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By Donald W. Murphy, John Chipman

Recent developments in iron alloys containing nitrogen have indicated that this element may exert a considerable influence on the properties of the metal. This influence is not always in an undesirable direction and the indications are that nitrogen should be regarded as an alloying element, the amount of which should be subject to control, rather than as an inherently deleterious impurity. In controlling this element in liquid iron to the best advantage, it is necessary to have a reliable background of fundamental data pertaining to solubilities, rates of solution and chemical reactions of nitrogen in liquid iron. Obviously, the first step in such an investigation is the determination of the solubility of nitrogen in pure iron, and this has been the object of the experiments described in this paper. The solubility of nitrogen in solid iron has been measured by Jurich,' Sieverts,2 Martin,3 and Iwasé4 and the agreement among the first three inspires confidence in their results. No accurate determinations of its solubility in liquid iron have been recorded though several investigators have obtained approximate results. Strauss6 was able to introduce 0.03 to 0.04 per cent nitrogen into steel by the action of either ammonia or nitrogen on the liquid metal. This was accomplished by Eilender and

Jan 1, 1935

The reported values of the standard reduction potentials of the Au(NH3)2+/Au(0) and Au(S2O3)23-/Au(0) couples are reviewed to emphasise the experimental difficulties associated with the measurement of reliable values for these quantities. The standard reduction potential for Ag(I)/Ag(0) in ammonia and thiosulphate solutions measured at ionic strength 0.1 and 25oCis used to predict the following relevant stability constants () for gold complexes based on the linear free energy correlations: Au(NH3)2+2 = 1013, Au(S2O3)23-2 = 1024 and Au(NH3)43+4 = 1033. The equilibrium constant ( 10-11) for the reaction Au(S2O3)23- + 2NH3 = Au(NH3)2+ + 2S2O32- based on these stability constants is in reasonable agreement with the measured value (10-9) based on potentiometric and spectroscopic data when excess ammonia was added to a solution of Na3Au(S2O3)2. This also indicates that the stability constant of Au(NH3)2+ is 9 to11 orders of magnitude less than that of Au(S2O3)23-. Relevant species distribution and Eh-pH diagrams based on the revised data are presented.

Jan 1, 2003

By John Chipman, Donald W. Murphy

Recent developments in iron alloys containing nitrogen have indicated that this element may exert a considerable influence on the properties of the metal. This influence is not always in an undesirable direction and the indications are that nitrogen should be regarded as an alloying element, the amount of which should be subject to control, rather than as an inherently deleterious impurity. In controlling this element in liquid iron to the best advantage, it is necessary to have a reliable background of fundamental data pertaining to solubilities, rates of solution and chemical reactions of nitrogen in liquid iron. Obviously, the first step in such an investigation is the determination of the solubility of nitrogen in pure iron, and this has been the object of the experiments described in this paper. The solubility of nitrogen in solid iron has been measured by Jurich,' Sieverts,2 Martin,3 and Iwasé4 and the agreement among the first three inspires confidence in their results. No accurate determinations of its solubility in liquid iron have been recorded though several investigators have obtained approximate results. Strauss6 was able to introduce 0.03 to 0.04 per cent nitrogen into steel by the action of either ammonia or nitrogen on the liquid metal. This was accomplished by Eilender and

Jan 1, 1935

By Matthew Spedding

The complex nature of the carboniferous measures prevailing in the U.K. has dictated the types of mining required to exploit the coal seams. Most mines in Britain are referred to as deep mines in the sense that they operate at depths of 1800 - 3000 feet. The main system of coal transport to the surface is by vertical shafts which intersect the workable seams which at times number between 4 and 5. As mining has been practiced in most of the major coalfields in the U.K. for well over 100 years, with the initial extraction of the shallower and more profitable seams, the present management have been left a legacy of indiscriminate extraction which severely hampers their efforts to maximise the mine layouts. There is no single standard design of mining layout capable of meeting the wide variety of conditions which exist in the British coalfields. Mining layouts are subject to fixed and variable parameters. In discussing multi-seam working, the main parameter must be the effect of old workings above and below the seam to be extracted. There is a distinct lack of reliable information which would enable layouts to be designed to completely avoid or control these destructive forces. The guidelines are, therefore, mostly empirical.

