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By R. L. Dalton, L. A. Rapoport, C. W. Carpenter

Procedures have been developed to study the performance characteristics of unconfined pilot water floods using scaled laboratory models. The effects of operating conditions on pilot performance for variozrs well patterns have been investigated. The limitations of the laboratory model studies are outlined. Relationships between the oil recoveries of pilots and large-scale floods have been established. The applications of model studies to the prediction of large-scale waterflood performance and pilot flood design are discussed. INTRODUCTION Pilot water floods are undertaken to evaluate operational procedures and to gain advance information about the performance of an extensive water flood. In general, however, the performance of a pilot flood is not directly indicative of what can be expected from a large-scale pattern water flood. This difference stems from the fact that the over-all flow configurations are not the same for the two systems. A water flood normally consists of an array of identical well patterns. In such an array, the perimeters of the well patterns are axes of symmetry and act as impermeable boundaries. Thus, an extensive, pattern water flood can be visualized as a repetition of "confined" floods. In contrast, a pilot water flood involving only one or a few well patterns is "unconfined". Here the well patterns are not balanced by other flood units; hence, the perimeter of the pilot area does not act as an effective boundary. Accordingly, only a portion of the fluids injected (and also of those originally contained within the pilot area) is captured by the producers of the pilot. The rest escapes into the surrounding reservoir. This usually causes the amounts of oil and water produced in the pilot to be different from those recovered by a producer in an extensive water flood. Moreover, the recovery observed in the pilot can be expected to be greatly influenced by operating conditions, i.e., by the bottom-hole pressures at the injection and producing wells. The above considerations show that full utilization of pilot test results and reliable prediction of large- scale water floods require a knowledge of the relationship between the recovery performance of confined and unconfined well patterns. To date, only limited basic information is available on the behavior of pilot water floods. Craig, et al,' have investigated the effects of initial gas saturation, oil-to-water mobility ratio, and well damage on the oil recovered from a single, "normal" five-spot pilot pattern (Fig. 1). Rosenbaum and Matthews2 studied the effect of initial gas saturation and mobility ratio on the ratio of production rate to injection rate for various groupings of five-spot patterns. Paulse113 investigated the effect of mobility ratio and distance from the pilot to the edge of the reservoir on the areal sweep in a single "inverted" five-spot (Fig. 1). However, none of these studies considered the effect of operating conditions on pilot flood behavior. Moreover, hardly any of the work to date dealt explicitly with the oil-recovery performance of the pilot floods. The purpose of this paper is to introduce the concept of interrelation between pilot flood behavior and operating conditions, to illustrate this interrelation by means of experimental data and to compare the recovery performances of dif-

By M. Karmis

For several centuries surface subsidence has been recognized as an inevitable consequence of most underground mining. In fact, British court records of disputes and litigations related to property damage due to mining subsidence can be traced to the early fifteenth century (Shadbolt, 1978). The first systematic investigations of the mechanisms involved in mining subsidence can be credited to Belgian Mining Engineers. The re- search effort was initiated after the widespread movements and the resulting structural damages suffered by the City of Liege in the 1920's. The publication of Gonot's 1871 treatise "Loie de la NomZ" (normal theory) was one of the most not- able achievements of the Belgian school of that era (Gonot, 1871). During the past 100 years the phenomenon of mining subsidence has been the subject of intensive research, particularly in Europe where long- wall is the most common method of underground coal mining. Many theories have been advanced to explain the mechanism of ground movement as it develops from the excavation, through the superincumbent strata, to the surface. Such theories include the original concepts of beams, arches, domes and the contemporary mathematical modeling principles of strata movement assuming two extreme concepts-- a continuous elastic medium and a stochastic medium for the superincumbent strata. An excellent review of the development of these theories ?-s given by Shadbolt (Shadbolt, 1978). In conjunction with the theories of mass strata movement in the vicinity of mine workings, the subject of surface subsidence predictions has also been the subject of extensive research. The development of reliable and rational techniques of subsidence prediction is imperative, if this phenomenon is to be recognized and controlled within acceptable environmental levels. Empirical as well as mathematical methods have been proposed to fulfill this objective and a comprehensive analysis of these methods has been presented in the literature (Bramer, 1973; Shad- bolt, 1978; Virginia Polytechnic Institute and State University, 1980). As a result of this intensive research effort, it is now accepted in many )coal fields-- mainly in Europe-- that the state of art in subsidence prediction and control has approached a level where mining induced surface displacements can be predicted to a suggested accuracy of less than + 20 percent. Furthermore, such movements can be translated into anticipated structural failures using established damage criteria, thus enabling appropriate precautionary measures to be implemented. In this country, subsidence is rapidly gaining emphasis as an important environmental problem of underground coal mining. Damage resulting from this phenomenon ranges from land settlement to severe structural damage and has been witnessed in rural (Illinois, Colorado, West Virginia, Virginia, Pennsylvania) as well as in urban areas (Pennsylvania, West Virginia, Illinois, Wyoming). Yet, the art of subsidence prediction and hence control in this country, for both longwall and room-and-pillar coal mining, is far from approaching the maturity reached by the Europeans. In this paper, field measurments and computer modeling techniques have been used to develop some basic relationships of longwall subsidence and its related parameters. Because the objective of this study was to develop regional subsidence trends, all processed information pertains to the Appalachian coal region.

