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By R Higashi, D Maruoka, T Murakami, Y Iwami

The ironmaking industry consumes a large amount of fossil fuel derived carbon as heat source, reducing agent of iron ores and carburising agent of reduced iron. Although the demand for drastic decrease of carbon dioxide emission, carbon is an essential element for smelting process of molten iron. The carbon recycling ironmaking process by circulating CO has been already proposed to achieve carbon neutrality. However, the production of molten hot metal is not considered in this process because sufficient amount of carbon does not dissolve in reduced iron by CO. Therefore, our group has suggested a new carbon recycling ironmaking process which can produce hot metal. In this process, free carbon and iron carbides produced by carbon deposition reaction using metallic iron as a catalyst are used. It is known that only Fe3C is obtained as iron carbide by using CO gas, however, Fe5C2 is also produced by adding H2 gas. The composite agglomerated with these carbonaceous materials and fine iron ore (Deposited Carbon-Iron oxide Composite: DCIC) is reduced and melted in a furnace. It is reported that Fe3C in DCIC accelerates the reduction reaction and melting of the composite. In this study, the effects of iron carbides and free carbon on the melting behaviour of DCIC are investigated. Fe3C, Fe5C2 and free carbon were produced by vapour deposition using porous iron whiskers and CO-CO2-H2 gas. These were agglomerated with hematite reagent at a certain ratio to prepare DCIC samples with and without Fe5C2. The samples were heated up to 1300°C in inert atmosphere. The DCIC containing Fe5C2 completely melted and iron nuggets were obtained after the experiment. This behaviour was not observed in the composite without Fe5C2. This indicates that using Fe5C2 is more preferable than Fe3C for molten iron production using DCIC.

Jun 19, 2024

By Magnus Troilius

The method of using the bromine process of determining sulphur in steel, described below, is in successful use at the Midvale Steel Works. Ten grams of drillings are weighed out and put into the 1/2-liter flask A, with long neck. The flask is connected with a wide glass tube C', which, in its turn, is connected with the absorption bulbs B, containing HCI, 1.12 specific gravity, and ahout 5 C.C. of bromine. The wide tnbe C causes the vapor to condense and flow back into the flask A during boiling. The bulbs B connect with a long glass tnbe, which may be made to carry off the bromine fumes through a hole in a window, or, better still, through a flue with powerful draught. The connections being made, 100 C.C. of boiling water are run in through the thistle tube T. The air is thus completely driven out of the flask. 100 C.C. of HC1 (about 1.19 specific gravity) are then run in. When the gas begins to run rattler slowly through B, heat is applied until boiling gradually ensues. The steel being completely dissolved, the apparatus is disconnected, and the contents of B rinsed out into a beaker of 100 C.C. capacity, into which a few C.C. of a concentrated solution of BaCI, have been previously introduced. Heat is then applied (best by means of the hot iron plate) until the bromine is completely driven off and the BaSO, has settled nicely to the bottom. The BaSO4, is then filtered off on a small

Jan 1, 1884

By Xihuai Gong, Hongshuang Di, Jianping Li, Ning Yan

In this work, we investigated the effect of the rolling process (warm-rolled or cold-rolled) on microstructure evolution and mechanical properties of 9Mn steel. After intercritical annealing at 670°C for 10min, both cold-rolled and warm-rolled microstructures are composed of ultra-fined austenite and intercritical ferrite. The austenite in warm-rolled sample includes two types of morphology, namely equiaxed and lamellar, which exhibits a wide distribution of grain-size. The incomplete recrystallization or recovery behavior of ferrite in warm-rolled and annealed sample results in higher yield strength and shorter yield point elongation. Moreover, the warm-rolled and annealed sample extends the TRIP-related work hardening over a broad strain range, resulting in a better combination of ultimate tensile strength and total elongation.

Oct 1, 2019

By Benjamin Kohler, Amelinda Olson, Marc Snyderman, Chanaka De Alwis, Mike Lewis, James Cox, Matthew Call, Julia Kluck

UTRS Inc. has developed a novel two-step method to extract commercially viable titanium alloys (patent pending no. 20130164167[1]). This approach has proven its potential to produce a variety of titanium alloys (Ti-6Al-4V,Ti Al ,etc.,) x y and has demonstrated a number of advantages over the current commercial titanium production process. Additionally, the UTRS Process operates without producing CO2 and eliminates the use of TiCl. Step 1: Aluminothermic reduction makes available many types of ores that could otherwise not be used. Due to the aluminothermic reduction technique and the composition of the ore,metal extracted from this step will inherently contain non-titanium elements. Step 2: Electro-refining removes undesirable elements from the thermally extracted titanium. This refined metal has a dendritic morphology with a wool-like appearance that is referred to as “titanium wool”. This new morphology of titanium allows it to have a diversity of endproduct types from titanium powder to bulk titanium.

