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Titanium dioxide (TiG ) is produced 2 commercially by two methods generally referred to as the "sulfate" route and the "chloride" route. The SCM Corporation, in supplying 15% of the world's demand for TiO 2, uses both of these processes. Of the two processes the sulfate route is generally regarded as the older and more established technology. Worldwide the sulfate route accounts for some 70% of total Ti02 production. However, in the U.S.A. the chloride process accounts for 80% of production. The processes vary in chemistry and raw material requirements. In the "sulfate" process finely ground ilmenite or titanium slag is digested with sulfuric acid to produce a porous "cake" vrnich is extracted with water and recovered liquor. The solution is treated with scrap iron to reduce any ferric ions to the ferrous state which is then crystallised and removed as ferrous sulfate heptahydrate. The liquor is concentrated by evaporation and hydrolysed to form the insoluble hydroxide which is filtered and washed free of impurities. This is converted to the dioxide by calcination at 800 - 1000¦C and milled to break up any aggregates. The "chloride" process uses a higher quality feedstock of natural or synthetic rutile and/or high grade titania slag. The feedstock is mixed with ground high-purity coke and chlorinated at 950¦C in a fluidised bed. The resulting crude titanium tetrachloride is purified by distillation and chemical treatment. The purified titanium tetrachloride is burned with oxygen or oxygen enriched air to give titanium dioxide and chlorine, which is recovered and recycled to chlorination. Titanium dioxide pigment from both processing routes undergoes similar finishing techniques. It is subjected to further stages of wet and dry milling, then coated with layers of inorganic oxides in order to enhance its properties for specialist applications.

Jan 1, 1986

By James Ludwiczak

This paper consists of the conduct of a forensic criminal investigation of the components, construction, use, and functioning of two suicide bombs. As the title states, the task was to form professional opinions as to whether the bombs would work, would cause property damage, and would injure or kill. The bombs were created and installed by a defendant in a Federal death penalty case where the defendant’s daughter was killed in a shootout with the West Virginia State Police. The two black powder bombs were placed under the front seats of the defendant’s automobile and were designed to function by the use of a toggle switch connected to the automobile’s cigarette lighter. The forensic work first consisted of an inspection of the remains of the wiring system and bombs at the Bureau of Alcohol, Tobacco, and Firearms Laboratory, in Ammendale, MD. This was necessary to determine and detail the wire diameter and lengths, the lengths and size of the wire used, the type of toggle switch used, the type of containers, the type of rocket motors used to initiate the black powder, the manufacturer and amount of black powder used in each bomb, and the type, wraps, and amount of duct tape used for the construction of each bomb. Using this data, tests were conducted by duplicating the wiring system and the two bombs to insure that the system functioned properly. Each bomb was duplicated and initiated to observe the violence produced when initiated in the open air. Duplicate bombs were placed under the seats of a similar type of automobile and initiated. The purposes of the tests were to duplicate the bombs, to observe the violence of the initiation, and to observe the damages to the automobile produced by the initiation.

Jan 1, 2007

By Anne C. Chinellato, Alejandra T. Soria, Nelida L. del Mastro, Amanda C. S. Pereiral, Esperidiana A. B. Moura, Anibal V. Abreu

"This work presents a comparative study of the thermo-mechanical and morphological properties of sugarcane bagasse fiber/HDPE composite treated with electron-beam and gamma radiation. The composite samples obtained by extrusion and injection molding processes were irradiated at 50 and 90 kGy using either a 1.5 MeV electron beam accelerator or gamma irradiator EMI-9, at room temperature in presence of air. The irradiated and non-irradiated samples were submitted to mechanical and MPI tests, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), sol-gel analysis and X-Rays Diffraction (XRD) and the correlation between their properties was discussed. Improvement of the bagasse fiber/HDPE composite properties, using electron-beam or gamma radiation, was found.IntroductionResidues of sugarcane bagasse fiber are widely produced in Latin America and other countries: in Southern Africa, Egypt, South-Eastern Asia, India, China, Australia, Cuba, among other producers, as by-products of the sugar and bioethanol industry. The sugarcane industry in Brazil and Uruguay is well established and expanding with large potential to increase the production of sugarcane bagasse in the next years [1-3]. Although the major portion of the bagasse is currently burnt for energy supply in the sugarcane industry, the disposal of this byproduct is still inefficient and, consequently, it is critical for agricu1ture profitability and environmental protection. Sugarcane bagasse is a lignocellu1ose fiber mainly constituted by around 46 % cellu1ose, containing hemicellu1ose, lignin, fat and waxes, silica and other elements [3, 4]. Studies have reported that sugarcane bagasse can be used to produce thermoplastic polymeric composites with excellent properties for many applications. [5-8]. Based on this survey, the transformation of bagasse into high quality industrial products, such as bagasse-polymer composites, can provide its more effective utilization."

