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By V. A. Chanturiya

In Pt- and Au-keeping complex ores processing, about 10% ~ 15% of noble metals are lost with true tailings that are due to low floatability of Pt- and Au-keeping minerals by the conventional collectors. With the aim to achieve the effective recovery of noble metals at flotation of Pt-Cu-Ni and Au-keeping ores organic complex reagents keeping electron-donating atoms of nitrogen, oxygen, sulfur or phosphorus may be offered as selective collectors for the indicated minerals. These rea-gents tend to form complex compounds with PGM. Besides this, Cu-Ni-Pt and complex Pt and Au carbonated mica ores are characterized by finely disseminated (up to nanometer size) mineral forms of Pt in multivalent states. In this connection, the use of a combination of the strong ionic collectors with nonionic reactants that are capable to derivate complex compounds with multivalent PGM seems to be expedient for this type of ores. In the research new complex reactants were tested such as cyclic alkylene-trithiocarbonates, oxyalkyl butylxanthogen acid ethers, a combination of the collectors ? mercaptobenzothiazole (MBT) and dialkyldithiophosphates (DTP). Sorption and flotation tests were made with monomine-ralic samples of chalcopyrite, pentlandite, pyrrhotite, pyrite, and Pt-Cu-Ni sulfide ore samples. Sorption properties were examined by the extractive UV spectrophotometric method and potentiometric measurements. To indicate a structure of modified xanthate solutions the method of a thin-layer chromatography (TLC) was applied. The chromatographic behavior of the basic components of modified xanthate solution ? ButX, cyclic propylene-trithiocarbonate (PTTC), diethyl-dithiocarbamate (DEDC) and the product of its modification ? oxypropyl-S-ether of dithiocarbamatic acid was studied on plates ?Silufol UV ? 254?. The composition of organic solvents and its ratio in a mobile phase was deter-mined for simultaneous chromatography of the main components of a reaction mixture. It was found that operating selectivity of MBT, DTP and cyclic alkylene-trithiocarbonates incorporated in modified xanthate in relation to Pt-Cu-Ni and Au-containing sulfide minerals might be explained by an electoral sorption of this nonionic collector on a surface of the minerals studied. It was demonstrated that the application new reagent modes with the use of a combination of designed complex reactants helped to increase the extraction index of Pt- and Au-keeping minerals from complicated ores.

Jan 1, 2014

By Haydn H. Murray

Kaolin is defined and described as an industrial mineral. In addition the types of deposits -primary and secondary are defined and the genesis of kaolin from feldspars and other minerals discussed. The major deposits of the world found in the United States, Great Britain, Brazil, and Czechoslovakia are described along with many of the minor kaolin deposits. Four areas which have very large deposits of kaolin could, with technological breakthroughs to reduce viscosity significantly, become important factors in supplying the world markets which are increasing year by year.

Jan 1, 1977

By Eric J. Beckman

Recovery of metals from dilute solution, whether the matrix is solid, or liquid, remains a considerable technical and financial challenge. Methods currently exist whereby metals can be extracted from either type of matrix, yet these methods consume significant quantities of reagents and can also generate multiple waste ,streams in the process. Technology developed in our lab allows efficient application of environmentally-benign CO2 to a number of separation problems involving metals. For example, we have employed biphasic mixtures of C02 and water as a green acid leach medium. Metals have been extracted from a steelmaking process residue and then recovered as metal carbonates through depressurization. In this process, metals are extracted and recovered without the use of reagents other than CO2 and water, and CO2 is sequestered as a solid. In addition, through synthesis of Cal-miscible phase transfer agents, we have shown that CO2 can replace the organic solvent currently used in refining of precious metals, The sensitivity to pressure of phase behavior in a CO2-mixture may allow significant streamlining of the process as well. Finally, CO2 soluble chelating agents have been used to extract toxic metals from acidic effluent such as that found in plating facilities.

