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By Masami Taguchi

"It is found that lead monoxide, PbO, has an ionic conductivity, and the all solid-state electrochemical cell using this oxide as an electrolyte has attracted the attention of battery researchers. In this study, thin film PbO2/PbO/Pb solid cells were produced on glass substrates and their discharge properties were investigated. The acti.ve material for the positive electrode, PbO2, was obtained by reactive sputtering of a Pb target in oxygen plasma. The PbO electrolyte and the active material for the negative electrode, Pb, were vacuum evaporated from /3 -PbO powder and a Pb block, respectively. The open-circuit voltage of the cell agreed with the theoretical value based on the thermodynamic data, and the close-circuit voltage was improved by the addition of a univalent impurity such as sodium or potassium to the PbO electrolyte. The connection of the cells in series and in parallel produced a higher electromotive force and a larger capacity. Also, the charge-discharge cycling test revealed that the cell could be charged and function as a storage battery.IntroductionGenerally, the ionic conductivity of a solid-state electrolyte is lower than that of a liquid electrolyte near room temperature. This has been a serious obstacle to using such electrolytes in an electrochemical cell. However, some solid-state electrolytes, which can preferentially pass a specified ion and have high ionic conductivity, have been found. Lead monoxide, PbO, which is an oxygen ion conductor, is such an example (1)(2). If a solid-state electrolyte is adopted for use in an electrochemical cell the problem associated with a liquid electrolyte such as leakage can be alleviated. The cell structure also can be simplified, because the electrolyte plays the role of separator to prevent the active materials from mixing. Thus, physical vapor deposition technology may make it possible to develop a very thin film cell, which consists of only solid phases (3)(4). In this study, the thin film PbO2/PbO/Pb solid cell with a thickness· of only a few micrometers, in which all the constituents were systematically deposited on a glass substrate by reactive sputtering and vacuum evaporation, has been produced and the charge-discharge properties were investigated. An attempt was made to improve the discharge properties by doping impurities such as Na2CO3 and Sb2O3 into the PbO electrolyte. Moreover, the connection of the cells in series and in parallel to get a higher electromotive force and a larger capacity, and the charge-discharge cycling test to determine its use as a storage battery were carried out."

Jan 1, 2000

By B. K. Mohapatra

Small manganese ore bodies in south Odisha, India occurs both as stratiform and stratabound ore bodies. These two ore bodies show contrasting mineralogical, petrographical and chemical characteristics. Stratiform type of Mn-ores consists of manganese, iron and silicate- phases in approximately same proportion. In contrast, stratabound ore bodies contain a high proportion of manganese oxides, silicates and phosphorus phases. Phosphorus is found within apatite in the stratabound ore bodies while in the stratiform ore it occurs as an adsorbed state with iron phase (goethite). Both ore bodies are low-grade (17-23% Mn) therefore do not have a market value. However, the stratabound ores are enriched in phosphorus (P2O5: >1%) compared to the stratiform ores. Both the ore types were processed through gravity, magnetic and roast reduction followed by magnetic separation techniques. The strata bound ore could be upgraded to 33% Mn from a feed of 23% by combination of dry and wet magnetic separation methods. But the phosphorus content also suits up (P2O5: 1.2%) in the processed product making it unsuitable for further use. The stratiform ores do not respond to either gravity or magnetic separation because of close association of manganese with iron phases. However, this could be beneficiated through roast reduction followed by magnetic separation. An ore with 17% Mn content could be upgraded to 40% Mn with a 42% yield and 78% recovery. The goethite, having phosphorus, converts to magnetite and is retained within the magnetic fraction, thereby reducing the concentration of phosphorus in the non-magnetic fraction, which becomes the product. This report demonstrates the influence of ore petrology in determining the up-gradational potential of manganese ore in the southern Odisha, India. Keywords: manganese ore, physical beneficiation, phosphorus rich ore

Sep 1, 2012

By Débora Cardoso de Oliveira Silveira, Jean-Christophe Huber, Hamzeh Hamadeh, Kateryna Pastel, Guillaume Brosse

