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By P. H. Turnock, R. D. Pehlke

The effects of mutual interactions between elements on the solubility of nitrogen in liquid iron alloys containing chrormium, columbium, molybdenurn, nickel, or silicon have been determined. The equilibrium nitrogen solubilities in the liquid iron alloys were measured by the Sieverts method. The second-order effects caused by the presence of chrormium, columbium , or silicon in the melt were found to be significant. The solubility of nitrogen in liquid iron alloys containing several alloying elements has also been measured as a function of melt temperature and nitrogen pressure. The heat of solution of nitrogen in microcomponent iron alloys has been found to be a function of the logarithnz of the activity coefficient of nitrogen, irrvespectilje of the composition of the melt. The heat of solution of nitrogen in pure liquid iron was determined to be 1265 ± 450 cal per g-atom of N over the temperatxue range 1600° to 1800°. Sieverts ' law was obeyed for all melt compositions studied in the pressure interval 0.4 to 1.0 atm. The solubility of nitrogen in liquid pure iron and in many dilute binary liquid-iron alloys has been the subject of many investigations. Pehlke and Elliott' made a comprehensive investigation on this subject in which they summarized and compared previous researches. However, the practical application of these solubility studies requires prediction of the nitrogen solubility in the multicomponent alloys encountered in operating practice. The interaction parameter as defined by wagner2 has been used to predict the behavior of a solute in a complex alloy, and a modification of this approach has met with reasonable success in several instances.'1"5 The necessity for extending the nitrogen solubility data on binary alloys is caused by the lack of direct measurements of the solubility of nitrogen in molten alloy steels. A direct comparison between measured solubilities and those predicted for multicomponent alloys based on data in binary systems has been made in only a few instances, and most of these were reviewed by Langenberg,6 who developed a graphical technique for predicting nitrogen solubilities in multicomponent iron alloys. The solubility of nitrogen has also been studied over the entire Fe-Cr-Ni ternary system by Humbert and Elliott.? Both studies compared the solubilities computed from binary iron alloy data with those measured in ternary alloys in the liquid state at 1600°C. Most of the nitrogen solubility measurements referred to above were for iron alloys at 1600°C; thus, the ability to predict nitrogen solubilities in molten iron alloys has been restricted primarily to alloys at 1600°C. Recently, Nelsson8 devised an approximate method for calculating the change in nitrogen solubility in molten iron alloys as a function of temperature, but an assumption of regular solution behavior limits the applicability of the method. Chipman and Corrigan9,10 have developed an empirical correlation. based on the activity coefficient of nitrogen in the iron alloy at 1600°C, which facilitates the estimation of nitrogen solubilities at higher temperatures. This method also has limitations, due to the necessity of calculating the activity coefficient for nitrogen in a multicomponent iron alloy at 1600°C from the nitrogen solubility data for binary iron alloys. The shortcoming of such a straightforward approach to the problem of predicting nitrogen solubilities is the disregard of mutual interactions between elements in a complex iron melt. This investigation was conducted in an attempt to provide a more reliable method of predicting nitrogen solubilities in multicomponent iron alloys. The effects of the mutual interactions between chromium, nickel, silicon, molybdenum, or columbium in iron were studied, using the Sieverts' technique1,7 to measure the effects of alloy composition, temperature, and pressure on the solubility of nitrogen in ternary liquid iron alloys.

Jan 1, 1967

By Oliver Bowles

The use of fire as a source of heat was the first step from primitive existence toward modern civilization, and heat has performed functions of inestimable importance throughout the ensuing ages. The first commercial steam engine invented in 1698 demonstrated that heat was an important source of power, and heat has since become the motivating force for railroad trains and steamboats as well as for machines in multitudes of factories. Aside from its function of supplying power, heat is an agent of vast importance in chemical reactions and engineering processes. Because of the high temperature of steam under pressure, losses by radiation from boilers and pipes become excessive unless the radiating surfaces are covered with insulating materials. Insulation is important also for hot-water pipes and many other types of equipment from which heat may radiate. Radiation losses from heated surfaces increase rapidly