Jan 1, 2012

By P. M. Solozhenkin

"Galvanochemical process (GChP)) cleaning of sewages is realized in the field of shortcirquited galvanic elements from the mixture current the materials place in purification’s solution and form multitude galvanopairs without external electric field in presence oxygen of the air. The galvanochemical process is electrochemical process utilizing galvanic pairs: coke - iron, iron - copper and others and process does not require chemical reagents.The effect of basic parameters of the cleaning effectiveness have been studied depending on oxidizing of galvanopairs. Adjusting nature, type of galvanic pairs and forming three component system possible to enlarge emf circuits to 2.378 V.The role of ?2, as basic agent, for generation of hydrogen peroxide and hydroxyl ions.It was stated, that removing of metal ions from solutions occur mainly on account of sorption and hydrolytic sedimentation of iron oxihydrates.Determined separate stages of the process: coagulation, sorptions of admixtures on freshly formed ferric oxides and oxidizing destruction of organic components of effluents in presence of ?2 ? ?2?2. Shown efficiency of the method for removing of Cu, Cr, Ni, Zn, As ions, as well as fluoride, phosphate and cyanide anions and oil products, surface-active and flotation reagents. Cleaned water can be recycled for some processes non-critical toward residual concentration of admixtures, as total salt contents is lowered on 60-75 % and reaching limits of concentration for toxic components.The concept of high power unit creation was developed, and galvanochemical pulsator is presented. The pulsator is not expensive, and exploitation expences are low, as well as servise is simple with high effectiveness, and capacity. The galvanoflotation process is developing, combining galvanochemistry and flotation of hydrofobic admixtures (oil, surface-active agents).The galvanochemical flotators are presented."

Jan 1, 2003

Discussion of the paper Of NOEL CUNNINGHAM, presented at the New York meeting, February, 1915, and printed in Bulletin No. 99, March, 1915, pp. 601 to 608. C. H. POIRIER, New York, N. Y. (communication to the Secretary*). -Mr. Cunningham's paper, written from the standpoint of a stamp advocate, while commenting more or less favorably upon the installation of ball mills in the Vipond plant, does not, in my opinion, give as much emphasis to the comparatively new departure as the installation of ball mills in the place of stamps justifies. This discussion is based upon my personal and intimate practical work for several years with stamp mills, and for the past three years with Hardinge ball and pebble mills. The fact that the Vipond mine contains about equal quantities of the A and B classes of ore mentioned by Air. Cunningham, and the further fact that I have had a most intimate knowledge of the working of both classes of ore in the Porcupine district in stamp mills and ball mills, justifies upholding my final decision to use ball mills in the place of stamps, and defends my present further action in now increasing the present Vipond capacity by the addition of another 6-ft. Hardinge ball mill, in which action the directors of my company concur. This is one of the strongest evidences I can possibly offer in substantiation of my opinion that the ball mill exceeds the efficiency of the stamp, both in metallurgical and mechanical economy. It is hardly fair to compare a 100-ton per clay plant with a mill handling several times this amount, yet it is my belief that the cost per ton. of grinding in the ball mill is far less than that of any stamp mill in the district, where capacities run up to 400 tons per clay.

