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For the convenience of those who are unfamilar with thermodynamics, the following brief description and explanation is given of the thermodynamical terms and methods used in this book. It must, however, be strongly emphasized that the account given below is not an introduction to chemical thermodynamics; its sole purpose is to give the reader a rough understanding of the methods used in the earlier chapters. For further information, reference must be made to the standard textbooks on chemical thermodynamics by Glasstone.

Jan 1, 1953

By W. G. Sandell, L. C. Bauerle, K. C. Dean

"INTRODUCTION As a part of the wartime activities of the Bureau of Mines, metallurgical services were extended to other Government agncies engaged in purchasing and stock-piling some of the more critical and strategic materials. At the request of Dr. Alan M. Bateman, special representative of the Metals Reserve Company, metallurgical studies were made on three samples of oxide tin ore from, the States of Zacatecas and Guanajuato, Mexico. The samples were submitted for testing by A. Porraz of the Financiera Miners, S. A., institution Financiera, Edificio Guardiola, Despachos 500-507, Mexico, D. F.The samples as received were marked Nos. 1, 2, and 3 and described as follows:Sample 1. - Origin: Mining camp ""El Naranjo,"" municipality of Sombrerete, State of Zacatecas, Mexico. This sample was partly concentrated by washing and as received was all minus 10-mesh in size.Sample 2. - Origin: Deposits in Sierra. Fria and Juan Cherey, municipality, of Jerez,State of Zacatecas, Mexico. This sample represented run of-mine ore.Sample 3. - Origin: Mine ""La Frontere, "" Ranch of San Pedro del loya, State of Guanajuato, Mexico. This run-of-mine sample was low in tin content but came from a highly mineralized tin field."

Jun 1, 1947

By M. G. Zabetakis

Benzene and toluene are the first two members of an important homologous series whose general formula is CnH2n-6. The members of this series differ in composition from benzene by some integral multiple of CH2; they can all be prepared in the laboratory by the Wurtz-Fittig, Friedel-Crafts and Grignard syntheses. Because 'of the industrial importance of these-hydrocarbons, the limits of flammability of eight members of the series have been determined at 100° C.-(A temperature of 1000 C. was chosen because the determination of the upper limit of flammability of p-cymene requires an apparatus temperature. of at least 90° C. As elevated temperature data are available for other combustibles at 100° C. but not at 90° C., all data were taken at 100° C. in order to obtain comparable results.) Minimum ignition temperatures of these combustibles have been determined at laboratory-pressures.

Jan 1, 1951

By Krishna R. Reddy, Jyoti K. Chetri, Girish Kumar

Geotechnical engineering encompasses a major portion of the civil and infrastructure projects. The large amounts of energy and resources typically used in these projects leads to undesirable emissions and wastes which contribute substantially towards global environmental impacts (e.g., global climate change). This could further include secondary economic and societal issues which are often unaccounted in traditional engineering design of the geotechnical projects. In order to address this issue, it is imperative to integrate the broader environmental, economic and social implications into decisions of a geotechnical project. Recent years have seen a major impetus on life cycle assessment to evaluate the environmental sustainability of the geotechnical designs. However, there are no tools that can quantify the life cycle triple bottom line sustainability of potential design alternatives in a project with holistic considerations towards broader economic (indirect costs and benefits) and social impacts (stakeholder preferences, socio-environmental and socio-economic impacts). This study presents a new framework for quantitative assessment of life-cycle sustainability (QUALICS) for alternative designs in engineering projects. The framework integrates two multi-criteria decision analysis methods namely, the Integrated Value Model for Sustainable Assessment (MIVES) and Analytic Hierarchy Process (AHP), to support decision making on the potential design alternatives. In this study, a brief overview of the framework is presented. A case study demonstrating the use of QUALICS framework is discussed with its application to the sustainability assessment of two deep foundation systems, caissons and piles, over their design life. The technical designs of both systems are developed based on bearing capacity, both primary and secondary settlements, and structural integrity. The results from the sustainability assessment of the two deep foundation systems are discussed, and the most sustainable option based on different stakeholder preferences and site-specific conditions are identified.

