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Geopolymers are novel engineering materials with the potential to play a highly significant role in the transformation of the construction materials and building products industry in the push to-wards sustainable development. These materials are formed by activation of industrial aluminosilicate waste materials such as coal ash or blast furnace slag with alkaline solutions. Some mineral waste can also be used, either as fillers or as reactive components. The use of waste-based geopolymers results in significant (up to 90%) reduction in carbon dioxide emissions when used in cement replacement applications. In addition to the formation of conventional pre-cast products, these high performance mineral binders are ideally suited to use in the conversion or encapsulation of toxic waste, including radioactive waste, due to their chemical stability and resistance to acid attack. It is the aim of this paper to review recent developments on the science underpinning this ?green? technology, and to discuss the technical and commercial drivers governing the large-scale adoption of the technology. Some of the recent fundamental breakthroughs in the study of geopolymer technology at the University of Melbourne will be presented. Despite the complexity of this reactive sol-id-gel system, progress has been made in the development of a thermochemical reaction kinetic model that has been validated using both calorimetric data and synchrotron kinetic data. Geopolymerization is potentially a disruptive technology, so that it is normal to expect strong resistance from established companies in the construction materials industry. It is increasingly necessary that waste generating industries such as mining collaborate with industries such as construction that could utilize this waste. The world?s first full scale geopolymer plant utilizing waste and re-cycled material has been commissioned recently in Melbourne, Australia, so progress on commercialization will also be presented. The authors frequently present keynote lectures on geopolymer science and technology at materials science, ceramics and construction materials conferences. However, this interdisciplinary technology that is still in its infancy, deserves more attention in the mineral processing and mining industry in view of its potential use in the mining industry, and also in view of the importance of mineral processing techniques in recent advances in geopolymers.

Jan 1, 2014

By D. A. Longhurst

Improper size distribution of the grinding media in a multicompartment mill can be a source of many operation problems encountered. Inefficient use of the power expended for grinding, and an undesirable product size distribution are two frequent resultants. It is necessary to resize the grinding media in the leading mill compartment at time intervals related to the abrasive nature of the material being processed. In practice, this is done when time permits and with sketchy guidelines, if any. Maintenance of the grinding media size distribution can be scheduled, and would be, with a realistic method supplied to the user.

Jan 1, 1984

By E. L. Montgomery

Salar basins in the Andean Highlands of Northern Chile contain ground-water resources which could be used to satisfy requirements for the mineral industry in the region. Salars occur in arid zones; average precipitation is about 200 millimeters per year at altitudes of about 4,000 meters, and average annual evaporation is two meters or more. The salar basins are hydrogeologic sinks where water flows from recharge areas at the margins of the basins to discharge areas at the salt encrusted salar at the lowest point of the basin floor. Groundwater circulation occurs principally in the alluvial and fractured bedrock aquifers. Results of pumping tests for exploration and production water wells indicate a range in maximum sustained pumping yield of 62 to 126 liters per second, and where abundantly fractured, ignimbrite comprises the most prolific aquifer. Chemical quality of groundwater is good. Long-term pumping from properly located production wells in the salar basins would result in lowering of groundwater levels and salvage of water in areas where groundwater is lost via evaporation.

Jan 1, 1986

The need for an integrated approach to optimization of unit operations in both the pit and the mill has long been recognized, but the complexity and nature of the overall problem has up to now resisted solution. This paper reports on a modeling methodology which couples symbolic and numeric computing to unify operations in both the pit and mill. The ultimate goal of this work is to optimize all operations that are influenced by blasting. Blasting plays a key role in all facets of operations. Obviously, drilling and blasting costs are determined by blast design, but the down-stream costs that are closely related to blasting results are often treated as separate functions: loading, hauling, cleanup, and crushing and grinding are all heavily influenced. Diggablilty and bucket fill factor are a function of fragmentation, the condition of the floor and uniformity in the shape of the muck pile. Likewise, cycle times and loading delays partially determine haul cycles, while fragmentation distribution and size determines the efficiency of truck loading. Removal and breakage of oversize causes loading delays and increases cleanup costs. The influence of blasting doesn't stop at the crusher. Mill productivity, power consumption, and maintenance are a function of the feed. Even at the SAG mill a reduction of a critical particle size during blasting can increase throughput. Thus, a bottle-neck for production far removed from unit operations in the pit can be alleviated by a modification in blast design. The question is: how do we optimize blasting with respect not only to itself but to al\ related mining and milling operations? For that matter, how do we even model blasting so that we can control the results of a blast?