Jan 5, 1915

By Hung Tran, Denis Fleury, (Ken) Qian Liu

Pastefill technology has gained an increasing popularity over the past decade. The main advantages are: environmental performance (mainly in tailings disposal), low operation costs and ease of operation, as well as homogeneous properties. However, its weaker nature compared to other types of fill makes it more vulnerable to blast damage. In the last few years, Louvicourt Mine has experienced some cases of pastefill sloughage during the mining of secondary stopes. In order to reduce pastefill sloughage, some studies have been undertaken to investigate the causes and to find possible solutions by looking at stope design, extraction sequence, ground support and blast design. This paper presents the results of a blast damage study carried out at Louvicourt on the 860m level. The instrumentation included vibration monitors (using 6 sets of triaxial geophones grouted in the pastefill), a borehole camera to observe the damage in the pastefill, and a cavity monitoring system for three-dimensional surveys of the blasted stope. The test stope was mined out by four slot blasts and three mass blasts. Most of the damage was created by the mass blasts. It was found that the accumulation of ground vibration was mainly due to the low seismic velocities in the pastefill and the relatively tight delay between blastholes. In addition, there was a substantial difference between the critical PPV in the confined and unconfined pastefill. In practice, these findings have led to modifications of blast design to minimise the exposure time of pastefill walls to air. Such modifications included changes of blast sequence in secondary stopes and delay layout between heavily loaded blastholes. Over the paste two years, the implementation of new blast sequence has shown encouraging results in terms of reduced pastefill sloughage and dilution.

Jan 1, 2000

By NONE N/A

THE Section on Aerial Geologizing of the American Institute of Mining and Metallurgical Engineers convened on Monday afternoon, Feb. 17, 1936, during the Annual Meeting of the Institute. Mr. Theodore Marvin presided. CHAIRMAN MARVIN.-We hope to get through with the papers on the program in time so that you can examine the instruments that are dis-played here, and also the photographs and air views brought by the Fairchild people. This is what we might call the first bread and butter session of the Aviation Committee. The group, as many of you know, was started at the request of the Board of Directors two years ago. We have had two sessions since then, both of them of a somewhat general nature, their pur-pose being to point out the reasons why mining and petroleum engineers should be more interested in the facilities of aviation. Today we have two papers. The first is one by Mr. Eliel, of the Fairchild Company's California branch. In Mr. Eliel's absence, Mr. Gale, of the Fairchild Company, will read it. C. H. GALE.-Before I begin to read Mr. Eliel's paper, I would like to point out two instruments that he mentions. One is what he calls the solar-navigator, a new type of aerial navigating device which he has developed for use in flying cameras in aerial surveys. Flying a camera at high altitudes over unfamiliar territory is a very difficult procedure and only a few pilots in this country can do it. So far as I know, this is the first time this device has been discussed in public. Another facility I want to refer to in advance is the use of the stereoplanigraph in making contour maps from photographs. This is an extremely interesting procedure, which we are appreciating more than ever at the present time.

Jan 1, 1936

By Samuel B. Flagg

The Bureau of Mines is endeavoring to ascertain how mineral fuels in which the Government has a direct interest, by ownership or use, can be utilized with highest efficiency. For this reason the bureau has been, and is, carrying on investigations to ascertain the condi- tions of furnace construction and management that are necessary to insure the smokeless combustion of the different coals that are found in public lands or are purchased for Government ships and power plants. Another reason for the bureau undertaking these investigations is the need of better furnace management and a more careful selec- tion of fuel at many Government plants. There are Federal build- ings in hundreds of cities. The coals available at many of these cities differ greatly in quality, and the furnaces in some of the Fed- eral buildings were not designed for efficient utilization of the cheap- est available coal. Hence, some of the boiler plants smoke badly unless fed with low-volatile coal and have caused repeated com- plaints not only from neighboring property owners who have suffered damage, but from persons endeavoring to create a civic pride in clear air. In the course of its fuel investigations the bureau has noted the conditions governing fuel consumption in different cities and has studied the attempts made by these cities to abate smoke through the passage of ordinances imposing penalties on smoky stacks. Some results of that study are presented in this report. The most im- portant conclusion reached is that smoke abatement by ordinance can not hope to succeed unless supported by public sentiment and that a smoke ordinance should look to future prevention rather than to immediate prohibition. In other words, strict control of furnace construction offers much greater hope for smoke abatement than desultory imposition of severe penalties on the escape of "dense" or "black" smoke.

