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By D. G. F. Hedley, F. Grant

"In 1958, the Ontario Department of Mines appointed a committee to study the accident situation and mining methods used in the uranium mines in the E1liot Lake district. This committee reviewed the existing knowledge on mine design, pillar support and roof spans and came to the conclusion that scientific knowledge had not yet reached the stage of producing rational design procedures which would reduce the dependence on trial-and-error methods. Since that time, the Mining Research Centre has made numerous stress measurements in two mines to define the pre-mining and pillar stresses. A comprehensive series of tests has been done in the laboratory to measure the compressive strength of the rock; a geological survey of the region has been made to evaluate tectonic stresses; and a survey was done on mining conditions with regard to stable and unstable pillar configurations. This information has been used to evaluate pillar design as effected by pillar width and height, depth below surface, extraction and pre-mining stress fields. The resultant design of pillar widths and corresponding extraction as the depth increased is in line with past and present experience in these mines. The information available on roof stability is still insufficient to design stable stope spans with the same degree of confidence; experience and trial-and-error methods are still required."

Jan 1, 1972

By K. Anand Rao

Extensive exploration for uranium metal by the Department of Atomic Energy in India led to the discovery of new carbonate host rock uranium deposits Tummalapalle and Gogi, which are located in southern part of India. Alkaline leaching at elevated temperature and pressure using autoclave is the central unit process in the overall strategy for extraction of uranium from these new ore deposits. Autoclave leaching is affected largely by intrinsic nature of the ore and by the process variables and the equipment settings. In order to understand such a complex process and also to be able to predict the process performance under randomly (ore grade, uranium mineralogy, gangue mineralogy etc.) and consciously perturbed variable settings (partial pressure of oxygen, temperature, concentration of leachant, stirring speed and time), sound and robust mathematical models are needed with analytical and/or numerical solutions. Present investigation attempts to develop a variant of kinetic correlation based on shrinking core model for batch alkaline leaching process in an autoclave. The leaching model incorporates particle size distribution according to popular Gates-Gaudin-Schuhmann equation, rather than assuming a single mean size for all the particles participating in the leaching reaction. Kinetic experimental data generated in autoclave leaching of Gogi uranium ore was used to evaluate various constants of the model developed. The ore sample used for experiments assayed 0.21 per cent U3O8. The partial pressure of oxygen was varied between 0.15 to 6.5 atm, temperature from 343 K to 438 K, concentration of sodium carbonate leachant in the range 0.47 g mol/L to 0.94 g mol/L, and the stirring speed from 573 rev/min to 900 rev/min in the experiments. The goodness of fit of the leaching process model is found to be >0.95. Morphological studies carried out on leached and unleached particulate matter using Scanning Electron Microscopy with Energy Dispersive X ray analyses are included in the present study.

Sep 1, 2012

By Jim Hazzard

A numerical investigation is presented to examine fluid flow in fractured rock slopes. In mining geomechanics, different numerical modelling approaches are used to estimate fluid pressures in open pit mines. The most common technique is the Equivalent Porous Medium (EPM) approach in which the fractured rock is assumed to behave as a porous continuum. Depending on the geometry and properties of the problem, this may not always be the best approach. The paper presents a parametric study to examine the effect of fracture spacing, fracture and matrix diffusivity and excavation rate on the fluid behaviour in rock slopes. Based on the model results, guidelines are provided as to when EPM models can be used and when different modelling approaches (e.g., discrete fracture flow) may be necessary.

