Search Documents

By M. Hancer, J. D. Miller

The sign of the surface charge of selected potassium soluble salt minerals namely KClO4 , K2SO4 , KNO3, and KCl was determined from nonequilibrium electrophoresis measurements and found to be negative for each of the salt. Dodecylamine flotation of these salts revealed that the concentration of amine required for flotation increases in the order KClO4< K2SO4< KNO3<KCl. Precipitationof the amine collector colloid was not required for flotation of the oxyanion salts and in this case it appears that adsorption of the dodecylamine cation is sufficient to create the hydrophobic surface state. The order for flotation is explained in terms of surface hydration of these respective potassium salts based on contact angle measurements and FT Raman spectroscopic characterization of water structure.

Jan 1, 1999

By Kim Lapakko

Increasing public concern over the welfare of the environment has placed demands on the mining industry to evaluate the environmental impact of mining development. This is a difficult task and involves considering the influence of a multitude of variables on complex processes over a long time period. Few studies which focus on the evaluation of the environmental impact of mining have been conducted and, therefore, there is little past experience to rely upon. This article describes some of the work done to evaluate the potential environmental impact of mining development in Minnesota. Interest in developing the major copper and nickel sulfide deposits near the wilderness areas of northeastern Minnesota aroused concern regarding the environmental impact of mining development in the region. As a result laboratory and field studies were initiated to investigate the potential for trace metal leaching and acid generation due to dissolution of Duluth gabbro. Chemical equilibrium computer modeling was conducted to aid in data interpretation. The goals of the study included the investigation of leaching mechanisms and rates of release (1, 2).

Jan 1, 1980

By Rosana Silva Xavier

Compósitos magneto-elétricos (ME) combinam fases magnetostrictivas e piezoelétricas e podem ser utilizados na geração de energia a partir de vibrações e campos magnéticos presentes no ambiente, sendo também aplicáveis em sensores de campo magnético e em redes de sensores sem fio. Neste trabalho, um compósito ME foi processado pelo método cerâmico com 15 vol% CoFe2O4 (ferrita de cobalto) como fase magnetostrictiva e 85 vol% BaTiO3 como fase piezoelétrica. É mostrada a relação entre os parâmetros de processamento/sinterização e a microestrutura do compósito ME, com três tipos diferentes de arranjo das fases: particulado (obtido por dois diferentes métodos) e em camadas. Foram compactadas pastilhas dos compósitos para sinterização nas temperaturas de 1.200ºC, 1.300ºC e 1.400ºC por 4h, sendo que ocorreu a fusão da pastilha sinterizada a 1.400ºC. As amostras sinterizadas foram observadas em microscópio eletrônico de varredura (MEV), onde foram analisadas as características de porosidade, tamanho de grão e a distribuição das fases na microestrutura. Foram realizadas também análises cristalográficas por difração de raios-X (DRX), de espectroscopia RAMAN e de espectroscopia de energia dispersiva (EDS). Foram relacionados os parâmetros de processamento utilizados com os resultados obtidos.

Aug 8, 2018

By I M. Platten, Y Xie

Complex gold deposits are generally characterised by variable geometries, strong structural controls on grade distribution and a high-nugget effect. The use of diamond drilling and fire assays in this environment often results in an understatement of grade. Bulk samples are likely to be the closest estimators of true grade, and may be required to evaluate geological/grade risk during resource estimation/feasibility studies. Any bulk sampling program requires appropriate planning and implementation. The planning stage should attempt to delimit the extent and nature of mineralisation; characterise mineralogy and metallurgical properties of the ore; and define bulk sample size and how it will be sampled/processed. The approach to sample processing will be governed by the results of metallurgical testing and geological knowledge. Careful design of sampling protocols must be undertaken through material characterisation, understanding of gold particle sizing and the application of GyÆs Sampling Theory.

Jan 1, 2008

By Bin Xu, Qian Li, Qiang Zou, Yongbin Yang, Long Hu, Tao Jiang, Xuefei Rao

The recovery of palladium from the chloridizing leaching solution of spent Pd/Al2O3 catalyst was studied mainly by sulfide precipitation tests and chemical composition analysis. The effects of key parameters including sodium sulfide concentration, pH, addition rate, temperature, and stirring speed on palladium precipitation efficiency are systematically investigated and optimized.