Mar 1, 2017

By Wenjun Duan, Zhimei Wang, Tianwei Wu, Qingbo Yu

In order to recover the waste heat of molten blast furnace slag, a reactor with top-submerged lance was established. The numerical simulation and experiment study of the flow characteristic in the reactor were conducted. The mathematical model of reactor was established and the Euler-Euler model was employed to simulate the gas-liquid flow in molten slag bath. Meanwhile, the experiment results were obtained and compared with the simulation to testify the accuracy of the established model. According to the bubble behavior in bath, there were four stages: initial expansion stage, bubble detachment stage, freedom lift up stage and bubble broken stage. When the flow field in bath fully developed, the gas fraction decreased with the increasing of bath depth. During injection process, the area near the nozzle and lower the bath would first generate two symmetric heliciform flow regime, and then the flow regime in whole bath would become irregular because of bubble lifting up and rupturing. The gas fraction in bath, the average velocity and turbulence energy of slag would decrease before it increased to maximum and then it would keep fluctuate in a range.

Mar 1, 2018

Geophysical Abstracts 1 - 86 were issued in mimeographed form by the Bureau of Mines; Abstracts 87 - 111 were published in bulletins of the Geological Survey; Abstracts 112 - 116 were issued in mimeographed form by the Bureau of Mines as Information Circulars 7256, 7257, 7267, 7273 and 7285. 1. GRAVITATIONAL METHODS 7380. Dryden, H. L. A reexamination of the Potsdam Absolute Determination of Gravity. Jour. Research Nat. Bureau of Standards, vol. 29, No. 5, 1942, pp. 303-314.

Jan 1, 1944

By R. D. Brown

For the first time in years, the spring budgets of federal and provincial governments have not brought down major new proposals affecting the tax burdens of the mining industry in Canada. It seems appropriate to use this unaccustomed period of tranquility to set out an extremely abbreviated summary of the principal features of the federal and provincial income and mining tax rules affecting the mining industry.

Jan 1, 1977

By Oliver Bowles

"The manufacture of asbestos paper began commercially about 40 years age but its principal development has taken place during the past twenty-five years. The asbestos used by the ancients, termed amiantus by Pliny was used for winding sheets, tablecloths and other fabrics. It was probably chrysotile fiber and was a woven and not a felted product, and there¬fore is not to be confused with asbestos paper. There are, however, some early references to paper manufacture that are of interest. Pontoppidian, Bishop of Bergen, in his Natural History of Norway, published in 1750, refers to paper made from asbestos found in the parish of Waldens. He states that this paper did not burn when thrown in the fire, but the writing on it totally disappeared. This indicates that the primary ob¬ject was to obtain an indestructible writing paper. About 100 years later, further efforts were made with the same object in view. In 1853, a patent was issued for a process of making paper from a mixture of asbestos and alum. Many experiments were made to manufacture suitable asbestos printing paper. Some such papers contained only about one-third asbestos, the remainder being of combustible material. Such papers would burn, but would leave a white residue which retained its shape and preserved the written characters. On account of the difficulty of obtaining a smooth and even surface, and the tendency for the material to absorb ink like blotting paper, asbestos paper is not well adapted for writing or printing purposes. Other early uses of asbestos paper were for ornamental wall-paper and carpet linings. None of the uses mentioned above have developed to anything of importance in a practical way, but the manufacture of asbestos paper has become a very important industry, and it has found extensive uses in ways that were never dreamed of by the early investigators.It is recorded that the first sheet of asbestos paper made in America was manufactured in 1876 by John Roberts & Son Company, in a mill near Waltham, Mass. The material first used was a long-fibered amphibole asbestos from Italy. About three years later, Canadian fiber was introduced and proved to be very satisfactory. The shorter grades of fiber which would otherwise be wasted were used for the manufacture of paper and board. For several years, the product of this mill was sold through Rice Kendall of Boston, Mass. From 1881 to 1900, the H. W. Johns Company, of New York, took the entire product which was 30C to 700 tons per year. The latter company built their own asbestos paper mill at Brooklyn in 1900. Keasbey & Mattison Company, of Ambler, Pennsylvania, began to manufacture in 1897. Other early manufacturers were: the Asbestos Paper Company, at Baldwinsville, Mass„ and Mr. B. S. Binney, at Shirley, Mass. The number of manufacturers gradually increased until at present asbestos paper is manufactured by the following ten companies:"

