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By S. B. Leonov, K. I. Popov, S. B. Polonsky

The offered technological line includes a flotation pulp air conditioner operating on the impact-mechanical effect and two column apparatuses with a descending pulp-air flow mounted in series. The technology developed makes it possible to increase considerably the valuable component in the concentrate simultaneously with a reduction in energy consumption for the flotation process. The experience achieved with the technology showed the possibility for obtaining sulphide silver-bearing ore superconcentrates with the noble metal content 2-10 times higher than that in the concentrates obtained by the conventional technology. The same results were obtained in the process of calcium-bearing boron-silicate ore-dressing.

Jan 1, 1995

By Yaw Boadi, Andrew McCallum, Sandy Gray, Yavuz Atasoy, Peter Wemyss

"Various full-scale test programs and installations of the InLine Pressure Jig (IPJ) have provided evidence that pre-concentration of the difficult to leach sulphide mineral through gravity can provide significant increases in economic recoveries. The continuous gravity concentrates are intensively treated either by re-grinding or Intensive Cyanidation. Data from various mine sites worldwide is presented. Treatment of complex ore bodies with this low cost methodology may render previously uneconomic ore bodies financially viable and assist in the recovery profile of transitional ore.INTRODUCTIONThe use of gravity is made extremely attractive in complex ore situations due to the low cost of operation, typically a few cents per ton operating cost and lack of chemicals.Gold mines which suffer from poor recovery due to complex mineralogy such as Stibnite, Arsenic, Carbon, Telluride, Silver and other pacifying agents such as Iron, which can form coatings, can all benefit from the process proposed in this paper. The key issue is not overall recovery as much as one of economic recovery. The key to this is maximised recovery at the lowest possible capital and operating cost. Other options such as flotation are reviewed but are not seen in many instances to be the panacea due to issues discussed in the paper. The use of the InLine Pressure Jig in the re-circulating load of the milling circuit is a cost effective means of recovering a sulphide/gold concentrate containing the complex mineral assemblages which require re-grinding and intensive leaching for optimised gold recovery.The benefits of Jig Assisted Grinding (JAG) are many and the challenge over the past years has been developing, understanding, implementing and evaluating the benefits of various flowsheet models. This has involved the reconciliation of results in plant scale trials back to the original laboratory test program. The following paper outlines the insights gained in this area through extensive work carried out by many people across both laboratories and plant sites in Australia and overseas. The examples in this paper are some of the work carried out on a few selected sites but similar work has been carried out on other sites such as Penjom, Granny Smith and Agnew. This work has eventuated in several installations which we believe have great importance in the future of the gold processing industry. They will lead the way forward to the modern all-gravity plants of the future.Compared to flotation, for the recovery of sulphides, gravity is a simple option. The simplicity generally translates to low capital and operating cost."

Jan 1, 2004

By Paul Worsey, Larry Frost, Braden Lusk, Seok Bin Lim

For certification of blast resistant windows, current tests consist of arena tests or large air gun tests. Arena tests involve the detonation of more than 1000 pounds of explosives with windows placed in the range of hundreds of feet. The result of an arena test is a loading on a window consistent with an expected industrial or terrorist blast. Due to the nature of this type of test, only a limited number of facilities are available and operational costs can be extremely high. Air gun tests involve the use of compressed air and a failing diaphragm fired through a large tube. Although this test is more cost effective and easier to administer with lower environmental impacts, it is not an explosive loading and does not create a negative phase on the tail of the pressure pulse. Simply using a small charge in close proximity to the window is not a viable option either. The pressure peak can be reached using this method, but the duration of the pressure pulse is such that the positive phase impulse is on the order of ten times less than that for an arena test.