Jan 1, 1991

By Kim Chan, Bryn Thomas, Ben Dening

"Increased rail capacity is required into Kooragang Coal Terminal near Newcastle, NSW, Australia to relieve rail traffic congestion and improve management of train arrivals. An additional arrivals track is proposed on new embankment within a heavily constrained site located between existing railway tracks, a high pressure gas pipeline located 7m beyond the toe of the embankment and an environmentally sensitive wetland area. Ground conditions at the site consist of deep soft estuarine clays, a soil profile which is consistently encountered throughout this part of the east coast of Australia. Upon determining that a ground improvement solution was required to ensure global embankment stability, various solutions were considered including a piled viaduct, retaining walls, dry deep soil mix (DSM) columns and concrete injected columns (CICs). DSM columns were adopted as the design solution, a decision which was driven by the presence of sensitive infrastructure and a confined site. DSM offered further advantages including reduced impacts on temporary working platform design, where the use of a thinner platform could be justified owing to the lower track loads of a DSM rig relative to other ground improvement techniques.INTRODUCTIONThis paper presents a case study of the design of DSM ground improvement works to provide support for and enable safe construction of a new railway embankment over deep soft soils with a number of nearby infrastructure and other constraints. The project site is approximately 1km long and is constrained by existing railway tracks, a high pressure gas pipeline and a wetland area of ecological significance. Due to the site constraints and ground conditions, a number of ground improvement techniques were considered during the design process, with DSM columns eventually adopted. This paper discusses the design development and the particular suitability of the technique for use in this application.SITE DESCRIPTIONLandformThe site is located along the northern boundary of the Kooragang Coal Terminal (KCT) at Kooragang Island (KI), a collection of former islands located near the mouth of the Hunter River, north of Newcastle, NSW. The topography of the original area was generally flat with mudflats, swamps and mangroves existing along tidal water courses. Subsequent dredged fill reclamation and development has amalgamated the previous islands into the current KI. The site area extends over numerous channel infills including the buried former course of the Moschetto Channel (paleochannel).Figure 1 shows the proposed 1km long new rail corridor construction area in relation to the various natural and man-made site constraints including existing tracks, the high pressure gas pipeline, the wetland area and the existing reclaimed area."

Jan 1, 2015

By F. G. Loper

Simulation as a mathematical technique is not new. However, recent increases in digital computer speeds and the ease of programming with languages such as Fortran have centered a good deal of attention around simulation in the last few years, Many sophistications of the method have been developed during this time. However, the ability to simulate mathematically still hinges on the ability to ignore unimportant details which would complicate the mathematics and make simulation impractical, Thus, with this attitude in mind, it becomes very easy to design a pseudo- simulator which will predict average conditions very well, but can not truly allow a detailed study of the system being simulated. Most simulations fall into this category, along with the case mentioned here. This paper is not intended to be a critical treatise of the simulator used to study a particular mining system. Instead, it will be used to illustrate the aspects of simulator development. The steps in the development of any simulator are described, along with same detail of the phosphate mine simulator itself.

Jan 1, 1966

By John M. Lovejoy

FEDERAL regulation of the petroleum resources of the nation has long been an interesting topic for discussion. A plan to accomplish Federal control has now taken definite form. At the request of the President of the United States, a bill to be known as the Petroleum Conservation Act of 1939 has been presented to Congress-H. R. 7372, offered by Representative Wm. P. Cole, Jr., and more usually known as the Cole bill. It is an act ostensibly designed to conserve our petroleum resources, through regulation of production practices. Hearings are being held currently by a subcommittee of the Interstate and Foreign Commerce Committee, in compliance with the request of the President to report the bill early in the next session of Congress.

