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By Kumar Ashish, Shukla Akhilesh, Kr. Rokkam Kiran, M. Sheeba, S. Sombhatla Sundar

"Purification of zinc leachate plays a predominate role in zinc leaching refineries, to produce impurity free cathode sheets. As a part of such purification sequences, copper cementation with zinc dust is the preliminary step, since the presence of copper will preferentially deposit during zinc electro deposition and has the effect of reducing current efficiency. The cake thus produced is being accumulated as an inventory, due to invariable market and leading to space constraints & hazardous ambience. Hence, a project has been taken up for in-house generation of copper sulphate solution through ammonical leach followed by solvent extraction process and utilizing it as an active promoter for zinc sulphide flotation in Hindustan Zinc’s own captive mines. Cold purification cake majorly contains copper (30-40%) along with zinc (10-20%) and cadmium (2%). Confirmation to the above statement, photomicrographs of purification cake also confirmed the major presence of copper in metallic or oxidized form. In present work ammoniacal carbonate leaching of purification cake followed by solvent extraction using diketone based solvent has been studied under the influence of various parameters viz., temperature, agitation, pulp density, ammonia, CO2 dosages, solvent concentration, and impact of w/s zinc on leaching and solvent extraction. Leaching kinetics determined based on shrinking core model. Chemical reaction at unreacted core was found to be the rate controlling step. The estimated activation energy was found to be 24 KJ/mol. Leached copper has been extracted by solvent extraction with a ß diketone based solvent and is stripped with sulfuric acid as concentrated copper sulfate solution. The above established R&D findings are successfully implemented in the Commercial plant with a treatment capacity of two tons of cold purification cake per batch. Till now 500 MT of Purification cake has been treated, and generated 6500 MT of copper sulphate (55 g/l Cu), with final Cu recoveries between 87-90%."

Jan 1, 2018

By Murali Gadde

Among different types of ground control problems associated with underground coal mining, those related to in situ stresses are the most common ones affecting the safety and economy of a mining operation. As a result, this has been the focus of many ground control research works done in the last three decades. This paper summarizes a recent work done on in situ stress related ground control issues of underground coal mine development workings. The approach used in this study was three¬-dimensional finite element modeling by an implicit code, ABAQUS/Standard. In the models, roof stability evaluations were made using Hoek-Brown rock mass failure criterion. Influence of the in situ maximum horizontal stress angle on the stability of both entry and intersection was examined to help determine the best development layout orientation. Also, the effect of in situ stress ratios on the stability of development openings was studied. To make the work more general, both 'low' and 'high' in situ stress fields were considered In general, the modeling results indicated that entries oriented in the direction of maximum horizontal stress were in the best condition while those oriented at 90° had the least stability. For intersections, the maximum and the minimum stability were seen at 0°/90° and 45°, respectively. However, under some combinations of input conditions, the best or the worst conditions were noticed at same other orientations as well. Based on these findings, layout design charts were prepared for both entries and intersections. It was also found that the change in ground conditions with change in layout orientation was more significant for 'low' in situ stress fields than for the higher ones. Change in the average safety factor with change in the ratio of in situ maximum horizontal to vertical stress resembled a lognormal distribution curve. However, the effect of the ratio of in situ maximum to minimum horizontal stress lacked such a clear trend for different input combinations considered.

Jan 1, 2004

By S. K. Kawatra

Under normal conditions, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. In order to reduce this pyrite recovery, it is first necessary to determine the primary recovery mechanism, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not the major mechanism for recovery of liberated pyrite, and that the bulk of the recovered pyrite is there either as a result of simple entrainment or by being physically locked with floatable coal particles.

Jan 1, 1991

By A. S. Ratnayake, H. C. S. Subasinghe

In this study, we review the role of mechanical activation in the pyrometallurgical, hydrometallurgical, and electrometallurgical processing of titanium feedstock. Mechanical activation has been shown to decrease the activation energy of chemical reactions, thus enhancing process efficiency and product quality by reducing processing time and energy consumption. Pyrometallurgical processing is energy-intensive and time-consuming. Hydrometallurgy is costly, requires high-grade feed material, and generates toxic waste. Waste generation and process complexity are the major drawbacks of electrometallurgy and solvent extraction. Bioleaching via a mechanically activated pyrometallurgical process can be identified as an alternative method, but the lengthy processing time is the major disadvantage. Mechanically activated titanium concentrate can be used in a finely tuned combined metallurgical process to overcome the challenges and drawbacks in these technologies.