Jan 1, 2006

By R. L. Crosby, L. W. Higley

Magnesium- rich magnesium- aluminum- zirconium alloys in the cast and in the extruded and heat- treated condition were studied to identify the phases present and to determine phase distribution . In cast alloys , two intermetallic compounds were identified : ZrAla by X- ray diffraction ; and Mg₁ Al₁₂ by microscopical observation . Based on microscopical comparisons between the known phases in the cast structures and the phases in the structures of extruded and heat - treated rods , ZrAl₂ and Mg1 , Al12 were identified in the structure of the latter . The presence of these intermetallic compounds in rod specimens could not be confirmed by X- ray diffraction . ZrAl₂ was observed in the structure of extruded and heat - treated rod specimens containing as little as 0.01 weight - percent zirconium . The presence of aluminum restricts the solubility of zirconium in magnesium because of the strong tendency to form ZrAla . This intermetallic compound segregated in clusters of small particles in the matrix of cast alloys , and only slight improvement in distribution was noted when the alloying techniques were varied .

Jan 1, 1964

By G. J. Simandl

"Since the 1980s, China has become the predominant producer of REEs. Recently, it introduced REE export quotas and this started a world-scale REE exploration rush. REE resources are concentrated in carbonatite-related deposits, peralkaline igneous rocks, pegmatites, REE ± P veins, ion adsorption clays, placers, and some deep ocean sediments. REEs could also be derived as a by-product of phosphate fertilizer, U processing, Ti-Zr-bearing placers, and exploitation of Olympic Dam-type sub-type of IOCG deposits. The ideal REE development target would be located in a politically stable jurisdiction such as Canada. REE grade and tonnage, mineralogy, and permissive metallurgy are some of the key technical factors that could be used to screen projects. INTRODUCTIONAccording to the International Union of Pure and Applied Chemistry (IUPAC), the term “rare earth elements” (REEs) encompasses yttrium (Y), scandium (Sc), and the lanthanide series: lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu). This definition is used throughout this paper.REEs are subdivided into light (LREE) and heavy (HREE) categories. LREEs include, Sc, La, Ce, Pr, Nd, Sm, Eu, and Gd and HREE include Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y. Promethium (Pm) does not occur in nature. Concentrations of individual LREEs in the upper crust of the Earth are comparable to those of base metals. Even the least abundant REE (Lu) is about 200 times more abundant than gold.The production of REEs, reported in the form of oxides (REOs), for 2011 is estimated at 140 000 t (Figure 1a). Although high technology industries can substitute several REEs with other materials, these substitutes are typically more expensive or less effective than the REEs they replace. A number of countries, including the United States, consider several REEs essential for national security, their economy, and a general reduction in green house gas emissions. The forecasted demand for individual LREOs is much higher than that of HREOs (Figure 2). Dy, Eu, Tb, Nd, and Y are essential for the US economy and subject to predicted supply disruptions (U.S. Department of Energy, 2010)."

Jan 1, 2012

By Muldoon T

Water sprays on mining machines are generally put there to reduce dust; however, research by the Bureau of Mines and others has shown that considerable airflows may also be generated by these sprays. This recognition of water spray-gen- erated air movement led to the "Spray-Fan" - a continuous miner auxiliary ventilation system which was shown to reduce methane peaks by a factor of 15. Recent successes and failures of the Spray Fan are reviewed. More recently, the same principles were used in the design of the "Shearer- Clearer" for reducing dust at longwall shearer operators. The original design was successful; however, a new design is now available which is more practical to install and does a much better job of holding the dust against the face downwind of the shearer. The latest research objective is to eliminate the negative impact of spray- generated air turbulence on continuous miner dust control. Most coal faces in the USA are ventilated in the exhaust mode using "line curtain", and the forward airflow on the side of the heading opposite the curtain is inevitably weak. Air turbulence generated by sprays which are incorrectly located and/or operated at excessive pressures can cause roll back - in which the dust cloud at the face is forced unwind against the ventilation and spreads over the miner cnerator. The general approach to reducing "roll back." is reviewed and art anti-roll back water spray system is presented.

