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By Alan J. Hurd

"New insights into the development of microstructure in sol-gel films have recently been revealed by several diagnostic techniques, including imaging ellipsometry, ""chemical imaging"" by fluorescent tracers, light scattering from capillary waves, and finite-element modeling. The evolution of porosity during the continuous transition from dilute sol to porous solid in restricted geometries such as films and fibers is becoming clearer through fundamental understanding of evaporation dynamics and capillarity.IntroductionWith sol-gel processing, the full flexibility of solution chemistry can be exploited to make ceramic films and fibers with well controlled compositional characteristics. No less important is the ability to tune porosity and connectivity for specific applications such as optical and electrical coatings and membranes. Since the chemical and physical factors that determine the microstructure are not entirely understood, new diagnostics applied to sol-gel processing are welcome.Sol-gel films and fibers are distinguished by processing that takes a sol through continuous stages of increasing concentration and connectivity of a solid precursor. The liquid carrier is usually volatile or, at least, volatilizable through heat treatment. During deposition through states of increasing solids concentration, this sol might gel, as in bulk sol-gel processing, however, the gel state may be a fleeting transient that quickly empties of liquid. Nevertheless, the structures formed in solution during this stage influence the structure of the final solid. In particular, porosity is likely to be a remnant of networks formed in the sol-to-gel transition. Here we report on experiments whose goal is to discover the factors involved with porosity development."

Jan 1, 1994

By G. R. Drennan, N. J. Wagner, M. J. T. Sebola

The Soutpansberg Coalfield hosts South Africa's hard coking coal reserves. However, coals in this region are understudied compared to other coalfields in the country. This study characterizes the properties of fine-float fraction samples extracted from a wide diameter borehole core in the Makhado Project, Tshipise sub-basin, Soutpansberg coalfield. Conventional analyses were used to determine the coal quality, petrographic composition, mineralogy, geochemistry (including trace element and rare earth element composition), and free swelling index of samples from six coal horizons and three partings from the economic No.6 Seam. The coal samples are classified as medium rank bituminous C coals (0.88 %RoVmr, 0.92 %Rmax) and are highly vitrinitic in composition (97 vol% mineral matter free (mmf)). The samples show strong caking potential (FSI of 9). The total rare earth concentrations range between 570 and 3193 ppm in the ash samples. Preliminary analysis show all but two samples are promising sources of rare earth elements as the total concentrations exceeded the 1000 ppm cut-off grade. Further research is required to confirm these preliminary findings.

Aug 2, 2022

By R. T. C. Rasmussen

"INTRODUCTION This is the second report of investigations describing tests in full-scale commercial heats of steel-using electrolytic manganese having a purity of about 99.95 percent, produced in the Bureau's pilot plant at Boulder City, Nev. The first report dealt with tests in cooperation with two companies can the use,of electrolytic manganese in the manufacture of stainless steel. 3/ Plans aril cost estimates for reasonably large commercial, electrolytic plants based upon pilot-plant experience, as well as the comments of a number of concerns where electrolytic manganese has been tried, are contained in another publication.4/ The tests in cooperation with industry are part of the Bureau of Mines program of investigations of methods of utilizing low-grade domestic manganese ores, thereby the United States leas dependent upon foreign sources of manganese for metallurgical use. The Boulder City pilot plant already has demonstrated the feasibility of producing electrolytic manganese from several of the most important reserves of low-grade manganese ore. As the ferromanganese normally used by the steel industry represents the bulk of the Nation's manganese requirements, the usefulness and possi¬ble advantages of electrolytic manganese in the manufacture of steel must be established if electrowinning from domestic ores is to become an important factor of manganese supply.Preliminary arrangements for the cooperative tests at the Atlas Steel Casting Co., Buffalo,. N. Y., were made with E. L. Altenburg, vice president and general manager of the company, by A. A. Dow. 5/ The data on the tests at the Atlas plant presented herein are based upon reports of E. L. Altenburg and information obtained by the author during a visit to the plant to observe the initial trial heats with electrolytic manganese in the open-hearth and the electric furnace."