Aug 3, 2023

By O. Tshifungat, A. Luzanga, N. Goel, S. Sandoval

"Tenke Fungurume Mining Company (TFM), located in Katanga Province, Democratic Republic of Congo (DRC), began production of copper cathode and cobalt hydroxide in March 2009. Copper production capacity was 115 000 t/a utilizing a semi-autogenous grinding, agitated leach, countercurrent decantation process followed by solvent extraction and electrowinning (SX-EW). Cobalt production capacity (as cobalt hydroxide) was 8000 t/a utilizing a three-stage purification/precipitation process treating raffinate from the copper SX-EW process. Recently a phase II expansion was completed, in which copper electrowinning capacity was doubled and four stages were added to the SX plant. Corresponding enhancements were made to mining, milling, and processing to bring production to 195 kt/a copper and 15 kt/a cobalt. An additional sulphuric acid plant is currently being constructed, adding 1400 t/d sulphuric acid to bring total acid production to 2250 t/d for use in leaching at TFM.Initial copper electrowinning results were satisfactory, but cathode quality and current efficiency decreased as copper production increased. The Freeport-McMoRan (FCX) Technology Centre and TFM personnel began operation of two bench-scale copper electrowinning cells in the tankhouse to diagnose chemistry effects on the cathode and anode. The results indicated an excellent electrolyte chemistry, producing finely crystalline copper at 430 A/m2 current density with 98% current efficiency. Attention next turned to the physical factors of the electrowinning cells, including electrode insulator geometry and performance. A demonstration cell was selected in the tankhouse and was operated with varying cathode and anode insulator geometries. Operation of the demonstration cell with a three-side cathode edge strip, A-style anode insulators, and an improved cell furniture design increased current efficiency from 77% to 89% at 400 A/m2 current density. Cathode quality improved correspondingly. TFM is now operating at 92% current efficiency."

Jan 1, 2016

The standard procedure of fire refining consists of sulphur removal via air injected through tuyeres, arsenic slagging via soda-lime flux and oxygen reduction by air or oxygen deficient air or a steam fuel mixtures. The use of porous plugs to stir with an inert gas has been mainly considered as a surface renewing agent that increases the product quality and shorten the refining cycle. In the present study the effect of the bottom stirring by nitrogen gas injection through porous plugs for the treatment of the crude copper in the range of 400-150 ppm sulphur, 3,000-2,000 ppm arsenic and 14,000-7,000 ppm oxygen content was investigated. The combined effect stirring-reducing, by the use of air or a steam fuel mixtures through tuyeres for oxygen removal, follows a kinetics of first order where the constant, K, can be represented by the following polynomial expression: K = A * R2 + B * R + C Where A, Band C are constants that depend on the nitrogen flow rate and R is the air-fuel ratio or the steam-fuel used in the reducing step. Depending on the optimization of the flow of nitrogen and the air-fuel or steam-fuel mixture and only if just the oxidation, complexing and reducing steps are considered, the process cycle might be shortened by 45%.

Jan 1, 2003

By C. Acuna

The standard procedure of fire refining consists of sulphur removal via air injected through tuyeres, arsenic slagging via soda-lime flux and oxygen reduction by air or oxygen deficient air or a steam fuel mixtures. The use of porous plugs to stir with an inert gas has been mainly considered as a surface renewing agent that increases the product quality and shorten the refining cycle. In the present study the effect of the bottom stirring by nitrogen gas injection through porous plugs for the treatment of the crude copper in the range of 400-150 ppm sulphur, 3,000?2,000 ppm arsenic and 14,000-7,000 ppm oxygen content was investigated. The combined effect stirring-reducing, by the use of air or a steam fuel mixtures through tuyeres for oxygen removal, follows a kinetics of first order where the constant, K, can be represented by the following polynomial expression: K = A .* R2 + B * R + C Where A, Band C are constants that depend on the nitrogen flow rate and R is the air-fuel ratio or the steam-fuel used in the reducing step. Depending on the optimization of the flow of nitrogen and the air-fuel or steam-fuel mixture and only if just the oxidation, complexing and reducing steps are considered, the process cycle might be shortened by 45%.