Jan 1, 1999

By Y. Belloa, C. Dorfling

The presence of impurities such as Se and Te in copper sulfate leach solutions can have a detrimental effect on electrowinning efficiency. These elements can be removed from the solution by precipitation; sulfurous acid is commonly used as a precipitation reagent, while studies have also reported improved precipitation with the addition of metallic copper. This paper aimed to determine the effect of conditions used during the solution purification step on the characteristics of the precipitates that formed. Precipitation tests were performed in a batch reactor with copper sulfate leach solutions obtained from the base metal refinery of a platinum group metal producer. The effects of agitation rate (250 and 500 rpm), SO2 flow rate (4.4 and 5.8 mL/min.L), temperature (65 and 95°C) and metallic copper powder addition (0, 1 and 2 g/L) on the characteristics of the precipitates formed during the tests were determined using scanning electron microscopy. The major phases detected in the precipitates formed when using SO2 as the only precipitation reagent were elemental Se and Cu2Se. The introduction of copper powder led to the production of different sulfide phases for the experiments conducted at 65°C irrespective of the values of the other reaction parameters. At 95°C, Cu crystals, Cu2O and tiny inclusions of Cu2(Se,Te) were the prominent phases noticed in the precipitates produced from all the tests conducted with copper powder as precipitation enhancing reagent. Keywords: copper, precipitation, selenium, tellurium

Jan 1, 2020

By Törbjorn Naarttijärvi, Bengt Ludvig, Agne Rustan

"Falling rock is one of the major causes of serious injuries and deaths in Swedish mines. The research at the Division of Mining and Underground Construction was therefore directed toward controlled blasting in hard intense jointed rock.The project was started with an extensive literature review. Model tests with a new equivalent model material have been initiated to find ways of improving blasting techniques. The result showed that long cracks arise at the perimeter holes when there is a long time delay between adjacent holes. This led to the theoretical development of a new initiation method with ultra short delays (1,5 ms) f or controlled blasting, called ""Cutblasting"".Full-scale tests have been done at LKAB in Malmberget in hard intense jointed magnetite ore. Four different types of perimeter charges have been tested, namely: tube charges, ANFO mixed with plastic beads, detonating cord and linear shaped charges. Three types of initiation of the perimeter holes have been used, conventional (half-second delay detonators), instantaneous and ultra short ""cutblasting initiation"" (1,5 ms delay). The change in rock strength before and after blasting has been studied with bore hole periscope, vibration measurement and ocular observation of the rock surfaces.Thefull-scale tests showed that ""cutblasting"" with detonating cord in the perimeter holes gave the smallest damage to the surrounding rock. A combination of cutblasting initiation and tube charges are anticipated to give an even better result. A new method of controlled blasting using linear-shaped charges has also been tested, however, this charge type needs further development.The full- scale test also showed that the damage which can be seen on the rock surf ace is about the same for different controlled blasting methods but the not-visual-damage zone varies as much as from 0,1 to 0,7 m.A new classification system for controlled blasting regarding the damage to the surrounding rock has been devised."

Jan 1, 1985

Knowledge of initial ground pressures or in-situ stresses and mechanical properties and geological conditions is of great importance in drivage and maintenance of a mine roadway. Field measurements of the in-situ stresses and the geological and mechanical properties have been carried out. However, these methods are really impractical in using in underground mines. Alternatively, back analysis method using measured displacements during drivage of roadway can be used. The paper presents discussion on some problems in applying inverse formulation of back analysis to a roadway driven in an in- homogeneous rock mass. The back analysis is formulated by 2-0 finite element method. The inverse procedure is carried out using a microcomputer, but for the multi-rock layer, a larger computer or a main-frame computer is used due to an iterative procedure.

Jan 1, 1990

By Young C. Kim

Introduction and Objective of This Paper Computerized open pit mine models* are more and more used today for feasi¬bility studies as well as for long range mine planning. In fact, using these models is becoming an enforced practice due to various reasons. One main reason is its capacity to evaluate several designs in a fraction of time required by manual effort. Another reason is the necessity to evaluate several. pit designs due to ever decreasing grade of the orebody and increasing financial risk due to smaller profitability margin. In spite of today's accepted use of computer models, very little guidelines are available which the average practitioner can follow either to choose or to build the type of model best suited for his need. Consequently, the objectives of this paper are: 1. To review the current state of the art in the computerized open pit mine models. 2. To provide some suggestions for model selection. 3. To share our experiences in developing a model for a highly irregular copper ore deposit (see Appendix).