Jan 1, 1983

By I. Jashnani, J. R. Lawter, D. B. Lindsay

INTRODUCTION It is a generally recognized obligation of owners and operators of underground mines in the United States to protect the health of miners against the potential carcinogenic effect of airborne alphaemitting radionuclides, in particular the shortlived radioactive daughter-products of 222Rn. In meeting this obligation, a number of strategies are available, and it is largely up to the operator to decide what combination of methods he will use. Because the officially accepted theory of the mechanism by which radon and its short-lived progeny cause cancer of the respiratory system, the objective in controlling this health hazard is to limit as far as possible the inhalation of the three daughter products, 218Po, 214Pb, and 214Bi. (214Po, the fourth nuclide in the chain, is so short-lived that its alpha-decay occurs almost instantaneously after the beta-decay of its parent, 214Bi.) The reasoning in this theory leads to the conclusion that the alphadecay of radon itself causes essentially negligible physiological damage, and that the amount of daughter product activity attributable to decay of radon within the respiratory system is also very small. As every ventilation engineer in this business knows, however, focusing remedial actions exclusively on the daughter products themselves is choosing the hard way, and will probably never lead to effective control of this health hazard in underground mining activities. The reason for this troublesome fact can be seen in Figure 1. Let us say that we have air containing 222Rn and its short-lived daughters in near-equilibrium, a not-uncommon condition in the air of a poorly ventilated underground mine, and that we wish to purify it by removing only the toxic daughter products. If we have been very thorough in our purification efforts, we might expect to achieve a 99% reduction of the Working Level (WL) measurement. Figure 2 allows us to examine closely the early regrowth of WL's in this freshly cleaned air. Within the first five minutes, for instance, the WL's are back to 10% of their full equilibrium value, and ten minutes later the level has more than doubled and is on its way to an almost complete defeat of the clean-up effort by the end of the next hour. It is quite clear from this simple illustration that no matter how effective an air-cleaning system may be if it is directed only at the selective removal of the toxic trio, 218Po, 214Pb and 214Bi, its beneficial effect will be quite temporary. A truly effective attack on the problem must always include methods aimed at the control of the unruly parent, radon. Then, even if its progeny have an inalienable "right to life", their brief lives will not be spent in the miners' lungs. The object of the present paper is to show how state-of-the-art environmental air

Jan 1, 1981

By Claudia Monreal L., Dafne Herreros

"The Geological Modeling is the undisputed point of split of any type of mining method, the effect that the vision and experience of the geologists is propagated trough the development of the project and is an important part of the final success. The collection of information is taken in stages. In earlier stages uses the greater part of the budget and the strategy to store and manage this data collection, as its performing will define the destiny of the deposit and of the business. With this background the geology and its modeling receive great attention from the industry and care providers being a fertile field in research and innovation. "

Sep 1, 2017

By A. Robles-Vega

In recent years, tellurium has been extensively used in the manufacture of semiconductor materials. For this type of application, high-purity tellurium is required. Selenium, lead and silicon are usually the main impurities in tellurium. During the electrolytic refining of copper, tellurium gold and silver are collected in the anode slimes. A pyrometallurgical treatment is used to recover gold and silver from the decopperized anode slimes whereas tellurium is oxidized and skimmed off from the refining furnace as a Na2CO3-based slag. In the slag, tellurium is present as sodium tellurite (Na2TeO3), which is further water-leached from the slag. The first step in the conventional process for tellurium recovery consists of the precipitation of the tellurium contained in the leaching solution as tellurium dioxide (TeO2). The solid TeO2 is then dissolved under acidic conditions for its further reduction with sulfur dioxide gas (SO2). In this paper, an alternative route for tellurium production is presented in which a sodium tellurate [Na2TeO4] intermediate is obtained by oxidation of the sodium tellurite in an alkaline solution following the water leaching step. Sodium tellurate is then dissolved in acid media and high-purity tellurium is obtained by reduction with SO2 gas. Experimental tests under laboratory conditions indicate that the novel process yields higher precipitation selectivity for tellurium than the conventional process. A comparison of its efficiency concerning impurities co-precipitation with respect to the conventional process is discussed.

