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By Vladimir Vigdergauz, Sergey Kondratiev

The paper reviews the existing criteria of the formation of particle-bubble aggregates during flotation. It is shown that predictions obtained by these criteria do not completely fit to the interaction between mineral particles and air bubbles. Experimental results of the studies into the influence exerted by molecular forms of collectors on the particle-bubble interaction are reported. Rate of dry spot expansion on the surface of pyrite with various combinations of chemically and physically adsorbed xanthate are examined. It is shown that molecular forms of collectors accelerate the rate of dry spot expansion on the mineral surface after the local rupture of the water film between particle and air bubble. The authors come to a conclusion that the molecular forms of collectors remove water from the interlayer between mineral particle and air bubble during their contact. Similarities of the proposed mechanism with the action of ion-molecular associates of fatty acids and amines are discussed. Reagents with high surface pressure and rate of spreading at the water-bubble interface are required for the effective interfacial dewatering. It is concluded that the value of surface pressure can serve as the criterion for efficiency of physically adsorbed reagents. The low surface pressure indicates weak collecting ability but high selectivity of the collector. Therefore, the presence of the molecular forms of collectors in the sorption layer is the necessary condition for formation of particle-bubble aggregates, and comparison of the surface tensions of collectors could be recommended as the estimation criterion of their flotation activity and selectivity.

Jan 1, 2014

By H. F. Perkins

CORROSION as an economic problem is growing rapidly in importance not only because it entails a replacement of corroded parts, but because it interrupts operation and causes hazards of damage and injury through failures of corroded equipment. Nearly all industries are interested in this subject. This paper, although concerned chiefly with corrosion in a complete refinery on the sea coast, discusses many of the various forms of chemical decomposition, most of which are found universally. The petroleum refining industry, in the writer's opinion, is seriously afflicted by the presence of sulfur in nearly all crude oils. The complete removal of sulfur from the crude as it enters the plant would cause such a relief from corrosion that this problem for research would seem to demand active attention. Next to sulfur the most troublesome corrosive agent is the saltmagnesium chloride, found in the water associated with crude oil, the last traces of which are so difficult to remove. This is much less serious, however, than the sulfur. Refinery corrosion can be tabulated as follows: Causes of Corrosion and Places of Attack in a Refinery CORROSIVE ELEMENTS MATERIAL ATTACKED Air: Pipe lines Moisture Tanks COQ Electric fixtures Sulfur gases Still towers Chlorine Condenser boxes Other acid-forming gases Ladders and stairs Smoke stacks Steel buildings All exposed metal Water: Alkali Fire lines and hydrants Acids Cooling water lines Air Condensers and coolers Other dissolved gases Boiler tubes Steam Steam pipes and valves Turbines Oil Sulfur compounds Tanks, pipes, valves, stills, towers MgCl2-Hydrochloric acid Condensers Air contamination

Jan 12, 1926

By Philip K. Hopke

A systematic study of the mechanism of interaction of 218Po(RaA) armed by the decay of 222Rn with airborne particulate matter has been made. The rate of attachment of RaA to particles in the diameter range of 0.1 µm to 10.0 µm has been measured as a function of particle size, concentration, and composition, radon concentration, time of interaction, relative humidity and temperature. It was found that under the conditions in these experiments the attachment rate was proportional to the square of the particle diameter and varied with temperature and relative humidity. The composition of the particles apparently has no effect on the attachment. The variation in attachment rate was related to a sticking probability coefficient of approximately 0.02 that varies systematically with temperature and humidity. In addition, the rate of deposition of RaA on the wall of the attachment kinetics system was measured and also found to change with temperature and relative humidity.

Jan 1, 1980

By Bern Klein

Motivation for Improved Energy Efficiency in Mining ? Canada potentially adopting Greenhouse Gas Emissions and Intensity Legislation in 2013 ? BC -Climate Action Plan and Energy Conservation Agreement in 2008 ? BC Energy Plan 2007 -BC Hydro is mandated to save 50% of new load growth ? TSM Initiative -Energy Management, Energy Reporting, Setting Energy Targets, GHG Management BC MOU for Energy Conservation Agreement -MEMPR, MABC, BC Hydro

May 1, 2010

Flotation of Phosphate Gangue from Magnetite Fines - Non-Ionic Surfactant as Atrac Collector Modifier

