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By S Khosrowshahi, A Weeks, W J. Shaw

"To provide an indication of expected performance of the mine and mill, feasibility studies should include an assessment of the expected day-to-day variability in process plant feed. Attempts to do this based on conventional resource models will be flawed as such studies fail to consider and account for the in-built smoothing (averaging) of input data.This can lead to one of two situations: an expensive, over-engineered process plant that can cope with every possible situation, or operational strategies that fail to manage the natural variability within the orebody and the impact of day-to-day operational decision-making.In both cases the value of the project diminishes through excessive capital costs or reduced throughput or recovery during operations.Unlike conventional estimation techniques, the geostatistical method of conditional simulation can reproduce the inherent variability of the deposit. Once a valid model has been developed, it is possible to analyse the model using a transfer function that simulates the proposed mining processes and provides a representation of the likely variation of mill feed characteristics at any time scale.The case study demonstrates how the proposed mining strategy would result in mill feed being considerably more variable than expected, resulting in poor recovery, low throughput and potential breaches of environmental conditions. Mitigation measures included budgeting for additional mining equipment to enable greater flexibility during mining and revised stockpiling and crusher feed strategies.Awareness of the benefits of modelling the variability of geometallurgical parameters will increase the use of this approach in producing more realistic financial models of expected mine performance at the design stage.CITATION:Shaw, W J, Khosrowshahi, S and Weeks, A, 2013. Modelling geometallurgical variability - a case study in managing risk, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013, pp 247-252 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 29, 2013

By M. S. Hedley

"The Lucky Jim mine is at Zincton in Slocan mmmg division; on the Kaslo-Nakusp branch of the Canadian Pacific railway. It is owned and operated by Zincton Mines; Limited; a subsidiary of Sheep Creek Gold Mines; Limited. The mine is far in the lead in the production of zinc in the Slocan. Its recorded production from concentrates and shipping ore was 102; 260; 191 pounds of zinc to the end of 1945.GENERAL GEOLOGY With the exception of acidic dykes the rocks near the Lucky Jim mine belong to the Slocan series, which is Triassic in age and consists principally of argillaceous rocks. It disconformably overlies greenstones of the Triassic Kaslo series about 3 miles to the northeast, and is cut by granitic rocks of the Nelson batholith 5 miles to the southeast.The sedimentary rocks in this area are best referred to on the whole as slates. They lie within the more fissile basal part of the Slocan series. The term 'slate belt' conveniently distinguishes this area of rocks characterized by slaty cleavage from the more massive argillites that are more characteristic of the Slocan as a whole. The contact between the slaty and massive argillites lies ½ mile southwest of the mine."

Jan 1, 1954

By Michael Cruickshank

All life on Earth relies on the ocean and yet the ocean is 95 percent unexplored, unknown and unseen by human eyes,? said Paula Keener, director of education programs for National Oceanic and Atmospheric Administration?s (NOAA) Office of Ocean Exploration and Research. ?To better understand, manage and protect the ocean and its resources, NOAA believes it is critical to use the best technology to explore, discover, inform, educate and motivate? (MTS, newsletter, January 2011). In the last few decades, our understanding of the global mineral resource base has been drastically changed by some surprising new developments. The potential for commercial minerals per unit area in the oceans and seabed appears to be similar to that of the terrestrial lands. Thus, almost three-fourths of the global mineral resources are in, or under, the sea and are virtually undeveloped. The area of the Pacific seabeds alone is greater than the total area of the global lands. Half of the global seabed minerals are now controlled by nation states within their Exclusive Economic Zones (EEZ). The other half is controlled by the United Nations (UN) through the International Seabed Authority (ISA) within the ?areas beyond national jurisdiction? known as The Area. Thus, the Law of the Sea, ratified in 1994, has resulted in the largest transfer of control of natural resources in the history of mankind. This paper was prepared by the Society for Mining, Metallurgy and Exploration (SME) Committee on the Offshore Technology Conference for the SME Board of Directors and other interested parties. As the premier professional society for the mining and mineral community in the United States, with a history dating back to the 19th century, SME?s mission is to encourage and support young men and women engineers in the minerals industry, provide the services they need, improve the image of the industry, strengthen the networking among global industry professionals and engage in proactive collaboration among industry, government, academia and nongovernmental organizations (NGOs). The accomplishment of this mission can be strongly advanced by highlighting what is probably now the most significant development in the history of the modern minerals industry - the exploration of the marine environment and the understanding of the potential for the development of the minerals therein.

