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By I. Mc Dougall

Water-cooled copper tap-hole blocks provide an effective means of extending the life of tap-hole refractories, as the lower temperature of the refractory material inhibits wear and other damage and promotes the formation of a protective frozen slag layer. This is particularly beneficial during prolonged tapping cycles. The copper block forms an integral part of the lining, and provides mechanical support to the refractory, facilitating rapid replacement of tapping channel bricks without disturbing the surrounding lining. Safety considerations are an important design factor, and the positioning of the water channels is optimized to prevent leaks although the copper is not in direct contact with the molten fluids during normal operation. Water-cooled copper blocks designed by Tenova Pyromet have successfully been utilized on metal, matte, and slag tap-holes for a number of processes, including nickel, platinum group metals, and mineral wool.

Jan 1, 2014

By Claus Becker

The new, 2.600 m long pipe under the river Elbe in Hamburg/Germany required for 2 traffic lanes, emergency lane and space for utilities a boring diameter of 14,20 m(46,6 ft). According the geology (glacial deposits consisting of clay, sand and marl, all containing big boulders) a Slurry-Shield with crusher was selected. With a minimum cover of 7 m and a maximum pressure of 5,6 bar extensive ground treatment was necessary to make the drive feasible. The machine contains a lot of new developments. The drive was finished in spring 2000 so all experiences can be reported. A special risk sharing contract avoided completely litigation.

Jan 1, 2001

By M. Steyn

The coordination compound tetrakis(1,3-diphenyl-1,3-propanediona to)zirconium(IV), [Zr(DBM)4], (DBM = dibenzoyl methane/1,3- diphenyl-1,3-propanedionol) was synthesized and characterized by single-crystal X-ray diffraction. [Zr(DBM)4] crystallizes in the monoclinic space group P21/c (a = 24.769(4) Å, b = 10.216(5) Å, c = 19.314(4) Å, and = 101.541(5)°). The coordination geometry around the zirconium atom, formed by the eight O-donating atoms of the four -diketonates, is found to be a near-perfect square antiprism. Crystal packing is stabilized by C?H... interactions throughout the crystal lattice. This structure is a noteworthy example of the application of ambient condition synthesis of zirconium compounds in N,N'-dimethylformamide (DMF) as reaction and crystallization solvent, highlighting the possibilities of aerobic condition metal purification through chelation.

Jan 1, 2014

Goethite ore are the third most abundant source of iron. The overwhelming part of these ore is represented by low-grade varieties which cannot be used in iron and steel industry without preliminary beneficiation. Biomass is a renewable solid fuel, which is feasible for the substitution of coke and coal in the manufacturing due to its lower contents of harmful elements and abundant raw material sources. Utilization of biomass in iron ore sintering process as heating agent and reducing agent contributes to energy conservation and emission reduction. The biomass was mixed together with goethite ore for roasting process to investigate the effects of reduction roasting. The results show that the goethite ore is dramatically reduced and magnetized into maghemite by biomass with the biomass dosage less than 20% and the roasting temperature below 650 oC. When the goethite ore roasted with biomass, the magnetization values could be enhanced more than two orders of magnitude, meets the standard of magnetic separation, which could significantly reduce the iron beneficiation cost. Keywords: biomass, goethite, reduction, magnetization, roasting

Sep 1, 2012

By James P. Bennett

The Bureau of Mines investigated the effect of refractory oxide additions, introduced in soluble form, on the high-temperature properties of 90- and 98-pct-MgO brick. Brick samples were soaked in solutions containing Al, Ca, Cr, Co, Fe, Mg, Mn, Mo, Ni, Si, Sr, Sn, Ti, or Zr ions. Additions to 98-pct-MgO brick did not generally result in statistically significant property improvements. Statistically significant improvements were noted in hot modulus of rupture (MOR), slag resistance, and spalling resistance of the 90-pct-MgO brick for additions of Al, Mg, or Sn. High-temperature performance of treated 90-pct-MgO refractories was equal to or approached that of 98-pct-MgO brick. The marked improvements due to tin were obtained with additions of only 1.14 wt pct Sn02.