Jan 1, 2009

By C. J. Pritchard, R. D. Jacksha, K. V. Raj, C. Sunderman

"In underground metal/nonmetal mines, repeated short-term exposure to high levels of airborne contaminants can become a serious health issue. Currently there are no common mechanisms to control or mitigate these localized short-term high exposures to contaminants. To improve miners’ health and safety, the National Institute for Occupational Safety and Health (NIOSH) Spokane Mining Research Division (SMRD) is developing a Smart Monitoring and Control (SMAC) system for real-time monitoring of mine air quality, with integrated countermeasures to reduce these high concentrations of airborne contaminants in localized sections of mines. To develop and test a SMAC system that could be implemented in an underground mine, researchers at SMRD built a test apparatus incorporating a fan, louver, ducting, and sensors combined with atmospheric monitoring and control software. This system will institute effective countermeasures to reduce contaminant levels, improving miner safety and health. INTRODUCTION Underground metal/nonmetal mines continue to expand production by employing large equipment in greater numbers and by mining into hotter and more challenging environments which are typically further away from fresh air sources. This challenges the ventilation system to provide adequate quantities of fresh air to the workplace and increases the potential for air contamination that could result in immediate and long-term health and safety issues to miners. Currently, airflow and contaminant concentration in mines are typically based on full-shift sampling which may not identify repeated short-term exposures to high levels of airborne contaminants such as NO2, CO, diesel particulate matter (DPM), and dust with high silica contents. Repeated short-term exposure to these high levels of airborne contaminants over long periods can lead to serious health issues which are documented in several studies [1-3]. Based on data from ventilation surveys and contaminant measurements, mines often attempt to minimize exposures by sending more fresh air to the working areas where contaminant concentrations are found to be high. Real-time monitoring and control allows mines the option to monitor contaminants and implement controls in real-time. Real-time monitoring and control of the underground mine atmosphere has been a subject of research since its beginning in Finland at Outokumpu’s Pyhäsalmi Mine in 1969 [4]. More recently, the real-time monitoring and control problem has been addressed using ventilation on demand (VOD) systems [5, 6]. A VOD system attempts to deal with this issue on a global level by controlling fans, louvers, and doors to increase airflow to active work areas and reduce contamination. However, a VOD system only controls the distribution of airflow and may not be helpful in mines where the airflow is at maximum capacity. Researchers at SMRD are developing a SMAC system for real-time monitoring of mine air quality with an integrated ability to trigger countermeasures to reduce high concentrations of airborne contaminants in localized sections of mines. The SMAC system will be designed, tested, and refined in the laboratory environment before being demonstrated in an underground mine. This system will not only try to minimize the gaseous contaminants by regulating the airflow locally, but will also potentially employ a filtration system to reduce the airborne contaminants in case the maximum airflow capacity is reached. This paper presents development of the test apparatus for the SMAC system."

Jan 1, 2017

By Harry Power

THE relative merits of air and natural gas as propulsive agents in pressure drive operations have been discussed for a number of years. When air or gas is introduced into the sand, various factors lead the operator to the selection of what he believes to be the proper propelling medium; but when the question of relative drive effect is raised, several physical and chemical premises must be taken into consideration in arriving at a conclusion as to the superiority of one medium over the other. Dow and Calkins1 and Beecher and Parkhurst2 have contributed fundamental experimental work on the effect of dissolved gas in lowering the viscosity and surface tension of crude oil. Herold3 and Tickell4 have indicated that whatever type of reservoir control obtains, gas plays other important parts in the movement of oil towards the well, namely: 1. The propulsive and expansive force of the gas. 2. The "Jamin effect," or resistance to the movement of oil in a porous media due to the formation of gas bubbles. When quantitative studies are made, parallel conditions must be selected whereby we may say definitely whether air is superior to gas as a driving medium, or vice versa. Examples of similar conditions are not easy to find in the field. However, in the laboratory we can make determinations which may lead to general conclusions when applied to the field. The- experimental and research work described here was started at the laboratories of the University of California in January, 1927, and completed in private laboratories at Tulsa, Okla., in February, 1928. The apparatus used was designed especially for the work.

