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Carlisle: An old friend and good friend, Alan Bateman, is the Silliman Professor of Geology Emeritus at Yale and editor of the Journal of Economic Geology. Now, Alan, let's start off by telling us something about how you became interested in copper. Bateman: Well, after I left Yale in 1913, I was appointed one of the field members of the Secondary Enrichment Investigation. We spent three years in the field studying all the copper deposits of North America, trying to find out how secondary copper enrichment took place. As part of this investigation, I went up to Kennecott, Alaska, in 1916. After the trip I was asked by the president of the company to become consulting geologist to them. I accepted his offer, and to this day I'm still consulting geologist to the Kennecott Copper Corp. Up at Kennecott, there were both Henry Krumb and my good friend Henry DeWitt Smith, who was general superintendent. He and I had been together at Yale, and I had ushered at his wedding. Interestingly enough, Henry took his bride to Alaska and I took mine there two months later. My assistant was Don McLaughlin, and I think that was his first experience in a mining camp. We published a paper on Kennecott together and cemented a friendship lasting to this day.

Jan 11, 1964

By Shintaro Takamiya, Kazunari Yoshida

"Recently, small sized micro-needles for medical are required more frequently by patients. The biggest reason is that it presents great burden on the patients, due to the size of the needle injection. People need to use a very small needle to lower the pain, but the downfall is that it makes them more expensive due to their complicated manufacturing method. Therefore, we need to fabricate a needle by wire-drawing to decrease its price. Tube-drawing is beneficial for its production value; however, in conventional tube-drawing it is difficult of control the wall thickness of the tube and makes it 1mmor lower in diameter. That is why, we propose fluid-mandrel drawing for new tube drawing. This method allows fabrication of a fine tube by using the pressure of the fluid in the tube. In this research, the goal is the fabrication of a fine tube by fluid-mandrel drawing and its evaluation. Finally, the fabrication of a fine tube by fluid-mandrel drawing was conducted and in result a tube with a diameter of 0.2mm, high strength and thin wall and fine inner surface was drawn, which can be used as a lesser pain micro-needle.INTRODUCTIONThe main manufacturing method of the current medical needles is roll forming. With this method, it is difficult to make a tube with a diameter lower than 1mm. Deep drawing has been proposed and used as method to further reduce the diameter, but this method is costly and the injection needle obtained by this method is several times more expensive.Therefore, we need to obtain a fine medical needle by drawing process that can be mass-produced and inexpensively manufactured. However, with the conventional drawing process, it is not possible to obtain a syringe needle with a reduced diameter easily, that is why, a fluid-mandrel drawing has been proposed which can reduce the diameter without damaging the inner surface. The methodology of the method is, a fluid is filled in the sealed tube and the pressure inside the tube during drawing is responsible for the good inner surface and wall thickness. It is also expected that the fluid can be easily discarded and that the tube can be manufactured on a long scale."

Jan 1, 2017

By Paulo Sérgio de Oliveira, Joaquim D. Donda, Andreia C. Rosa

"The search for energy efficient technologies for comminution processes is constant in mineral processing studies, since those processes represent a major percentage of operational costs. In this context the use of stirred mills is increasing, especially for ultrafine grinding. Although many authors claim that these new equipment are more efficient than the conventional ball mills, there were very little chances to prove that in a practical way, since there are few industrial circuits where those technologies perform the same duty. Therefore, the regrinding circuit of Germano second concentrator offers an interesting opportunity: a vertical mill operating in parallel with two ball mills. During almost two years of operation, several sampling campaigns were conducted to evaluate the vertical mill performance and to compare the operational data of the three mills. The industrial data was also compared to jar mill tests results, which are monthly conducted in Samarco labs in order to predict the specific energy consumption required by the ore fed to these circuits. The vertical mill demonstrated the same ability to achieve the product specifications of the ball mills while proved to be able to reduce the medium specific energy consumption in about 40%."

