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By L. Escudero-Castejon, S. Sanchez-Segado, A. Jha, Y. Hara, S. Parirenyatwa

In a world where declining ore grades are increasingly common, it has become necessary to process low-grade feedstock. Carbothermic reduction in the presence of alkali (Na2CO3) has been adapted to beneficiate waste that contains titaniferous minerals (TiO2 ca. 12 wt%), in order to recover valuable constituents such as TiO2, Fe and V2O5. The waste from vanadium metal processing has environmental legacy as it leaves nearly 1 wt% V2O5 process waste, which is environmentally problematic due to V5+ ions in contact with water and soil. This investigation focuses on the kinetics and mechanism for alkali reduction of mineral waste bearing 10–12 wt% TiO2, which we studied in the 1073–1323 K range. The thermogravimetric analysis (TGA) technique was used to record weight loss data. Two distinct regimes demonstrated mixed-control kinetics: (1) at low temperatures the activation energy was found to be 199 kJ mol−1, which corresponds to the outward diffusion of O2− ions; and (2) at high temperatures the calculated value was 130 kJ mol−1, which is consistent with the activation energy for the outward diffusion of Fe2+ ions. The metallic iron, sodium titanate and sodium aluminosilicate phases that formed were characterised using X-ray powder diffraction (XPRD) and scanning electron microscopy (SEM) techniques, and their significance for metal recovery is explained.

Mar 1, 2017

By J. McCreedy

"The addition of Portland cement to hydraulic sand fill has resulted in the production of stable and self-supporting cemented sand fill. The use of cemented fill in the mines of The International Nickel Company has resulted in substantial economies in timber requirements, de-creased dilution of ore and greater flexibility in mining methods.Coupled with special mining techniques, it has permit-ted mining by both cut-and-fill and shrinkage stoping methods to much greater depths than heretofore. The use of cemented sand fill has permitted revisions to undercut-and-fill mining which have significantly improved the efficiency of this method.Automated mixing systems have been developed for preparing cemented sand fill in surface sand plants on a continuous throughput basis. Control of cement-sand mixtures is obtained by the use of a mass flow measuring system and weighing cement feeders."

Jan 1, 1966

By Jack A. James

Lancaster Lime and Stone Corporation developed a quarry operation in 1971 and 1972 for the production of high calcium limestone and construction aggregates, or roadstone. The quarry operation is situated in southeastern Pennsylvania in the northern part of Lancaster County. The geology of the high calcium limestone deposit had a powerful influence on all aspects of planning this operation. My purpose is to trace the influence of geology throughout the planning and thereby point out the discipline that geology imposed on the planning, and indeed, continues to impose on the operation. Lancaster Lime and Stone Corporation is one of four wholly- owned subsidiary companies of Kurtz Materials Corporation. Kurtz Materials Corporation, through its operating subsidiaries, is a supplier of basic materials to the construction industry including crushed stone, ready mixed concrete, concrete masonry units and a wide range of precast and prestressed concrete products.