Nov 1, 1945

By Batric Pesic

The interactions of mineral-pyrite with T. ferrooxidans were studied by using a cyclic voltametry technique. The interactions with bacteria were examined during the entire growth stage of bacteria (fermentation), The pyrite ?surface invariably drastically changed ' its. properties at the second day of fermentation. Beyond two .. days of fermentation, the cyclic voltamograms were insensitive to convective diffusion produced by stirring. The product layer was examined by SEM,. X-ray diffraction and chemical analysis. The SEM study revealed that bacteria populated the pyrite surface at an extremely high density levels. The high density of bacteria, and the solid reaction products formed on the pyrite surface created conditions for pore diffusion which explained why the CVs became .insensitive to convective diffusion in solution (stirring). The x-r:ay diffraction study confirmed jarosite as a product layer. A mechanism of T. ferrooxidans cells serving as nucleation sites for jiarosite formation is proposed.

Jan 1, 1991

By Norma R. Golumsic

Gasoline and other liquid fuels may be obtained from coal by direct and indirect hydrogenation.3/ The direct process, usually termed the coal-hydro-genation or the Bergius process, was patented in Germany by F. Bergius in 1914 and developed to a commercial stage by the inventor and I. G. Farben-industrie. From a chemical point of view, the coal-hydrogenation process consists of adding hydrogen to the complex coal molecules and removing oxygen so that its chemical constitution is changed to that of petroleum, whereupon the coal substance liquefies, yielding an aromatic crude oil. In the indirect-hydrogenation process, known as the Fischer-Tropsch process (invented by Franz Fischer and Hans Tropsch in Germany), coal, lignite, or natural gas is first converted to water gas, a mixture of carbon monoxide and hydrogen. This mixture of gases, in proper proportion and after suitable purification, is then passed over a solid catalyst at relatively low pressures (1 to 20 atmospheres) and temperatures ranging from 180° to 260° C. The products obtained are gasoline, Diesel oil, liquefiable gases, and paraffin wax.

Jan 1, 1946

By S Flanagan, M M. Mete, A R. Tiryaki, M Guresci

First Quantum Minerals (FQM) operates the Cayeli underground copper mine in Turkey. In response to a lost time incident (LTI) that occurred at the mine in 2022, the mine management decided to introduce a new safety approach on-site. The initiative began with a comprehensive safety culture analysis conducted by Arti Consulting, involving focus group studies. Employees actively participated in candid discussions, sharing their insights on safety issues and offering solutions. These conversations were meticulously audio recorded, resulting in over 150 000 words collected from more than 100 employees. These transcribed narratives then underwent rigorous semantic analysis, with the assistance of a sociologist, to identify and dissect patterns of unsafe behaviour. This analysis found areas for improvement, particularly in near-miss and incident reporting, quality of safety toolbox talks and effectiveness of pre-work risk assessments. Subsequently, mine management deliberated on these insights and devised corrective actions. An emphasis was placed on involving all employees in the corrective actions through communication training, empowering them to own the decisions and changes made. These impactful measures were seamlessly integrated into FQM’s Think! Safety Program, which embodies FQM’s sensible health and safety strategy. FQM partnered with Strika Entertainment (Strika) to develop innovative visual-first safety communication tools that use illustration, animation and graphic design to simplify complex messaging into easy-to-understand edutainment. As part of this approach to safety communications, Cayeli and Strika revamped the safety toolbox talks to encourage employees to voice their concerns and receive feedback when their suggestions were implemented. The response from employees has been positive, with over 200 unsafe behaviours and conditions reported within the initial two months of launching the Think! Safety Program. Remarkably, the Cayeli Mine has not experienced any LTIs for the past 500 days as of 9 December 2023. This paper encapsulates the dedicated efforts to transform Cayeli into a safer mining operation.

Apr 16, 2024

By M. Zavvari

Flotation, as with most engineering disciplines, involves testwork. Commonly this means going from lab scale to pilot scale to industrial scale. It is important to conduct tests to identify key parameters and to optimize even at the lab scale. To reduce the number of tests while maximizing the information, it is necessary to use Design of Experiment and Statistical Analysis. In this communication Fractional Factorial Design was used to identify the effect of 7 main factors on barite flotation recovery from jig gravity tailings at the Dorrin Kashan operation. The factors include: pH, collector and depressant dosage, impeller speed (RPM), pulp dilution, particle size and flotation time. By analysis of the output with Minitab software all factors were shown to have an effect. Among the factors, pH and flotation time have an interaction effect but the others have wise effect as an interaction effect and main effect. Finally, reliability tests at pH= 9, RPM= 1000, collector 1 000g/ton, depressant l 750g/ton, particle size 90 µm, flotation time 90 s, pulp dilution 23 % solids, the optimum level of each factor, were done. At the optimum level a barite concentrate with average specific gravity 4.308 g/cm3, average grade 93.72% and average recovery 90.04% was produced from the jig tail.

