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By A. G. Lylie

Introduction At the Britannia Mining and Smelting Company's mill, the equivalent of 2,500 to 2,800 pounds of copper sulphate crystals per day is made from copper which is precipitated from the mine-water. This copper sulphate is used in the mill for the recovery of sphalerite by2 flotation. From 1932 until 1936 it was produced by exposing the precipitate to air for thirty days and then dissolving the oxidized copper with dilute sulphuric acid. In 1936, the flotation of sphalerite was discontinued and, when it was resumed in 1947, steps were taken to try to improve the former method. The present paper outlines the way in which this was done, and describes the plant and procedure by which copper sulphate is now being made, and by means of which an appreciable saving is being effected. Aboratory Tests The previous work had established that the precipitate, which consists mainly of metallic copper, must be oxidized before the copper would dissolve in dilute sulphuric acid. Various methods for oxidizing it were tried but in the early laboratory work the only suitable one found was to heat the precipitate to 600°C. and hold it at this temperature for two hours. When this was done, approximately 90 per cent of the copper became soluble in .acid. This percentage was considered satisfactory for practical purposes, but the cost of roasting was prohibitive because only a small amount of roasted precipitate was required each day.

Jan 1, 1951

By James E. Lawver

At the present time, the Florida phosphate industry is experiencing one of the worst marked slumps in its one hundred year history. Recent agriculture over-production has caused low grain prices such that the net income of U.S. farmers is expected to drop to its lowest level since the 1932 depression. The farmers' low income, along with high interest rates that preclude them from borrowing to purchase fertilizer, make the immediate U.S. phosphate market outlook bleek at best. The export outlook is also pessimistic due to world recession and the U.S. dollar's high exchange rate. In June, 26% of the phosphate industry's workers were laid off for an indefinite period of time. Despite the immediate painful slump, the long-term outlook for the industry looks good. Florida has enormous reserves and will continue to produce a third of the world's phosphate supply simply by making changes in the present system of mining, beneficiation, waste disposal and land reclamation.

Jan 1, 1983

By R. Tipman

"In 25 years, processing of tar sand progressed from two small pilot plants to two major commercial operations owned by Syncrude and Suncor. These plants mine tar sand and extract the bitumen which is then converted into a synthetic crude oil. Considerable research on extraction of bitumen from tar sand has been undertaken by these two companies as well as other major oil producing companies, private individuals, universities and the federal and provincial governments. These studies have produced a number of alternate processing schemes which have yet to be commercialized. The producing companies are focusing their efforts on achieving increased processing efficiency, which includes improved bitumen recovery, reduced unit cost, energy conservation, and equipment reliability. In this review, the Syncrude process and examples of new process developments will be briefly described. IntroductionTwenty-five years ago, tar sand processing was limited to two pilot plants owned by Cities Service Athabasca Ltd., and Great Canadian Oil Sands. Earnest Manning was Premier of Alberta and was inviting proposals for the construction of a commercial tar sands plant. The invitations called for a much larger operation than those which had been undertaken in the past. All of the previous attempts at commercial operations up to 1960's had failed, largely because of a poor technical understanding of the process requirements, lack of suitable equipment, and lack of adequate capital. The previous record was not good. The pending new large scale plant was based on improved but not proven technology and equipment, which were developed from the pilot plant studies. In addition, the surplus of conventional oil in Alberta and low world oil prices were factors reducing the need for such a plant."

Jan 1, 1987

By V. P. Yakushkin, B. S. Ksenofontov

"Multistage model designed and used for more detailed description of floatation process. The study develops a new model of flotation kinetics description. It defines flotation as process that consists of several stages: air bubbles and particles are separate, air bubbles and particles form a raising aggregate, aggregate raises to froth layer. This description significantly differs from commonly used model, which is much simplified. The multistage model gives an in-depth description and considers different aspects of flotation. Experimental approval of the new model resulted in its accuracy.The model is to be used for description of all flotation processes’ kinetics of wastewater treatment. It helps in accurate designing of flotation treatment plants and may be used for further research of flotation process. Columnar flotation installation was designed by using multistage model. This installation consists of new tubular aerators with special ejectors, froth pressing system as well as unit of thin-layering lighting to catch microflotocomplex “particle – bubble”. Usage of tubular aerators allowed to aerate the overall volume of pulp. Due to use of special ejectors with longer mixing camera we state higher volume of small-sized floto-active bubbles. Use of multistage model allowed to optimize and get higher technological results of potash salts enrichment. Tests were conducted on centrifuges-floatation installation system. Meanwhile, froth concentrate contained mainly thin hydrophobic particles sized circa 0,1 mm. As a result we set that during floatation cleaning process of froth concentrate 95-98% of chloride potassium (KCI) is derived from foam.The final product satisfies production quality. Columnar floatation installation productivity was 17 – 21 m3/m2h, which is a high technological result. Columnar floatation installation is one of the best examples of concentrating equipment using nearly all technological indices."

