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By B. W. Howlett, M. B. Bever, Somnath Misra

The heats oj- formation at 0°C of the compounds AuSn,, AuSn2, AuSn, and the £ phase were measured in a metal -solution calorimeter with liquid tin or a liquid Sn-Bi alloy as solvent. The melting point, heat of fusion, and heat capacities near the melting point of- the compound AuSn in the solid and liquid state were measured in a constant temperature gradient calorimeter. The free energy and entropy of formation of the compound AuSn at its melting point and at 298 °K were calculated from the experimental results and published data. The heats of formation are discussed in relation to the nature of the compounds. The heat capacity below the melting point, heat of fusion, and entropy of fusion of AuSn are interpreted in terms of processes oc-curring before melting. The atomic arrangement in liquid Au-Sn alloys and the bonding in the intermediate phases of. the Au-Sn system are discussed in the light of the measured thermodynamic properties. THE available thermodynamic information on the intermediate phases in the Au-Sn system consists of the heats of formation of the compounds AuSn4, AuSn2, and AuSnly2 and of one composition of the < phase2 besides values of the heat content of the compound AuSn from 0" to 635".&apos; However, the heats of formation refer to different temperatures ringing from 90" to 450°C. Also, the reported error limits of some of the values are large and several inconsistencies are apparent. In the investigation reported here the heats of formation of the compounds AuS-, AuSnz, and AuSn and of three compositions of the < phase were determined for a single reference temperature of 0°C by liquid metal-solution calorimetry. The compound AuSn, which is the only congruently melting intermediate phase in this system, was further investigated in a constant temperature gradient calorimeter by measuring its heat of fusion, melting point, and heat capacity in the solid and liquid states near the melting point. From these data and published free energies of the liquid of composition Au~n,&apos; the free energies of formation of the compound AuSn at the melting point and at 298°K were calculated. The results shed light on the solid-liquid transition of AuSn and on the atomic bonding and state of association of gold and tin in the solid and liquid phases. 1) EXPERIMENTAL PROCEDURES 1.1) Preparation of Samples. Stoichiometric amounts of gold and tin, each 99.99+ pct pure, were melted in evacuated Vycor capsules (12 mm ID). The melts were maintained approximately 150°C above the liquidus for about 12 hr and shaken repeatedly. Samples of the compound AuSn were cooled slowly to room temperature. Melts of the other phases, all of which solidify by peritectic reactions, were transferred to the narrow end (5 mm ID) of the capsule, which was then quenched into iced brine. The solidified samples were annealed in the unopened capsules for 10 days at 30" to 50° C below the respective solidus temperatures. The absence of microsegregation and second phases was confirmed by metallographic examination. At least two batches of each composition were prepared. 1.2) Solution Calorimetry. The heats of formation were determined by liquid metal-solution calorimetry. In this technique, the difference between the heat effects on dissolution in a liquid metal, or alloy bath, of the compound and a mechanical mixture of its annealed components, adjusted for changes in composition of the bath, is the heat of formation of the compound at the temperature from which the samples are added. Details of the equipment and technique have been described."&apos; A tin bath at 300" or 350°C was used with the compounds AuSn,, AuSnz, and AuSn. The high gold content of the £ phase would have caused it to dissolve with an appreciable exothermic heat effect. In order to achieve thermal compensation, the samples were added from 0°C to a bath at 350°C consisting of 66.2 wt pct Bi (99.999+ pct pure), balance Sn (99.99+ pct pure). This solvent gives thermal compensation because gold dissolves exothermically in tin and endothermically in bismuth. The calorimeter was calibrated by adding from 0°C approximately 0.015 g-atom of the solvent.

Jan 1, 1965

Notices Competition for Student Members of the South African Institute of Mining and Metallurgy Each year the Institute offers a prize (or prizes should the entries warrant it) of up to Rl00 for the best paper or dissertation on a topic appropriate to the interests of the Institute. The competition is open to all Student Members of the Institute. NEW PUPLICATION Bougainville-the establishment of a copper mine. St. Kilda (Australia), &apos;Foundations&apos;, 1973. The editors of Foundations, Australia&apos;s journal of architecture, engineering, and construction, are preparing the above book for publication late in 1973. The story of Bougainville is told and illustrated NIM REPORTS Report No. 1503 Fast-neutron-activation analysis for the determination of oxygen m rock sam ples. Report No. 1514 The determination by X-ray-fluorescence spectrometry of minor amounts of niobium and tantalum in geological materials. Report No. 1530 AUREOL - an X-ray-absorption analyser for the determination of the uranium on loaded resin in ionexchange plants. Report No. 1534 The determination, by atomicabsorption spectrophotometry, of noble metals in the presence of sodium, barium, or sulphate ions. A comparison of uranium and lanthanum as &apos;releasing agents.