Jan 1, 1928

By M. Batzle

The upper Arkansas basin has some of the greatest potential for geothermal development in Colorado. Over several summers, students conducted an investigation using seismic, gravity, and magnetics in order to help identify the large structures and basin fill associated with the Rio Grande Rift. Adjacent to Mount Princeton Hot Springs, near surface geophysics was conducted to help understand the faulting and fractures that act as a conduit for hydrothermal flow. The methods used included high frequency 3D seismic, magnetics, gravity, D.C. resistivity, and self potential. Throughout the Mount Princeton area, passive seismic, vertical seismic profiling, and well logging were also used to better understand the geology and activity of the region. The results indicate for the area northwest of the hot springs, a 40 to 50 m thick unconsolidated layer overlying the fractured granitic basement. The DC profile shows a deep geothermal anomaly of low resistivity which correlates with a positive SP anomaly in the same region. In the Chalk Creek valley, a shear zone extends from the north east to the south west, just south of the Chalk Cliffs. There appears to be an upward migration of the water through this shear zone which then flows along the porous sediments towards the south in this area. The deep seismic data collected in the center of the basin suggests that the depth to the basement is approximately 2000m. Also identified on the deep seismic are two major faults on the west end and two minors at the east end of the cross-section. An alteration zone is identified between the faults and a possible Precambrian northeast trending shear zone. The potential for developing an Enhanced Geothermal System (EGS) near the center of the valley is high. Our geophysical results indicate a deep basin fill near the center of the basin providing high temperatures. The range front (Sawatch) fault is observed to penetrate under the center of the basin and is an attractive target for natural fractures.

Jan 1, 2011

By D. C. Carter

"The Nova Scotia Department of Mines and Energy located a drillhole at Riverside Corner, Hants County, Nova Scotia, to examine the stratigraphy, structure and potash potential of the Kennetcook River gravity low. This evaporite-related gravity anomaly is one of the largest virtually unexplored gravity anomalies in Nova Scotia. The drillhole intersected a structurally complex sequence o flower Windsor Group ('B' Subzone) evaporites. Downhole geophysical wireline logs were used, in conjunction with detailed lithological descriptions, to interpret the structure and stratigraphy of the sequence. Similar application of total gamma ray, density, caliper and neutron-neutron log responses allows stratigraphic correlation of Windsor Group carbonate marker units separated by up to 35 km in Cape Breton. This work confirms the value of downhole geophysical logs as a tool in the exploration of evaporite deposits regardless of the presence or absence of high quality core. INTRODUCTIONThe exploration methodology for evaporite (specifically salt/potash) deposits in eastern Canada (and worldwide) is relatively simple: identify a negative gravity anomaly within a favourable geological setting, Windsor/Cordroy Group sediments in eastern Canada, and drill it (Anderle, 1980). Although this is an obvious oversimplification of the necessary expertise in the planning and complet ion of an exploration program, those familiar with potash exploration drilling can attest to the risks and expense, in terms of time and problems , associated with the location and drilling of diamond-drill wildcat holes. Potash exploration programs in eastern Canada, their results and inherent difficulties, have been documented by Anderle et al. (1979), Cooper (1981), Dekker (1982), Carter and Boehner (1986), Carter (1988) and Carter and Anderle (in prep .).Downhole geophysical wireline logs have become an important tool in the stratigraphic and structural interpretation of evaporite sequences in eastern Canada and, in many cases, represent the only information recovered or the only information available due to the drilling method (rotary) and/or the long term instability of evaporite cores. This paper documents examples of downhole geophysical log responses which, combined with detailed lithological examination of drill core, or in the absence of core, are used in the interpretation of the complex lithology and structure of a deformed evaporite deposit. Geological and geophysical data from the Nova Scotia Department of Mines and Energy (NSDME) Riverside Corner 85-1 drillhole are presented here as a partial case history and prime example of the use of this method to interpret the complex structure of an evaporite deposit. Drilling of NSDME Riverside Comer 85-1 was conducted in late 1985and early 1986by the Department (Carter and Boehner, 1986) under a program to assess the potash potential of selected areas of the province as part of the Canada-Nova Scotia Mineral Development Agreement 1985-89. A reinterpretation of a portion of the available data from two exploration drilling projects on Cape Breton Island in the Canso-Bras d'Or area is also presented (see inset, Fig. I). Several drillholes have intersected the Windsor Group evaporite sequence in these areas and the available geophysical logs are a valuable tool in the interpretation of the structure of the deposits. However, no attempt has been made to present or discuss the detailed geological investigation and comparison of these two deposits. They are presented here as an example of the reinterpretation of existing data and their application to stratigraphic correlation and structural interpretation of complex evaporite deposits. Further work is necessary to document the stratigraphic and structural correlation of these two areas."