Jan 1, 1912

By Isaak I. Maksimov, Tatyana E. Koltunova, Mikhail F. Yemelyanov, Liudmila A. Otrozhdyonnova

"INTRODUCTIONMetals losses amount up to 50% in coarse fractions in (>100 µm) and composite particles, and to 20- 25% in fine fractions (<10 µm) at non-ferrous floatation concentrating plants of the CIS. Therefore, reduction of metals losses in difficult fractions is of high significance.IMPROVEMENT OF FLOATABILITY OF COARSE AND COMPOSITE PARTICLESReagent regimes with application of strong collectors – xanthates ?5-?8, combination of butyl xanthates and aerofloats ?10-?12, butyl xanthates with hydrocarbons are proposed for this purpose. Application of such reagent regimes for copper and copper-molybdenum ores permitted to increase copper and molybdenum recovery by 0.5-3.9%.Studies, performed by means of specially designed non-frothing flotation machine with independently controlled agitation intensity and narrow size-ranges of air bubbles, established that the best results are achieved with employment of bubbles of 0.5-0.8 mm size regarding particles of any size, with small amounts of up to 2 mm size “transport” bubbles to be expediently used for floatation of coarse particles.Energy dissipation in the main volume of floatation cells must be lower than 0.2-0.25 m2/s3.Performed experiments permitted to formulate requirements to development of machine for floatation of coarse and composite particles. Such floatation machine with volume of 8.5 m3 provided for weak agitation in the main volume of floatation cell and uniform distribution of coarse particles throughout the depth owing to establishing of pulp circulation with upward flows. In addition, in the upper part of floatation cell where agitation is considerably weaker, favorable conditions are created for attachment of particles to bubbles. Testing of this floatation machine demonstrated a 7.5% increase in recovery of +0.2 mm particles in pyrite floatation and a 12-14% increase in recovery of +0.2 mm particles in apatite floatation as compared with a reference floatation machine."

Jan 1, 2003

SUGGESTIONS that existing schools give instruction bearing on the mineral industry, or that schools for that purpose should be established in the United States, began to be made early, and it would require too much space to catalogue them all. Some of the more important may be mentioned to indicate their general character. In the "advertisement to such parents as have now (or expect to have) children prepared to be educated in the College of New York," which appeared in the New York Mercury of June 3, 1754, Samuel Johnson, the first president of King&apos;s College, the predecessor of Columbia, said that it was the "design of this college to instruct and perfect the youth," among other things, "in the arts of Numbering and Measuring of Surveying, and Navigation and Geography. . . . and in the Air, Water and Earth around us, and the various kinds of Meteors, Stones, Mines and Minerals, Plants and Animals; and in the knowledge of all Nature in the Heavens above us, and of everything useful for the Comfort, Convenience and the Elegance of Life . . . " Though the concept that natural science should be used to enlarge the bounds of human life was thus implicit at Columbia from the , very beginning (John Stevens graduated from it in 1768, James Renwick in 1807, Horatio Allen in 1833, and A. W. Craven in 1899), it was only during the period of Renwick&apos;s professorship of Natural and Experimental Philosophy and Chemistry (1830- 1853) that much attention was given to applied science.* Among the Austin papers, published by the American Historical Association,~ there is a draft in Stephen F. Austin&apos;s handwriting of a proposed memorial from the legislature of , Missouri to Congress, not only urging "the propriety and utility * See chapter 4 for early interest in this subject in Philadelphia.

Jan 1, 1941

By William T. Folwell

INTRODUCTION - CURRENT RAISE BORING PRACTICES Raise boring is a comparatively new tool to the underground mining and construction industries. Underground raise boring, in this country, had its beginning in the early 1960&apos;s, in the iron mines of Michigan. These first raises were bored 40 in. and 48 in. in diameter with maximum lengths of approximately 200 ft. Since the late "sixties", the raise boring machine has been accepted by the mining industry as an important machine to increase excavation rates, provide adequate ventilation airways, improve safety, and reduce costs, to name a few of the benefits. The construction industry is now accepting raise boring techniques for hydro-electric power projects, water supply projects, tunnel projects, waste water projects, etc. Raise drills are now capable of boring raises to diameters as much as 12 ft, in the softer rock types. Raise lengths range from 200 ft to as long as 1700 ft. Bored raises, in general, are bored at dip angles ranging from 45º to 90º, depending on the requirement of the raise. The general practice is to drill the pilot hole down to an opening below and up ream the pilot hole to the required diameter. The pilot hole (9-7/8", 9", 11", or 12-1/4" diameter) is generally drilled with compressed air to remove the cuttings. In the event that ground water is encountered and removal of cuttings is impeded, a foaming agent is added to assist in lifting the cuttings. When excessive water is encountered, water is used as the circulation medium and the cuttings are removed by pumping. During the reaming cycle, the cuttings fall by gravity and are removed from the bottom of the raise by conventional methods.