Jan 1, 2003

Waihi Gold Mining Company Limited, a wholly owned subsidiary of Normandy Mining Limited, operates the Martha gold mine, located in the township of Waihi, New Zealand. The operation, an unincorporated joint venture, comprises Normandy Mining Limited (67.070/0) and Otter Gold Mines (32.94%). Since gold was first discovered at Waihi in 1878, it has formed a key part of the region's economy. In 1909 the Waihi mine was described in a report to Parliament as æthe most important gold mine in Australasia and one of the greatest in the world.Æ That was a record year for production, with 416,813 tons of ore mined and some 1,120 men employed. Today the mine produces up to 1,250,000 tonnes of ore annually, and the project employs some 234 men and women. In 1999 the value of the gold and silver produced ($59 million) made up 47% of Waihi's estimated GDP. Waihi Gold has made significant contributions to the Waihi economy, community and the Hauraki region as a whole. Since the mine was re-opened in 1987, thousands of local people have benefited from the mine. In 1999, consents were granted allowing an extension to the mine life (the Extended Project) and this will result in a further seven years of economic benefits resulting from mining activity. The Company has undertaken extensive consultation throughout project planning, construction, operations and rehabilitation. Ongoing liaison and involvement with all community sectors, including Tangata Whenua and Iwi, local residents, recreational groups and schools remains an integral part of the operation. Throughout the life of the modern Martha Mine, the Company has actively supported the local community in the form of donations, sponsorships, the provision of amenities, and by participating in community events. A well established environmental team exists at the site. Environmental and community performance is measured by an independent five-assessment process, and the Company is committed to achieving excellence through ongoing improvement programmes and staff awareness. When the mine is closed, the open pit area will be transformed into a recreational lake, and the tailings storage facilities will be rehabilitated to become a combination of wetlands, grassed areas and ponds. Resources will be provided by the Mine to ensure the rehabilitated site remains in a safe and self-sustaining, stable condition in perpetuity. The mine is regarded as a showcase on a world standard of how a modem mining operation can successfully coexist with the nearby community.

Jan 1, 2000

By W. W. Adams

The first full year of the second World War for the United States presented a picture of the metal-and nonmetal-mining 4 industry which, without proper analysis and explanation, would convey a distorted view of achievements during 1942, especially because employment at gold and silver (lode and placer) mines-the largest group-declined to such an extent that the over-all totals for the country were reduced even though increases were made at mines producing copper, lead-zinc, iron, miscellaneous metals, and non-metals. A complete panorama of the metal-and nonmetal-mining industry, exclusive of coal mining, reveals a decrease in the number of men employed, the man-hours of employment, and the accident-frequency rates. Were the gold and silver (lode and placer) mines to be considered as a separate category; it would be seen that the number of men employed at all the other groups of mines increased appreciably over 1941. These other increases must be considered important, since these mines produced the vital war minerals that made valuable contributions to the military successes of the United States and its Allies during the year. A separate analysis of each of the various groups of mines may be found elsewhere in this bulletin. For the purpose of maintaining continuity in this series of bulletins, however, the discussion in this introduction will be confined to the entire metal-and nonmetal-mining industry (excluding coal mining, for which a separate bulletin, No. 462, has been published).

Jan 1, 1945

By S. R. Zimmerley

[In the course of a flotation investi~ntion, a siliceous gold ore was ground ir, R 'ball mill to ~inils 300-mesh. It mas found that the small mount of zlus 300-~esh mnterial had a go12 assw approximately twice that of the oricinal ors, md thst this oversize ~roduct also contained much abra?.ed iron. >!oreover, the gold assay of the abraded iron, which was separated ma~etic-dl:;, wno ei::ht tiaes tkat of the ore. These facts sug,~estsd th~t sone r3laticnshin existed between the abnormally high .gold content and the preseace of abrade4 iron. It was ciecided, therefore, to investl~ate furtkor ths acsoclation of the ;old nith the iron abraded from the balls durir-g grincing. As a nrelininary ex?rr>hent, a samy?le of siliceous gold ore 786 grolznd for 1-1/2 hours i;l 3 ball mill and the nuln was divided into two products electri~mag-etically. The racult s follow: ]

Jan 1, 1937

By H. O. McDonald

The Bureau of Mines reviewed the chemical vapor deposition (CVD) literature of the group IVB, VB, and VIR elements. This review was utilized in the Bureau's research to provide erosion-, abrasion-, and corrosion-resistant coatings for valve components used in coal gasification units. This report attempts to bring together the many CVD references that have been published since 1966. Each of the group IVB, VB, and VLB metal coatings were reviewed, and some of their preparation methods, uses, and properties are given. A total of 160 references were found for the nine elements. Isotope separation, stronger steels, solar absorbers, alloys, superconductors, optical fibers, and coatings to increase the life of materials are some of the new uses for CVD.