Jan 10, 1973

By Robert Glass Cleland

THIS IS a history of a company whose roots run deep into the nation&apos;s past and whose field of operations has never been narrowly confined. The men who founded Phelps Dodge were men of initiative and imagination. They were men of strong convictions and upright character. They held fast to the simple virtues and traditions of the days when America was young. This heritage they passed on to their successors. From the very beginning, under such leadership, Phelps Dodge became a company of large affairs. It bought and sold, exported and imported, built factories and organized railroads, converted great forests into lumber, and operated coal and iron mines. Much of the iron, copper, and tin plate used in the United States for a generation was under its control. Its business abroad was extensive enough to warrant the organization of a separate partnership in England. Then, almost half a century after its foundation, the company began to substitute new activities for old and eventually transferred its major operations to the West, primarily to Arizona. The family partnership became a corporation. Exporting and importing gave place to mining and metallurgy. Phelps Dodge became one of the largest

Jan 1, 1952

By Brian H. Zelenko, Patricia M. Perry

INTRODUCTION The environmental requirements of the next section of Washington, D.C. METRO subway tunnels present unique challenges to the Contractor. The 14th Street Tunnels contract includes twin 975 m (3200 linear ft) soft ground tunnels. A stringent environmental soil and groundwater monitoring and free product recovery program was specified by the owner. A project-wide dewatering program hinges on satisfactory completion of the environmental requirements. Implementation of the Contractor&apos;s environmental program is discussed, including the pros and cons of the program, as they relate to progress of the project. Environmental issues on tunneling projects have become an important part of the urban tunnel construction process. Delays associated with environmental issues can have a major cost impact on tunneling projects. This paper will discuss the first of five Washington Metropolitan Area Transit Authority (WMATA) tunnel and station contracts awarded in 1994. These contracts are part of WMATA&apos;s Fast Track Plan to complete the original 166 km (103 mile) system by 2001. As such, stringent environmental requirements have been specified as a part of these contracts to limit delays associated with local regulators in order that the tunnels may be constructed on schedule.

Jan 1, 1995

By Borsaru M

The production of high-grade calcined bauxite is very dependent on the moisture content of the final product. Existing procedures rely on the ignition of small samples to monitor the effectiveness of the calcination process. The results obtained by this gravimetric technique are several hours behind production and do not permit regular adjustment of the furnace to optimize the control of the chemically bound water content (LOI).To provide rapid and hence more relevant results, a neutron moderation technique has been developed for measuring the LOI of bulk samples of calcined bauxite while they are still hot. The method uses fast neutrons from an 241 Am-Be neutron source to irradiate the samples, and the backscattered thermal neutrons detected are a measure of bound moisture content.The rms deviation between neutron and conventional determinations of LOI, in 15 calcined bauxite samples, was 0.08 per cent LOI over the range 0.1 to 0.9 per cent LOI. When allowance is made for the rms error in the ignition method, the error in the neutron method is found to be 0.07 per cent LOI.

Jan 1, 1985

By J. D. Miller, C. L. Lin

In general, x-ray computed tomographic (CT) techniques are able to provide 3D images of the internal structure of opaque materials in a nondestructive manner. The unique cone beam geometry allows acquisition of all 2D projections with only one rotation of the sample thus providing for fast data acquisition and better x-ray utilization, as a complete 2-D detector array receives the cone-shaped flux of rays. Thus, an isotropic 3D volume can be reconstructed without the mechanical translation and the stacking of sequential slices as is the case for more conventional CT scanners. In this regard, a state-of-theart, custom designed x-ray microtomography facility to provide very detailed 3D spatial analysis of multiphase particles has been installed and is in operation at the University of Utah. The reconstructed 3D tomographic volume allows for an adjustable spatial resolution from 5 to 20 microns for sample dimensions from 10 to 40 mm in diameter, respectively. For example, a packed bed of coal particles is shown below in which different crystalline froms of pyrite are distinguished in 3D.