Jan 1, 2014

By H Kim, M J. Sun

In order to reduce carbon emissions from the steelmaking process and achieve carbon neutrality, global steel companies are establishing their own medium to long-term strategies and implementation plans using competitive technological advantages held by each steel company. At this point, Hyundai Steel has formulated a product-oriented carbon-neutral strategy based on innovative processing that makes use of Hyundai Steel’s own strength. Based on our experience in electric arc furnace product manufacturing and blast furnace operation in an integrated steel mill, Hyundai Steel is driving the Hy3 (Hy-cube) project, which involves a unique hybrid production system utilising hydrogen and hydrogen-based renewable energy sources. This initiative aims to achieve carbon-neutral production and eventually specialise in producing premium carbon-neutral automotive parts. The project has originality in that it involves not only designing processes using electric furnaces to produce premium steel products such as car body panels and electrical steel sheets, but also aims to reduce carbon emissions from the process, developing carbon-neutral products based on market demand. To assess the feasibility of the Hy3 project, Hyundai Steel conducted two pilot productions. The first pilot was producing a prototype of lower-arm part using electric arc furnace with three different kinds of raw materials: molten iron, HBI (hot briquetted iron), and scrap. Successful performance evaluation of auto parts with 1 GPa strength was achieved. The second pilot has been focused on tire cord steel, with the first-phase tests yielding a 33 per cent reduction in carbon footprint (CFP). Using the advantages of operating experience in electric arc furnace, Hyundai Steel is preparing for test operations producing various automotive parts using an electric arc furnace (EAF) to advance the Hy3 concept. From a medium to long-term technological development perspective, Hyundai Steel’s blueprint includes producing high-end carbon-neutral steel products using hydrogen-reduced iron as raw material.

Jun 19, 2024

By S. Rideout

The United States Department of the Interior's Office of Surface Mining (OSM) is responsible for regulating active coal mining and reclaiming abandoned coal mines in the United States. In working with the State government agencies that implement these programs, OSM is building a new approach that moves away from traditional "command and control" regulation and towards an approach that focuses on providing long-term environmental and economic sustainability on lands disturbed by coal mining. This initiative called "Reclaim the Future!" looks to enhance opportunities for economic development, wildlife preservation and enhancement, reforestation, and other beneficial and productive uses of lands disturbed by coal mining. The initiative is also focused on ensuring that the landowners and the local public have significant involvement in determining how best to reclaim mine sites and what post-mining land uses are most appropriate for each individual abandoned mine reclamation project or active mine reclamation. Through the use of the best scientific input in an open, participatory process, OSM hopes to further sustainable development principles for coal mining within the framework of existing United States law.

Jan 1, 2007

By Robert Franke

(Butte Meeting, August, 1913.) IN view of the prominence which the conical mill has attained in the fine-crushing field .within the few years since its introduction, the following comparison with its more mature forerunner, the Chilean mill, based on extensive tests, is submitted in the interest of the milling profession. Soon after designing the concentrating plant of the Miami Copper Co. in 1909, the Hardinge conical mill made its appearance in the milling forum. . Its possibility as a suitable crushing device for the plant was well recognized, but in view of the lack of commercial demonstration, at the time, as to capacity, efficiency for desired product, and the still more uncertain factors of cost of maintenance and power consumption, it was deemed that the immediate adoption of this machine throughout the plant would be a hazardous undertaking. For these reasons it was decided to equip the majority of the immediately required units of the plant with Chilean mills, the fine-crushing proficiencies of which were better known, and one section with Hardinge mills, to serve as a test unit for the guidance of future installations and replacements. Thereby, after 1.5 years' operation with both types of mills, a thorough test as to metallurgical efficiency and cost economy has been obtained. The conical mill used in these tests is the 8-ft. Hardinge pebble mill, having a cylinder 22 in. in length. The cylindrical portion of this mill is lined with cast-iron liner plates, and the conical extensions with silex bricks bound together by cement. Each. liner plate carries a projecting lifter, the function of which is to increase the height of drop of the lifted material. Danish No. 5 pebbles, obtained from the coast deposits of Denmark, are used for the grinding charge. The Chilean mill used is a fast-running, 3-roller, 6-ft. Saturn mill, with screens of 0.037-in. opening. The feed to these mills is the oversize of Callow screens having 0.029-in. openings, which. follow rolls crushing to 0.5 in.