Jan 1, 1989

By B. P. Watson

Several large falls of ground occur annually in the narrow, tabular stopes mined in the Bushveld Complex. These falls comprise safety risks and cause substantial production losses and compromise efforts to increase productivity. Underground observations in conjunction with instrumentation sites were used to establish the strategic parameters required to describe the rock mass behaviour of shallow-dipping stopes on the Bushveld platinum mines. Existing rock mass rating systems were evaluated using the observations and instrumentation results. None of the current systems adequately described all the relevant geotechnical conditions. Thus a hybrid of several current systems was developed, and the proposed system is discussed in the paper. The new rock mass rating system is termed the ?New Modified Stability Graph? system and follows the method originally described by Mathews et al.1and revised by Hutchinson and Diederichs2.Changes have been made to some of the tables provided by Barton3and to the stress analysis suggested by Hutchinson and Diederichs2. In addition, the logistical regression analysis has been applied to databases, formed using the suggested analyses, for three support resistances and risk levels established.

Jan 1, 2004

By N. Naude, W. P. Roux

Fine particle beneficiation plays an ever-increasing role in mineral processing plants and it seems that technology can’t keep up with the challenges involved in the treating of these fines. The REFLUX™ classifier has proven itself able to treat high tonnages of fine material, especially in the coal industry. There are various fine ore applications that can benefit from such a process, yet laboratory and pilot-scale tests on many of these ores show poor efficiencies and recoveries. A better understanding of the design, operation and mechanisms of the REFLUX™ classifier is required to determine if and how it fits into these applications. The mechanisms in gravity separators are very complex due to the complex hydrodynamics, and the REFLUX™ classifier is no exception. The mechanisms of these systems are usually described through theoretical single particle-models that are hard to verify through analysing the feeds and products of these processes. To verify these models the movement of individual particles must be measured, which is not an easy task. In this paper the separation mechanisms in the incline channels of the REFLUX™ classifier were investigated with high-speed videography. A small lab scale model of the incline channel was constructed for this purpose. It was possible to capture and track the trajectories of particles under certain conditions and match these trajectories with theoretical models. The resuspension of particles, clustering and streaking was also observed and captured. Keywords: REFLUX™ classifier, particle trajectory, beneficiation, high-speed videography