Jan 1, 1943

By Virgil A. Marple, Susanne V. Hering

"5.1 IntroductionTraditional impactors do not offer much size resolution for submicrometer particles; typically their finest size cut is around 0.4 µ.m. Yet for many aerosol applications it is useful to be able to size segregate aerosols in the size range below 0.4 µ.m. Diesel emissions, welding fumes, cigarette smokes and photochemically generated smog aerosols typically exhibit mass median diameters between 0.1 and 0.6 µ.m. When sampling these aerosols with a traditional impactor, fifty percent or more of the aerosol mass can penetrate the final impactor stage. Allhough the material can still be collected on a backup filter, the filter gives no size resolution. As a result, the investigator has no size information on a substantial portion of the sample. One needs a sampler that size-segregates the majority of the aerosol mass. A lower size cut of 0.1 µ.m or less is required for most combustion smokes and smog aerosol s.To obtain smaller cutpoints two types of impactors have been developed, namely low-pressure impactors and micro-orifice impactors. Both instruments can provide cutpoints as small as 0.05 µ.m. Low-pressure impactors were introduced more than twenty years ago (Stem et al., 1962), and a variety of these samplers are in use today. Micro-orifice impactors have been developed at the University of Minnesota within the last five years (Marple et al., 1981 ). To date theirs are the only examples of these instruments in use.5.2 Operating PrinciplesThe low-pressure and micro-orifice impactors use two different approaches to achieve their very small particle-size cuts. Low pressure impactors resemble ordinary impactors, but are operated at reduced pressures of 5-40 kPa (0.05 - 0.4 atm). They take advantage of the decreased aerodynamic drag on particles that occurs when the mean free path in the air is as large or larger than the particle diameter. Micro-orifice impactors operate at near atmospheric pressure, but employ very small orifices, 40 µ.m to 200 µ.m in diameter. The streamlines of the air impinging upon the impaction plate have correspondingly smaller radii of curvature; the air is accelerated more quickly, making it more difficult for the particles to follow. The basic operating principles for both types of impactors are evident from the particle Stokes number, defined as:"

Mar 1, 1989

By Tassos Grammatikopoulos, Mike Johnson, Niels Verbaan

Seabed polymetallic nodules, which contain significant quantities of metals key to electrification such as nickel (Ni), cobalt (Co), copper (Cu) and manganese (Mn) can be processed using several different metallurgical processing options, including direct smelting and subsequent hydrometallurgical refining of the copper/nickel matte; ammoniacal leaching (gas reduction or Cuprion); and acid leaching (often reductive). Many of these approaches suffer from reduced cobalt extraction, difficult physical performance, or overall circuit complexity in general, leading to increased risk to the overall project. SGS has considered the pressure acid leaching of nodules for further investigation, as publicly shared data on this processing route stem from the 1970s and 1980s, and are not always easily accessible. This article details the series of tests conducted and provides updated results obtained — high Ni/Co/Cu recovery with limited manganese/iron (Mn/Fe) — as well as comments on the potential treatment options on the product solution and residue.