Jan 1, 1997

H. G. DAVIS, * Wilkes-Barre, Pa. (written discussion ? ).-The only practical method of testing mine air for gas, until recent years, was by the effect of the gas on the flame of the ordinary Davey Lamp, and it is quite surprising how nearly the correct percentage of gas can be deter-mined by many men by observing the behavior of the safety-lamp flame in the different mixtures. Mine foremen frequently guess the percentage of gas to within 0.1 per cent., making certain allowances to cover the dust-laden atmosphere, in which the test was made. It is not meant by this that anthracite dust is explosive, but that its properties increase the length of a fuel cap on an ordinary oil-burning lamp, which, as Prof. -Young contends, increases in height with the proportion of gas and in-creased temperature. Naphtha or benzine-burning lamps have a hotter flame, and, there-fore, are more sensitive so that a smaller percentage of gas can be detected. Some of the fire bosses in this region some years ago preferred the Koehler lamp, while others did not care to use it in their morning examinations. In 1911, when the experimental mine of the Bureau of Mines at Bruce-ton, Pa., was being prepared to be exploded, a large number of mining men went through it to examine the entries, which were lighted by electricity. While so doing, they saw in the face-return-airway a Koehler or Wolfe lamp, that seemed to he burning with difficulty. An investigation showed that the lamp had been filled to overflowing with naphtha and was generating this surplus gas. This shows how easily we can be

Jan 11, 1919

By William Wraith

At the Washoe smelter, Anaconda, Mont., the blister-copper from the converters is transferred, by means of a crane, to a re-fining-furnace, in which it is brought to proper pitch by means of air and poles. From this furnace the refined copper, containing gold and silver, is poured into cast-iron molds placed on a platform-convejor, giving an anode 36.75 in. long, 35 in. wide, and 2 1/16 in. thick. By reason of a disagreement between the smelter and the refinery, in reference to the silver-content of the anodes, it becanle necessary to investigate the methods of sampling used. 11. SMelter Method of SampliNg. At the smelter the sampling is done by " shotting " into water a small portion of the molten stream of copper as it flows from the furnace, by " batting " the stream&apos;with a wooden paddle. The first sample is taken 30 min. after the pouring i.: started, three other samples being taken at 1-hr. interrals, each sample Weighing from 4 to 6 oz. The samples are dried, esamined for particles of burnt wood, screened on a 10-mesh screen of NO. 8 wire to remove the fines, the oversize then screened on a 4-mesh screen of No. 20 wire to remore the coarse, the undersize of this screen being taken as the sample. The four portions thus obtained are thoroughly mixed and split in half by passing over a 16-slot splitting-device, slots being 0.5 in. wide. One-half of the sample is sent to the laboratory for analysis and one-half kept as a duplicate. 111. Refinery Method of Sampling. The method used at the refinery and also used in this in1-estiyation is the one developed by Dr. Edmarcl Keller, of

Jan 1, 1911

By J. W. Gilbert

DuriNG the sinking of the Needmore shaft, on one of the leases of the Eagle-Picher Mining and Smelting Co north of Webb City, Missouri, a very strong flow of water was encountered at a depth of 140 ft. Because OF the speed at which the water rose in the shaft after pumping was discontinued, and in order to speed up sinking operations, a new type of shaft bar and drilling equiprnent was devised, which saved approximately one hour on each shift This bar is made of an ordinary scren type shaft bar with a common drill arm attached to the bar by clamps and welded Into place To this drill arm is attached an ordinary arm clamp with set collar below Through this clamp is attached another drill bar of ordinary length so constructed that it slides back and forth and rotates around the perimeter of the shaft on the set collar A tripod saddle with legs removed is welded to the rotating bar, which enables the drill operator to drill holes at any angle completely around the shaft and also, after an arm extension, permits the drilling of the corner holes without removal of the rig from the saddle Upon completion of the drilling of a shaft round, all that is necessary for the complete removal of the drill machine and shaft bar is to engage the hoist hook through a. ¾-in. eye provided for that purpose on top of the bar and disconnect the air and water lines from the machine, thereby making it possible to pull the whole apparatus out in one piece. At no time is it necessary to remove the machine from the saddle Screw jacks are installed on the vertical bar to further ensure the rigidity of the shaft and bar arm. The accompanying sketch illustrates the details and method of setting up.

