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By M Z. Abzalov

Drilling mineral sand deposits has specific challenges, which are different from drilling hard rock deposits: Drilled sequences are represented by non-consolidated free-flowing sands to semi-consolidated clayey sands and indurated layers. Valuable heavy minerals (ilmenite, rutile, zircon, leucoxene) have an average density of 4.6 g/cm3, which is significantly heavier than the hosting sand matrix; mainly represented by quartz (density = 2.6 g/cm3). The large difference in the mineral densities can result in sample segregation in the drilling rods and capturing devices causing biased composition of the recovered samples. The drilled strata can contain beds of consolidated sediments, hard pan lenses and concretions. Therefore, chosen drilling equipment should be flexible and permit a switch from drilling the free-flowing sands to hard rock drilling. Thickness of the sand hosted mineralisation varies from several metres to more than 170 m. Mineralisation is distributed above and below the water table. Evaluation of the mineral sands deposits is based on hundreds of drill holes and many thousands of samples, therefore drilling methods should be fast and cost effective. The drilling methods commonly used for mineral sand deposit evaluation, include aircore, triple tube diamond and sonic; including its variants, such as vibrocore drilling technique. The ability of the studied drilling techniques to properly address the above listed challenges in mineral sand deposits, whilst maximising the quality of the obtained samples has been compared in three deposits: Corridor Sands (Mozambique), Richards Bay (Republic of South Africa) and Fort-Dauphin (Madagascar).This study has shown that aircore samples tend to be negatively grade biased, underestimating the heavy minerals content, in particular when drilled intervals are located below the water table. Triple tube diamond core method can produce non-biased samples. However, results can be marred by incorrectly chosen drilling mud. Sonic drilling is a relatively new technique based on a high frequency vibratory technology. It is the only production drilling technique that allows a continuous relatively undisturbed sample of unlithified sands to be obtained. The main limitations of this technology preventing its wider use for developing mineral sand resources are the relatively high drilling costs, in particular when the depth of drilling exceeds 100 m, and speed of drilling advance.

Oct 5, 2011

By Charles A. Steen

Publication of this information circular results from an invitation extended to the Bureau of Mines by the Utex Exploration Co. to visit the company mine, on the Mi Vida claim about 39 miles southeast of Moab, in the Big Indian mining district, San Juan County, Utah. The Bureau is pleased to present this record of the Utex mine -- a property that in the relatively short period of 4 months has become one of the major uranium-ore producers on the Colorado Plateau. The ore deposit was discovered in July 1952 by Charles A. Steen, a geologist-prospector, now chief geologist of the Utex Exploration Co., in tae course of drilling the first diamond-core borehole in the Big Indian district. High-grade ore, 14 feet thick, was penetrated by the borehole. Sinking of a shaft, from which to develop the ore body, was begun in October, and the first shipment of ore left the property December 6, 1952. Ore production, as recorded on ore-settlement sheets received by the company up to July 15, 1953, totaled 16,000 tons averaging, 0.51 percent U305 and 1.25 percent V205. Discovery of the ore body and the large production of ore were achieved without any financial assistance from the Government.

Jan 1, 1953

By George T. Faust, S. R. B. Cooke

"The Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama, is investigating the preparation of pulverized coal for fuel. In this study the relative amount of surface in various products and samples had to be assessed. Because of the familiarity with screens and because of the simplicity of using the inverse ratio of the opening for ascertaining the amount of relative surface in the respective sizes, screens down to and including 270-mesh were used. This choice was made in full cognizance of the irregularity of screens, but it seemed that if the same screens were used throughout all the tests the relative values would be satisfactory.In dealing with the subsieve sizes, pneumatic elutriation was used to make several fractions to extend the sizing analysis into the range of hypothetical screens. This kind of a sizing analysis was thought necessary because it is familiar to all operators, and, furthermore, it is amenable to several ways of plotting curves that bring out the characteristics of various coals and various methods of grinding.The method of obtaining the data from which to set up the hypothetical screen scale is the subject of this paper. It consists in determining the average projected area of the particles in the respective elutriated products. By extending the ""area method"" to sieve sizes, a factor is found that may be applied to the subsieve sizes, and thus the scale is projected in a regular manner. This method avoids contentions about specific surface and steers clear of ""average diameter"" except as material sized on screens may be said to have an average diameter."