Jun 1, 2012

By L Bergin, D J. Williams, S Islam, T A. Vangsness

The flooding of open strip coal mines in the Bowen Basin and Hunter Valley Coalfields of Eastern Australia has the potential to soften the spoil and floor materials to produce “mud”. This mud can act as a slip plane or weak zone when spoil is dumped into it, resulting in geotechnical instabilities. Once mud has formed, typical handling techniques include its costly removal by mechanical means, or its isolation and capping.There are little data available on the moisture state and shear strength of the capped mud. To investigate the effectiveness of isolation and capping, research has been conducted using a large slurry consolidometer (150 mm in diameter by up to 410 mm in height) to simulate capping in situ. Once consolidated, the mud was subjected to shear strength testing in a direct shear box measuring 60 mm by 60 mm by about 20 mm high. The shear strength of the consolidated mud was compared to that of competent, fresh spoil, a mixture of spoil and mud, and to completely degraded spoil (mud alone).These results have been used as inputs in stability calculations using the commercial computer program Slide 7.0, which demonstrates the strong influence of consolidation of the mud on overall low wall slope stability. The results provide insight into the design and construction of capping to isolate in-pit mud.CITATION:Vangsness, T A, Williams, D J, Islam, S, Smith, A and Bergin, L, 2018. Consolidation and shear strength testing and stability analysis of coal mine spoil degraded to mud, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 97–109 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By F. W. Gray

Foreword: It is not my purpose, in this address, to write the history of the Geological Survey of Canada, which has from time to time been reviewed by the officers of the Survey itself, and by men more competent than myself to handle so large a subject, but rather to set out some of the reasons for the regard in which the Survey is held by our Institute, the body best qualified to speak for the mining men of Canada. And, a further purpose is to publish the desire of our Institute that the work of the Survey shall be maintained at the highest pitch of efficiency the resources of our country. will permit, because to scrimp expenses on the Survey is 'to save at the spigot and lose at the bunghole." A historical examination of the grounds on which it may be asserted the Geological Survey has been, and still is, of fundamental economic value to our country, discloses a prescience on the part of the forefathers of Canada, calling for our admiring gratitude, and reveals a unanimity among the real leaders of Canadian thought, on the value of geological knowledge, that is impressive in its continuance dawn to this date. There seems always to have been before our people the realisation that large stretches of Canada are unfitted for agricultural settlement, and that our glaciated areas, the barrens and tundra of the North, and our extensive mountain ranges, had promise of compensating mineral content which the geologist and the prospector, labouring together through the years, would disclose. The Geological Survey is one of Canada's oldest public services, distinguished by an unimpaired tradition of honourable and useful labour. Founded in 1843, under William Edmond Logan, not yet 'Sir William', one year after the Act of Union, it was directed by him until 1869, or into the early years of Confederation, so that the early years .of the Survey were also, politically, the formative years of Canada, as we know her today.

Jan 1, 1932

By Garry W. Warren

The electrochemical oxidation of chalcopyrite in the absence of-a chemical oxidant was studied in ammonia/ammonium sulfate solutions by anodically polarizing electrodes prepared from massive chalcopyrite. The effects of pH, cupric and ammonia ion concentration were systematically evaluated. Kinetic parameters were obtained from the anodic charge-transfer regions of the anodic polarization curves. Increasing ammonia and hydroxyl ion concentrations increased the rate of oxidation. A mechanism is proposed which explains the first order dependence of (NH3) and (OR) associated with a single electron transfer process. An empirical relationship which accurately describes the dependence of the rest potential (i.e. zero current potential) on solution composition is also given.

Jan 1, 1978

By Yazn Khasawneh Ph. D. P. E., Will Tjaden, Spencer E. Ness P. E., Mohammed Nasim Ph. D. P. E.

Wind turbine components undergo many loading cycles during their operational life. Additionally, wind turbines may undergo extreme loading conditions from natural hazards, mechanical failures, or emergency stops. Current design practice for the foundations of wind turbines accounts for these complex loading conditions through a simplified pseudo-static approach based structural loading combinations. A rotational stiffness for the foundation is estimated from the pseudo-static analysis and then compared to an acceptable minimum rotational stiffness provided by the turbine manufacturer. These minimum rotational stiffnesses are based on dynamic analysis of the tower and nacelle system with the foundation represented as linear springs. This approach provides a reasonable approach to the foundation design but does not accurately capture the true dynamic performance of the entire soil-foundation-tower-nacelle system. This becomes especially important for pier-type foundations, which are being more commonly used to support modern and future generations of larger turbines. Additionally, the dynamic performance of the foundation will vary as the adjacent soil undergoes a large number of loading cycles of varying strain magnitudes. In this study, the full turbine-tower-foundation-soil system was modeled using finite element methods. An advanced non-linear soil constitutive model and dynamic loading time histories were used to investigate changes in stiffness of the soil, and the possible impact on the dynamic response of the system. Results were compared to conventional design methodologies with the goal of reducing foundation capital costs while avoiding increases in O&M costs and which can lower the LCOE of wind energy.