Jan 1, 1977

To clean coal mine air by developing a low-cost scrubber suitable for belt transfer and similar applications. Approach Design a scrubber operated by water only, with no moving parts. Use conventional water spray nozzles located within a duct to both move and clean the air. Use a droplet eliminator to get the water droplets and mist back out of the airstream. How It Works Conventional scrubbers require a mechanical fan driven by either an electric or a hydraulic motor. They also require water sprays and some type of scrubbing mechanism. The water powered scrubber, however, offers higher reliability over conventional scrubbers since it utilizes the water sprays to both move the air and scrub the particulate from the air. Conventional water spray nozzles are placed near one end of a rectangular duct open at both ends. The sprays are directed towards the far end of the duct where a stationary wave blade water droplet eliminator is located. Movement of the water spray droplets coming from the nozzles generates (by momentum transfer) an air movement In the same direction as the sprays. The volume of air moved Is primarily a function of the duct cross-section size, water pressure and water

Jan 1, 1981

Lance based copper-nickel matte converters have become an established technology in the field of base metal sulphide smelting and converting. An Ausmmelt® converter is currently being constructed at Anglo Platinum in South Africa to convert a nickel-copper rich matte containing platinum group metals (PGM's). The accurate prediction of the matte chemistry is required to control the composition at the endpoint which influences segregation of PGM's during the subsequent slow cooling and magnetic separation processes. A hybrid modelling approach is introduced in this paper that incorporates both the effect of thermochemistry and system dynamics. It will be shown how the model relates to fundamental conservation laws, while still providing enough flexibility to adapt to changing operating conditions. It will also show how off-line modelling can be incorporated into a robust on-line model. Based on the data from many pilot plant trials, the model prediction performance is shown to be within the accuracy requirement set by industry and therefore constitutes a reliable basis for model based control. The final generic model structure takes on the form of an thermodynamically integrated ARMAX hybrid model. The final model has the advantages of being dynamic, adaptive, robust and it can be related to thermochemical fundamentals.

Jan 1, 2002

By F. R. Hewitt

THE methods of mining talc are simple, and in western North Carolina are almost entirely by open cut and quarry. The larger part of the talc of this section lies in various-sized "veins" inclosed in quartzitic walls, the majority of which have by folding been thrown into a perpendicular position, or nearly so, and the exposed edges of which have been covered by debris from erosion of the mountain above. This covering of loose rocks and earth is from 5 to 25 ft. thick, and in most cases has to be removed because it is difficult to support. Sometimes the covering is heavy enough to "catch" and timber successfully, and in this case the talc can be worked out by the usual method of following the "vein," using stulls for holding up the walls until the vein is worked out, and then allowing the cut or drift to fall in. In some cases it proves more convenient to sink shafts and run drifts, following the talc "veins" until exhausted. The talc deposits of this section are badly broken and faulted both laterally and perpendicularly, and in some cases are found many feet below the level of drainage, necessitating pumping at considerable expense. . My own experience in mining talc has been that the chief point is to get a reliable "vein," and that then the mining is not as difficult, or any more so at least, than that of any common ore. If the. "veins" are pure talc it is simple; if the talc is admixed with foreign matter, such as tremolite in excess, or stains of iron or manganese, as is often the case, one had better abandon the deposit.

