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By Madgwick J. C, Ralph B. J

A method for the determination of microgram quantities of uranium in leachates from low grade uranium ores is described. Solubilized manium is purified by transfer to an organic solvent by a selective solvent extractionprocedure using tributyl phosphate, iso-octane, and aluminium nitrate. The organic phase is mixed with scintillation fiuors in toluene and the radioactive decay determined in a liquid scintillation counter. The method is sensitive and reproducible in the range 3-30 µg uranium.

Jan 1, 1978

By S. Goto, S. Yamashita, K. Hata

"The average consumption of zinc dust for purification of zinc leaching solution is more than 25 kg per tonne of electrolytic zinc. Authors proposed to remove impurities in zinc leaching solution by electrolysis instead of cementation by zinc dust. The effects of copper and arsenic on electrodeposition of cobalt in zinc sulfate solution were examined fundamentally using a potentiostat. It is observed that cobalt is easily deposited on a cathode at potentials under -480mV with arsenic. Mesh cathodes of stainless steel and lead anodes were used in a small electrolytic cell and the electrolyte was circulated through 'the electrodes during the electrolysis. The effect of electrolyte circulating rate , pH, cell temperature, current density, and concentration of copper and arsenious ions on removal of cobalt were studied. Removal of Cd and Ni are also examined.IntroductionCobalt is difficult to remove from a zinc leaching solution by a simple cementation reaction using zinc dust. However, it is easily precipitated by zinc dust with co-addition of arsenious or stibinous oxide and copper ion in practical operations(I), (2), (3). The consumption of zinc dust for purification is 16-152 kg per tonne of electrolytic zinc and 65% of this zinc dust consumption is used for cobalt purification. The average retention time for purification of cobalt is 4.5 hours (1). A more economical process for purification is desired instead of zinc dust. The mechanism of this acceleration effect of copper and arsenious oxide on removal of cobalt are explained by the authorsas follows; a galvanic cell is formed between zinc dust and copper which is precipitated firstly, and cobalt is reduced on copper as Co-As alloy by this galvanic current(2). This assumption was confirmed in experiments using a galvanic cell with a membrane( 4). The following galvanic reactions occur between zinc dust and copper precipitate; on copper cathode,2H+ + 2e -= Hz(g)2Coz+ + 2HAs02 + 6H ++ 10e -= 2CoAs + 4HzOand on zinc anode,Zn = Zn = 2+ 2e –This galvanic current becomes almost zero in a zinc sulfate solution which includes only cobalt and no arsenious oxide, and cobalt is weakly deposited on a copper cathode. Cobalt deposition requiers a high degree of cathodic polarization. However, the galvanic current flows almost constantly in an electrolyte, which includes arsenious oxide, and the cathode potential is kept at about -500mV. Cobalt is precipitated as Co-As on the cathode.The authors assumed that cobalt may be removed by electrolysis at a very low current density instead of zinc dust and the following experiments were carried out. In the first part of this paper, the fundamental experiments using a potentiostat on the behaviour of cobalt in zinc sulfate solution are described. In the second part, the results of the electrolysis are reported. Cobalt is removed by a new type of an electrolytic cell, which was desigoed to <Iccelerate the rate of deposition of cobalt. The removal of cadmium and nickel in a solution which includes cobalt and arsenic are also examined."

Jan 1, 1997

By S. Shrestha

Magnesium-based alloys are of growing interest for many industrial applications due to their favourable strength-to-weight ratio and excellent castability. Mass reduction has advantages in many industrial sectors for example, in automotive, a reduction in mass improves fuel economy and can lead to more efficient mechanical systems by reducing the weight of moving parts like wheels, gears, pistons. However, the relatively poor corrosion and wear resistance limits the use of magnesium and its alloys in many potential applications. The patented Keronite® plasma electrolytic oxidation (PEO) process enables manufacturers to overcome such problems and, in its latest generation equipment has been developed to industrial realisation for high volume production. This paper presents microstructural characteristics and corrosion performance of two most widely used high pressure die-cast magnesium alloys AZ91D and AM6OB with a duplex corrosion protection coating system that comprised a thin Keronite pre-treatment followed by a subsequent automotive grade final powder coat.

Jan 1, 2006

By Waldbillig. D.

A baseline of the poisoning effect of hydrogen sulfide (H2S) fuel impurities on solid oxide fuel cell (SOFC) anodes was developed using polarization testing. After the baseline behaviour was characterized, tests to study the effect of various H2S concentrations on the rate and amount of cell voltage degradation and recovery were performed. Attempts were made to improve the rate and amount of recovery by various methods. Testing was very reproducible, but significant electrochemical performance degradation was seen after all H2S poisoning tests even at an H2S concentration of 0.1 ppm. Degradation is initially quite rapid, but after a period of time the rate of degradation levels off. After poisoning was complete, the H2S flow was stopped and the cells were allowed to recover. Some recovery was seen after poisoning, but cell performance was never fully recovered.