Mar 1, 2017

By K. W. Deter

The gold ores in the Jerritt Canyon district have been recognized as refractory since they were first encountered by FMC geologists in 1976. Upon obtaining managing rights as joint venture partner, Freeport McMoRan Inc. developed an operating plan featuring carbon-in-leach gold recovery techniques for the oxide portion of the ores and a patented sulphide oxidation step followed by chlorination for treating the organic carbon constituents of the refractory ores prior to CIL gold recovery. The plant was successfully started up in 1981 with the first gold poured on July 4, 1981. Initial plant throughput was designed to be 2495 MTPD (2750 STPD) total through the dual processing trains.

Jan 1, 1991

By C. D. Messelt

The Bureau of Mines investigated the application of a diffusion model to sintering rate data developed for lithium titanium ferrite. The data were obtained by sintering pressed pellets under identical conditions for various times up to 11 hours. Stereological measurements were made on polished sections, and sintering rates were calculated. A model for intermediate stage sintering was fitted to the stereological data. This procedure produced a method by which these type data could be used to study the relative importance of volume and grain-boundary diffusion under a variety of sintering conditions.

Jan 1, 1979

By O. V. Suvorova, V. G. Minenko, D. V. Makarov, A. L. Samusev, E. A. Selivanova

"Saponite is a valuable marketable product widely used foundry, metallurgy and construction, in the chemical, food and consumer goods industries, in medicine, and in agriculture.The feasibility of producing of high-quality construction materials with enhanced physical-chemical and decorative characteristics from saponite-containing products has been given a scientific basis and experimentally validated. The compressive strength of the samples in the sintering temperature range of 800-1000 ?? varied between 35 and 80.9 MPa; the bending strength 8 and 26.7 MPa, which is superior to the high-grade ceramic bricks of the M-300 brand. It has been established that the saponite-containing product obtained using the electrochemical separation of process water has a high sorption capacitance relatively the heavy-metal ions such as nickel and copper (40.7 and 99.8 mg/g, respectively). As a result of sintering at 750 ?? the sorption capacity of the sorbent for the nickel and copper ions increased to 194.2 and 212.8. Using the XRD and SEM with energy-dispersive spectroscopy studies, we diagnosed the metal-containing phases and validated the metal sorption mechanism.This study opens up the possibility of practical realization of the saponite-containing product as high-quality building materials and heavy-metal sorbents while addressing the issue of process water treatment. INTRODUCTION The Lomonosov deposit of the Archangelsk diamondiferous province accommodates 10 kimberlite pipes. The anticipated volume of diamond-bearing ore and dump rock to be removed before reaching the open-pit mining limit is 300 mln t (Karpenko, 2009; Bezborodov, etal. 2003). Rock in the deposit is almost completely displaced by clay minerals, predominantly saponite, amounting to 90% in the vent facies (Karpenko, 2009)."

Jan 1, 2018

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

It was determined by the authors that the water that remains in the filter cake after filtration in iron ore concentrators can contain several hundred times greater concentrations of calcium ions and other cations, due to surface chemical effects carrying the ions along with the water. Filter cake from two plants was analyzed. The water retained in samples of magnetite concentrate filter cake in Plant 1 contained 5088 ppm calcium and 5995 ppm magnesium, while the Plant 2 filter cake contained 231 ppm calcium and 119 ppm magnesium. These levels were dramatically elevated compared to the water that was removed from the concentrate by filtration for recycle to the plants (9 ppm calcium/15 ppm magnesium for Plant 1, and 11.9 ppm calcium/9.3 ppm magnesium in Plant 2). In addition to possible effects on agglomeration performance, the presence of these cations also affected the efficiency of filtration. In order to reduce the effects of these cations on filtration in Plant 2, carbon dioxide was injected into the slurry before it entered the filter press. This was found to increase filtration rates by up to 23.7%. Comparison of the results from the two plants shows that the concentrations of cations present in the filter cake will vary greatly from plant to plant, with correspondingly large variations in their effects on plant operations.