Sep 1, 2025

By P. L. Yorio, D. R. Willmer

"The current paper presents the results of a study designed to explore the types of practices that are fundamentally important to developing and maintaining comprehensive risk-based health and safety management systems (HSMS) in mining organizations. Eighteen practicing health and safety (H&S) executives, managers, and professionals from a variety of mining commodities were asked to assess the fundamental importance of 20 distinct elements and 133 different practices assembled from a review of several HSMS consensus standards. The research approach assumes that developing and maintaining a robust HSMS requires unwavering attention to activities designed to either: 1) directly contribute to a risk management system’s plan-do-check-act cycle; or 2) build an organization’s internal infrastructure without which the cycle cannot be sustained. The results of this study suggest that the following areas require consistent focus and attention: Leadership Development; Accountability; Knowledge, Skills, and Abilities Development; System Coordination; Culture Enhancement; Behavior Optimization; and Risk Management Studies. Each element and its corresponding top-ranked and top-rated practices are discussed.INTRODUCTION Since the time of the Industrial Revolution, occupational health and safety (H&S) management has been a topic of practitioner thought and academic inquiry (1). In the U.S., decades of regulation and research have resulted in a surplus of prescriptive information (techniques, tools, approaches, standards, programs, practices, policies, etc.). With an abundance of such information, a simple H&S solution to address a problem in the U.S. mining industry may seem straightforward. Counter to this assertion, however, some evidence suggests that the abundance of information may create complexity and cause confusion in the minds of organizational leaders and H&S managers, ultimately discouraging the voluntary pursuit of a sound approach (2). In line with this perspective, in 2006 the U.S. National Mining Association (NMA) formed an independent commission to examine H&S management issues within the mining industry. The findings of the commission called for the mining industry to adopt a risk-based management paradigm. In the presentation of its findings, the commission stated that “…every mine should employ a sound risk-analysis process, should conduct a risk analysis, and should develop a management plan to address significant hazards identified by the analysis” (3). Grounded in the well-known plan-do-check-act cycle, the recommended risk management system allows for mines to ground strategic management choices in their mine-specific hazards and risk profiles"

Jan 1, 2015

By Neil D. Donnell, O&apos

Ore reserve estimation at the Syncrude Canada Ltd. open-pit oil sands mine in Northern Alberta has evolved since the project's inception. Early techniques followed a conventional petroleum reservoir analysis format, with relatively widely-spaced drill holes and semiquantitative grade data. Experience has developed a more standard mining approach, including classification of geological materials by both lithology and sedimentary origin, timely and multi-purpose drill holes, precise analytical data, empirical recovery factors, a computerized geological data base, and an ore body block model. Future efforts will involve enhancement of existing techniques, use of geostatistical algorithms, quantification of confidence limits, and improved control of the ore model by geological parameters.

Jan 1, 1985

By H. Yoshida

Jet grouting was first introduced in Japan in the second half of the 1960s, approaching 50 years ago. By the end of the first 40 years, jet grouting from single to triple fluid systems had become a global technology. In the last ten years, progress in the jetting has been remarkable, and operational efficiency has improved. The quantity of carbon dioxide emitted in unit soil improvement has become one-third that of the initial technology. Meanwhile, technologies in waste recycling and horizontal jet grouting are also emerging. This paper discusses developments in the most recent ten years.

Jan 1, 2010

By Carlton E. Brown

In 1935 , Brown and Yant / described a microprojector ( microscopic arrangement for projecting images on a screen ) for use in counting and measuring the size of dust particles in Owens - jet dust - counter and simila dry samples of dust collected from the air . In 1938 Brown and others , described a modification of this microprojector that could be used also in counting dust in impinger samples . Microprojectors of this second type have been set up by many mining companies and others and have been made commercially available . Hamly and Pullen5/ described a modification of this microprojector for use in making rapid comparative estimates on konimeter samples and other determinations . This report contains information on still another modification named the "midget microprojector " because of its small size .

Sep 1, 1944

By Mark L. Munsell

In recent years, miners have tried many approaches to maintenance such as: - Highly sophisticated computerized programs. - large planning groups designed to preplan and schedule work. - Contract maintenance. - Break down maintenance. Each of these approaches has faced the added constraints: - High replacement cost of equipment necessitating longer useful equipment life - management?s increased scrutiny of all indirect costs such as maintenance. Faced with these factors, what system of maintenance control is right? After visiting many properties recently, it appears there is no right system. Maintenance programs need to be tailored to the people and production constraints that occur at an individual property.

Jan 1, 1976

By J. T. Dunham

The Bureau of Mines studied by dilatometry the effect of titanium on the thermal expansivity of hot-rolled zinc and Zn-l percent Cu alloy. The titanium content of the alloys was varied up to 0.3 percent. Expansion coefficients were determined from measurements made both parallel and perpendicular to the plane of the rolled sheet. Titanium reduced expansion parallel to the plane of the sheet, especially in the rolling direction, but increased expansion perpendicular to the sheet. Basal-plane pole figures showed that the degree of preferred orientation increased with the titanium content in the alloy, and that anisotropic expansion can be correlated to sheet texture.