Jan 1, 2011

By E. F. Evoy

"The Gunnar uranium deposit was within metasedimentary rocks of the late Archaen Tazin Group. These rocks were intensely altered by albitization so that the immediate host to the ore consisted dominantly of albite, and by the subsequent introduction of calcite. The ore consisted of disseminated pitchblende and uranophane in a pipe-shaped breccia zone. Oxidation of the ore was more intense near surface than at depth, but there was no near-surface enrichment.IntroductionThe Gunnar Mine site is on the tip of Crackingstone Peninsula, on the north shore of Lake Athabasca, Province of Saskatchewan, Canada. The peninsula forms the southern part of the Beaverlodge mining area. The ore consisted of disseminated pitchblende and uranophane in brecciated metasedimentary rocks of the Tazin Group, and the deposit was characterized by extreme albitization and subsequent carbonatization of the host environment.Production from the mine began in 1954 and the ore was depleted by 1963. In that interval the deposit yielded about 5 million tonnes of ore containing about I. 75 kg/tonne U3O8. It was mined initially from an open-pit and subsequently from underground; the open-pit contributed about 55% of total tonnage. Uranium was recovered by atmospheric leaching in sulphuric acid, ion exchange concentration, and precipitation with magnesia.This paper is based on studies made during the productive life of the mine and is concerned primarily with pre-ore alteration of the rocks containing the deposit, and with the ore mineralogy."

Jan 1, 1986

By P A. Grossman, J H. Rubinstein, M Brazil

The installation of truck turntables at above-ground crushers has the potential to yield gains in efficiency and productivity by eliminating the need for the trucks to turn around and reverse up to the crusher to dump their loads. The benefits include savings in time, fuel consumption and tyre wear. In addition, having a smaller area near the crushers dedicated to manoeuvring the trucks can be a significant benefit at some sites. Safety is also enhanced using turntables.This paper describes a project with the Australian Turntable Company to develop software that generates near-optimal layouts for the paths taken by the trucks in the vicinity of the crushers when turntables are present or absent. The geometry of the paths is constrained by the turning radius of the trucks and by the boundary of the manoeuvring area. The software quantifies the benefit of installing turntables by generating a design for paths with turntables and comparing it with the layout in current or planned use by the mining company. Through the use of this software tool, a mining company can readily assess the benefits of using turntables at their site.CITATION:Brazil, M, Grossman, P A, Rubinstein, J H and Thomas, D A, 2014. Demonstrating efficiency gains from installing truck turntables at crushers, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 259–266 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By J. Grant Spratt

THE Turner Valley gas-field, situated some thirty miles southwest of Calgary, Alberta, has been the topic of much discussion, particularly from a geological viewpoint. Several papers (1, 2, 3, 4, and 7) dealing with the structural and stratigraphical geology have already been published and are available for reference(l). In this article, the geological conditions will be treated only as they directly refer to the crude-oil prospects along the west flank of the anticline. HISTORY During the past twelve years, Turner Valley has been known mainly as a field which has produced a high-gravity naphtha from relatively large quantities of gas. For about ten years prior to the discovery of this naphtha-bearing gas, which is produced within the upper 450 feet of a dolomitic limestone of Carboniferous age, a minor production of light crude-oil was obtained from overlying sands of Cretaceous age. Up to June 1st of the present year, the field had produced 9,473,582 barrels of naphtha from approximately 829,000,000 M.c.f. of gas. For the past four years, the total daily production of 80 to 90 wells has averaged about 3,200 barrels of naphtha from 250,000 M.c.f. of gas. This is an average of 13 barrels per million cubic feet. The naphtha is extracted from the gas by ordinary gas-oil separators and absorption plants. After the naphtha has been recovered, about ten per cent of the gas is marketed for fuel to supply the cities of Calgary and lethbridge and intermediate cowns. The remaining ninety per cent is burned to the atmosphere, with the exception of some four to five million cubic feet per day which the Calgary Gas Company score in the depleted Bow Island gas-field.