Jan 1, 1979

By Jimmy Guarnizo

El yacimiento de La Zanja ubicada en el caserío La Zanja, Santa Cruz de Succhabamba, Cajamarca, inició sus actividades de exploración en 1991 y las de producción en el 2010. MLZ construyó el embalse o reservorio llamado Bramadero, que acumula las aguas de escorrentía de la quebrada del mismo nombre durante el periodo de lluvias, las cuales son empleadas para el consumo humano en la unidad minera, y en menor escala durante la época de estiaje para los procesos de operación. En este sentido, el presente texto señala la construcción de la presa Bramadero, la cual genera agua para beneficio de las poblaciones ubicadas aguas abajo de las instalaciones. Asi también cuenta con un programa de monitoreo ambiental para vigilar la calidad y la cantidad de aguas superficiales y subterráneas. Por tal motivo, cuenta con estaciones hidrométricas para evaluar en tiempo real la calidad del agua en los cuerpos receptores del área de influencia de la unidad minera.

Sep 1, 2015

By Kenneth L. Rubow, Virgil A. Marple, Bruce K. Cantrell

"In a cooperative study by the University of Minnesota and the U.S. Bureau of Mines, diesel exhaust and mineral dust concentrations have been measured for aerosols generated in the laboratory and in five underground coal mines. Three mines utilized diesel-powered haulage equipment and two used all-electric equipment. Two source apportionment techniques have been applied to differentiate between the mineral dust and diesel exhaust aerosol concentrations measured. The first technique, using a micro-orifice, uniform deposit impactor (MOUDI) for size selective sampling, is based on modeling aerosol size and the premise that the diesel exhaust portion of the aerosol is predominantly submicron and the mineral dust portion is mostly greater that one micrometer in size. The second technique, Chemical Mass Balance (CMB) modeling, was used to referee the analysis of diesel exhaust and mineral dust aerosol concentrations from the size selective sampling results.The MOUDI size distribution data were modeled to obtain parameters describing the fine and course fractions of the sampled aerosol and to estimate the contributions to each mode from both mineral dust and diesel exhaust aerosol sources. The results showed the size distribution of the mixed aerosols exhibited two definite modes with the minimum between the modes occurring at 0.8 µm. Less than 5 pct of the coal mine diesel aerosol was found in the coarse size fraction. CMB analysis confirms the original premise for using aerosol size to separate diesel exhaust and mineral dust aerosol during sampling.Based on the results from the size selective sampling, a personal diesel aerosol sampler has been developed for measuring diesel aerosol mass concentrations. Th.is sampler uses an inertial impactor to size separate the respirable aerosol at 0.8 µm. All material less than 0.8 µm is collected on an after filter for subsequent gravimetric analysis."

Jan 1, 1990

By J. R. Iwinski

Escanaba, Michigan, is located on the South¬ern shore of the Upper Peninsula on a sheltered area of Lake Michigan called Little Bay de Noquet. The Chicago and North Western Transportation Company has operated a rail-to-ship ore transfer facility at this location for well over 100-years. It is the only terminal of its type on Take Michigan and thus can offer a longer navigation season to lower lake markets than other upper lake ports. It all started in 1864 when the Peninsula Railroad of Michigan, now a part of the C&NW, completed a 100 km rail line from Little Bay de Noquet to the Jackson Mines at Negnauee, Michigan. During that first year of operation approximately 31 000t of ore were loaded onto ships at Escanaba from what was then called the Merchants Dock. By 1871 demand had already exceeded capacity and it was necessary to build a larger dock, which in turn was replaced with a still larger pocket dock in 1903. There are no plans or records available to indicate how the ore was handled from rail to ship prior to the construction of the pocket dock.

Jan 1, 1981

By E. J. Hammer

In the crushing and grinding of metallics for beneficiation, the sizing is normally done to liberate the metals or sulphides for further processing to improve recoveries of the basic metals or minerals. The objective is to reduce the ore in size through various closely controlled stages to that degree of fineness which gives an economic liberation of valuable mineral, but which avoids as much as possible the production of sliming fractions. A different philosophy applies to the crushing and grinding of Gypsum. Our requirements normally demand controlled grinding and/or crushing of the material not only to a fineness suitable for further processing of the mineral into end products, but to produce various sizes of material which are them- selves saleable products. The majority of our tonnage ultimately ends up in stucco for Wallboard. Therefore, our mineral reduction is normally designed toward this end, but it is done in a manner that permits drawing off inter- mediate products to meet various Customer requirements. This forces us into compromises at times in our equipment installations, and our equipment must sometimes be more versatile and complex than we would like it to be. We try to process our basic rock, Gypsum, for the most efficient size reduction. We market 5 to 6 different sizes intermediate to the end product, which generally is the fineness of material to be used for stucco for Wallboard, and we do this with controlled crushing, grinding and sizing cycles of the material. To summarize, we use a different philosophy of crushing and grinding than the metallic field which uses comminution or crushing and grinding to improve recovery, whereas we choose our equipment to crush and grind primarily for product performance.