The dynamic behavior of oxygen gas flow, determined by the lance nozzle and blow pattern, is a key factor for determining jet efficiency in BOF Steelmaking. The present work compares the performances of Laval and parabolic nozzles with the aid of the Computational Fluid Dynamics (CFD). The Method of Characteristics (MOC) was applied to design a minimum length parabolic nozzle. The results show that the parabolic nozzle generates more uniform and stable jet, with 2% longer potential core and supersonic length and less shock waves. For the parabolic nozzle, the pressure nearby the nozzle wall is higher, which can protect this region from reverse flow of converter gases and offer longer life for the lance tip. Likewise, the flow rate variations would affect less this nozzle. In addition, the nozzle wear was investigated, and the parabolic nozzle has proven relatively less sensitivity to the presence of this deformity.

Oct 1, 2019

By Alan Rice

Abstract-The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultramafic igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on fluid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other fields dealing with suspended loads in fluids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By Alan Rice

The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultrama?c igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on ?uid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other ?elds dealing with suspended loads in ?uids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By W. F. Baker

Location and History God's lake is in the northeastern part of Manitoba, about 400 miles northeast of Winnipeg, or about 250 miles due north of Red lake, Ontario. The lake is quite large, having an overall length of 54 miles and a maximum width of 18 miles. There are numerous islands in the lake, the largest of these, known as Elk island, being about 15 miles long and 3 miles wide in the widest part. The accompanying map (Figure 1) shows the location of God's lake and of the mine. The God's Lake area has long been regarded as promising country for the prospector, but, due to its inaccessibility, practically no prospecting was done prior to 1927. In the years 1927-1931, inclusive, a few prospectors visited the area, but no discoveries were made. In 1932, Bob Jowsey and Archie McDonald entered the area from Island lake. They first prospected in the vicinity of Knife lake, which is immediately south of the main part of God's lake, and then moved on to the latter lake, heading for the north shore of Elk island. The first afternoon on God's Lake, when looking for a place to camp on the north shore of what is now known as Jowsey island, Jowsey discovered a quartz porphyry dyke which was cut by a number of gold-bearing bluish quartz stringers. On the strength of this discovery, he and McDonald began at once to stake the Reno group of claims. Rumours of the discovery brought in other prospectors, and other groups of claims were staked to the east, along the north shore of Elk island. A second discovery was soon made by Dan McCrea on his Gold Standard claims, three and a half miles to the east of the original discovery. Staking still continued to the east, along the north shore of Elk island, and Bob Brown and Harvey McKenzie staked the Akers group on a discovery approximately two miles east of McCrea's discovery. Through the efforts of Jowsey, the Reno, Rand, Elk, and Cona groups, belonging to the original syndicate for which Jowsey and McDonald staked, were combined with the Gold Standard, Greenstone, and Akers groups, and the Company known as God's Lake Gold Mines, Limited, was formed. Several additional groups of claims were later taken over by the Company and a considerable area of adjoining ground was staked to round-out the property.

Jan 1, 1935

By R. Venugopal

Hydrocyclones have been used extensively for more than 100 years to classify mineral slurries for recirculation in grinding circuits. Sometimes hydrocyclone classification is carried out in more than one stage to improve the efficiency of classification. Factors affecting separation efficiency include fluid velocity, density, and viscosity as well as the mass, size, and density of the particles. The geometric configuration also affects its efficiency; it includes parameters like cyclone diameter, underflow and overflow diameter, position of vortex finder, height of the cyclone, feed inlet geometry, and diameter etc. Besides changes in the basic parameters some modifications in cyclone has also been introduced from time to time which have affected its efficiency, some of these are :-(i).Introduction of magnetic force along with the centrifugal and drag force to control the flow of the magnetic particles inside the chamber.(ii). Introduction of sparger, air is introduced in the chamber in the form of bubbles, to control the flow of fine particles and hydrophobic particles. (iii). Introduction of dilution technologies for the dilution of thickened underflow. (iv).Introduction of new model. In spite of wide use and simple geometry, the real working principle of hydrocyclone chamber is extremely complex because of the swirling turbulent flow inside the device. In order to get more knowledge about hydrocyclones and to increase its efficiency, past 10-15 years simulation techniques are being developed. The simulation models also enabled a deeper insight into the static and dynamic behavior of hydrocyclones. Therefore, more emphasis on simulations by methods like Computational Fluid Dynamics (CFD), Finite Element method (FEM) is given. Overall, a status review of the work carried out on the analysis of hydrocyclone performance, modeling approaches and its contribution in the efficiency of mineral processing operation is highlighted.