Jan 1, 1973

By A. W. S. Schumann

A. W. S. Schumann The first reason for todays success lies in the very high standard which was set by our speakers today and I think that we owe a very special vote of thanks to Messrs P. M. C. Wilson, A. A. Oakes, M. J. Deats, A. C. Coetzee, R. E. Burnton and J. G. Ferguson. This, however, cannot account for the fact that there was a tremendous response even before anyone knew who was going to speak or what they were going to speak about. I suggest that the response was enthusiastic because people expected a more informal gathering with a greater opportunity for feedback, for an exchange of views and for questions and answers. The very popularity of the idea has defeated its own ends to some extent. This gathering is too big and many people must have been left with questions unanswered. Possibly one should arrange for a number of meeting places-there are many in the Chamber and the surrounding mining houses-and then have separate meetings in the morning with joint reporting session in the afternoon. Alternatively, we could have a symposium after the colloquium, using Webster's definition of a symposium as as 'a drinking party of merry fellows'. We all know that it is easy to discuss mining into the small hours. Obviously one cannot summarise todays papers and discussions, but I would like to make a few comments on technical matters and after that I would like to speak for a moment about what I see as major trends or tendencies which arise from discussions of this nature. Regarding the question of placing a village on a mine or away from a mine, I would mention that there is quite a body of literature on the adverse sociological effects on the development of children in any community in which the great majority of parents share the same occupation. It is something to be avoided if possible. We discussed the concept of the moving stockpile. If this is proved to be successful, it could save a considerable amount of money for Escom who could then avoid the construction of very large and costly staithes which are now regarded as parts of power stations. One does not see why both a moving stockpile and a staith should be necessary. By the way, speaking of Escom, I see that Mr Bob Scott is here; he has stopped pulling my leg by saying that we sell stone to Escom; perhaps someone has told him that if this is true, it must be the cheapest stone you can buy in this country. My next point relates to the use of epidiascope. It struck me again that this instrument which provides a visual image to accompany your message, can be very effective if it is properly used. These papers speak of a great deal of hard work which went into their preparation, and one really feels that the authors should have taken a few minutes more to prepare their drawings specifically for the epidiascope. There should be nothing on the drawing which is not necessary to illustrate a particular point and there should be nothing on the drawing which is not visible from the back of the hall. In particular, if one cannot read the figures along the sides, then one

By Louis Cabot

A pilot plant of the Modular Gold Processing Unit (MGPU) was designed, installed and operated, over a 8 months period, by RSW-Béroma, at the Granada Mine located near Rouyn-Noranda, Quebec. A description of the project geology, plant set up as well as exploitation results, including productivity and profitability curves, are given for a small scale mining operation in comparison with larger ones. Copyright ã 2001 CIM

May 1, 2001

By J. J. Gusek

Several final pits in the Seneca No. 1 Surface Coal Mine were abandoned in the 1960's without king reclaimed. In addition, a progressive landslide aggravated by the abandoned mine land conditions was threatening a county mad and private property. An AML-funded project to stabilize the landslide and reclaim the final pits was completed in 1986 for the Colorado Division of Mines and Geology (formerly Colorado Mine Land Reclamation Division). The site was visited after ten growing seasons. The land is stable and the vegetation re-establishment is strong. Volunteer native plant species are now invading the reclaimed sites.

Feb 24, 1997

By M. Hodgson

The redox reactions that occur on pyrrhotite and pentlandite in contact with oxygenated deionized water were examined using voltammetry. Reactions were put forward in which both minerals were progressively hydroxylated to form thermodynamically metastable surface intermediate products. These intermediates were modelled as metal deficient sulphides where a sulphurous layer was coordinated onto the remaining metal sites via polysulphides. Prior to hydroxylation pentlandite exhibited changes in the surface stoichiometry which were not related to pH effects. The formation of polysuiphide-sulphur intermediates were believed to promote collectorless; flotability for the two minerals. Microflotation tests (0.3 g samples) verified that the surface potential and particle size affected the flotation response, excessive oxidation inhibiting the minerals' flotability. Larger scale tests using ore samples (30 g) confirmed that the extent of pulp oxidation, particle size distribution and the presence of frothers affected the flotation response, the findings being in accordance with the postulated model for the hydrophobic species generated on the pentlandite and pyrrhotite surfaces.

Jan 1, 1985

By A. Viksne

A series of tests were conducted by the Bureau of Mines to determine the best means of reducing noise generated by the detonating cord that is utilized for trunklines in quarry blasting. Ten different types of detonating cord were tested and evaluated for their acoustic qualities. The results of the investigation showed that noise levels produced by "low-core-load-per-foot" detonating cord "not covered" were lower than those produced by "high-core-load-per-foot" detonating cord covered with 6 inches of unconsolidated material.