Oct 1, 2022

By V. Montaruli, A. Nieto, M. Cardu

Nickel is a metal whose workability and mechanical strength at high temperatures and in corrosive environments makes it an indispensable alloying element for the realization of stainless steel, specialty steel, super-alloys, rechargeable batteries and electroplating. Because its main fields of application are key to the development of industry and, thus, to society, nickel has recently been recognized as a potentially critical mineral, despite its abundant reserves. The purpose of this paper is the creation of possible case scenarios determined by factors and events that, in the medium to long term, could change the current structure of the nickel market on the demand and/or the supply side. Four scenarios have been determined by considering a demand variation due to the occurrence of a natural disaster and an aerospace plan implementation and taking into account the resource nationalism and the skills shortage as supply varying factors. Through the creation of a georeferenced global nickel database, the paper proposes supply strategies related to the four scenarios for each top nickel consumer: China, India, European Union, United States and Japan.

Jan 1, 2013

By J. B. Zadra

Much has been published by various investigators on the use of activated carbon for adsorbing precious metals from cyanide solution and pulp. For the benefit of the reader, a list of these earlier publications appears at the end of this report. The present paper deals only with a process for extracting gold from gold-laden carbon and re-use of the de-adsorbed carbon. At the Getchell mine, Redhouse, Nev., experiments have been in progress for several years concerning the use of activated carbon to adsorb gold from their slime circuit pulp. The experimental work has been successful. Their practice has been to ship the gold-laden carbon to a smelter for treatment, which meant the total loss of the carbon in addition to smelter and freight, charges, all of which proved costly and wasteful.

Jan 1, 1950

By Iain M. Mason

Linear meridional zones of bad roof conditions have been frequently encountered in producing collieries working the Permian age Lithgow seam in the western coalfield of New South Wales. The prediction of such zones ahead of mining is desirable for reasons of both safety and economics. In March, 1981, we carried out an experimental, three-component in-seam seismic survey at Invincible Colliery to discover whether such zones have any unambiguous seismic effect. The underground survey was the first of its kind to be attempted in an Australian mine. The data quality was excellent with the spectra broadband and clear. Polarisation analysis disclosed two modes: one compressional; the other shear horizontal. The SH model was clearly dispersive and well gound to the plane of the seam. Modal velocities decreased by up to 15% at the fracture-swarm site. There is a strong suggestion on the RLS maps obtained here that the distributed fault zone is acting as a composite scatterer of channel waves. The P-SV and SH wave tomograms obtained show, in a general way, the distribution of stress in the coal panel.

Jan 1, 1982

By K A. Campbell, K A. Rodgers

The Plumduff sinter occurs at Whenuaroa, near Puhipuhi, approximately 30 km north of Whangarei. It is one of three residual sinters in the southern portion of a mid- to late-Pliocene geothermal system. The deposit consists of many large sinter breccia boulders, including rudrocks (coarse breccias), scattered around the flanks and summit of the small conical hill of Plumduff. Three types of sinter breccia occur: (i) rudrocks consisting of large, angular to sub-angular clasts of layered sinter up to 0.8 m across, as well as smaller clasts of sinter (20 - 100 mm dia), and fragments of stromatolitic structures; all clasts are supported in a matrix of microcrystalline, transparent to translucent to milky quartz; (ii) fragments of layered angular to irregularly mottled sinter of white to grey or bluish hue supported in a translucent to opaque silica matrix; (iii) smaller, matrix-supported breccias with clasts both partially surrounded and/or penetrated, by a clay-like weathering rind, and sinter conglomerates with rounded to oblate clasts. Three principal types of fabrics constitute the bulk of the sinter: (i) stromatolites, including columnar, palisade and filamentous networks, showing progressive silicification, in fenestral, tufted to clotted fabrics; (ii) peloids and pisoids; (iii) plant-rich facies in which various silicified plant species occur in a silica matrix. All fabrics have counterparts in hot spring deposits in the Taupo Volcanic Zone formed at temperatures from 75¦C to 35¦C. Also present is steam-condensate-produced alteration: kaolinite and alunite as well as boulders of quartz lattice texture. Cinnabar only occurs in sinter on the north and south central slopes of the hillside. No quartz veins or geyserite were recognised.