Sep 1, 2012

By Robert H. Ridgway

This circular outlines salient facts regarding the manganese-ore industry in the United States and the world. It is founded chiefly upon published information available in the literature of the subject. The Bureau of Mines has in its files additional, more detailed data upon many of the topics presented very briefly here, and will endeavor to assist the mineral industries and public by giving further information in response to individual inquiries. The Bureau will welcome comments, criticisms, and contributions of data that may assist in making later additions of this circular more accurate, or in developing more fully its mineral files pertaining to manganese. In reporting the production of manganese-bearing ores in the United States the following classification has been adopted by the Bureau of Mines: (1) Metallurgical-grade ores, under which have been classified manganese ores containing 35 percent or more of manganese used in the manufacture of iron and steel, ferruginous manganese ore containing 10 to 35 percent of manganese, manganiferous iron ore containing 5 to 10 percent of manganese, and manganiferous zinc residuum; (2) battery ore; (3) fluxing ores, under which are classified ores that may contain a few ounces of silver and are rich enough in manganese to make them valuable chiefly for fluxing purposes in nonferrous smelters; and (4) miscellaneous ores, under which are classified the ores shipped to brick manufacturers, glass makers, and manufacturers of manganese chemicals.

Jan 1, 1933

By N. N. Moebs

The Bureau of Mines air-sealed a 77-acre) above-drainage coal mine to evaluate sealing as a means of reducing the acid and metallic salt contents in drainage from abandoned mines. An approximate reduction in acidity of 150 ppm (equivalent to 193 pounds per day) and in iron of 98 ppm were directly attributed to sealing. The topographical, hydrological, and other factors involved in air-sealing are discussed, and the construction used to seal the mine is described.

Jan 1, 1970

By James J. Dowd

The investigation to evaluate the reserves of coking coal in the United States suitable for the manufacture of metallurgical coke is being made by the Bureau of Mines in three parts: (1) To estimate known (measured plus indicated) recoverable reserves of all coking coal; (2) to study the carbonizing properties of coals and coal blends not now widely used for metallurgical coke making; and (3) to upgrade marginal coals through effective preparation. This is the second7j of a series of reports giving the results of studies by counties under part (1) of the investigation. This report covers Indiana County, Pa., which comprises parts of the Smicksburg, Punxsutawney, Elders Ridge, Indiana, Barnesboro, Latrobe, New Florence, and Johnstown Quadrangles. (See fig. 1.) A base map for each bed in each Quadrangle was made to the scale 1 inch equals 1,200 feet. Maps of mines, locations of drill holes, bed and total coal thicknesses, and the outcrop of the bed were plotted on the maps. With all available data plotted, isopach lines were drawn to limit areas of known unmined reserves in beds 0 to 14 inches thick, 14 to 28 inches thick, 28 to 42 inches thick, and over 42 inches thick. These areas of coal reserves also were divided into "measured" and "indicated" categories. All areas in each thickness range and in each category, mined-out areas, areas excluded from the estimate, and areas outside of the outcrop were measured by planimeter on the base maps. Estimates of total reserves 14 inches and more thick and maps for individual beds were prepared from these data.