Jan 1, 1977

By S. P. Sandoval

Previous research by the U.S. Bureau of Mines demonstrated that nonionic surfactants increased the leaching rate of copper in the flask leaching of chalcopyrite with ferric sulfate if sufficient ferric sulfate was present. This research was continued by the Bureau in Part 2 to further explore the application of nonionic surfactants to the dump leaching of chalcopyrite. A polyoxyethylene lauryl ether was selected as the superior nonionic surfactant tested at 25° and 50° C. The addition of the surfactant increased copper leaching by 116 pct at 25° C and 1.0 pct solids and by 61 pct at 50° C and 0.5 pct solids at Fe 3+ concentrations greater than 1 g/L. At 0.1.0 g/L Fe 3+ and below, the addition of the surfactant produced as much as a 35 pct decrease in leaching. Each of the nonionic surfactants studied was found to be heavily adsorbed by a typical chalcopyrite ore, which poses a serious barrier to the application of nonionic surfactants in an actual chalcopyrite dump.

Jan 1, 2010

By H. Agnerian

"A survey of 925 mineral property transactions worldwide was carried out between 1987 and 2004. These mineral properties with reported Mineral Resources include 457 gold properties, 322 base metal properties, and five platinum group element (PGE) properties. Based on constant Canadian dollars, the results of the survey indicate that:• In general, unit metal values in the ground (e.g. $/oz Au or $/lb Cu) have kept pace with the changes in the respective metal prices during the period of the survey.• A general decrease in unit gold values in the ground has occurred from about $57/oz Au in 1987 to about $11/oz Au in 2002 for Canadian mineral properties, with the exception of a peak of $58/oz Au in 1996.• A similar trend for mineral properties has occurred in the United States, but with lower unit values, in the range from $1/oz Au to $10/oz Au during the last three years of the survey. • Unit metal values in the ground for gold properties in Canada were higher than for those in the rest of the world.• Unit metal values in the ground for copper properties in Canada were in the mid-range compared with other countries in the rest of the world; the United States and Australia were higher and Latin America, Asia, Africa, and Europe were lower than in Canada.• Unit metal values in the ground for zinc properties in Canada were also in the mid-range compared with other countries in the rest of the world; Latin America and Europe were higher and the United States, Australia, and Asia were lower than in Canada.• Unit metal values for nickel properties in Canada were highest compared with other countries in the rest of the world, followed by the United States, Australia, Africa, and Asia.• Gold values in the ground in Canada have ranged from 6% to 14% (with an average of approximately 10%) of the gold price.• The unit values of base metals in the ground have been in the order of 2% of the quoted metal price, during the period of the survey."

Jan 1, 2006

By Jack Eloranta

This paper documents the relationship between material handling and processing coete compared to blasting cost. The old adage, "The cheapest crushing is done in the pit", appears accurate in this c!ase study. Comparison of the accumulated cost of: powder, selected wear materials and electricity; indicate a strong. inverse correlation with powder factor (lbe powder/long ton of rock). In this case, the increased powder cost is more than offset by electrical savings alone.

Jan 1, 1995

Recovery of Tantalum Capacitors from Waste Printed Circuit Boards Using a Pneumatic Separator

Sep 13, 2010

By Manqiu Xu, Glen Robertson, Steve Wilson, Pete Quinn

"The middlings circuit, once called the pyrrhotite rejection circuit, at Inco’s Clarabelle mill was a single flotation stage. It used to process a combined feed consisting of the main flotation scavenger concentrate and the non-magnetic portion of the magnetics flotation circuit tails. The typical circuit metallurgy was 55% nickel recovery at 6.5% Cu+Ni concentrate grade. In the past few years, a research project with the objective of improving the circuit metallurgy was initiated between Inco’s research laboratory and the Mill’s Process Technology group. This project has gone through three steps: a) initial laboratory studies, b) on-site pilot plant investigation, and finally c) full plant implementation.The present paper describes the initial laboratory test work. The development of a two-stage circuit consisting of separate rock and pyrrhotite rejection stages to replace the simultaneous rejection of both rock and pyrrhotite in a single stage is discussed. A two-stage circuit simulation based on batch laboratory flotation data is also presented. Further development work, including the on-site pilot plant test work and the plant implementation of the new circuit design, will be described in a later publication.INTRODUCTIONThe milling operation at Inco’s Clarabelle mill, Copper Cliff, Ontario processes a rich complex sulfide ore from several large production mines around the Sudbury basin (Agar, 199 1). The sulfide mineralization is simple, consisting of chalcopyrite (Cp), pentlandite (Pn) and pyrrhotite (Po). The main gangue minerals are pyroxene, feldspar and quartz with minor amphibole and talc. Estimates of mineral composition are routinely calculated from Cu, Ni and S assays. In the mineralogical calculations, all gangue minerals are conveniently grouped and treated as rock (Rk)."