Jan 1, 1936

By I. C. Christopher

Introduction The geology of the Cochen-our Willans gold mine has been described in reports by the late Dr. H. C. Horwood (1) in 1940 and by Dr. J. P. Nowlan (2) in 1947. Information from these and other (unpublished) reports has been incorporated in the present paper, together with some recent ideas regarding structural features which are at present being used to locate ore shoots. Location and History The mining claims of Cochenour Willans Gold Mines, Limited, occupy 705 acres in Dome township, on the east shore of Red lake opposite McKenzie island. Adjoining properties are those of McKenzie Red Lake Gold Mines on the west, Boymar Gold Mines on the north, Marcus Gold Mines on the east, and Martin-McNeely Gold Mines on the south. The claims of the original group were staked by W. M. Cochenour, Dan Willans, and H. G. Young, and the Cochenour Willans Syndicate was formed in 1928. Work was carried out by the Syndicate and several other companies during the next eight years with inconclusive results, due to the irregular occurrence of the ore. In 1936, Cochenour Willans Gold Mines, Limited, was incorporated and production was finally started late in 1939.

Jan 1, 1951

By M J. Nugus, J G. McLellan, T G. Blenkinsop

High fluid pressures and deformation have been instrumental in the formation of high-grade gold lodes at the Archaean granite greenstone 12 Moz Sunrise Dam gold deposit in Western Australia. Historically, predicting the location of these lodes has been difficult due to the irregular nature and high-grade nugget characteristics of the deposit. Recent exploration successes and the discovery of the Vogue system have led to an improved knowledge of the deep extents of the mine. This new structural and gold distribution data has enabled a new 3D interpretation of the system and has provided a better insight into the links between deformation, fluid pressure evolution and gold deposition. Here we employ 3D geomechanical and coupled fluid flow modelling to better constrain areas of high strain partitioning, rheological failure and focused fluid flow, which provides a substantially increased predictive capacity for further within-mine exploration. The localisation of deformation in and around the main felsic porphyry and major shallow shear zones provides critical insights into fluid pathways that have contributed to the distribution of fracture networks and ultimately gold deposition during late stage deformation events. Understanding the relationship between deformation events, fluid pressure evolution and the partitioning of strain is paramount in understanding the distribution of gold and for focusing on future target areas.CITATION:McLellan, J G, Blenkinsop, T G and Nugus, M J, 2013. Fluid pressure, geomechanical evolution and predictive targeting of the Sunrise Dam gold deposit, Western Australia, in Proceedings World Gold 2013 , pp 419-426 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Sathit Tandanand

Horizontal displacements and ground strains induced by mine subsidence are significant information needed for calculating damage and developing precautions against subsidence effects on surface structures. To devise a simple method for determining the surface horizonal displacements and strains simultaneously with the subsidence prediction, the U.S. Bureau of Mines examined the significance of the tilt number, which is the proportionality constant in the relationship between the horizontal displacement and the slope of the subsidence profile. The ratio of the tilt number to the critical radius of the subsidence trough is identical to the ratio of the maximum possible horizontal displacement to the full subsidence, which is found to be constant in most European coalfields. If this ratio is known for a particular minesite in the United States, then horizontal displacement and ground strains can be readily obtained from the primary subsidence data.

Jan 1, 2010

By Patricia Curtis Petty

Thirty years ago, the appearance of a female mining engineer, geologist or miner in a company, union or mine environment would have been unthought of, unwelcomed and violently opposed. Twenty years ago, the intellectual perception of the news that women were interested in becoming mining engineers, geologists and miners had been accepted by the industry-but no one wanted to be the first to hire one of these exotic creatures. Ten years ago, those who had been most vehemently opposed to the philosophical idea of women working in these areas were faced with competent, productive engineers, geologists and miners-who only incidentally happened to be women-and began hiring them. Historically, of course, one can always find the isolated individual who worked in these areas-the first female graduate of the Colorado School of Mines with a mining engineering degree graduated in 1903-but the concept of woman as professional engineer was very slow in arriving in the United States. The few who worked as miners generally worked in small family enterprises, such as some of the coal mines in both Eastern and Western United States. Others accompanied husbands or sons into wilderness areas searching for gold and other precious metals.

Jan 1, 1984

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By M. I. Dobrynina

At the beginning of the 80-s the first diamond pipe in the East-European platform was discovered in the North of the Russian Federation on the White Sea Winter coast. During several years while studying this unique area data on kimberlites and country rocks petrophysical characteristics have been collected. Considerable experience in geophysical methods when searching and exploring diamonds was accumulated, and various methods of geophysical data interpretation were used. It has been established from the analysis of geophysical data that diamond-bearing kimberlites are located in the most ancient and the most stable block of the East-European craton.