Sep 13, 2010

Provide long-term measurement of mine sidewall closure in backfilled stapes subject to flooding. Approach A water resistant extensometer is made by enclosing a rod-actuated transducer in a telescoping tube which is enclosed within an oil-filled outer housing. How It Works To assemble a water resistant extensometer, a cylinder -shaped transducer and two support rings are pushed into the small-diameter section of the telescoping tube where the transducer is held in place by friction. The outside of the small-diameter section of the telescoping tube is then greased and slid into the slightly larger-diameter section. See drawing. The cylinder-shaped transducer contains a potentiometer whose actuating arm is attached to a stainless steel extension rod that passes through one end of the telescoping tube. A similar rod is attached to the opposite end of the transducer body, and extends through the other end of the telescoping tube. A coil spring inside the large diameter end of the telescoping tube extends the tube

Jan 1, 1978

Radio Detection and Ranging is an active form of remote sensing. The-imaging system sends out a source of electromagnetic energy to 'illuminate' the terrain and then records the energy returned. The wavelengths used by radar are in the microwave region and vary from a few millimetres to about a metre. Radar systems are independent of lighting conditions and weather. In addition, targets may be illuminated in the optimum direction to enhance features of interest. New Zealand was one of the principal investigators on the Shuttle Imaging Radar (SIR-B) experiment, part of the payload on Challenger Mission 41-G in October 1984. Data collected over New Zealand was restricted to two very poor quality optical images and one poor quality digital data take. The digital image covered the ranges between the Hawke Bay-Wairoa Basin and the Volcanic Plateau. Variations of texture in this image frequently were indicative of variations in lithology and induration. The image also clearly depicted major faults where these had had a significant effect on the topography.

Jan 1, 1986

By Ron Millions, J. A. Folinsbee, Ishwinder Grewal, Michael Fullam, Don Strickland, Tony Y. Chong

"Since milling began in 1912, the Dome mill, now part of the Porcupine Joint Venture (PJV), has been expanded several times, the most recent increasing the milling rate from 3,500 to 11,500 tonnes per day. Dome uses conventional crushing and grinding followed by gravity concentration to recover free milling gold. A cyanidation/CIP process recovers the remaining gold in the gravity tails.Over the past few years, continuous gravity improvements have increased the gravity recovery from 20% to nearly 50% of the plant feed gold. This paper describes some of the factors that have contributed to this dramatic increase, and suggests how gravity recovery can be further improved. Gravity circuit availability has been improved to >98% with the implementation of a preventative maintenance program. More Knelson concentrators have been added to the circuit, and in 2002, an Acacia Intensive Leach Reactor was installed to replace the shaking table. In 2003, the entire gravity circuit was audited to evaluate and quantify the circuit performance. The metallurgical and mechanical operating conditions of the gravity circuit are now well understood, and areas for further improvement are well defined.INTRODUCTIONThe Porcupine Joint Venture was formed in 2002 between Placer Dome Inc. and Kinross Gold Corporation. One of the goals of the JV was to use the milling capacity of the Dome mill to process ore from Placer Dome and Kinross mines in the Timmins Camp. The PJV Dome Mill utilizes gravity concentration, cyanide leaching and carbon in pulp gold circuits to recover gold. Gravity recovery has been used in some form at the Dome Mill for most of its existence, first using conventional jigs, these being replaced in 1993 by two Knelson Concentrators, one for each of the two grinding circuits in the Dome mill. Over the years more concentrators have been added to improve the gravity recovery, most recently in 2002 for a current total of five. Also in 2002, an Acacia Intensive Leach Reactor was added to process the Knelson concentrate, replacing the shaking table."