Jan 1, 1981

By H. T. Clark, S. Feigenbaum

THE importance of measuring the temperature of molten steel in the open-hearth furnace has been recognized for many years. Poor temperature control may be costly to steelmaking operations and lead to a lowered quality of the steel. Low or excessive temperatures may shorten the life of the furnace, ladles and molds. Rates of reactions in the furnace and efficiencies of deoxidizers are known to change materially with a change in the temperature of the metal and slag. Ladle skulls and mold and stool stickers cause steel to be scrapped instead of being converted into useful products. Finally, the structure, segregation and surface condition of ingots are affected by the teeming temperature. Mill investigations of the effect of bath temperature upon steelmaking operations have been largely qualitative in character, based upon observations by practical melting men. The physical chemist has used the empirical information available and has reached reasonable and useful conclusions with respect to the various melting processes. The introduction of a reliable direct- reading pyrometer will permit accurate quantitative evaluation of the effects of temperature and should furnish a more rational basis for study of the thermo- chemistry of steelmaking. The problem is not merely one of making a small number of temperature measurements in the open-hearth furnace. This has been done by several methods to a degree of precision that was apparently satisfactory. Considerable effort by a number of investigators has been directed rather to the development of an open- hearth bath pyrometer that would be both accurate and practical for routine measurements. To be practical, the pyrometer should be inexpensive to operate; that is, the installation, operating and maintenance costs should be exceeded by the tangible benefits to the open-hearth operator. Temperatures from 2800° to 3100°F. are encountered in the open-hearth furnace. The surface of the molten metal is covered by several inches of slag, which prevents direct observation of the metal surface for optical or radiation measurements. Both slag and metal are highly reactive at these temperatures and will attack to a greater or lesser extent any material immersed in them. Adequate protection of thermocouples, which of necessity must be brought to the temperature of the bath, has generally resulted in a large, heavy assembly made up of .brittle materials, unsuited for handling on the open-hearth floor. The lie of the equipment was short and maintenance was an important consideration. EARLIER WORK Any one of a number of physical proper- ties of liquid steel could conceivably be used as a basis for temperature measurement. Efforts to the present time, however, have been confined largely to measuring either the thermal electromotive force generated between two dissimilar materials immersed in the steel or the intensity of radiation from the surface of the steel. These

Jan 1, 1946

By John W. Padan, John E. Crawford

Beginning with a small but positive participation in undersea mining, the Bureau of Mines continues its active investigations into this potentially tremendous field. The Bureau began its active role in undersea mining in September 1963, with a small task force of three dedicated scientists and a secretary, establishing headquarters at the old Tiburon Naval Net Depot about seven miles up the coast from San Francisco. The past months have been both busy and productive. With 22 Federal agencies involved in oceanography, it logically was the intent of Congress that the Bureau of Mines undertake research concerned only with the technology of marine mineral production and utilization. The Bureau has maintained this purpose in its activities at Tiburon, for while institutes, universities, the Navy and other Government agencies have developed exceptional programs in the fundamental science of the oceans, commonly called oceanographic research, little has been done toward advancing man's ability to exploit the ocean floors other than by drilling for oil and gas and sulfur.