Jan 1, 2001

By P. Rosten

US mine production of iron ore in 1984 showed some improvements compared to 1983. But reduced demand from the iron and steel industry caused temporary shutdowns of many iron ore mines and pelletizing plants. US raw steel production in 1984 was slightly above 1983, but still at a depressed level. Production was 83 Mt (92 million st), compared with 77 Mt (85 million st) in 1983 and 68 Mt (75 million st) in 1982. Two major production trends continued in 1984. They were the increased production from electric furnaces and the growing use of continuous casters. Electric furnace production included 33.2% of the steel poured in 1984, compared with 31.5% in 1983. Continuous casting was used for 39% of 1984 steel production, compared with 32.1% in 1983. Statistical Process Control Statistical Process Control (SPC) has taken on new proportions in the iron ore and steelmaking industries within the last year. This mathematical technique is used to monitor, control, evaluate, and analyze a manufacturing process. The technique charts variability of important quality parameters. Training and adaptation of SPC techniaues for process control have been initiated at Inland, Steel's Minorca, Pickands-Mather's Hibtac, Cleveland-Cliff's Empire and Sherman operations, and at Reserve Mining. One of these operations has requested its bentonite supplier provide SPC charts on quality specifications. Some of the steelmaking operations (Inland Steel, Bethlehem Steel, Dofasco, LTV Steel, National Steel, Stelco, Weirton Steel, and Wheeling-Pittsburgh) have set up SPC programs within their operations. And they also have insisted that some of their suppliers use SPC. Plant Shutdowns The permanent closure of Stelco's Griffith mine at Red Lake, Ontario, has been delayed by one year. This gives employees more time to adjust. The mine is now set to close in April 1986, instead of April 1985. Sidbec (Canadian government) and its other partners (including British Steel Corp., Quebec Cartier Mining, and US Steel) closed its iron mining operations at Gagnon, Quebec. The pellet plant has been leased to Quebec Cartier. New Iron Ore Operations The massive Carajas iron ore project in Brazil is scheduled to come onstream in Jan. 1986. It is to achieve full-scale commercial shipments by July of that year. The 66% iron crude ore requires only crushing and screening before shipment. The product consists of 83% sinter feed and 17% coarse ore. Annual production capacity will be 32 Mt (35 million st) when the project is completed. Principal customer for the ore is Nippon Carajas Iron Ore Co., a consortium of Japanese steel mills. The Arab Iron & Steel Co. (AISCO) has started up a $US300 million, 3.6 Mt/a (4 million stpy) iron ore pelletizing plant built by Kobe Steel Ltd., at Al Hidd-hide in Bahrain. By 1986, this grate-kiln-cooler plant will supply high quality iron ore pellets to feed direct reduction plants in the immediate Gulf area and Far East markets. Iron ore supplied from Brazil, Peru, India, and Mauritania provides the feed to the pellet plant. Hydrated lime (2%) is used as a burden.