Jan 1, 2004

Pyrometallurgy has played a very important role in southern Africa for at least four centuries. It continues to do so, and recent years have seen many exciting developments in pyrometallurgical technology. The wonderfully diverse rich mineral deposits in this area of the world have provided some unique opportunities for industrial processes to be established. The ?Southern African Pyrometallurgy 2006? conference was set up to showcase southern African pyrometallurgical operations, and to provide a forum for the exchange of ideas between people working at various types of smelters. Papers have been obtained from a wide variety of pyrometallurgical plants in southern Africa. These descriptions of plant operations (as well as some history, and highlights of current work) will provide useful reference information for some time to come. Contributions are also included from universities, research organizations, and engineering companies, so that the full spectrum of pyrometallurgical activities can be covered. The plant descriptions will be published on a website, where they can be updated as and when required, with the eventual goal of having a description of every smelter in the region. The conference venue was selected to be the 'Cradle of Humankind' world heritage area, about 40 km from Johannesburg. Not only does this keep the conference within easy reach of the city and yet far enough out into the countryside to allow people to focus on the conference, it is also within easy reach of many pyrometallurgical plants. There is a particular significance to the choice of location, in that the Swartkrans area close to the Sterkfontein Caves is the site of the earliest evidence of the deliberate controlled use of fire by human beings (about 1.3 million years ago), and this is obviously a necessary precursor to pyrometallurgy. The area also lends itself to a very wide range of outdoor, social, and cultural activities to supplement the technical content of the programme. It is hoped that activities such as a hot air balloon safari and visits to the world-renowned Sterkfontein Caves and Wonder Cave will help to make the conference a memorable one for those able to attend. I trust that the ongoing value of the papers and presentations will make all the hard work of the many contributors most worthwhile.

Jan 1, 2006

The Awareness and Preparedness for Emergencies at the Local Level (APELL) program is a process that helps people prevent, prepare for and respond appropriately to accidents and emergencies. APELL was developed by the United Nations Environment Program, in cooperation with industry groups, governments and local communities. Since its beginnings in1988, the program has been implemented in more than30 countries. APELL is a tool for bringing people together to allow effective communication about risks and emergency response. The program provides a common-sense approach to accident prevention and response.

Jan 1, 2003

By W. P. Yant

A previous report of the Bureau of Mines dealt with the toxicity of dichlorodifluoromethane5, a new refrigerant that has a remarkably low toxicity. Continued research by the Prigidaire Corporation6 and toxicological experiments performed in the Laboratory of Applied Physiology of the University of Cincinnati7 revealed another organic fluoride, dichlorotetrafluoroethane, whose toxicity also appeared to be of a very low order and whose physical-and chemical properties make it suitable for refrigeration purposes. In addition to low toxicity, safety in its use is further enhanced by its physical properties, which permit the design of equipment that operates at comparatively low pressures and hence mitigates the dangers and problems of leakage. The investigation described in this report was performed by the Bureau of Mines at the request and with the cooperation of the Frigidaire Corporation.

Jan 1, 1932

A general outline of the significant features in the quality and manufacture of the more common refractories is given. Where possible, linkage between quality development and control and service applicationhas been shown and explained. INTRODUCTIONThe refractory industry is no stranger to change. New processes and revision of old processes in other industries are the harbinger of new and revised products in refractories.Few of the changes are dramatic; generally they are evolutionary rather than revolutionary. New developments are additional to, and inclusive of, established practice.Therefore in this paper it is necessary to repeat much of what is already known in order to show the development taking place.FIRECLAY REFRACTORIESGeneral technology Fireclay refractories are the most common, the most varied and the most versatile of all refractories. Virtually any composition of silica and alumina up to the composition of kaolin is possible. For purposes of comparison they may be classified in the Continental fashion in accordance with chemical composition or in the American way according to "duty". That the two methods are equivalent is shown by an inspection of the alumina-silica diagram of Bbwen and Greig (1924). 'Fireclay refractories are composed of a glassy and a crystalline component derived from the chemical and physical nature of the raw materials used in their manufacture.

Jan 1, 1961

By N. Anacleto, S. Ganguly

Reduction of Groote Eylandt (Australia) and Wessels (South Africa) manganese ores using CH4-H2-Ar gas mixture was investigated in a fixed bed laboratory reactor in the temperature range 1000?1200oC. The extent and kinetics of manganese ore reduction as a function of gas composition and temperature were determined by on-line off-gas analysis using mass-spectrometer and dew point sensor. Morphology of ores and its change in the course of reduction was examined by optical and scanning electron microscopy. Phases of raw materials and reduced samples were analysed by XRD and EPMA. Manganese oxides were reduced to carbide Mn7C3. High extent and rate of reduction by methane-containing gas in comparison with carbothermal reduction were attributed to high carbon activity in the reducing gas, which was in the range 15 - 50 (relative to graphite). The reduction rate of Wessels manganese ore increased with increasing temperature. Reduction rate and extent of Groote Eylandt manganese ore achieved maximum at 1050oC. The decrease in rate and extent of reduction of Groote Eylandt ore at higher temperatures, particularly at 1150-1200oC, was due to sintering and formation of semi-liquid silicate slag. The optimum conditions for the reduction of manganese ores were established as follows: a) temperature: 1150-1200oC for Wessels and 1050-1100oC for Groote Eylandt ores, b) methane concentration: 10-15 vol%, c) hydrogen concentration: above 30 vol%, (d) size: 1-3 mm. An addition of lime (10-15 wt% CaO) to the Groote Eylandt manganese ore increased melting temperature of slag and significantly increased the rate and extent of reduction at elevated temperatures.