Jan 1, 2004

By B. Dubreuil, J. -M. Lalancette, D. Lemieux

A gold bearing pyrite concentrate was treated at the pilot scale for the extraction of gold. Mineralogical analysis of the concentrates identified gold to be mainly present in the form of a solid solution in pyrite. Gold distribution resulted in a poor extraction yield of 55 % by direct cyanidation. A piloting campaign including an oxidative pre-treatment by roasting in a fluid bed was followed by treatment with halogens for gold extraction and has led to a gold extraction yield of 94%. Sulphur removal during the oxidation was very efficient at >99.5% and gold extraction by the halogens was completed within a 1 hour contact time. The piloting was performed on a 300 kg sample and used a diluted solution of hypohalites as the oxidizing agent for gold extraction. Sulphuric acid was injected in the reactor during the halogens treatment to lower pH to 2. The diluted solution of hypohalites (1-3%) was generated by electrolysis during the piloting campaign in a diaphragm-less electrolysis cell. The extracted gold was recovered via adsorption over silica and the gold depleted brine was treated for impurities removal. This brine was recycled for further gold extraction. With the recycling of water and brine, the regeneration of hypohalites and with a barren solid that is inert and stable, the Nichromet Extraction technology is a green process where the protection of the environment does not preclude profitability.

Jan 1, 2014

By P. James

"INTRODUCTION Control of target stream acidity is widely used in MIW (mining influenced water). Tailoring pH (a measure of acidity) finds application for controlling key chemistry in both process and waste streams. Traditional lime addition for neutralization and precipitation is most often used but has high reagent costs and results in large amounts of mixed metal sludge requiring costly disposal. A new adaptation of BPS’s patented DEMET™ technology (Dynamic Electrolytic Metal Effluent Treatment) platform offers a potentially improved and “reagentless” alternative to traditional chemical addition for pH adjustment. Electricity rather than chemical addition utilized in BPS’s proprietary approach controllably tailors target stream pH. The method offers a simple, low-cost processing technique yielding cleaner treatment chemistry. BPS’s “green” approach may yield lower operating (OPEX) and life cycle costs and significant reductions (up to 50%) in sludge generation compared to conventional lime treatment. It can also allow new opportunities to generate revenue via selective recovery of valuable processing byproducts. Specific savings and revenues depend on the target site chemistries, details, and processing goals. A more detailed discussion of the process and its operational principles may be found in Reference One.[1] Here application of the BPS treatment to POx (Pressure Oxidation) leaching as an alternative to traditional chemical addition is examined. An example operation process flow for gold mining is considered.[2] Promising processing points for potentially replacing conventional processes with DEMET are noted. The possibilities for lowering OPEX costs, lessening sludge creation, and capturing various valuable byproducts and residuals are examined. Financial life cycle benefit estimates of the principal gains provided by DEMET application to the example operation are noted. Extension and generalization of the analyses to a wider range of scenarios is explored."