Aug 1, 1939

By A. J. Kauffman

This inventory of the industrial mineral resources of the Pacific Northwest indicates that each of the States comprising this great region annually produces nonmetallic materials valued at mans million dollars. Commodities or their products that have a large, localized market predominate. These include Portland cement, sand and gravel, stone, clay, and lime. The region's output of magnesite, vermiculite, pumice, and diatomaceous earth is outstanding. The magnesite deposits of Stevens County, Wash., are the largest and most important in this country. Mast of the domestic vermiculite production is obtained from deposits in Lincoln County, Mont. Oregon and Idaho rank third and fourth, respectively, as domestic pumice producers. Production data for diatomaceous earth show Oregon second and Washington fourth among the producing States.

Jan 1, 1952

By F. H. Touwen, N. C. Joughin

"Simulation is a technique for studying the operation of systems by synthetic experimentation. With digital computers it is possible to simulate even the complex production processes in gold mining. This has great potential in that it enables the investigation, analysis and comparison of mining systems to be done accurately, rapidly and at low cost. Two programs have been developed to simulate the principal underground production processes in gold mining.These are the simulation of any stope contract and the simulation of underground transport operations. The programs synthesize these mining activities from a large number of small unit operations. The stope contract program simulates rockbreaking by drilling and blasting and the cleaning of the panels by face and gully scraping. The transport program simulates the functions and movements of all vehicles running on rails on one underground level. The simulation programs provide an effective means for experimenting with mining activities."

Jan 1, 2014

By E. F. Vegman, Ndabezinhle Dube

"In the practice of conventional sintering, production is always afflicted with the problem of being unable to get a uniform quality of produced sinter in the bed. Invariably the top layer of the sinter cake is composed of weak but highly sinter, while the bottom layer is over-fused, forming a sinter that is very strong but less reducible. These symptoms point to a variable distribution of the heat balance in the process of sintering which results in a deficit of heat in the top layers of the sinter bed and an excess of heat in the bottom layers, due to an increasing input of regenerated heat in the heat balance down the bed. This causes losses in the productivities of the sinter machine and the blast furnace.The current work was designed to improve on the solution to the above problem through the establishment of a more accurate combustion zone heat balance of the sintering process. This development is mostly on the method of determining the regenerated heat input in the overall heat balance. Previous methods were based on the assumption that the width and the velocity of the combustion zone remain constant through out its whole life, which is not the case since tests have shown that both its width and velocity increase as the combustion zone moves down the bed. In this work, these factors have been taken into account. Tests and calculations using the model were carried out for haematite and limonitic ores. The high sensitivity of the model to changes in the sinter mix composition and sintering conditions was demonstrated.The results present the following prospects:• The minimum theoretically possible coke breeze consumption during the sintering of any type of iron ore fines, under any sintering conditions, can be established.• The model can be used to control the metallurgical quality of the sinter in any point in the sinter bed since calculation data includes desired basicity, combustion zone temperature and FeO content in the sinter produced."

Jan 1, 2001

By C. K. Leith

OTHERS here are far better qualified than I to discuss some of the specific proposals for government regulation of the oil industry. I shall make no attempt to carry oil to Oklahoma. The question of public control, however, is inherent in other branches of the mineral industry in varying degrees, and my comments will be directed mainly toward some of the trends affecting the mineral industry as a whole, as a background for your more specific consideration of oil legislation. A proud American tradition has been the insistence on freedom of competition, on equality of economic opportunity, on a policy of laissez faire. Nowhere has this principle been given wider application than in the mineral industry. The mineral field has been open to all comers, and the job of mineral exploitation has naturally attracted daring and independent spirits. The laws governing conditions of discovery and development, as well as the anti- trust laws, have been devised to foster the spirit of private initiative. The result has been the building of a mineral industry on a scale never before approximated anywhere in the world. The impetus thus gained, the methods, the technique, the financial resources, have been projected be- yond our boundaries and have made the American mineral industry the purveyor to the world for many essential commodities and first in the exploitation of the world's minerals. Our habits of individual self-reliance and success are deeply ingrained, and there is hardly an individual in the entire mineral field who does not instinctively recoil fro111 the extension of collective control, whether public or private.

