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By R. B. Gavert, David J. Mack

ROOM- and elevated-temperature compression tests were made on the binary 3/2 electron compounds AuZn, CuAu, AgZn, AgMg, AuCd, and NiA1. These compounds possess either the B2 CsC1-type ordered structure or the A2 bee disordered structure represented commonly as ß and ß on equilibrium phase diagrams. In testing at room temperature, cylindrical specimens 0.508 cm by 0.330 cm diam were seated directly on an instron compression load cell (CF 0 to 10,000 lb). At elevated temperatures, testing included a special apparatus with a furnace heat source and a protective atmosphere.' The specimens were strained at a rate of 1 pet per min. The compounds were prepared from 99.99 pet or better high-purity elements. Vacuum and/or argon cover gas was used throughout the mixing, melting, and specimen drawing processes. The generally equi-axed specimen grains varied in size from 0.5 to 1.5 mm for the five different compounds. The stress-strain curves in compression showed

Jan 1, 1968

By J A. Shonhardt, I Porter

All types of coal are liable to spontaneous combustion to a variable degree according to the inherent characteristics of the coal and also extrinsic factors. In order to successfully extract coal from highly capital-intensive longwall mining operations it is necessary to evaluate and manage any risks that may be present due to spontaneous combustion. A spontaneous combustion risk management plan for longwall mining is described in this paper. This risk management system comprises identification of conditions promoting spontaneous combustion risk, a laboratory or empirical risk classification system, determination of gas ladder, adoption of adequate ventilation plans and gas monitoring systems that will lead to the development of the spontaneous combustion action plan. The risk management system was applied to a greenfield site in NSW in 1992 when prediction of a high-risk category for the coal seam was made. After commencement of production a spontaneous heating problem emerged as predicted. Description of the case history of spontaneous combustion risk management for a longwall operation in this coal seam is included in this paper.

Jan 1, 2003

By Cyril Stanley Smith

BeTa brass (consisting of approximately equal atomic proportions of copper and zinc) exists as a random solid solution at high temperatures, hut at low temperature< an ordered structure is stable, with the copper and zinc atoms occupying alternate sites on the body-centered-cubic lattice. On cooling, ordering commences at a temperature of 450° to 470°C., depending on the composition. The degree of ordering progressively increases at lower temperatures until it becomes virtually complete at about 100°C. The electrical resistivity of the alloy illustrates the changes clearly (Fig. I). This type of reaction has been a favored subject for study by physicists. An excellent summary of the theory is to be found in a paper by F. C. Nix and W. Shock1ey.l All published data on electrical conductivity, specific heat and other properties agree in indicating that the ordering reaction in beta brass takes place so rapidly that it cannot be prevented or even retarded by quenching&apos; With most ordered alloys, cold-working induces disorder and

Jan 1, 1943

By Cyril Stanley Smith

BeTa brass (consisting of approximately equal atomic proportions of copper and zinc) exists as a random solid solution at high temperatures, hut at low temperature< an ordered structure is stable, with the copper and zinc atoms occupying alternate sites on the body-centered-cubic lattice. On cooling, ordering commences at a temperature of 450° to 470°C., depending on the composition. The degree of ordering progressively increases at lower temperatures until it becomes virtually complete at about 100°C. The electrical resistivity of the alloy illustrates the changes clearly (Fig. I). This type of reaction has been a favored subject for study by physicists. An excellent summary of the theory is to be found in a paper by F. C. Nix and W. Shock1ey.l All published data on electrical conductivity, specific heat and other properties agree in indicating that the ordering reaction in beta brass takes place so rapidly that it cannot be prevented or even retarded by quenching&apos; With most ordered alloys, cold-working induces disorder and

Jan 1, 1943

By Roberto Parra

The wear and corrosion phenomena in the furnace lining of the ferrous and non ferrous pyrometallurgical processes are complex problems where chemical, interfacial and mechanical phenomena are presents. The characteristics of the processes determine the conditions to which these materials are submitted, where the thermal conditions reached during the operation is one of the most important parameter. Assuming that all the degradation phenomena are thermal activated, the rate of the different steps of the wear mechanism will depend on the thermal field in the lining. In view to apply the independent physicochemical knowledge of degradation mechanisms to the analysis and design of furnace lining the methodology of the Nodal Wear Model (NWM) was done. It combines the mathematical modelling of the heat transfer in the lining with the physicochemical control equation for the wear-corrosion phenomena. The NWM has been applied to different examples: theoretical analysis, laboratory scale test and industrial applications. We present in this paper the theoretical background of the model and two examples of applications: the sole of an electric furnace and the earth of a blast furnace.