Jan 7, 1913

By Edwin Higgins

INTRODUCTION IT is the purpose of this paper to set forth the relation and functions of the various organizations and institutions engaged in the promotion of safety iii the iron mines of the Lake Superior region; also to indicate the value of this work. Ten to 15 years ago there was practically no organized safety work; the accident rate was high, excessively so in some districts, and dangerous practices and conditions existed in many of the mines. During recent years, however, a gradual change for the better has been made. The chief causes of this change have been (a) public opinion, which has set the stamp of disapproval on the disregard for human life; (b) certain State laws which have made the operators responsible in dollars and cents for injuries to workmen; and (c) the humanitarian attitude of many of the operators, who have always decried the great loss of life in the mines. Today the Lake Superior region as a whole stands second to no other metal-mining district in the United States in its efforts to promote the welfare and safety of the miner. Dangerous practices in and about the mines are fast disappearing. The operators are ready and eager to adopt any expedient, rule, or device that holds forth a reasonable promise of reducing the hazards of the miner. Today the value of a mine captain or shift boss is reckoned, not alone on his ability to "get the ore," but also on his capacity for reducing accidents. While the progress made has been remarkable, there still remains much to be done, for the accident records of the Lake Superior iron mines, while lower than those of the chief metal-mining regions of the United States, still compare unfavorably with those of the metal mines of practically all foreign countries.

Jan 10, 1914

By P. D. Duever, P. J. Readyhough, P. L. Silveston

"The Plastojrost apparatus, developed by Ritter and Juranek in the 1960s has been modified primarily, to automatic temperature control. A limited investigation of carboniferous and cretaceous coal samples showed that both coals undergo the same changes when coked in the Plastofrost unit. Dilatometer plastic range and total dilatation correlated well with the Piastofrost plastic range for the carboniferous Appalachian coal, but not for the cretaceous western Canadian coal. Work to elucidate the characteristics of some western Canadian coals using the Plastofrost is in progress. IntroductionCoke quality is critically affected by the properties of the plastic phase in the coal-to-coke transformation. Since these properties exist in a coke oven and are not measurable, they are approximated by standard laboratory tests, such as free swelling index, plastometry, and dilatometry. Of particular interest to us is the anomalous behaviour of western Canadian coals of cretaceous origin. By many predictive methods, these coals should not produce coherent cokes. When coked in pilot scale test ovens, in fact, they produce cokes of good stability. They typically make up 20% of Japanese coking coal blends and are also used in South Korea, Mexico, Brazil, and several European countries. This anomalous behaviour has been studied in our laboratory<8.9.1O). Plastic properties or rheological tests examine just the external ramifications of the coal-to-coke transformation. To understand the process, however, microscopic examination of the coal and coke seems to be needed. The Plastofrost unit has been shown to be a convenient means to this end."

Jan 1, 1987

By Howard L. Hartman

If I told you tonight at the outset that my prognastications for the future of mine ventilation were imparted to me by a palm reader or inspired by a vision, you&apos;d dismiss what I had to say before I said it! If, on the other hand, I told you that my forecasts were the result of an elaborate computer model, derived from a complex algorithm, which in turn relied on finite element analysis -- and the entire projection confirmed by on-site experiments with a turbo hybrid-flow mine fan -- you&apos;d sit up in anticipation and hang on my every word!! All of which places me in a terrible dilemma, because my predictions really lie somewhere in between. My intent is to talk to you out of my background of forty years in mine ventilation, looking ahead to conditions that I expect to prevail in the next fifteen years. You may be curious why I picked an unlikely time span of 55 years for my overview, and my response is that it bridges a career lifetime. "The last forty", of course, corresponds with the period of my professional employment since graduating with a B.S. and M.S. here at Penn State. "The next fifteen" bridges the period I expect (the Lord willing) to remain professionally active -- and coincidently brings us into the beginning of the 21st century. (I must confess to stacking the deck a bit: Since it&apos;s infinitely harder to look ahead than to look behind, I purposely minimized the forecast period and maximized the history! Besides, "forty" and "fifteen" have a nice phonetic ring, perfect 20/20 vision sums to "forty", etc., etc.). With these disclaimers, I&apos;ll invite you to join me now in a fast 55-year overview of mine ventilation, of necessity limited to a broad-brush treatment of the subject. (After all, this is an after-dinner talk, not a marathon!) In each- segment, I&apos;ve selected the seven topics that seem to me of paramount importance: in the first part, seven accomplishments in retrospect, and in the last, seven expectations for the future. (The number "seven" needn&apos;t confound you, either: In the bible, it signifies "wholeness" or "completeness".))