Jan 1, 1950

Prior to the merger of BHP and Billiton, both companies had a keenfocus on improving their performance in health, safety, environment and community (HSEC) matters. This shared intent, albeit executed insomewhat different ways, provided an excellent foundation for the newCompany. During the integration planning phase, a team was formed toconsider the organisational design for consistently achieving world class HSEC performance. The design included the policy platform, resources, structures, standards and procedures to be implemented in the merged entity. A key aspect of the design was the fully integrated HSECManagement Standards. These Standards create the framework for theconsistent application of BHP BillitonÆs HSEC Policy at all of ourmanaged operations across the world. The Standards have their origin in similar frameworks adopted by BHP during the 1990s, as well as thewell-known quality related standards (eg ISO 14001). However, they areunique in that they combine all aspects of HSEC management into asingle integrated set of auditable standards. By combining these areas and integrating our HSEC Management Standards with other aspects of the æBHP Billiton WayÆ, we are establishing a holistic, line management driven improvement approach. Over time, the BHP Billiton Way will embed a systematic improvement philosophy that we expect will become a key source of competitive advantage. The HSEC Management Standards are consistent with ISO 14001,OHSAS 18001, the Australian Minerals Industry Code for EnvironmentalManagement and generally aligned with SA8000. While compliance withthese external standards ensures that a systematic approach andimprovement plans are in place, BHP BillitonÆs HSEC Standards gofurther to include minimum performance requirements that reflect theintent of our HSEC Policy. Therefore, implementation at site levelensures that robust systems are in place to implement our Policy and that accreditation can be achieved to external standards if required.To assess implementation of the HSEC Management Standards anaudit system has been designed which incorporates both self-assessmentand peer review. Each site is required to undertake an annualself-assessment of compliance with the Standards using a commonassessment protocol. Every three years a peer review is conducted at each site to confirm the results of self-assessment and to provide a means of sharing knowledge throughout the Company. The review teams are composed of line managers and HSEC professionals from around theCompany, representatives of our joint venture partners and independentspecialists as required. The Company has committed to public reportingof the audit results through our annual HSEC report and this is reflected in our published targets. From a wider perspective, as we in the resources industry strive tocollectively raise our HSEC performance and reputation, there may be arole for industry based HSEC Management Standards complemented bya level of independent review.

Jan 1, 2002

By S. M. Shelton, M. M. Fine, T. L. Johnston

"INTRODUCTION The Bynum property is about 15 miles west of Gadsden and 1 mile north of Walnut Grove, Etowah County, Ala. The ore lies in layers and as irregular masses and pockets in the clay residue from decomposed quartzite and limestone formations to the district.The property has been developed by means of numerous shallow shafts sunk to water level - about 25 foot. Operations are confined to small-scale, selective mining of pockets of high-grade ore. The ore is marketed directly, without beneficiation. The property does not yield a large amount of manganese ores. No estimates of reserve ore tonnages are available.A 206-pound sample was furnished for test. It was taken at random from a stock rile estimated to contain 130 tons of ore. The sample con¬sisted of a mixture of manganese oxides, iron oxides, and siliceous fragments in clay. The manganese occurred largely as soft, unconsolidated pyrolusite and wad. Some hard, crystalline pieces of psilomelane were distributed through the soft material. Small amounts of iron oxides were associated with the manganese oxides. Chert, quartzite, and clay comprised the gangue minerals.Dry analysis of the sample was as follows: 36.0 percent manganese, 6.1 percent iron, 2: .0 percent silica, 1.5 percent calcium carbonate, 0.36 percent phosphorus, 3.0 percent alumina, 2.2 percent barium, and 0.31 percent zinc."

May 1, 1942

By José Vidalón G

El presente trabajo analiza los diversos métodos de concentración de minerales de estaño empleados en los países productores de este metal. Asimismo se describen los procesos de gravedad, se analiza la flotación de caseterita, la concentración por volatización, así como se presenta algunos diagramas de flujo ilustrativos.