Jan 1, 2006

The increasing need for robust pyrometallurgical furnace construction is driven by two trends in the copper and other base metals smelting industry: ? the desire for increased production within a single furnace line by greatly increasing smelting intensities, which generates high heat fluxes to the crucible. walls, and ? the operational and economic imperatives of maintaining high percentage on- line times and long campaign lives between rebuilds. A key feature of furnaces capable of producing at high rates, while containing intense processes, is a strong, thermally robust wall cooling system. Equally important design aspects include the furnace steel structure, refractories, a cooling water supply and piping arrangment for safety from leaks and disruptions, and instrumentation/controls for monitoring and rapid mitigation of process excursions. Integration of the cooling elements into these furnace systems is essential for optimum performance of the cooling elements, and indeed the entire furnace. This paper discusses the development of a composite copper / refractory water- cooled design, which has been successfully implemented on several copper smelting and converting furnaces, including Kennecott&apos;s flash converting furnace, INCO&apos;s MK reactor, and Kidd Creek&apos;s converting furnace.

Jan 1, 1999

By J. M. Lohr

THE characteristics and uses of thermocouples of platinum and the platinum alloys being so well known, this paper will be confined to base-metal couples. During the past decade, there has developed a strong demand for thermocouples made of metals cheaper than the platinum alloys, and suitable for industrial heat measurements. Much research has been clone but only a very limited number of alloys have been found to possess the necessary characteristics for general technical use. In the development of thermocouple alloys it is necessary to consider the following points: The electromotive force and temperature relations; permanency or constancy; reproducibility; manufacturing difficulties; durability; and accuracy in use. The electromotive force developed by the thermocouple should increase with the rise of temperature according to some definite law. It is desirable that the electromotive force should vary directly with the temperature difference of its junctions, in other words, giving a curve linear or nearly so. It is also desirable that the resulting electromotive force be as large as possible for any given range of temperature, thereby insuring greater accuracy of readings.

Jan 9, 1919

By P. Barrios

Over a period of one year, an in-depth investigation was carried out in a conventional copper refinery to understand the behaviour of silver in copper electrolysis. The increase in silver content in the cathodes increases almost linearly with the duration of electrolysis, and the silver content of the electrolyte between the electrodes shows similar behaviour. The silver content of the cathode deposited daily depends directly on the silver concentration of the electrolyte and this, in turn, is strongly influenced by its internal temperature. The average temperature between the electrodes rises from the first to the second and to the third crop, because of the increase in the distance between the electrodes and the heat generated by the passage of the current. The mechanism of dissolution of silver from the anode, and its passage to the cathode, are discussed. Following the change to the Isa system, it was proved that the results and conclusions are analogous. Based on these results, a reduction of more than 20% in silver losses in the cathodes was achieved.

Jan 1, 1999

By D. C. Wilder

Deformations during heating and cooling of three drifts in granitic rock were influenced by the presence of faults and shear zones. Thermal deformations were significantly larger in sheared and faulted zones than where the rock was jointed. but neither sheared nor faulted. Furthermore. thermal deformations in faulted or sheared rock were not significantly recovered during subsequent cooling thus a permament deformation remained. This inelastic response is in contrast with elastic behavior identified in unfaulted and unsheared rock segments. A companion paper (Butkovich and Patrick, 1986a) indicates that deformations in un- sheared or unfaulted rock were effectively modeled as an elastic response. We conclude that permanent deformations occurred in fractures with crushed minerals and fracture filling or gouge materials. Potential mechanisms for this permanent deformation are asperity re-adjustments during thermal deformations. micro-shearing, asperity crushing and crushing of the secondary fracture filling minerals. Additionally, modulus differences in sheared or faulted rock as compared to more intact rock would result in greater deformations in response to the same thermal loads.

Jan 1, 1986

The price of copper has gone into the tank. So has gold. Environmental regulations are more restrictive. Global warming has world leaders and environmental groups seeking international regulations to keep the planet from heating up - mostly by restricting the use of fossil fuels. And the US Secretary of the Interior wants to make it more costly -prohibitively so for smaller companies - to mine hard rock metals in the United States. By rights, miners should be carrying around a pessimistic attitude about their industry. But miners are an optimistic lot, always believing that things will improve. That optimism was in evidence in Tucson, AZ in early December, when about 620 miners met at the Double- tree Hotel for the Annual Meeting of the Arizona Conference, put on by SME. Attendees listened as a United States congressman commented on the recent tax cut bill, mining regulations and the continuing need for the mining industry to improve its image in the eyes of the general public. Session speakers discussed how improved technology has made their processing operations at Sierrita and Morenci more efficient and cost-effective.