Jan 1, 2003

By Peter G. Smith

Tri-calcium aluminate (TCA) is a dominant alkaline component of the red mud residue from the Bayer process. A method being considered for industrial implementation partially neutralizes the residue by contacting it with gaseous CO2. This paper outlines the chemistry of CO2neutralisation of TCA under conditions relevant to the treatment of Bayer residue. CO2 neutralisation of the liquor is fast. It results in the formation of amorphous aluminium hydroxide and dawsonite that agglomerate together. Neutralisation of solid TCA is slower and leads to the formation of calcite, dawsonite and amorphous aluminium hydroxide. The dissolution of TCA in partially neutralised slurries causes pH reversion. However the carbonated solutions contain a store of bicarbonate that can supply aqueous carbon dioxide to complete the transformation. The pH at which the carbonation is carried out will affect the degree of TCA transformation during the carbonation process. In particular, if the pH of the carbonation is too low (near 7.0), calcite precipitation is inhibited and the degree of transformation is low. Controlling the carbonation pH helps to optimise the neutralisation process.

Jan 1, 2003

By Poltak Sinaga

PT Kaltim Prima Coal&apos;s 13.1 km overland conveyor was commissioned in 1991. It is of conventional 3 roller 350 troughed belt type. Cost and performance optimisation during initial design ended up with 5.4m/s belt speed, 1,000mm belt width to convey 1,350tph, and 7mtpa of coal. Despite high initial figure, the belt speed was lifted to 6.5 mps in 1996 to accommodate mine throughput increase. In 2002, new low loss ST2100 1,100mm wide belt replaced the old ST2250 due for change-out. An upgrade project was initiated at the end of 2003 to further increase the belt speed to 8.5 mps, hence to increase the OLC capacity to 30mtpa. Performance data, experience of site personnel, site observation and tests, benchmarking, and information from equipment manufacturers were major inputs to the design review. The project fast track was another challenge in addition to executing modifications on a production lifeline. The project was completed within fifteen months and the OLC was successfully commissioned at 8.5 mps belt speed in February 2005. The OLC has been to date conveying 4200tph satisfactorily.

Jan 1, 2008

In the three years to June 2005, 959 injuries associated with continuous miners (CMs), shuttle cars (SCs), load-haul-dump and personnel transport (PT) were reported by NSW underground coal mines, comprising 23% of all injuries reported. The present paper reports an analysis of the narrative field accompanying these reports to determine opportunities for controlling injury risks. The most common combinations of activity and mechanism were: strain while handling CM cable (96 injuries); caught between or struck by moving parts while bolting on a CM (86 injuries); strains while bolting on CM (54 injuries); and slipping off a CM during access, egress or other activity (60 injuries). For the other equipment considered, the common injury mechanism was the vehicle running over a pothole or other roadway abnormality causing the driver or passengers to be injured (169 injuries). Potential control measures include: monorails for CM services; hydraulic cable reefers; handrails on CM platforms; redesign of CM platforms and bolting rigs to reduce reach distances during drilling and bolting; improvements to guarding of bolting controls; standardisation and shape coding of bolting controls; two handed fast feed; improvements in underground roadway maintenance, vehicle suspension, visibility and seating; and pedestrian proximity warning devices.

By Hobart M. Kraner

THE mineralogy of blast furnace sinter is of interest because its mineral content is one of the important factors contributing to its character. There are so many other factors affecting the properties of the sinter, however, that it is well to mention them here. The proportion and character of the raw materials, that is, raw ores, concentrates, returns, and fuel, as well as the mixing and the water content, all have a marked effect on the physical properties of the product and the degree to which sintering action can be carried on. The process of sintering is a relatively fast operation. In as much as appreciable time is required to carry on processes of fusion in such masses of low thermal conductivity, large lumps of hematite ore frequently remain unfused and partly unchanged in state of oxidation in the sintering process. The kind, the grain size, and the amount of fuel used affect both the completeness of the fluxing reaction and the prevailing atmosphere. The rate of reduction in laboratory tests is not only dependent upon the state of oxidation of the sinter but also upon the sizing and porosity.

Jan 11, 1953

Melbourne, capital of sedate Victoria, is oddly enough the home of a game known as "Australian Rules." Euphemistically described by devotees of the game as a cross between Rugby and Soccer, it appears to the novice to be more akin to organized mayhem. They don&apos;t even play it in some parts of Australia, but in Melbourne 60,000 to 80,000 whooping spectators throng the Cricket club of a Saturday afternoon to see a match. Actually, the game is fast and grueling but the victory laurels always go to the skillful team, the one that plays the ball rather than the man. Australians also play the ball in their ground rules affecting those interested in mineral exploration and mining. Prospecting Rights: Throughout the island continent, nearly all mineral rights are reserved to the Crown, administered by the individual states and, in the case of the territories by the Commonwealth government. The owner of the surface rights cannot sit on his minerals, and the term minerals even includes sand and gravel. Prospectors are protected by mining codes or ordinances of the various governments, which are quite similar from state to state.