Jan 1, 1932

This paper discusses equipment replacement strategies and specifically addresses the upgrading of technologically superseded equipment. The process of equipment replacement evaluations is reviewed, and areas have been highlighted where currently accepted practice results in a bias towards retaining existing equipment longer than otherwise justified. The Discounted Average Cost Method is described and the advantages of the technique for this style of decision making discussed. Several key issues influencing the replacement evaluation are also presented together with examples from recent consulting work.

Jan 1, 1992

By H Hoogvliet

The Goondicum Crater industrial minerals deposit is located about 30 km east of Monto, Central Queensland, Australia. Early exploration programs in the 1990s found alluvial ilmenite along the banks of the Burnett River. This mineralisation was traced upstream to the Goondicum Crater. The Goondicum Crater is a topographic feature centred on a roughly circular 6 km diameter layered gabbro complex. Significant ilmenite, apatite, titano-magnetite and feldspar mineralisation are present in a weathered horizon up to 25 m thick. After several drilling campaigns in the Crater and subsequent feasibility studies, the project was developed by Monto Minerals Ltd, an ASX listed company, in 2007. However, the project never achieved production performance expectations and ran out of commissioning funds. The company subsequently went into voluntary administration in August 2008.In 2009, the RMM Capital group, of Brisbane, took control of Monto Resources Pty Ltd, and renamed the company Belridge Enterprises Pty Ltd (Belridge). Belridge commissioned a redevelopment study aimed at recommencing mining and processing operations. As part of the redevelopment study the authors planned a drilling campaign, managed a quality control program and developed a block model. This paper describes the drilling program, analytical procedures, quality control procedures and the preparation of the block model.The block model for the resource estimate was created using 1 m high blocks, wireframes defining the main material types, and 2.5 m thick horizontal search ellipsoids with a radial pattern. The deposit was ‘flattened’ prior to modelling. To assist with the economic evaluation of the project, each block in the model was assigned a net dollar value based on economic parameters provided by Belridge, including anticipated revenues and costs. This modelling technique allowed for efficient investigation of various scenarios and was used extensively in the development and optimisation of the project’s financial model. At a zero net value per block, comparable to a break-even cut-off grade of four per cent ilmenite equivalent, the Indicated plus Measured resource is estimated at 51 Mt, averaging 4.1 per cent ilmenite, 1.9 per cent apatite and 2.5 per cent titano-magnetite.

Oct 5, 2011

By ARCHIBALD DOUGLAS

AT various times during the past quarter century proposals have been made that the basic Federal mining law of 1872 be repealed or amended, and that in its place a new and simpler law be enacted to provide for the entry upon, working, and the taking up of claims on the unallotted Federal mining lands in our western states and in Alaska. Serious discussion and study have been given such proposals but little has resulted there from, except perhaps a lively interchange of opinion and the conclusion that though the Apex law of 1872 is in many ways highly unsatisfactory and frequently a fomenter of strife and trouble, it still bids fair to remain with us. Under this act a greater part of the non-ferrous mining industry of the United States has developed. With all its short-comings it is the legal bridge that has carried over the innumerable caravans of adventurers and prospectors who explored our mining frontiers. For without any amendments of substance this act has for fifty-eight years been the guide in the location of our western Federal mineral claims and has stood unchanged during the most important period of our mining history. While Federal and state acts and amendments have been ground out by thousands and tens -of thousands the mining act of 1872, with a :strange tenacity, has remained as constant as the Rock of Gibraltar, and under it states, mining districts, and local customs have developed different codes for its application but its fundamentals have been unaltered. "Use doth breed a habit in a man"; until now the application of the law of 1872 has become a second mining nature.