Jan 1, 2018

Standards in the public reporting of resources and reserves in Australia have dramatically improved since the implementation of the Australasian Code for Reporting of Mineral Resources and Ore Reserves (The JORC Code) in 1989. Whilst the JORC Code states clearly that Mineral Resources and Ore Reserves are imprecise calculations and should be treated as estimates, there is strong evidence that many people regard them as fact, including some accountants, directors, auditors and investors. Mineral Resources and Ore Reserves are key inputs in the valuation of a mining company and the determination of financial performance. Geological knowledge is the foundation upon which Mineral Resources, Ore Reserves and investment decisions are made, however this information carries with it substantial uncertainty. Case studies and company reports have established that errors derived from inadequate geological inputs have led to reduced profitability in operating mines and in extreme cases the premature closure of mine operations. Whilst there are many causes of mine closure and reduced profitability, including commodity prices and exchange rates, the cumulative effect of all geological uncertainty contributes significantly to the erosion of the credibility of mining within the investment community. There are a number of methods used to characterise and model uncertainty in Mineral Resource and Ore Reserve estimation. Empirical mining indexes, sensitivity analyses, Monte Carlo simulations and Conditional simulations are used to identify and estimate geological uncertainty, notably the quantification of uncertainty in grade and tonnage estimates. These techniques have not generally been applied to estimating geological uncertainty associated with key Ore Reserve inputs such as appropriate mining technique, equipment selection, production rate, mining dilution, stability requirements, materials handling, metallurgical processing, product quality and waste storage. New software tools are needed to model the entire mining process with all its geological and other interdependencies, enabling all uncertainties to be separately identified and estimated. By its very nature, mining involves the assumption of significant technical, financial, political, environmental and social risk. Success comes by understanding and managing these risks and consequently the mining industry will never choose to reduce the level of geological uncertainty to nil. The ultimate aim of improved identification and estimation of geological uncertainty is to quantify inputs into the Ore Reserve process, allowing a company to assess the risks and manage these accordingly. This approach is relevant to feasibility studies for new projects as well as life-of-mine planning through to the weekly schedule at existing mines.

Jan 1, 2003

By V. G. c Papangelakis, M. Huang

A conductivity cell, developed previously, was employed in an effort to investigate the inter-relation between electrical conductivity and acidity of sulphuric acid - metal sulphate solutions at high temperatures. The measured solutions include the H2SO4-H2O, MgSO4-H2O, H2SO4-MgSO4-H2O, H2SO4-MgSO4-Al2(SO4)3-H2O solutions. All solutions reported in this paper were measured from 15 to 250 °C at equilibrium vapour pressure. The maximum measured concentrations of H2SO4, MgSO4 and Al2(SO4)3 were 0.45 m, 0.30 m and 0.10 m, respectively. It was found that, from 15 to 250°C, there is a linear relationship between H2SO4 concentration and electrical conductivities for acid concentration up to 0.45 m. At 250 °C and constant H2SO4 concentration, the solution conductivity drops with the increase of MgSO4 concentration. Lt is suggested that this drop is caused by a decrease in the concentration of H. Finally, an empirical model was developed based on the available measurements. This model has been tested against real laterite leach solutions where sulphuric acid and metal sulphates are dominant electrolytes. The average difference between the estimate acid concentration from this model and the one from titration was less than 5%.