Jan 1, 1998

By Francis B. Foley

THE casting of steel in large molds brings into play all of the undesirable effects that result inevitably from slow cooling. The origin of the molten metal, whether basic or acid open hearth or electric furnace, has little if anything to do with the phenomena involved. If the quantity of molten metal to be cast in a single mold is large enough, there is very little one can do about it-the metal will cool so slowly that &apos;nothing one can do, other than to provide as good feeding as practicable from an adequate reservoir of metal in the sink head, will be of any avail. Recently we have had occasion to cast a 108-in. octagon ingot weighing 545,700 lb, necessitating the combining of metal from three 100-ton open-hearth heats. This is one of the largest ingots ever made. The body of the ingot weighed 448,800 lb, which includes a bottom pool of about 7500 lb of metal, and the sink-head weight was 96,900 lb, or about 18 pct of the total weight.

Jan 1, 1947

By W. H. McCormick, H. J. Benecki

CONSIDERING that a typical modern drilling machine strikes approximately 2000 blows per min and may develop a force of 30 to 200 ft-lb, de- pending upon size of the drill used, the importance of uniform stress distribution in this type of drilling becomes obvious. If the rod were perfectly symmetrical, and if it did not rotate, the problem would be relatively simple, however, the necessary forging, machining and heat treating operations prevent attaining this state of perfection. Take the modern hollow drill rod. The blow is transmitted not from the striking end of the rod directly through to the point of impact of the bit in the rock, but rather through a somewhat complex tool. To add further problems, this entire assembly is rotated immediately after the impacting blow. Rather than attempt to discuss the magnitude and distribution of stresses, it is desired to present a few things that will minimize unusual stress concentration and produce a rod in which the stress distribution will approach the theoretical ideal.

Jan 3, 1954

By E. Kokinou

The main scope of the present study is to investigate the suitability and sensitivity of the magnetic susceptibility as a pollution monitoring tool in urban areas. For this purpose, a municipal park located in the centre of Chania city, which may be affected by traffic and domestic heating pollution, was selected as the study area. In the context of the present work, magnetic susceptibility measurements were conducted in two phases. Surface soil samples were collected in 2006 from the area under investigation and they were analyzed in order to estimate the spatial distribution of the magnetic susceptibility. One year later, mapping of the magnetic susceptibility has been contacted in situ using Bartington MS2D and MS2F sensors. Additionally, soil samples were collected from selected positions in order to compare the values of the magnetic susceptibility with that estimated in 2006 research. Both investigations indicate high values of the magnetic susceptibility around the park near the roads and in a small area inside the park where a café is located.

Jan 1, 2008

F. W. Gordon, Philadelphia, Pa.: There can be no objection to the use of cross-compound blowing-engines; and when they are condensing they are susceptible of great range of duty with slight loss in efficiency. By those who have use for the full heat of the waste gases, this type of engine is advantageous; but many furnaces are not so located. The pig-iron is their finished product, and the gases are to be employed only for furnace-use. In this case simple engines are preferable, being less expensive and having less parts to take care of. These reasons determined the introduction of the engines, a sketch of which is distributed at this session. There are three of these engines to furnish blast for two furnaces, for a make of abont 250 tons per day, using 75 per cent. anthracite and 85 per cent. magnetic ores; and they are expected to blow up to twenty pounds pressure per square inch. For blast-furnaces I prefer the single to the coupled engine, except

Jan 1, 1894

By D. J. Dunn, J. L. Huiatt, T. E. Norman

Corrosion studies in laboratory ball mills and grinding environment simulations produce corrision rates and total metal removal rates much lower than those recorded in operating production ball mills. The corrosion component of ball metal loss in many mills probably represents less than 10% of the total loss, judging from AMAX experience and recent US Bureau of Mines (USBM) tests. Such small absolute losses are consistent with ball metal loss measured in production ball mill marked ball wear tests to determine effects of corrosion and abrasion resisting properties of alloys in operating mills. These indicate that metal hardness and microstructure determine relative metal loss rates of a given situation. The combination of ore characteristics and grinding process dynamics determine metal loss severity. Alloying for corrosion resistance and modification of the milling corrosion environment yield relatively small metal loss reductions. Alloying and heat treatment to produce high hardness and microstructures of high carbon martensite and, for cast irons M7C3 carbides, produces the lowest metal losses in typical wet grinding applications.