Jan 1, 2005

By J. Visman

"The Compound Water Cyclone is a concentrator for the wet processing, in bulk, of finely divided materials such as slack coal, fine ores and mineral sands. It was originally developed by the Fuels and Mining Practice Division of the Mines Branch, Department of Mmes and Technical Surveys, Ottawa, for the cleaning of friable slack coals and slurries.Since its introduction in the coal industry in 1962, its application to other materials has also been studied, with special emphasis on simplicity of operation and low over-all cost per ton of finished product .In this paper, a description is given of commercial two-stage units presently available for the processing of granular materials, including wastes a1:1d other low-grade products. A pneumatic control system is used for operating the cyclone under back pressure .and for automatic cut-point adjustment. An account is given of results obtained on coal mineral sands and ores in the Wes tern Regional Laboratory of the Department of Mines and Technical Surveys. Results of several industrial applications are discussed."

Jan 1, 1966

By Qin Hua, Xiangru Chen, Qijie Zhai, Yongsheng Yan, Liang Chang

"In this paper, pure bainite ductile iron and their alloying form of 0.2wt% niobium were prepared by a controlled cooling heat-treatment. The effect of niobium alloying on the microstructure, hardness and impact toughness of bainite ductile iron was studied. The results show that adding niobium effectively improves the hardness and toughness of bainite ductile iron. The hardness and the impact toughness of niobium-alloyed bainite ductile iron were investigated by varying the temperature at which samples were fed to the incubator.IntroductionThere are two essential methods to prepare the bainite ductile iron: isothermal quenching [I-31, and alloying [4• 51• Isothermal quenching process is very time and energy consumable, concerned as a high cost technique for mass production. Besides, there are certain limitations on the size and shape of castings in this process. In addition, it potentially harms the environment. As for the alloying, Ni, Mo, and Cu have to be utilized to obtain bainite. However, the large demand and high cost of Ni makes it not feasible in practice.It is well known that niobium can promote the formation of carbon compound, and improves the stability ofundercooled austenite, which is preferred to the increase of the hardenability. Previous studies showed that niobium could refine the grain and improve the mechanical properties of gray cast iron [6-81 • Therefore, in the present work, the effects of niobium and the temperature at which samples were fed to the incubator on the microstructures and properties of niobium alloyed bainite ductile iron were investigated."

Jan 1, 2014

By J. M. Goris

The U.S. Bureau of Mines is conducting research on cable bolt ground supports to assess their material and support properties, to provide design criteria for using cable bolt supports as roof control systems under various types of underground mining conditions, and to provide a mathematical model of cable bolt support systems. Part 1 describes laboratory studies of the support properties of cable bolts made of conventional steel cables and provides recommendations on such topics as the use of thick grouts, selection of breather tubes, and reduction of water bleeding in cement-based grouts. The studies evaluated both single and double cables; effects of different embedment lengths, water-cement ratios, and grout curing temperatures on support strength; effects of use or nonuse of breather tubes; pumpability and water-bleeding properties of grouts; and the strength properties of sand-cement grouts. Part 2 will cover the strength characteristics of birdcage cable bolt supports, epoxy-coated cables, and cables with steel buttons attached.

Jan 1, 1990

By Louis Frost

MINE ventilation has for many years been the subject of intensive study by numerous investigators who have presented their findings in forms that are understandable to the average mining man, and all this writer hopes to do is to review those findings in relation to the &apos;manager&apos;s&apos; problem in mine ventilation. It would not, perhaps, be wholly correct to acclaim practical mine ventilation as an exact science, because of the many variables entering into the problem. Each mine has its own particular problem and ventilation characteristics. Fan design, in contra distinction to mine ventilation, is an exact science, but the designer cannot always take into proper consideration the practical variations to which each mine is subject. Fan designers, accordingly, are forced to base their design on such data as the mine manager or engineer is able to supply, and, when it is borne in mind that the mine characteristic is constantly changing, it is not at all surprising that fans do not always show efficiencies hoped for. In many instances, fans work far beyond the de-signer&apos;s limitations, and, in consequence, are an economic disability in the colliery cost-sheet, and it is of paramount importance that the colliery manager evaluate all the factors involved in relation to fan performance for the colliery to receive full benefit from its investment.