Jan 5, 1985

By M. McClintock

"High Pressure Grinding Rolls (HPGR) is increasingly being chosen for comminution circuits for its energy-efficiency for hard rock mining operations. Despite HPGR’s growing popularity, geo-metallurgy programs are still prohibitively expensive because of large sample requirements. Traditionally, sizing HPGR application requires a significant amount of sample, in the order of 1 to 10 tonnes, depending on the level of study and complexity of the resource. Therefore, engineering and design of HPGR circuits typically are reliant on few composites that are required to be representative of the resource and mine plan. Three bench scale HPGR test methodologies were developed in 2015 at NBK Institute of Mining Engineering at the University of British Columbia (UBC) capable of defining the energy size breakage relationship of pilot HPGR. These methodologies were developed to allow bench scale testing for different levels of study from PEA (Preliminary Economic Assessment) to detailed design and operations. The Piston Press test defines the energy size reduction relationship by measuring specific energy consumption and corresponding feed and product size distributions. The advantage of Piston Press testing is the small sample requirement of 5 to 10 kg. Small sample requirements allow multiple samples to be tested across a deposit. Piston Press testing allows extensive geo-metallurgy programs that can determine ore variability and inform in optimization and production planning. To date, the Piston Press methodologies have been validated on a pilot-scale HPGR unit located at UBC. Recently, testing was conducted to calibrate and validate the Piston Press test against full-scale HPGR on a gold sulphide ore deposit. The program included the collection of operational data with the respective HPGR feed and recycle sample. Sample collected was used both for Piston Press testing and HPGR piloting. This paper discusses the test-work and results as carried out during this program, using the aforementioned methodologies."

Jan 1, 2018

By Michel Bustamante

The occasional substandard performances of continuous flight auger in particular soil conditions have prompted the drilling rig manufacturer to improve the standard CFA in order to reduce its negative effects. A real improvement of interest was the launching of the double rotary CFA system. The promising features of the latter have incited the authors to implement an extensive experimental research on pile constructed using this type of technique but in the specific context of cohesive soils. Short-term static load tests were carried out on a total of 9 test piles of various installation techniques in order to compare the respective performances. The promising features of the double rotary CFA have incited the LCPC & Durmeyer Company to implement an extensive experimental research on this type of pile technique but in the specific context of cohesive soils and more particularly in clayey marls. After load tests completion the research has been completed by an excavation of the double rotary CFA piles. All the collected data concerning the implemented program are reported.

Jan 1, 2002

By J Morton

The Resource Management Act 1991 represented an innovative and unique piece of planning and environmental legislation when it was introduced. Since the Act was passed into law in 1991 it has been subject to nine amendments, many of which were of the ætinkerÆ variety. These amendments recognise that the Act has not been as successful in providing the æone-stop shopÆ for resource users that the Act was hoped to be. The latest and most significant attempt at changing the Act was the Resource Management Amendment Act 2003. The amendments made by the Amendment Act have proved to be largely unsuccessful in achieving any significant changes to the way resources are managed in New Zealand, and have failed to address many of the concerns which drove the original Resource Management Amendment Bill in 1999. The recent decision to discontinue further investment in Project Aqua has once again placed the Act in the spotlight as a significant hand-brake on major projects. This particular event has led to yet another review to be undertaken this year. The review will focus on five key areas:   1.   achieving the right balance of national and local interests; 2.   improving the design and process for local policy formulation; 3.   improving the consent decision making process; 4.   allocation of natural resources (water, air and geothermal); and 5.   supporting measures for building capacity and promoting best practice and implementation at the local authority level.  It is important for the business community and the mining industry in particular to seize the opportunity that this review provides to make sure that any amendments undertaken as a result of the review achieve the aims listed above. The review needs to be considered in light of the current regime for the management of natural resources in New Zealand. In addition to the Resource Management Act 1991, the Crown Minerals Act 1991 and the Building Act 1991, which form the core resource statutes in New Zealand, there have been other developments affecting the regime. Special legislation over and above the Resource Management Act 1991 has been enacted to protect the Hauraki Gulf and special legislation is currently being considered to protect the Waitakere Ranges in Auckland. In the Hauraki District mining is prohibited in some areas and a plan change mechanism is specified as the appropriate tool to use in the event a mineral resource is to be developed in those areas. The current review is a further opportunity to remedy the inadequacies of the Act.