Jan 1, 1985

By Osarnu Inoue

In Mitsubishi Continuous Copper Smelting and Converting Process, smelting, slag-matte separation and matte converting are continuously carried out in series in three furnaces connected by launders. As a result of this operational configuration of the furnaces, influence of the change in operating condition in upper stream, such as variation of feeds in the smelting furnace, propagates to down stream with some delay. In order to achieve stabler operation, process control algorithm based on the dynamic characteristics of each furnace would be very effective. In this study, the dynamic process simulation model was developed for the smelting furnace. The model consists of two mathematical modules, i.e. the thermodynamic module and the mixing module. The calculation results using operating data obtained at Naoshima Smelter showed good agreement with the actually observed change in temperature, composition and flow rate of matte and slag at the outlet of the furnace. In addition, operation parameters such as reaction efficiency of oxygen and coal, dead volume of melts were estimated.

Jan 1, 1999

By Bruce A. McFarlane

"I WOULD LIKE TO SAY how honoured I am that I have been invited to participate in this panel discussion. I have taken the liberty of narrowing my topic somewhat so that instead of speaking on the Sociology of Professions as a whole I will speak on one aspect of it, that is, on Manpower Problems in the Minerals industry of Canada, with some reference to a new social role for the professionals engaged in this industry. This probably means that I will be encroaching on areas covered or to be covered by other speakers, but I hope that when I do so I will do so from a slightly different vantage point. That is, from a sociological perspective rather than from a historical, industrial, business or professional perspective. I plan to divide my discussion into three areas, namely: (i) problems of ownership and control; (ii) environmental problems; and (iii) manpower and recruitment problems. I do not plan nor am I able to provide clear-cut solutions to the various problems I raise under these three headings. Rather, I hope that my discussion of the problems may form the basis for an extended discussion here and elsewhere. Because of the limitations of time, I will only briefly discuss the first two problem areas noted above – (i) ownership and control and (ii) environmental problems - and I plan to concentrate on the manpower issue."

Jan 1, 1972

By W Angerer

This paper describes the design of the marine riser structures, including the design measures for sealing and protection from flooding, dewatering and connection to the main tunnels, for the Gold Coast desalination plant in Queensland. The risers connect the intake and discharge tunnels to the ocean. Construction commenced on both in April 2007. The paper describes the key design criteria for the risers, the construction constraints that influenced the design and the design of the main elements of the risers and the connections to the tunnels.

Jan 1, 2008

By S. Kamalpour

It has been observed that the productivity of ferromanganese furnaces, and the stability of metal and slag compositions, vary considerably according to the type of coke used as reductant. However, the desired properties of coke for optimum furnace performance are not well understood. In this investigation, the behaviour of four cokes, which exhibited a wide range of performance in ferromanganese production, was investigated by means of laboratory simulations of reducing conditions in the furnace. The Stationary Charge in Controlled Environment (SCICE) technique was used to simulate the conditions in the furnace shaft. Batches of raw materials, mixed in the same proportions as used in practice, were heated at fixed rates to 900, 1100 and 1300°C then cooled. The mass loss was used as a measure of the degree of reduction. Conditions in the lower part of the furnace were simulated by means of melt-reduction experiments in which lumps of coke were drilled out to form crucibles in which enriched ferromanganese slags were reduced at 1500 and 1550°C then cooled. An examination of the raw materials and the cooled, reacted charges using a variety of analytical and characterization techniques enabled the sequence of reaction and changes in morphology of the raw materials to be followed. This enabled an understanding of the behaviour of the cokes during reduction to be developed, which was then used to explain the observed performance of the cokes in practice. By relating the observed behaviour of the cokes in the laboratory tests to measurable properties of the unreacted cokes and to their observed performance in practice, it was shown that to achieve high productivity and good furnace performance, cokes should be selected to have moderately high reactivity towards CO2 (Boudouard reactivity) relative to conventional iron blast furnace cokes.