Jan 3, 1965

By Rudi Podjadtke

In a short chronological review the development concepts and improvements in steel roadway support are shown. The successful standardization concept of RAG Deutsche Steinkohle and currently used support systems are important topics. The history of optimizing the material properties for the steel arch support with different alloys up to the tempering used today is discussed. The present-day application of the steel support is additionally presented. Today, it represents a system component of modern roadway support also for highly stressed roadways. In addition to the yielding roadway arch support, this overall system - the combination support - consists of the additional components of a rockbolting system and concrete backfilling. The comparison of the application areas for each individual partial system with the overall system illustrates its high performance capability. Actual practical experience with the state of the art typed steel arches are pointed out exemplarily. Understanding the complete system permits the selection of the economically optimal support for all conditions.

Jan 1, 2008

By Alice Barreto Bevitori, Felipe Perissé Duarte Lopes, Denise Cristina Oliveira Nascimento, Sergio Neves Monteiro, Isabela Leão Amaral da Silva

"The piassava fiber is one of the most rigid natural lignocellulosic fibers, which has since the last decade been investigated as possible reinforcement for polymeric composites. In the present work, the tensile properties of polyester composites reinforced with piassava fibers with thinner diameters were investigated. Composites with volume fractions up to 30% of continuous and aligned piassava fibers were tensile tested at room temperature to evaluate the ultimate strength, elastic modulus and total strain. For each volume fraction, individually separated fibers with the smaller diameters were tested. The results indicated that the tensile properties tend to improve with increasing volume fraction of the thinner piassava fibers. The role played by the fiber/matrix interaction was analyzed by scanning electron microscopy.IntroductionA significant change in the transportation sectors mainly the aerospace and automotive, occurred last century with the introduction of stronger and lighter materials. The most relevant example was the polymer composite reinforced with synthetic fiber. They are nowadays replacing conventional materials such as the aluminum alloys in airplane body owing to superior specific strength. in recent years, however, environmental problems in a global scale are imposing a reversion in the use of synthetic fiber specially the glass fiber. In spite of its higher specific strength, this fiber and its polymer composites can neither be recycled nor incinerated in a thermal plant to generate electricity [1]. Moreover, the fabrication, processing and transportation of a glass fiber composite are associated with C02emission, the major responsible for global warming [2].A possible substitute for glass fiber without the above-mentioned environmental problems, could be a natural fiber. In fact, natural fibers obtained from cellulose-rich plants, also called lignocellulosic fiber, are already being used in several engineering fields, particularly the automobile industry [3-6]. Figure 1 illustrates an automobile and its many components made of lignocellulosic fiber composite [7]."

Jan 1, 2011

By R. R. Cellan

There have not been many opportunities to date for comparison between laboratory and commercial neutralization rinse data. Homestake Mining Company's Santa Fe project is one such comparison. This paper discusses laboratory procedures and results from a 100' leach pad height simulation column neutralization rinse test and compares principal data with that achieved in actual commercial leach pad neutralization rinsing procedures. Principal comparisons include the rate of WAD cyanide neutralization, decrease in effluent pH, stabilization of dissolved silver and copper, and the quantity of dissolved gold recovered during rinsing.

Jan 1, 1996

By C. A. Rowland

"Plant owners and operators, plant designers and grinding mill manufacturers are giving much attention to the design and manufacture of autogenous and semi-autogenous grinding mills, particularly the mills that have large diameters and draw power up to 10,000 hp and greater. Reliable designs giving long operating lives are required in today 's ore processing plants.This paper reviews bench-scale and pilot-plant testing to determine first if the ore is suitable .to be ground by these methods and then reviews the data obtained from pilot-plant testing that is used to select the mills and the grinding circuit. The paper then discusses the use of the pilot-plant results to design the mills. The most important pilot-plant data used for mill design are power and the amount of ball charge to be used. The mill size selected is a combination of these factors. Pilot-plant data not only establish power requirements, but can be used in the selection of the type of drive, variable speed or fixed speed, and the operating procedure to be followed. This leads into the mill control circuit to be used. The total charge in the mill, the type of drive and mill discharge arrangements are needed in the calculation of stresses and bearing loads. Conclusions reached from pilot-plant work are used to obtain data for process design, and autogenous and semiautogenous mill design should be part of any test program incorporating either or both of these grinding methods."