Jan 1, 1941

By Philip Weaver

The MIDAS project is funded by the European Commission (DG Research) and began on the 1st November 2013. The project will investigate the environmental impact of deep-sea mineral and energy extraction: specifically, polymetallic sulphides, manganese nodules, cobalt-rich ferromanganese crusts and the potential mining of rare earth elements. As deep-sea mining becomes ever closer, and the International Seabed Authority begins to develop its regulatory framework for exploitation of deep-sea minerals, MIDAS is well timed to provide fundamental scientific information. The MIDAS partnership represents a unique combination of scientists, industry, social scientists, legal experts, nongovernmental organisations and small and medium enterprises. MIDAS is carrying out research into the nature and scales of the potential impacts of mining including 1) physical disturbance of the seabed by mining, the creation of mine tailings; 2) the potential effects of particle-laden plumes in the water column, and 3) the possible toxic chemicals that might be released by the mining process. Key biological unknowns, such as connectivity between populations, impacts of the loss of biological diversity on ecosystem functioning, and how quickly the ecosystems will recover will all be addressed. The plan is to use this information to aid development of recommendations for best practice in the mining industry. A key component is the involvement of industry within the project and through stakeholder engagements to find feasible solutions. The project will work closely with European and international regulatory organisations to take these recommendations forward into legislation. A major element of MIDAS will be to develop methods and technologies for 1) preparing baseline assessments of biodiversity, and 2) monitoring activities remotely in the deep sea during and after exploitation, including ecosystem recovery. To carry out this work MIDAS is conducting a number of research cruises to examine the above issues at potential sites for exploitation of SMS and nodule deposits. This talk will present some of the recent findings of the project.

Sep 1, 2014

By D. W. Frommer, M. M. Fine

Early in 1957 St. Joseph Lead Co. announced discovery of three new centers of iron ore deposition in east central Missouri.1 The discovery resulted from exploratory drilling in the vicinity of a magnetic anomaly or high. A deep hole, drilled into the Pre-Cambrian porphyry to determine the cause of anomaly, penetrated a magnetite-rich deposit.2 The magnetic surveys that revealed the anomalies were begun by the Missouri Geological Survey in 1929 and were continued into the 1930&apos;s 3. At that time an area in Crawford County known as the Bourbon magnetic high was located. A second anomaly, similar in size and intensity, was discovered about six miles to the northeast in Franklin County in the vicinity of Sullivan. This area was not studied in detail until the early 1940&apos;s.

Jan 3, 1959

By S. B. Castor

Proceeds from industrial mineral mining in Nevada were approximately equal to those from metal mining during the barite boom in the late 1970s and early 1980s; however, since then the economic importance of industrial minerals has been overshadowed by gold mining (Fig. 1). The total value of industrial minerals mined in Nevada increased by about 60% during the 1980s, reaching an estimated $306 million in 1990 before falling slightly in 1991. The state&apos;s most important industrial mineral commodities, in order of estimated value, are aggregate, lithium carbonate, diatomite, lime, cement, gypsum, barite, clay, silica, and magnesia (Fig. 2). Industrial minerals produced on a smaller scale are colemanite, dimension stone, dolomite, perlite, salt, and zeolite. In 1991 industrial mineral commodities other than aggregate were produced at 39 operations in Nevada. Most of these operations are located near the two major metropolitan areas of the state, or along the major transportation routes (Fig. 3).

Jan 1, 1993

By A. R. Laplante

Gold recovery early in the flowsheet, typically from the primary grinding circuit, has seen significant advances in the past three years. Some of the advances achieved under the auspices of the AMIRA P420B Gold Processing Technology project are reviewed. The areas covered are gravity-recoverable gold (GRG) characterization, GRG behaviour in classification, gravity recovery simulation and the link between gravity recovery and cyanidation.

Jan 1, 2005

By Francisco Raunelli

Anglo American Quellaveco S.A. perteneciente a Anglo American PLC, construyó las bases de la aceptación social del proyecto Quellaveco, (Moquegua) después de un largo proceso de relacionamiento social (comunitario, institucional). En ese sentido, el presente texto describe el proceso de la Mesa de Diálogo con participación del sector civil, autoridades y Anglo American, que buscó consensos para el desarrollo de Moquegua. Así el diálogo, la transparencia y la generación de confianza se ven fortalecidos mensualmente con la participación de Anglo American en las reuniones de la Comisión, donde se decide y se informa del trabajo y avances desarrollados para el cumplimento de cada uno de los compromisos asumidos. Así también se adelanta el cumplimiento de algunos de ellos considerados como prioritarios para la población, ya que los compromisos están asignados para diferentes etapas de la mina (preconstrucción, construcción, operación y cierre).