Jan 1, 1972

By L. K. Witika, J. H. Masinja

"Investigations of flotation characteristics of Lumwana and Kansanshi ores using formulated frothers were carried out. Of the six frothers tested, two came from the alcohol family, two from the glycol family and last two were formulated products. The initial work involved determining the optimum mesh of grind and frother dosage for Lumwana and Kansanshi ores. Further work involved carrying out surface tension, bubble size and froth stability measurements. Finally, water recovery tests were conducted at Lumwana and Kansanshi mine sites. For froth stability tests, six frothers were tested on a two-phase (water–air) system using the Bikerman column flotation cell, while water recovery tests were conducted using a total of seven frothers, including the standards for each plant. The results of the testwork showed that (i) although a stable froth is essential for optimum recovery of valuable minerals, a higher molecular weight frother, like Dowfroth 250, caused poor selectivity when used on fine ores and (ii) a lower molecular weight frother was suited for Lumwana ore, while a mid to higher molecular weight formulated product was suitable for Kansanshi sulphide ore. INTRODUCTION Investigations of flotation characteristics of Lumwana and Kansanshi ores using formulated frothers were carried out. The initial work of this project involved determining the optimum mesh of grind and frother dosage for Lumwana and Kansanshi ores. Further work involved carrying out surface tension, bubble size and froth stability measurements. Finally, water recovery tests were conducted at Lumwana and Kansanshi mine sites. In order to investigate the gangue entrainment levels in the Lumwana and Kansanshi sulphide ores, two well-known methods (froth stability and water recovery) were used. Firstly, froth stability tests were conducted using six frothers, two from the glycol family (Dowfroth 200 and Dowfroth 250), two from alcohol family (MIBC and pine oil) and other two from the formulated family (Betafroth 20 and Betafroth 245), at the University of Cape Town’s Centre for Mineral Research (CMR) laboratories. Froth formation and stability measurements were conducted using the Bikerman column flotation cell."

Jan 1, 2015

By Leandro Augusto Viana Teixeira, Angela Avelar, Ruberlan Gomes Silva, Virginia S. T. Ciminelli, Daniel Majuste

Rare earth elements are essential for modern life products and green technologies. Recent supply constraints have boosted the development of rare earth projects after the price peak of 2011. The feasibility of a project depends on the definition of a processing route, which in turn depends primarily on the rare earth mineral, with monazite and bastnaesite representing the two most relevant minerals. Monazite-type ores usually contain high acid consumption impurities, such as iron, aluminum, calcium, magnesium and phosphates, and may also contain prohibitive levels of radioactive thorium in its composition. Based on thermodynamic analysis, the present work discusses the fundamentals of a selective process route for rare earth extraction from monazite ores with high iron content. This process involves sulfation by means of concentrated sulfuric acid and roasting at a high temperature. The route yields high rare earth extraction with low iron and thorium extraction and low acid consumption. Rare earth extractions as high as 80 percent were achieved, while iron and thorium extractions were lower than 1 percent, and acid consumption was lower than 0.34 kg of sulfuric acid per kg of ore. The operational window was compared to the one predicted by thermodynamic modeling, with 700 °C representing the optimal roasting temperature.

By M. J. Senk, A. Lusin

Federal regulations require that methane liberated at the face be diluted and removed to maintain methane gas concentrations below 1 pct (CFR) in working places and intake air courses. The delivery and distribution of intake air at the face is critical for effective face ventilation. Improved techniques for monitoring the movement of intake air to the face are needed. A test system was developed and a computer program written for using a three-axis ultrasonic anemometer to measure airflow in a simulated mine entry. Results of tests conducted in the entry showed that the anemometer is a valuable tool for measuring mine airflow conditions near the face.