Jan 8, 1916

By Larry A. Lien

Membrane technology has been available for about 30 years, but has been used very sparingly within the general mining industry. However, recent developments in polymer chemistry, spiral wound element construction, pretreatment equipment and element cleaning techniques have improved the reliability and robustness of membrane based systems. These improvements have expanded the potential to use this "new" technology to enhance critical recoveries of gold and silver in heap leaching operations or in the extraction circuit. Another opportunity for the mining industry will be to use membrane technology in new processes like controlling organic acids or ammonium thiosul­fate to enhance gold and silver extraction during leaching opera­tions. Finally, the most common use for membrane technology is for the control of mining water balance and acid mine drainage issues. Polymeric membranes, specifically thin-film composites, have been developed that will purify, fractionate or concentrate gold or silver. Recent applications have been developed for spi­ral wound modules that operate across the pH spectrum from 0 to 14. Systems using membranes have been constructed that operated on feed streams from 200° C to 3000 centipoise. Most recently, membrane based systems have been pilot tested suc­cessfully to purify solvents, like LIX. Opportunities exist to apply membrane technology to concen­trate gold and silver cyanide solutions with thin-film composite Reverse Osmosis (RO) membranes at elevated pH values above 10. Incorporating membrane technology could allow one to increase production without incurring additional expansion of the gold extraction side of the process. Furthermore, free cyanide is not rejected by the Reverse Osmosis membranes, but other inorganic salts are rejected 98+%, thereby, allowing an essentially ion free, except for the free cyanide, to be recirculat­ed back to the heap leach operation for enhanced extraction.

Jan 1, 1998

By N J. Arunakumaren

A coal mine is proposed for an area where a major river traverses the project area. There were initial concerns that inflow of groundwater from exposures of high permeability alluvium associated with the river system could pose mine dewatering problems together with adverse impacts on surface water resources in the river. The project included collation and analysis of geological and hydrogeological data collected historically over a long period of project investigation and evaluation. The project also included establishment of additional groundwater monitoring points to provide a reliable groundwater contours. The groundwater level contours were produced to allow numerical models to be calibrated to support estimation of groundwater inflow. River bed cross sections were also prepared to assist study of the effect of river flow on the inflow. Two separate MODFLOW groundwater models were produced to simulate long-term groundwater inflow to the mine with an upper model consisting of the Quaternary and Tertiary alluvium lumped together and a lower, separate model consisting of Mesozoic coal measures. Analytical solutions were used to predict initial inflow from the alluvium and from the coal measures.

Jan 1, 2003

By Weber W

Methods of calculation of the reliability of process computers are getting more and more important. The paper presents long period observations of 21 process computers with online applications in the iron and steel industry. About 5000 failure events during 10 years have been systematically recorded and evaluated. On the basis of these long time observations it is possible to develop a probability model of the failure behaviour of process computers.This failure model is constructed with four different states of the process computer:Working phase, working phase with undetected reasons, repair phase, failure phase resulting from external influences.The model is defined by differential equations for the probability of one of these four phases. Long time observations show, that all of these four phases are closely correlated with the capa-city of a process computer, restarting without detection of failure reason, changes of programs and software, costs and time of repair. So the result of this analysis is a model of failure for process computers, which allows to predict breakdowns of process computers on the basis of external parameters.

Jan 1, 1985

By E. O. Bennett

Various methods of making leakage tests have been tried during a study of losses in the transmission of natural gas. This work has been carried on by the Bureau of Mines in cooperation with the Natural Gas Association of America. Results of tests show that the "shut-in pressure-drop" method described by Rawlins2 is the most accurate and reliable; therefore its use is recommended. This paper describes a graphic method for computing the rate of leakage from the fall in pressure and change in temperature determined by the "shut-in pressure-drop" method of testing. METHOD OF MEASURING PRESSURE DROP The gas is "shut in" the line to be tested and is not allowed to escape except through existing leaks. The leakage causes the pressure in the line to fall. The change in pressure is obtained with a dead weight gage. Approximate results may also be obtained from readings on a good spring test gage. Numerous tests show that the dead weight gage is more sensitive to small changes in pressure than spring gages.

Jan 1, 1926

By Eric D. Marks

Fatalities resulting from ground workers colliding with objects and construction equipment accounted for approximately 18% of the total construction fatalities experienced in 2010. Current injury and fatality measuring methods have proven to be inadequate due to their use of passive measures of safety rather than a more active approach, such as the use of leading indicator data (also called near misses) of hazardous proximity situations between ground workers and heavy equipment on construction sites. The objectives are to create and evaluate the effectiveness of a reliable algorithm for collecting and analyzing the resulting leading indicator data from hazardous proximity situations. Numerous experiments emulating typical interactions between workers-on-foot and heavy equipment are used to evaluate the proximity sensing and detection technology. Safety leading indicator data (also called near misses) generated by the proximity sensing and detection technology during the experimental trials are used to create and assess the resulting algorithm. Results from the experiments indicate that leading indicator data generated from these systems can be processed and analyzed to identify hazardous proximity situations and incidents on construction sites.