Apr 1, 2015

By Nagahiro Saito, Takahiro Ishizaki, Mituhito Hirota, Akio Fuwa

"Owing to their extremely high toxicity in the environment, the dioxins have been attracting social, technical and scientific attention in recent years. The authors theoretically had predicted the thermodynamic properties of all the dioxins via quantum chemistry and statistical thermodynamics and elucidated the generation-decomposition behavior of dioxins in the equilibrium calculation· of C-H-0-Cl system. In actual combustion processes, it is said that metallic compounds have much influences on the dioxins behavior. The aim of this study is to reveal the roles of metallic compounds the generation-decomposition behavior of dioxins is revealed from the viewpoints of quantum chemistry. Especially, the catalytic effect of copper has been investigated for the reaction, 2HCl(g)--H2(g}+Cl2(g) and for the etherification reaction from precursors, which is Phenol(g) here, to dioxins. The catalytic role of Cu is shown to have much influence on the generation -decomposition of dioxins.1. IntroductionIt is well known that dioxins are very harmful not only for our health but also for that of our children and grandchildren because they are very stable substance and their reaction rates of decomposition are considerably low. On the other hands, it is not well know how dioxins are generated and decomposed; the generation-decomposition conditions and paths as well as the catalysts to decompose them'1l. The authors believe that the thermodynamic and kinetic study of dioxins is useful to find a solution to these issuers. The authors have been investigating the following problems to reveal the generation-decomposition behavior of dioxins; (a) the prediction of the thermodynamic parameters of dioxins (2), (3), (b) the generation -decomposition behavior of non-chlorinated dioxins by the thermodynamic equilibrium calculations in C-H-O system(4) and (c) the generation-decomposition behavior of dioxins by the thermodynamic equilibrium calculations in C-H-O-CI system(5). Summaries of these thermodynamic researches are as follows.(I) The thermodynamic parameters for dioxins, which had been unknown and/or inaccurate'6 l, could be predicted and are available within the scientific accuracy."

Jan 1, 2000

By Thomas S. Mackey

The industrial types, sources, and quantities of USA tin residues are identified and the methods of treatment reviewed. The effect of a lower tin price, due to a current major world surplus of tin metal, is mentioned and covered in some detail. The names and locations of over 100 USA firms recovering tin residues are listed. Current smelting and refining charges are included to convert the residues into tin metal and alloy. The impact of the suspension of the LME daily tin price since October 24, 1985 to date, and the failure of the International Tin Council to support the Buffer Stock Manager are reported with comments.

Jan 1, 1986

By A. D. Rovig

Metallurgical evaluation of autogenous grinding of Anaconda&apos;s Berkeley Pit ores indicated that tonnage throughput increases, at a finer flotation feed size, were possible by converting autogenaus mills to steel ball mills. In addition, initial test work showed that the improved grind resulted in slight recovery gains in subsequent flotation processing.

Jan 1, 1974

By L. M. . Chia

The successful treatment of waste materials to recover metals with acceptable purity is often hampered by the presence of undesirable impurities. The problem is further complicated by the need to insure that any residues or solutions generated are environmentally acceptable. Hydrometallurgical processes involving leaching- solvent extraction-electrowinning offer some attractive features which address many of these problems. However, in certain instances trace impurities that contaminate the organics are difficult to chemically strip and interfere with the overall process efficiency. A new processing scheme has been developed which appears to provide some attractive alternatives for impurity removal from organics. It has been shown that many ionic impurities can be electrochemically removed from the organic by spontaneous direct reduction using solid metals. A variety of metal ion impurities have been removed from selected common organic extractants such as D2EHPA and TBP using different metals as the reducing agents. The results and probable mechanisms involved in the reactions are discussed.