Jan 1, 1995

By I. B. Tulu, M. M. Sears

"In 2015, 40 longwall mines provided nearly 60% of the US coal production from underground mining methods. This represents a substantial, yet gradual increase from just under 50% over the last 5 years. As a result of this increased production share, the percentage of ground fall related fatalities in longwall mines has also increased when compared to all US underground coal mines. Additionally, about 80% of ground fall related fatalities have occurred in areas where the roof was supported. In an attempt to better understand the status quo of current US longwall support practices, a sample of 21 longwall mines were visited, representing about 40% of the currently active longwall mines in 4 of the 5 major US longwall producing regions. The resulting data was obtained from a wide variety of overburden depths, geologic conditions, mining heights, ground conditions, support practices, and gateroad configurations. The data collected is reported using both qualitative and quantitative methods. The results from the research update previous efforts in classifying mining accidents and injuries as well as current support practices. This data provides a necessary background for future research aimed at further reduction of ground fall accidents and injuries. INTRODUCTION Maintaining ground stability in gateroad entries is essential for longwall productivity and safety (Campoli, 2015). In 2015, 148 unintentional roof falls were reported in US longwall mines. About 34% of these resulted in mineworker injuries. Safety considerations not only include injury from roof and rib falls but also egress from the longwall face during an emergency (Mucho et al., 1999). Over the past 30 years, a number of researchers have studied longwall tailgate support performance (Mirabile, 2015). This research aims to take a snapshot of the ground support installed in modern US longwall mines and provide a supplement and update to the overview provided by Barczak (2005). This will provide a framework for future research into improving gateroad support systems. BACKGROUND Large unplanned roof falls at or above the primary support or those impeding travel and/or ventilation must be reported to the Mine Safety and Health Administration (MSHA). Reportable roof falls, normalized based on production in million metric tons, generally relate to the amount of roof exposed during the mining process (Pappas and Mark, 2012) and provide an evidence-based statistical background for this review of current support practices. Figure 1 shows the reportable roof fall rate in US underground longwall mines for the period 2006-2015 (MSHA, 2016). Over the past decade, roof fall rates have shown a gradual decrease with numbers now at a rate nearly half of what was observed just five years ago. However, over the past few years, roof fall rates in US longwall mines appear to have stagnated at levels just over 1 per 2,000,000 tonnes mined."

Jan 1, 2017

By G. G. Manekar

MOIL Limited (formerly Manganese Ore India Limited), a Government Enterprise, under the Ministry of Steel, Government of India, produces about 1.1 million tonnes (T) of manganese ore annually from three opencast and seven underground mines. The underground operations are mining using an overhand cut and fill method. The orebody is too narrow for the use of larger equipment and the poor to fair rock mass quality limits the size of stable excavations. Prior to the 1990s underground support consisted primarily of timber square sets in tandem with timber chocks and props. As mine production requirements increased throughout the 1990s led to larger opening sizes and more modern support practices. Research was conducted on ground support design based on rock classification and empirical techniques for designing ground support. Based on the findings and field trials, the Company adopted full column cement grouted cable bolts for back support. Instrumented field trials, using extensometers and load cells on the cable support confirmed the support effectiveness. Stope design was based on two and three dimensional stress modeling which resulted in a significant increase in stope dimensions. The rock mechanics studies for safe stope design were carried out using numerical modeling tool in two and three dimensions for the analysis of stresses. Based on the findings, the safe stope geometry with new stoping parameters was introduced. The earlier stope length of 30 mtrs were changed to 60 mtrs with in situ rib pillar at the cross cuts and in situ post pillars to be left-out in the stope. This leads the formation of of panel comprising of three stopes, for production, supporting and filling. For mechanical handling of ROM in stopes Side Discharge Loaders (SDL) were introduced. The above changes have improved the face productivity from 2?3.5 T with manual operation and 9 T with SDL. The above rapid mining operations has improved the stope productivity but reduced the stope life from 6 to 3 years. For the improvement of the stope availability, further studies were conducted by numerical modeling of stress analysis. The related studies confirmed that with the existing supporting system and proper instrumentation, level interval could be increased up to 45 mtrs from the existing 30 mtrs at deeper levels. At present below 12th Level interval is 45 m at Balaghat Mine. For future mechanization program for introduction of Single Boomers, LPDT, Cutting Machines etc for the development headings rock mechanics studies are underway. The paper provides details of rock mechanics studies that were carried out to study efficacy of the cable bolt support, safe stoping parameters and increased level interval for the improvements in safety, production and productivity at Balaghat Mine.