Aug 1, 2013

Studies of the minor element content of sphalerite and pyrite have generally been concerned with individual deposits or localised groups of deposits. However, a small number of more regional investigations have been reported (e.g. Davidson, 1962; Groves and Loftus-Hills, 1968; Loftus-Hills and Solomon, 1967; Price, 1972; Bralia et al., 1979) which have used the minor element abundances to evaluate the petrogenesis and geological affinities of diverse ore types and to fingerprint metallogenic provinces (e.g. Ivanov, 1964). While generally held to be valid, some doubts have nevertheless been cast on the reliability of minor element abundances in petrogenetic deliberations (e.g. Mercer, This paper reports on the distribution of he. Cpl and Mn in sphalerite, and Co, Ni and Mn in pyrite, from sulphide mineral occurrences within the "eugeosynclinal" prism comprising the New England Region of north-eastern New South Wales and south- eastern Queensland (Fig. 1). The occurrences examined are representative of two well-defined styles of mineralisation (Stanton et al., 1974) within which clear patterns of ore-rock distribution give rise to specific metal associations (Herbert. 1977).

Jan 1, 1987

By Thorvald Wetlesen

Computer controlled drilling is now proven technology. It was first introduced by the development of the Furuholmen system for a prototype three boom tunneling jumbo in Norway in 1978. Now, 13 rigs with this concept are in operation in Europe, 3. in mining in England and. 10 in tunneling elsewhere in Europe. The system is also adapted to roadheader guidance. Practical experience has shown that the computer control system makes it possible to drive tunnels with a more accurate contour thus reducing the total amount of rock excavated, and where a full concrete lining is required a reduction in concrete volume is achieved. The total tunneling economy is improved. In the future we expect to see a wider range of instrumentation on jumbos, from the simple direction instruments to computer guidance systems for monitoring only, as well as fully automatic drilling to a programmed drilling pattern. More compact and reliable electronics will be available. Systems with low power consumption will fit easily into flameproof applications. Cabling complexity will be reduced by connection of sensors to serial signal lines.

Jan 1, 1989

Introduction The mine winder is an essential element in the mining of ore in deep level mines and therefore requires a high degree of reliability to avoid interruption of production. Failure of any component on a winder may also be dangerous and expensive to repair. The larger the failure the larger the stoppage. The failure of a winder drum is the ultimate catastrophe, not only because of the cost of replacement, but also because of the lead time in procuring a new drum. Today these types of failure are not as common but many failures have occurred in the past and even today many an old winder is con- sidered for a new and often more arduous duty. As far back as the turn of the century a lot of information had been gathered to try and clear up the complexities of the multi- layering effect of coiling rope under tension onto a drum. Before comparing results obtained by various researchers the nature of the pressure distribution between rope and drum due to multi-layering will be discussed briefly.

Jan 1, 1987

By J. M. Scharer, Bruce E. Halbert, Pettit. Carol M., Lysane Bolduc

The ratio of neutralization potential (NP) to acid production (AP) ratio is often employed for predicting acidic discharges from waste rock dumps. The available NP was evaluated in laboratory studies of limestone dissolution in simulated acidic mine water. The available neutralization potential strongly depended on the particle size. Using limestone particles of 114" (6.4 mm) or greater, less than 20% of the total neutralization potential was exhausted at the onset of acid conditions. Apparently, the dissolution of limestone became mass transfer limited. Under mass transfer limitations, the rate of pyrite oxidation may exceed the rate of neutralization by buffering minerals. The implications concerning the controls on limestone dissolution were examined using a geochemical predictive model for sulphide mineral oxidation in waste rock. The results have shown that in case of heterogeneous waste rock piles the NP/AP ratio is a reliable indicator for short-tam predictions only. Kinetic data on the depletion rate of the neutralizing minerals and geochemical modelling suggest that waste rock environments with NP/AP ratios as high as 5.0 may turn acidic in the long term.