Jan 1, 1965

By Thomas T., Read

SUGGESTIONS that existing schools give instruction bearing on the mineral industry, or that schools for that purpose should be established in the United States, began to be made early, and it would require too much space to catalogue them all. Some of the more important may be mentioned to indicate their general character. In the "advertisement to such parents as have now (or expect to have) children prepared to be educated in the College of New York," which appeared in the New York Mercury of June 3, 1754, Samuel Johnson, the first president of King's College, the predecessor of Columbia, said that it was the "design of this college to instruct and perfect the youth," among other things, "in the arts of Numbering and Measuring of Surveying, and Navigation and Geography. . . . and in the Air, Water and Earth around us, and, the various kinds of Meteors, Stones, Mines and Minerals, Plants and Animals; and in the knowledge of all Nature in the Heavens above us, and of everything useful for the Comfort, Convenience and the Elegance of Life . . . " Though the concept that natural science should be used to enlarge the bounds of human life was thus implicit at Columbia from the very beginning (John Stevens graduated from it in 1768, James Renwick in 1807, Horatio Allen in 1823, and A. W. Craven in 1829), it was only during the period of Renwick's professorship of Natural and Experimental Philosophy and Chemistry (1820- 1853) that much attention was given to applied science.* Among the Austin papers, published by the American Historical Association,2 there is a draft in Stephen F. Austin's handwriting of a proposed memorial from the legislature of Missouri to Congress, not only urging "the propriety and utility

Jan 1, 1941

By C. R. Fettke

In 1914, the officials of the Brundred Oil Corpn., faced with the problem of introducing new methods to increase production in the old and nearly depleted pools of Venango County, became interested in the Smith-Dunn (Marietta) process which was at that time being tried out in southeastern Ohio and which was already yielding very encouraging results. A license to use the process in Pennsylvania was secured from the owners of the patents. These patents were later declared invalid. The method was first used in Pennsylvania on a property consisting of about 434 acres, of which 300 are productive, at Hamilton Corners, 15 miles northwest of Oil City, in Cherry Tree and Oakland Townships, Venango County. The producing horizon is the First Sand of the Venango Group. A small oil pool was opened up in this vicinity in 1904. By July, 1916, when the compressed air was first introduced to restore pressure, the production had dropped to a point where it was no longer possible to continue profitable operation. From that time until March, 1927, over 100,000 bbl. of oil have been recovered from the tract. The property is being operated at present by the Brundred Oil Corpn. and LUX. The 1926 production, amounting to 10,650 bbl., was only 400 bbl. short of the maximum reached during any year of the 10-year period that the process has been in operation. Inasmuch as the Hamilton Corners pool is the first one in Pennsylvania in which the Marietta process was tried out, and the one in which it has been longest in continuous operation, considerable interest attaches to the results obtained. Through the courtesy of H. D. Brown and W. J. Brundred, officials of the Brundred Oil Corpn., all their data on this operation were made available to the writer in connection with an investigation of rejuvenation methods in the State for the Pennsylvania Geological Survey. Stratigraphic Position of the Producing Sand The producing sand at Hamilton Corners is encountered at depths of from 364 to 560 ft., depending on the location of the well and the topog-