Jan 1, 1939

By J. W. Hawkins, K. B. C. Brady, M. W. Smith

The Pennsylvania Department of Environmental Protection (PaDEP) has been issuing surface mining permits since 1984 that authorize remining in areas that will affect preexisting pollutional discharges. These permits require the mine operator to employ best management practices to reduce pollution loading from abandoned mine discharges. A total of 110 completed mining operations with 233 discharges were evaluated to determine the impact to water quality. Overall, acid loading from these discharges was reduced by 7, 200 kg (15, 900 lbs) per day or 61%. Metal loadings were also reduced. For acidity, 49% of discharges improved or were eliminated, 52% showed no significant change and fewer than 1 % got worse. Loading reductions resulted from a combination of reduced concentrations and lower flows.

Jan 1, 2003

By Dalia. R. Mohamed, Hisham H. Hafez, Marawan M. Shahien

"Construction activities in major projects that involve deep excavations necessitate the use of vertical walls surrounding the construction site to play an important role as earth retention system. The walls are usually partially penetrating impervious walls which can increase the efficiency of the ground water control system that usually consists of number of partially penetrating wells. The analysis and design of such system requires 3D numerical simulation. The aim of this study is to develop simplified semi-empirical approach to analyze and design such system. The analyzed model is a single well in a square site that is surrounded by impervious walls along the perimeter of the site in an unconfined aquifer. The results of the parametric analysis are presented in this paper aiming to assess and understand the factors that influence dewatering in terms of ground water or drawdown profile surrounding the well. The parametric analysis is carried out using the 3D finite difference software. The parametric analysis comprises with more than 550 cases calculated. The study involved the parameters; well penetration depth, impervious wall penetration depth, size of the construction pit, coefficient of permeability, well yield and well location or distance between well center to impervious wall edge.IntroductionThe presence of groundwater in a site may have impact on the construction processes involved during the course of project construction, especially those projects that involve deep excavations. Deep excavations, especially in urban areas, require the construction of supported walls all around the site perimeter to ensure the stability of the excavation. In most of cases, the constructed walls are relatively impervious. Depending on the ground and site conditions, the walls are not penetrating all the way down through to the bottom of the aquifer and thus the walls are partially penetrating walls. The presence of ground water necessitates the lowering of the groundwater to levels below the bottom of the excavation to ensure working in dry. This paper focuses on groundwater control systems that consist of deep wells inside square areas enclosed by impervious walls partially penetrating unconfined aquifers. The wells are partially penetrating the aquifer, as well. There are many factors or parameters that are related to the configurations of the components of the system that may influence the drawdown of a well in such groundwater control system. This paper is a part of a comprehensive study that aims to development of a simple method for estimating the drawdown of dewatering system of the described configuration. In order to achieve such a major goal, a 3D finite difference model is developed for the problem in hand. A comprehensive parametric analysis was then carried out to investigate the influence of all the parameters on the drawdown of a deep well in such groundwater control system. This paper describes the problem, the model, the parametric analysis including the involved parameters. The paper, then, demonstrate the results of the analysis showing the influence of the studied parameters on the drawdown of a single well."

Jan 1, 2016

By R. Karl Zipf, Z. T. Bieniawski

"A set of fracture profile photomicrographs is presented for fractures generated under mixed mode loading of the Pittsburgh coal. The fractal dimension is used· to characterize the irregularity of these profiles and a tentative relationship is presented between the fractal dimension and the fracture toughness. Surface roughness appears to depend solely on the stress intensity and no other dependence was observed with fracture loading mode, loading rate· or specimen orientation. Observations of crack bifurcations.in fracture profiles can indicate crack growth direction whereas direct surface observations generally cannot in materials such as rock and coal.1 INTRODUCTIONThe production of fine fragments of material as a result of some loading event occurs in many industrial processes. In crushing and grinding, the efficient production of fine fragments is the desired end result; .however, in coal cutting, the production of fine fragments may lead to high levels of respirable dust in the immediate atmosphere with the danger of human lung diseases. Two of the most important sources of fragments in the 1 to 10 micron size range during a cutting process are 1) severe crushing in a zone near the loading tool and 2) subsequent shearing along major crack surfaces that form the larger fragments during material reduction. These and other sources of fine fragments generation are discussed by Roepke (1984) and Zipf and Bieniawski (1986). The physical character of the nearly created major crack surfaces is believed to have a strong influence on the amount of fine fragment generation that occurs during subsequent shearing movement. When the major large fragments initially form, they are ""locked"" in place by the irregular character of the new fracture surface. Only after some relative motion has occurred between fragments are they actually liberated, and the net result is the formation of additional fine fragments. The fine fragmentation is not necessarily limited to the shearing of high points from the macrocrack surf ace since material remaining in the wake of the crack tip is damaged to a substantial depth below the actual crack surface."