Jan 1, 1987

By G. B. Pryde, R. M. Magraw

In laying out a new mine, provision should be made for the ultimate recovery of as much coal in any given bed as is consistent with safety and economic mining. Though each mining district, if not each individual mine, has problems that make the adoption of any hard and fast rule impossible, certain basic principles are adapted to practically all conditions. One of the most vital is the provision for barrier pillars of ample dimensions to protect all haulage and permanent airways during the life of the property. Where conditions permit, room or butt entries should be driven on the strike or slightly to the rise, and rooms turned at right angles to these entries. The width of rooms and room pillars is governed by conditions prevailing in the mines under consideration. A safe rule is: In advancing, extract not more than 25 to 35 per cent. of the entire seam; in exceptionally thick seams, considerably less than 25 per cent. should be taken. Rooms usually vary in length from 250 to 350 ft. (76 to 106 m.) with a barrier pillar of not less than 80 ft. between the last crosscut. in rooms and the back entry of the level above. All entries, rooms, and entry-and-room crosscuts should be driven .on sights and room crosscuts should be driven at, right angles to the direction of the rooms. In mines under excessively heavy cover or where roof conditions are bad, rooms should be driven narrow and a barrier pillar left at every fifth to tenth room. This barrier should be of such dimensions that one or more rooms, with pillars of usual dimensions, may be turned through it when the barrier is no longer required. Two of the advantages of such a barrier are the protection of the panel against peaking of roof load during pillar extraction and the easy closing of the entry in case of fire. Where economic conditions permit, it is preferable to follow the retreating panel system of mining. In the case of coal that outcrops, and even in cases where no outcrop is exposed, it is preferable to commence pillar extracting on the high side of the mine. Where the retreating

Jan 1, 1922

By A. F. Lucas

EACH day, the fact becomes more evident that the ever-growing demand for oil is farther outstripping production, regardless of the increase in output throughout the past twenty years. The development of known oil fields and the prospecting for new ones along present lines are not resulting, in, and cannot bring forth, supplies large enough adequately to meet the oil needs of the country. The usual methods of prospecting-for new supplies are insufficient to meet the exigencies of the situation which threatens, in the not distant future, to reach a critical stage. Were it not that within the last two years new and prolific oil fields have been discovered in northern Louisiana, central Texas, and California, this crisis would undoubtedly be now at our door. Stocks are being exhausted in spite of the rapid growth of imports. The time is therefore fast approaching when some radical departures must be made in the method of prospecting and developing old and new fields in order to increase our oil supplies. Methods and chances, that have seemed unwarranted will not only be given serious consideration, but, according to the results promised, will be put to the test. Meanwhile, however, nearly all the oil fields are responding to the stimulus of higher prices, whereby enormously growing capital is attracted to this important industry, both here and abroad; the increase in our petroleum production at the present time is due to this circumstance. Yet, although a most active search is being made for possible sources of additional supply, one section of our country is not yielding the results that, in my opinion, it is capable of producing: I allude to the coastal dome belt of Texas, Louisiana, and Mexico. The United States Geological Survey has estimated that three-fourths of a billion barrels are available in the ground in the Coastal Plain of the two states just mentioned. Numerous papers have been written on the subject of the salt domes of the Coastal Plain and more or less attractive theories have been advocated by leading geologists to account for their origin and the presence of the oil, sulfur, and salt associated in them. However, owing in part to the generally monotonously level country in which the coastal

Jan 9, 1920

By J. P. Lesley

The old do not love to see the young pass away from the light of the sun before them. Fathers would fain keep their sons by their side to the. end of life ; but the old Greeks, who loved the old gods, were wont to moderate their grief with the sweet superstition that only those whom their gods especially loved died early. The Christian church found consolation in that superstition applied in a new form to its new sorrows, and paid its most enthusiastic devotion to the memories of its young and beautiful martyrs. The natural science of our century is robbing us fast of this and all other superstitions, sweet as well as bitter, and leaving us for consolation to the teaching—colder, yet kinder—of personal fortitude and that optimism Which intelligently translates the Cosmos of Humboldt back into its old name of the Harmonia of Pythagoras. The Homeric Kataclothes, the three fates, are dead and gone for us, with that old world which comprehended none of the laws of cause and effect, and sorrowed for those who were cut off from the land of the living without hope of more than a shadowy existence beyond the river of death. All the more the ancients cherished the memory of their dead and lavished their choicest art upon their monuments. We moderns have lost the monumental arts, but we better keep the monuments which our dead leave behind them. No one of us who has done good work can fail to be remembered; and in an Institute like this, which keeps the press at work, an immortality in the memory of men is more possible, more certain, for every one of its members than the greatest heroes of antiquity could anticipate for themselves. In old apocalyptic times the works of men followed them through death to the throne of God to be their advocates in judgment, but in these modern times our works remain this side the grave, to follow the name of the departed one as it takes its course along the history of his peculiar art or science advancing slowly to perfection. We write the epitaph, not upon the mouldering stone of a tomb, but on the pages