Aug 1, 2013

By Heinz W. Sternberg

The literature on electrochemical treatment of coal is reviewed, and possible avenues of further research in this field are discussed in this report. Electrolytic reduction of finely distributed coal resulted in the addition of as many as 9 atoms of hydrogen to 100 atoms of carbon. Reduction of coal extracts at controlled potentials indicated the presence of condensed aromatic hydrocarbons and reducible quinones in coal. As much as 65 percent of low-rank coal can be made alkali soluble by electrochemical treatment. Higher rank coals gave smaller yields of alkali-soluble products. However, the nature of this reaction is not clear. The difficulty of reducing coal electrolytically is probably due to the insolubility of coal and not to any structural peculiarity. Reduction of coal by electrolytically generated radical anions appears to be a promising approach for further research.

Jan 1, 1962

By R. C. McMurchy

"The Powell mine is in western Quebec about 2 miles northwest of the adjoining towns of Noranda and Rouyn. It is the original discovery of the area, its gold-bearing quartz vein having been discovered in 1922. Considerable work was done on this vein by several companies and discontinued because the grade, when gold was $20 an ounce, was too low for profitable extraction. Between 1922 and 1924 an inclined shaft was sunk to 225 feet and drifts were driven 240 feet on the 100-foot level.In 1929, due to the discovery and development of the Horne mine at Noranda, interest was revived in the property. Sulphide deposits of the disseminated and vein types were explored on the Powell claims. On the B copper 'showing', a vertical shaft, now known as the 'old copper shaft', was sunk to ·a depth of 167 feet and 300 feet of lateral work was carried out on the 150-foot level. As no orebody was discovered this work was discontinued.In 1933 the present company, Powell Rouyn Gold Mines, Limited, was formed and the gold-bearing quartz veins were again tested by drilling and trenching. In 1936, the price of gold having risen to $35 an ounce, operations were resumed. Since then the inclined shaft (No. 1) has been deepened to 500 feet, a second shaft (No. 2, vertical) on the main quartz vein has been sunk to 2,630 feet, and ll; shallow vertical shaft (No. 3) on the same vein but in the south claim has been sunk to 500 feet.Lateral work now approximates 9 miles, and to November 15th, 1946, 1,685,674 tons of ore, which averaged 0.129 oz. gold per ton and 73.6 per cent. Si02, had been extracted."

Jan 1, 1954

By C. McAllister, D. Preece, J. Berendzen

"The Multiple Blasthole Fragmentation (MBF) model models multiple explosive charge contributions and the effect on fragmentation of delay timing with its associated scatter for each blasthole. The model uses near-field blast vibration attenuation parameters and the ground p-wave velocity as inputs for part of the in situ rock property to model rock fragmentation. It models most blast design parameters explicitly and simulates the effect of wave reinforcement due to the interaction of simultaneously arriving waves or diminishing cooperative contribution from long delay intervals between charges within a blasthole or among blastholes. The fragmentation size is calculated at three-dimensional grid points within a blast, and the fines and oversized blocks are treated explicitly. The model takes a surveyed irregular geometry of the free face of a blast as the calculation boundary.This paper presents a case study on applying the MBF model at an openpit mine. Near-field vibration measurements from signature hole blasts were conducted to obtain the stress-wave magnitude and attenuation parameters as well as ground sonic velocity. A production blast was then monitored with the corresponding fragmentation measured, serving as site-specific inputs to the MBF model. Various blast design scenarios were then simulated to develop ones that provide better fragmentation to improve mill throughput for the mine. IntroductionThe semiempirical fragmentation models currently found in the literature (Cunningham, 1987; Lownds, 1995) cannot explicitly model contributions from multiple blastholes with varying delay intervals. Most of these models are not three-dimensional. Furthermore, these models predict an average fragmentation size within a volume surrounding a blasthole and use the average size to generate a size distribution over the volume. The percentage of fines and oversize blocks is included in the distribution. Typically, such models are inadequate for predicting fines and oversize blocks (Cunningham, 1987)."