Jan 1, 1986

By M. J. Pool, R. K. Saxer, J. R. Myers, D. S. Dickson

ThE equilibrium phase diagram of the Mo-Cr system, described by anssen,&apos; indicates that chromium and molybdenum form a continuous series of solid solutions above 1673K. The liquidus and solidus have been reported to have a minimum at about 12 at. pct Mo and 2133°K by Bloom and Grant2 and by Putnam, Potter, and Grant.3 X-ray studies by Trzebiatowski and ploszek4 and Baen and Duwez&apos; revealed no indication of solid solution decomposition after long anneals at 1473", 1273", 923", and 873°K. However, Bloom and rant&apos; by means of cooling and heating curve analysis of alloys containing up to 45 at. pct Mo found thermal effects at temperatures approximately 100" * 30°K below the liquidus. The only previous thermodynamic study of the Cr-Mo alloy system was made by Laffitte and Kuba-schewski6 who used the Knudsen effusion method at 1471°K. These investigators reported the possibility of a miscibility gap because they observed positive deviations from ideality in their chemical activity

Jan 1, 1970

By Raja V. Ramani, Ralph W. Barbaro

This paper presents an application of a Mixed Integer Programming (MIP) model to the problem of locating a centralized coal preparation plant and determining the production schedule for the mines. The system used for illustrating model application is hypothetical but realistic. It consists of three mines, two potential preparation plant sites, heavy media processing plant, and one market. The goal is to maximize the total profit of the system while satisfying the coal delivery schedule over a three year period meeting both quantity and quality requirements (ash, sulfur, and heat content). In addition to the base case, four different scenarios are analyzed. These four modifications are: (1) removing the flotation circuit from the preparation plant and sending all of the fines directly to the clean coal, (2) lowering the quality of coal from one of the mines, (3) applying discounts to the unselected site to improve its competitive position, and (4) adding a new mine. A detailed discussion of the base case and the effect of these four alternatives is presented.

Jan 1, 1983

By V. J. Decarlo, J. J. Gilman

POLISHING pure zinc differs somewhat from polishing less reactive metals. The problem is not that of finding a suitable reagent, but rather of producing the polish in such a way that the surface remains polished after it is removed from the polishing bath. In other words., the anodic film that is vital to the polishing mechanism&apos; must be tightly adherent and nonporous. It is usually desirable that it be thin. Polishing solutions consist of proper proportions of an acid and a strong oxidizing agent. In electro-polishing, the external circuit acts as the oxidizing agent. The proportions are critical because the essential surface film must be maintained at approximately constant thickness during the polishing process. In the case of zinc, chiefly two oxidizing agents, chromic and nitric acids, have been used. The simplest polishing reagent is concentrated nitric acid. However, it has certain disadvantages. It tends to pit: an excessive amount of heat is evolved during polishing; and the oxide film that it produces is not very stable, so that the polished sur-

Jan 1, 1957

The stability of mine roofs in permafrost zones is determined mainly by temperature and ice content. The deformation resulting from creep and temperature-dependent physical properties of frozen rock mass is the dominant component of total deformation. Roof bolts can consolidate the roof and control its deformation. In this paper, a finite-element model, for the analysis of the effects of roof bolting in a frozen rock mass is presented. The model includes the variables normally encountered when analyzing the effects of roof bolting in rocks. It also accounts for properties unique to frozen rock mass: creep deformation and the change in Young&apos;s modulus with changing temperature. The model shows that, as bolt spacing decreases, there is a trade-off between increased roof stability from increased mechanical support and decreased stability from increased conduction of heat into the frozen roof. This result was expected and shows that, for a given set of rock-mass conditions, including ice content, temperature, particle size, etc., there is an optimum bolt length and bolt density for minimum roof deflection.

Jan 1, 1997

By David L. Rife

Fluid inclusions have been studied since the mid-1800s. In 1858, the famous English geologist H. C. Sorby, stated that ". . . there is no necessary connection between the size of an object and the value of a fact, and that, though the objects [inclusions] ... are minute, the conclusions to be derived from the facts are great."&apos; This statement philosophically emphasizes why fluid inclusions should be studied. Fluid inclusions supply the economic geologist with "hard" data on the chemical environment and mechanisms of transport for ore fluids. Such studies enable geologists to understand more about their complex nature. The information that can be obtained from fluid inclusions is as follows: 1) Fluid inclusion "filling temperatures" measured with the microscope heating stage, reflect the hotness of an ore fluid at the time of its entrapment and are one of the most accurate methods of geologic thermometry. 2) Ore fluid densities indicate the extent to which ground water becomes mixed with ore fluids. Density is determined from the composition of inclusions, the ratios of gas to liquid (at room temperature), and from

Jan 1, 1973