Jan 1, 2020

By S. A. Falconer

The benefication of non-sulfide or non-metallic minerals by froth flotation has been practiced commercially for at least 30 years. In the pioneer stages of development of this flotation art, most of the promoters investigated were fatty acids or soaps that had been found to float sulfide minerals. When commercial application of froth flotation started to assume importance in the late 1920' s and 1930's, a great deal of fundamental research work was done in the laboratory (11-14, 19, 22, 23, 26, 29, 32). Among other subjects, this work included studies of the relative effectiveness of the different fatty acids and their salts on the flotability of various non-sulfide and non-metallic minerals. The successful present-day use of fatty acid and petroleum sulfonate type promoters results from better understanding of the principles of non-sulfide flotation plus the developnent of effective selectivity modifying agents. Many investigators have contributed to a greater appreciation of the numerous interrelated factors involved in fatty acid and soap flotation of non-sulfide minerals. Of these, mention should be made of recent fundamental studies by Tagart and Arbiter (31); Wolstenholme and Schulman (35); Schulman and Smith (28); Wark and his co-workers(3,4) Du FIietz(l5); and J. Leja(24). According to J. Rogers, K. L. Sutherland and E. E. and I. W. Wark(27), "the basic requirements for a 'collector' in flotation are that it shall form a film over the surface of the mineral to be floated and that this film should be oriented so that hydrocarbon (non-polar) groups form the effective surface." When modified in that way, the mineral surface possesses some degree of air avidity. All investigators would agree with Taggart, Taylor and Ince (33)that such a film can be produced only if the collector compound contains an active (polar) group to be attracted to the mineral surface, as well as the non-polar group. The commonly used anionic-type promoters for non-sulfide, non-metallic and metallic oxide ores include: 1. Fatty acids, and their soaps and emulsions. 2. Fatty acids residues — "pitches" and "foots." 3. Sulfonated and sulfated fatty acids and so-called "petroleum sulfonates." 4. Paraffin chain salts — sulfonated and sulfated higher alcohols. 5. Cyclic organic acids or salts, such as naph-thenic acid and naphthenates. Certain fatty acids are more effective than others as promoters for particular minerals under certain specified conditions. Some of the more costly fatty acids or collectors of the paraffin chain salt type may give improved selectivity in some instances and are being used commercially in a limited number of operations. Local availability may dictate the choice of the fatty acid used — for example, the use of palmoil fatty acid for flotation of copper carbonate ores in the Belgian Congo. Coconut oil fatty acids have also found limited use.

Jan 1, 1961

By A. J. Lynch, L. Ergun, M. Oner

"A research program on modelling cement grinding circuits has been in operation at Hacettepe University, Ankara, for four years. It has concentrated so far on tube mill and air separator grinding circuits for cement clinker, with emphasis on plant sampling surveys, including axial sampling inside the tube mills. The data used for model development have come from 33 surveys in 9 plants.The operating conditions have been:- mill sizes - 3.2 to 4.8 metres diameter and 8.5 to 15 metres long,- mill feed rates - 46 to 158 tonnes per hour,- air flow through mills - 25000 to 125000 cubic metres per hour,- cement clinker work indexes - 10.3 to 18,- separator sizes - 2. to 3.1 metres diameter,- separator feed rates - 132 to 689 tonnes per hour,- separator speeds - 12.3 to 21 metres per second.The ball mill model is Whiten’s perfect mixing model and the separator model is the Tromp curve with a fish-hook. This paper emphasises the importance of calculating the breakage rates and the discharge functions with three case studies at five different circuits which were selected for discussion because they show how particular features of circuit operation can be included in the general models. Size distribution graphs are used to illustrate every aspect of the discussion"

Jan 1, 2003

By Yunnen Chen

The test and use of natural materials as biosorbents for the removal of heavy metals from industrial wastewater is under constant development. In the present study, the biosorption capacity of waste microzyme was studied for cadmium The cadmium removal study has been carried out batchwise where the influence of physico-chemical key parameters such as pH value of solution, contacting time and initial cadmium ions concentration have been considered. The influence of metal ion concentration was evaluated and the results were fitted using adsorption isotherm models. The kinetic of cadmium biosorption was also investigated. The maximum percent removal was attained at the pH 7.0 after about 30 min. Waste microzyme was a potential biosorbent for the removal of Cd(II) from the effluent of electroplating industry.