Jan 1, 1928

By B. Damjanac, S. Maxwell, D. Chorney, M. Grob, F. Zhang, J. Hazzard

"A hybrid discrete-continuum numerical scheme is developed to study the behavior of hydraulic fractures crossing natural fractures. The fully coupled hybrid scheme utilizes a discrete element model for a core domain, within which the hydraulic fracture propagates and interacts with natural fractures, and a surrounding continuum domain to better approximate boundary effects. The results show that the behavior of hydraulic fractures crossing natural fractures is affected by a combination of factors. Nevertheless, three fundamental crossing scenarios can be identified from all of the simulations: no crossing, partial crossing, and direct crossing. Each crossing scenario has a distinct injection pressure history which may suggest guidelines for interpreting field hydraulic fracture injection data. Additionally, the capability for these models to generate synthetic microseismicity makes them appealing for the integration of microseismic field data with the reservoir geomechanics for ultimately providing a practical engineering tool for improvement of well completion and stimulation. The model is capable of examining and verifying four different shear deformation mechanisms associated with a propagating hydraulic fracture. The natural fracture can fail solely due to the stress perturbation of the passing hydraulic fracture or it can fail due to a combination of stress and pore pressure changes across different types of interaction scenarios. The simulations also illustrate that the level of fracturing complexity increases as the number and extent of the natural fractures increase. INTRODUCTIONAlthough hydraulic fracturing technique has been applied extensively as a reservoir stimulation technique in the oil and gas industry for over 60 years (Economides & Nolte, 2000), it is one of the key factors promoting the shale gas boom in the past decade (King, 2010; International Energy Agency, 2014). The hydraulic fracturing of shales can be differentiated from hydraulic fracturing of conventional reservoirs by the fact that shale formations often have a pre-existing discrete fracture networks which greatly impact the hydraulic fracture propagation. Based upon field production data as well as microseismic observations, it is believed that so called “fracture complexity” may result from interactions between a created hydraulic fracture and pre-existing natural fractures and planes of weakness (Warpinski, 2009; Maxwell & Cipolla, 2011)."

Jan 1, 2015

By Charles A. Chase

This paper, descriptive of a single mine, is presented in the belief that it may furnish useful suggestions to mine-managers encountering similar problems; and it includes the details which will enable them to estimate the value of the methods employed—especially where these depart from common practice. Tt should be added, however, that this mine is not typical of the San Juan district, but differs markedly from neighboring mines in physical conditions and metallurgical requirements. The Liberty Bell mine is situated in San Miguel county, Colo., on the west front of the San Juan mountains, 2 miles north of Telluride. The vein was discovered in 1876 by Wm. L. Cornett, who, with subsequeilt locators, took up claims along the apex. A few hundred feet of development-work was accomplished, and a few? tons of ore were smelted or milled; but profitable working proved impossible under existing

Jan 1, 1912

By R. G. Sinclair, E. Sangine, S. M. Fortier, J. Brainard, K. Stone

"The U.S. Geological Survey and Natural Resources Canada conducted a study on the net import reliance of each North American country, and the impact of North American trade on the net import reliance of 12 nonfuel mineral commodities that are associated with advanced technology products: cadmium, cobalt, gallium, germanium, graphite, indium, lithium, nickel, rare earth elements, selenium, silver and tellurium. The combined results for North America, using 2014 data, showed greatly reduced net import reliance for nearly all of the commodities evaluated, which is largely the result of pooling the resources of production and recovery in Canada and Mexico of materials that are consumed in the United States. This study highlights the mitigation of potential supply risk for critical materials that results from trade within the North American trade bloc. IntroductionMultiple metrics and definitions exist for what constitutes a critical material, but there is broad acknowledgment that a mineral commodity may be considered critical if, among other factors, its production is geographically concentrated, if it has few or no substitutes, or if the country of origin is politically unstable. Numerous governmental and independent researchers have proposed methods of investigating criticality, with differing priorities such as economic resilience or strategic military supplies (European Commission, 2014; Graedel et al., 2015; U.S. National Science and Technology Council Subcommittee on Critical and Strategic Mineral Supply Chains, 2016). While criticality really depends on who is asking the question, and despite the differing priorities, there are several commodities that are commonly found to be of concern. In particular, some critical or potentially critical materials are used increasingly in advanced technologies, or they have complicated supply chains because they are coproduced or are produced in controlled markets.Commodities for which imports are required to satisfy domestic demand are those for which the importing country is net import reliant. Net import reliance (NIR) in this study is calculated as the amount of imported material, including changes in stockpiles, minus exports and is expressed as a percentage of domestic consumption:"