Jan 1, 1994

By Stephen Buttling, Zhong Rui

"A single unit gas fired power station was being built on the edge of the Gulf of Thailand in 2001. The soil conditions consisted of very soft to soft Holocene Marine Clay, and the site was part of a coast line which had been subsiding below high water mark for some time. In order to provide access around the power station a road system in a figure-of-eight formation was required, and this also needed to be above the design flood level, allowing for future settlement. A ground improvement scheme was proposed and constructed, which consisted of two spacings of prefabricated vertical drains (PVD) over two depth ranges, vacuum consolidation and pre-loading, and rigid inclusions.During the construction phase, the vacuum consolidation was applied for 202 to 221 days in different zones, and monitoring allowed a prediction that the future settlement, including secondary consolidation over a period of 25 years, would be within the range of 175 to 355 mm, which met the contract requirement of less than 400 mm.The power plant was completed and became operational in 2003. Monitoring of the road levels continued, as did the settlement, and in early 2010 the total settlement since the end of vacuum consolidation had reached about 800 mm. The monitoring data both during the ground treatment and for the following 7 years is presented and analysed. This is supported by numerical analysis using 3D finite element methods which shows good agreement with the measured data, and allows a preliminary explanation as to why the predictions were so far out.BACKGROUNDAfter a period of bidding and negotiation, the Eastern Power and Electric Co Ltd (EPEC), an Independent Power Producer, entered into an agreement with the Electricity Generating Authority of Thailand (EGAT) in November 1997 to sell them power. In 1999 an Engineering, Procurement and Construction (EPC) contract and an Operation and Maintenance contract were signed with a supplier to provide a gas-fired (with oil as a back-up fuel) 350 MW combined cycle power plant in Bang Bo, Samut Prakarn Province, east of Bangkok. The site of the plant at Bang Bo is located immediately to the east of the Samut Prakarn Wastewater Treatment Plant, adjacent to the Gulf of Thailand (see Figure 1) in an area of very soft to soft marine clay (Bangkok clay) having low shear strength and potential for excessive settlement. The site layout comprises the main Power Plant components of generating block, cooling towers, fuel unloading area and storage tanks, switchyard and administration block, separated by access roads."

Jan 1, 1900

By L Keeney

Cu-Au porphyry deposits are large tonnage low-grade resources dependent on processing large volumes of material. The ability to understand and predict comminution performance is critical, as it is frequently the rate-limiting step during processing. Parameters required from geometallurgical mapping and modelling of comminution performance are: A×b processing domains based on impact breakage variability, and BMWi processing domains showing grind response variability which lead to Mine throughput domains for a specific comminution circuit configuration. Due to the cost and/or large sample requirements of traditional comminution tests, insufficient data density and distribution of comminution indices commonly exist, making it difficult to model and map deposit scale variability. One method routinely applied to three dimensional domaining is to have an a priori zoning based on geological features (lithology, alteration, mineralogy, textures), and then apply to all material within a given domain the metallurgical values measured on a single sample or average of samples from that domain. The problem with this approach is that commonly the geological domains do not reflect comminution response, therefore compromising the quality of the average domain estimate. To resolve this problem an alternate integrated geometallurgical mapping and modelling method is applied to model and map comminution performance at Cadia East. This paper uses a data set of ~32&nbsp;000 assay measurements and geological logging information, integrated with ~150 comminution measurements to analyse and develop proxy support models for comminution indices (ie A×b, BMWi, and throughput) based on inherent geological variability. Discrete downhole comminution processing domains are created, mapping orebody response while maintaining inherent variability.

Sep 5, 2011

By Pierre Filiatreault, Brian Straight, Stephanie Thibeault, Devin Castendyk, Londie Cameron

"Working on or near water at active, closed or abandoned mine sites is inherently dangerous. Between 1996 and 1999, the U.S. Mine Safety and Health Administration (MSHA) reported 17 fatalities involving drowning at U.S. metal, non metal and coal mines (MSHA, 2000). Openpit mines which fill with water following mine closure, called pit lakes, present numerous risks to environmental monitoring teams including: a) drowning, b) hypothermia, c) falls to the ground from the top of high walls, d) collapse of unstable access roads, e) rock falls and avalanches from pit walls, f) avalanchegenerated tsunamis traveling across the lake surface and g) rapid degassing events.Some pit lakes are simply not safely or easily accessible for ongoing monitoring. However, the routine collection of water samples from the entire water column on a regular basis is needed to monitor the evolution of water quality over time, verify the accuracy of numerical predictions and, ultimately, manage lake water chemistry and ecological risks. For pit lakes with surface water discharge, regular monitoring is used to appropriately design and adjust water treatment plants in order to produce acceptable site discharge water quality.As a product of these risks and the need for water samples, mining companies spend considerable expense on pit lake safety as part of monitoring programs. This includes training personnel for on water duties and hazards, purchasing or hiring specialized equipment and personnel (such as boats, boat operators, personal floatation devices and cold-water clothing called mustang suits), stabilizing pit walls and maintaining safe access roads to the lake surface and employing spotters who can directly communicate with emergency medical services to watch sampling activities because cell phones and radio signals can be blocked by pit walls. Some sites utilize redundancy to prepare for unexpected incidents and accidents. For example, one Canadian mining company requires two boats on the water during pit lake sampling events, with a third boat on the shoreline, gassed and ready to go. In addition, water samplers are required to hold Marine Emergency Duties training to ensure the entire boat crew is sufficient and competent for the safe operation of the vessel in the event of an accident."

Jan 7, 2017