Jan 1, 2000

By J. R. Cobble

As part of the Federal Bureau of Mines project to develop new or improved materials for metallurgical furnace applications, the Tuscaloosa (Ala.) Research Center has conducted research to develop a reproducible laboratory test for evaluating the resistance of refractories to molten slags. Tests were conducted with a slag representative of slag used to produce mineral wool. A rotating cylindrical furnace was lined with the brick being tested, and it was operated at temperatures up to 1,660° C for periods ranging from 8 to 32 hours. The effects of such variables as slag temperature, rotational velocity, charge rate, and contact time on refractory erosion were determined. The research demonstrated the reproducibility of the test procedure developed.

Jan 1, 1980

By G. L. Fitzpatrick

Preliminary results of an experiment in seismic holography indicate that the techniques of acoustical holography may be successfully used with seismic waves to determine the size and general shape of underground objects. This experiment was carried out under field conditions on a moderately large scale compared with the typical laboratory experiments in acoustical holography. The object to be mapped was a 100-foot-diameter, spherical, low-velocity zone of explosively fractured rock in oil shale at an average depth of 80 feet. The seismic wavelength of the Fourier component wave used in making the seismic holograms was 50 feet at a frequency of 140 cps. The hologram sampling aperture was 226 feet square and was sampled by 441 geophones in a 21 by 21 rectangular array. One novel aspect of the experiment was the use of a wide-band polychromatic explosive source of seismic waves rather than a narrow-band quasi-monochromatic vibrator source. A successful laser reconstruction of the object image from a lensless Fourier-transform hologram in the form of a 5/l6-inch-square photographic transparency is illustrated. The size of the underground object measured from the laser reconstruction of the object and the size inferred from a knowledge of the amount of explosives used to fracture the site and the tensile strength of the oil shale are found to agree.

Jan 1, 1972

Development of a permanent human base on the Moon for exploration requires a self sustaining system. This entails production and processing of limited amounts of raw material on the Moon. Any mining and construction activities on the Moon can only be performed by a robust excavation machine that can excavate a variety of material from loose surface regolith to consolidated (frozen) regolith with embedded rocks in the mixture. Meanwhile, limited amount of information on lunar regolith is available to develop and optimize a machine for given lunar ground conditions. Therefore, any excavator designed for use on the lunar surface should have the ability to adapt to a wide range of operating conditions. A prototype cutterhead for the lunar excavator was built and tested at the Kennametal facility in Latrobe PA A. This paper discusses the results of initial material characterization as well as full scale tests of a prototype cutterhead inrelevent material. A brief review of anticipated production rates under various assumed ground conditions will also be presented.

Jan 1, 2009

By Patrice Favreau

In 1990 the Noranda Technology Centre commenced a project to develop an interactive three-dimensional blast design system using a commerical computer-aided drafting and design package (CADD). The objective was to alleviate the blast engineer from the tedious and time consuming blast layout and design functions normally done by hand. This would allow more time for optimizing blast designs through assessing multiple options. Since several blast design software "tools" already existed at Noranda, the need arose to integrate all the applications into one overall system that shared one common database. The result is BLASTCAD.

Jan 1, 1992

By N. Sasto, E. Bondi, G. R. Lane

Cyest Corporation has been involved in economic modelling and optimisation with various mining clients within South Africa, and internationally, for the past 5 years. In the mining industry in particular, the relationships between variables that are controllable, and those that are not, and the physical and economic outcomes are complex and often non-linear. These relationships constitute an economic system. In the mining context, although many of the relationships can be accurately quantified on a ?single variable to single variable? basis, such simplistic relationships will not suffice in order to understand the dynamics of an entire mine. One has to specify and quantify the relationships between hundreds, if not thousands, of variables. Furthermore, in reality, these relationships change over time. This is the role of an economic model where all the relevant cause-effect relationships, within pertinent constraints, are accurately represented. Models that are used for optimisation must therefore capture the dynamics of the economic system in question as well as anticipate changes to the relationships between these variables. An accurate economic model is a prerequisite for successful optimisation. Optimisation entails the allocation or configuration of resources, within control of management, which will maximise (or minimise) a desired objective function. An optimal configuration (implying trade-off) of controllable variables therefore exists for a given set of assumptions that will yield a maximised objective function. Due to the multi-variant trade-offs required for optimisation, the concept of the ?Economic Surface? or ?Hill of Value? has been used to represent these optimisation outcomes and to discern the route to an optimal configuration. A good example of this is the volume versus cut-off grade trade-off that yields an optimal value for a particular shaft with its unique geological and economic assumptions. More recently, Cyest has extended these economic models to incorporate risk associated with variance in assumptions and inputs. This is termed DFA (dynamic financial analysis) and incorporates stochastic modelling and some of the latest actuarial techniques around modelling global assumptions (such as pricing and exchange rate). This paper will cover the theory around mine optimisation through some example case studies, and also explain the latest thinking regarding incorporating DFA.