Nov 1, 1919

By WALDEMAR T. SCHALLER, EDWARD P. HENDERSON

THE material available for mineralogic study, consisted of drill cores, 2 to 3 in. thick, supplemented by small well cuttings. Such study has added no essential new information regarding the minerals, though the refractive indices, used for determinative purposes, have been determined more accurately than before, permitting the development of a scheme for the rapid identification of these minerals. The essential points brought out by the investigation are two: (1) that certain mineral associations evidently point the way to an understanding of the geologic history and (2) that a definite sequence of mineral formation has taken place so that the original minerals formed have been in part-reacted on producing new compounds and associations; Twenty minerals have been found. The most important are :

Jan 1, 1929

By Collin L. Stewart

Published subsidence data for the western United States is limited in comparison with data for the east. This paper summarizes the results of a subsidence monitoring program above two longwall panels at the Foidel Creek Mine located in northwest Colorado. The monitoring area is characterized by overburden ranging from 1000 ft to 1100 ft in thickness. The surface slope parallels the dip of the bedding at approximately 5 deg. Average mining height is 9 ft. Smax averaged 3.4 ft. Draw angles averaged 15 deg for up-dip ribsides and 19 deg for down-dip ribsides. A site-specific profile function is developed from the data.

Jan 1, 1986

By R. Elliott, H. Bayati

"Effect of time and temperature on microstructure and mechanical properties of an austempered ductile iron, ADI, of composition 3.6%C, 2.6%Si, 0.4%Cu, 0.2%Mn are reported. Xray analysis and. microstructural observations indicate that lowering the working temperature, aging temperature, increases the lifetime of ADI significantly. Results show· that lowering the aging temperature increases the strength and reduces the ductility of ADI. DSC traces for ADI austempered at 340°C are presented. Comparison of the DSC analysis and kinetic measurements demonstrates that the DSC traces can be· used to predict the life time of ADI successfully.IntroductionAustempered ductile iron, ADI, is one of the most significant developments in cast iron technology over the past two decades. Outstanding properties of high yield, ultimate strength, ductility, fatigue and wear· resistance make ADI suitable for a range of applications including gears, connecting rods, crankshafts and agriculture machine components. The austempering reaction in cast iron occurs in two stages, Fig. I, in contrast to the single stage reaction in steel. In stage I the relatively low carbon austenite produced during austenitising transforms into ferritic plates and high carbon austenite, a metastable structure called·ausferrite. The high carbon ailstenite and supersaturated ferrite produced in stage I decompose into ferrite and carbide in stage II: to form a structure similar to the bainitic structure in steel. This behaviour exposes a well-defined processing window, t1 - t2, over which the maximum amount of ausferrite is produced, Figure 1. Whereas the bainitic structure determines the properties of austempered steel, ADI properties are mainly affected by volume fraction of retained austenite (VRA), austenite carbon content (ACC), unreacted or martensite volume fraction (UA V), compositiori and amount of carbides, and morphology of ferritic plates[l,2]. Due to the detrimental .effect of martensite and carbides on properties of ADI, an ideal structure of ADI consists only of ausferrite [l,2]. Thus, it is common to determine the processing window for each austempering treatment in order to identify the optimized austempering time. Decomposition of austenite (stage II) signals the end of the life time for an ADI component, therefore, the aging behaviour of ADI at different working conditions can be studied by determining the t2."

Jan 1, 2000

By K. K. Kelley, W. W. Weller

Heat capacity measurements of akermanite ( Ca,MgSiO ) , cordierite (Mg2A14 Sig018 ) , gehlenite ( Ca₂Al₂ SiO ) , and merwinite ( Ca ,MgSiO ) were conducted over the temperature range from 50 ° to 298.15 ° K. The entropies at 298.15 K ( expressed in cal / deg mole ) were evaluated as follows : Akermanite , 50.0 ± 0.5 ; cordierite , 97.3 ± 0.9 ; gehlenite , 47.4 ± 0.4 ; and merwinite , 60.5 ± 0.5 . All four compounds have positive entropies of formation from their constituent oxides at 298.15 ° K ; the values range from 4.6 cal /deg mole for akermanite to 10.1 cal / deg mole for cordierite .