Jan 1, 2004

By G. W. Jones

The operation of combustion engines of various types at high altitudes and other combustion processes at reduced pressures have made it desirable to determine limits of flammabilities -under these conditions. Experiments carried out by the Bureau of Mines have shown that although natural gas-air mixtures become more difficult to ignite as the pressure is reduced below atmospheric, with a suitable source of ignition the limits of flammability are as wide at 175 mm mercury absolute as they are at atmospheric pressure.

Jan 1, 1949

By J. J. Jakosky, D. H. Zellers

"IntroductionThe Bureau of Mines has been conducting experiments in underground communication during a period of several years, and a brief summary of what has been done is as follows:During 1919-1920, investigations were conducted with the geophone. This instrument was used extensively during the World War for detecting enemy digging and mining operations, by means of the vibrations transmitted through the earth strata.A preliminary investigation using short wave-length (200 to 300 meters) radio equipment carried out jointly with engineers of the Westinghouse Electric & Mfg, Co. during 1922.The step was to investigate ground conduction signaling, (called T.P.S. in Signal Corps parlance)."

Nov 1, 1924

By Chris L. Powell, Russell J. Denny.

"The remotely located Cockatoo Island iron ore mine off the Kimberly coast in Western Australia, which has been in operation since 1951, was recently expanded up to 50m below sea-level using staged construction of a rock-filled seawall around the open cut mining operation. The most recent stage of the seawall expansion required a seepage reducing cut-off barrier to be installed through the seawall into underlying seabed sediments. A line of grout holes at 1m centres was proposed to form the seepage barrier, with grouting extending 17m below the top of the seawall. Top hammer drilling techniques were used to penetrate the 12m deep rockfill to seabed level, and permeation grouting carried out within the rockfill to fill voids and stabilise material around grout holes. The local 10m tides meant that tidal washout of fines and grout would be a major risk, and so a combination of cementitious and chemical grout was used to create rapid gel times. Following permeation grouting, holes were re-opened to allow jet grouting to hydraulically mix and grout permeable seabed sediments below the seawall. Using the duplex jet grout system in a single pass to 17m below platform level, the jet grouting was extended upwards into the seawall fill itself to overlap with the earlier permeation grouting. Finally a soil/cement mixed capping trench was installed using slurry trenching techniques with soil/cement/bentonite mixed backfill in order to complete the grout treatment. The approach taken allowed considerable onsite flexibility in technique. An automated slurry batching plant allowed adjustment of mixes to suit the varying subsurface conditions which were encountered during the works.IntroductionLate in 2013 Wagstaff Piling was engaged to install a seepage barrier through a rockfilled seawall built to allow expansion of sub-sea iron ore mining operations on Cockatoo Island off the remote Kimberley coast in the North West of Western Australia. Earlier stages of seawall construction had used a variety of different construction techniques with varied success, and the history of sub-sea mining on the island had been plagued with failures, including failures in the slope of the seawall itself, hanging wall failure underneath and inside the seawall, and footwall failures as the ore was mined leaving the rock face inclined at 55 degrees, parallel to the bedding. The current expansion, known as the Stage 4 expansion, was more tightly constrained by the pit geometry and available materials than previous seawall expansion stages that adopted clay core and sheet pile seepage barrier solutions. In Stage 4, an innovative grout curtain seepage barrier solution was selected to ultimately provide the necessary cut-off to allow access to high grade ore, while protecting the mine from inundation by the sea."