Oct 14, 1980

By Forrest T. Moyer

Injury experience at metal mines and mills (excluding officeworkers) in 1964 was 60 fatal and 3,672 nonfatal disabling work injuries during an exposure time of 149 million man-hours worked. These injuries occurred at a frequency rate of 24.57 per million man-hours and had a severity rate of 3,687 days lost or charged per million man-hours. Employment at 2,363 metal mines and 291 mills, excluding officeworkers, was 68,140 men in 1964. The average number of days worked was 274 The principal cause of fatal injuries at all mines and mills was haulage accidents and in underground mines, only, was falls of ground. The principal cause of nonfatal injuries was handling material accidents. The frequency rate at metal mines and mills in 1964 was slightly below that of 1963, whereas the severity rate was higher. Injury experience at 94 primary nonferrous smelters, refineries, and reduction plants (excluding officeworkers) was 8 fatal and 999 nonfatal disabling work injuries during a worktime of 98 million man-hours worked. The combined injury-frequency rate in 1964 was 10.29 and the injury-severity rate was 1,005. The 36,956 employees worked an average of 329 days during 1964. The principal cause of injuries at these plants was handling material accidents.

Jan 1, 1968

By C. W. Owning

"The Bureau of Mines has repeatedly emphasized the necessity of completely ""rock-dusting all coal mines, except anthracite mines, in every part whether in damp or dry condition."" Every open accessible part of, the, mine without exception should be thoroughly rock-dusted, including parallel entries, air courses, trackless entries, crosscuts, and rooms to within at least 40 feet of every coal face. Very few mines have followed this recommendation and warning, with the result that there have been explosions not only in mines which have not used rock dust but also in so-called rock-dusted mines. Following a number of mine explosions it has been reported that the mine was rock-dusted,"" whereas it is probable that only some of the haulage roads had been given a hurried application of rock dust and in most instances not as much as 5 per cent of the mine was really rock-dusted. That is not rock-dusting.Some conscientious, well-meaning mining men have felt that rock-dusting of haulage roads would effectively stop an explosion; however, when shown, through widespread explosions in mines ""well rock-dusted"" according to the above method, that leaving large areas undusted, furnishes paths through which a violent explosion may travel, these mining men have realized the necessity of thorough rock-dusting and have adopted this explosion-prevention method.The Mather Collieries mine, Pickands, Mather and Co., operators, at Mather, Pa., was the first mine in Pennsylvania to receive, full credit for rock-dusting under the new 'stringent ruling of the Pennsylvania Compensation Rating Bureau, the provisions of which require that:"

Feb 1, 1931

By H. L. Gilbert

Improvements in production of high-purity chromium metal by magnesium reduction of anhydrous chlorides and by hydrogen treatment of electrolytic chromium are reported. Hydrogen-treated chromium has been arc-melted, and the arc-melted material has been successfully forged, rolled, and swaged. The material also has been forged at liquid-air temperatures. X-ray and metallographic studies indicate the recrystallization temperature of rolled chromium sheet to be about 750° C. Preliminary investigation of hot-bending characteristics of rolled chromium sheet shows the minimum bending temperature to be about 325° C. The heat resistance of chromium has been investigated.