Jan 1, 1930

By Ross W. Smith

Microorganisms are increasingly finding use in mineral processing and hydrometallurgy both for the enhancement of mineral engineering operations and for the remediation of mineral industry wastes. Some of the applications, such as biologically assisted leaching of sulfide ores and biooxidation of refractory sulfide gold ores, are established commercial processes. Others, such as the use of organisms for the removal of heavy metal ions from dilute aqueous streams, are nearing commercial application. Other uses of microorganisms are potentially possible. These include use of microorganisms in leaching non-sulfide ores, the flocculation or flotation of minerals and remediation of toxic chemicals discharged from mineral engineering operations.

Jan 1, 1993

By F. A. Renninger

The terms environment and environmental control, when used in today's context, generally imply to the average individual, something to do with pollution and pollution control. These latter terms, likewise, impart visions of fouled air and dirty water attributable largely to the industrial segment of American society. We have been conditioned, by various means, over the past ten years to equate environ¬mental control with pollution control. We have been trained to think of industrial environmental control programs as efforts conceived only to comply with one or more of the recently imposed pollution control regulations. Almost automatically we; approach consideration of environmental control with a degree of pessimism that is we assume that pollution prompted the control program. It is the purpose of this discussion to demonstrate that environmental control. at least as it exists and has existed within the crushed stone industry, involves far more than simply control or reduction of air and water pollution. It involves a dedication to the enhancement of each of the several "mini-environments" which together comprise the total world surrounding any given crushed stone operation. Environmental control, exercised properly, is an optimistic, constructive, forward-looking, enhancing type of activity. It is a function which has been, and should continue to be, willingly and expectantly undertaken by informed management personnel. In short, environmental control. is an activity from which both industry and society can and should benefit.

Jan 1, 1972

By S Maritsa, D Simbi, E K. Chiwandika, S M. Masuka

The steel industry is facing challenges on a global scale that include depletion of resources, huge energy consumption, and the emission of CO2. The demand for iron products is increasing due to the increased infrastructural development. Zimbabwe produced cast iron from scrap metals. However, there is currently a shortage of scrap, and yet Zimbabwe is rich in limonite ores that are currently being underutilised. The possibility of using limonite ore as a sustainable feed for pig iron production was investigated by preparing some limonite ore carbon composite pellets. The results showed that the addition of coal to the limonite ore and calcium carbonate mix to form the composite pellets resulted in a decrease in the drop number as well as the dry compressive strength of the composite pellets. This research aims to improve the physical properties of the green pellets by the careful addition of hydroxyethyl cellulose as a binder that was found to improve the physical properties of the green pellet. This is important for materials handling during the production process of the composite pellets. Results showed that the drop number was substantially improved by the addition of 0.4 wt per cent hydroxyethyl cellulose while the dry compression strength improved from 2.5 kg/pelIet to around 23 kg/pellet irrespective of the amount of binder added. The binder improved the physical strength of the iron-carbon composite pellets enough to allow for large-scale production of the pellets that can be an alternative and sustainable feed for cast iron production. However more results on the indurated compression strength and other properties such as the reduction degradation index, swelling index, and the reducibility test are required.

Jun 19, 2024

By Vijayakumar Viramuthu, Martin Heinrich

Tower of Lot L, L1 & M, Kuala Lumpur City Centre when completed would stand 700 m tall. This Mega tall Skyscraper would merely be less than 500 m away from the world tallest Twin Tower, the Petronas Twin Tower. From June 2018 to February 2020 BAUER (MALAYSIA) SDN. BHD. constructed 225 nos bored piles with diameters of 2.0 m and 2.5 m for this tower. To comply with the depth requirement of the initial design and the need to have the pile toe 2.0 m above competent bedrock, the drilling equipment was required to be able to achieve a maximum drilling depth of 150 m. Actual piles constructed on site were deeper than 120 m. These dimensions caused superlative challenges which included but were not limited to controlling the open borehole stability over time with polymer, installing 70 t heavy steel cages and pouring up to 550 m³ concrete continuously in conjunction with installation of 88 t heavy kingposts into workable fresh concrete. The piling works were executed with one BAUER BG 48 and one BG 72, the biggest drilling rig globally available.