Jan 1, 2009

By Benjamin P. Hay

Complexation of a metal ion to a ligand often results in structural changes that introduce steric strain within the ligand. A design criterior:1 for ligands that will complex metal ions more strongly is to choose Iigar:1d architecture, that minimizes this strain. This paper describes how molecular mechanics models can be used to define the degree of ligand binding site organization in terms of' ,strain energies associated with conformational reorganization and distortion of the binding conformer. This approach yields a method to predict how modifications to ligand structure will affect metal binding affinity.

Jan 1, 1999

By C. Cristonffanini, S. Nazari

"In the past, simulation was considered to be an offline tool disconnected from plant operation. Advancements in the computation power combined with utilizing physics and chemistry sciences have allowed us to significantly improve the modeling and simulation technology for mining and mineral processing. This paper investigates the benefits of first principle models and simulation by connecting them to real time operation. Process data are connected to high fidelity models executed in parallel to the operation. In recent literature, this concept is known as Digital Twins. The Digital Twin is used for various purposes such as optimization, virtual instrumentation and condition monitoring. Using IDEAS™ simulation software we are able to construct a digital twin for different equipment inside a mineral processing plant. Two case studies for building a digital twin for the primary hydrocyclone feed pump and thickener underflow are presented. Using the pump’s model, a digital twin is developed and is installed in a gold extraction plant that is able to infer the slurry density in real time. Additionally, it is used for detecting sanding in the pipes and impeller condition monitoring.INTRODUCTION Since the eighties, thanks to advances in computation technologies, computer based simulation of processes using first principle models has become a well-known engineering tool for various industries. As our understanding of processes has increased, their representative models have become more realistic and more sophisticated. Due to this increase of accuracy, use of simulation is becoming more fundamental in process industries. The main goals to use accurate simulation is to decrease the engineering and construction cost, optimize the process design and improve the operation performance by decreasing operation cost and increasing efficiency. The term Digital Twin was first introduced in 2010 by NASA (Shafto et al., 2012) in aerospace industry. Subsequently, the concept quickly spread through other industries. As of today, no standard organization has provided an official and unique definition of Digital Twin for process industries. However, there are three important aspects that are common throughout various descriptions. When simulation is core functionality of the process (1) along the entire life cycle of the plant (2) with direct linkage to operation (3), it is called that process has a Digital Twin. According to Gartner, the concept of Digital Twin has elected as fourth most important disruptive technology for the year 2018 (https://www.gartner.com/, 2017)."

Jan 1, 2019

By R. A. L. Drew, G. Mendoza-Suarez, J. Filipi, R. Vintila, J. A. Kozinski

Economics and environmental considerations along with the increasing demand of hydrogen encourage development of novel technologies such as plasma processing of hydrocarbons and thermal cracking of natural gas. Plasma discharges, either in thermal or non-thermal regimes are expected to allow low temperature and fuel flexible on-site hydrogen generation. The main drawback of thermal plasma reformers is the high-energy consumption resulting from high-temperature operation. On the other hand, non-thermal plasma, generated by dielectric barrier discharge (DBD), is able to simulate the chemical reactions employing much lower energies than those required by thermal treatment processes. The non-thermal plasma process allows for instance, a direct conversion of methane into hydrogen and carbon black with no CO2 release. The focus of this research was on the GHG-free method of H2 generation in compact non-thermal plasma reactors using low, medium and high permittivity dielectric ceramics. A stable, non-thermal plasma was generated by placing a dielectric ceramic between two electrodes with a 25 thou gap and applying an alternating current of 1-5kHz and voltages of 4-8kV. In order to ensure energetic efficient plasmas, experiments were conducted to analyze the behaviour of different permittivity ceramics. It was found that the dielectric properties of a ceramic, when used in a DBD reactor, have a strong influence on the discharge characteristics, which in turn influence the power consumption. Higher dielectric constant resulted in higher conversion rates of methane (higher yield of hydrogen and carbon). At the same time, the mechanical properties of the dielectric material, which are closely associated with its processability, influenced its resistance to electron bombardment, as well as thermal and mechanical damage. Therefore a reliable ceramic should have good dielectric properties, in addition to good thermo-mechanical stability.