Jan 1, 2004

By Yasuyuki Murayama

MF is the semi-blast furnace which has been developed at Mitsui Miike Smelter in the 1960's to treat vertical retort residue. The MF has also been tested for treatment of various recycling materials and wastes. Now various secondaries and wastes (steel dust, zinc leaching residue, Cu-Ag sludge, spent catalyst and spent rubber, etc.) are mainly treated. Powder materials are briquetted with reductant before being fed to the furnace. Products are crude zinc oxide, matte, non-hazardous slag and steam. Zinc and lead are recovered in oxide dust, and copper and silver are recovered in the matte. The MF furnace can be widely applied to many kinds of materials which contain such non-ferrous metal-valuables. In addition, the improvement in operation and technology has effectively made the unit capacity much larger. The MF furnace now has many advantages for these treatment processes.

Jan 1, 1992

By Michael G. Zabetakis

Vaporization of a solvent into an airstream at temperatures above the flash point of the solvent is hazardous if vapor is liberated at a rate that is sufficient to produce a flammable mixture. In may operations, the formation of such a mixture is prevented by rapid diluton of the vapors with air. The minimum air requirements for the dilution process are determined by the composition of the lower limit mixture at the temperature and pressure of interest. Because limits of flammability cannot always be calculated with sufficient accuracy for a proposed operation, they .rust often be determined experimentally. The present Bureau of Mines investigation was prompted by an application in which the lower limits of flammability of a number of solvent mixtures were required over a range of temperatures at atmospheric pressure. These limits were to be used along with available solvent-vaporization-rate data to establish minimum airflow rates needed to prevent the formation of flammable mixtures in an industrial process. Lower limits of flammability were determined for a number of mixtures containing methyl ethyl ketone, tetrahydrofuran, toluene, ethyl alcohol, and ethyl acetate in dry air-at atmospheric pressure and temperatures between 16° and 200° C. The experimental values were found to be in good agreement at with those predicted by Le Chatelier's law; variations with temperature were in fair agreement with those predicted by a modified Burgess-Wheeler law.

Jan 1, 1962

By S Hille, J Karageorgos

With the increased variability of todayÆs large-scale mining operations, consistent flotation performance is important to improving and sustaining overall recovery through the circuit. The Newcrest Telfer Mine has implemented advanced process control technology to obtain stable level operation and consistent mass pull in the copper rougher and scavenger flotation circuits. The final result has been an overall reduction in variability, which impacts on both copper and gold recovery. This paper describes the methodology and implementation of the improvements in control at the Newcrest Telfer Mine as being an essential part of the business for minerals processing.

Jan 1, 2007

By H. H. Rachford, J. Douglas, D. W. Peaceman

A numerical solution of equations describing two-phase flow in porous media shows promise in providing a technique for predicting the displacermet from satlds of oil by water or gas. The description includes the influence of relative permeability, fluid viscosities and densities, graviry, and capillary pressure, and, tholrgh tested ortly for two-dimensional cases, should be eqlmlly applicable in three-dimensional geometry. Two memorical methods ore presented: the first method is quite general in its applicability; the second method can be used only with certain types of boundary conditions but requires less computing. Comparisons of computed results with data from Inhoratory models are presented. These data were taken on a water flood of a strarified model and on water floods of a five-spot model for favorable and unfavorable mobility ratios. On the stratified model, excellent agreement with recovery at breakthrough was obtained; agreement with recovery after breakthrough was poor. In the five-spot model, good agreement was obtainecl with recovery at and after breakthrough. The purpose of this paper is twofold: first, to present a reservoir engineering method requiring knowledge only of rock geometry and the normally measured rock and fluid properties for calculating the multi-dimensional flow of water displacing oil from porous, water-wet rock containing connate water; and, second, to investigate the validity of the method by comparing results of calculations with previously observed displacements in laboratory models. The availability of such a verified technique of reservoir analysis would afford major advantages. First, it would demonstrate that the fundamental macroscopic concepts of two-phase fluid mechanics, i.e., relative permeability and capillary pressure, yield an adequate description of the physical process. Also, since most reservoir rocks appear to be water-wet and contain connate water along with oil, it would provide a method of technical and economic value for calculating the course of oil displacement by water directly from measured reservoir and fluid properties. It is important to emphasize that the calculation is subject only to the limitations of detail and precision of reservoir information, but not to limitations introduced by simplifying assumptions. Further, it would providc almost the only means of examining the influence of factors such as the size and extent of reservoir inhomogeneities and uncertainties in the basic reservoir data. Knowledge of this influence is essential in stating quantitatively the detail required to define a reservoir and in establishing the relation between the uncertainty in the definition of reservoir properties and the reliability of predicted performance. Moreover, in the process of solving a particular problem much detailed information would become available about the displacement process. For example, at each point in the reservoir for all stages of the displace ment. the calculations would yield not only the water and oil saturations but also the direction and magnitude of fluid velocities and the local fluid mobilities. Such dctail is potentially of great value in giving insight into the mechanics of particular displacements. The development of such a method has long been the goal of research in the application of numerical an-alysis to petroleum reservoir enginecrinz. The most complete treatment of the displacement process published to date is that of Douglas. Blair, and Wagner,' which, however, was limited to flow in a single dimension. The method presented in the present work is hascd on the numerical solution of a finite difference analogue of the multi-dimensional differential system describing the displacement process. Although current work has considered only displacement of oil by water from water-wet sands, the differential system for other immiscible displacements, such as gas displacing oil with which it is in phase equilibrium, is quite similar. It should therefore be expected that the technique described will be applicable to displacement by gas as well. The description of the simultaneous flow of fluids through porous media in terms of relative perrncability and capillary pressure has been adequately discussed in the literature and standard textbooks. Sec, for exampje, Muskat. Chapter VII.'