Jan 1, 2016

By M. O. Lai

"Metal matrix composite (MMC) with composition of Al-4.Swt.%Cu reinforced by IOwt.%TiB2 or ISwt.%SiC particulate has been successfully fabricated using powder metallurgy technique. Disk, compression and beam specimens were prepared with (a) layered structure containing ductile Al-4.Swt.%Cu with brittle Al-4.Swt.%Cu/TiB2 or Al-4.Swt.%Cu/SiC layers, and (b) homogenous constituent with composition of Al-4.Swt.%Cu/lOwt.%TiB2' The specimens for the fracture toughness measurement were built through three ductile-brittle-ductile alternating layers. For the beam specimens, the layers were built through brittle-ductile-brittle sequence. The brittle layer consisted of Al-4.S%Cu with fixed amount of reinforcement. Fracture toughness testing revealed an increase for layered composites although the total amount of the reinforcement was the same for all disk specimens. The increase in fracture toughness is due to the existence of ductile layers which manifests a strong influence on delaying the occurrence of fracture. It acts as a barrier to resist the propagation of crack and hence increases the fracture toughness of the layered MMC specimens, Delamination in the beam specimens was observed to be due to shear stresses. Fracture surfaces of both disk, compress and beam specimens were characterized using the SEM. IntroductionMechanical and thermal properties can be achieved by the incorporation of refractory secondary phases to constrain the plastic flow of the matrix in a metal matrix composite (MMC). The size of the reinforcement particulate incorporated must be in the range larger than the dislocation cell size and strongly bonded to the matrix (I). Particulate reinforced metal matrix composites hence provide high modulus, improved wear resistance and strength (2-4). Because of the incorporation of refractory phases which are generally brittle, the major limitation in the mechanical properties of MMCs is their limited ductility in comparison to their base metals. Cracks normally initiate from the reinforcement and voids (4, 5). Due to the lack of ductility, cracks propagate rapidly with increase in load. As a result, the interactions between reinforcement particles and propagating cracks have recently been of great research interest (6). In addition, volume fraction of reinforcement and aging condition of the matrix significantly affect the mechanical behaviour of MMCs. In the case of AI-3.5%Cu reinforced with varying volume fractions of SiC particulate, it has been found that the probability of particle fracture increased with increasing volume fraction of reinforcement (7)."

Jan 1, 1996

By L. Mark Irwin, R. A. Marsyla

The objective of this laboratory investigation was to develop a mattesmelting process for the recovery of copper from industrial smelter dusts . Experimentation was conducted on three samples of Cottrell precipitator dust from a northern Michigan smelter with variations in the following conditions : Temperature , charge composition , pelletization , and moisture content . Based on chemical analyses of the furnace slags , poorest recovery of copper was effected in smelting dry charges regardless of composition . Some improvement was noted with uniformly moistened charges and still more with pelletized (but dry) mixes , but best results were obtained from smelting moist , self - fluxing pellets . Under favorable conditions , experiments yielded furnace slags with an average copper content of only 0.15 percent , which is well below that of industrial copper reverberatory slags .

Jan 1, 1963

By Yu. E. Emelyanov, A. V. Bogorodsky, R. N. Nabiulin, S. V. Balikov

"The paper describes the results of the study of gold-copper flotation concentrate atmospheric oxidation at different sizes of material, varying oxidation time, with air or oxygen blow. The study showed the low rate of sulphide oxidation during oxidation of flotation concentrate at a feed size (P98 -74 µm). The coppery recovery into solution was 48%; the recovery of gold by subsequent cyanidation reached 86%. Preliminary flotation concentrate grinding to P98 -20 µm provided oxidation of 90% of copper minerals, 80% of arsenopyrite and 15% of pyrite. The gold recovery by atmospheric oxidation of a fine-ground flotation concentrate increased by 59%, from 36% to 95%, the NaCN consumption reduced by 21 kg/t, from 30 to 9 kg/t. INTRODUCTION Processing of sulphide gold-copper ores and concentrates using conventional cyanidation technology results in higher reagent consumption and lower gold recovery. Destruction of sulphide minerals and extraction of copper from a processed product prior to cyanidation is essential for improving efficiency of precious metals recovery and reducing main reagents consumption. Atmospheric oxidation (AO) is one of the most promising hydrometallurgical methods of refractory gold-copper concentrates processing, along with biooxidation and pressure oxidation. The nature of this approach lies in oxidation of sulphides at 90-95°C, in acidic or alkaline conditions, with bubbling of oxygen or air, after preliminary ultrafine grinding (1-4). The following reactions of sulphide oxidation occur during atmospheric oxidation of a gold-copper flotation concentrate. Pyrite is oxidized with the formation of ferric sulphate (1) and elemental sulphur at low temperatures (2), whereas some portion of elemental sulphur reacts to form sulphuric acid: FeS2+3,75O2+0,5H2O=0,5Fe2(SO4)3+0,5H2SO4; ?G=-1144,02 kJ/mol (1)"

Jan 1, 2018

By M. L. Leblanc, J. F. Burzynski, D. J. Mossman

A strong heterogeneity in the distribution of Sb+/-Au deposits exists within the North Atlantic Acadian-Hercynian domain. This is reflected in the regional disparity in Sb production among the various producing countries. This work focuses on the nature and distribution of Sb+/-Au occurrences in the Acadian-Hercynian domain. A summary listing of the general features of Sb-Au deposits found in this area is given