Jan 1, 1963

By Chang Wei, Zhigan Deng, Minting Li, Cunxiong Li, Gang Fan, Xingbin Li

Iron precipitation occupies a vital position in the metallurgy industry, especially for treating iron-bearing sphalerite in hydrometallurgical processes. This paper emphasizes techniques for removing iron from high-iron sphalerite via hematite precipitation, and describes the results of research performed to examine ferrous oxydrolysis and precipitation. The behavior and mechanism of conversion between the iron phase and hematite residue at elevated temperature under pressure is ascertained by investigating the dissolving characteristic and thermodynamics stable area of hematite at sulfate system. The results show hematite precipitation went through the process of crystallization, dissolve, oxidation and precipitation of ferrous sulfate, and the overall iron precipitation was determined to be controlled by the rate of ferric sulphate hydrolysis rather than the oxidation of ferrous sulphate or the re-dissolution of ferrous sulphate crystals, or the transformation of basic ferric sulphate.

Mar 1, 2018

By Gordon Lewis

A complex mixture of hydrated reaction products is obtained from hydrothermally treated refractory cements and castable concretes. TGA can be used both to identify the product phases in the mixture and to determine a quantitative relationship among the phases. When reacted mixtures contain compounds that decompose simultaneously, or nearly so, additional assumptions must be introduced in order to develop a quantitative phase analysis. It is the purpose of this paper to examine some of these assumptions and to demonstrate their application, particularly to refractory cement systems.

Jan 1, 1982

By R. A. Burns

The production of kaolin and calcium carbonate in North America exceeds 13 million tons sold into higher value market segments. With a few exceptions, the markets supplied exhibit mature growth rates. In some market sectors, technology changes have and continue to occur shifting pigment-type consumption and growth. New sources of supply will impact current businesses. New product and process developments for kaolin and calcium carbonates are continuing. Each of these issues is examined in developing a view of the future for kaolin and calcium carbonate in North America.

Jan 1, 1997

By H. J. Seaman

The cost of keeping platinum ware in repair becomes such an important item in laboratories where much fusion-work is done, that a method of saving in this direction may not prove unacceptable to at least some of the members of the Institute. Some two years since I had the misfortune to puncture an almost new Bishop crucible. As an experiment I endeavored to patch it, and with such success that it is still in constant use. This may be accomplished in the following manner : The crucible and patch, which should be of stout foil, are rubbed bright with silica, or rotten-stone; a light platinum wire, welded to a corner of the patch, and the whole treated for several hours with hot concentrated hydrochloric acid; after which they are thoroughly washed with distilled water and dried. The head of an ordinary iron rivet, 4 inches by $ inches, is rounded off by hammering to somewhat the shape of the crucible. This is sunk 2 inches in a block of hard wood, and firmly wedged in place. This serves for an anvil. The hammer is an ordinary cast-iron toy, 11/2 inches long, and # inches in face, mounted on a 4 inch iron rod, 10 inches long. A gas-blowpipe is fixed in a horizontal position, and the strongest heat obtainable with it directed upon the rivet head; this soon at-

Jan 1, 1885

By Steven E. Mischler, Jay F. Colinet

The Mine Safety and Health Administration (MSHA) promulgated a rule in 2014 that required numerous changes in compliance dust sampling requirements for coal mine operators. Two key parts of this rule were the lowering of the respirable coal mine dust standard from 2.0 mg/m3 to 1.5 mg/m3 and requiring operators of underground coal mines to use a continuous personal dust monitor (CPDM) for compliance sampling. The CPDM currently approved for compliance sampling is equipped with a display that provides miners with in-shift information on their respirable dust exposure. The goal was to provide an indication of a potential overexposure and empower the miner and mine operator to implement changes in controls and/or operating practices to prevent an overexposure from occurring.

T. Kirke Rose, London, Eng. (communication to the Secretary*) :—The authors have shown that, under certain conditions, the rate of dissolution of gold by chlorine and bromine is reduced by the addition of 10 per cent. of silver to the gold, and that the action is almost stopped when the silver amounts to 30 or 40 per cent. of the alloy. Even if full recognition is given to the practical way in which the work was done, however, it is to be regretted that Prof. Hofman and Mr. Magnusou did not determine the temperature at which the experiments were carried out. From the details given, it may be inferred that the temperature was raised by chemical action by about 20' C. when 21 g. of sulphuric acid was added, and that the mixture was then slowly cooled down during the experiment. When bromine or very weak chlorine solutions were used, there could not have been any perceptible heating-action. As the action of both chlorine and bromine is aided by heat, it follows that the stronger solutions of chlorine were given an unfair advantage over the weaker solutions, and over bromine. If the temperature had been the same in each case, I do not think that the conclusions deduced by Prof. Hofman and Mr. Magnuson' would have been found to be justified. (This is speaking generally. In barrel-treatment the conditions are similar to those in the experiments.) The superior speed of bromine as compared with chlorine at equivalent strengths is not yet disproved, and the differences noted between strong and weak solutions of chlorine may have been largely a function of the temperature. Moreover, the authors used somewhat-coarse particles of gold, and did not try how far time was a factor, although it is obvi-