By G. Kazonich, S. L. McGill, J. W. Walkiewicz

Naturally occurring minerals and reagent-grade compounds were tested to determine their receptivity to microwave heating. The maximum temperature achieved for the samples and the time required to reach temperature are reported. A description of the microwave oven and a thermocouple technique that accurately measures and continuously records the temperature of samples during irradiation are reported. Extractive applications using the generated microwave data were investigated. Stress fracturing at mineral grain boundaries in a gangue matrix was shown. This should significantly affect grinding energy requirements and liberation properties. A method to produce a magnetic phase on pyrite surfaces, a method of using microwave heating to retort cinnabar concentrate, and a roast-leaching microwave treatment of chalcopyrite ore are described.

Jan 1, 1987

By J. Morris, R. Sellaro

El petrodiesel es un colector común para la flotación de carbón, pero la partición de compuestos orgánicos de diesel (DRO por sus siglas en inglés) en corrientes de proceso no ha sido ampliamente estudiada. Investigaciones preliminares sugieren que bajo esquemas de dosificación normales los contenidos residuales totales de DRO en aguas de procesos deben estar limitados a la fracción soluble en agua (WSF por sus siglas en inglés) sub-ppm. Es más, los hidrocarburos aromáticos poli-cíclicos (PAH por sus siglas en inglés) debería segmentarse de manera proporcional con los compuestos orgánicos de diesel (DRO). El propósito de este estudio fue confirmar estos resultados en pruebas de flotación realizadas en laboratorio. Se midieron los contenidos totales de DRO Y PAH en aguas asociadas con los flujos o corrientes de concentrados y relaves. Los resultados muestran que las aguas con concentrados tenían de manera consistente mayores cantidades de DRO que las aguas de relaves. Es más, los contenidos de DRO en ambos flujos generalmente se incrementaban con el aumento de la dosis de diesel. De acuerdo con la investigación preliminar, los DRO parecían estar limitados a la fracción soluble en agua (WSF) y los PAH tendían a segmentarse proporcionalmente con los DRO. Bajo condiciones de operación típicas, los DRO residuales no deberían representar una preocupación medioambiental, pero deben evitarse situaciones que permitan una sobredosis significativa de diesel.

Jan 1, 2014

By G R. F Alvear Flores

Mineral resources are becoming more complex in composition and structure making it more difficult to produce clean concentrates for primary metal smelting. In parallel, providing technological solutions to the recycling and recovery of end-of-life materials is becoming more important in moving towards the goal of increasing circularity. The availability of fundamental thermodynamic data and advanced thermodynamic tools greatly assists in evaluating these complexities and their impact on existing and new processes. In addition, it is fundamental to support the economic performance of smelters. This paper describes several examples on how fundamental work can be applied to industrial processing..