By D. R. Murray

A four-year study was carried out to determine the ability of coniferous trees to aid in the reclamation of uranium tailings at Elliot Lake. Five species were planted: white cedar, white spruce, jack pine, scotch pine and red pine. More than 570 bare-root, two-year-old seedlings were planted on bare tailings and in areas of established grasses. A further division was made between areas of coarse and fine tailings. Over-all survival and growth of the trees has been far below expectations based on previous experience with several varieties of grasses. The criteria for assessment have been per cent survival and yearly growth as determined by plant height. Pine was superior, with 68% survival when planted in bare coarse tailings, 45% for vegetated coarse tailings and 34% for vegetated fine tailings. Cedar had the worst survival rates at 49%, 14% and 7% respectively. No species survived on bare fine tailings. The survival and growth of the coniferous trees have been related to species, environmental conditions and tailings properties.

Jan 1, 1978

By M A. Tuck

Atmospheric air on a moisture free volume basis consists of approximately 21 per cent oxygen. The current minimum threshold for oxygen in Australia is 19.5 per cent. Atmospheric air generally will also contain water vapour and will also pick up further moisture as it flows around a mine ventilation network. This paper details the results of a study to determine how much oxygen depletion can occur due to the sole impact of increasing the moisture content of air and the potential impacts of this on ventilation system design. The study shows that the moisture content can have a significant impact on the oxygen concentration in mine air. The main factors controlling the impact are the barometric pressure, dry bulb temperature and relative humidity of the air.CITATION:Tuck, M A, 2015. What is the oxygen depletion potential of ?water vapour?, in Proceedings The Australian Mine Ventilation Conference, pp 173–176 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By Sylvie Poirier

This paper focuses on new developments regarding thermal rock fragmentation applications. The technology consists in a strong burner powered by diesel fuel and air. The thermal reaction, which is created, allows for the enlargement of 125-mm to 450-mm holes by breaking the rock in a spalling effect. It has been used for over 30 years in Russian open pit mining. Following an agreement between Dynamitage T.C.G. Inc. and the owner of the technology, major improvements have been brought to this technology, allowing for the fabrication of a prototype suitable for the Canadian industry. In Russia and Ukraine, thermal rock fragmentation is actually used to drill large diameter holes in surface mining. Upon having acquired a better knowledge of this technology, it seems that it presents a great potential for selective mining in narrow-vein operations, for either surface or underground mining. Rocmec International Inc., a subsidiary of Dynamitage T.C.G. Inc., and Natural Resources Canada are technical partners in the evaluation of the operational parameters and environmental aspects, such as gas, heat, dust and fog emissions. Furthermore, Canada Economic Development is a financial partner in this project. This paper presents the technology and its history. It also reports on the changes brought to the equipment to adapt it to North American environments. A summary of the tests realized since 1995 is provided, along with the main conclusions obtained. The anticipated applications for the use of this technology in both surface and underground environments are described, such as open pit mining, bulk sampling and narrow-vein ore extraction. An estimate showing a comparison between the thermal fragmentation mining concept and the long-hole mining method is presented and, finally, the future developments planned are listed.

May 1, 2002

In flotation, particulate materials are separated by controlling the hydrophobicity of the particles using appropriate collectors. In this regard, contact angle (?) is the most important process variable. However, the flotation models used in industry today do not include ? as a parameter. As result, flotation circuits are designed based on the first-order flotation rate constants (k) determined from laboratory experiments. A problem with this approach is that laboratory experiments usually give substantially higher k values than achievable in full-scale operations, which makes it difficult to use the model for plant design. In the present work, we have developed a model from first principles using both surface chemistry and hydrodynamic parameters, such as ?, ?-potentials, surface tension (?), particle size, energy dissipation rate, etc. The basic approach is similar to the one developed previously for bubble-particle interactions under laminar flow conditions (Yoon and Mao, J. Colloid and Interface Science, 181, 61, 1996) except that the model parameters have been modified by considering the turbulence in a flotation cell. In addition, the model describes the recovery processes in froth phase, including bubble-coarsening due to coalescence. Based on this model, we have developed a computer simulator (FlotSim) that can be used to design flotation circuits from the mineralogical (or liberation) data on the feed and the hydrodynamic characteristics of a flotation machine. Since the model is dynamic, it can also be used for process control. Further, the simulator has predictive capacity as it is based on a first-principles model. The model-based simulator has been validated in a carefully controlled bench-scale flotation experiments. Keywords: flotation kinetics, flotation model, contact angle,?-potential, size-by-size recovery, liberation, DLVO theory