Jan 1, 2000

By Duk-Won Park

A vast majority of the operating longwall sections use shield-type face supports to provide ground control in the United States. As a co-operative research program between the University of Alabama (UA) and Jim Walter Resources, Inc.(JWR), a joint research program is underway to study interaction of shields with surrounding rock masses. A series of analyses on the response of shields are performed using monitored data at a longwall face in a deep coal mine. In this paper, various effects of parameters, such as leg pressure, setting load, developing load, maximum loading rate, pressure in capsule, and convergence between canopy and base, are discussed and recommended as stability indices. A microcomputer program is being developed for instantaneous interpretation of the shield monitored data, and for giving warnings of potential problems. The preliminary results define the effects of the setting load, developing load, and rate of developing load or leg closure rate. The objective of the study is to understand the shield characteristics and their interaction with surrounding strata in real time, then develop a reliable program for maintaining longwall stability.

Jan 1, 1992

In this presentation, CiDRA?s patented technology platform and its applications will be described. CiDRA's non-invasive, passive sonar array-based flow meter technology provides the volumetric flow rate of single or multiphase fluids by measuring the speed at which naturally occurring structures such as turbulent eddies or density variations convect with the flow past an axial array of sensors. These sensors are incorporated in a band that is wrapped around the outside of the pipe, resulting in no process downtimes for installation and unprecedented reliability. This technology has resulted in a unique ability to measure the flow rate of most fluids ? clean liquids, high solids content slurries, pastes, and liquids and slurries with entrained air. Unique and difficult minerals processing flow measurement problems and their solutions will be described. Examples of these problems include flow measurements in froth lines and flotation feed lines with entrained air, slurry lines with magnetite and other magnetic ore, slurry lines with abrasive or corrosive materials, high pressure lines, and lines exhibiting scale buildup. Recent technology developments will be covered.

Jan 1, 2008

By J. E. Chilton

No regular monitoring of methane is required in areas of gassy coal mines outby the mining face. Methane ignitions that have occurred in mine outby areas indicate the need to provide better protection to workers. Handheld methane monitors are now used by some miners to make periodic measurements of methane at the working face. The IYONI II gas detector which is incorporated into a miner’s cap lamp and worn on a miner’s helmet can continuously provide an alarm signal whenever methane levels exceed a set level. Tests were conducted to evaluate the performance characteristics of this methane detector by measuring response times with methane gas supplied through a calibration fixture or adaptor. Other response time tests were performed with the detector in an environmental test box. Performance was also evaluated in a full scale test gallery where face methane emission and underground ventilation were simulated. Procedures for calibration by response time measurement of the IYONI II detector have been developed. In limited testing, the IYONI II detector was found to reliably detect the presence of 1 percent by volume methane.

Jan 1, 2003

By William R. Groseclose, Cecil E. Tackett

Since 1965 when the first mole was used on Bureau work, the Bureau of Reclamation has completed 17 tunnels of over 5,000 feet in length. The longest was 12.8 miles. Total length of the 17 tunnels was 376,207 feet, or over 71 miles. The finished diameter varied from 7 feet 0 inch to 18 feet 0 inch with 82 percent (58 miles) being less than 12 feet 0 inch in diameter when lined. All of these tunnels except one are gravity flow, water conveyance tunnels with relatively flat gradient. One is a low-head pressure tunnel. All were constructed by contracts resulting from fixed-price bids. Starting in 1964 the Bureau of Reclamation initiated the practice of giving several options in the specifications on methods of tunnel excavation. Since that time, construction work has been completed on 17 tunnels. Of this number, 11 were mole excavated and 6 were excavated by conventional drill and blast methods. In general, there has been 2 feet of mole excavation for every 1 foot of drill and blast. Cost comparisons are based on only 13 tunnels because the Bureau has 4 recently completed tunnels that have pending claims; therefore, final cost data are not available. Some definite trends show from the data available; however, the number of completed tunnels in some categories is so small the results cannot really be considered a trend. As more data become available, the indications will become more reliable. The information is presented to indicate general trends and comparisons and cannot be meaningfully used for a one-on-one comparison because of individual tunnel differences not considered.

Jan 1, 1974