Jan 1, 1981

By John M. Smith

Kaolin is an important industrial mineral because of its unique properties and low cost. Strictly defined, kaolin is the name given to a group of hydrous aluminum silicates of which kaolinite is the most common mineral (1). Through common usage the mineral, kaolinite, is called "kaolin" or "china clay". In 1972 over 4, 000, 000 tons of kaolin will be beneficiated and shipped by domestic producers. By far the largest user of kaolin is the paper industry which utilizes approximately 65 to 70 per cent of the total production. Kaolin is used in paper as a filler in the interstices of the sheet and as a coating to impart smoothness, gloss, brightness, and printability to the paper. The rubber industry is also a large user of kaolin where it is used as a filler because it adds strength, abrasion resistance, and rigidity to both natural and synthetic rubber goods. Kaolin is used as an extender in paints because it is chemically inert, has a high covering power, gives desirable flow properties, and is low in cost. In ceramics, kaolin is used in whitewares, tile, insulators, refractories, and in some face brick where a white color is desired. Kaolin is also used extensively in plastics as a filler in thermosetting and thermoplastic mixes to give smoother surfaces, a more attractive finish, good dimensional stability, and resistance to chemical attack. Many other process industries use kaolin as a filler, suspending medium, or for color improvement.

Jan 1, 1972

By J. S. Hegwer, P. M. Dunlap

An improved acid for the treatrrzent of sulfate-con-raining limestones and dolomites is described. The acid is designed to reduce he reprecipitation of dissolved calcium sulfate and the possibility of plugging permeable flow channels. In addition, this improved acid has a much lower reaction rate than that of regular acid; the advantages of a "retarded" acid are obtainable. Field testing of the acid has shown it suitable for use in sulfate-containing formations. Substantial improvements in productivity generally resulted. INTRODUCTION Acid treatments of limestones, dolomites and other formations bearing carbonate deposits are frequently unsuccessful when the calcareous formation contains sulfate, either as anhydrite (CaSO,) or gypsum (CaSO4. 2H2O). Preliminary dissolution in acid followed by redeposition of calcium sulfate appears to be a major factor contributing to poor well performance after acidizing. The precipitate is usually the gypsum form of calcium sulfate, but in higher temperature formations it may be anhydrite. The freshly precipitated crystals are nearly always very small and needle-like. They may occupy a gross volume many times that of the original anhydrite crystals and will obviously constitute an impediment to flow through newly enlarged flow channels. It is believed that the redeposition problem is most severe when anhydrite lines the fracture systems and large pores which supply the effective permeability of a formation. Microscopic inclusions of calcium sulfate also present large sulfate surface areas for dissolution in acid. In either case, great amounts of calcium sulfate may dissolve before the acid can be spent on formation carbonates. For regular spent acid (originally 15 per cent hydrochloric acid) the precipitate could be as much as 270 Ib gypsum/1000 gal acid. Two techniques have been applied by the industry for reducing sulfate plugging during acidizing. The method'.' commonly employed in the field is the attempted removal of a quantity of regular treating acid before it has reacted completely with the formation. This is practiced because the solubility of calcium sulfate is greater in a solution that is still acidic than in one which has been largely spent on the formation rock. The chance of precipitative plugging is therefore reduced if the withdrawal is successful. However, it is often impossible to get the acid out of the formation before precipitation occurs. A second possible method, which at first glance appears practical, involves addition to the acid of sequestering agents which form strong soluble complexes with calcium ions. These chemicals do increase the "solubility" of calcium sulfate in fresh acid, but to a lesser extent in spent acid. The sequestering agents have, therefore, proved unsatisfactory because the amount of sulfate eventually deposited from the spent acid may be greater than that from regular acid. Another logical approach to the problem of calcium sulfate reprecipitation is the prevention of the initial dissolution of calcium sulfate by the common ion effect. This may be accomplished by adding a soluble calcium salt to the fresh acid. The use of calcium salts in treating acids is not entirely new. An earlier suggested use of a soluble calcium salt in hydrochloric acid apparently failed to recognize the full extent to which the solubility of calcium sulfate could be suppressed. The present study extends this earlier work and adds certain improvements toward the development of a practical anti-anhydrite acid. LABORATORY DEVELOPMENT Calcium Sulfate Solubility Table 1 shows the results of a laboratory study performed to establish the effect of calcium chloride concentration on gypsum solubility. Because of the strong tendency of calcium sulfate to form supersaturated solutions, accurate solubilities are difficult to determine. These solubility data probably are reliable to within ± 15 per cent. The solubility of calcium sulfate in 15 weight per cent hydrochloric acid increases with increasing temperature. This trend is also followed in hydrochloric acid which cantains calcium chloride. This is contrary to the solubility behavior of calcium sulfate in water, wherein the solubility decreases with increasing temperature.