Jan 1, 1952

By Robert Rennie, Taylor Davies, Ahsanul Rafi

Electric locomotives powered by extensive electrical cabling systems were prevalent in the mining industry in the early days of the 20th Century [1]. Since the movement of tethered electrical mining locomotives was limited, the advent of diesel-powered mobile mining equipment provided more flexibility. This led the mining industry to be dominated by diesel-powered locomotives for most of the 20th Century and the entire 21st Century, to date. However, diesel power has certain drawbacks. Diesel-powered vehicles produce tailpipe emissions such as diesel particulate matter, carbon dioxide, sulfur dioxide, and nitrogen oxide. Mine workers exposed to these emissions were, and continue to be, subject to health issues such as respiratory problems, increased risk of lung cancer, and cardiovascular disease. [2][3]. Extensive ventilation systems are required to dilute the diesel exhaust and dissipate the heat generated by these vehicles. Moreover, as mines are getting deeper due to depleting resources, ventilation costs in diesel-powered mines are becoming increasingly high. These factors, coupled with the trend towards greenhouse gas (GHG) reduction in mine operations, has allowed zero-emission electric locomotive systems to gain traction. As lithium-ion battery technology is becoming more advanced, battery-powered electric vehicles can now perform duty cycles comparable to those of diesel-powered vehicles. Although battery-electric vehicles (BEVs) are comparable to diesel-powered vehicles in terms of mobility, they have certain limitations. For instance, the amount of onboard energy is limited by the battery energy density and specific energy. The MT42 diesel haul truck from Epiroc, for example, has a fuel tank capacity of 580L, which is equivalent to around 1450 kWh of net electrical energy [4]. The electrified version of the MT42, on the other hand, has an onboard battery with 375 kWh of usable energy weighing around 4.9 metric tonnes [5]. Moreover, storing and refueling of diesel-powered vehicles is simple and quick, whereas battery energy storage and charging systems require extensive infrastructure development. Charging time is mostly limited by battery chemistry and design. Due to these limitations, the benefits of battery-powered mining vehicles are more likely to be realized with proper planning and optimization of the BEV fleet. This includes optimizing mining layouts for BEV use, charging infrastructure design, and management of onboard energy storage systems.

Jun 25, 2023

In traversing lately the Sierra Madre, west of Sail Pedro and Guanacevi, I estimated the topographic summit at several points, by aneroid barometer, at about 8,500 ft. Mr. Weed's measurements, 40 miles further north, are from 9,000 to 9,500 ft., and indicate the correctness of the impression I obtained at the time, namely, that the greatest movement in the elevation of the Sierra was between Guanacevi and Guadaloupe y Calvo. This is suggested also by the course of the headwaters of the Rio Conchas and of the Nazas, and by the relative corrasion of the branches of the two streams. Mr. Weed's statements as to the unevenness and great relief of the andesite floor underlying the later dacites and rhyolites are very interesting, and lead me to add that the floor of the andesite breccias and flows is uncovered for several square miles east of Guanacevi. This floor is of reddish, bluish and gray shales, lying horizontal or dipping slightly east. Their age is unknown; but from the interbedded occurrence of copper sulphides, I took it to be Triassic,

Jan 1, 1903

By M. C. Malamphy

A general description of the activities and results of bauxite investigation by the Bureau of Mines at its bauxite project in Saline and Pulaski Counties, Ark., has been given in Report of Investigations No. 4251. The factual data obtained during the project are reported in a series of Reports of Investigation beginning with No. 4251, of which this is the seventeenth. The data are accompanied by maps showing the location of holes drilled and the deposits developed. Each area upon which work was done is reported by half townships. Each bauxite deposit investigated was assigned a name and a number for ready reference and identification, and its location and name are shown on the appropriate half-township map. The description of each half township is followed by a description of each deposit developed in that half township. The 14 half-township maps and 77 detail maps of the bauxite deposits in this series of reports give the locations and numbers of all the holes drilled on the project, except the deep holes drilled to test the geophysical anomalies. The locations of those holes show on figure 13 in volume 1. The descriptions of the deposits developed are followed by complete detailed logs of the drill holes.

Jan 1, 1948

By F. Turatti

Rio Tinto is one of the world's largest mining companies, involved in every stage of metal and mineral production, producing aluminium, copper, diamonds, coal, iron ore, uranium, gold and industrial minerals. Operations are in more than 50 countries in multiple continents and vary in location between large urban centres, regional industrial complexes and remote regions. A risk-based strategy was developed by Rio Tinto to manage its air quality impacts on a global scale. The strategy consists of three objectives ? improving air quality performance, developing industry leading practices and engaging and influencing in air issues. This paper discusses three major successes achieved this approach. Firstly, how air shed resources are managed in constrained air sheds. Secondly, how financial modelling is used to value air quality constraints, and thirdly, how a rigorous and comprehensive e-learning course is used to improve the overall level of air management knowledge of Rio Tinto?s environment managers.

Feb 27, 2013