Aug 31, 1989

The exploitation of the underground is currently undergoing a major transformation process. Besides mining, alternative ways of utilization are playing an increasingly important role. These alternative utilizations include the storage of gases, the disposal of radioactive wastes and the implementation of geothermal storage facilities. In addition, more and more mining operations are being shut down, like the German hard coal mining industry in 2018. But the integrity of closed mines must be ensured in the post-mining phase.

Jan 7, 2020

By A. S. W. Kurny, M. Z. Huq

Bangladesh ilmenite is partially altered, containing pseudorutile, rutile and haematite as well as the predominant ilmenite phase. A typical analysis is 39.45% TiO2, 24.19% FeO and 33.0% Fe2O3. Reduction of the ilmenite by charcoal was found to involve two major reactions: conversion of pseudorutile into ilmenite and rutile, and change of ilmenite into metallic iron and rutile. The first, which was much the faster reaction, was responsible for an initial increase in ilmenite content with reduction time at lower temperatures. Apart from these two major reactions, rutile was reduced to lower oxides at 1 100 degrees C with a consequent decrease in its XRD peak height

Jun 19, 1905

By K. E. Tame

Pollution from radioactive nuclides, principally Ra226, in liquid waste from uranium mills can be minimized by reusing the waste solution within the mill. Such reuse of waste solution in the Vitro Chemical Co.-type process was investigated in the laboratory. Vitro employs an acid leaching process for dissolution of the uranium, countercurrent decantation for liquid-solid separation and washing, and amine solvent extraction for recovery of the uranium from solution. The simulated reuse of barren raffinate in the mill circuit was carried through two separate laboratory campaigns of 29 and 31 cycles. Conventional chloride stripping of the amine was employed in the first campaign, whereas nitrate stripping was used in the second campaign. Dissolution of uranium from the are in the acid leaching circuit averaged 96 percent. Washing efficiencies of 98 to 99 percent were attained by using 4 volume tons of combined raffinate and makeup water per ton of ore. Uranium recovery from the pregnant solution using a 5-percent solution of amine LA-1 in kerosine ranged from 99.3 to 99.9 percent.

Jan 1, 1962

By K B. Quast, A Schuurmans

Laboratory batch rod and ball milling tests were conducted on samples of Heavy Medium Separator (HMS) sinks from Renison Limited. The effects of mill rotation speed, rod volume and ball size on the resulting product size distribution were investigated. Between 48 and 69 per cent of critical speed, the product sizing distribution curves remained very similar, with a finer grind resulting from increasing the speed of rotation at constant grind time. Increasing the rod loading from ten to 53 per cent by volume caused the product size to become finer and more closely sized with a transition occurring at approximately 29 per cent. This was interpreted as a change of dominant grinding mechanism from abrasion to impact. No preferential grinding of the cassiterite was observed. The effect of increasing ball size at constant charge weight was to preferentially grind the coarser particles and generate more intermediate sized particles, whereas the product from a mixed ball charge gave a distribution similar to that obtained when a charge containing only smaller balls was used.