Jan 1, 1946

By T. H. Udayashankara

Soil pollution, a very serious environmental problem, has been attracting considerable attention in recent years. It is now generally recognized that land as a component of the environment deserves the same attention and protection as water and air. This recognition has arisen perhaps because of increased incidents of land pollution, the scarcity of land, and increased awareness and concern about long-term effects of land pollution on terrestrial and aquatic eco-systems and on ground water quality. Contamination of land results from a wide range of human activities, including industrial discharge process, disposal of wastewater and agriculture. The environmental impact of exploration, production and refining of crude oil is a major concern in developed and developing countries. Because of the known adverse effects of petroleum hydrocarbons on soil ecology and fertility there has been growing interest in the development of efficient technologies for the remediation of contaminated land, with a view toward making it available for further use. Crude oil is a natural product and as such is susceptible to degradation by naturally occurring micro flora. Bioremediation has become an important method for the restoration of oil-polluted environments. A bench scale study was conducted to evaluate the bioremediation technique in treating soil contaminated with transformer oil. The steps involved in this study are: (1) Preparation of contaminated soil, (2) Extraction of PAHs and PCBs from contaminated soil, (3) Treatment of contaminated soil in slurry batch reactor, and (4) Analysis of PAHs and PCBs by gas chromatography technique. The performance of reactor was assessed by measuring parameters like COD, PAHs and PCBs. The study was con-ducted for six different pulp densities ranging from 20% to 40%. The maximum removal of PAHs and PCBs was observed for 20% pulp density.

Jan 1, 2008

By A. T. Sutaone

"Battery grade Mn ore is not found in India except in Dongri-Buzurg Mine, Dist. Bhandara, Maharashtra. The mine located in central India is operated by a premier company viz. Manganese Ore India Ltd., under Central Government Public Sector Undertaking. The company is not selling the product as battery grade material but instead primarily catering to the needs of the iron and steel industry in the country. However, a part of the ore is being used in-house for the production of electrolytic manganese-dioxide in their EMD plant, which is located near the mine.The production of lumpy ore for steel industries generated through multi-stage crushing and screening has resulted in accumulation of about 50,000 tonnes of low grade fines over the year, which contain low of Mn values. Further, the generation of fines is still on going process due to the production of lumpy ores. These fines are stacked in the form of unconsolidated dumps, which create environmental problems like air and water pollution and siltation in the adjoining fields. Besides they are occupying large space, which is scarce in this mining area. The Indian Bureau of Mines under one of its statutory functions has suggested the company to explore the possibility of recovery of additional values under conservation and environmental aspects. Hence the company has sponsored a bulk sample for beneficiation studies in the Modern Mineral Processing Laboratory and Pilot Plant of Indian Bureau of Mines at Nagpur, India. The main manganese minerals present in these mine rejects have been identified as pyrolusite and psilomelane. The purpose of this study was to explore the possibility of evolving a suitable beneficiation flowsheet to obtain manganese concentrates assaying over 72% MnO2 to be used as raw material for the manufacturing of dry cell batteries."

Jan 1, 2003

By P. K. Gbor

Over 2 million tonnes of smelter slags containing Co, Ni and Cu are produced and stockpiled in Canada each year. Smelters also produce SO2 an air pollutant. Recycling these materials will maximize the value of natural resources and minimize possible environmental impacts of industrial operations. The objectives of this research were to understand the characteristics of slag, the reaction of slag with SO2(aq) and to develop a novel method for extracting Co, Ni and Cu from slag using SO2. The properties of slags from different smelters were studied, with emphases on the form of Co, Ni, Cu and Fe. Leaching experiments were carried out in a batch reactor. The parameters investigated included concentration of SO2(aq), stirring speed, particle size, temperature and pH. O2 was introduced into the reactor to study its effect on the system. The amount of each of Co, Ni and Cu in all the slags was less than 1%, while Fe was between 30% and 45%. The form of Co and Fe was primarily oxide, however, significant portions of Ni and Cu were present as sulphides. SO2(aq) alone, was effective in leaching Co and Fe. Cu dissolution was negligible due to precipitation. The presence of O2 improved Cu and Ni extraction. SO2(aq) was found to be more effective in leaching slag than H2SO4 at the same pH. The leaching process was modelled using the shrinking core model. A scheme was proposed for the extraction of Co, Ni and Cu from slag using SO2(aq). The process makes efficient use of SO2, separates Co and Cu at an early stage, and minimizes the consumption of base during Fe separation.