By J. Shanks

A S far back as 1925, Brazeau Collieries, Limited, became interested in .briquetting. This was brought about by complaints from their principal customer that stack losses, due to a high percentage of fine coal in their mine run, were excessive. The Company considered oil spraying of the fines. This, after some experiments and tests had been made, was ruled out as uneconomical and impracticable. When sufficient oil to be effective was put into the fines, it caused the coal in the tender of stoker-fired engines t0 arch over the screw feeder. The Company ultimately placed their problem in the hands of the Re-search Department of the University of Alberta. Experimental work was carried on by this department over a period of more than a year. The results obtained and the experience gained in this research work were conveyed to Brazeau Collieries in a report dated October 31st, 1929, and in a supplementary report dated February 2nd, 1935. Most of the results obtained in experimenting with Brazeau coal are embodied in a brochure, reprinted from the proceedings of the Second International Conference on Bituminous Coal, Vol. 19-24-28, entitled Principles in the Briquetting of Coking and Non-Coking Bituminous Coals, by E. Stansfield and W. A. Lang. All who are interested in briquetting should read this brochure. In the writer's opinion, iris the most important treatise on the subject printed in recent years. The results given in the paper are, of course, those obtained in laboratory investigation. It was pointed out to the writer that it would be most interesting to have such results correlated with those obtained in commercial practice. In this short paper, an attempt is made to do so.

Jan 1, 1942

By G. L. Oldright

This paper is the thirteenth of the series on Smelting in the Lead Blast furnace, and the third of the series on Handling Zinciferous Charges. Two other papers have been written on the Rate of Descent of the Stock Column, and Formation of Accretions. These are Reports of Investigations 2963 and 3094, for the Tooele plant and the Bunker Hill plant, respectively.

Jan 1, 1934

By G. L. Oldright

The data in this paper were collected at the Trail smelter of the Consolidated Mining & Smelting Co. of Canada, Limited, through the courtesy of S. G. Blaylock, vice president and general manager; James Buchanan, smelter superintendent; George Murray, assistant smelter superintendent; and the staff members given in Paper XI, Report of Investigations 3243. INTRODUCTION This paper is the thirteenth of the series on Smelting in the Lead Blast Furnace, and the third of the series on Handling Zinciferous Charges. Tyro other papers have been written on the Rate of Descent of the Stock Column, and Formation of Accretions. These are Reports of Investigations 2963 and 3094, for the Tooele plant and the Bunker Hill plant, respectively.

Jan 1, 1934

By W. G. Davenport

Chapter 6 examined autotherrnal smelting of pure chalcopyrite concentrate with 50 mass% O2-50 mass% N2 blast. It showed that production of 1500 K products with this blast requires: 181 kg of pure oxygen 337 kg of air per tonne, of concentrate. It also showed that the grade of matte produced with this blast is 58% Cu. This chapter re-examines autotherrnal smelting by asking: (A) WHAT COMPOSITION BLAST (MASS% 02 -MASS% N2), 298 K, WILL AUTOTHERMALL Y PRODUCE 65% Cu MATTE 1500 K FROM PURE CHALCOPYRITE CONCENTRATE? (B) HOW MUCH PURE OXYGEN AND AIR WILL BE NEEDED? These are important questions for flash? smelting because furnace operators usually want to send specific composition matte to converting. This chapter shows how a specified matte can be produced autotherrnally with 298 K oxygen-air blast. Later chapters show how it can be done with hot blast, hydrocarbon combustion, different concentrates etc.

