The concentrate flow-rate, i.e. mass pull, is generally measured by means of froth image analysers on industrial plants. A model-based soft-sensor will not only provide a means to validate froth image analyser results, but could potentially substitute them as they are less expensive to implement and maintain. Keywords: Concentrate flow-rate, estimation, flotation, modelling, observability, soft-sensor

Jan 1, 2020