Jun 17, 2024

By A. López-Valdivieso, M. A. Corona-Arroyo, M. Llamas-Bueno

Magnetite (Fe3O4) ore is concentrated by low-magnetic-field drums to recover a magnetite concentrate that is low in silica (SiO2). The presence of SiO2 in the magnetite concentrate for steel production increases the steel processing costs, so a major challenge in magnetic concentration is to lower the SiO2 grade in the Fe concentrate. This work presents studies that were carried out on the removal of SiO2 from the magnetite concentration at the plant scale. Studies were performed with a three 36 × 96″ drum unit processing 46 ton/h of rougher magnetite concentrate. These studies showed that silica appears in the magnetite concentrate by three mechanisms, namely SiO2 entrainment in Fe3O4 chains, heterocoagulation between Fe3O4 and SiO2 particles, and mineral locking of SiO2 to Fe3O4. The SiO2 entrainment mechanism had the highest contribution (75%) to the SiO2 recovered in the Fe concentrate. Electrokinetic studies on Fe3O4 and SiO2 showed that heterocoagulation occurs because of the low negative zeta potential of the minerals at the pH of the plant slurry. This study also showed that a high percentage of ultrafine size SiO2 particles trapped in Fe3O4 agglomerates was not removed by the dilution water for the slurry fed to the drum. To lower the SiO2 recovery in the drum magnetic concentration process, work should be directed towards the removal of trapped SiO2 in Fe3O4 agglomerates.

By James C. Barker

In 1981 and 1985-1986, the Bureau of Mines conducted orientation studies of marine placer platinum-group metals (PGM). PGM are derived from the Goodnews Bay ultramafic complex and magnetic surveys show that the complex extends offshore at least four mi. The present seafloor was an emergent foreland as recently as 8000 years ago. High-energy ocean processes are transporting and depositing sediment such that PGM-bearing materials are reworked and later masked by barren littoral drift. Exploration targets include 1) placers formed since present transgression began, and 2) ancient marine and drowned fluvial deposits. Additionally, there is evidence of PGM solution transport and accretion. At least minor values of PGM in Recent lag-type placers and possible submarine strands are concentrated along an offshore scarp incised through glacial deposits into the preglacial surface between Flat Cape and Red Mountain. Other Recent PGM-bearing features include Flat Cape shoal, Chagvan Bay, Salmon River delta, and modern beaches. Ancient placers include possible N-S fluvial systems 2 to 3 mi offshore, a nearshore scarp 50 ft below sea level, and strands adjacent to projected ultramafic bedrock slopes. The existance of ancient placers is dependent on depth of glacial erosion. SEM studies show PGM are principally isoferroplatinum and osmiridium, with minor sperrylite, moncheite, and platiniridium. Gold is a co-product, and concentrates comprise chromite, ilmenite, and magnetite. Beneficiation tests successfully concentrated precious metals from natural blacksand accumulations, but failed to concentrate low-grade lag gravels.

Jan 1, 2011

By Y S. Zhang

Natural phenomena and human engineering construction activities had great influence on the geosciences space. Natural disasters, particularly mine disaster and other geological disasters happened frequently, which brought great losses both in people’s lives and economics, therefore, to explore the essential causes and mechanisms of disaster by some useful approaches is the most important step in mine disaster prevention. In a variety of methods, building an aground-underground seamlessly integrated model, and then analysing the formation and development mechanism of mining disaster based on this model is a useful way. In this paper, we studied an aground-underground seamlessly Integrated modelling method, and correspondingly given an aground-underground seamlessly integrated 3D spatial model, CSG+CD-TIN+GTP-TTS, by which we can carry out analysis of surface subsidence and underground laneway distortion efficiently, finally preliminary applications verified the effectiveness of this method.