Jan 1, 2009

By P. Prusti

An air dense medium fluidised bed separator (ADMFBS) is the efficient process for dry beneficiation of coal. Magnetite powder is used as medium to make required pseudo-fluid density in the fluidised bed. The dynamics behavior of coal particle with reference to its position changes from ideal solution to pseudo-fluid condition in different bed densities depending on its shape, size and density. In this study, three set of projected areas of coal particles were taken. Each set contains four different shapes i.e., cubical, rectangular prism, spherical and triangular prism with different density starting from 1.3 to 1.8 gm/cc. It is observed that coal particles having density less than the bed density, floats in different positions in the dense medium fluidised bed. Higher projected area particles float in deeper height in comparison with smaller projected area. The difference in position of coal particles in the bed increases (nearly 1 to 4 cm) as the coal density approaches towards bed density irrespective of the different shapes. Different shapes of coal particles behave in different ways based on the operating parameters like bed density, coal density and projected area of coal particle. Empirical model equations are proposed to predict the position of coal particle of each shape in the air dense medium fluidised bed system. Keywords: ADMFBS, particle dynamics, projected area, shape

Sep 1, 2012

By W. M. Albrecht, W. D. Klopp, R. I. Jaffee, B. G. Koehl

Kinetic studies were made of the reactions of tantalum with oxygen, nitrogen, and air at 400o to 1500°C. The tantalum-oxygen reaction is linear from 500° to 1250°C. The tantalum-nitrogen reaction follows a cubic rate law at 400° to 700°C and a parabolic rate law at 800" to 1475°C. The reaction behavior in air is initially parabolic followed by a transition to linear behavior. In the search for high-temperature materials, considerable interest is being shown in the refractory metal, tantalum. It is the third highest melting metal with a melting point of 2996°C. Also, tantalum has excellent ductility, making it one of the most workable refractory metals. In considering high-temperature applications of tantalum, the oxidation kinetics of the metal must be known. Such information also serves as a basis for the development of corrosion resistant tantalum-base alloys. Therefore, this study was made to investigate the reaction of tantalum with air, nitrogen, and oxygen. LITERATURE Several oxides of tantalum have been reported. The pentoxide, Taz05, is the only oxide of tantalum whose identity has been established. A high-temperature modification, aTa2Os, has been reported by several investigators.1-4 A low-temperature phase, ßTa2O5, undergoes an allotropic transformation at 1320o to 1350oC. 5-8 Four other oxides of tantalum have been reported. The oxides TaO2, TaO, and Ta4O have been reported by schonberg.9 A suboxide Ta2O, was observed by Wasilewski 6. However, the presence of oxides lower than Ta2O5 is questioned by Lagergren and Magneli.7 In oxidation studies, vermilyeal0 and Peterson, et al.,12 reported one possible phase intermediate between Ta and Ta2O5. Only Ta2O5 was formed in the tantalum air reaction, as reported by Michae1.l3 Several studies have been made on the kinetics of the tantalum-oxygen reaction. vermilyeal4 investigated the range 50° to 300°C and found that the rate of growth of a thin adherent oxide film could be described by the Cabrera-Mott theory. Gulbransen and Andrew15,18 studied the reaction kinetics of tantalum in oxygen pressure of 1/10 atm at 250° to 450°C. At all temperatures the reaction followed the parabolic rate law for periods up to two hours. The oxidation behavior in the range 500" to 1000°C was found to be linear at oxygen pressures of 0.2 to 600 psi according to Peterson. et al.l1 At very low pressures (1 x 10-3 to 2 X lo-' mm of Hg) Gebhardt and seghezzi17 reported linear oxidation at 800° to 1500°C. The reaction of tantalum with air is similar to the reaction with oxygen. Studies have been made by Waber, et a1.,12 and Michae1.l3 Two nitrides of tantalum, TaN and Ta2N are known. Their structures have been determined by Brauer and Zapp 18,19 The tantalum-nitrogen reaction kinetics have been investigated by Gulbransen and Andrews. 15, 16 The reaction follows the parabolic rate law at 500° to 850°C at a nitrogen pressure of 1/10 ,atm. At the same temperature, the tantalum-nitrogen reaction is much slower than the tantalum-oxygen reaction. EXPERIMENTAL TECHNIQUES Material— The material used in this study was high-purity, electron-beam-melted tantalum obtained from the Temescal Metallurgical Corp. The hardness of the as received ingot was 76 Vhn. The analysis of the material is given in Table I. Methods—Cylindrical specimens of tantalum approximately 0.9 cm in diam and 0.5 cm in length

Jan 1, 1962