Jan 1, 2004

This report summarizes the results of several field tests conducted by Collins for the Bureau of Mines under contract S0122076 and contract H0232056. The field projects represent a part of Collins continuing effort on a broad study of coal mine communications. These experiments analyze the propagation characteristics of radio signals in a working coal mine environment. The intent of the program is to provide basic propagation loss characteristics by which we may evaluate various approaches to an integrated mine communications system. The goal of such a system is to satisfy both operational and emergency communications needs in the mine.

Jan 1, 1974

By A. I. Kogut

Impurity minerals in fluorspar ores and concentrates from a deposit in Southern Africa have been studied by reflected light, transmitted light, and cathodoluminescence microscopy. The principal impurities are quartz, calcite, aegirine, apatite, ankerite, magnetite, goethite, and synchysite [Ca(La,Ce,Nd)(CO3)2F]. Cathodoluminescence microscopy was found to be very useful in studying the character of the fluorite and especially for recognizing the presence of apatite and calcite impurities. Fluorite exhibits blue, calcite shows yellow, and apatite has white, light purple, and pink cathodoluminescence. The cathodoluminescent character of apatite varies with its geological environment and position in the orebody. The results of this microscopic study show that phosphorus present in fluorite concentrates occurs principally in binary locked apatite-fluorite particles. Successive fluorite cleaner concentrates contain progressively smaller amounts of locked apatite-fluorite particles. Free apatite has been effectively partitioned to the final tailings.

Jan 1, 1995

By B. Chareyre, H. Pourpak, L. Scholtès, E. Papachristos

"Numerical methods used to study hydraulic fracturing in low permeability rock masses need to take into account the interaction between the progressive failure mechanism of the intact rock matrix and the pre-existing natural fractures. A fully coupled hydro-mechanical 3D discrete elements model dealing with such interaction is presented here. The ultimate objective is to grasp the role of the rock-matrix failure on the propagation of the main fluid driven fracture under different stress fields and pre-existing fracture orientations. The proposed method provides the spatiotemporal distribution of the induced crack events which can be tracked during the simulations, making possible the identification of the local mechanisms leading to macro-failure in the rock matrix or reactivation of the discontinuity planes. Fluid flow inside a fracture, pressurized crack and hydro-fracking experimental tests were simulated as part of the validation process of the model and, are presented in this paper.INTRODUCTIONWith the expansion of shale gas and geothermal reservoirs exploitation, the technique of Hydraulic Fracturing (HF) has been widely used over the past years (McClure, 2012; Britt, 2012). Despite recent advances in micro-seismicity analysis or numerical modeling (Nagel et al., 2013), the way progressive failure of rocks affects the fluid flow depending on the in situ stress conditions or the rock heterogeneities is not fully controlled yet (Zoback, 2010).In this work we focused on setting up a three-dimensional discrete elements model to study fluid driven fractures propagation. The intact rock is modeled by a discrete element method (DEM) able to reproduce fracture initiation and propagation (Scholtès and Donzé, 2013, Garcia et al., 2013). The pre-existing fractures are explicitly modeled and can be individually defined or be part of a discrete fracture network (DFN) (Harthong et al., 2012). Their mechanical response is fully coupled with the fluid within a HM-DEM framework. The fluid flow and it’s interaction with the intact matrix and the pre-existing discontinuities is modeled through a Pore-scale Finite Volume (PFV) scheme specially enhanced for fractured rock modeling (Chareyre et al., 2012, Catalano et al., 2014) ."