Jan 1, 2001

By Robert F. Droullard

The Bureau of Mines has investigated techniques of using gross alpha or beta detectors to continuously measure working levels. Both methods measure radioactive particulates collected on a filter paper using a constant airflow. Inherent-error studies indicate a value of about ±3 percent for the gross alpha method and about ±8 percent for the beta method in typical mine atmospheres. However, the beta method avoids problems associated with alpha detectors and is therefore more useful. Applications of these continuous working-level detectors include work area monitoring of exposure levels in underground openings, such as mines and caves, and calibrating personal dosimeters exposed over extended time intervals.

Jan 1, 1977

By C Delwig

ThyssenKrupp specialises in the manufacture of high-grade steel-sheet products. Its main customers include the automotive, construction, household appliance, energy and packaging industries.At its works in Duisburg, Germany, ThyssenKrupp Steel Europe produces 12 Mt of crude steel annually, making Duisburg one of the world’s largest steel hubs.ThyssenKrupp have installed an online elemental analyser and limestone dosing control System on one of three Sinter strands at Duisburg in an attempt to control the sinter raw mix with better precision. Traditionally, set point changes to the raw mixture were made after sampling and laboratory analysis of the sinter product. The analyser chosen uses prompt gamma neutron activation analysis to determine the elemental content of moving material on a conveyor each minute and was supplied by Thermo Fisher Scientific. The project goal was to control the CaO/SiO2 ratio (basicity) and reduce its variability in the sinter feed.Evaluation of the system has shown that the addition of the online analyser reduces the time lag related to the former method, therefore upset conditions can be reacted more quickly by the control system, and this has resulted in a more stable sintering process. As a result, the sinter feed variability in case of the basicity has been reduced by half. While CaO/SiO2 control was the initial aim of the project, a number of other benefi ts have been realised, such as a reduction in return fi nes and a financial benefi t of 0.11 €/ton of sinter attributed to the reduction of coke breeze and limestone. ThyssenKrupp Steel Europe has identifi ed that additional information available from the analyser could be used to optimise the complete sinter process.The project was carried out with a financial grant of the research program of the ‘Research Fund for Coal and Steel’.

Jul 11, 2011

By Ernest F. Burchard

MOST of the iron ore smelted in Alabama blast furnaces is mined within Alabama, although deposits in the neighboring States of Georgia and Tennessee may be drawn upon when occasion requires. Of the four commercial kinds of iron ore, the anhydrous ferric oxide, hematite (Fe2O3) ; the hydrous ferric oxide, mostly the type commonly known as limonite (2 Fe2O33H2O) ; the carbonate, siderite (FeCO3) ; and the magnetic oxide, magnetite (Fe:3O4) ; the first two are found in abundance in Alabama, the third in less than commercial quantities, and the fourth only rarely. Both the hematite and the hydroxide are found in somewhat different forms according to their geologic environment. The Red Mountain hematite, of Silurian age, that crops out in well¬defined beds for 1.50 miles northeast-southwest and 40 miles northwest-southeast is the predominant source of ore. Only a small part of this area carries ore of commercial value; Birmingham and Gadsden are now the only centers of production. The ore is of sedimentary origin, probably altered from vast deposits of greensand mixed with calcareous, fossiliferous. marine debris. Other types of hematite not vet mined commercially are in metamorphosed rocks-red ore in slates in Columbiana Mountain and specular hematite (gray ore) in quartzite in the Talladega Hills.