May 1, 2022

By Duane A. Smith

Introduction From the days of the Spanish in the eighteenth century, Colorado's San Juan mining district has attracted miners and public interest. The Spanish left behind names - San Juans, La Plata, Animas, legends of lost mines, and the remains of a few scattered mining operations. They came, but did not stay. Again in 1860-61, as a spinoff of the Pike's Peak gold rush, prospectors climbed the mountains and descended into the canyons searching for gold. They found some, not enough to convince them to remain and confront the isolation, often hostile environment and the Utes, who rightfully felt this to be their home. Not until the 1870s did miners come to stay. In their wake little camps grew in the high valleys and squeezed into narrow canyons. Nowhere else in Colorado were there more rugged mountains, a higher average elevation, nor a climate that one old Swede said was "three months of mighty late fall and nine months of winter." The San Juans proved eventually to be a mineral treasure chest. At the moment, however, the prospectors sought gold. Then they discovered silver deposits and the first rush was on. It got started just in time to be completely overcome by the Leadville excitement. At Leadville, investors almost fell over themselves to buy claims and stock in the hopes of becoming another millionaire like Leadville's own Horace Tabor. The San Juaners could only look from the sidelines and speculate how it might have been had fate been kinder. Fate was seldom kind, as these pioneers quickly discovered. From the mid-1870s on, the San Juaners wrestled with some major problems. And the fate of their district rode in the balance. The problems they faced were similar to those of other Colorado districts, compounded by their geographic isolation. Every mining district needed the best transportation system available, experienced investors combined with sound investment, and mineral reserves to develop. The San Juans offered the last in abundance. It was hoped the first two would appear. Railroads - much needed transportation link Nothing was more desired than railroad connections, the penultimate nineteenth century form of transportation. Colorado's own, the Denver & Rio Grande, resolved the issue with its mountain-hugging narrow gauge. As early as the mid-1870s, the D&RG dreamed of tapping this potentially lucrative market in southwestern Colorado. A national economic depression and then the Leadville silver excitement prevented immediate construction. Not until 1879-80 did survey crews start work.

Jan 2, 1988

By A. L. Holley

The occurrence of this gas, in quite appreciable quantities, has been observed for many years in its escape along the creeks of Western Pennsylvania, and more recently, in much larger quantities, from the oil wells in and near Venango County. Within about five years several gas wells have been struck, from which the gas has escaped continuously in prodigious quantities and at great pressure. During the last year a systematic attempt has been made to utilize the flow of gas from one of these wells, and results have been reached which were quite unexpected. This well, near Leechburg, Armstrong County, is about twenty miles northeast of Pittsburgh, on one of the side tributaries of the Alleghany River. It had been drilled in search of oil to a depth of 1250 feet in 1871, but none was found. A great flow of gas was developed, however, accompanied by a slight spray of salt water, and this has continued with little or no diminution to the present time. The gas in its escape has been discharged through a 5-inch pipe, and at a pressure of from 60 to 80 Ibs. per square inch, but no exact determinations, either of the pressure or quantity, have been made. The rolling mill of Messrs. Rogers & Burchfield is on the opposite side of the river, and it has been for some years devoted to the production of fine grades of sheet iron from charcoal pig metal, by puddling and in knobbling fires. The usual weekly product of the mill has been 30 tons of No. 30 tin plates, and 50 tons of No. 24 to 28 sheets. The well was bought by this firm for $1000, and the gas is led across the river, a distance of about 500 feet, through a 3-inch pipe. It is distributed through half-inch pipes, and at a pressure of about 45 Ibs. per square inch, to several of the furnaces, but a large fraction of the total flow of gas is still wasted at the well. No essential alteration in any of the furnaces has been found necessary in the use of the gas fuel, except to brick up the firebridge and to put in the gas and air pipes. The old grate used for coal is loosely covered with bricks and cinder, so that a slight percolation of air may take place through them. The gas is admitted through a half-inch pipe, and blows toward the fire-bridge through 18 or 20 one-eighth inch jets. The air is blown in at about 2 lbs.