Jan 10, 1964

The advent and easy availability of fast and powerful digital computers has marked a transition from one era to another in the field of process control in many industries. Mineral processing is no exception. Aims, practices and problems associated with process control of mineral beneficiation plants in the &apos;old days&apos; are compared with those available at present. Although basic processes remain generally the same, there have been simultaneous social and economic developments, which directly relate to the development and present value of process control. Lower head grades are now treated, plant capacities have increased, and a large proportion of future capital in the mineral industry will be associated with large capacity plant, treating still lower grades. Environmental considerations have pressurised moves to better control in some areas. With these changes, economic operating incentives have changed, and process control has, in many plants, become more critical. Finally, while computer technology has developed recently at a very rapid rate, developments in the fields of instrumentation, basic on-line measurement and sampling have in general lagged behind, limiting the progress possible in process control. Hence, the benefits of computer control vary depending on

Jan 1, 1977

By Kitzinger F

The economic climate of the Canadian mining industry forced an increased interest in rapid, continuous excavation techniques for hard rock formations. The potential applications and advantages of continuous mining over the present drill- blast-muck labour intensive cyclical methods are considerable. Noranda investigated an electrical technique, Plasma Blasting showing considerable promise for mining hard rock. The background of the technology and the theory of blasting rock with electricity is described. The Plasma Blasting process is based on the fast discharge of stored electrical energy into a small amount of electrolyte, suitably located in the rock. The electrical energy converts the electrolyte into high pressure plasma, which expands very quickly, thereby, generating a shock wave. This shock wave produces a stress field inside the rock, resulting in a blast similar to that made by chemical explosives, but without the deleterious fumes. Noranda is currently blasting boulders of 4-5 tonnes and is at present constructing a mobile, autonomous secondary rock breaker for underground and open pit applications. Tests on in situ hard rock formations will lead to the development of a continuous mining machine. Production rates of 500 tonnes per man-shift could be obtained with such a machine.

Jan 1, 1990

By J. J. Kollé

A compressed-water hydraulic pulse generator (HPG) for nonexplosive blasting of rock and concrete is described. Energy is stored in the HPG by compressing water to ultrahigh pressure. A large, fast-opening valve discharges the compressed water, resulting in a high-energy impulse. The HPG can be used for small-scale bench blasting by discharging the water through a nozzle that is closely fitted into a borehole. A bench blasting system requires an HPG, a drill and an indexing mechanism to allow insertion of the HPG nozzle into a drilled borehole. Systems with discharge energies ranging from 40 to 250 kJ have been used to excavate hard rock, including andesite, granite and quartzite. The largest system can excavate 15 t/h (16.5 stph) of massive quartzite based on a 2-min cycle time for hole drilling. Blasting with an ultrahigh -pressure hydraulic pulse generator was demonstrated as an effective means of excavating hard, massive rock under the confined conditions of a tunnel opening or underground sloping panel. Hydraulic blasting provides a continuous mechanized mining capability that is well suited for deep-level mining and urban excavation sites where explosives are prohibited.

Jan 1, 1998

By B. G. White

NIOSH researchers have identified a pattern of fracture zone development that suggests an explanation for fracture formation around rectangular openings in underground mines. This pattern is characterized by shearing and dilation that result in either faults or in the repeated formation and propagation of en echelon fractures from sites of tension. Two computer modeling codes, Fast Lagrangian Analysis of Continua (FLAC) and Particle Flow Code (PFC), were used to model different aspects of this pattern. Use of very small elements with FLAC enabled the identification of sites of initial tension near the skin of square-cornered rectangular openings, while PFC allowed the initiation and progressive development of fractures from these sites to be followed as the fractures evolved. Such studies can lead to a greater understanding of how roof support can be better selected and installed for specific conditions in underground mines prone to roof falls and rock bursts. These studies may also lead to modifications of corner and opening shapes that could be incorporated into mine designs to produce more stable mine openings and reduce the risks of rock falls and rock bursts.