Jan 1, 1906

By James Warren Andrews, Philip C. Nyberg

The regulation of exposure of underground personnel to radon and its daughter products has significantly changed since the 1950's. The U.S. Bureau of Mines - Mining Enforcement and Safety Administration (MESA) - Mine Safety and Health Administration (MSHA) sequence of standards and regulations have lowered the maximum allowable occupational exposure and now the new Environmental Protection Agency (EPA) National Emission Standards for Hazardous Air Pollutants, effective in 1990, have further regulated uranium mine emissions. Under the authority of Section 112 of the Clean Air Act (42 U.S.C. 7401), the EPA has set regulations for the control of radon (Rn-222) emissions from underground uranium mines as well as other sources. Since the venting of radon from the mine atmosphere to the outside air is a major component of the miner's protection, and since this is the first quantitative effort to limit gaseous mine emissions to the environment, it was felt that it would be useful to examine the implementation of the EPA regulation at working mines. The concern was not only for determining compliance with the regulation but also for observing what effect the rule might have on mine air quality and thus on worker exposure. The regulation is stated in terms of the maximum permitted radiation dose to the closest potentially exposed individual, which is calculated from a computer program supplied by EPA and radon emission rates measured by the mine operator. Relative proximity to nearby populations determines the allowable magnitude of mine exhaust ventilation emissions. For some mines this is a serious operational constraint.

Jan 1, 1991

By C. Dalton, H. L. McGill

The purpose of this study was to develop a method for predicting the time delay created by metering a fluid through an annular restriction with translational motion of the boundaries. This time delay is utilized to control the opening of valves in various down-hole oilfield tools and forms the basis for the "hydraulic jar". The hydraulic jar is used to give upward impact forces to tubing or other tools that become lodged down-hole. The design of these jars has primarily been by trial and error; varying the clearances, fluid viscosities and dimensions of the jar until a satisfactory time delay was achieved. Obviously, a better understanding of the fluid flow characteristics is required to produce designs that are satisfactory and to eliminate the trial-and-error approach. Previous studies of flow in annular spaces were based on constant length of the annular restriction. Any motion of the boundaries of the annular space was confined to a rotational motion, like that encountered in journal bearing design. Consideration of the effect of translational motion of one boundary with respect to the other was necessary in applying this previous work to a time delay device. A prediction method was developed that takes into account this relative translational motion. Equations were developed to predict the relative velocity, the flow rate, and the time delay in a concentric annular space. The effect of eccentricity also was included. Experimental data were obtained and closely correlated with the prediction method. This correlation is presented graphically in terms of predicted and actual relative velocities for various annular clearances and pressure drops. This extension provides design equations which predict the performance of the hydraulic jar, thereby eliminating trial-and-error solutions and reducing the development time required for satisfactory designs. INTRODUCTION The design of down-hole oilfield tools which use hydraulic delay systems based on flow through annular orifices with relative motion of the boundaries is usually a trial-and-error process. The annular clearances, fluid viscosities and dimensions of the mechanisms were varied until satisfactory delay times were obtained. The development of these tools has been expensive, and a better understanding of the characteristics of annular flow with relative motion of the boundaries could result in superior and less expensive designs. The purpose of this investigation was to provide a method of predicting the performance of down-hole tools which use annular flow and, in particular, the performance of a down-hole tool known as the "hydraulic jar". The hydraulic jar is used to free pipe, packers and other tools that become lodged down-hole. The jar, located in the tubing string between the surface and the object which is stuck, releases the object though the repeated application of upward impact blows. The jar is basically a slip joint that is restrained in a collapsed condition until the desired tubing tension has been developed. The slip joint is then released and accelerates rapidly until it shoulders, delivering an impact blow or jar to the object. The delay obtained by metering the fluid through the annulus formed by the jar valve and housing provides the time delay necessary to stretch and apply tension to the tubing or pipe. Fig. 1A gives a schematic diagram of the hydraulic jar and brief details of its operation. The metering of the hydraulic jar begins when the tension force being applied to the jar by the pipe creates a pressure differential across the valve that is approximately equal to the force divided by the displacement area of the valve. This pressure differential induces flow through the annular restriction formed between the valve and housing. The valve moves with respect to the housing as the

Jan 1, 1969