Jan 1, 1890

By M. K. Larson, B. G. White

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are investigating the causes and mechanisms of roof failure in underground mines. It is expected that a better understanding of these causes and mechanisms will lead to better layout and support designs that will help prevent accidents and fatalities associated with fall of ground. Two numerical experiments were conducted by NIOSH researchers using the Fast Lagrangian Analysis of Continua (FLAC) computer modeling program with a strain-softening continuum to simulate fracture zones. Two models, one of a round hole in a plate and one of a rectangular opening, were constructed and boundary conditions were applied to simulate far-field shear. The Particle Flow Code in Two Dimensions (PFC2D) computer program was used to look at the effects of far-field shear in generating fractures around an underground opening, but these models are preliminary until boundary conditions, strengths, and stiffnesses are matched to the FLAC models. Results showed that shear zones propagated from the opposite corners of openings in directions that appeared to be determined by opening shape and far-field stress. Tensile failures also formed and extended away from these shear zones. The consistent direction of shear deformation with respect to far-field shear provides a plausible explanation for preferred directions of shear as seen in geologic environments.

The scope of this paper is to introduce a mathematical model based on matrix algebra in order to determine similitude quantities, which can be arranged in specific formats to simulate the field conditions and associated behaviour. The formulation of a typical mathematical model applicable to Geomechanics is demonstrated here. The examples provided are intended to facilitate comprehension and application of the proposed model in practice.

Jan 1, 1989

By P. A. Riveros

This paper describes the leaching of the common copper minerals tennantite (Cu12As4S13), tetrahedrite (Cu12Sb4S13) and enargite (Cu3AsS4) in acidic media using Fe(SO4)1.5, FeC13 or 02 as oxidizing agents. At temperatures <100°C, tennantite dissolves slowly in Fe(SO4)1.5-H2SO4 media, and the rate is directly proportional to the area of the sized tennantite. The rate increases sharply with increasing temperature and the apparent activation energy is 69 kJ/mol. Increasing Fe(SO4)1.5 concentrations slightly increase the tennantite leaching rate. The kinetics of dissolution of disks of synthetic iron-bearing tetrahedrite in Fe(SO4)1.5-H2SO4 media are linear; the leaching rates are slow but increase significantly with increasing temperature, with an apparent activation energy of 120 kJ/mol. The dissolution of sized particles of natural Ag-bearing tetrahedrite in FeC13- HC1 solutions proceeds according to the shrinking core model, and both Cu and Ag dissolve at about the same rate, provided that the total chloride concentration of the solution is sufficiently high to solubilize the AgC1 reaction product. The leaching rates are slow, and the apparent activation energy is 116 kJ/mol. The addition of sulphate ions to the FeC13-HC1 system reduces the tetrahedrite leaching rate to values similar to those realized in the Fe(SO4)1.5-H2SO4 system. At <100°C, enargite dissolves slowly in either Fe(SO4)1.5 or FeC13 media, and the dissolution rate obeys the shrinking core model. The rate increases with increasing temperature and the apparent activation energies are 50-64 kJ/mol. The rate increases slightly with increasing FeC13 concentrations in 0.3 M HC1 media. The leaching of enargite at elevated temperatures and pressures was also investigated. Potentially useful leaching rates are achieved above 170°C, at which temperature sulphate, rather than sulphur, is produced. Lower temperatures (130-160°C) lead to fast initial leaching rates, but the dissolution of the enargite is incomplete because of the coating of the enargite particles by elemental sulphur.