By Stavros A. Argyropoulos, Radhakrishna Valiveti, Bernard Closset

"The use of microprocessors in metallurgy is currently increasing at a very fast rate. A large number of companies are offering systems ""off the shelf"" which are aimed at the data acquisition and process control market. There are two main drawbacks to these systems: first, they are usually quite expensive, and second, they are not completely compatible with the target metallurgical application. An alternative is to develop a microcomputer-based system "" in lab "".A dedicated microcomputer system has proved to be very useful in many metallurgical research applications(1,2)). However, in this system the analog input signals had to be transferred over long distances , and significant noise was introduced despite the use of shielded cables. In order to overcome this problem a network of low pass-filter s was designed and built. The usage of the abovementioned system brought the need to digitize the analog signals in-situ and transfer the digital signals, which are much less susceptible to noise over very long distances. This distinctly different design philosophy has become a reality with the evolution of microprocessor technology over the last few years. This design philosophy is utilized in this development."

Jan 1, 1984

By Antonio De Biase

In October 2006, a 7m Double Shield TBM, boring through very poor volcanic formations, was pushed back by fluid mud, which presence had not been detected during previous field investigations, due to the high covers characterizing the majority of the tunnel axis. The present work describes the investigations made to gain better knowledge of the conditions in front and all around the TBM, the special measures implemented, the exploratory and bypass tunnels excavated, the extraordinary occurrences came true during the execution of these tunnels, the drainage campaigns, the design of the chamber excavated to free the TBM, the dismounting and restarting of the TBM.

By J. G. Groppo

Eastern U.S. oil shale contains approximately 10 to 12 gallons of oil per ton and 7 to 10 percent pyritic sulfur. Physical beneficiation of these low grade shales using froth flotation provides a high grade material which will make extraction of oil more economically attractive. The Alabama oil shale used in the present study contained 16.46 percent organic carbon and 14.5 gallons of oil per ton as determined by Fischer assay. Liberation size of the kerogen was estimated at 10 /-Lm. &apos;Ken-Flote&apos; column flotation technology provided a high grade concentrate containing as much as 60 percent organic carbon, however, carbon recovery was about 60 percent. Carbon recovery was improved to 75-85 percent while maintaining concentrate grades in excess of 40 percent carbon by providing longer retention time in the column which facilitated effective bubble-particle collision and attachment.

Jan 1, 1993

By R. A. Kinzie

In a conventional cement plant, the drying and heating of the raw material takes place in the upper section of a cylindrical kiln where the heat exchange is poor. In a Lepol kiln this part of the process is carried out on a traveling grate where the heat exchange is efficient. The increase in fuel economy justifies the greater complexity of the installation.

Jan 2, 1950

By Claude Deveau

"Studies on the performance of Falcon batch type concentrators treating ultrafine tantalum at Tanco have revealed that very fine heavy minerals are concentrated within certain areas of the concentrate bed. This information led to the design of a bowl which would allow entrapped lighter low grade particles to escape while providing more space for heavier particles to be recovered in the bed.Numerous tests were then completed with a modified batch-type and non-fluidized Falcon bowl in which the diameter of the discharge lip was adjusted downward manually in steps. This allowed for the gradual building of a higher grade concentrate bed.This work ultimately led to the design of a new Falcon with an automated continuously variable lip. In April 2005, Tanco commissioned the first Falcon UF600.This paper will discuss laboratory scale results and also plant performance of the Falcon’s UF technology.INTRODUCTIONTantalum Mining Corporation of Canada, also known as Tanco, is a wholly owned subsidiary of Cabot Corporation based in Boston, Mass. Operating since 1969, the underground highly mechanized room and pillar operation produces tantalum, lithium and cesium minerals and is located a 2 hour drive east-northeast of Winnipeg Manitoba, Canada.At Tanco, tantalum is recovered using conventional gravity concentration, enhanced gravity concentration and flotation. This paper will discuss how the need for improved equipment to treat very fine tantalum particles was filled by a machine which was modified to the point of creating a completely new technology.In November 2003, Tanco began the investigation for the potential use of a high g-force smooth walled concentrator for treating ultra fine tantalum produced by its flotation circuit. Until then, the tantalum flotation concentrate had been treated by a circuit which consisted of a Mozley Multi-Gravity Separator 902 (MGS), a Mozley MGS 900 and a Bartles cross belt concentrator. Through QemScan analysis, it was found that the majority of the losses from this circuit were of an extremely fine nature which exceeded the recovery limits of equipment on hand. Mean particle size of the tantalum losses was less than 10 µm."

Jan 1, 2006