Jan 1, 2007

By T. W. Beck

Overexposure to respirable dust remains a widespread health hazard to roof bolter occupations in underground coal mines. Recently implemented mist drilling technology was evaluated for its effectiveness in controlling respirable dust exposures for roof bolting personnel. This work presents the findings from NIOSH field and laboratory studies comparing respirable dust levels on mist drilling roof bolter machines to dust levels measured on machines using a conventional vacuum drilling system. Gravimetric and instantaneous respirable dust samples were collected for multiple drilling cycles. These dust measurements were used to assess the potential dust control capabilities relative to conventional drilling. Controlled laboratory tests found 0.3 mg/m3 more respirable dust with mist drilling than with the conventional vacuum method. A separate field investigation of the two techniques observed higher dust levels around the mist bolting machine.

Jan 1, 2008

By M. -C. Noël, G. P. Demopoulos

In this work the formation and environmental stabilization potential of arsenate-containing fluoroapatites is considered. In particular in this research various compounds were precipitated from synthetic solutions containing fluoride, arsenate/phosphate and calcium by varying different parameters-temperature, Ca:As ratio, pH, and P:As ratio, and aging time. The results obtained helped determine the operating window that should be used for the formation of highly crystalline fluoroapatites, in particular svabite (Ca5(AsO4)3F). It was found that svabite has a specific pH range of precipitation, with lower pH yielding CaF2 and calcium arsenate compounds such as CaHAsO4•H2O. At higher pH, a mixture of svabite and johnbaumite (Ca5(AsO4)3OH) precipitated, yielding a less stable material. This range of precipitation varied with the concentration of arsenic in the starting solution, and widened with higher initial concentrations of Ca2+, AsO4 3- and F-. Furthermore, svabite/fluoroapatite solid solutions were formed by using the same procedure as svabite but replacing some of the arsenate in solution by phosphate. The increase in phosphate content yielded a gradual change in morphology and crystallinity. Work on stability evaluation is currently under way.

Jan 1, 2014

By E. Gratz, U. Pal, A. Powell, S. Pati, J. Milshtein

"The solid oxide membrane (SOM) process has been used at 1150 'C to produce magnesium by direct electrolysis of its oxide. Magnesium oxide is dissolved in a molten CaF2-MgF2 ionic flux. An oxygen-ion-conducting yttria-stabilized zirconia (YSZ) SOM membrane separates the cathode and the flux from the anode. During electrolysis, magnesium ions are reduced at the cathode and Mg(g) bubbles out of the flux into a separate condenser. The flux has a small solubility for magnesium which imparts electronic conductivity to the flux. The electronic conductivity decreases current efficiency of the process and also degrades the YSZ membrane. This study investigates different methods for reducing the electronic conductivity of the flux due to magnesium solubility. One effective method shown here is inert gas flushing near the magnesium nucleation site. Potentiodynamic and potentiostatic experiments along with AC impedance spectroscopy are used to characterize the effectiveness of the approach.IntroductionMagnesium is the third most abundant metal in the earth's crust. Since magnesium is the lightest of all metals used for construction alloys, magnesium is the leading candidate to replace steel and aluminum in automobiles. Automobile manufacturers would like to increase magnesium content from 4-5kg per vehicle to 40-IOOkg per vehicle [I]. Using magnesium alloys instead of steel and aluminum can reduce automobile weight and improve fuel efficiency. However, in order for automobile manufactures to make this change, it is generally believed that new cost effective methods of magnesium production must emerge.One approach for magnesium production which has been shown to be effective on a laboratory scale is the direct electrolysis of magnesium oxide utilizing an oxygen-ion-conducting solid oxide membrane (SOM), this is known as the SOM process [2]. A recent study estimated that a commercial SOM plant could produce magnesium from magnesium oxide at a cost that is 40% less than current technologies [3]."

Jan 1, 2012