Jan 1, 1969

By W. Almdal

"To compete in the ever expanding global market, companies must continuously improve. Benchmarking, a tool that can help determine where the best areas for improvement are, is more than comparing measures, it is comparing how business is carried out and how decisions are made. The key to success is in integrating benchmarking results into the organization, so that those most affected by the results own them and are empowered to use them as a positive change agent. This is a necessary step to achieving substantive change to practices and achieving optimum performance improvement. IntroductionBenchmarking is a powerful tool that can assist in the continuous goal of improvement. Benchmarking is more than comparing productivity rates or unit costs, it is seeking out best practices and assimilating them into a business to provide a positive change agent.Benchmarking is a continuous process - is time consuming, labour intensive, and requires a lot of discipline. There are no easy answers and no easy solutions, just a lot of work. The results, however, are nothing short of spectacular. More and more companies are adopting benchmarking practices because it is a key tool of the learning organization and will become part of the way business is done, part of the way it is managed. Business must change to stay ahead or to get ahead and benchmarking can accelerate the process of business change. Improvements in an organization can happen faster and more effectively with a benchmarking approach."

Jan 1, 1994

By K. Rüter

Sustainable investment is a global growth market. Companies that can reconcile economic, environmental and social objectives not only minimise risks, but also realise significant potentials of added value. This particularly applies to the metals & mining industry, as it is an attractive sector for investors and, at the same time, faces major challenges in the field of sustainable development. oekom research AG is an independent rating agency specialised in the analysis and evaluation of the environmental and social performance of companies, sectors and countries for institutional investors and financial service providers in the socially responsible investment (SRI) sector. oekom research has been active in the sustainable investment field since 1993 and its research is currently being used by managers of more than 60 bond and share funds with a volume of assets totalling more than 4.5 billion Euro. The company?s research and its central instrument, the Corporate Responsibility Rating (CRR), are based on the world's most comprehensive set of criteria for the ethical assessment of companies. With the support of an independent scientific advisory board, these universal and industry-specific sustainability criteria are being constantly updated reflecting the dynamics of global challenges in sustainable development. Increasingly, the rating results and benchmark reports of oekom research are also being recognised by the companies as a valuable tool to identify best practices, areas for improvement, and potential risks. This paper will outline the methodology of oekom research, the identification of key sustainability issues in the metals & mining industry, the development of industry-specific sustainability criteria (indicators) for the assessment of the metals & mining industry and key findings of the recently completed CRR of twenty major metals & mining companies.

Jan 1, 2007

By K J. Riihioja, E Nozawa

SmartTag is a radio frequency identification (RFID) based technology designed to allow tracking of ore from its source through blasting, run-of-mine (ROM) pads, crushers, intermediate stockpiles and finally into the concentrator. This paper presents current developments and the future direction of the SmartTagÖ ore tracking system, as well as presenting some case studies. Successful applications of the SmartTag system have encouraged development to allow the system to be used in a wider variety of plants, in particular plants with finer crushing and screening stages. This presented Metso with a number of technological challenges, including RFID tag and antenna design. By reducing the traditional RFID tag diameter from 60 mm to 20 mm the RFID tags can now successfully pass through a secondary crusher. The new smaller RFID tags (referred to as mini RFID tags) have been used in some Process Integration and Optimisation projects with very promising results. The results indicate that the miniature RFID tags have a higher survivability to blasting and through secondary crushing stages. Extending ore tracking further through the process allows more reliable linking of spatial data with time based process performance. Metso is looking at developing even smaller micro RFID tags, and is also investigating other applications for the SmartTag system, including ore tracking from the original source to the final destination (ie from the mine, through the plant and ports to the customer).

Sep 26, 2011

By Alan Rice

Abstract-The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultramafic igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on fluid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other fields dealing with suspended loads in fluids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By Alan Rice

The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultrama?c igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on ?uid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other ?elds dealing with suspended loads in ?uids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997