Jan 7, 2018

By Dennis A. Hansen

As part of a U.S. Bureau of Mines program to develop a more continuous titanium metal extraction process that uses domestic resources, a study was made to determine the extraction of titanium (Ti) and iron (Fe) from New York rock ilmenite using fluosilicic acid (H2SiF6). The effects of leach temperature, acid concentration, and particle size were investigated for the rate at which Ti and Fe are extracted from the ilmenite. Within the leach time studied, the extraction data fit a shrinking-core model; the rate-controlling step was diffusion of H2SiF6 through an ash layer resulting from a heterogeneous leaching reaction. The rate is linearly dependent on the H2SiF6 concentration and is inversely proportional to the square of the particle diameter. Using 2.6M H2SiF6 at 85°C, 49% of the Ti and 53% of the Fe in 44-to 74-µm New York rock ilmenite were extracted in 3 h.

Jan 1, 2010

By Joseph A. DeCarlo

For the first time the Bureau of Mines is combining, in one report, comprehensive tabulations on both beehive and slot-type ovens. This publication presents statistical data on the number and capacity of all such coke ovens in the United States on December 31, 1957. Combining data on both types of ovens should prove helpful to those interested in keeping abreast of the latest changes in carbonizing capacity, particularly since the coke has similar properties and uses. Annual reports furnished to the Bureau of Mines by coke-oven operators shared that 78 oven-coke plants were operating in 22 States on December 31, 1957. This was a decline of one plant from December 31, 1956, as the Republic Steel Corp. took the ovens at Canton, Ohio, out of production on December 17, 1957, for dismantling and rebuilding in 1958. Total oven-coke capacity was 80,299,400 tons in 1957.

Jan 1, 1958

By R. F. Tenney

No detailed information has been published heretofore on the performance of small industrial-type anthracite stokers in building-heating service, apparently because of the difficulty of comparing the performance of one unit with that of another over an entire season's operation. Studies of competitive heating fuels have been similarly handicapped, and attempts to compare fuels are seldom technically sound in this investigation, the performance of a 60-in. Losch4 stoker burning rice-size anthracite in a standard commercial boiler was observed during a 4-month winter-spring season. It was used to heat two buildings at the Bureau of Mines' Anthracite Research Center at Schuylkill Haven, Pa., with the customary type of automatic pressure-range control. Attendance was limited to inspecting, fuel weighing, data recording, and ash removal. Results were computed daily and grouped by weekly periods to minimize daily irregularities. The same stoker-boiler unit had already been tested in a series of American Society of Mechanical Engineers (ASME) test code runs, with the stoker running continuously and with other conditions well stabilized A comparison of results from the code test and the building-heating tests provided information not available in the past for a single stoker unit, assisted in analyzing heat losses not computable in a cyclic operation, and established a basis for evaluating stoker performance in heating service.

Jan 1, 1963

By P. W. Jeran

The Stereonet Analysis Program (SNAP) is a mathematics tool which, by means of a computer, reproduces mathematically the manual techniques of pre- paring stereograms. This computer program was developed to provide a fast, accurate, and economical means of analyzing fracture orientation data. It is mitten in FORTRAN IV for use on a UNIVAC 1108 operating under an Exec II system, but can be adapted to other systems. SNAP is currently being used to aid in the analysis of cleats and other geologically induced fractures associated with coalbeds that are being mined underground, Methane flows through the coalbed and into these mine workings predominantly through the fracture system. Therefore, knowledge of fracture orientation is an invaluable aid in the development of methane control technology.

Jan 1, 1970

By Juliana Parreira

La aplicación de sistemas automatizados constituye una oportunidad para incrementar la eficiencia de las operaciones mineras y alcanzar las expectativas de sostenibilidad en la pequeña y gran minería. En este sentido, el presente texto señala la implementación de la estrategia de la automatización en la calidad del ambiente laboral a través de la reducción de las exposiciones a ambientes inseguros que afecten la integridad de los empleados. Asimismo, los camiones autónomos de transporte de mineral (Autonomous Haulage Truck) aseguran condiciones de manejo constantes, optimizando el consumo de combustible y disminuyendo la emisión de gases del efecto invernadero; de forma que los costos de mantenimiento de equipos también son reducidos al tornarse predictivos y controlables.

Sep 14, 2009