Oct 1, 2016

By Graham J. C. Carpenter, Marc Charest, Jason Lo

"The method of producing magnesium-based composites with silicon carbide (SiC) particulates embedded in the matrix of magnesium AZ9I D alloy by the squeeze-casting technique are described. This method involves the fabrication of a SiC particulate preform and the subsequent squeezing of molten magnesium into the preform. In this study, alumina, aluminum phosphate and a proprietary binder were used for the fabrication of SiC particulate preforms. The procedures employed in the fabrication of SiC! AZ9ID composites are presented, together with the results of characterization of the composites using optical and transmission electron microscopy. Special attention is given to the reaction products in the bulk alloy and at the interfaces between SiC particles and the AZ9ID matrix alloy.1. IntroductionInterfacial, microstructural and metallurgical characteristics play an important role in determining the mechanical properties of a composite. In theory, reinforcing magnesium with SiC particulates should provide an improvement in strength and modulus of the composite over the unreinforced counterpart. However, many factors resulting from the fabrication process can cause degradation rather than improvements to the mechanical properties. In particular, the interfacial characteristics are known to critically influence the properties of composites [1]. Before evaluating the mechanical properties of a composite, it is always useful to examine the microstructure, which is closely related to the mechanical behavior. This helps to reduce the labor-intensive steps of sample preparation for mechanical property evaluation, which can be particularly difficult as a result of the high hardness of composite materials, as well as providing a wealth of information on the microstructural and interfacial characteristics, particularly the reaction products caused by processing. This information is also pertinent in understanding the factors governing the mechanical properties of the composites.There are many factors which determine the nature of the interfacial characteristics of a SiClMg composites. Qualitative estimations of the interfacial bonding have been performed based on thermodynamics, electronic and electrostatic concepts. In addition, the kinetic conditions during the fabrication play an important role. From an interfacial energy standpoint, the driving force for the formation of a metal/ceramic interface is the decrease in free energy that occurs when intimate contact is established between metal and ceramic surfaces. The simple representation of the energy change per unit area of interface formed (~G) is given by Dupre equation [2]:"

Jan 1, 1996

By Cheryl Hill, Michael Keane, Pamela Mike, Raghoottma Pandurangi, William Wallace, Mohindar Seebra, Val Vallyathan

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte bemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz and kaolin dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect of lecithin adsorption. Dust hemolytic potential versus medium pH is presented. Fourier transform infrared spectroscopy and photo-acoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis. INTRODUCTIONQuartz dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction.In the alveolar ·spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, among other functions, mechanically stabilizes the lung from collapse by reducing the surface tension of water in the alveolar sacs.1 This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11 % in dog lavage fluid), and phospholipids (about 88%).2 Pbosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalmitoyl lecithin (DPL).2 Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occurring upon deposition of a particle in a pulmonary alveolus. As may be seen from Figure 1, the DPL molecule has several fixed charges at neutral pH; a positive charge on the trimethylamine (choline) moiety, and a negative charge on the phosphate group. Also evident are the two fatty acid residues of palmitic acid, which are bonded through ester likages to the glycerol segment of the molecule. The fatty acid moieties of phosphatidyl choline make the molecule inso1uble in aqueous solutions under normal conditions, but a colloidal unit of aggregated molecules called a micelle is usually formed spontaneously above a certain minimum concentration. Small micellar vesicles are generally formed in the laboratory by using ultrasonic agitation or by solvent evaporation methods."

Jan 1, 1990

Spiral concentrators are compact, cost-effective and generally efficient gravity concentration separators for a wide range of applications (for example: coal, beach sands, iron ore, chromite and tantalite). Large mineral processing plants consist of thousands of spiral concentrators resulting in large plant footprints (capital intensive) and the adjustment of splitters is time consuming, impractical and is in many cases neglected?high capacity (HC) spiral concentrators aim to address these shortcomings. As a result Exxaro Namakwa Sands is currently investigating high capacity spiral technology for the spiral circuit upgrade at the primary concentrator plants (PCPs). This article summarizes the rougher spiral performance evaluation that was conducted on different types of spiral concentrators (the traditional MG4 spiral concentrator and the high capacity (HC) spiral concentrator) under different feed conditions. In addition, the effect of slimes on the spiral concentrator performance was also investigated. Slimes rheology was linked to the poor concentrator performance at the higher slimes concentrations. The test campaign shows a sacrifice in recovery under design-feed conditions can be expected when using high capacity spiral concentrators in the rougher stage when compared to traditional spiral technology currently in use. Both spiral concentrators show a detrimental impact of slimes on the performance, but the high capacity spiral concentrator is more sensitive to the higher slimes conditions.

Jan 1, 2010