By J. D. Sullivan, Chester R. Austin, J. L. Nunes

It is characteristic of most shales and surface clays that a bloated or vesicular structure is produced by burning to a sufficiently high temperature, usually about 150° to 200°F. above the normal maturing temperature used when making common brick of the same material. Early investi-: gators recognized this phenomenon and attributed it to the release or expansion of gases in the vitrified piece. A number of theories have been advanced on the source of the gas and the manner in which it is evolved, but none has been proved conclusively. T. E. Jackson's1 early theory that bloating was due to oxygen evolved by ferric oxide in forming ferrous oxide or ferrous silicate was never substantiated by - experimental work. Orton2 thought this explanation unlikely, as all clays should bloat at the same temperature, if this were true. He found that clays bloated in the range from IIoo° to 17oo°C. Also, many clays containing iron did not bloat at all, but fused. Orton also stated that oxida- tion of different types of carbon was a source of gas during burning of clay and should be expelled before vitrification was reached. Seger3 said that he had dissolved ferric oxide in glass with no apparent evolution of gas. Matson4 came to the conclusion that ferruginous clays burned ' to vitrification in an oxidizing atmosphere did not have the iron in a ferrous form. According to Wilson,= the gases responsible for bloating might be entrapped air, water, sulphur dioxide, carbon monoxide, oxygen, and hydrocarbons. He spoke of two causes of bloating: (I) incomplete oxidation below the vitrification temperature, and (2) decomposition of compounds and evolution of gases above the vitrification temperature. Decomposition of calcium sulphate was given as the principal example of the latter. Bleininger and Montgomery0 stated that if any time after vitrification began the evolution of gaseous matter was rapid enough so that pressure was produced within the clay, bloating was certain to take place, and a vesicular structure would be formed. They recognized that initial structure, rate of heating, kiln atmosphere, and many other variables affected bloating. Work done by the Emergency Fleet Corporation7 indicated that clays suitable for bloating should be high in compounds of metallic oxides, carbon, sulphur, sodium, potassium, or other equivalent compounds, which either act as a flux or give off gas. Orton2 studied the chemical status of the carbon, iron, and sulphur in clays during various stages of burning, using a Huron shale that bloated under oxidizing or reducing conditions. He found that only a small amount of sulphur remained in the clay and that it could be detected only by dissolving the clay in hydrofluoric acid; i.e., the sulphur was in combination with the silica. orton said that this sulphur was probably in the form of iron sulphide dissolved in the glass phase. The iron sulphide was not broken down by heating, but was dissolved in the basic slag or glass,

Jan 1, 1942

By J. D. Sullivan, Chester R. Austin, J. L. Nunes

IT is characteristic of most shales and surface clays that a bloated or vesicular structure is produced by burning to a sufficiently high temperature, usually about 150° to 200°F. above the normal maturing temperature used when making common brick of the same material. Early investigators recognized this phenomenon and attributed it to the release or expansion of gases in the vitrified piece. A number of theories have been advanced on the source of the gas and the manner in which it is evolved, but none has been proved conclusively. T. E. Jackson's1 early theory that bloating was due to oxygen evolved by ferric oxide in forming ferrous oxide or ferrous silicate was never substantiated by experimental work. Orton2 thought this explanation unlikely, as all clays should bloat at the same temperature, if this were true. He found that clays bloated in the range from 1100° to I700°C. Also, many clays containing iron did not bloat at all, but fused. Orton also stated that oxidation of different types of carbon was a source of gas during burning of clay and should be expelled before vitrification was reached. Seger3 said that he had dissolved ferric oxide in glass with no apparent evolution of gas. Matson4 came to the conclusion that ferruginous clays burned to vitrification in an oxidizing atmosphere did not have the iron in a ferrous form. According to Wilson,5 the gases responsible for bloating might be entrapped air, water, sulphur dioxide, carbon monoxide, oxygen, and hydrocarbons. He spoke of two causes of bloating: (I) incomplete oxidation below the vitrification temperature, and (2) decomposition of compounds and evolution of gases above the vitrification temperature. Decomposition of calcium sulphate was given as the principal example of the latter. Bleininger and Montgomery6 stated that if any time after vitrification began the evolution of gaseous matter was rapid enough so that pressure was produced within the clay, bloating was certain to take place, and a vesicular structure would be formed. They recognized that initial structure, rate of heating, kiln atmosphere, and many other variables affected bloating. Work done by the Emergency Fleet Corporation7 indicated that clays suitable for bloating should be high in compounds of metallic oxides, carbon, sulphur, sodium, potassium, or other equivalent compounds, which either act as a flux or give off gas. Orton2 studied the chemical status of the carbon, iron, and sulphur in clays during various stages of burning, using a Huron shale that bloated under oxidizing or reducing conditions. He found that only a small amount of sulphur remained in the clay and that it could be detected only by dissolving the clay in hydrofluoric acid,i.e., the sulphur was in combination with the silica. Orton said that this sulphur was probably in the form of iron sulphide dissolved in the glass phase. The iron sulphide was not broken down by heating, but was dissolved in the basic slag or glass,