Jan 1, 2019

By Arvid E. Nissen, Knox Taylor, John H. Hall

Some months ago one of the authors was asked to write a paper on the heat treatment of steel castings that would be more comprehensive than other matter he had published; this is an attempt to present in condensed form the results of experimental work and actual practice carried out for the most part in 1907, 1908, and 1909. It is not a laboratory research and the work done was carried out for the express purpose of putting in practice the processes discovered as fast as possible. Most of the tests are the result of commercial practice and not of bars annealed in our laboratory; most of the micrographs were made for our own records and not for publication. Certain of the micrographs, therefore, are not as clear as we may wish but they were good enough for our purpose at the time they were made. The tests and micrographs are selected from several thousands in our files. All of these micrographs are magnified 60 diameters. These experiments were conducted almost entirely on steel made in a 3-ton bottom-blown converter, and most of the steel illustrated analyzes about 0.05 in phosphorus and sulfur. Unfortunately, a certain number of specimens are shown of which we do not have the complete analysis, but in most cases in which the phosphorus and sulfur vary much from the figure just given that fact is noted. For purposes of comparison, we have included a certain number of micrographs and tests of steel made in the electric furnace, some of which were from specimens made in other shops and some in our own shop, and some tests of acid open-hearth and tropenas steel. A brief examination of the tests in Table 1 shows that certain treatments of, for instance, 0.30 per cent, carbon steel are not represented by any test data. Had this been a laboratory research, this information would undoubtedly have been furnished, but as this work was done for commercial purposes the omissions are due to the fact that, at the time the work was done, we saw no advantage in trying every composition of steel with each treatment discussed in the paper.

Jan 1, 1920

By S. E. Stallibrass, A. M. McNamara, J. P. Panchal, Leonardo M. LaLicata

Urban development in congested cities requires a better exploitation of the available surface, leading to taller structures. These buildings are usually founded on piles that have to be increased in dimension to accommodate the larger loads. Consequently, both the cost and the carbon footprint of the pile foundations rises. An alternative option is to improve pile performance by enhancing shaft capacity, which is commonly the most important factor in determining the ultimate capacity of a pile constructed in a clay soil subjected to axial load. For piles in stiff clays, such as London Clay, the soil/pile friction may be increased by profiling the side walls of a bored cast in situ pile with small discrete “impressions” such that the latter form nodules on the shaft of the concreted pile. The results from centrifuge and full scale field tests showed that the impression pile represents a viable technology to enhance the shaft capacity as they provide an increase in capacity of 40%. Alternatively, reduced length impression pile can be used. This paper explores the implications of the impression pile technology on the potential carbon saving.

May 1, 2022

By Jordan Hoover, Erika Moonin, Chuck George

"In response to a severe regional drought and in preparation for the further decline of water levels in Southern Nevada’s Lake Mead, the Southern Nevada Water Authority (SNWA) built a new intake system to ensure water supply to Las Vegas and its surrounding communities. In 2015, design began on the Low Lake Level Pumping Station (L3PS) that will move the water from this lower intake, ensuring operability of the water delivery system despite these declining lake levels. The L3PS Project includes a 159-meter-deep shaft, a large underground chamber, and 34-each 152-meter-deep, 2.4-meter-diameter drilled well shafts to be constructed in highly faulted and fractured ground. The Construction Manager at Risk (CMAR) delivery method was chosen to facilitate early contractor involvement in the design process to address the significant challenges and risks anticipated on this US$650 million Project. This paper describes the CMAR selection process; the CMAR involvement during design and benefits resulting from that involvement; and the unique collaborative effort among the owner, engineer, program manager and CMAR used to evaluate and select the best design approach, preferred underground construction methods, and coordinated geotechnical baseline report. PROJECT BACKGROUND AND NEED Seven of the United States’ western states rely heavily on the Colorado River and its tributaries for their water supply. The primary source of water for the Colorado River is winter snow that falls in the mountains ringing the Colorado River Basin. Flows in the Colorado River vary significantly from year to year, depending on the amount of snow and rain deposited in the basin. Beginning in the year 2000 and continuing to the present, snowfall has been well below documented historical averages and Colorado River flows have diminished."

Jan 1, 2016

By J A. Gilliand

Mineralogical cross sections of orebodies on the 300-,600- and 900-foot levels of the Coronation mine have been interpreted in terms of centers of mineralization. The maximum concentration of chalcopyrite occurs closest to these centers, with pyrite and pyrrhotite concentrated some distance away. The magnetite concentrations are farthest removed from the centers. A hydrous halide fluid model is established. Attempts to explain the observed mineralogy by the action of temperature gradients on the fluid model were unsuccessful. Likewise, the action of diffusion alone on the fluid model cannot explain the observed mineral distribution. The concept of attenuation is introduced-i.e., the rate of diffusion of a particle species is related to the product r2 I/ M, the attenuation coefficient, where r is the particle radius and M its molecular weight. Attenuation, acting on the fluid model alone, will not produce the observed mineral distribution, but, when considered together with the action of temperature gradients, the observed mineralogy can be well explained by the combined effects of these two processes on the assumed fluid model.