Sep 1, 2012

By Dan Wang, Qian Xu, Guangshi Li, Xionggang Lu, Xingli Zou, Zhongfu Zhou, Hongwei Cheng, Changyuan Lu

The preoxidation of the ore has a profound significance to the concentration, separation and purification of nickel and copper from the lean complex ore. In this paper, the natural Ni-Cu sulfide mineral samples under the elevated temperature condition in air were investigated, as well as under isothermal condition at 600 oC in air. The mineralogical characterization was studied using XRF, ICP and the Rietveld method. The oxidation behavior and the element migration of the Ni-Cu sulfide ore were studied by XRD, SEM-EDS and TG. The XRD Rietveld method was successfully developed in the phase identification and quantification of this complex ore powder sample. The oxidative intermediates (Cu/Ni-ferrite) were detected by XRD, and the process of the element migration was obviously revealed by the line scans using SEM-EDS. It is the preoxidation of this mineral that provides guidance for the extraction of valuable metals from low-grade Ni-Cu sulfide ores in the future.

Jan 1, 2015

By Xiaohui Li, Lianyun Liu, Hongmin Zhu, Chunfang Zi, Kai Huang, Hongjie Li

"The dissolution kinetics of steelmaking slag in pure water was studied, and the relative influential factors were investigated. The dissolution behavior of slag particles in water was well described by Noyes–Whitney equation, and for this kind of sparingly soluble rigid mineral this simple model was extensively applicable to describe their dissolution process. Experimental data were also obtained to confirm the significant promotion effect on the growth of some algae.1 . IntroductionIt has been found that the population of phytoplankton distributed in the ocean was significantly related to the concentration of some elements [1]. For example, silicon and iron were very low in the high-nitrate low-chlorophyll (HNLC) areas, which was the main factor limiting phytoplankton and other biomass growth in these open ocean surface water [7]. The silicon and iron-rich test also confirmed that the supply of these elements had the direct effect on the growth of phytoplankton processes at HNLC areas [2-8]. So in order to promote the growth of phytoplankton in these ocean areas, providing some of these elements into these ocean areas is a natural idea for choice. Steelmaking slag is a good resource for consideration because it usually contains silicon, iron, phosphorus and other elements that are necessary for the growth of phytoplankton [8-10].Haraguchi has proposed the following idea that [5-6], if steelmaking slag can be spread to the open ocean, the trace components like silicate, iron and phosphate as the indispensable nutrients for the growth of phytoplankton, will be leached into the sea water, not only promoting the growth of phytoplankton, but also making good use of these huge amount of steelmaking slag produced every year. Based on this idea, they have carried out studies in recent years and they found that silicon and iron in the slag could be extracted into seawater effectively and play a positive role in the growth process of many algae. About the dissolution of the steelmaking slag, the Japanese scholars' research work mainly focused on the thermodynamic analysis of its dissolution possibility, and in the process of dissolution they tried to adjust the pH value of the seawater by continuously adding hydrochloric acid, which was deviated from the natural conditions of dissolution, and so the laws drawn under these special conditions can not give the identical guide to the practical application. Therefore, it is quite necessary to investigate the dissolution behavior of the steelmaking slag in the seawater at the normal pH range without adjustment to simulate the dissolution possibility under the natural conditions. In the present study, the silicon extraction behavior from the steelmaking slag was investigated and the dissolution kinetics in this process was also discussed in detail. Further studies were also performed here to evaluate the promotion of steelmaking slag on the growth of algae."