Jan 1, 2007

By Catherine Johnson, Kelly Williams

The ability to measure the overpressure of a shock wave is necessary for explosives research such as shockwave focusing and field testing of blast-resistant designs for buildings and vehicles. To record the peak overpressure of the nearly instantaneous pressure rise at the shock front, pressure transducers with a fast response rate and streamline pencil design are needed. Time spent setting up sensors coupled with the expense of high-frequency data acquisition systems, and the inconvenience of low impedance cables can make the process challenging. Additionally, only small inaccuracies in sensor position can drastically change the measurement recorded. Advances in high-speed video imaging make it possible to see the refraction of light due to the high-density gradient at the shock front without the need for parabolic mirrors or additional light sources necessary for Schlieren or shadowgraph imaging. The average shock front velocity between two points can be calculated by dividing the change in position by the elapsed time between the images. Using the Rankine-Hugoniot relationship demonstrated by Swisdak the peak overpressure of the shock wave can be calculated from its velocity eliminating the interference of the gage and mount. This paper investigates the accuracy of this method by setting dual transducer pencil probesat0and180 degrees perpendicular to the central axis of a285-gram(0.63-pound)cylindrical charge to record pressure versus time for comparison to the high-speed video. The axis of the camera lens is aligned with the central axis of the charge with both pencil probes in view. The pencil probes have two pressuretransducersset100millimeters (3.9 inches)apart to measure the time of arrival and are used to validate the velocities calculated from the high-speed images. This method can be used to evaluate the shock wave propagation from more complex prismatic charges with different cross-sectional shapes where precise placement of cumbersome pencil transducers in the near field is almost impossible.

By Enrique Fernandez

M-30, Madrid’s inner ring, covers 42 sq km of the city centre where one million people reside. It was constructed in several phases during the sixties and the eighties. The design criteria applied to those phases were different and were not always homogeneous with urban roads with lighting regulation as well as speedways. These areas had a heavy concentration of access and exits and there had been made many changes on the number of traffic lanes which has caused heavy traffic congestions and high accident rates. The environmental impact and noise pollution in residential areas are also consequences of M-30. The Madrid Major took a decision at the beginning of the present legislation, based on socio economic and environmental evaluation; rebuild the M-30 with the following sustainable mobility principles: Underground transfer of a considerable portion of the main ring and some of its links replacing some parts of the surface with new green areas in order to reduce the environmental impact. Increase the traffic capacity, improving the traffic continuity and fluidity and eliminating the lighting regulation areas, which is one of the main congestion problems currently. Increase the traffic safety with clear signalling information panels and avoiding difficult maneuvering. Redesign the links with the high capacity radial highways and other connecting lanes of the city. The project is worth 3.7 billion Euros. In 2007, when the construction is completed, it is expected will save 14 million of journey hours that represent 4.5 million Euros saved in fuel consumption per annum, There will be a very significant reduction of 35,000 tons of CO2 in terms of pollution and 400 less car accidents. Those values will increase even more in the following years. The areas beside Manzanares River, running parallel to the M-30 on the western side of Madrid, will be highly enhanced. Better water quality and the recovering of the green areas existing in old times will also return for the citizen’s enjoyment. TUNNEL CROSS SECTION OF CALLE 30 SOUTH BY PASS One of the major challenges of the new Calle 30 is actually not only the related to the main road but also to the link with the A-3, with highway to Valencia. This link is currently the most congested area and has one of the highest traffic densities of Spanish roads, with more than 250,000 vehicles/day. The remodelling of this area is the principle objective of the South by-pass. The tunnel is the only answer for this by-pass as the road alignment will go among buildings. A twin tube design, one for each direction, with three lanes allowing the circulation of both, light cars and heavy trucks, is the solution that has been

Jan 1, 2007

By Robert C. Mackenzie

EXAMINATION by the differential thermal analysis technique of a large number of samples of soil and other clays from various parts of the world has demonstrated that the occurrence of cold-precipitated hydrated ferric oxide (the identification of which in soil clays has previously been reported5) is not confined to any limited locality; e.g., it has been found in varying amounts in clays from Britain, France, South Africa, and Mexico. The conditions necessary for its formation have not yet been elucidated in spite of the number of samples examined, and, since this mineral is so easily prepared in the laboratory, it has been considered that a study of its constitu¬tion and of the conditions under which it could be prepared might. lead to a better understanding of the factors involved. These experiments form the subject of this short paper, and while they do not supply a definite answer to the mode of formation of this mineral in nature, they may, it is hoped, add something to our knowledge in this direction. EXPERIMENTAL WORK Materials Employed The a-Fe2O3.H2O (goethite) and B-Fe2O3.H2O (Weiser and Milligan") were obtained from the Department of Geology, University of Aberdeen, and Rothamsted Experimental Station, respectively. The beta material had been prepared by the method described by Fernelius.1 y-Fe2O3.H2O (lepidocrocite) was prepared at the Macaulay Institute for Soil Research by the method of van Schuylenborgh.6 The method employed for preparation of the cold-precipitated hydrated ferric oxide* was as follows: 1: 1 NH4OH was added (moderately fast with rapid stirring) to a solution of 5 grams FeC13.6H2O in 250 ml distilled water at room temperature (ca. 15°C) until red litmus turned blue, and then 2 to 3 drops in excess. The resultant precipitate was filtered off on a Buchner funnel and washed free from Cl- with distilled water. Previous experiments having shown that drying over P2O5 at room temperature or drying at 105°C in the oven did not significantly affect the thermogram,5 samples were nor-