Jan 1, 2016

By Jorge Munoz Reyes, Guillermo

The new entity, Yacimientos Petroliferos Fiscales Bolivianos, created in 1936 for the development and exploitation of all petroliferous zones of Bolivia, including those formerly belonging to the Standard Oil Co., is doing its utmost to bring about rapid development and by this means to create a new source of revenue for the State. With this in view, Y.P.F.B. has opened a new field in the Samaipata region, on the main road between Cochabamba and Santa Cruz. Installation of machinery has begun for the drilling of several wells on the five anticlines that occur in this region. Work has also begun in the Saipuru field, on the Santa Cruz-Charagua highway, which was discovered by the Standard Oil and temporarily abandoned. In this new field, a topping plant will be installed, to supply gasoline and kerosene to Santa Cruz. Explorations are also being made on the neighboring structures of Saipuru. At the end of 1937, the committee that is to study the region of the Chapare in the northeastern part of Cochabamba, was organized. The structures were studied 10 years ago by Kirtley Mather and other geologists. It is hoped that by March 1938 this camp will begin work, as this zone gives promise of being valuable. Development The capacity of the refinery at Camiri has been enlarged in order that it may supply all the needs of that region. In order that the supply of crude may be adequate, several wells that had been almost abandoned by the Standard Oil are being cleaned out. New wells have been located at this camp following the principal anticlinal structure, and during the first half of the year 1938 several wells will be drilled. The same program is being followed in Sanandita but on a greater scale, as the nearness of this district to the Argentine border, which is the best market for the Bolivian petroleum of the south, allows immediate sale of the petroleum. Possibly a new refinery will be installed at this camp, as the one now in existence is only a rudimentary distillery. At the Bermejo camp, which is farther south, intensive work is being done to bring the wells into production. The Standard Oil produced limited quantities several years ago, but since 1927 the wells of this dis-

Jan 1, 1938

By A. Niedbalska

A technique was developed for low pressure diamond synthesis using a specially prepared glassy carbon. The glassy carbon is produced in the form of solid plates by slow carbonization process of phenol formaldehyde resin interrupted at temperatures of 1273° K, 1073° K, and 923° K. The diamond synthesis is performed using cobalt plates as a catalyst-solvent. Synthesis was carried out at applied pressures of 6.0 and 3.8 GPa and a temperature of 1970° K and 2170° K. The products were analyzed by the x-ray powder dyffraction method and by microprobe to identify the diamond crystallites. The samples were taken from the place of contact between the glassy carbon and the cobalt catalyst. They were separated from the charge by a chemical method. Diamonds of the best form and the largest size were obtained at pressures that were much lower than those used in the traditional graphite method of diamond synthesis.

Jan 1, 1989

By Ramana G. Reddy, Yuxiang Peng

The long-term corrosion behavior of Haynes 230 (H230) alloy in MgCl2–KCl eutectic salt was evaluated at 1273 K for 500 h in Ni crucible in argon gas. The results showed H230 alloy has good corrosion resistance. In addition, corrosion was noted to occur by depletion of Cr, which was deposited on the Ni crucible. Based on the calculation of Gibbs energy of Ni-Cr alloy and exchange current density of Cr in MgCl2–KCl, the Tafel model was constructed to investigate the corrosion potential and rate. The galvanic corrosion can be explained as the predicted results were in agreement with the experimental data.

Mar 1, 2017

The richer, shallower sapphire deposits of the New England region of New South Wales which have been traditionally mined by the small miner are almost worked out. Larger mining and exploration companies are replacing the small miner and exploring for the primary source of sapphire or lower grade alluvial deposits.   Although in recent years considerable exploration effort has been directed at locating the primary source, commercial exploitation of sapphire is still restricted to the working of alluvial deposits.   If the Australian industry is to compete against Asian and African producers it must use cost effective exploration, mining) processing and marketing methods.

Jan 1, 1990

By A. Felipe Uribe-Henao, Camilo Ballesteros, Luis G. Arboleda-Monsalve, David G. Zapata-Medina

Conventional excavation analysis based on total or effective stress methods can result in inaccurate estimation of ground movements when impervious soil conditions or rapid excavation sequences are not found in the excavation (i.e., assumption of undrained response is not valid). The influence of excavation rate, hydraulic conductivity, and excavation geometry on the fully coupled solid-fluid behavior of a braced excavation in cohesive soils are studied parametrically using PLAXIS2D. The coupled excavation analysis is performed using the Hypoplasticity clay model to reproduce the constitutive behavior of soil and the poro-elasticity Biot’s theory to account for changes in pore water pressure due to deformations in the soil skeleton. Results obtained from the parametric studies indicate that excavation rates to hydraulic conductivity ratios, ER/k, smaller than 0.1 and larger than 104 can be used as limits for drained and undrained analyses, respectively. In practical applications, undrained and partially drained excavation analysis with ER/k larger than 102 resulted in a similar ground deformation. However, smaller ER/k ratios demand fully coupled solid-fluid analysis. An analytical method aimed at predicting excess pore water pressures and determining the required type of analysis associated with soil and excavation conditions, e.g., drained, partially drained, and undrained analysis, is proposed herein to accurately estimate the ground movements induced by the excavation.