Jan 1, 2004

By F. R. Erick Mulder

"AbstractTwo bottom-hole samples have been taken from two new completions in the Turner Valley field, Royalite Lowery No. 8 on the west flank and Royalite No. 73, which was deepened into a lower fault block, on the northeast flank. From the bottom-hole oil of Royalite Lowary No. 8 a synthetic sample was prepared to simulate the original fluid in the reservoir, saturated at the gas-oil contact conditions. The sample from Royalite Lewery No. 8 has been shown to be the original fluid present at this well and represents the oil phase near the oil-water contact in• the reservoir. Complete chemical analysis, P.V.T., and viscosity data have been obtained on these reservoir fluids, which represent the range of saturation from the gas-oil to the oil-water contact in the Turner Valley oil structures. Sampling techniques and the application of the analytical data to reservoir conditions and field operations are discussed. Super-compressibility curves for an average separator tail gas have also been prepared. These data have not been available before. They will be of fundamental value in futu.re reservoir engineering studies of this field and will also serve as a guide in determining operating practices."

Jan 1, 1950

By Harry J. Cain

Introduction The property of Pioneer Gold Mines of B. C., Limited, is located in the Lillooet mining district of British Columbia, on Cadwallader creek, 54 miles distant by motor road from Shalalth, a station on the Pacific Great Eastern railway. Milling by the present Company was commenced in 1924, a small amalgamation plant, consisting of a crusher, Bryan mill, and plates being operated until 1928. Tailing from this plant was impounded and later treated in the 100-ton continuous counter-current decantation cyanide plant which was erected during 1927-28 and placed in operation during May of 1928. A second cyanide plant, employing continuous counter-current decantation, having a nominal capacity of 200 tons, has been erected during the past few months and was put into operation during September of the present year. The ultimate capacity of the combined units of the present mill has not been determined, but it is expected to be much in excess of the rated capacity. The Ore The ore, as received at the mill, consists chiefly of quartz carrying free gold, with small amounts of pyrite, arsenopyrite, and pyrrhotite in evidence, though probably amounting to less than one per cent of the total. Some gold is very closely associated with the sulphides. The country rock is a basic igneous rock, probably an augite diorite. Near the vein it is highly altered to sericite, which slimes readily on grinding, and does not settle very well. The quartz is of two types, clear and ribbon. In the latter, the ribbons, which are not much thicker than paper, consist of shattered sulphides. In crushing this ribbon quartz, breakage is often along the streaks, exposing these shattered faces to advantage in subsequent treatment. While gold is the metal for which the ore is mined, some silver is also present and is paid for by the mint. It is, however, unimportant from a commercial viewpoint. From the standpoint of crushing and grinding, the ore might be termed 'medium 'hard'.

Jan 1, 1932

By M. Nusheh, C. Bumby, A-H. Puichaud

"Vanadium-bearing titanomagnetite ironsand deposits occur along a 480 km stretch of the west coast of New Zealand. In the present study, the leaching behaviour of NZ ironsand was investigated in hydrochloric acid (2–10 M) solution at 50–80°C for 2 h. The resulting leaching liquors exhibited Fe/V ratios in the range 150–180. The distribution of trace element contaminants between solution and solid residue was investigated, and processing conditions have been determined for rapid and efficient dissolution of Fe, Ti and V into the leaching solution. In addition, mineralogical analysis of raw ironsand and leached residues was performed in order to study the leaching mechanism. Samples were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy (EDX), X-ray fluorescence spectroscopy, qualitative and quantitative X-ray diffraction and inductively coupled plasma mass spectrometry (ICP). Results indicate that the dominant dissolution process follows shrinking particle mechanism. However, ironsand particles containing ex-solution lamellae exhibited a different leaching behaviour compared to homogenous titanomagnetite particles.INTRODUCTION Titanomagnetite ironsand (blacksand) forms Quaternary onshore beach and dune deposits and offshore marine deposits (Figure 1) along 480 km of coastline from Kaipara Harbour south to Wanganui on the west coast of the North Island (Christie, 2016). It attracted the attention of scientists from the earliest times (Galbreath, 1998). The principal minerals in ironsand are titanomagnetite (TTM), ilmenite, quartz and ferromagnesian minerals such as augite, hornblende, diopside, and olivine with smaller amounts of rutile and apatite (Mauk, 2016).Several large ironsand deposits have been discovered and exploited since the late 1960’s. The Waikato North Head and Taharoa mines are currently operating and they have a 2015 measured resource of 400 million tonnes in total and provide over 2 million tonnes of concentrate per year by simple cost effective magnetic separation process (Christie, 2016; Christie & Brathwaite, 1997). The concentrate contains not only 7–8% TiO2 and 56–60% SFe, but also 0.3–0.6% V2O5, is both a valuable titanium mineral and a source of vanadium. All the production is used for steelmaking industries. The other potential for utilizing more of this resource without requirement of integration into an iron and steel producing plant is to develop a hydrometallurgical route with advantages of higher efficiency along with lower emissions. Currently, there is no existing commercial process capable of extracting all three of these elements as industrial-grade commodity products. Acid leaching of TTM concentrate with higher degrees of recovery and selectivity is a key step in any possible hydrometallurgical route."