Jan 1, 1998

By Peter E. Price

Salt dome hosted metallic sulfide deposits are the product of a complex evolutionary system involving halokinesis, cap rock development and diagenesis, and the generation, migration, and accumulation of basinal brines and hydrocarbons. Hydrocarbons play an important role in: (1) the production of calcite cap rock which hosts some of the metallic sulfide and sulfur concentrations, and (2) the generation of the reduced sulfur available for metallic sulfide precipitation and sulfur formation. Hydrocarbons and related fluids also are involved in the transporta¬tion and remobilization of the metals. Hydrocarbon consumption, in the course of cap rock development and sulfide mineralization at Hockley dome, is estimated to have been 6.4 million barrels of oil or 114 million cubic feet of methane. Mineral textures, including cap-rock banding, sulfide bands in anhydrite, and fine sulfide mineral banding indicate both episodic fluid influx and fluid compositional differences through time. Features such as pyrite "shells" and sphalerite and marcasite hemispheres may have been localized by hydrocarbon droplets and /or bacterial colonies. Marcasite mineralization in shallow strata above and flanking Hockley dome is best developed over the western and southern parts of the dome. This pattern mimics the known distribution of sulfide mineralization, which is dominantly marcasite, in the underlying cap rock. The iron sulfide paragenetic sequence in the sediments is pyritohedral and cubic + pyrithohedral pyrite followed by marcasite which is encrusted by cubic pyrite. Sulfur isotopic averages for the three stages are +20.8, -20.2, and +6.4 per mil, respectively. These values generally coincide with cap rock sulfate (+20 per mil), cap rock hosted metallic sulfides (-20 to +4 per mil), and sulfur in hydrocarbons (+5.8 per mil). Hydrocarbon compositions indicate provincial variations in oil composition and generation history. Long Point and Boling domes, which have an intergrown sulfide-sulfate-sulfur mineral assemblage indicative of mixed reducing-oxidizing environment, contain oils that are less mature than Hockley dome which appears to be more mineralogically segregated. Sterane biomarker compositions of the oils at Hockley, Long Point and Boling domes indicate a local, dominantly terrestrial source. An oil sample from supracap sandstones on the northeast flank of Hockley dome contained over 750 ppm combined Fe, Zn, Pb, and Co, indicating that hydrocarbons are carrying or remobilizing metals. Cap rock calcite and anhydrite also exhibit provincial variations in strontium isotopic ratios. Calcite and anhydrite cap rocks from several sulfide mineralized domes in the Houston diapir province have strontium isotopic ratios that are more radiogenic than Jurassic sea water (>0.7078). A calcite sample within massive sulfides at Winnfield dome also has a high 87Sr/86Sr ratio (0.7085). Variations in strontium isotopic ratios with strontium content indicate the mixing of at least three Sr-bearing fluids in the cap rock environment, one of which may have been the metal carrier. Anhydrite residues from diapiric salt have strontium ratios up to 0.7100, considerably more radiogenic than Jurassic seawater. These high ratios indicate either that salt and anhydrite recrystallized sometime post-Jurassic in the presence of a fluid with a high 87Sr/86Sr ratio, or that they precipitated in the Jurassic from a fluid with a higher 87Sr/86Sr ratio than Jurassic seawater. Salt domes with cap rocks containing metallic sulfides have only been found in basins that have geopressured zones. Waters from geopressured zones in the vicinity of mineralized salt domes have salinities that are two or more times higher and iron and base metal concentrations that are three to one thousand times higher, than geopressured fluids from other parts of the basin.

Jan 1, 2013

By C. H. Grant

On the Mesabi Range, Ammonium Nitrate is used for blasting a variety of materials having widely varying blasting characteristics. The materials vary from hard, dense, magnetic taconite, which requires heavy blasting, through relatively soft, earthy, direct shipping ores, which require only light blasting to facilitate shovel operation. In view of the fact that materials gradational between these two end members are encountered in large tonnages, it is evident that a wide range of blasting situations face the mine operators on the Mesabi Range. In April of 1956, at Cleveland-Cliff s Hawkins Mine near Nashwauk, Minnesota, a fertilizer grade of Ammonium Nitrate prills was first used as a blasting agent. This first attempt was made without the addition of any carbonaceous material and even though it did go off, the force was not sufficient to produce the required results. Fuel oil was then added In the amount of one gallon for each 80 pounds of Ammonium Nitrate, with the oil and Ammonium Nitrate being added to the hole simultaneously. This blast was successful. Since then most of the mining companies have used Ammonium Nitrate, experimenting with various ratios of oil and fertilizer, mixing these ingredients either before or during loading of the holes. Since the additional of fuel oil to the Ammonium Bitrate before loading produces a more uniform saturation, most companies have adopted the method of pouring the fuel oil directly into the Ammonium Nitrate bags and then pouring the mixture into each hole. The ratio of 3- ½ quarts of fuel oil to each 80 pound bag of Ammonium Nitpate prills is now being used.