Dec 1, 1991

By M. A. Trevits, J. E. Urosek, A. C. Smith, M. P. Valoski

Unlike other types of mining accidents, where an incident generally involves only a few workers, the danger of a mine fire extends to every person working in the underground environment. Mine fires can trap or kill those working underground by blocking avenues of escape and rapidly creating heat, asphyxiating gases and toxic fire products that can quickly spread throughout the mine. The National Institute for Occupational Safety and Health (NIOSH), in partnership with the Mine Safety and Health Administration (MSHA), is conducting research to test, evaluate and improve or modify coal mine fire-fighting strategies and methodologies through large-scale tests. Because wood is the second most abundant fuel available during a coal mine fire, it was decided that a series of large-scale wood crib fire tests was needed to measure the products of combustion and to observe the capability of commonly available direct application fire suppression equipment, namely, fire extinguishers, water and gas-enhanced foam. This paper discusses the wood crib fire tests, provides insight into the products of combustion and describes observations made during the application of the fire suppression agents.1

By Thomas L. Hurst, Joseph M. Hans

INTRODUCTION The former Shiprock uranium mill site is located in the community of Shiprock, New Mexico on a bench overlooking the San Juan River (Figure 1). Both Shiprock and the mill site are located on the Navajo Indian Reservation. The millsite was built on a 230 acre tract leased by Kerr-McGee Oil Industries Inc., and was operated from 1954 to 1963. The Vanadium Corporation of America and its successor, the Foote Mineral Company, operated the mill from 1963 to 1968. During its entire operation, 1.5 million tons of uranium ore was milled producing 3711 tons of U308 concentrate. The concentrate was sold to the former U.S. Atomic Energy Commission. During milling, the ore was crushed to less than 35 mesh and acid leached to remove the uranium. The [ ] uranium was removed from the leach solution by solvent extraction and the uranium-barren solution discharged into raffinate ponds for disposal by evaporation and seepage. The spent solids (tailings) were pulped with waste process fluids and water and discharged to form tailings piles. The piles (ponds or dams) were formed with earth starter dikes. The dike walls were then raised using the separated sand fraction of the tailings. The slime fraction of the tailings were discharged into the diked impoundment. Since only a small fraction (0.25 percent) of the ore was U308 by weight, most of the ore bulk ended up as wastes. The wastes contain nearly all of the uranium decay chain radionuclides present in the ore except uranium. The mill was shut down and partially dismantled before the lease expired in 1973, and the remainder of the mill and wastes reverted back to the Navajo Tribe which was the lessor. Portions of the millsite were then occupied by the Navajo Engineering and Construction Authority (NECA), a Tribal enterprise. In order to provide skilled personnel to operate earth moving equipment, a heavy equipment operator&apos;s training school was also established on the mill site and was administered and operated by NECA. The U.S. Public Health Service (PHS) and the Environmental Protection Agency (EPA) staff conducted radiation surveys at four inactive uranium millsites on the Navajo Reservation in April 1974. During the survey of the Shiprock millsite, it was noted that the training activities were degrading its radiological condition. Both the PHS and EPA staff recommended that the training activities be directed towards the decontamination of the millsite area and interim stabilization of the tailings piles. Preparation for the decontami-nation work commenced in April 1974. In order to facilitate the decontamination activities, the mill site and its contaminated environs were divided into major areas labeled A through F (Figure 2). Areas A, B, and C are defined as "perimeter" areas and contained surface contamination ranging from 5 to 30 cm deep. Area D defined the mill yard and contained contamination ranging from 0.6 to 5.5 m deep. Area E contained several raffinate ponds which were removed to line up the northwest boundary of the tailings pile and to move the contaminants away from the vicinity of the occupied on-site buildings. The contaminants in Area E ranged from 0.05 to 5.5 m in depth. Area F encompassed the ore storage yard. Contaminants in this area ranged from 0.18 to 1.2 m deep. Washes, however, had contamination exceeding 7.6 m deep.