Jan 1, 1942

By J. D. Sullivan, Chester R. Austin, J. L. Nunes

It is characteristic of most shales and surface clays that a bloated or vesicular structure is produced by burning to a sufficiently high temperature, usually about 150° to 200°F. above the normal maturing temperature used when making common brick of the same material. Early investi-: gators recognized this phenomenon and attributed it to the release or expansion of gases in the vitrified piece. A number of theories have been advanced on the source of the gas and the manner in which it is evolved, but none has been proved conclusively. T. E. Jackson's1 early theory that bloating was due to oxygen evolved by ferric oxide in forming ferrous oxide or ferrous silicate was never substantiated by - experimental work. Orton2 thought this explanation unlikely, as all clays should bloat at the same temperature, if this were true. He found that clays bloated in the range from IIoo° to 17oo°C. Also, many clays containing iron did not bloat at all, but fused. Orton also stated that oxida- tion of different types of carbon was a source of gas during burning of clay and should be expelled before vitrification was reached. Seger3 said that he had dissolved ferric oxide in glass with no apparent evolution of gas. Matson4 came to the conclusion that ferruginous clays burned ' to vitrification in an oxidizing atmosphere did not have the iron in a ferrous form. According to Wilson,= the gases responsible for bloating might be entrapped air, water, sulphur dioxide, carbon monoxide, oxygen, and hydrocarbons. He spoke of two causes of bloating: (I) incomplete oxidation below the vitrification temperature, and (2) decomposition of compounds and evolution of gases above the vitrification temperature. Decomposition of calcium sulphate was given as the principal example of the latter. Bleininger and Montgomery0 stated that if any time after vitrification began the evolution of gaseous matter was rapid enough so that pressure was produced within the clay, bloating was certain to take place, and a vesicular structure would be formed. They recognized that initial structure, rate of heating, kiln atmosphere, and many other variables affected bloating. Work done by the Emergency Fleet Corporation7 indicated that clays suitable for bloating should be high in compounds of metallic oxides, carbon, sulphur, sodium, potassium, or other equivalent compounds, which either act as a flux or give off gas. Orton2 studied the chemical status of the carbon, iron, and sulphur in clays during various stages of burning, using a Huron shale that bloated under oxidizing or reducing conditions. He found that only a small amount of sulphur remained in the clay and that it could be detected only by dissolving the clay in hydrofluoric acid; i.e., the sulphur was in combination with the silica. orton said that this sulphur was probably in the form of iron sulphide dissolved in the glass phase. The iron sulphide was not broken down by heating, but was dissolved in the basic slag or glass,

Jan 1, 1942

By E. H. Smith

St. Joe Minerals Corp., a subsidiary of Fluor Corp., treats high-grade gold, silver, and copper ore at its El Indio plant at an altitude of 4 km in the Chilean Andes. The ore is complex, being a mixture of massive pyrite-enargite and quartz, both containing very fine gold and silver. Treatment produces a copper flotation concentrate containing high levels of gold, silver, and arsenic, and also dore bullion. Part of the flotation concentrate is roasted to remove the arsenic content, and arsenic trioxide is collected as a by-product.

Jan 1, 1987