Jan 1, 1958

By NORMAN D. FitzGkrald

IN 1942 the outstanding characteristic of the petroleum industry was the multiplicity of war-induced distortions in virtually every segment of the business. So devastating was the success of the Nazi submarine campaign along the shores of the western Atlantic and on transoceanic routes that within six months after our entry into the war petroleum rationing was necessary in the East Coast area. The conquest of the Netherlands Indies by the Japanese three months after the opening of the war in the Pacific cut off our normal sources of rubber, and in our first year of war nationwide rationing of gasoline had to be invoked to conserve rubber-borne transportation facilities. Meanwhile the oil industry faced the imperative necessity for rapid expansion in the output of aviation gasoline and later accepted the vast responsibility for developing a new industry. synthetic rubber manufacture. Probably no other essentially peacetime industry has been forced to make so many complicated adjustments, yet its response to its wartime obligations has been nothing short of dramatic.

Jan 1, 1943

By L. Alagha, L. Sanchez-Calderon, M. Silwamba, W. Kirk

Selenium-rich metallurgical waste, also known commercially as “crude selenium,” is a byproduct of the copper (Cu) refining process. This by-product, contains ~ 90% selenium (Se), precious metals, platinum group metals (PGMs), and other critical elements. This study investigated the leaching efficiency of Se from the sludge under alkaline conditions using different oxidizing agents to enrich PGMs and precious metals in the leach solid residue. The effectiveness of each oxidizing agent during leaching was assessed and compared. Additionally, Eh-pH diagram for Se was established under specific experimental conditions and utilized to inform process optimization. Key variables, including leaching time, temperature, and oxidant concentration, were evaluated for their impact on the efficiency and the selectivity of the oxidative alkaline leaching process.

Feb 1, 2025

By V. Baltazar

The behaviour of arsenic and antimony during copper electrorefining was studied in order to identify the conditions under which good quality copper cathodes could be produced from anodes with high levels of these impurities. Examination of the effect of current density over the range 21 to 37 mA/cm2 indicated that the relative amounts of As and Sb entering the electrolyte affected the onset of passivation. When the ratio of As/Sb entering the electrolyte was greater than 2, the anodes showed no sign of passivation even at the highest current density; when the ratio was less than 2, the anodes passivated at 37 mA/cm2. Cathode analyses showed that anodes with an As/Sb dissolution ratio less than 2.0 tend to produce cathodes of inferior quality even at normal current densities (25.7 mA/cm2). The criterion of a minimum As/Sb dissolution ratio of 2.0, and mathematical correlations for the distribution of As and Sb between the electrolyte and slime developed in a previous study, allow the calculation of the maximum allowable Sb level in en anode for a given As concentration. Analyses of plant data at the CCR Division of Noranda Inc. for the last four years of operation have demonstrated that the use of this as a quality control tool has allowed the quality of copper cathodes to be maintained despite a significant increase in the average Sb levels in anode receipts.

Jan 1, 1987

By J. A. du Plessis, C. Dorfling

Selenium, tellurium and other precious metals (OPMs, namely Rh, Ru and Ir) dissolve in the final leaching stage of base metal refineries. Se and Te are typically removed from the copper sulphate leach solution by precipitation with sulphurous acid. Recovery of dissolved OPMs is desirable because it will reduce OPM inventory and losses. Thiourea is an effective OPM precipitation reagent, but yields insufficient Te removal. Copper is known to enhance Te precipitation when using sulphurous acid as precipitation reagent. The primary objective of this project was to evaluate whether simultaneous precipitation of Se, Te and OPMs using thiourea with metallic copper as precipitation reagents is possible. Batch precipitation tests were performed to evaluate the effect of temperature (50 – 70°C), thiourea addition (160 – 430% excess) and copper addition (2 – 8 g/L) on Se, Te and OPM precipitation. Increasing the temperature from 50°C to 70°C resulted in an average increase of 55.6 percentage points for Se precipitation and 13.5 – 23.5 percentage points for OPM precipitation. The copper addition did not have a significant impact on the precipitation behaviour. Increasing the thiourea addition increased the precipitation of Se and Te, especially when the copper addition was low; Rh and Ru precipitation also increased with up to 10 and 12 percentage points, respectively. Despite these observations, the precipitation of Se was significantly faster when no thiourea was added. It is not currently clear why thiourea appears to inhibit the Se precipitation by reaction with metallic copper. In general, Te precipitation was low (less than 30%) at the conditions investigated. Simultaneous precipitation of Se, Te and OPMs at temperatures below 80°C does not appear to be a viable option; a multiple stage operation for sequential removal of Se and Te with copper followed by OPM precipitation with thiourea would be required.

Jan 1, 2016