Jan 1, 1981

By H. E. Criner, M. G. Driessen

Maurice Rey—The influence of cyclone diameter upon the fineness of separation is an important point which, however, cannot be discussed adequately if the injection pressure or the rate of flow are not specified. Perhaps some light can be thrown on the matter by using the formulas derived by Dahlstrom. Let us consider several geometrically similar cyclones where the apertures e and b are equal and proportional to the diameter D and which are operated with the same pressure drop. Eq 8 of Dahlstrom&apos;s paper can be written: Q Q = K D&apos;. " or. if F is constant: Q = K D18 K is a constant of proportionality. Introducing this value of Q in eq 13 gives elimination efficiency = K D ,41 Elimination efficiency, in the terminology of Dahl-strom, means the diameter of particles, in microns, which divide equally between the underflow and the overflow. This denomination is regrettable and it would be preferable to call it diameter of separation or characteristic size or any other name connoting a size rather than an efficiency. Whatever the name used, the above equation shows a slow increase in the fineness of separation when the diameter of the cyclone decreases. For example, if a 14-in. cyclone gives a 400-mesh separation (37 microns), geometrically similar cyclones, having the same pressure drop will give separations at the sizes shown below.

Jan 1, 1951

By M. G. Driessen, H. E. Criner

Maurice Rey—The influence of cyclone diameter upon the fineness of separation is an important point which, however, cannot be discussed adequately if the injection pressure or the rate of flow are not specified. Perhaps some light can be thrown on the matter by using the formulas derived by Dahlstrom. Let us consider several geometrically similar cyclones where the apertures e and b are equal and proportional to the diameter D and which are operated with the same pressure drop. Eq 8 of Dahlstrom&apos;s paper can be written: Q Q = K D&apos;. " or. if F is constant: Q = K D18 K is a constant of proportionality. Introducing this value of Q in eq 13 gives elimination efficiency = K D ,41 Elimination efficiency, in the terminology of Dahl-strom, means the diameter of particles, in microns, which divide equally between the underflow and the overflow. This denomination is regrettable and it would be preferable to call it diameter of separation or characteristic size or any other name connoting a size rather than an efficiency. Whatever the name used, the above equation shows a slow increase in the fineness of separation when the diameter of the cyclone decreases. For example, if a 14-in. cyclone gives a 400-mesh separation (37 microns), geometrically similar cyclones, having the same pressure drop will give separations at the sizes shown below.

Jan 1, 1951

By Nicola Baldo, Marco Pasetto

"Recycling of tyre rubber in the road pavement, may be one of the best way to reduce waste tires in large quantities and, at the same time, improve some engineering properties of asphalt mixtures. The paper discusses the results of an experimental study, developed in order to analyse the potentialities of crumb rubber from road tyres in bituminous mixtures, using the dry process. Two types of porous asphalt mixtures and reference mixes without rubber were formulated by the traditional Marshall methodology, and mechanically evaluated by means of the Indirect Tensile Stiffness Modulus test, the Creep test (with confinement), and the Indirect Tensile Fatigue Test. Results of this study indicate that the tyre rubber has a positive influence on the performance characteristics, depending also on the grading and volumetric properties of the mix being studied: an interesting increase of the fatigue life, a better stiffness behaviour at lower temperatures and a bigger permanent deformation resistance at high temperatures are guaranteed. Introduction Recycling the rubber from used tyres, in the construction of road pavement layers, is potentially one of the more interesting and advantageous solutions from both the technical and environmental points of view, in order to reduce the total amount of car and lorry tyres to dispose. In road-building techniques, a technology, termed “wet”, for modifying bituminous binders with crumb rubber has by now become well consolidated. There have been numerous scientific studies conducted on this technology and its applications, particularly in the United States, where it has been adopted and codified in specific technical regulations (ASTM D-6114). If the wet process can be considered amply tested, the same cannot be said for a second technology, termed “dry”, which deserves careful study to evaluate its suitability and advantages. In “dry” processes, the rubber is usually used as a partial substitute of aggregate of equivalent grading and mixed with bitumen after integrating the crumb rubber in the lithic skeleton."

Jan 1, 2008