Jan 1, 2017

By H. Pempel, J. Markowski, P. Ay

"Metal-coated thermoplastic parts find more and more functional and aesthetic applications in the interior and exterior of cars. The vapor-deposited or electroplated coatings are usually composed of a plurality of nickel- and chromium-containing layers, which are applied to copper-containing carrier layers on the polymers. Previously, recycling processes are mainly focussed at the recovery or thermal utilization of the plastics. Targeted and selective recycling of the metallic coatings is usually not carried out. Together with several SME, BTU developed a process, in which a complete and separate recovery of all components in high purity is possible with biotechnological methods. The bioleaching is carried out with iron and sulfur-oxidizing bacteria, especially Acidithiobacillus ferrooxidans. The copper-containing layers are dissolved in the solution; chromium- and nickel-containing particles are precipitated as solids. After the bioleaching, a mechanical separation of the individual metal-containing components and their separate workup are carried out. End-products are metallic copper, a nickel- and chromium-containing solid and the cleaned plastics. The bioleaching ensures a high purity of the end products. Through the use of bacteria, which are also found in nature, the process is environmentally friendly. Compared to chemical leaching using inorganic acids, considerably shorter leaching times can be achieved. In addition to the optimization of the leaching process, the R/D-project also includes the development and testing of the apparatus technology.INTRODUCTION The material complexity of many end-user products has increased in recent years, especially in the fields of electrical appliances, vehicle technology and medical technology. However, the demands on functionality, safety, comfort and energy efficiency still play a greater role in product design as factors such as sustainability and usability. For example, if a car still holds more than 70% of steel in the 1980s, a vehicle nowadays includes a larger proportion of a variety of difficultly separable plastics and composite materials, as well as complex metal composites. This relates in particular to composites made from such different materials as metals and plastics. The processing and recovery of the components of those complex material mixtures is difficult for recycling companies."

Jan 1, 2017

By Víctor Vázquez, Guillermo Tiburcio, Martin Encinas, Jesús L. Valenzuela, Erick Montaño, Alejandro Valenzuela, José Parga

Merrill-Crowe is the primary process used for the concentration and purification of silver in a cyanide solution. The Langmuir Adsorption model for silver recovery in a cyanide solution was used for the study. The maximum adsorption capacity was 6.19 mmol/g for silver. This model properly adjusts the experimental results of the adsorption equilibrium with high correlation coefficients, which also favors the formation of a single layer of molecules adsorbed for the silver in the electrocoagulation- generated species. The thermodynamic parameters ΔG, ΔH, and ΔS were estimated, and it was found that the adsorption process is exothermic and spontaneous. For the kinetic study, the Lagergren second-order equation was used to study the adsorption speed. To characterize the solids coming from the electrocoagulation, X-ray diffraction (XRD), and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX) were used; the results of this study suggest that silver is present in aluminite, hydroniumjarosite, and alunogen.

Oct 30, 2021