Nov 22, 2011

By Sherwin F. Kelly

THE geophysical scene shifts and alters, the emphasis changes, and new possibilities loom, but the tendency is always towards widening the field and deepening the analytical penetration. Seismic methods have had their heyday, the torsion balance is being displaced by the gravimeter, electrical methods are showing deeper penetration, soil analysis is the newest tool, and gamma-ray logging appears on the horizon. One of the striking features of re- cent geophysical work in the oil fields has been the marked decrease in the number of seismic crews employed. Although the percentage of company crews is believed to have increased appreciably. the sum total has fallen sharply, as shown by the figures for the Gulf Coast area. About two years ago probably over 100 seismic parties were operating there, whereas now there are only about 35. This decrease may be partly due to the low prices of petroleum with a consequent reluctance to spend money to increase crude-oil re- serves but more probably to the fact that reflection and refraction shooting have been carried on so extensively that they have been applied to a large pro- portion of the areas in which they may reasonably be expected to succeed. Some of the earlier enthusiasm, particularly over reflection prospecting, may have erred on the side of over- optimism; some of the present curtailment may be due to over pessimism; but in the opinion of various observers seismic work at the present rate seems to be at it- optimum. It nevertheless remains pre-eminent as a technique for detailing structures in areas where good reflections can be obtained and is the only method that will give accurate depth to definite beds. Results may be poor in certain areas but many regions still remain wherein it can be applied, so that plenty of structural mapping remains to be done by the reflection seismic method.

Jan 1, 1940

By D. R. Lanners

Samples of the same coal measure overburden spoil were obtained from three different mine sites. Site A used a 27-m3 tub-mounted dragline, Site S used a front-end loader and truck combination, and Site C used a 6-m3 crawler-mounted dragline. The spoils were analyzed in the laboratory for the strength parameters using drained triaxial tests conducted on 150-mm diameter specimens. Regression analysis was utilized to determine the appropriate failure criterion for the strength data from each site. Spoil obtained from Site S yielded higher shear strengths than Sites A and C.

Jan 1, 1993

By William Blake

Mining induced rock bursts have been a severe operational hazard associated with the deep silver mines of the Coeur d'Alene mining district for over 30 years. Recent studies during the past fm years have led to a better understanding of the different types of rook bursts and their causative mechanisms. This has resulted in ground control measures that more effectively minimize burst occurrences as well as contain burst damage. Case histories of burst incidences and examples of control measures are presented.

Jan 1, 1987

By D. Gorc, T. M. Fraser, Z. T. Nikic, R. Pesalj

"Mount Polley is an alkalic porphyry copper-gold deposit of Lower Jurassic age within the Quesnel terrane in south-central British Columbia. The silica-saturated Mount Polley intmsive complex is assumed to be coeval with volcanic rocks of similar composition in the Nicola Group in which it was emplaced. Other intmsions and some of the volcanic rocks in the Mount Polley area are silicaundersaturated and contain feldspathoids.The Mount Polley deposit is characterized by multiple intrusions that vary from diorite to crowded plagioclase porphyry to monzonite. Intmsion breccias are associated with some of the intmsive phases. Abundant hydrothermal breccias occur on the margins and above plagioclase porphyry intmsions. These breccias provide the main host for mineralization and are associated with the highest concentrations of copper and gold. The breccias are subdivided into four distinct types based on the dominant hydrothermal mineral in the matrix. Actinolite breccia is developed in an elongate zone within the core of the Central zone and grades laterally and vertically into biotite breccia to the southeast. Magnetite breccia is irregularly distributed and is relatively sparse throughout the deposit and albite breccia is dominant in the West zone. Pervasive and vein-related alteration correlates with the breccia types. The core of the hydrothermal system at Mount Polley is subdivided into three zones: actinolite, biotite and K-feldspar-albite. The margins of the core zone are overprinted by a discontinuous zone of calc-silicate minerals. This intermediate zone passes outward into propylitic alteration. Mineralization is most prominent within hydrothermal breccias and is generally present as disseminations, blebs within the matrix and abundant veins. Mineralization is associated with a chalcopyrite-magnetite-bornite assemblage in the core of the deposit passing out into magnetite-pyrite-chalcopyrite. Relatively constant copper to gold ratios suggest that both metals were precipitated under similar conditions.Hydrothermal breccias are genetically related to the emplacement of the crowded plagioclase porphyry melt. Crystallization of the melt was probably accompanied by volatile/aqueous exsolution, forming a water saturated carapace. Decompression of the chamber in response to magma withdrawal, fracture propagation and possible fault movement allowed hydrothermal brecciation to occur at the apex and margins of the intmsion. Alteration and mineralization appears to have been controlled by fluids migrating away from the plagioclase porphyry."

Jan 1, 1995