Jan 1, 2011

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By P. R. Taylor

Titanium carbide and titanium diboride powders have been successfully synthesized by direct treatment of ilmenite concentrates in a non-transferred arc thermal plasma reactor. Methane gas was used as the reducing agent and boron oxide was used as the boron source in these processes. Free energy minimization plots were used to predict the behavior of each system under different molar ratios and operating conditions. Products were characterized by XRD, SEM and chemical analytical techniques. The average size of the ceramic product is in the submicron range. Metallic iron apparently is finely deposited on the surface of the titanium carbide or titanium diboride particles. Minor impurities such as silica, manganese and zircon were converted to the carbide form.

Jan 1, 1995

By Run Huang, Xuewei Lv, Lei Lei, Guibao Qiu, Chenguang Bai

"The TiO2-rich slag and pig iron can be produced from ilmenite concentrate by the electric furnace process. In this study, ilmenite concentrate was reduced in a vertical furnace equipped with a weighting data acquisition system. The effects of reducing agent (carbon) amount on the iron reduction were studied. The phase transformation, morphology and chemical compositions of reduced samples were investigated by X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. It was found that the reductive degree of ilmenite concentrate increased with the increase of reducing time. The phases of reduced samples were mostly iron, rutile, Ti3O5 and Fe2TiO5. The mass loss percentage increased with increasing the carbon amount from 8% to 12%. When the carbon amount exceeded 12%, the mass loss percentage decreased with the increasing of carbon amount.IntroductionIlmenite and rutile are the main raw materials for producing titania pigment and titanium metal. With the development of the titanium industry, huge amounts of titanium resources are needed. As sources of high-grade titania mineral decrease worldwide, more attention should be paid to the processes involving low grade mineral such as ilmenite ore. In ilmenite, MgO and CaO are the gangue parts. Therefore, the ilmenite refining becomes more and more popular. In the previous studies, the methods of ilmenite refining are electric furnace smelting, direct acid leaching, selective chlorination and thermal reduction [1]. Electric furnace smelting method is widely used in the titanium industry, however, which consumes a great deal of energies and has a high CO2 emission. Its essence is to remove iron oxides and obtain a high titania slag. So the thermal reduction of ilmenite concentrate is an important step in titanium industry, which can decrease carbon reagent consumption and save energy.Over the past several decades, many studies have been carried out on the mechanism and kinetics of the reduction of different ilmenite ores, which are as follows: The carbothermal reduction of Panzhihua ilmenite initiated at about 860 oC. In the temperatures ranging from 900 oC to 1400 oC, the reaction rate was changed like a shape of “M”. That was to say that the reaction rate increased with the growth of temperature at first, then decreased, afterward increased again and at last the reaction was arrested [2]. The Mohammad A.R group [3, 4] showed that the carbothermal reduction of primary ilmenite concentrate was faster in hydrogen and initiated at a lower reduced temperature than in argon and helium. The reduction in argon and helium had about the same rate and extent. Titanium oxycarbide started at 1000°C in hydrogen. The conversion of primary ilmenite concentrate to metallic iron and titanium oxycarbide at 1200 °C was completed in 300 minutes. Monoxide as the reductant to reduce ilmenite had been studied intensively by a few research groups [5, 6]. The rate and the degree of reduction depended on the formation of a metallic shell of iron which inhibited the transfer of CO to the reaction zones; titanium had a strong effect on the mechanism and rate of reduction of iron oxides. Wang and Yuan [7] studied the reductive kinetics of the reaction between a natural ilmenite and carbon. At temperature below 1100°C, chemical reaction was the rate controlling step, at 1100 to 1250°C mixed controlling was rate controlling step, above 1250°C diffusion through the product layer controlled the reaction. Zhang [8] investigated the reduction of natural, sintered and preoxidized ilmenite concentrates in hydrogen methane mixtures. Preoxidation and sintering of ilmenite concentrates changed their phase composition and caused a sharp decrease in specific surface area of raw materials and an increase in carburization temperature. Sintering also increased the metallization temperature of iron."

Jan 1, 2011