Jan 1, 1965

By Paul K. Sims

The Central City district is one of several adjacent mining areas in the Front Range, Colorado, that contain precious metal-bearing sulfide veins of Laramide (Late Cretaceous and early Tertiary) age. The districts are in the Front Range segment of the Colorado mineral belt, and are characterized by porphyritic igneous rocks of intermediate composition that have intruded Precambrian crystalline rocks in the core of the Front Range. The veins and minor stockworks that constitute the ore deposits in the district were formed largely as fracture fillings. The veins range from simple fissures to complex, branching lodes, and commonly range from less than 0.5 to about 1 m in width. The principal values are in gold and silver. The common metallic minerals are pyrite, sphalerite, chalcopyrite, tennantite, and galena; minor minerals are enargite, pitchblende, and gold tellurides. Quartz, cryptocrystalline silica, carbonates, fluorite, and barite compose the gangue. The ore deposits have a well-defined concentric zonal arrangement. A core of pyrite veins (central zone) is surrounded by a peripheral zone of galena-sphalerite vein with gold and silver. An intermediate zone contains transitional veins that have minerals characteristic of both the central and peripheral zones. The minerals were deposited in three stages during a single period of mineralization: uranium; pyrite; base metals, gold and silver. The wall rocks were altered primarily during pyrite-stage mineralization. Sericite envelopes developed adjacent to fractures, and were succeeded outward by zones of argillized rock. The valuable ore minerals were deposited in ore shoots localized by several types of structural controls, principally vein intersections, the physical nature and structure of the wall rocks, and irregularities along the fractures themselves. During supergene alteration, gold was concentrated in the upper, oxidized parts of the veins, commonly to depths of 50 m. The precious metal-bearing sulfide ore deposits are closely associated in space and time with the Laramide porphyritic igneous rocks and are believed to have been derived from hydrothermal fluids related to the magmatic activity. The ore deposits have mesothermal aspects and apparently formed in the temperature range 200°-320°C.

Jan 1, 2013

By A. M. Kivari

OPERATIONS at the cement plant of the Permanente Corporation, in the hills about 45 miles south of San Francisco and 12 miles west of San Jose, are interesting to the members because of the adoption of modern hydrometallurgical methods for handling and beneficiating raw materials Closed-circuit grinding, classification, hydroseparation, flotation, agitation, and thickening are familiar terms at this cement plant These methods make it possible to process refractory limestone into suitable materials for the manufacture of modern cements Construction of the plant, haying originally a design capacity of 7000 bbl of cement per clay, was started in June 1939, and the first clinker was ground on the following Christmas Day At present the capacity is about 12,000 bbl of finished cement per 24 hr , most of the production being low-heat cement † About 3130 tons of limestone, 620 tons of clay and 100 tons of gypsum are required daily for this output Occasionally iron oxide is added to the clay to obtain the desired composition This, together with the gypsum, is purchased from outside sources Up to the present time, the corporation has produced low-heat, normal, moderate¬ heat, moderate-sulphate-resisting, high-early-strength, oil-well, modified-oil-well, and plastic cements Most of the present production is for Shasta Dam, near Redding, Calif , the told demand being 5,800,000 bbl of cement Following are sonic of the cement requirements of the Shasta D [im] specifications [ ] The average specific surface in the bin s sampled shill be not less Ulan 1800 sq cm per gram and no individual sample less thin 1600 sq centimeters Compressive strength The average compressive strength in pounds per square inch of three mortar cubes composed of one part cement and 2 75 parts fine testing sand, by weight, shall be equal to or greater thin the following

Jan 1, 1941

By F. R. Cattoir

The Federal Bureau of Mines refined chromium from an aqueous electrolytic process in molten sodium chloride-chromium chloride electrolytes. Oxygen and nitrogen contents were reduced by a factor of 10 to 40, but most other impurities were little changed. The product usually contained a little more iron than the feed. Since iron was entering the bath from the iron pot and the graphite liner at a nearly constant rate, contamination of the chromium deposits by it was more serious at low currents and deposition rates. A few runs in an iron cell with a nickel liner yielded chromium containing one half as much iron as the feed, but up to 1.5 pct. nickel. In all cases the anode feed lay in the bottom of the container, which itself was used as the anode connection. With a 12-in. cell, variations in applied voltage from 0.05 to 1.5, in current from less than 10 to over 100 a., and in initial cathode current densities from less than 100 to over 2,000 a./sq.ft. had little or no effect upon the analysis of the metal produced) except for iron content. Changes in bath analysis from 3 to 11 pct. chromium were also without effect. These changes did bring about large differences in the physical forms of the crystals obtained. The thick heavy crystals produced at low voltage and current contained voids which made them difficult to leach free of chlorides. Easiest to leach were the thin leaf-like crystals obtained at around 1 v.