Jan 1, 2004

By W. K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating the electrochemistry of mineral flotation. A significant need in this area is greater reliability of sensors. The USBM is testing electrolytic methods to clean and condition redox-sensing electrodes to improve the reliability and extend the service life of these instruments in the harsh physical and chemical environment of mineral processing slurries. A novel method for removing scale from fouled electrodes has been developed that includes anodic polarization to 1.2 V versus the Ag/AgCl reference potential, followed by brief potentiodynamic conditioning. Laboratory results show that this technique removes calcarious deposits from gold sensing electrodes and returns the electrode to useful service within approximately 10 min. Mechanical abrasion to remove the scale is thereby avoided.

Jan 1, 1994

By S. M. Pickering, L. T. Gregg

Appraisal of industrial minerals beneath privately owned land requires a different approach and mindset from valuation of base and precious metals or energy minerals, and from valuation of government-owned mineral lands. First, is it the value of inground minerals or of mining rights that is being sought? Second, value to whom, the mining company, a potential investor, the mineral landowner, a lending institution, the property tax assessor, or a condemnor? Third, how should mineral value be apportioned between the land and mineral owner, and a mining company with limited years of lease-hold interest? These and many other questions must be addressed before a valuation method and Discount Rate are selected. For various reasons the Income Method is most often used, with Net Present Value calculations made for long term predicted mining income. Choice of an appropriate Discount Rate is critical.

Jan 1, 2000

By P F. Hodkiewicz

"Our understanding of mineral resources relies on three basic steps: data capture data interpretation model construction. Until recently, all three of these steps required significant time and manual effort to produce a single resource model for mine planning, typically taking more than a year to progress from drilling to the final block model. Over the past several years, BHP Billiton has been developing innovative workflows in rapid resource modelling projects to significantly reduce these time constraints and make the process more productive by replacing manual activities with automated ones. Rapid resource modelling is the process of combining recently developed off-the-shelf technology with internal technology developments to fundamentally change the way we collect, interpret, model and evaluate geoscience data. Initiatives include automated systems and standardised workflows to make it safer, faster and cheaper to continuously update multidiscipline resource models. Specifically, rapid resource modelling workflows combine: real-time analysis of drill holes and drill samples with downhole tools and hyperspectral scanning systemsautomated interpretation of drill hole intervals based on pattern-recognition algorithmscontinuous modelling workflows using implicit modelling software. This paper outlines technology developments and workflows that provide a more thorough understanding of mineral resources to support faster and more informed strategic, planning and production decisions.CITATION:Hodkiewicz, P F, 2014. Rapid resource modelling – a vision for faster and better mining decisions, in Proceedings Ninth International Mining Geology Conference 2014 , pp 183–188 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 18, 2014

By A G. L Pratt

Inclined troughed belt conveyors are more frequently being selected from a range of alternatives, which include shafts and trucks for ore haulage in underground mass mining projects. Belt conveyor haulage systems are being operated with lifts exceeding those normally associated with truck haulage systems and approaching the limits of shaft haulage systems. A belt conveyor haulage system, in this context, incorporates subsystems for: crushing,tramp detection and removal, andhaulage. This paper presents details of recent inclined troughed belt conveyor systems for underground mining operations, and explores the application of inclined troughed belt conveyors for the increasing demands of future underground mass mining projects.

Jan 1, 2008

By A. B. Hooker

Investigations at the Pittsburgh Experiment Station have shown that the satisfactory operation of aflame safety lamp depends not only upon proper design and assembly of the lamp but upon the kind of fuel used, and that much of the trouble experienced with permissible flame safety lamps at mines is due to the common use of motor gasolines, none of which is suitable in the present types of permissible flame safety laps. This report gives the results of a limited study to determine what satisfactory fuels are available, the specification limits of such fuels, and to suggest modifications of assembly and care of the lamps to improve performance with any satisfactory fuel.