Jan 1, 1938

By T. F. Mitchell, J. A. McAllister, S. J. Hussey

"INTRODUCTION During the Bureau's extensive program of investigating possible domestic sources of manganese, an are-dressing study was conducted in its laboratories at Salt Lake City, Utah, on a sample of oxide manganese ore representative of vein material from the Ophir Hill mine at Ophir, Tooele County, Utah. The sample (obtained by blasting down and mixing a portion of the vein) was submitted by the Ophir Development Co. of Ophir, Utah. As the ore was too law in grade to be acceptable for direct production of ferromanganese, it was tested to determine its amenability to concentration by ore-dressing methods.At the beginning of the investigation of manganese-ore beneficiation in December 1940, the only product marketable to Metals Reserve Company was ferrograde manganese, grade B, the requirements for which follow: Mn, min., 48 percent; Fe, max., 7 percent; Si02, max., 10 percent; P, max., 0.18 percent; A1203, max., 6 percent; Zn, max., 1 percent.Later, the specifications were modified gradually. As of May 15, 1943, manganese products were acceptable if they contained over 35 percent manganese and less than 3 percent zinc and 1 percent phosphorus. Prices were based upon material containing 48 percent manganese, 6.0 percent iron, and 11 percent silica plus alumina. Premium were paid for manganese content in excess of, 48 percent and iron content below 6 percent, penalties being imposed upon products containing less than 48 percent manganese or more than 6 percent iron or more than 11 percent silica plus alumina. The specifications for commercial manganese further required that maximum particle size be 12 inches and that 75 percent of the product be coarser than 20-mesh. Therefore, fine material, such as table and flotation concentrates, had to be nodulized or sintered. In addition, carbonate manganese ores were not acceptable unless calcined."

Oct 1, 1947

By Voyle R. McFarland, Robert A. Burmeister, David A. Stevenson

The distribution of lead between phases in the Ag-Sb-Te system was studied using microautoradio -graphy. Two compositions were investigated, both containing an intermediate phase Known as silver antimony telluride as the major phase, and one containing AgzTe and the other SbzTes as the minor phase. For both compositions, two thermal treatments were used: nonequilibrium solidification from the melt and long equilibration anneals of the as-solidified structure. For each composition, lead was segregated in the minor phase of the as-solidified structure, but was distributed in the matrix after anneal. The electrical resistivity and carrier type were insensitive to the distribution of lead in the two-phase structure. ThERE has been considerable interest in the Ag-Sb-Te system because of its thermoelectric properties. The major interest has been in compositions on the vertical section between AgzTe and SbzTes, particularly the 50 mole pct SbzTes composition AgSbTez (compositions are conveniently expressed as mole percent SbzTes along the AgzTe-SbzTes section). One of the major problems in the proper evaluation and utilization of this material is the inability to control the electrical properties through impurity additions: all alloys prepared to date have been p-type, even with the addition of large amounts of impurities. It has been shown Wit all the compositions previously studied contain an intermediate phase of the NaCl st'ructure as a major phase (denoted by b) and a second phase, either AgzTe or SbzTe3, as a minor phase.'-3 One explanation for the unusual electrical behavior of this material is that the impurity additions have a higher solubility in the second phase than in the matrix; the impurity would segregate to the second phase, leaving the bulk matrix essentially free of impurity.4 In order to investigate this mechanism with a specific impurity element, the distribution of lead between the two phases was determined using autoradiography. Lead 210 was chosen because of the suitability of its 0.029 mev 0 particle for autoradiography and also because of the interest in lead as an impurity in this system.5'6 EXPERIMENTAL PROCEDURE Two compositions were taken from the vertical section between AgzTe and SbzTes, 50 mole pet SbzTes (Viz. AgSbTez) and 75 mole pct SbzTes, in which AgzTe and SbzTes appear, respectively, as the minor phase. Lead containing radioactive lead (pb210) was added to the above compositions to provide a concentration of 0.1 wt pct Pb. The material was placed in a graphite crucible in a quartz tube which was then evacuated and sealed. The samples were melted and solidified by cooling at a rate of 8°C per min and then removed and prepared for microa~toradiography. After autoradiographic examination of these samples, they were again encapsulated and annealed in an isothermal bath at 300°C for a number of days and prepared for examination. An alternate method of preparation employed a zone-melting furnace; the molten zone traversed the sample at a rate of 1.2 cm per hr and the solid was maintained at a temperature of 500°C both before and after solidification. This treatment had the same effect as solidification at a slow rate followed by an anneal for several hours at 500°C. In order to obtain the best resolution, thin sections of the alloy were prepared by hand lapping to a thickness of approximately 20 p. Other samples were prepared for examination by lapping a flat surface on the bulk sample. The resolution, although somewhat better in the former procedure, was adequate in both instances and the majority of the samples were treated in the latter fashion. A piece of autoradiographic film (Kodak Experimental SP 764 Autoradiographic Permeable Base Safety Stripping Film) was stripped from its backing, care being taken to avoid fogging due to static-electrical discharge. A small amount of water was placed on the sample, the film applied emulsion side down on the surface of the sample, and the sample and the film dipped into water in order to assure smooth contact. After drying, the film was exposed for 2 to 5 days, the period of time selected to give the best resolution. The film was developed on the specimen and fixed and washed in place. Two major factors must be considered in establishing the reliability of an autoradiograph: the in-