Jan 1, 1960

By Richard T. Newcomb

Federal and utility industry research has largely ignored coal beneficiation techniques in the implementation of SOx control. This paper accepts the hypothesis that beneficiation cum scrubbing is the cheapest way for the vast majority of seams in the eastern coal provinces to comply with standards. Comparisons are based on point estimates of average beneficiation costs from a model of coal preparation (COBET) designed to simulate four levels of cleaning. The paper describes how economic theory can be applied to derive econometric supply functions from actual data on the geology of minable seams, washability and technical constraints. West Virginia is taken as an example of a producing region. Spatial supply functions are derived empirically from the engineering model simulations.

Jan 1, 1977

By Robert W. Yokom

As the search for new sources of energy and minerals leads to more remote areas of the country - and the world - the need to plan for adequate housing and community facilities for the construction and operations workforces and their families takes on an importance equal to the mining and processing facilities themselves. A corollary to the need for planning is the increasingly crucial need for development companies to devise effective strategies for dealing with the local communities impacted by these projects. Experience has amply demonstrated the high price to be paid for failure to learn this lesson, a price measured in lost productivity, confrontation with local communities, labor turnover, mental health and other social and eocnomic problems. In Sweetwater, Wyoming, a new industrial activity caused the population to double from 18,000 to 36,000 between 1970 and 1974. During that period industrial productivity fell 25 to 40 percent, cost overruns on the principal new industrial facility exceeded 33 percent, annual employee turnover rates climbed above 100 percent, the local mental health clinic workload increased nine times and complaints to the local law enforcement agency increased 60 percent.

Jan 1, 1981

By N. C. Joughin

A simplified economic model is derived for the financial return from a new gold mining project. The model is used to analyze the effects of changes in the mining rate, capital costs, working costs, value of the reef and the stoping width. The most effective avenues for improving the return from a new project are indicated. It is shown that those technological innovations which would improve the return significantly, and therefore make it possible to open more mines, are the use of smaller mines, means for improving the mining rate to capital costs ratio for smaller mines, planning and control of mines by computer simulation, an improved mine valuation procedure and means for mining at a decreased stope tramming width.

Jan 1, 2014

By Luke Erickson

San Francisco Public Utilities Commission is planning to replace 5 miles of pipeline under San Francisco Bay. The tunnel will be constructed using an Earth Pressure Balance (EPB) TBM and will be the first TBM-driven tunnel under the Bay. The alignment passes under environmentally sensitive habitats, through interbedded layers of sands and clays, and through a buried bedrock ridge. This paper discusses the geotechnical characterization and anticipated tunneling conditions and presents the analysis of various construction methods that resulted in the selection of an EPB TBM. Considerations related to tunneling with an EPB TBM are described in detail, including ground conditioners, TBM cutterhead wear, muck control, and squeezing ground.

Jan 1, 2008

By Haijian Fan

Currently, deep foundation designs for the service limit state are deterministic in nature. The settlements and lateral deflections of deep foundations are calculated by means of numerical techniques whereby the foundation-soil interactions are characterized by discrete load transfer curves such as t-z or p-y curves. The noted deficiency of the deterministic approach is that the uncertainties arising from various sources, such as soil properties and model errors are not considered. To address this deficiency, a performance-based reliability design methodology is developed using Monte Carlo statistical methods. The performance based design criteria are defined in terms of the specified allowable displacement. The input to the numerical solution techniques, including the soil strength parameters, unit weight of the soil are relevant to the generation of the load transfer curves are treated as random field. The well established random field generator algorithm, local averaging subdivision, is used to generate random samples of input, where the mean values, variances, the probability distribution, and correlation structures are required statistical parameters for these random variables. The objective of the performance based reliability design is to determine the optimized foundation dimensions so that the probability of failure is less than the target probability of failure. The probability of failure by the Monte Carlo approach is simply the ratio of the number of unsatisfactory performance to the sample size. A numerical example for laterally loaded drilled shaft is given to illustrate the application of the methodology. The incorporation of the correlation length is shown to be critical for properly accounting for the site soil spatial variability.