By N J. Potter, N W. Brand, J M. F Clout

The increasing demand for iron ore with low concentrations of trace elements, puts increasing pressure on iron ore producers for high-quality material. Understanding the mineralogy, petrography, chemistry, and mineral association of iron ore deposits is becoming increasingly important to provide iron ore products that meet the ever-increasing standards of steel mills. Limited attention has been paid to documenting new orebodies beyond bulk RC drill chip assays and product specification data. Therefore, limited information is known about the spatial distribution of minor and trace elements at the hand specimen scale, and elemental deportment within different ore and gangue minerals. In this study, samples from high-grade microplaty hematite, supergene-enriched martite-goethite and hematite iron ores are examined for their elemental and mineral associations. These samples contain distinctive minor and trace element distributions, with the mapping of deleterious elements (eg Zn, As, Cu) enabling the deportment and abundance within the ore and gangue minerals to be assessed. Results from this study show a diverse range of minor and trace mineralogy that are present in typical iron ore samples, in abundances below the detection limit of routine XRD scans, that host the deleterious elements, including but not limited to, sphalerite (Zn and S), chalcopyrite (Cu and S), xenotime (P and Y), apatite (P and Ca), cryptomelane (K and Mn), barite (Ba and S), alkaline feldspar (K, Al and Si) zircon (Zr and Si) and chromite (Cr and Al). The presence of these minerals and associated deleterious elements, even at low concentrations, has implications for producers, with the ongoing restrictions and tightening of environmental constraints in shipped iron ore products. By understanding the distribution and location of these elements within the iron ore, steps can be considered to maintain increasingly higher quality iron ore supply around the world.

Nov 8, 2021

By J. B. Umhau

During 1928 the United States consumed 73,270 long tons of virgin or primary tin, which was approximately 7.5 per cent more than the 68,198 long tons con¬sumed in 1927 and equaled 41 per cent of the world's production in 1928 (approximately 178,000 long tons). Consumers' stocks amounted to 9,268 tons on January 1, 1928, and 8,587 long tons on December 31, 1928, a net reduction of 681 tons. In addition to the virgin tin accounted for above, 12,106 long tons of secondary metallic tin were used by manufacturers of tin products in 1928. These figures are the result of an inquiry addressed by the Bureau of Mines to manufacturers to determine the amount of metallic tin used by them; in reply, 1,307 establishments reported consumption in 1928. The distribution of the amount consumed by various uses, as shown in the allowing tabulation based on Bureau of Mines canvasses for 1927 and 1928 in comparison with consumption by uses reported by the War Industries Board for 1917, emphasizes the fact that new uses for tin have been developed in only minor or insignificant amounts. Furthermore, although the studies for recent years show that some older uses have been discontinued, the amounts involved were all small and insignificant. Variation in consumption from year to year parallels the fluctuations in demand for the already well-established tin products. For example, the manufacture of bearing metals and solders for motor cars and trucks required 19,000 tons in 1928 compared to 16,000 tons in 1927; the canning industry continues to require the greater portion of the tin plate and also much solder. Growth in the electrical and the more recently developed industries (aeroplane, refrigerators, radio, etc.), while affecting total consumption of bearing metals, solders, etc., has made little change in the proportions required for these basic methods of using tin.

Jan 1, 1929

By Mark Ward

The Rincon del Tigre (RdT) complex is one of South America’s largest and best-developed mafic-ultramafic layered intrusions. It is set in the SE Bolivian lowlands, about 50 km from the Brazilian border.The BGS (British Geological Survey) and GEOBOL (Servicio Geologico de Bolivia) carried out an initial investigation of the RdT complex from 1976 to 1986. In this sense, the paper point out the geology background of The Rincon del Tigre, economical potential, typical ore secuence in laterite nickle deposit and pega pega erosional surface (Oligocene).

Apr 24, 2001