Jan 1, 2003

By Stanislaus Skowronski

THE melting of cathode copper, usually containing 99.98+ per cent. Cu, would appear to be a simple matter. Owing to the well known affinity of copper for sulphur, however, so much sulphur is absorbed by the copper during the operation that a long and expensive refining process is required to remove it, and the final product is inferior in purity and lower in electrical conductivity than the original cathode copper. The furnace operation, as now conducted, includes the following stages: 1. Charging the cathodes into the furnace. 2. Melting the cathodes. 3. Oxidizing period-saturating the copper with cuprous sub-oxide and bringing the metal to the condition known as "set copper;" this is now done by blowing air into the molten bath of metal. 4. Reduction period, otherwise known as "poling," whereby the oxygen previously added is removed by covering the molten bath completely with coke or charcoal and introducing large poles of green wood; this reduces the cuprous sub-oxide, bringing the copper to the "tough pitch" stage ready for casting. 5. Casting Period. Many experiments have been made to obviate the long periods of oxidation and subsequent reduction, with no success. While the copper first, cast will be good, as indicated by the set surface of the bars, it is impossible to hold it to the "tough pitch" condition, and long before the whole charge has been poured the copper will become "overpoled," entailing numerous difficulties. Sulphur has always been blamed by the furnace men as the reason why this refining process is necessary, yet the literature on the subject does not sufficiently emphasize how small a proportion of sulphur will ruin copper for practical purposes.

Jan 3, 1918

By William Catron

BECAUSE the rich La Colorada orebody of the Cananea Consolidated Copper Co. does not outcrop at surface, after its discovery (by churn drill) and before mining was begun, a large amount of development work was done to learn the shape and extent of the ore and to provide for eco-nomic and effective mining. As these openings progressed, the actual shape of the orebody became known and with this knowledge came the realization that mining this rich and unusual deposit without loss of ore or danger to workmen presented several difficult problems. This paper will describe one of these problems; namely, the handling of an inverted cone-shaped core of barren rock, on the periphery of and below which the ore occurred. It was clear that as the ore was mined out from around and under this inverted cone of rock, weighing about 3,000,000 tons, it would hang over the workings, held suspended only by its own tensile strength and threatening to crash into the stopes below with disastrous results to men and mine. The method of mining developed during the years 1928, 1929 and 1930 anticipated and provided for the eventual collapse of this core of rock. In November 1936 the core settled clown gradually on the edges of the stopes, descending a total of about 50 ft. vertically. The men in the stopes had ample to warning and no lives were endangered. There were no air blasts in the mine. The core broke loose from its top support at the 500-ft. level along old fracture planes and evidently is crushed to the ninth level. Movement was of short duration; the following shift went to work in the stopes as usual. No ore was lost.

Jan 1, 1938

By Gilbert Thiessen

The use of a pneumatic process for removing fine material (usually less than 48-mesh) is increasing in the preparation of stoker-size coal. The fine material, produced as a byproduct, is known as dedusting-plant dust. Since fusain is the most friable ingredient in bituminous coal (it may readily be rubbed to an impalpable powder with the fingers), it tends to accumulate in this byproduct. While studying the properties of cokes produced by blending Illinois coals with other materials, considerable quantities of fusain were required. Dedusting-plant dust suggested itself as a convenient supply. It became necessary, therefore, to determine how much fusain was contained in a measured sample of dust, how the fusain was distributed with respect to size and specific gravity in the sample, and whether or not it would be feasible or desirable further to concentrate or to recover the fusain from the dust before using it in the blends to be coked. The results obtained indicate the possibilities of production of a high-fusain material. Previous Work Lehmann and Stach have developed a processl,2 for separation of banded bituminous coals into their band ingredients by impact pulverization followed by screening or air separation. They found, as might be expected, that the fusain was concentrated in the very fine material. Prockat and Raute3 examined samples from dedusting plants operating in the Ruhr. They separated the dust into various screen sizes and determined the composition of each of these sizes in terms of the banded ingredients of the original coal. In the dusts examined by them, the finest material was always high in fusain, and most of the fusain contained in the original samples could be recovered from this fraction.

Jan 1, 1936