By M. Holmes, R. Molnar, E. Norton, K. Baxter, J. Riordan

The Boleo Copper-Cobalt-Zinc-Manganese Project of Baja Mining Corp. is situated adjacent to Santa Rosalia on the Baja Peninsula of Mexico. The El Boleo ore is a mixed oxide-sulfide deposit with major values in copper, cobalt, zinc and manganese. The metallurgical process designed to treat the El Boleo orebody involves a sulfuric acid leach in seawater using oxidative and then reductive leaching to maximize metal extraction. The leach solution is separated from the barren solids via counter current washing through a series of high rate thickeners. Copper is recovered using conventional SX-EW processing as cathode. Zinc and cobalt are extracted from the copper SX raffinate after iron and aluminum precipitation. The CSIRO DSX solvent system (Versatic® 10 and LIX® 63 mixture) are used in this extraction. Manganese remains in the DSX raffinate and is recovered by soda ash addition as a high quality manganese carbonate precipitate. Zinc and cobalt are acid stripped from the loaded DSX solvent. Zinc is then re-extracted away from cobalt using Cyanex® 272 extractant and stripped into a highly concentrated strip liquor (+100 g/L Zn) and directed to either a spray dryer or a granulator for production of zinc sulfate monohydrate. The zinc solvent extraction raffinate, containing cobalt, advances to another SX circuit using Cyanex® 272, for the recovery of cobalt as cobalt cathode. In this paper, the detailed results from bench and integrated pilot plant testing for zinc recovery from the El Boleo ore will be described. The results of this testing are currently being used to engineer the commercial plant at El Boleo.

Jan 1, 2008

By B. Wasmund, M. Parravani, M. Jastrzebski, Z. Coull

"One of the main drivers of overall profitability of pyrometallurgical vessels is refractory lining campaign life. Increased economic pressure to improve vessel life requires innovative solutions to the problem of refractory cooling. Hatch has recently developed a high-intensity, waterless cooling system that bridges the performance gap between external shell cooling and internal water-cooled copper elements. External shell cooling has a limited effectiveness in protecting the refractory lining, because it is thermally insulated from the hotface of the lining by its thickness. This situation does not improve until the lining itself has become worn near the end of the campaign. The patented technology developed by Hatch overcomes this problem by positioning high-velocity air-cooling channels within the lining, closer to the hotface where the cooling benefits can be realized throughout the entire duration of the campaign. The current paper presents the development and application of Internal Air Cooling technology as well as results from the pilot campaign in an operating commercial vessel. Various adaptations for this novel, cost-effective and inherently safe system are also discussed."

Jan 1, 2015

By Larry Hopkins

The molten metal circulation pump has become a staple for melting aluminum in reverberatory furnaces. The forced convection that is created in the melt efficiently provides circulation while dramatically improving melt rates, lowering fuel consumption, extending refractory life, and providing metallurgical homogeneity. Two metallurgical guidelines that are important to many casthouses are molten metal inclusion levels and hydrogen gas content. In order to improve molten metal quality, furnace and casting practices must 'manage these molten metal defects, Today specialized in-line degassing and filtration equipment is used downstream of the furnace to accomplish these tasks. In contrast, the molten metal gas injection pump has metallurgical contact time in the process for hours during the charging/homogenization cycle. The qualitative benefits of employing a gas injection pump to "pre-clean" are outlined and discussed against historical empirical information obtained with alternate methods. Further, a recent study quantifies the merits of this gas injection technique as an effective molten metal quality improvement tool. Specifically, the effects on inclusion level as determined by PoDFA?, gas content as determined by A1SCAN? sampling and alkali metal content as determined by spectrographic analysis are examined in relationship to various gas feed compositions and flow rates.

Jan 1, 1995

By Antonio Marinucci, Robin Mao

The new Hangzhou West Railway Station, which is currently in the early stages of construction, will be located in the city of Hangzhou, China. To accomplish the ambitious goals of the project, the construction work and station building was divided into three project areas. The original design utilizes 1,580 drilled shafts with diameters of either 800 mm or 1000 mm (32 or 40 inch) to support the new Station and its various ancillary structures. The drilled shafts will be tipped into the moderately weathered argillaceous siltstone a distance between 5 and 15 m (16.5 and 49 ft), resulting in an effective pile length ranging from 35 to 43 m (115 to 141 ft), respectively. For the first phase, approximately 550 production drilled shafts will be installed. Eight (8) sacrificial drilled shafts each with a diameter of 1000 mm (40 inch) were installed to a depth ranging from 50 to 57 m (164 to 187 ft), and were tested to confirm the design parameters used for the first phase, to evaluate the contractor’s installation means-and-methods, and to provide guidance whether redesign is warranted for the subsequent two phases. Bi-directional static load testing was performed using a donut-shaped Super Cell to apply unidirectional axial loads up to 13,200 kN (2,970 kip). This paper will describe the bi-directional testing and select results obtained therefrom. The axial compressive and uplift resistances determined from the testing verified that the available axial resistance of a single drilled shaft exceeded the minimum design requirements.