Jan 1, 2015

By H. C. Cooke

Those who have followed the geological developments in connection with the copper deposits of Quebec will recall that on many properties the sulphide bodies occur as replacements of fault breccias or tuff breccias, and exhibit a pronounced distaste for the more massive lavas. At the same time the rocks around the ore-bodies are profundly altered, first by addition of silica and sericite, later by conversion of these minerals into chlorite. It has been known for some years that at the Amulet and Waite-Ackerman Montgomery mines these conditions do not prevail. At both mines the ore-bodies are replacements of massive lavas, and at the Amulet they are associated with a very peculiar rock christened ?spotted dog', or 'dalmatianite'. Accordingly, when in 1929 the writer had the opportunity to make a further examination of these properties, two problems presented themselves for solution. The first was to determine, if possible, the conditions under which massive lava, rather than breccia, is replaced by the sulphide masses; the second, to find out the exact nature of dalmatianite and its relations to the sulphide bodies. The first of these problems is believed to have been solved; the second has been found very complex, and will require further work before it is satisfactorily settled.

Jan 1, 1930

By Ari I. Kogut

Impurity minerals in fluorspar ores and concentrates from a deposit in Southern Africa have been studied by reflected light, transmitted light, and cathodoluminescence microscopy. The principal impurities are quartz, calcite, aegirine, apatite, ankerite, magnetite, goethite, and synchysite [Ca(La,Ce,Nd)(C03l2Fj. Cathodoluminescence microscopy was found to be very useful in studying the character of the fluorite and especially for recognizing the presence of apatite and calcite impurities. Fluorite exhibits blue, calcite shows yellow, and apatite has white, light purple, and pink cathodoluminescence. The cathodoluminescent character of apatite varies with its geological environment and position in the orebody. The results of this microscopic study show that phosphorus present in flUorite concentrates occurs principally in binary locked apatite-fluorite particles. Successive fluorite cleaner concentrates contain progressively smaller amounts of locked apatite-fluorite particles. Free apatite has been effectively partitioned to the final tailings.

Jan 1, 1995

By George Langford

Introduction The fiftieth anniversary is, for an individual or a society, an appropriate time for a review of the past so that events and experiences may be viewed m perspective, and thereby serve as a useful guide to the future. In this review of mining geology it is proposed to set forth the situation as it was when the Institute was founded, and then trace the developments during three appropriate periods-the first from 1898 to 1918 the second from 1919 to 1939 and the third from 1939 to 1948. Mining activities were widespread in Canada in 1898 and some of the operations were considered large for their day. The total value of the metals produced in that year was $21,705,854, and in the case of five metals the output had a value in excess of one million dollars. In order of importance these were gold, silver, copper, nickel, and lead. The important producing areas were ova Scotia, Quebec, Ontario British Columbia, and Yukon. This diversification of the mining areas and the metals produced created an interest in mining throughout Canada, and was an important factor in making Canadians conscious of their mining industry. In the year 1898 geology was a recognized science. The principles of physical geology were well known, but the same cannot be said of economic geology and structural geology. Ore deposits and their occurrence had been studied chiefly in Europe. A great many important observations had been made but the theories linking these facts together were still m a formative stage. The same condition was true of structural geology. These two branches of geological science which are so important in what is now called 'mining geology', had not progressed far enough to be of practical assistance mining operations. For this reason, geologists were regarded as dreamers in ivory towers-a concept chat still lingers in the minds of those who have not kept abreast of the growth of the science.

Jan 1, 1948

By I Gray

This paper examines the effects of the changes in stress that a coal may undergo as part of the drainage process. As a consequence of this, some coal seams will come to the situation that they have zero horizontal stress existing within them at the time of mining. The hypothesis of this paper is that this lack of horizontal confining stress means that on mining, the vertical stresses may be easily raised to a level where failure occurs. This failure may be accompanied by significant energy release from energy stored within the coal as well as that coming from the roof and floor. To determine the state of stress within the coal seam, the concept of the effective stress path that the coal passes through is examined and is found to be very dependent on the shrinkage of the coal with degassing, the Young’s modulus of the coal and its Poisson’s ratio. The Young’s modulus of the coal is important and has been found to be highly dependent on the state of stress within the coal. It may change by more than an order of magnitude.CITATION:Gray, I, 2014. The consequences for pillar stability of zero confining stress brought about by forced or natural drainage, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 331–336 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014