Jan 1, 1938

By R. R. Klimpel

This paper describes four new families of flotation products which are currently being introduced at the industrial level. A brief summary of the chemical basis behind each product family will be given. This is then followed by a selection of flotation examples which illustrate the more important use characteristics that have been observed to date. It is becoming more apparent with further testing that these four new product families can offer both technical and economic advantages to the industrial flotation process operator.

Jan 1, 1992

By F. Parada, R. Parra

"The neutralization process of SO2 from coal burning plants is a well-defined technology using limestone to form CaSO4 according to the following reaction: CaCO3 + SO2(g) + 1/2O2(g) = CaSO4 This paper presents the results of a study carried out to validate the option of capturing SO2 using gases from a non-ferrous smelter; SO2 content was up to 12% using a three-stage fluidized bed reactor. The difference in SO2 content affects equilibrium conditions and kinetics, rendering a direct extrapolation of the high efficiency achieved for low SO2 content impossible. The R&D program consisted of a laboratory study using a semi-pilot operation of a one-stage fluidized bed reactor and the construction and operation of a three-step reactor prototype. Results show that the reaction proceeds according to the unreacted core model that imposes a compromise between CaCO3 conversion and SO2 capture. For high SO2 capture, the calcine from the reactor contained CaSO4 and CaO. A complete capture of SO2 from gases with 8 vol.% can be achieved with a mean reaction time of two hours at 800°C."

Jan 1, 2007

By Rolf A. Knopp

This paper discusses how design differences in FLP diesel equipment in underground coal mines came about. "Design standards" tend to create differences between countries while fostering uniformity among products of competing manufacturers. "Performance requirements," on the other hand, tend to eliminate differences between countries while encouraging competitive development of better products. Examples of regulations from the U.S., Canada. Great Britain. Australia. South Africa, etc., are used to illustrate differences in the design and certification of diesel equipment for underground coal mines.

Jan 1, 1978

By S. K. Palm

The commercial life of a mineral product can be long, but like hitech electronic and software products that soar in sales one day to become obsolete and forgotten a few months or years, mineral products have a life cycle. They are invented, commercialized and eventually decline and disappear from commerce. Diatomite and perlite are produced from mined minerals, but almost none of the products in these industries spring from the earth in finished form. Straight calcined diatomite was invented over 100 years ago and flux calcined diatomite just a few years later. The expansion properties of perlite were discovered and first exploited about 75 years ago. Some applications for diatomite have disappeared or currently face competition from newer products. Dry cleaning was once the second-largest application for diatomite but disappeared over 30 years ago. Both the beer and wine filtration markets for diatomite face increased competition from membrane filters. A pipeline of new, proprietary products is critical to the future of the industry.

Mar 2, 2022

By B. Vasanthakumar

In this study, the effect of adaptation of B.subtilis to sphalerite and galena with respect to the selective flotation of sphalerite from the sphalerite-galena synthetic mixture has been examined. The changes in the surface charge of the mineral and the bacterium, cell wall components and the profiles of secreted proteins are discussed. The flotation recovery of galena increases with the increase in the adaptation cycle of B.subtilis to sphalerite and galena, while the flotation recovery of sphalerite is independent of the adaptation cycle with either mineral. From the gel electrophoresis analysis, the protein profile for the unadapted and adapted cells is found to differ distinctly and this may be attributed to varying molecular weight fractions arising from different growth conditions. Electrokinetic measurements showed shifts in the iso-electric points of not only B.subtilis but also of the chosen minerals after adaptation. Additionally, the zeta potential of B.subtilis is found to become less negative after bacterial adaptation to the chosen sulfide minerals, while it showed an increase in the magnitude of surface negative charge after various enzymatic treatments. The change in the surface morphology and cell wall components such as phosphate, uronic acid and acetylated sugars of the bacterial species during adaptation to sphalerite and galena has been assessed. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite can be preferentially floated from galena in the presence of the insoluble fraction of lysed B.subtilis cells initially adapted to sphalerite, with a high selectivity index. Keywords: bioflotation, b.subtilis, mineral adaptation, sphalerite, galena

Sep 1, 2012