Jan 1, 1952

By Travis Davidsavor, Stanley: Dong Vitton

Concrete is a common construction material used throughout the world, and with increasing demand of fast-track construction, blasting and concrete casting are occurring simultaneously at many sites where rock is being excavated for concrete placement. However, there has been significant disagreement in the construction industry as to what intensity of shock vibrations green, or fresh concrete can tolerate. Peak particle velocities are often arbitrarily chosen, or are simply based on materials such as plaster and drywall that have been more thoroughly studied in relation to damage. Previous research on green concrete has used the concrete’s static strength subjected to shockwaves at different ages as the primary damage criteria. In addition, the static strength tests have been based on curing time. However, changes in temperature or humidity can dramatically alter the hydration rate, which affects strength development of different cements. To account for temperature changes and humidity the concept of concrete maturity is commonly used and allows the researcher to see where the concrete was in terms of hydration progress. In general, static testing determines the failure stress that the concrete’s macrostructure can handle, and often failure occurs in the natural materials first or along large defects in casting techniques. Dynamic testing or high strain rate testing, on the other hand, loads materials at such a high rate that larger defects do not have time to react and instead the microstructure is more highly stressed leading to higher strength and stiffness values. This is known as the material’s strain rate sensitivity. Since dynamic testing better tests the microstructural strength, it is believed that it may provide a better way to assess damage to green concrete. Testing includes both static and dynamic compression as well as static and dynamic splitting tensile strength to assess whether damaged has occurred to the concrete. No significant statistical evidence was discovered that damage to the concrete occurred at five different “green” maturities from peak resultant velocities ranging from 10.66 in/s (271mm/s) to 4.40 in/s (112 mm/s) with average intensity of 6.7 in/s (170mm/s).

Jan 1, 2003

By llya Perederiy, Vladimiros G. Papangelakis, Indje Mihaylov

"Nickel slags obtained from various smelting furnaces and converters differ in terms of their chemical composition and microstructure. The microstructure of the slag is largely affected by how fast the slag is cooled after being discharged from the furnace. Slow cooling is known to promote crystallization and growth of phases such as crystalline fayalite (Fe2Si04), magnetite (Fe3Ü4) and vitreous silica (S1O2). Slag granulation causes rapid solidification of the melt in the form of either an amorphous solid or highly intergrown crystalline silicate and oxide phases. Smelter slags contain entrapped Ni, Co and Cu in the form of dissolved oxides and matte inclusions. Extraction of the entrapped metals by high pressure oxidative acid leaching (250°C, 70 g/L initial H2SO4, up to 90 psi O2, 45 min) relies on the dissolution of the metal bearing minerals. The impact of the slag microstructure on the accessibility of these minerals to leaching, as well as the morphology of the produced residues is discussed in this paper.IntroductionIt was shown previously that entrapped base metals can be efficiently extracted from naturally cooled (as opposed to granulated) crystalline nickel smelter and converter slags using high pressure oxidative acid leaching operating at 250°C, ~40 g/L terminal acid and 60 to 90 psig oxygen overpressure [1, 2,3,4, 5, 6].Mineral characterization work performed on a naturally cooled crystalline nickel furnace slag from Vale's operations in Sudbury (ON, Canada) was previously reported [4]. Fayalite (Fe2Si04) and magnetite (Fe3U4) were detected using powder X-ray diffraction. These two minerals as well as silica (S1O2) and matte ([Fe,Ni,Cu]Sx) were also identified with the help of energy dispersive X-ray spectroscopy (EDX) on cross-sectional images obtained with a scanning electron microscope (SEM) operating in the backscattered mode. Nickel converter slags obtained from Vale's operations in Sudbury were found to be mineralogically similar to the furnace slag, but with higher contents of matte entrainment and magnetite based on the SEM-EDX observations [6]."

Jan 1, 2012