Jan 1, 1964

Crushing and grinding The Crushing and Grinding Technical Committee There was substantial activity in the area of crushing and grinding with the improved outlook in the industry. The Crushing and Grinding Committee's theme of 1987's Annual Meeting in Denver was Fundamentals of Mechanical Design for Crushing and Grinding Mills. At the meeting, the concept of gearless sag mill variable speed drives was taken out of the closet, dusted off, and a wraparound motor was put on hard copy with the ordering of a 9.7- x 4.5-m, 8.2-MW (32- x 15-ft, 11,000-) sag mill. Additionally, comparisons were provided to the mill design of the gearless drive sag mill and the twin 4.5 MW (6000 hp) do variable speed drives placed on the drawing board for the Kennecott UCD Expansions. This involved a 10- x 4.5m, 8.9 MW (34- x 15 ft, 12,000 hp) sag mill. Differing opinions were also expressed in technical presentations pertaining to the need for quality mill specifications in design and manufacturing. J. Berney-Ficklin of Bechtel presented a paper outlining the need for quality design and manufacturing specifications in large scale grinding mills, and the overall cost reduction in capital and operating costs. Others presented differing specific views, but all emphasized a central theme. Quality and reliable designs in large mills should not be compromised. In-pit crushing applications continue to increase, overseas and in the US, in both mining and quarrying. Different in-pit crushing units have been classified as mobile, with integral transport systems; semi-mobile, typically modular systems that use separate transporters for repositioning; semi-stationary plants that must be dismantled before transporting and typically require earthwork and concrete foundation work; and stationary in-pit crushing plants, which remain in place for the life of the pit. The majority of equipment sales of conventional crushing and grinding circuits in 1987 were to gold mining operations. There have been two areas of end use: • conventional jaw/gyratory or impact crushing circuits preparing low grade ores for heap leaching; and • small scale sag/ball mill circuits preparing higher grade ores for classical cyanide leach/ recovery circuits. There was also continued interest in ABC and SABC circuits for both base and precious metals plants. High pressure roll crushers continue to attract considerable interest in the cement industry. There, they are used to prepare raw materials or clinker for subsequent ball/tube milling. However, they have apparently been less successful in the mineral industry where the energy savings/ capacity gains have been much less dramatic. Several papers covering the theory and application of these machines were presented in an industrial minerals session on cement at the SME Annual Meeting. The Third International Conference on Hydrocylones, held in England in October produced several papers of interest on classification and screening to the mining industry. In particular, a new cyclone apex, developed by Mt. Newman Mining, shows promise of reducing water flow to the cyclone underflow stream and, therefore, increased underflow pulp densities and reduced fines recycle in grinding circuits. A twin vortex hydrocyclone was also described and shown to give a sharper split than conventional units. Similar double cyclones were introduced in the 1950's, but failed to achieve widespread acceptance. This was due mainly to a proneness to blockage in the transitional zone. It will be interesting to see whether this latest variant can overcome this problem in the typical operation. A number of North American iron ore plants installed the capability to produce fluxed iron ore pellets. Most chose to grind the stone on site with circuits designed to grind taconite ore. Methods employed to grind this material included single-stage ball mills closed with fine screens, rod and ball mill circuits - both open and closed with cyclones - and semiautogenous mills, followed by ball mills closed with screens or cyclones. Dewatering and tailings disposal B.M. Moudgil and D.L. Sober, University of Florida Due to tightened environmental regulations and the need for more efficient land use, a greater interest in dewatering and waste disposal has developed. As a result, research efforts in flocculation, surface chemistry, and polymers science have focused on the problems related to the dewatering of solid mineral wastes. A few studies have been conducted to examine the flocculation process. Hogg et al., (1987) discussed the formation and growth of flocs. They determined the size and density of flocs was controlled by the physical conditions of the system (e.g. agitation,

Jan 5, 1988